Geophysical monitoring and evaluation of coastal plain aquifers

We use time domain electromagnetic (TDEM) soundings to monitor ground water conditions beneath the coastal plain in eastern North Carolina. The TDEM method measures the earth's response to an induced electromagnetic field. The resulting signal is converted, through a complex inversion process, to apparent resistivity values, which can be directly correlated to borehole resistivity logs. TDEM soundings are used to map the interface between fresh and salt water within coastal aquifers, and estimate depth to basement when siting new monitoring wells. Focused TDEM surveys have identified areas of salt water encroachment caused by high volumes of discharge from local supply wells. Electromagnetic sounding, when used in tandem with the state's network of monitoring wells, is an accurate and inexpensive tool for evaluating fresh water/salt water relationships on both local and regional scales within coastal plain aquifers.     

A simple method for locating the fresh water-salt water interface using pressure data

Salt water intrusion is a key issue in dealing with exploitation, restoration, and management of fresh ground water in coastal aquifers. Constant monitoring of the fresh water-salt water interface is necessary for proper management of ground water resources. This study presents a simple method to estimate the depth of the fresh water-salt water interface in coastal aquifers using two sets of pressure data obtained from the fresh and saline zones within a single borehole. This method uses the density difference between fresh water and saline water and can practically be used at coastal aquifers that have a relatively sharp fresh water-salt water interface with a thin transition zone. The proposed method was applied to data collected from a coastal aquifer on Jeju Island, Korea, to estimate the variations in the depth of the interface. The interface varied with daily tidal fluctuations and heavy rainfall in the rainy season. The estimated depth of the interface showed a good agreement with the measured electrical conductivity profile.     

Stack unit mapping of coastal aquifer to predict and control sea water intrusion using remote sensing and a geographical information system

Aquifers are inherently susceptible to contamination and coastal aquifers in specific are highly vulnerable to sea water intrusion. For efficient planning and management of coastal aquifers in Kayalpattu and Tiruchopuram villages, which extend over 4·05 km², it is essential to delineate and predict the extent of intrusion into the shallow aquifer. Management of ground water in coastal aquifers is composed of major elements that should be properly evaluated, and special attention is given to the sea water intrusion problem. Different data, like hydro‐geomorphological and depth‐wise iso‐apparent resistivity, are integrated spatially using a geographical information system. The stack‐unit mapping approach is used to delineate the zones with iso‐apparent resistivity of less than 10 Ω m have been found to be increasing in areal extent with reference to depth. Copyright © 2003 John Wiley & Sons, Ltd.     

Impact of Sea-Level Rise on Sea Water Intrusion in Coastal Aquifers

Despite its purported importance, previous studies of the influence of sea-level rise on coastal aquifers have focused on specific sites, and a generalized systematic analysis of the general case of the sea water intrusion response to sea-level rise has not been reported. In this study, a simple conceptual framework is used to provide a first-order assessment of sea water intrusion changes in coastal unconfined aquifers in response to sea-level rise. Two conceptual models are tested: (1) flux-controlled systems, in which ground water discharge to the sea is persistent despite changes in sea level, and (2) head-controlled systems, whereby ground water abstractions or surface features maintain the head condition in the aquifer despite sea-level changes. The conceptualization assumes steady-state conditions, a sharp interface sea water-fresh water transition zone, homogeneous and isotropic aquifer properties, and constant recharge. In the case of constant flux conditions, the upper limit for sea water intrusion due to sea-level rise (up to 1.5 m is tested) is no greater than 50 m for typical values of recharge, hydraulic conductivity, and aquifer depth. This is in striking contrast to the constant head cases, in which the magnitude of salt water toe migration is on the order of hundreds of meters to several kilometers for the same sea-level rise. This study has highlighted the importance of inland boundary conditions on the sea-level rise impact. It identifies combinations of hydrogeologic parameters that control whether large or small salt water toe migration will occur for any given change in a hydrogeologic variable.     

Ground water discharge and nitrate flux to the Gulf of Mexico

Ground water samples (37 to 186 m depth) from Baldwin County, Alabama, are used to define the hydrogeology of Gulf coastal aquifers and calculate the subsurface discharge of nutrients to the Gulf of Mexico. The ground water flow and nitrate flux have been determined by linking ground water concentrations to 3H/3He and 4He age dates. The middle aquifer (A2) is an active flow system characterized by postnuclear tritium levels, moderate vertical velocities, and high nitrate concentrations. Ground water discharge could be an unaccounted source for nutrients in the coastal oceans. The aquifers annually discharge 1.1 +/- 0.01 x 10(8) moles of nitrate to the Gulf of Mexico, or 50% and 0.8% of the annual contributions from the Mobile-Alabama River System and the Mississippi River System, respectively. In southern Baldwin County, south of Loxley, increasing reliance on ground water in the deeper A3 aquifer requires accurate estimates of safe ground water withdrawal. This aquifer, partially confined by Pliocene clay above and Pensacola Clay below, is tritium dead and contains elevated 4He concentrations with no nitrate and estimated ground water ages from 100 to 7000 years. The isotopic composition and concentration of natural gas diffusing from the Pensacola Clay into the A3 aquifer aids in defining the deep ground water discharge. The highest 4He and CH4 concentrations are found only in the deepest sample (Gulf State Park), indicating that ground water flow into the Gulf of Mexico suppresses the natural gas plume. Using the shape of the CH4-He plume and the accumulation of 4He rate (2.2 +/- 0.8 microcc/kg/1000 years), we estimate the natural submarine discharge and the replenishment rate for the A3 aquifer.     

Hydrologic significance of carbon monoxide concentrations in ground water

Dissolved carbon monoxide (CO) is present in ground water produced from a variety of aquifer systems at concentrations ranging from 0.2 to 20 nanomoles per liter (0.0056 to 0.56 microg/L). In two shallow aquifers, one an unconsolidated coastal plain aquifer in Kings Bay, Georgia, and the other a fractured-bedrock aquifer in West Trenton, New Jersey, long-term monitoring showed that CO concentrations varied over time by as much as a factor of 10. Field and laboratory evidence suggests that the delivery of dissolved oxygen to the soil zone and underlying aquifers by periodic recharge events stimulates oxic metabolism and produces transiently high CO concentrations. In between recharge events, the aquifers become anoxic and more substrate limited, CO is consumed as a carbon source, and CO concentrations decrease. According to this model, CO concentrations provide a transient record of oxic metabolism affecting ground water systems after dissolved oxygen has been fully consumed. Because the delivery of oxygen affects the fate and transport of natural and anthropogenic contaminants in ground water, CO concentration changes may be useful for identifying predominantly anoxic ground water systems subject to periodic oxic or microaerophilic conditions.     

Economic Commission for Europe inventory of transboundary ground water in Europe

In Europe, a long history of cooperation over transboundary rivers--most notably the Rhine and Danube rivers--exists. To help foster cooperation and communication vis-à-vis transboundary ground water, the United Nations Economic Commission for Europe (UNECE), as part of its ground water program, conducted a survey on transboundary aquifers in Europe. The survey produced 25 responses from 37 countries and identified 89 transboundary aquifers. Respondents reported on the degree of ground water use within their own boundaries, transboundary aspects (agreements, joint commissions, etc.) of ground water, and transboundary aquifers themselves. The inventory proved useful, but a number of problems were identified: different map scales and symbols, difficulty in identifying transboundary aquifers, inconsistent labeling of aquifers, and data discrepancies. The UNECE ground water program also drafted guidelines for monitoring and assessment of transboundary ground water. These guidelines are not legally binding but have been adopted by 25 countries, deal mainly with monitoring and assessment, and are being implemented through a number of pilot projects. Other organizations-the United Nations Scientific, Educational and Cultural Organization, the Food and Agriculture Organization, the International Association of Hydrogeologists, and the European Union--are all supporting the investigation of transboundary aquifers in an effort to facilitate data sharing and coordinated management of these valuable resources.     

The Interface Configuration of the Fresh‐/Dead Sea Water – Theory and Measurements

The high‐density Dead Sea water (1.235 g/cm³) forms a special interface configuration with the fresh groundwater resources of its surrounding aquifers. The fresh groundwater column beneath its surroundings is around one tenth of its length compared to oceanic water. This fact alone indicates the vulnerability of the fresh groundwater resources to the impacts of changes in the Dead Sea level and to saltwater migration. Ghyben‐Herzberg and Glover equations were used to calculate the volumes of water in coastal aquifers which were replaced by freshwater due to the interface seaward migration as a result of the drop in the level of the Dead Sea. For that purpose, the dynamic equation of Glover approach has been integrated to accommodate that type of interface readjustment. The calculated amounts of freshwater which substituted salt Dead Sea water due to the migration of interface are 3.21 · 10¹¹ m³, from a Dead Sea level of –392 m to τ411 m below sea level. The average porosity of coastal aquifers was calculated to range from 2.8 to 2.94%. Geoelectric sounding measurements showed that areas underlying the coastal aquifers formerly occupied by the Dead Sea water are gradually becoming flushed and occupied by freshwater. The latter is becoming salinized due to the residuals of Dead Sea water in the aquifer matrix, the present salinity of which is lower than that of the Dead Sea water. At the same time salt dissolution from the Lisan Marl formation is causing collapses along the shorelines in the form of sinkholes, tens of meters in diameter and depth.     

Analytical models of contaminant transport in coastal aquifers

The Henry formulation, which couples subsurface flow and salt transport via a variable-density flow formulation, can be used to evaluate the extent of sea water intrusion into coastal aquifers. The coupling gives rise to nontrivial flow patterns that are very different from those observed in inland aquifers. We investigate the influence of these flow patterns on the transport of conservative contaminants in a coastal aquifer. The flow is characterized by two dimensionless parameters: the Péclet number, which compares the relative effects of advective and dispersive transport mechanisms, and a coupling parameter, which describes the importance of the salt water boundary on the flow. We focus our attention on two regimes – low and intermediate Péclet number flows. Two transport scenarios are solved analytically by means of a perturbation analysis. The first, a natural attenuation scenario, describes the flushing of a contaminant from a coastal aquifer by clean fresh water, while the second, a contaminant spill scenario, considers an isolated point source.     

Screened Auger Sampling: The Technique and Two Case Studies

The screened auger is a laser-slotted, hollow-stem auger through which a representative sample of ground water is pumped from an aquifer and tested for water-quality parameters by appropriate field-screening methods. Screened auger sampling can be applied to ground water quality remedial investigations, providing:(1) a mechanism for determining a monitoring well's optimal screen placement in a contaminant plume; and (2) data to define the three-dimensional configuration of the contaminant plume.
Screened auger sampling has provided an efficient method for investigating hexavalent chromium and volatile organic compound contamination in two sandy aquifers in Cadillac, Michigan. The aquifers approach 200 feet in thickness and more than 1 square mile in area. A series of screened auger borings and monitoring wells was installed, and ground water was collected at 10-foot intervals as the boreholes were advanced to define the horizontal and vertical distribution of the contaminant plumes. The ability of the screened auger to obtain representative ground water samples was supported by the statistical comparison of field screening results and subsequent laboratory analysis of ground water from installed monitoring wells.     

International borders, ground water flow, and hydroschizophrenia

A substantial body of research has been conducted on transboundary water, transboundary water law, and the mitigation of transboundary water conflict. However, most of this work has focused primarily on surface water supplies. While it is well understood that aquifers cross international boundaries and that the base flow of international river systems is often derived in part from ground water, transboundary ground water and surface water systems are usually managed under different regimes, resulting in what has been described as "hydroschizophrenia." Adding to the problem, the hydrologic relationships between surface and ground water supplies are only known at a reconnaissance level in even the most studied international basins, and thus even basic questions regarding the territorial sovereignty of ground water resources often remain unaddressed or even unasked. Despite the tensions inherent in the international setting, riparian nations have shown tremendous creativity in approaching regional development, often through preventive diplomacy, and the creation of "baskets of benefits," which allow for positive-sum, integrative allocations of joint gains. In contrast to the notion of imminent water wars, the history of hydropolitical relations worldwide has been overwhelmingly cooperative. Limited ground water management in the international arena, coupled with the fact that few states or countries regulate the use of ground water, begs the question: will international borders serve as boundaries for increased "flows" of hydrologic information and communication to maintain strategic aquifers, or will increased competition for shared ground water resources lead to the potential loss of strategic aquifers and "no flows" for both ground water users?     

An Application of HFE-D for Evaluating Sea Water Intrusion in Coastal Aquifers of Southern Vietnam

The coastal aquifers and inland waters of the Long Xuyen Quadrangle and Ca Mau Peninsula of southern Vietnam have been significantly impacted by sea water intrusion (SI) as a result of recent anthropogenic activities. This study identified the evolution and spatial distribution of hydrochemical conditions in coastal aquifers at this region using Hydrochemical Facies Evolution Diagram (HFE-D) and Geographical Information System mapping. Hydraulic heads and water chemistry were measured at 31 observation wells in four layered aquifers during dry and rainy seasons in early (2005), and more recent (2016), stages of agricultural development. Hydrochemical facies associated with intrusion or freshening stages were mapped in each aquifer after assigning mixing index values to each facies. The position of groundwater freshening and SI phases differed in Holocene, Upper Pleistocene, Middle Pleistocene, and Lower Pleistocene aquifers. The geographic position of freshening and intrusion fronts differ in dry and rainy seasons, and shifted after 11 years of groundwater abstraction in all four aquifers. The spatial and temporal differences in hydrochemical facies distributions according to HFE-D reflect the relative impact of SI in the four aquifers. The study results provide a better understanding of the evolution of groundwater quality associated with SI in a peninsular coastal aquifer system, and highlight the need for improving groundwater quality and management in similar coastal regions.     

Efficiency of joint use of MRS and VES to characterize coastal aquifer in Myanmar

The productivity and the water quality of coastal aquifers can be highly heterogeneous in a complex environment. The characterization of these aquifers can be improved by hydrogeological and complementary geophysical surveys. Such an integrated approach is developed in a non-consolidated coastal aquifer in Myanmar (previously named Burma).A preliminary hydrogeological survey is conducted to know better the targeted aquifers. Then, 25 sites are selected to characterize aquifers through borehole drillings and pumping tests implementation. In the same sites, magnetic resonance soundings (MRS) and vertical electrical soundings (VES) are carried out. Geophysical results are compared to hydrogeological data, and geophysical parameters are used to characterize aquifers using conversion equations. Finally, combining the analysis of technical and economical impacts of geophysics, a methodology is proposed to characterize non-consolidated coastal aquifers.Depth and thickness of saturated zone is determined by means of MRS in 68% of the sites (evaluated with 34 soundings). The average accuracy of confined storativity estimated with MRS is ± 6% (evaluated over 7 pumping tests) whereas the average accuracy of transmissivity estimation with MRS is ± 45% (evaluated using 15 pumping tests). To reduce uncertainty in VES interpretation, the aquifer geometry estimated with MRS is used as a fixed parameter in VES inversion. The accuracy of groundwater electrical conductivity evaluation from 15 VES is enough to estimate the risk of water salinity. In addition, the maximum depth of penetration of the MRS depends on the rocks' electrical resistivity and is between 20 and 80 m at the study area.     

Geophysical Constraints on the Hydrogeologic and Structural Settings of the Gulf of Suez Rift-Related Basins: Case Study from the El Qaa Plain,Sinai, Egypt

Groundwater has been identified as one of the major freshwater sources that can potentially meet the growing demands of Egypt’s population. Gravity data (from 381 ground gravity stations) were collected, processed, and analyzed together with the available aeromagnetic (800 line-km) data to investigate the hydrogeologic and structural settings, areal distribution, geometry, and water storage of the aquifers in El Qaa coastal plain in the southwest Sinai Peninsula, and to assess their longevity given projected extraction rates. Findings include (1) complete Bouguer anomaly and total magnetic intensity maps show two connected sub-basins separated by a narrow saddle with an average basin length of 43 km and an average width of 12 km; (2) two-dimensional modeling of both gravity and magnetic data indicates basin fill with a maximum thickness of 3.5 km; (3) using anomalous residual gravity, the volume of water in storage was estimated at 40–56 km³; and (4) progressive increases in extraction rates over time will deplete up to 40 % of the aquifers’ volume in 200–230 years and will cause the water quality to deteriorate due to seawater intrusion in 45 years. Similar geophysical exploration campaigns, if conducted over the entire coastal plains of the Red Sea and the Gulfs of Suez and Aqaba, could assist in the development of sound and sustainable management schemes for the freshwater resources in these areas. The adopted techniques could pave the way toward the establishment of sustainable utilization schemes for a much larger suite of similar aquifers worldwide.     

Transboundary aquifers: conceptual models for development of international law

More than one-half of the world's population is dependent on ground water for everyday uses such as drinking, cooking, and hygiene. In fact, it is the most extracted natural resource in the world. As a result of growing populations and expanding economies, many aquifers today are being depleted while others are being contaminated. Notwithstanding the world's considerable reliance on this resource, ground water resources have long received only secondary attention as compared to surface water, especially among legislatures and policymakers. Today, while there are hundreds of treaties governing transboundary rivers and lakes, there is only one international agreement that directly addresses a transboundary aquifer. Given that many of the aquifers on which humanity so heavily relies cross international borders, there is a considerable gap in the sound management, allocation, and protection of such resources. In order to prevent future disputes over transboundary aquifers and to maximize the beneficial use of this resource, international law must be clarified as it applies to transboundary ground water resources. Moreover, it must be defined with a firm basis in sound scientific understanding. In this paper we offer six conceptual models is which ground water resources can have transboudary consequences. The models are intended to help in assessing the applicability and scientific soundness of existing and proposed rules governing transboundary ground water resources. In addition, we consider the development of international law as it applies to ground water resources and make recommendations based on the models and principles of hydrogeology. The objective is the development of clear, logical, and science-based norms of state conducts as they relate to aquifers that traverse political boundaries.     

Brief Review on Methods of Estimation of the Location of a Fresh Water–Salt Water Interface with Hydraulic Heads or Pressures in Coastal Zones

Methods of estimation of the location of a sharp fresh water–salt water interface with hydraulic heads or pressures are relatively simple and are widely used. Progress has been made in the recent decade toward the mathematical relations describing the position of the sharp interface using hydraulic heads or pressures in coastal zones. This paper reviews several methods for estimation of the location of fresh water–salt water interface in coastal aquifers, including the classical Ghyben–Herzberg relation. The location of the fresh water–salt water interface in a coastal homogeneous, isotropic unconfined aquifer can be estimated based on piezometric heads at two points in the same vertical line tapping, respectively, the salt water zone (including the interface) and the fresh water zone (from the water table to the interface) when the groundwater flow system is in a steady state and satisfies the Dupuit assumption. If pressures are measured at two points in the fresh water and salt water zones in the same vertical line in the coastal aquifer under the same assumption, then the position of the interface can still be estimated with the pressure data. If the Dupuit assumption is not met in coastal aquifers and the vertical fresh water head gradients can be approximated with a straight line, the position of the interface can roughly be estimated by using the water level data in a partially penetrating well during drilling of the well.     

Vulnerability indicators of sea water intrusion

In this paper, simple indicators of the propensity for sea water intrusion (SWI) to occur (referred to as "SWI vulnerability indicators") are devised. The analysis is based on an existing analytical solution for the steady-state position of a sharp fresh water-salt water interface. Interface characteristics, that is, the wedge toe location and sea water volume, are used in quantifying SWI in both confined and unconfined aquifers. Rates-of-change (partial derivatives of the analytical solution) in the wedge toe or sea water volume are used to quantify the aquifer vulnerability to various stress situations, including (1) sea-level rise; (2) change in recharge (e.g., due to climate change); and (3) change in seaward discharge. A selection of coastal aquifer cases is used to apply the SWI vulnerability indicators, and the proposed methodology produces interpretations of SWI vulnerability that are broadly consistent with more comprehensive investigations. Several inferences regarding SWI vulnerability arise from the analysis, including: (1) sea-level rise impacts are more extensive in aquifers with head-controlled rather than flux-controlled inland boundaries, whereas the opposite is true for recharge change impacts; (2) sea-level rise does not induce SWI in constant-discharge confined aquifers; (3) SWI vulnerability varies depending on the causal factor, and therefore vulnerability composites are needed that differentiate vulnerability to such threats as sea-level rise, climate change, and changes in seaward groundwater discharge. We contend that the approach is an improvement over existing methods for characterizing SWI vulnerability, because the method has theoretical underpinnings and yet calculations are simple, although the coastal aquifer conceptualization is highly idealized.     

Estimating Flow Using Tracers and Hydraulics in Synthetic Heterogeneous Aquifers

Regional ground water flow is most usually estimated using Darcy's law, with hydraulic conductivities estimated from pumping tests, but can also be estimated using ground water residence times derived from radioactive tracers. The two methods agree reasonably well in relatively homogeneous aquifers but it is not clear which is likely to produce more reliable estimates of ground water flow rates in heterogeneous systems. The aim of this paper is to compare bias and uncertainty of tracer and hydraulic approaches to assess ground water flow in heterogeneous aquifers. Synthetic two-dimensional aquifers with different levels of heterogeneity (correlation lengths, variances) are used to simulate ground water flow, pumping tests, and transport of radioactive tracers. Results show that bias and uncertainty of flow rates increase with the variance of the hydraulic conductivity for both methods. The bias resulting from the nonlinearity of the concentration–time relationship can be reduced by choosing a tracer with a decay rate similar to the mean ground water residence time. The bias on flow rates estimated from pumping tests is reduced when performing long duration tests. The uncertainty on ground water flow is minimized when the sampling volume is large compared to the correlation length. For tracers, the uncertainty is related to the ratio of correlation length to the distance between sampling wells. For pumping tests, it is related to the ratio of correlation length to the pumping test's radius of influence. In regional systems, it may be easier to minimize this ratio for tracers than for pumping tests.     

Source speciation resolving hydrochemical complexity of coastal aquifers

There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km² area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.     

Forensic isotope analysis to refine a hydrologic conceptual model

Water resources in the arid southwestern United States are frequently the subject of conflict from competing private and public interests. Legal remedies may remove impasses, but the technical analysis of the problem often determines the future success of legal solutions. In Owens Valley, California, the source of water for the Los Angeles Aqueduct (LAA) is flow diverted from the Owens River and its tributaries and ground water from valley aquifers. Future management of ground water delivered to the LAA needs technical support regarding quantity available, interconnection of shallow and confined aquifers, impact on local springs, and rate of recharge. Ground water flow models and ground water composition are tools already in use, but these have large uncertainty for local interpretations. This study conducted targeted sampling of springs and wells to evaluate the hydrologic system to corroborate conceptual and numerical models. The effort included measurement of intrinsic isotopic composition at key locations in the aquifers. The stable isotopic data of boron (delta(11)B), sulfur (delta(34)S), oxygen (delta(18)O), hydrogen (delta D), and tritium ((3)H) supported by basic chemical data provided rules for characterizing the upper and the lower aquifer system, confirmed the interpretation of ground water flow near faults and flow barriers, and detected hydraulic connections between the LAA and the perennial springs at key locations along the unlined reach of the LAA. This study exemplifies the use of forensic isotopic approaches as independent checks on the consistency of interpretations of conceptual models of a ground water system and the numerical hydrologic simulations.