钼矿石物相的快速分析方法

钼矿石的主要矿物有辉钼矿,其次是钼钨钙矿、铁钼华矿、钼华矿和钼酸铅矿。样品经碱熔融分解,硫氰酸盐比色法测定总钼;利用电感耦合等离子体质谱法测定氢氧化铵溶解钼华中的钼;酒石酸溶解钼钨钙矿中的钼;碳酸钠溶解钼酸铅矿中的钼;盐酸溶解铁钼华矿中的钼。方法对不同钼矿石样品进行了5种钼矿石物相分析,结果与实际地质成矿组分符合。     

河南洛阳市土壤和农作物中钼分布规律与影响因素研究

钼是人体和农作物必需的有益元素,具有防癌抗癌作用。由于不同地区土壤中钼含量和土壤酸碱性的不同,农作物中钼含量有很大差异,同时不同农作物对钼的吸收也不相同。研究不同农作物中钼富集规律可以为健康地质发展、富钼农产品开发、功能农业发展、种植结构调整提供依据。本文以洛阳市硒资源详查区及其他农业种植区为研究区,通过采集22种大田种植的农作物及其根系土,采用电感耦合等离子体质谱法（ICP-MS）测定土壤和农作物钼含量,研究了不同农作物钼含量特征及其影响因素。结果表明：洛阳市土壤钼含量较高,是中国土壤富钼特色地区。绿豆、豇豆、黑豆、黄豆、红小豆和花生是富集钼的主要农作物,钼平均含量>9mg/kg,富集系数>500%,属于钼的超富集农作物。芝麻、豆角、谷子、小麦、玉米和油菜籽钼含量较高,钼含量均值介于0.446～2.437mg/kg,富集系数介于40%～300%,属于富钼农作物。辣椒、大蒜、红薯、秋葵的钼含量介于0.1～0.3mg/kg,富集系数介于10%～30%,属于高钼农作物。苹果、梨、葡萄、石榴、樱桃与中药材银条的钼含量<0.05mg/kg,富集系数<5%,是低钼农作物。大多数农作物钼含量与根系土钼含量呈正相关,而苹果、葡萄、石榴、樱桃等水果钼含量与根系土钼含量呈负相关。研究揭示了在碱性环境下土壤中的钼更容易被农作物吸收。区内农作物与中国其他地区相比均呈富钼特征,是开发富钼农业产业的有利地区。依据不同农作物钼含量,选择出绿豆、豇豆、黑豆、黄豆、红小豆和花生是研究区特色富钼农产品,芝麻、豆角、谷子、小麦、玉米和油菜籽是富钼农产品,辣椒、大蒜、红薯、秋葵属于高钼农作物。本成果为研究区富钼农产品开发、调整种植结构提供了科学依据。     

农业生态与土壤环境中钼元素的关系

本文论述了钼元素的地球化学特征及其分布,与钼元素有关的主要作物分类,作物产量和质量与钼元素的关系以及影响钼元素有效态和作物吸收钼元素的因素,钼肥的种类和施用方法与效果。     

从铀矿石浸出液中回收钼的实验方法

本文系统地研究了201×7阴离子交换树脂从铀矿石酸性浸出液中吸附铀、钼的吸附酸度,选择出最佳淋洗铀、钼的淋洗剂;采用不同的淋洗剂分步解吸的方法,使铀和钼分离,用沉淀法以氯化钙为沉淀剂,使淋洗合格液中钼生成钼酸钙沉淀;对沉淀酸度和沉淀剂用量进行优选,在选择的最佳条件下生成钼酸钙沉淀率为99%,钼酸钙产品中的钼质量分数≥30%为合格的产品。     

460铀钼矿床综合回收初步研究

460铀钼矿床综合回收是采用铀钼矿样和钼矿样分别浸出→固液分离→两种浸出液混合→萃取和反萃取铀钼→分别精制铀钼产品的水冶工艺流程。铀钼矿的铀钼浸出率分别达到90%和75%以上,钼矿样钼的浸出率达70%以上,取得了稳定的工艺参数;铀钼分离取得了较好的结果,制出了合格的铀、钼产品。     

陕南石煤及煤灰中钼元素在固液间迁移规律

钼是典型的环境敏感元素，同时也是潜在的稀有金属元素，为了查明钼元素在原煤和煤灰中含量特征及其在固（体）液（体）间的迁移规律，选取陕南石煤及煤灰样为研究对象，利用电感耦合等离子体质谱仪（ICP-MS）分析样品中钼元素含量，通过浸泡实验模拟纯水、酸性、碱性和矿井水4种溶液中石煤及煤灰中钼元素浸出率。结果显示:石煤中钼元素含量为315.4~785.4 μg/g，煤灰中钼元素含量675.5~1 005.1 μg/g，燃烧后钼元素具有向石煤灰中富集（迁移）的趋势；不同类型溶液对石煤中钼元素均呈现不同程度的浸出率，总体特征为酸性溶液中钼元素的浸出率普遍偏低，低于其他3种类型溶液；而石煤灰中钼元素在不同溶液中浸出率不同于石煤样，总体特征为酸性溶液中钼元素的浸出率较高。结合浸出量进一步分析表明，酸性条件抑制了石煤中钼元素的迁出能力，而石煤灰样在酸性溶液中的钼浸出率与浸出量普遍高于其他类型溶液。分析认为，有氧燃烧使有机质释放钼元素、含钼矿热解、对钼的吸附能力等方面发生了变化，导致石煤灰中钼元素的迁移能力有所提升。研究认识具有环境保护和钼元素提取利用双重指导意义。      

淮北平原农用地土壤钼测定与分布特征及影响因素

钼作为植物固氮酶、硝酸还原酶与人体多种酶辅基的重要组成成分,对维持植物生长发育和人体健康具有重要作用。研究农用地土壤钼含量分布及其影响因素对土壤科学施肥、土壤钼有效性提升具有重要的现实意义。安徽省淮北平原位于中国华北平原缺钼土壤区,目前缺乏对该地区土壤钼含量及其驱动因素的系统研究。本文以淮北平原典型土壤区511km²为研究区域,按照1件样品/km²采集0～20cm深度表层土壤样品,采用电感耦合等离子体质谱(ICP-MS)、电感耦合等离子体发射光谱(ICP-OES)等方法测定表层土壤中全钼、有效钼、TFe₂O₃、Al₂O₃、SiO₂、P、Mn及有机质含量与pH值等指标含量;利用统计学、相关性分析等方法系统研究土壤中全钼、有效钼含量和分布特征,并对制约土壤中全钼、有效钼分布特征的主要因素进行了探讨。结果表明：(1)砂姜黑土中全钼和有效钼含量以缺乏为主,全钼、有效钼缺乏土壤比例分别高达93.3%、87.3%;全钼含量主要受土壤pH值、Mn、...     

西藏冈底斯成矿带东段主要钼多 金属矿床成矿规律研究

文章以钼成矿作用为主线,对冈底斯东段主要钼多金属矿床成因类型、空间分布特征进行了总结,对主要钼多金属矿床成矿时代进行了统计,识别出了5期钼成矿事件。基于前人研究成果,对主要斑岩—矽卡岩钼多金属矿床成矿岩浆岩基本地质特征、岩浆岩主量元素、稀土和微量元素、锶同位素地球化学特征进行了阐述并对比了独立钼矿、钼(铜)矿、铜(钼)矿和钼多金属矿成矿岩体特征之间的差异。通过对南冈底斯南缘至冈底斯弧背断隆带不同钼多金属矿床成矿岩体锆石Hf同位素、矿石硫化物Pb同位素的梳理阐明了成岩—成矿物质源区差异与矿化元素组合空间分带之间的耦合关系。基于冈底斯东段钼多金属矿床产出大地构造位置及其形成时代,文章最后对主要钼成矿事件的动力学背景进行了初步探讨。     

大兴安岭地区铜钼矿床成矿区带背景及找矿前景分析

本文根据区域构造背景和已知铜钼矿床的分布规律,将大兴安岭地区划分为西拉木伦河钼多金属、大兴安岭南段铜钼、大兴安岭北段铜钼和额尔古纳铜钼4个成矿带.归纳了研究区铜钼矿床的成因类型,主要有斑岩型、热液脉型、矽卡岩型等,并就各成因类型进行了典型矿床的举例.对研究区铜钼矿床的时空分布特征进行了总结,并按照典型矿床形成时间的先后...     

钼同位素地球化学研究进展及其在成矿作用研究中的应用潜力

近年来,随着多接收器电感耦合等离子体质谱仪(MC-ICP-MS)的广泛应用和测试精度的不断提高,非传统稳定同位素成为同位素地球化学最前沿和最活跃的研究领域。其中钼同位素作为非传统稳定同位素发展较为成熟的方向之一,已经逐步应用到地球科学、生命科学、环境科学等各个重要领域,并取得了长足的发展。本文对近些年国内外所取得的钼同位素研究成果进行了系统整理、总结,并对钼同位素的应用潜力进行了概括性的综述,主要包括钼元素及其同位素的地球化学特征、钼同位素分析测试技术、钼同位素的分馏机制、不同地球化学储库的钼同位素组成、成矿作用过程中钼同位素组成的变化特征及其在矿床中的应用。以期让更多人了解钼同位素这一非传统稳定同位素的最新研究进展,进一步探索成矿作用过程中钼同位素的组成特征、分馏机制和影响因素等,并有效推动钼同位素地球化学在成矿作用研究方面的应用。     

Statistical considerations for grain-size analyses of tills

Relative percentages of sand, silt, and clay from samples of the same till unit are not identical because of different lithologies in the source areas, sorting in transport, random variation, and experimental error. Random variation and experimental error can be isolated from the other two as follows. For each particle-size class of each till unit, a standard population is determined by using a normally distributed, representative group of data. New measurements are compared with the standard population and, if they compare satisfactorily, the experimental error is not significant and random variation is within the expected range for the population. The outcome of the comparison depends on numerical criteria derived from a graphical method rather than on a more commonly used one-way analysis of variance with two treatments. If the number of samples and the standard deviation of the standard population are substituted in at-test equation, a family of hyperbolas is generated, each of which corresponds to a specific number of subsamples taken from each new sample. The axes of the graphs of the hyperbolas are the standard deviation of new measurements (horizontal axis) and the difference between the means of the new measurements and the standard population (vertical axis). The area between the two branches of each hyperbola corresponds to a satisfactory comparison between the new measurements and the standard population. Measurements from a new sample can be tested by plotting their standard deviation vs. difference in means on axes containing a hyperbola corresponding to the specific number of subsamples used. If the point lies between the branches of the hyperbola, the measurements are considered reliable. But if the point lies outside this region, the measurements are repeated. Because the critical segment of the hyperbola is approximately a straight line parallel to the horizontal axis, the test is simplified to a comparison between the means of the standard population and the means of the subsample. The minimum number of subsamples required to prove significant variation between samples caused by different lithologies in the source areas and sorting in transport can be determined directly from the graphical method. The minimum number of subsamples required is the maximum number to be run for economy of effort.     

Stress-strain analysis of geogrid-supported liners over subsurface cavities

Summary Finite element analyses were conducted to investigate the magnitude of tensile strains imposed on landfill liners due to the formation of subsurface cavities. The study incorporated the significance of using geogrids to reduce the magnitude of strains and possibly the potential for collapse of landfill liners. Variations of key parameters included depth of overburden (D) and diameter of the cavity (B). Estimated stress distributions were compared to theoretical values obtained from a model reported in the literature. Results indicated that, contrary to conventional wisdom, the critical area based on the mechanics of arching was above the edge of the cavity where stress concentration occurred. Incorporation of geogrid reinforcement reduced the magnitude of tensile strains. The tensile force in the geogrid was dependent upon the size of the cavity, the depth of the overburden, and the applied pressure.     

Viscous effects on penetrating shafts in clays

The penetration of rigid objects such as piles and penetrometers into soils creates a zone of soil disturbance around them. The extent of this disturbed zone influences the resistance of the moving rigid body. This paper presents a theoretical framework to analyze the resistance in the disturbed zone created by a shaft penetrating a clay soil. The soil is modeled as a viscous material after it reaches failure [critical state (CS)]. The results of this analysis show that the viscous drag stress component on the shaft surface is influenced by the size of disturbed zone that has reached CS around the shaft, the shear viscosity of the soil and the velocity profile (or strain rate) in the CS zone around the shaft. The size of CS zone, the velocity profile and the viscosity of soil are interdependent. Large variation in viscous drag occurs when the size of the CS soil zone is less than four times the shaft’s radius. Limiting drag occurs when the size of the CS soil zone exceeds six times the shaft’s radius. The theoretical velocity distribution of the movement of soil in the CS zone shows that the soil is dragged along with shaft in the near field (close to the shaft surface) and moves upwards in the far field.     

具彩色斑纹颅形贝在广西桂林下石炭统黄金组中的发现:兼论颅形贝属的地质地理分布

文中描述了产自广西桂林地区下石炭统黄金组下部的颅形贝属一新种,桂林颅形贝(Cranaena guilinensis)。新种以平直的前结合缘和背壳上发育中槽为特征。在4枚标本上发现保存有放射状的彩色条带,表明该种当时生活在温暖海域的浅水环境。对该属70个种的地质地理分布和生物多样性变化的初步分析表明,该属可能起源于早泥盆世欧美大陆西北缘的老世界区,之后的地理分布和生物多样性发展以北美地区为中心,经历了中泥盆世—晚泥盆世早期和早石炭世2次比较明显的辐射演化、迁移扩散高峰和晚泥盆世晚期的1次严重衰退。第1次高峰是中泥盆世—晚泥盆世早期,该属的生物多样性达到巅峰,生物地理分布范围扩大到欧美大陆之外的西伯利亚板块、哈萨克斯坦板块和华南板块等;第2次高峰是早石炭世,该属的生物多样性虽不及前一次,但获得了最广泛的地理分布,不仅在北方大陆有分布,而且已进入到冈瓦纳大陆边缘。晚泥盆世晚期该属的1次严重衰退显然与F/F灭绝事件有关。早石炭世之后,该属进入衰退阶段,最终在二叠纪初灭绝。     

Lower Carboniferous (Dinantian) stratigraphy and structure of the Walterstown-Kentstown area,Co. Meath,Ireland

Stratigraphic units are defined and described for the Lower Carboniferous succession in the Walterstown-Kentstown area of Co. Meath, Ireland. A complete (unexposed) Courceyan succession from the terrestrial red bed facies of the Baronstown Formation to the Moathill Formation of the Navan Group has been penetrated in several boreholes. Although the lower part of the sequence is comparable with the Courceyan succession at Navan and Slane, the middle part of the sequence differs markedly in the Walterstown-Kentstown area and two new members, the Proudstown and Walterstown Members, are defined in the upper part of the Meath Formation. Syndepositional faulting was initiated during the Courceyan, probably in latest Pseudopolygnathus multistriatus or early Polygnathus mehli latus time. Movement on the ENE trending St. Patrick's Well Fault influenced the deposition of the Walterstown Member and the overlying Moathill Formation and was probably associated with the development of the East Midlands depocentre to the south of the area. A second episode of tectonism in the latest Courceyan or early Chadian resulted in uplift and erosion and the development of ‘block and basin’ sedimentation. Subsequent transgression of the uplifted block led to the establishment of the Kentstown Platform, bounded to the north, west and south by rocks of basinal facies. The Milverton Group (Chadian-Asbian), confined to this platform, unconformably overlies Courceyan or Lower Palaeozoic strata and is subdivided into three formations: Crufty Formation (late Chadian), Holmpatrick Formation (late Chadian-Arundian) and Mullaghfin Formation (late Arundian-Asbian). The Walterstown Fault controlled the western margin of the Kentstown Platform at this time. Contemporaneous basinal sediments of the Fingal Group (Lucan and Naul Formations) accumulated to the west of the Walterstown Fault and are much thicker than age-equivalent platform facies. Platform sedimentation ceased in latest Asbian to early Brigantian time with tectonically induced collapse and drowning of the platform; platform carbonates of the Mullaghfin Formation are onlapped northwards by coarse proximal basinal facies of the Loughshinny Formation. A distinct gravity anomaly in the Kentstown area suggests the presence of a granitoid body within the basement. The Kentstown Platform is therefore considered to have formed on a buoyant, granite-cored, footwall high analogous to the Askrigg and Alston Blocks of northern England.     

Controls on the evolution and demise of Lower Carboniferous carbonate platforms,northern margin of the Dublin Basin,Ireland

Shallow water platform limestones of the Chadian–Asbian Milverton Group are restricted to the north-eastern part of the Lower Carboniferous (Dinantian) Dublin Basin. Here, they are confined to two granite-cored fault blocks, the Kentstown and Balbriggan Blocks, known to have been active during the late Dinantian. Three areas of platform sedimentation are delimited (the Kentstown, Drogheda and Milverton areas), although in reality they probably formed part of a single carbonate platform. Resedimented submarine breccias and calciturbidites (Fingal Group) composed of shallow water allochems and intraclasts sourced from the platform accumulated, along with terrigenous muds, in the surrounding basinal areas. Sedimentological evidence suggests that the Kentstown and Balbriggan Blocks possessed tilt-block geometries and developed during an episode of basin-wide extensional faulting in late Chadian time. Rotation of the blocks during extension resulted in the erosion of previously deposited sequences in footwall areas and concomitant drowning of distal hangingwall sequences. Antithetic faults on the northern part of the Balbriggan Block aided the preferential subsidence of the Drogheda area and accounts for the anomously thick sequence of late Chadian platform sediments present there. Continued subsidence and/or sea-level rise in the late Chadian–early Arundian resulted in transgression of the Kentstown and Balbriggan Blocks; carbonate ramps developed on the hangingwall dip slopes and transgressed southward with time. Subsequent progradation and aggradation of shallow water sediments throughout the Arundian to Asbian led to the development of carbonate shelves. Several coarse conglomeratic intervals within the contemporaneous basinal sequences of the Fingal Group attest to periodic increases of sediment influx associated with the development of the shelves. Sedimentological processes controlled the development of the carbonate platforms on the hangingwall dip slopes of the Kentstown and Balbriggan Blocks, though periodic increases of sediment flux into the basinal areas may have been triggered by eustatic falls in sea level. In contrast, differential subsidence along the bounding faults of these blocks exerted a strong control on the margins of the late Dinantian shelves, maintaining relatively steep slopes and inhibiting the progradation of the shelves into the adjacent basins. Tectonically induced collapse and retreat of the platform margins occurred in the late Asbian–early Brigantian. Platform sediments are overlain by coarse-grained proximal basinal facies which fine upwards before passing into a thick shale sequence, indicating that by the late Brigantian carbonate production had almost stopped as the platforms were drowned.     

Nouvelle interprétation tectonique de la montagne Sainte-Victoire (Provence,France)

The explanation normally given for the tectonics of Sainte-Victoire Mountain, a dozen kilometres east of Aix-en-Provence, to the north of the limestone Provence, is incorrect. To the east, the morphology of the Sainte-Victoire is subdued, whereas to the west, before the mountain breaks savagely, the morphology is that of a young mountain as appears in Alpine landscapes. This unusual aspect in the region and the large subvertical faults with vertically striated surfaces that mark the massif to the south and to the west, induce the idea of strong vertical uplifts and caste doubt on the tectonic interpretation given in 1962 by Corroy et al. According to those authors, the Sainte-Victoire is a unit of Jurassic and Cretaceous formations overthrusting 1800 m to the south conglomerates of the Late Cretaceous or Palaeocene. New observations about the conglomerate transgression over the Jurassic and Cretaceous beds, and about the faults around and on the massif do not give evidence of an overthrusting but, on the contrary, induce the idea of a uplift, perhaps still active, in the form of a ‘piano key’ inclined to the northeast. To cite this article: J. Ricour et al., C. R. Geoscience 337 (2005).     

Evolution of the European Cenozoic Rift System: interaction of the Alpine and Pyrenean orogens with their foreland lithosphere

The evolution of the European Cenozoic Rift System (ECRIS) and the Alpine orogen is discussed on the base of a set of palaeotectonic maps and two retro-deformed lithospheric transects which extend across the Western and Central Alps and the Massif Central and the Rhenish Massif, respectively.During the Paleocene, compressional stresses exerted on continental Europe by the evolving Alps and Pyrenees caused lithospheric buckling and basin inversion up to 1700 km to the north of the Alpine and Pyrenean deformation fronts. This deformation was accompanied by the injection of melilite dykes, reflecting a plume-related increase in the temperature of the asthenosphere beneath the European foreland. At the Paleocene–Eocene transition, compressional stresses relaxed in the Alpine foreland, whereas collisional interaction of the Pyrenees with their foreland persisted. In the Alps, major Eocene north-directed lithospheric shortening was followed by mid-Eocene slab- and thrust-loaded subsidence of the Dauphinois and Helvetic shelves. During the late Eocene, north-directed compressional intraplate stresses originating in the Alpine and Pyrenean collision zones built up and activated ECRIS.At the Eocene–Oligocene transition, the subducted Central Alpine slab was detached, whereas the West-Alpine slab remained attached to the lithosphere. Subsequently, the Alpine orogenic wedge converged northwestward with its foreland. The Oligocene main rifting phase of ECRIS was controlled by north-directed compressional stresses originating in the Pyrenean and Alpine collision zones.Following early Miocene termination of crustal shortening in the Pyrenees and opening of the oceanic Provençal Basin, the evolution of ECRIS was exclusively controlled by west- and northwest-directed compressional stresses emanating from the Alps during imbrication of their external massifs. Whereas the grabens of the Massif Central and the Rhône Valley became inactive during the early Miocene, the Rhine Rift System remained active until the present. Lithospheric folding controlled mid-Miocene and Pliocene uplift of the Vosges-Black Forest Arch. Progressive uplift of the Rhenish Massif and Massif Central is mainly attributed to plume-related thermal thinning of the mantle-lithosphere.ECRIS evolved by passive rifting in response to the build-up of Pyrenean and Alpine collision-related compressional intraplate stresses. Mantle-plume-type upwelling of the asthenosphere caused thermal weakening of the foreland lithosphere, rendering it prone to deformation.     

青藏高原风火山流域坡面尺度活动层土壤水热时空变化特征

以风火山流域某阴坡坡顶、 坡底和阳坡坡底活动层土壤水热及气象资料为基础, 对青藏高原多年冻土区不同地形条件下的土壤水热时空变化特征进行了分析。结果表明： 在融化阶段, 除表层5 cm外, 阴坡坡底各深度土壤开始融化日期均比坡顶早, 比阳坡坡底晚; 阴坡坡脚各深度土壤含水量均大于坡顶和阳坡坡底。在冻结阶段, 开始冻结日期在阴坡坡底均比坡顶早, 但比阳坡坡底晚; 阴坡坡底各深度土壤含水量均高于坡顶相应土层的含水量, 在20 cm、 100 cm、 160 cm深处高于阳坡相应土层的含水量, 但在5 cm、 50 cm深处, 稳定冻结后两者的含水量差异较小。在整个冻融过程中, 阴坡坡底土壤温度对气温变化的响应弱于坡顶及阳坡坡底, 但其土壤水分对降水的响应强于坡顶及阳坡坡底。植被生长发育受水分和热量条件的制约, 不同地形条件下水热时空变化差异将影响植被空间分布特征。在未来气候变暖情况下, 上坡位植被可能因为水分胁迫而退化, 出现荒漠化现象, 而下坡位由于受侧向流的影响, 土壤水分对降水的响应强烈, 植被不会发生显著退化; 在不同坡向之间, 同一坡位阳坡植被退化程度可能大于阴坡。     

渭河中游宝鸡-扶风北岸斜坡结构及其对大型滑坡形成机理的指示意义

渭河中游宝鸡-扶风段北岸塬边集中发育大型黄土滑坡,体积超过1 000×10⁴ m³的滑坡达58处。在区域活动断裂调查、地球物理勘察、典型斜坡结构与构造调查基础上,研究了大型滑坡结构及其形成机理。研究表明：渭河北缘活动断裂以地堑式结构控制北坡塬边斜坡的地貌,主断裂面倾向南,倾角平均为68°,而次级断面结构组合控制斜坡结构,影响塬边大型黄土滑坡结构;塬边主断裂面与多个大型黄土滑坡后缘滑壁一致,断裂最大下挫距离7.1 m,影响大型滑坡的形态及发生过程;活动断裂呈地堑式结构,局部次级断面控制塬边多级滑动面的结构及其演化过程,如杨家村滑坡,局部滑坡剪出受断裂结构控制,剪出口角度可达72°,大部分剪出口未受到断裂面影响,角度平均为23°;三门组黏土岩黏粒体积分数超过35%,塑限平均值为23,是滑坡的层间剪切带;降雨诱发老滑坡复活是目前新滑坡发育的主要形式,大量的老滑坡形成于0.009 Ma BP二级阶地侵蚀期,而古滑坡形成于0.13 Ma BP三级阶地侵蚀期。