Comparison of chemical hydrogeology of the carbonate peninsulas of Florida and Yucatan

Aquifers of the peninsulas of Florida and northern Yucatan are Tertiary marine carbonate formations showing many lithologic and faunal similarities. In addition, the tropical to subtropical climates of the two areas are similar, each having annual rainfall of about 1000 to 1500 mm.

Despite similarities in these fundamental controls, contrasts in the hydrologic and geochemical systems are numerous and striking. For example, Florida has many rivers; Yucatan has none. Maximum thickness of fresh ground water in Florida is about 700 meters; in the Yucatan it is less than 70 meters. In Florida the gradient of the potentiometric surface averages about 1 meter per kilometer; in the Yucatan it is exceedingly low, averaging about 0.02 meter per kilometer. In Florida the chemical character of water changes systematically downgradient, owing to solution of minerals of the aquifer and corresponding increases in total dissolved solids, sulfate, calcium, and Mg-Ca ratio; in the Yucatan no downgradient change exists, and dominant processes controlling the chemical character of the water are solution of minerals and simple mixing of the fresh water and the body of salt water that underlies the peninsula at shallow depth.

Hydrologic and chemical differences are caused in part by the lower altitude of the Yucatan plain. More important, however, these differences are due to the lack of an upper confining bed in Yucatan that is hydrologically equivalent to the Hawthorn Formation of Florida. The Hawthorn cover prevents recharge and confines the artesian water except where it is punctured by sinkholes, but sands and other unconsolidated sediments fill sinkholes and cavities and impede circulation. In the Yucatan the permeability of the entire section is so enormous that rainfall immediately infiltrates to the water table and then moves laterally to discharge areas along the coasts.     

Sea level variability in the Gulf of Mexico since 1900 and its link to the Yucatan Channel and the Florida Strait flows

The long-term variability of sea level and surface flows in the Gulf of Mexico (GOM) is studied using global monthly sea level reconstruction (RecSL) for 1900–2015. The study explored the long-term relation between the dynamics of the GOM and inflows/outflows through the Yucatan Channel (YC) and the Florida Straits (FS). The results show a century-long trend of increased mean velocity and variability in the Loop Current (LC); however, no significant upward trend was found in the YC and FS flows, only increased variability. Empirical orthogonal function (EOF) analysis of sea surface height found spatial patterns dominated by variations in the LC and temporal variations on time scales ranging from a few months to multidecadal. The time evolution of each EOF mode of sea level is correlated with the velocity of either the LC, the YC, or the FS or some combination of the different flows. The mean sea level difference between the GOM and the northwestern Caribbean Sea was found to be influenced by the North Atlantic Oscillation (NAO), with unusually high differences during the 1970s when the NAO index was low and the Atlantic Ocean circulation was weak. Extreme peaks in SL difference coincide with the extension of the LC and the seasonal eddy shedding pattern. The observed seasonal cycle in the extension area of the LC as obtained from 20 years of altimeter data is significantly correlated (R = 0.63; confidence level = 98%) with the seasonal YC flow obtained from 116 years of the RecSL data. However, the same LC extension record had lower correlation (R = 0.45; confidence level = 90%) with the observed YC transport obtained from direct moored measurements over ~ 5 years, indicating the need for much longer measurements, since the LC extension and the YC flow are strongly affected by interannual and decadal variations. The study demonstrates the usefulness of even a coarse-resolution reconstruction for studies of regional ocean variability and climate change over longer time scales than current direct observations allow.

     

Links between saltwater intrusion and subtidal circulation in the Changjiang Estuary: A model-guided study

In this paper we discuss the links between saltwater intrusion and subtidal circulation in the Changjiang Estuary based on a 3D numerical model. We restricted our study mainly to the three major outlets of the estuary: the South Passage, the North Passage, and the North Channel. Subtidal transport is landward in the South Passage and NNW- or NW-ward on the shoals, whereas it is mainly seaward in the North Passage and North Channel. Such a residual characteristic is caused by the interaction between tide and shallow water depth. Decomposing analysis indicated that Stokes transport is the major mechanism causing this particular residual transport pattern. Under its influence, the South Passage is the most saline outlet and the North Channel is the major route discharging the Changjiang runoff. Results of a tracer experiment indicated that active water mass exchange occurs from the South Passage to the North Passage and finally to the North Channel. Thus, the salinity in each outlet is determined not only by the tidal-averaged diversion ratio around the bifurcation of the South and North Channels but also by the subtidal circulation in the waterways and on the shoals. The northerly wind produces a horizontal circulation around the river mouth, which flows into the estuary in the North Channel and out of the estuary in the South Channel and South Passage. This circulation increases the salinity in the North Channel and decreases it in the South Passage. Recent engineering projects have intensified the landward residual in the South Passage, thereby increasing the salinity in the South Passage and decreasing the salinity in the North Channel.     

A numerical study of the circulation and monthly-to-seasonal variability in the Caribbean Sea: the role of Caribbean eddies

This study examines the circulation and associated monthly-to-seasonal variability in the Caribbean Sea using a regional ocean circulation model. The model domain covers the region between 99.0 and 54.0°W and between 8.0 and 30.3°N, with a horizontal resolution of 1/6°. The ocean circulation model is driven by 6-hourly atmospheric reanalysis data from the National Center for Environmental Prediction and boundary forcing extracted from 5-day global ocean reanalysis data produced by Smith et al. (Mercator Newsletter 36:39–49, 2010), and integrated for 7 years. A comparison of model results with observations demonstrates that the regional ocean circulation model has skill in simulating circulation and associated variability in the study region. Analysis of the model results, as well as a companion model run that uses steady annual mean forcing, illustrates the role of Caribbean eddies for driving monthly-to-seasonal circulation variability in the model. It is found that vertically integrated transport between Nicaragua and Jamaica is influenced by the interaction between the density perturbations associated with Caribbean eddies and the Nicaraguan Ridge. The impact of Caribbean eddies squeezing through the Yucatan Channel is also discussed.     

Dissolved and particulate trace metal fluxes through the central English Channel, and the influence of coastal gyres

Measurements of dissolved Cd, Co, Cu, Mn, Ni, Pb, and Zn have been made on a seasonal basis at five stations on a north–south transect across the central English Channel between Cherbourg and the Isle of Wight. Vertical and horizontal distributions of dissolved Cd, Pb, Cu and Zn are relatively uniform except for sampling sites near the English coast. Dissolved Mn and Co show increased concentrations in the English coastal waters, and for Mn the seasonal trend in concentration follows the pattern seen in the Strait of Dover with higher values in the late summer. Ni and Cu are higher in concentration on the English side, which reflects mainly riverine sources. Measurements were also made of particulate forms of the metals above plus particulate Al, Ca, Fe, Mg, Sr and Ti. Water column concentrations of particulate metals broadly follow the distribution of suspended particulate matter, with highest concentrations near the UK coast. Trace metal concentrations have been integrated with modelled data on fluxes of water to provide estimates of fluxes for these elements into the eastern Channel, and an initial comparison is made with data for fluxes of metals through the Strait of Dover obtained during an earlier study. A major influence on the fluxes of particulate metals through the Isle of Wight-Cherbourg transect is the gyre system to the South east to the Isle of Wight, which has important east to west as well as west to east transport components. For those elements where the dissolved form of the metal dominates, the large flow of water in the central Channel waters leads to major fluxes of the metals towards the east and the Strait of Dover. However, the high suspended particulate matter loadings in the coastal waters and impact of the gyre system lead to net east to west fluxes of particulate Al, Fe, Mn and Ti. Comparison of these fluxes with data on the net west to east transport of these materials through the Strait of Dover infers that there must be a significant supply of these particulate metals to the eastern Channel.     

The influence of wind forcing on across-shelf transport in the Florida Keys

Acoustic Doppler current profiles and current meter data are combined with wind observations to describe the transport of water leaving Florida Bay and moving onto the inner shelf on the Atlantic side of the Florida Keys. A 275-day study in the Long Key Channel reveals strong tidal exchanges, but the average ebb tide volume leaving Florida Bay is 19% greater than the average flood tide volume entering the bay. The long-term net outflow averages 472 m³ s⁻¹. Two studies in shelf waters describe the response to wind forcing during spring and summer months in 2004 and during fall and winter months in 2004–2005. During the spring–summer study, southeasterly winds have a distinct shoreward component, and a two-layer pattern appears. Surface layers move shoreward while near-bottom layers move seaward. During the winter study, the resultant wind direction is parallel to the Keys and to the local isobaths. The entire water column moves in a nearly downwind direction, and across-shelf transport is relatively small. During the summer wet season, Florida Bay water should be warmer, fresher, and thus less dense than Atlantic shelf waters. Ebbing bay water should move onto the shelf as a buoyant plume and be held close to the Keys by southeasterly winds. During the winter dry season, colder and saltier Florida Bay water should leave the tidal channels with relatively high density and be concentrated in the near-bottom layers. But little across-shelf flow occurs with northeasterly winds. The study suggests that seasonally changing wind forcing and hydrographic conditions serve to insulate the reef tract from the impact of low-quality bay water.     

Effects of lateral confinement in natural and leveed reaches of a gravel‐bed river: Snake River,Wyoming, USA

This study examined the effects of natural and anthropogenic changes in confining margin width by applying remote sensing techniques – fusing LiDAR topography with image‐derived bathymetry – over a large spatial extent: 58 km of the Snake River, Wyoming, USA. Fused digital elevation models from 2007 and 2012 were differenced to quantify changes in the volume of stored sediment, develop morphological sediment budgets, and infer spatial gradients in bed material transport. Our study spanned two similar reaches that were subject to different controls on confining margin width: natural terraces versus artificial levees. Channel planform in reaches with similar slope and confining margin width differed depending on whether the margins were natural or anthropogenic. The effects of tributaries also differed between the two reaches. Generally, the natural reach featured greater confining margin widths and was depositional, whereas artificial lateral constriction in the leveed reach produced a sediment budget that was closer to balanced. Although our remote sensing methods provided topographic data over a large area, net volumetric changes were not statistically significant due to the uncertainty associated with bed elevation estimates. We therefore focused on along‐channel spatial differences in bed material transport rather than absolute volumes of sediment. To complement indirect estimates of sediment transport derived by morphological sediment budgeting, we collected field data on bed mobility through a tracer study. Surface and subsurface grain size measurements were combined with bed mobility observations to calculate armoring and dimensionless sediment transport ratios, which indicated that sediment supply exceeded transport capacity in the natural reach and vice versa in the leveed reach. We hypothesize that constriction by levees induced an initial phase of incision and bed armoring. Because levees prevented bank erosion, the channel excavated sediment by migrating rapidly across the restricted braidplain and eroding bars and islands. Copyright © 2017 John Wiley & Sons, Ltd.     

Connectivity of the Apalachicola River flow variability and the physical and bio-optical oceanic properties of the northern West Florida Shelf

Maps of satellite-derived estimates of monthly averaged chlorophyll a concentration over the northern West Florida Shelf show interannual variations concentrated near the coastline, but also extending offshore over the shelf in a tongue-like pattern from the Apalachicola River during the late winter and early spring. These anomalies are significantly correlated with interannual variability in the flow rate of the Apalachicola River, which is linked to the precipitation anomalies over the watershed, over a region extending 150–200 km offshore out to roughly the 100 m isobath. This study examines the variability of the Apalachicola River and its impacts on the variability of water properties over the northern West Florida Shelf. A series of numerical model experiments show that episodic wind-driven offshore transport of the Apalachicola River plume is a likely physical mechanism for connecting the variability of the river discharge with oceanic variability over the middle and outer shelf.     

An altimetric transport index for Kuroshio inflow northeast of Taiwan Island

The Kuroshio inflow northeast of Taiwan Island plays an important role in the heat and nutrient balances over the East China Sea(ECS). Based on merged satellite altimeter data and the PCM-1 mooring observation at the East Taiwan Channel(ETC), the study employs a correlation iteration scheme to find the optimal transport index for the Kuroshio inflow. The sea level difference with the highest correlation to the ETC transport is across the ECS shelf break rather than along the PCM-1 line. The counter-intuitive result is caused by large signal noise and poor track coverage of altimeters near the Taiwan coast. The optimal altimetric index is highly correlated with the two-year in-situ measurements as well as the ten-year output of the global assimilation model. It serves as a better estimator of Kuroshio inflow than those using tidal gauge data, and helps pinpoint a 5 cm mismatch of mean sea level in the Keelung tidal record. The mean transport of Kuroshio inflow based on the twenty-year altimetric index is 20.55 Sv with a standard deviation of 3.05 Sv. Wavelet spectrum of the index reveals that semi-annual period dominates the Kuroshio variation northeast of Taiwan Island.     

Distribution,sources and fates of floating oil residues in the Eastern Gulf of Mexico

Pelagic tar was monitored over a two-year period in the Eastern Gulf of Mexico. A total of 416 surface and subsurface samples were collected during monthly cruises. Concentrations of pelagic tar found in the Eastern Gulf of Mexico were substantially higher than values reported for other areas around the world. Tar is primarily associated with the Gulf Loop Current, whereas continental shelf areas are relatively uncontaminated. Grounding of significant amounts of tar occurs primarily along the south-east coast of Florida, between Key West and Fort Pierce. Approximately 10–50% of the tar in the eastern Gulf is transported in from the Caribbean Sea via the Yucatan Straits. The remainder originates within the Gulf. Approximately half of the pelagic tar samples collected during the study appeared to have originated from tanker operations.     

Dispersion of dissolved trace metals from the Irish Sea into Scottish coastal waters

An investigation has been undertaken into the dispersal of contaminants from the Irish Sea into coastal waters of Scotland via the North Channel. A total of 97 surface samples have been analysed for dissolved copper, cadmium and lead. Salinity and reactive phosphate have also been determined. Evidence is presented to suggest that copper, cadmium and reactive phosphate behave essentially conservatively on mixing into Scottish coastal waters. This behaviour is likened to the dispersal of¹³⁷Cs from the Sellafield nuclear fuel reprocessing plant. It is suggested that this simple mechanism is inadequate to account for the lead distribution. It is proposed that this element is partly taken up by suspended particulates and sediments in the well-mixed turbid waters of the North Channel.It has been demonstrated elsewhere that contaminants from the Irish Sea, such as¹³⁷Cs enter the Firth of Clyde from the North Channel. In the present study North Channel waters are demonstrated to be an important source of trace metals to the Firth of Clyde. At the time of this survey however high concentrations of trace metals were not entering the Firth of Clyde from the North Channel. This is principally attributed to a salinity front associated with the entrance of the Firth which hinders transport across the sill.     

Wind influence on surface current variability in the Ibiza Channel from HF Radar

Surface current variability is investigated using 2.5 years of continuous velocity measurements from an high frequency radar (HFR) located in the Ibiza Channel (Western Mediterranean Sea). The Ibiza Channel is identified as a key geographical feature for the exchange of water masses but still poorly documented. Operational, quality controlled, HFR derived velocities are provided by the Balearic Islands Coastal Observing and Forecasting System (SOCIB). They are assessed by performing statistical comparisons with current-meter, ADCP, and surface lagrangian drifters. HFR system does not show significant bias, and its accuracy is in accordance with previous studies performed in other areas. The main surface circulation patterns are deduced from an EOF analysis. The first three modes represent almost 70 % of the total variability. A cross-correlation analysis between zonal and meridional wind components and the temporal amplitudes of the first three modes reveal that the first two modes are mainly driven by local winds, with immediate effects of wind forcing and veering following Ekman effect. The first mode (37 % of total variability) is the response of meridional wind while the second mode (24 % of total variability) is linked primarily with zonal winds. The third and higher order modes are related to mesoscale circulation features. HFR derived surface transport presents a markedly seasonal variability being mostly southwards. Its comparison with Ekman-induced transport shows that wind contribution to the total surface transport is on average around 65 %.     

On the dynamics of strait flows: an ocean model study of the Aleutian passages and the Bering Strait

A high-resolution numerical ocean circulation model of the Bering Sea (BS) is used to study the natural variability of the BS straits. Three distinct categories of strait dynamics have been identified: (1) Shallow passages such as the Bering Strait and the Unimak Passage have northward, near barotropic flow with periodic pulses of larger transports; (2) wide passages such as Near Straits, Amukta Pass, and Buldir Pass have complex flow patterns driven by the passage of mesoscale eddies across the strait; and (3) deep passages such as Amchitka Pass and Kamchatka Strait have persistent deep return flows opposite in direction to major surface currents; the deep flows persist independent of the local wind. Empirical orthogonal function analyses reveal the spatial structure and the temporal variability of strait flows and demonstrate how mesoscale variations in the Aleutian passages influence the Bering Strait flow toward the Arctic Ocean. The study suggests a general relation between the barotropic and baroclinic Rossby radii of deformations in each strait, and the level of flow variability through the strait, independent of geographical location. The mesoscale variability in the BS seems to originate from two different sources: a remote origin from variability in the Alaskan Stream that enters the BS through the Aleutian passages and a local origin from the interaction of currents with the Bowers Ridge in the Aleutian Basin. Comparisons between the flow in the Aleutian passages and flow in other straits, such as the Yucatan Channel and the Faroe Bank Channel, suggest some universal topographically induced dynamics in strait flows.     

Variability of bedload transport and channel morphology in a braided river hydraulic model

This paper investigates variability in bedload transport and channel morphology for 11 replicate experimental runs in an approximately 1:50 braided river model. The experiments, each of 90 h duration, were carried out in a 20 × 3m tilting flume. All the experiments started with the same initial conditions. Bedload transport was measured at 5 min intervals in a collection drum at the exit from the flume. The model showed reasonable hydraulic similarity when compared to prototype rivers. Results show that mean bedload transport rates for the 11 runs vary in the range 0·98 to 1·49gs^?1 (mean + 1·21, coefficient of variation 11 per cent). Within-run transport rates commonly vary from close to zero, to two and occasionally three or four times the mean rate. Within the bedload series, several irregular phases of transport intensity can be observed, but time series analysis of the data show little underlying serial structure (an AR(2) autoregressive model is appropriate). Channel patterns are narrow/braided, are established quickly and remain relatively stable throughout the runs, although channel widths increase between 20 and 103 per cent over the 11 runs. Channel behaviour varies from aggradational to transitional between aggradation and degradation. Time-averaged bedload transport rate is weakly correlated with braiding intensity. In general, these results demonstrate that for a given set of controlling variables, bedload transport and channel morphology can be approximately replicated.     

Sediment dynamics in an offshore tidal channel in the southern Yellow Sea

The geomorphology of the southern Yellow Sea（SYS） is characterized by offshore radial sand ridges（RSR）.An offshore tidal channel（KSY Channel） is located perpendicular to the coast,comprised of a main and a tributary channel separated by a submarine sand ridge（KSY Sand Ridge） extending seaward.In order to investigate the interactions among water flow,sediment transport,and topography,current velocity and suspended sediment concentration（SSC） were observed at 11 anchor stations along KSY Channel in RSR during a spring tide cycle.High resolution bottom topography was also surveyed.Residual currents and tidally averaged suspended sediment fluxes were calculated and analyzed by using the decomposition method.Results suggested that the water currents became stronger landward but with asymmetrical current speed and temporal duration of flood and ebb tides.Residual currents showed landward water transport in the nearshore channel and a clockwise circulation around the KSY Sand Ridge.Tidally-averaged SSC also increased landward along the channel.The main mechanisms controlling SSC variations were resuspension and horizontal advection,with spatial and temporal variations in the channel,which also contributed to sediment redistribution between channels and sand ridges.Residual flow transport and the tidal pumping effect dominated the suspended sediment flux in the KSY Channel.The KSY Sand Ridge had a potential southward migration due to the interaction between water flow,sediment transport,and topography.     

Using groundwater age distributions to estimate the effective parameters of Fickian and non-Fickian models of solute transport

Groundwater age distributions are used to estimate the parameters of Fickian, and non-Fickian, effective models of solute transport. Based on the similarities between the transport and age equations, we develop a deconvolution based approach that describes transport between two monitoring wells. We show that the proposed method gives exact estimates of the travel time distribution between two wells when the domain is stationary and that the method still provides useful information on transport when the domain is non-stationary. The method is demonstrated using idealized uniform and layered 2-D aquifers. Homogeneous transport is determined exactly and non-Fickian transport in a layered aquifer was also approximated very well, even though this example problem is shown to be scale-dependent. This work introduces a method that addresses a significant limitation of tracer tests and non-Fickian transport modeling which is the difficulty in determining the effective parameters of the transport model.     

On the general character of coastal flow

It is well-known that some coastal currents such as the Florida Current have a recirculating region on their coastal side, while other currents such as the East Australian Current have no such region. Under the hypothesis that the form drag on a coastal current by an irregular coastal topography reduces the momentum transport of the current to a minimum for the given flow within the current, the hydraulic theory of coastal currents is used to explain this behaviour.     

A test of a climatic index of dune mobility using measurements from the southwestern United States

The climatic index of dune mobility developed by Lancaster (1988) has been applied to a variety of different environments. The index is, however, untested and unverified. We tested the index by comparison of values of the dune mobility index calculated from climate data with rates of sand transport measured at three stations in Arizona and New Mexico over the period 1985 to 1997. Our results show that changes in measured rates of sand transport closely parallel temporal changes in the dune mobility index. The mobility index is, however, a relatively poor predictor of the magnitude of actual sand transport on a year‐to‐year basis. This discrepancy is probably due to the fact that sand transport rates at these sites are strongly influenced by vegetation cover, the state of which may lag changes in annual precipitation. There is, however, a good relation between the mean annual mobility index and mean annual rates of sand transport. This indicates that the dune mobility index is a valid predictor of the long‐term state of the aeolian system and can be used confidently for the purposes for which it was originally intended. Copyright © 2000 John Wiley & Sons, Ltd.     

Dissolved nutrient distributions in the Central English Channel

Samples for analysis of nitrate plus nitrite, dissolved reactive phosphate and silicate were collected in the English Channel along a transect between Cherbourg and the Isle of Wight, within the framework of the FLUXMANCHE II programme. A total of 130 samples were obtained during 15 cruises between December 1994 and December 1995, thus giving a full seasonal coverage. Nutrient concentrations were generally highest on the UK side of the Channel, where riverine inputs were greatest. Nutrient fluxes across this transect from west to east for the winter period, when the nutrients exhibited quasi-conservative behaviour, were calculated using the N, P and Si data, and estimates of water fluxes derived from a two-dimensional hydrodynamic numerical model. A gyre system off the Isle of Wight led to localised east to west fluxes of nutrients. Although nutrient concentrations are lower in the central Channel than in the coastal zones, the nutrient fluxes are greatest through this central zone because of the higher fluxes of water through this part of the transect. The fluxes obtained through this mid-Channel transect are greater than fluxes estimated through the Straits of Dover for a similar winter period as part of the earlier FLUXMANCHE I (December 1990– March 1991) programme, suggesting significant variability from year to year, and/or removal of nutrients in the eastern Channel.     

Dispersion in the Yucatan coastal zone: Implications for red tide events

The mechanisms governing dispersion processes in the northern Yucatan coast are investigated using a barotropic numerical model of coastal circulation, which includes wind-generated and large scale currents (i.e. Yucatan Current). This work provides the foundations for studying the dispersion of harmful algal blooms (HABs) in the area. Modelling experiments include effects of climatic wind (from long term monthly mean NCEP reanalysis), short term wind events (from in situ point measurements), and Yucatan Current (YC) characteristics. Its magnitude was approximated from published reports, and its trajectory from geostrophic current fields derived from altimeter data. These provided a range of real and climatic conditions to study the routes in which phytoplankton blooms may travel. The 2-D model results show that a synthetic and conservative bloom seeded in the Cabo Catoche (CC) region (where it usually grows), moves along the coast to the west up to San Felipe (SF), where it can either move offshore, or carry on travelling westwards. The transport to the west up to SF is greatly influenced by the trajectory, intensity and proximity of the YC jet to the peninsula, which enhances the westward circulation in the Yucatan Shelf. Numerical experiments show that patch dispersion is consistently to the west even under the influence of northerly winds. When the YC flows westward towards the Campeche Bank, momentum transfer caused by the YC jet dominates the dispersion processes over wind stress. On the other hand, when it flows closer to Cuba, the local processes (i.e. wind and bathymetry) become dominant. Coastal orientation and the Coriolis force may be responsible for driving the patch offshore at SF if external forcing decreases.