Groundwater flow dynamics of weathered hard-rock aquifers under climate-change conditions: an illustrative example of numerical modeling through the equivalent porous media approach in the north-western Pyrenees (France)

A numerical groundwater model of the weathered crystalline aquifer of Ursuya (a major water source for the north-western Pyrenees region, south-western France) has been computed based on monitoring of hydrological, hydrodynamic and meteorological parameters over 3 years. The equivalent porous media model was used to simulate groundwater flow in the different layers of the weathered profile: from surface to depth, the weathered layer (5?·?10^?8?≤?K?≤?5?·? 10^?7 m s^?1), the transition layer (7?·?10^?8?≤?K?≤?1?·? 10^?5 m s^?1, the highest values being along major discontinuities), two fissured layers (3.5?·?10^?8?≤?K?≤?5?·?? 10^?4 m s^?1, depending on weathering profile conditions and on the existence of active fractures), and the hard-rock basement simulated with a negligible hydraulic conductivity (K = 1 10 ^?9 ). Hydrodynamic properties of these five calculation layers demonstrate both the impact of the weathering degree and of the discontinuities on the groundwater flow. The great agreement between simulated and observed hydraulic conditions allowed for validation of the methodology and its proposed use for application on analogous aquifers. With the aim of long-term management of this strategic aquifer, the model was then used to evaluate the impact of climate change on the groundwater resource. The simulations performed according to the most pessimistic climatic scenario until 2050 show a low sensitivity of the aquifer. The decreasing trend of the natural discharge is estimated at about ?360 m³ y^?1 for recharge decreasing at about ?5.6 mm y^?1 (0.8 % of annual recharge).     

Summer rainstorm associated with a debris flow in the Amarilla gully affecting the international Agua Negra Pass (30°20′S), Argentina

The Central-West region of Argentina was seriously affected by a series of convective summer storms on January–February of 2013 generating many debris flows and rockfall in the Central Andes mountain regions. In particular, the unreported 8th February event caused the sad death of a 10-year-old child being completely ignored by society and local authorities. Despite this, meteorological conditions associated with this event and further episodes were rarely measured and determined mainly due to scarce meteorological stations in Andean mountain areas. In this paper, meteorological data from CMORPH algorithm and measurements of surrounding gauges were analyzed for estimating the triggering precipitation value of this event. As well, the particular debris flow channeled into the main branch of the Amarilla gully in the Agua Negra valley was geomorphologically described. The amount of precipitation associated with this debris flow was 5.5 and 13.2 mm accumulated previous to the event. This violent debris flow was generated in a talus zone in a periglacial environment located just below a covered rock glacier. However, the influence of the permafrost thawing in this process is not feasible. The altitude of the 0 °C isotherm was lower during the previous days of the event, and no monitoring on permafrost is available for this area. The volume of removed mass was estimated in 5 × 10⁴ m³, and the mean velocity was 35 km/h. Boulders of 4 m diameter were found in the source area, while the deposit is up to 75% sandy with clasts that hardly exceed 10 cm in the alluvial fan distal part. Herein the main objective is to advice about the probable catastrophic impact of similar events in the future. These findings could be useful for hazard remediation, mitigation, and prevention plans for the Agua Negra international pass under construction.     

Characteristics of landslides in western Colorado,USA

Mass movement can be activated by earthquakes, rapid snowmelt, or intense rainstorms in conjunction with gravity. Whereas mass movement plays a major role in the evolution of a hillslope by modifying slope morphology and transporting material from the slope to the valley, it is also a potential natural hazard. Determining the relationships of frequency and magnitude of landslides are fundamental to understanding the role of landslides in the study of landscape evolution, hazard assessment, and determination of the rate of hillslope denudation. We mapped 735 shallow and active landslides in the Paonia to McClure Pass area of western Colorado from aerial photographs and field surveys. The study area covers ～815 km². The frequency–magnitude relationships of the landslides illustrate the flux of debris by mass movement in the area. The comparison of the probability density of the landslides with the double Pareto curve, defined by power scaling for negative slope (α), power scaling for positive slope (β), and location of rollover (t), shows that α?=?1.1, β?=?1.9, and t?=?1,600 m² for areas of landslides and α?=?1.15, β?=?1.8, and t?=?1,900 m³ for volumes of landslides. The total area of landslides is 4.8?×?10⁶ m² and the total volume of the landslides is 1.4?×?10⁷ m³. The areas (A) and the volumes (V) of landslides are related by V?=?0.0254?×?A ^1.45. The frequency–magnitude analysis shows that landslides with areas ranging in size from 1,600 to 20,000 m² are the most hazardous landslides in the study area. These landslides are the most frequent and also do a significant amount of geomorphic work. We also developed a conceptual model of hillslope development to upland plateau driven by river incision, shallow landsliding, and deep-seated large landsliding. The gentle slope to flat upland plateau that dominated the Quaternary landscape of the study area was modified to the present steep and rugged topography by the combined action of fluvial incision and glacial processes in response to rock uplift, very-frequent shallow landsliding, and less-frequent deep-seated landsliding.     

Distribution and risk assessment of polychlorinated biphenyls (PCBs) in the remote air and soil of Manipur,India

∑₂₅PCB congeners including dioxin-like compounds were analyzed at three sites of Manipur India to assess the level of polychlorinated biphenyls (PCBs) in air and soil. The ∑₂₅PCBs were higher in urban air (average 2,454 pg/m³), followed by the mountain air (average 2,109 pg/m³) and rural air (average 1,756 pg/m³). PCB levels observed in urban air were higher compared to PCB levels reported in major Indian metropolitan cities especially along the coastal region and were comparable with the pristine sites of India and also with some pockets of China and Europe. The heavier congeners (tetra, penta, tri and hexa) were dominant in both air and soil samples and show significant correlation with the ambient temperature. Emission of PCB congeners was investigated from soil surface. The total organic carbon present in soil shows the significant correlation (r ² = 0.8; p < 0.05) with the PCBs could indicate that the PCBs originated from the similar sources. Principal component analysis revealed that the sources of higher chlorinated PCB congeners are local emissions while long-range atmospheric transport process is responsible behind elevated levels of lower chlorinated PCBs. Total calculated toxic equivalent (TEQ) levels in soil (37.17–160.5 pg/g) were superior to reported TEQ level of agricultural soil in Delhi, India (0.01–105.40 pg/g). Back trajectory analysis showed that the observed high levels of PCB at Manipur may due to movement of air masses, mostly from the Northern and Southern India and to some extent from Myanmar.     

Interactions between rock avalanches and glaciers in the Mont Blanc massif during the late Holocene

Rock avalanches are common in the Mont Blanc massif, which is bordered by valleys with large resident and tourist populations and important highways. This paper combines historical data with detailed geomorphological mapping, stratigraphic observation, and absolute and relative dating, to interpret several deposits resulting from rock avalanching onto glaciers.Nineteen rock falls and rock avalanches are described, ranging in volume from 10,000 m³ to 10 × 10⁶ m³. They occurred between 2500 BP and AD 2007 at six sites. The events at three sites (Miage and Drus Glaciers, and Tour des Grandes Jorasses) are characterised by short travel distances; those at Brenva, Triolet, and Frébouge Glaciers exhibit excessive travel distances.Interactions between rock avalanches and glaciers are of four types: (i) rock-avalanche triggering, where glacial and paraglacial controls include debuttressing of rockwalls due to glacier thinning and retreat, oversteepening of rock slopes by glacial erosion, and effects of glaciers on permafrost; (ii) rock-avalanche mobility, in which mobility and travel distance are modified by channelling of rock-avalanche debris by moraines and valleys, incorporation of ice and snow (often >50% for large events), and irregularities on the glacier surface; (iii) deposit sedimentology, where melting of incorporated ice transforms the final deposit by reducing its thickness typically to <5 m, and debris of variable thicknesses is juxtaposed in a hummocky deposit with chaotic piles of angular rock debris; and (iv) glacier dynamics where insulating debris deposited upon a glacier produces a debris-covered glacier of different dynamics, and high elevated scars can favour the formation of small glaciers.     

Relict rock glaciers and protalus lobes in the British Isles: implications for Late Pleistocene mountain geomorphology and palaeoclimate

Many relict rock glaciers and protalus lobes have been described in mountainous areas of the British Isles. This paper reviews their distribution, chronology, supposed origin and development, and places the research within current investigations and knowledge. Rock glaciers and protalus lobes are located in a number of different topographic locations and settings. They developed at the base of steep cliffs following the catastrophic failure of rock faces, at the base of scree slopes following the gradual accumulation of rock debris and in association with glaciers. Protalus lobes probably developed in response to the permafrost creep of talus material while rock glaciers formed through the deformation and sliding of large bodies of buried ice. Rock glaciers probably developed, or were last active, during the Younger Dryas, although the possibility exists that some of these landforms are Dimlington Stadial in age. The development of protalus lobes during the Younger Dryas suggests that precipitation levels were low and permafrost was widespread during this time. The lack of rock glaciers (sensu stricto) in the British Isles compared with other mountain areas is believed to be a consequence of the rock type and relative scarcity of weathered debris for their formation rather than a lack of suitable sites or appropriate environmental conditions. Copyright © 2007 John Wiley & Sons, Ltd.     

Estimation of soil organic carbon storage and its fractions in a small karst watershed

With few available soil organic carbon (SOC) profiles and the heterogeneity of those that do exist, the estimation of SOC pools in karst areas is highly uncertain. Based on the spatial heterogeneity of SOC content of 23,536 samples in a karst watershed, a modified estimation method was determined for SOC storage that exclusively applies to karst areas. The method is a “soil-type method” based on revised calculation indexes for SOC storage. In the present study, the organic carbon contents of different soil types varied greatly, but generally decreased with increasing soil depth. The organic carbon content decreased nearly linearly to a depth of 0–50 cm and then varied at depths of 50–100 cm. Because of the large spatial variability in the karst area, we were able to determine that influences of the different indexes on the estimation of SOC storage decreased as follows: soil thickness > boulder content > rock fragment content > SOC content > bulk density. Using the modified formula, the SOC content in the Houzhai watershed in Puding was estimated to range from 3.53 to 5.44 kg m^?2, with an average value of 1.24 kg m^?2 to a depth of 20 cm, and from 4.44 to 14.50 kg m^?2, with an average value of 12.12 kg m^?2 to a depth of 100 cm. The total SOC content was estimated at 5.39 × 10⁵ t.     

Experimental Studies on Permeability of Intact and Singly Jointed Meta-Sedimentary Rocks Under Confining Pressure

Three different types of permeability tests were conducted on 23 intact and singly jointed rock specimens, which were cored from rock blocks collected from a rock cavern under construction in Singapore. The studied rock types belong to inter-bedded meta-sandstone and meta-siltstone with very low porosity and high uniaxial compressive strength. The transient pulse water flow method was employed to measure the permeability of intact meta-sandstone under a confining pressure up to 30 MPa. It showed that the magnitude order of meta-sandstone’s intrinsic permeability is about 10^?18 m². The steady-state gas flow method was used to measure the permeability of both intact meta-siltstone and meta-sandstone in a triaxial cell under different confining pressures spanning from 2.5 to 10 MPa. The measured permeability of both rock types ranged from 10^?21 to 10^?20 m². The influence of a single natural joint on the permeability of both rock types was studied by using the steady-state water flow method under different confining pressures spanning from 1.25 to 5.0 MPa, including loading and unloading phases. The measured permeability of both jointed rocks ranged from 10^?13 to 10^?11 m², where the permeability of jointed meta-siltstone was usually slightly lower than that of jointed meta-sandstone. The permeability of jointed rocks decreases with increasing confining pressure, which can be well fitted by an empirical power law relationship between the permeability and confining pressure or effective pressure. The permeability of partly open cracked specimens is lower than that of open cracked specimens, but it is higher than that of the specimen with a dominant vein for the meta-sandstone under the same confining pressure. The permeability of open cracked rock specimens will partially recover during the unloading confining pressure process. The equivalent crack (joint) aperture is as narrow as a magnitude order of 10^?6 m (1 μm) in the rock specimens under confining pressures spanning from 1.25 to 5.0 MPa, which represent the typical ground stress conditions in the cavern. The in situ hydraulic conductivity measurements conducted in six boreholes by the injection test showed that the in situ permeability of rock mass varies between 10^?18 and 10^?11 m². The lower bound of the in situ permeability is larger than that of the present laboratory-tested intact rock specimens, while the upper bound of the in situ permeability is less than that of the present laboratory-tested jointed rock specimens. The in situ permeability test results were thus compatible with our present laboratory permeability results of both intact and jointed rock specimens.     

Measurement and estimation of the summertime daily evapotranspiration on alpine meadow in the Qilian Mountains, northwest China

Research on mountain evapotranspiration (ET) is important to help understand water cycling and predict streamflow in cold regions in China. Actual daily ET was measured in two types of micro-lysimeters with depth 40 cm and diameter 31.5 cm (A) and depth 27 cm and diameter 27 cm (B), from 1 July 2007 to 10 September 2007, on an alpine meadow in the Qilian Mountains in northwest China, where Bowen ratio measuring instrument and eddy covariance system are too costly and difficult to be built in the region. The results of micro-lysimeters were used as a way to calibrate and test a number of energy balance methods and determine the pan coefficient (K _p) for a mountainous site. The results indicate that the FAO-56 Penman–Monteith offers the best performance, with RMSE of 0.61 mm day^?1, MAD of 0.46 mm day^?1, and the index of agreement near 1, followed by ASCE Penman–Monteith, Priestley–Taylor and Hargreaves–Samani, and the K _p is estimated as 0.7 for the summertime.     

Dynamics and mass balance of the 2007 Cima Una rockfall (Eastern Alps, Italy)

On October 12th, 2007 about 40,000 m³ of dolomitic rock detached from the northern wall of the peak known as “Cima Una” (Val Fiscalina, Sesto Dolomites, Bolzano, Italy), and fell 900 m to Fiscalina Valley below. The event generated a dense dust cloud, which traveled up to 4 km from the source area. The failure surface was formed by two near-vertical surfaces, almost perpendicular to each other. The orientation of these surfaces is consistent with two of the main regional tectonic sets. Only a small portion of the fallen material appeared to be preserved as blocks deposited at the base of the rock wall. About a fifth of the fallen mass was deposited on a colluvial cone. The missing mass, estimated to be about 80 %, may be represented by highly fragmented rock in part deposited as sand on the valley floor and in part dispersed as a dense dust cloud generated during the rockfall. There appears to be a deficit of deposited material, which could lead underestimation in the calculation of rock–cliff recession rates. The dynamics of the rockfall, strongly conditioned by the local topography, partially explains the intense rock breakage and the generation of the dust cloud. The rockfall was not caused by an external trigger, such as an earthquake or heavy rainfall; the failure was most likely progressive due to mechanical and physical degradation along highly stressed failure surfaces, possibly promoted by permafrost degradation and freeze and thaw processes.     

Spatial and Temporal Variability of the CO2 Fluxes in a Tropical, Highly Urbanized Estuary

The spatial and temporal variations of the flux of CO₂ were determined during 2007 in the Recife estuarine system (RES), a tropical estuary that receives anthropogenic loads from one of the most populated and industrialized areas of the Brazilian coast. The RES acts as a source of nutrients (N and P) for coastal waters. The calculated CO₂ fluxes indicate that the upstream inputs of CO₂ from the rivers are largely responsible for the net annual CO₂ emission to the atmosphere of +30 to +48 mmol m^?2 day^?1, depending on the CO₂ exchange calculation used, which mainly occurs during the late austral winter and early summer. The observed inverse relationship between the CO₂ flux and the net ecosystem production (NEP) indicates the high heterotrophy of the system (except for the months of November and December). The NEP varies between ?33 mmol m^?2 day^?1 in summer and ?246 mmol m^?2 day^?1 in winter. The pCO₂ values were permanently high during the study period (average ~4,700 μatm) showing a gradient between the inner (12,900 μatm) and lower (389 μatm) sections on a path of approximately 30 km. This reflects a state of permanent pollution in the basin due to the upstream loading of untreated domestic effluents (N/P?=?1,367:6 μmol kg^?1 and pH?=?6.9 in the inner section), resulting in the continuous mineralization of organic material by heterotrophic organisms and thereby increasing the dissolved CO₂ in estuarine waters.     

Net Primary Productivity of <Emphasis Type="Italic">Spartina densiflora</Emphasis> Brong in an SW Atlantic Coastal Salt Marsh

Coastal marshes are known as organic matter producers. The goal of this work is to study tiller demography, standing biomass, and net aerial primary productivity (NAPP) in a Spartina densiflora coastal wetland, using a method applied to permanent sample plots located at two sites differing in topographic location, a regularly flooded zone [relative low marsh (LM)] and an irregularly flooded one [relative high marsh (HM)]. Measurements were made every 2 months during the 2005–2007 period. The annual NAPP was estimated to be 2,599?±?705 gDW m^?2?year^?1 for the HM and 2,181?±?605 gDW m^?2?year^?1 and 602?±?154 gDW m^?2?year^?1 for the first and second period of the LM populations, respectively, showing a seasonal pattern reaching maximum values in summer. The reduced NAPP values of the LM sites in the second year was associated with an extremely high precipitation period related to the 2007–2008 El Niño event.     

Spatio-Temporal Patterns of Submerged Macrophytes in Three Hydrologically Altered Mediterranean Coastal Lagoons

Rice cultivation in the Ebro Delta (Catalonia, Spain) has inverted the natural hydrological cycles of coastal lagoons and decreased water salinities for over 150 years. Adjustments in the water management practices—in terms of source and amount of freshwater inputs—have resulted in changes in the diversity, distribution and productivity of submerged angiosperms. Between the 1970s and late 1980s, a massive decline of the aquatic vegetation occurred in the Encanyissada–Clot and Tancada lagoons, but little information on the status is available after the recovery of macrophytes in the 1990s. Here, we evaluate the influence of salinity regimes resulting from current water management practices on the composition, distribution, seasonal abundance and flowering rates of submersed macrophytes, as well as on the occurrence of epiphyte and drift macroalgae blooms in three coastal lagoons. Our results show that Ruppia cirrhosa is the dominant species in the Encanyissada lagoon (185.97?±?29.74 g?DW?m^?2?year^?1; 12–27?‰ salinity) and the only plant species found in the Tancada lagoon (53.26?±?10.94 g?DW?m²?year^?1; 16–28?‰ salinity). Flowering of R. cirrhosa (up to 1,011?±?121 flowers?m^?2) was only observed within the Encanyissada and suggests that mesohaline summer conditions may favor these events. In contrast, low salinities in Clot lagoon (～3–12?‰) favor the development of Potamogeton pectinatus (130.53?±?13.79 g?DW?m²?year^?1) with intersperse R. cirrhosa (8.58?±?1.71 g?DW?m^?2) and mixed stands of P. pectinatus and Najas marina (up to ～57 g?DW?m^?2?year^?1) in some reduced areas. The peak biomasses observed during the study are 88 to 95 % lower than maximum values reported in the literature at similar salinities, and there is also little or no recovery in some areas compared to last reports more than 20 years ago. The main management actions to restore the natural diversity and productivity of submersed angiosperms, such as the recovering of the seagrass Zostera noltii, should be the increase of salinity during the period of rice cultivation, by reducing freshwater inputs and increasing flushing connections with the bays.     

Debris flow hazards for mountain regions of Russia: regional features and key events

The total area of debris flow territories of the Russian Federation accounts for about 10% of the area of the country. The highest debris flow activity areas located in Kamchatka-Kuril, North Caucasus and Baikal debris flow provinces. The largest debris flow events connected with volcano eruptions. Maximum volume of debris flow deposits per one event reached 500 × 10⁶ m³ (lahar formed during the eruption of Bezymyanny volcano in Kamchatka in 1956). In the mountains of the Greater Caucasus, the maximum volume of transported debris material reached 3 × 10⁶ m³; the largest debris flows here had glacial reasons. In the Baikal debris flow province, the highest debris flow activity located in the ridges of the Baikal rift zone (the East Sayan Mountains, the Khamar-Daban Ridge and the ridges of the Stanovoye Highland). Spatial features of debris flow processes within the territory of Russia are analyzed, and the map of Debris Flow Hazard in Russia is presented. We classified the debris flow hazard areas into 2 zones, 6 regions and 15 provinces. Warm and cold zones are distinguished. The warm zone covers mountainous areas within the southern part of Russia with temperate climate; rain-induced debris flows are predominant there. The cold zone includes mountainous areas with subarctic and arctic climate; they are characterized by a short warm period, the occurrence of permafrost, as well as the predominance of slush flows. Debris flow events are described for each province. We collected a list of remarkable debris flow events with some parameters of their magnitude and impact. Due to climate change, the characteristics of debris flows will change in the future. Availability of maps and information from previous events will allow to analyze the new cases of debris flows.     

Recent extreme slope failures in glacial environments: effects of thermal perturbation

This paper describes recent exceptional slope failures in high-mountain, glacial environments: the 2002 Kolka–Karmadon rock–ice avalanche in the Caucasus, a series of ice–rock avalanches on Iliamna Volcano, Alaska, the 2005 Mt. Steller rock–ice avalanche in Alaska, and ice and rock avalanches at Monte Rosa, Italy in 2005 and 2007. Deposit volumes range from 10⁶ to 10⁸ m³ and include rock, ice and snow. Here we focus on thermal aspects of these failures reflecting the involvement of glacier ice and permafrost at all sites, suggesting that thermal perturbations likely contributed to the slope failures. We use surface and troposphere air temperatures, near-surface rock temperatures, satellite thermal data, and recent 2D and 3D thermal modeling studies to document thermal conditions at the landslide sites. We distinguish between thermal perturbations of volcanic-geothermal and climatic origin, and thermal perturbations related to glacier–permafrost interaction. The data and analysis support the view that recent, current and future climatic change increases the likelihood of large slope failures in steep glacierized and permafrost terrain. However, some important aspects of these settings such as the geology and tectonic environment remain poorly understood, making the identification of future sites of large slope instabilities difficult. In view of the potentially large natural disasters that can be caused by such slope failures, improved data and understanding are needed.     

Quantifying land use influences on event-based flow frequency,timing, magnitude,and rate of change in an urbanizing watershed of the central USA

There is a need for research that advances understanding of flow alterations in contemporary watersheds where natural and anthropogenic interactions can confound mitigation efforts. Event-based flow frequency, timing, magnitude, and rate of change were quantified at five-site nested gauging sites in a representative mixed-land-use watershed of the central USA. Statistically independent storms were paired by site (n = 111 × 5 sites) to test for significant differences in event-based rainfall and flow response variables (n = 17) between gauging sites. Increased frequency of small peak flow events (i.e., 64 more events less than 4.0 m³ s^?1) was observed at the rural–urban interface of the watershed. Differences in flow response were apparent during drier periods when small rainfall events resulted in increased flow response at urban sites in the lower reaches. Relationships between rainfall and peak flow were stronger with decreased pasture/crop land use and increased urban land use by approximately 20%. Event-based total rainfall explained 40–68% of the variance in peak flow (p < 0.001). Coefficients of determination (r²) were negatively correlated with pasture/crop land use (r² = 0.92; p = 0.007; n = 5) and positively correlated with urban land use (r² = 0.90; p = 0.008; n = 5). Significant differences in flow metrics were observed between rural and urban sites (p < 0.05; n = 111) that were not explained by differences in rainfall variables and drainage area. An urban influence on flow timing was observed using median time lag to peak centroid and time of maximum precipitation to peak flow. Results highlight the need to establish manageable flow targets in rapidly urbanizing mixed-land-use watersheds.     

Growth behavior and resource potential evaluation of gas hydrate in core fractures in Qilian Mountain permafrost area,Qinghai-Tibet Plateau

The Qilian Mountain permafrost area located in the northern of Qinghai-Tibet Plateau is a favorable place for natural gas hydrate formation and enrichment, due to its well-developed fractures and abundant gas sources. Understanding the formation and distribution of multi-component gas hydrates in fractures is crucial in accurately evaluating the hydrate reservoir resources in this area. The hydrate formation experiments were carried out using the core samples drilled from hydrate-bearing sediments in Qilian Mountain permafrost area and the multi-component gas with similar composition to natural gas hydrates in Qilian Mountain permafrost area. The formation and distribution characteristics of multi-component gas hydrates in core samples were observed in situ by X-ray Computed Tomography (X-CT) under high pressure and low temperature conditions. Results show that hydrates are mainly formed and distributed in the fractures with good connectivity. The ratios of volume of hydrates formed in fractures to the volume of fractures are about 96.8% and 60.67% in two different core samples. This indicates that the fracture surface may act as a favorable reaction site for hydrate formation in core samples. Based on the field geological data and the experimental results, it is preliminarily estimated that the inventory of methane stored in the fractured gas hydrate in Qilian Mountain permafrost area is about 8.67×10¹³ m³, with a resource abundance of 8.67×10⁸ m³/km². This study demonstrates the great resource potential of fractured gas hydrate and also provides a new way to further understand the prospect of natural gas hydrate and other oil and gas resources in Qilian Mountain permafrost area.©2023 China Geology Editorial Office.     

Hydrogeochemistry and possible sulfate sources in karst groundwater in Chongqing, China

Groundwater from karst subterranean streams is among the world’s most important sources of drinking water supplies, and the hydrochemical characteristics of karst water are affected by both natural environment and people. Therefore, the study of karst groundwater hydrochemistry and its solutes’ sources is very important to ensure the normal function of life support systems. This paper focused on the major ion chemistry and sulfate isotope of karst groundwater in Chongqing for tracing the sulfate sources and related hydrochemical processes. Hydrochemical types of karst groundwater in Chongqing were mainly of the Ca-HCO₃ type or Ca(Mg)-HCO₃ type. However, some hydrochemical types were the K + Na + Ca-SO₄ type (G25 site) or Ca-HCO₃ + SO₄ type (G26 and G14 sites), indicating that the hydrochemistry of these sites may be strongly influenced by anthropogenic activities or unique geological characteristics. The δ³⁴S-SO₄ ^2? of collected karst groundwater sample fell into a range of ?6.8 to 21.5 ‰, with a mean value of 5.6 ‰. In dolomite aquifer, the δ³⁴S-SO₄ ^2? value ranges from ?4.3 to 11.0 ‰, and in limestone aquifer, it ranged from ?6.8 to 21.5 ‰. The groundwater samples from different land use types showed distinctive δ³⁴S-SO₄ ^2? value. The δ³⁴S-SO₄ ^2? value of groundwater samples had range of ?6.8 to 16.7 ‰ (mean 4.0 ‰, n = 11) in cultivated land areas, 1.5–21.5 ‰ (mean 7.2 ‰, n = 20) in forested land areas, and ?4.3 to 0.8 ‰ (mean ?1.7 ‰, n = 2) in coalmine areas. The δ³⁴S-SO₄ ^2? values of groundwater samples collected from factory area and town area were 2.2 and 9.9 ‰, respectively. According to the δ³⁴S information of potential sulfate sources, this paper discussed the possible sulfate sources of collected karst groundwater samples in Chongqing. The variations of both δ³⁴S and 1/SO₄ ^2? values of the groundwater samples indicated that the atmospheric acid deposition (AAD), dissolution of gypsum (GD), oxidation of sulfide mineral (OS) or anthropogenic inputs (SF: sewage or fertilizer) contributed to sulfate in karst groundwater. The influence of oxidation of sulfide mineral, atmospheric acid deposit and anthropogenic inputs to groundwater in Chongqing karst areas was much widespread. For protecting, sustaining, and utilizing the groundwater resources, the sewage possibly originating from urban, mine or industrial area must be controlled and treated, and the use of fertilizer should be limited.     

Holocene development and permafrost history in sub‐arctic peatlands in Tavvavuoma,northern Sweden

Under changing climatic conditions permafrost peatlands can play an important role in the global carbon budget through permafrost carbon feedbacks and shifts in carbon assimilation. To better predict future dynamics in these ecosystems an increased understanding of their Holocene carbon and permafrost history is needed. In Tavvavuoma, northern Sweden, we have performed detailed analyses of vegetation succession and geochemical properties at six permafrost peatland sites. Peatland initiation took place around 10 000 to 9600 cal. a BP, soon after retreat of the Fennoscandian Ice Sheet, and the peatlands have remained permafrost‐free fens throughout most of the Holocene. At the four sites that showed a continuous accumulation record during the late Holocene radiocarbon dating of the shift from wet fen to dry bog vegetation, characteristic of the present permafrost peatland surface, suggests that permafrost developed at around 600–100 cal. a BP. At the other two sites peat accumulation was halted during the late Holocene, possibly due to abrasion, making it more difficult to imply the timing of permafrost aggradation. However also at these sites there are no indications of permafrost inception prior to the Little Ice Age. The mean long‐term Holocene carbon accumulation rate at all six sites was 12.3±2.4 gC m⁻² a⁻¹ (±SD), and the mean soil organic carbon storage was 114±27 kg m⁻².     

Loading, Transformation, and Retention of Nitrogen and Phosphorus in the Tidal Freshwater James River (Virginia)

A nutrient mass balance for the tidal freshwater segment of the James River was used to assess sources of nutrients supporting phytoplankton production and the importance of the tidal freshwater zone in mitigating nutrient transport to marine waters. Monthly mass balances for 2007–2010 were based on riverine inputs, local point sources (including sewer overflow events), ungauged inputs, riverine outputs, and tidal exchange. The tidal freshwater James River received exceptionally high areal loads (446 mg TN m^?2 day^?1 and 55 mg TP m^?2 day^?1) compared to other estuaries in the region and elsewhere. P inputs were principally from riverine sources (84 %) whereas point sources contributed appreciably (54 %) to high N loads. Despite high loading rates and short water residence time, areal mass retention was high (143 mg TN m^?2 day^?1 and 33 mg TP m^?2 day^?1). Retention of particulate fractions occurred during high discharge, whereas dissolved inorganic fractions were retained during low discharge when chlorophyll-a concentrations were high. On an annualized basis, P was retained more effectively (59 %) than N (32 %). P was retained by abiotic mechanisms via trapping of particulate forms, whereas N was retained through biological assimilation of dissolved inorganic forms. Results from a limited suite of stable isotope determinations suggest that DIN from point sources was preferentially retained. Combined inputs from diffuse and point sources accounted for only 20 % and 36 % (respectively) of estimated algal N and P demand, indicating that internal nutrient recycling was important to sustaining high rates of phytoplankton production in the tidal freshwater zone.