黑河干流浅层地下水与地表水相互转化的水化学特征

通过分析黑河干流地表水与地下水的水化学特征,识别沿黑河干流不同地带地下水与地表水的相互转化关系.研究结果表明:(1)在祁连山区,地下水与地表水的转化以地下水向河流排泄为主.(2)南部盆地,在山前戈壁带,出山河水入渗转化为地下水;溢出带地下水以泉的形式转化为地表水;进入细土平原后,汛期河水补给地下水,非汛期地下水补给河水;在农灌区引河水通过田间入渗补给地下水.(3)北部盆地,在金塔灌区,地下水主要接受引水灌溉入渗补给;在金塔灌区到额济纳旗,河流入渗转化为地下水.     

Uraniferous waters of the Arkansas River valley,Colorado, U.S.A.: a function of geology and land use

The effect of local geology and land-use practices on dissolved U was investigated by analysis of surface water and some springs in the Arkansas River valley of southeastern Colorado. Water samples were collected during a 2 week period in April, 1991. The rate of increase of U concentration with distance downriver increased markedly as the river flowed from predominantly undeveloped lands underlain by igneous and metamorphic rocks to agriculturally developed lands underlain by marine shale and limestone. An additional abrupt increase in dissolved U was observed along the section of river where discharge is often greatly reduced because of extensive diversions for irrigation and where remaining flow is largely composed of irrigation return water. Dissolved U in this last section of river and in most of its tributaries exceeded the proposed U.S. drinking water standard of 20 μ/L In water samples collected from agricultural areas dissolved U showed strong positive correlation with major dissolved constituents Na, Ca, Mg, and SO₄ that increase as a result of sulfate mineral dissolution and clay mineral ion-exchange reactions in weathered shale bedrock and shaley soils. Highly soluble minor and trace elements Cl, Li, B, Sr, and Se that are not subject to strong sorptive uptake or precipitation in this setting also correlated positively with U. These combined observations indicate that natural leaching of U-bearing shale bedrock and derivative soils, additional leaching of rock and soil by irrigation water, and evaporative concentration in a semi-arid climate can produce concentrations of dissolved U in surface water and shallow ground water that may threaten nearby drinking water supplies. Other agriculturally developed areas of the semi-arid Western U.S. with similar geology are likely to contain high concentrations of U in irrigation drain water.     

石羊河流域水资源开发利用与补给之间的协调性评判

在甘肃省石羊河流域历史水资源开发利用情况简述基础上,结合城镇化进程,提出目前武威市的农业用水来源于祁连山山前水库拦蓄地表水,景电二期延伸工程向民勤所调黄河水及部分地方开采地下水;工业、生活用水均取自地下水,水量供给与天然补给上已处于严重失调状态。就城市地下水源地保护区划分而言,以传统的地下水开采影响半径为基本依据所进行的现代地下水源地保护区划分是不合理、不够科学的,应当在地下水补给、径流、排泄条件分析基础上,将水源地上游整个流域划定为保护区,以永久性解决城市地下水供水中存在的水源地安全问题。另外,针对石羊河流域重点治理规划中的调水方案,比较科学、合理的做法是：应从石羊河流域地下水文地质条件出发,遵循第四世地质历史时期形成的地下水补给、径流、排泄通道,在全流域实施压减灌溉面积、减少地下水开采量的同时,将景电二期延伸工程所调黄河水与祁连山山前部分水库地表水部分地或全部地从石羊河上游———武威盆地上游区域通过灌溉或其它方式下渗,补给进入地下水系统中,最终达到六河水系及下游地下水位停止下降,石羊河下游民勤盆地地下水位持续回升的综合治理规划目标,而不是将水直接调入下游民勤盆地。     

Spatial characteristics of water quality,stable isotopes and tritium associated with groundwater flow in the Hutuo River alluvial fan plain of the North China Plain

The groundwater flow system and the flow velocity in the alluvial fan plain of the Hutuo River, China, have been studied, with an emphasis on relating geochemical characteristics and isotopes factors. Seven stretches of one river, six springs and 31 wells, with depths ranging from 0 m (river waters) to 150 m, were surveyed. The groundwater has a vertical two-layer structure with a boundary at about 80–100 m depth, yielding an upper and a lower groundwater layer. The δ¹⁸O and δD values range from ?10.56 to ?7.05‰ and ?81.83 to ?59‰, respectively. The groundwater has been recharged by precipitation, and has not been subjected to significant evaporation during infiltration into the aquifer in the upper layer. Using a tritium model, the groundwater flow in the alluvial fan plain showed horizontal flow velocity to be greater than vertical velocity. Groundwater in the upper layer is characterized by Ca–HCO₃ type. From the spatial distribution characteristics of the stable isotope and chemical composition of the groundwater, agricultural irrigation was considered to have an influence on the aquifer by causing excessive groundwater abstraction and irrigation return.     

Was There a Pliocene-Pleistocene Fluvial-Lacustrine Connection between Death Valley and the Colorado River?

Since the turn of the century, a Pliocene-Pleistocene connection between the Death Valley-Owens River pluvial system and the Colorado River drainage basin has been frequently postulated. The two most commonly proposed routes involve (1) a southward overflow from the Death Valley Lake system or (2) southward migration of the Mojave River between its present course and a more southerly route. Under the present topographic regime, a Death Valley Lake capable of overflowing the bedrock saddle at Ludlow, California and discharging southward into the Bristol, Cadiz, and Danby Lake basins (and eventually the Colorado River) would be over 12,000 km² in size. Few surface and subsurface indicators exist to support either a fluvial or lacustrine connection. Evidence from deep cores and boreholes drilled in Soda, Bristol, Cadiz, and Danby dry lake basins indicate that a hydrologic connection has not occurred during the past 4 myr. No well-documented paleoshoreline features have been located at elevations corresponding to the above hydrologic systems in Death Valley, Silver-Soda, Bristol, or Danby Lake basins. In the Cadiz, Silurian, and Broadwell basins these features have not been found at all. Therefore, we conclude that a hydrologic connection between the Death Valley-Owens River system and the Colorado River has not occurred along either of these routes since the middle Pliocene.     

Hydrochemical model and probable pollution in the water of Euphrates River (Qaem–Falluja)

The study of hydrochemical models and probable pollution in Euphrates River from Qaem–Al-Falluja was performed through regime observation in ten water points. The hydrochemical properties of Euphrates River waters are determined by using the analysis results of 21 physico-chemical variables during the water year (2008). The interpretation of the hydrochemical phenomena is achieved in accordance with the statistical results of Polynomial Regression Statistic, calculating the coefficient of variation among the physico-chemical components of the water terminating by 14 models. The results of monitoring during the water year 2008 indicate a pollution case by SO₄ and Cd in Ramadi and downstream stations; TDS, Mg, Na, Cl, Mn, and CO₂ in Ramadi station; TDS, Ca, Na, Cl, and Fe in Baghdadi station; and Ca and H _T in Qaem station and Mg in Obaydi station. The research suggests the best locations for hydrochemical monitoring as continuous hydrologic stations used for the long-term monitoring. These stations are in Qaem city as inlet location and Al-Baghdadi and Ramadi cities terminating in Falluja city as outlet location. Furthermore, daily record system is recommended for the other stations in each city to complete the regime observation of Euphrates water type. From the configuration approach of hydrochemical models with the pollution phenomena, there are potential point sources of pollution such as municipal effluent pipes and reused water from mining process for building materials in the first sector of river, which extends between Qaem and Haditha dam. Also groundwater seepages and springs discharge of mineralized water mixed with sewage water from cities act as potential point sources of pollution on the river water in the second sector extended between Haditha and Ramadi scheme. The third sector of the river is affected by all reasons in the first and second sectors as well as the effectiveness of agricultural activities throughout drainage canals and irrigation projects extended between Ramadi and Falluja cities.     

Changes in major element hydrochemistry of the Pecos River in the American Southwest since 1935

The Pecos River, situated in eastern New Mexico and western Texas, receives water from a drainage area of 91 000 km². There are primarily two major water inputs, namely snowmelt from winter storms in the headwater region of the southern Rocky Mountains and runoff from warm-season monsoonal rainfall in the lower valley. The Pecos River suffers from high levels of total dissolved solids (TDS >5000 mg L⁻¹) under normal flow conditions. This not only poses serious problems for agricultural irrigation and safe drinking water supply, but also results in a permanent loss of biodiversity. This study examines changes in stream flow and water chemistry of the Pecos River over the last 70 a to better understand the long-term variability in stream salinity and the role of agricultural practices in salt transfer. A TDS record from the lower Pecos River near Langtry (Texas) back to 1935 was extracted to show a distinct pattern of decadal variability similar to the Pacific Decadal Oscillation (PDO), in which stream salinity is overall above average when the PDO is in positive (warm) phase and below average when the PDO is in negative (cold) phase. This is due to: (1) the dissolved salts contributed to the river are largely from dissolution of NaCl and CaSO₄-bearing minerals (e.g., halite and gypsum) in the upper basin, (2) the amount of the dissolved salts that reach the lower basin is mainly determined by the stream flow yield in the upper basin and (3) the stream flow yield from the upper basin is positively correlated with the PDO index. This further attests that large-scale climatic oscillation is the major source of long-term changes in stream flow and salinity of the Pecos River. On the other hand, there is also a strong indication that the rate of salt export has been affected by reservoir operations and water diversions for agricultural practices.     

Environmental isotopic study on the recharge and residence time of groundwater in the Heihe River Basin, northwestern China

The recharge and origin of groundwater and its residence time were studied using environmental isotopic measurements in samples from the Heihe River Basin, China. δ¹⁸O and δD values of both river water and groundwater were within the same ranges as those found in the alluvial fan zone, and lay slightly above the local meteoric water line (δD=6.87δ¹⁸O+3.54). This finding indicated that mountain rivers substantially and rapidly contribute to the water resources in the southern and northern sub-basins. δ¹⁸O and δD values of groundwater in the unconfined aquifers of these sub-basins were close to each other. There was evidence of enrichment of heavy isotopes in groundwater due to evaporation. The most pronounced increase in the δ¹⁸O value occurred in agricultural areas, reflecting the admixture of irrigation return flow. Tritium results in groundwater samples from the unconfined aquifers gave evidence for ongoing recharge, with mean residence times of: less than 36 years in the alluvial fan zone; about 12–16 years in agricultural areas; and about 26 years in the Ejina oasis. In contrast, groundwater in the confined aquifers had ¹⁴C ages between 0 and 10 ka BP.     

A hydrochemical framework and water quality assessment of river water in the upper reaches of the Huai River Basin, China

This study characterizes the major ion chemistry for river water in the upper reaches of Bengbu Sluice in the Huai River Basin in wet and dry seasons, and assessed the suitability of water quality for irrigation and human consumption. It is found that sodium and calcium are the dominant cations and bicarbonate is the dominant anion in most river water samples. River water in Zhoukou of the Ying River and Bozhou of the Guo River is characterized as a Na–Cl water type, whereas river water from the upper reaches and the lower reaches of the two cities is characterized as a Na-HCO₃ water type, which may be attributed by anthropogenic influences in these cities. The river water types vary from the upstream to the downstream of the Fuyang sluice, which indicates that the sluices play a critical role in determining the water type. The water chemistry of these rivers clearly shows that the second group of rivers is affected more severely by waste effluent than is the first group. Calculated values of sodium adsorption ratio, %Na, and residual sodium carbonate indicate that, in general, most of the river water is of acceptable irrigation quality. The river water in Zhoukou section of the Ying River and the Bozhou section of the Guo River cannot be used as drinking water; pollution control should be further improved and enhanced across the river.     

Irrigation related arsenic contamination of a thin,alluvial aquifer,Madison River Valley,Montana, U.S.A.

The arsenic concentration in 13 water samples from wells in the thin, alluvial aquifer of the Madison River Valley, Montana, U.S.A. ranged from 26 to 150 μg/l. The Madison River, which originates in Yellowstone National Park, has a mean arsenic concentration of 51 μg/l (σ=26 μg/l), based upon very limited sampling in the study area during the main irrigation period. Groundwater arsenic concentration increases down the valley can be best correlated with the intensity of ditch irrigation in this semiarid area. No other sources of dissolved arsenic as concentrated as that of the river water have been identified. Evaporative concentration of river-derived irrigation water is believed to have been the overwhelming factor in the contamination of this shallow aquifer.     

Impact of rehabilitation of Assiut barrage, Nile River, on groundwater rise in urban areas

To make optimum use of the most vital natural resource of Egypt, the River Nile water, a number of regulating structures (in the form of dams and barrages) for control and diversion of the river flow have been constructed in this river since the start of the 20th century. One of these barrages is the Assiut barrage which will require considerable repairs in the near future. The design of the rehabilitation of the barrage includes a headpond with water levels maintained at a level approximately 0.60 m higher than the highest water level in the headpond of the present barrage. This development will cause an increase of the seepage flow from the river towards the adjacent agricultural lands, Assiut Town and villages. The increased head pond level might cause a rise of the groundwater levels and impedance of drainage outflows. The drainage conditions may therefore be adversely affected in the so-called impacted areas which comprise floodplains on both sides of the Nile for about 70 km upstream of the future barrage. A rise in the groundwater table, particularly when high river levels impede drainage, may result in waterlogging and secondary salinization of the soil profile in agricultural areas and increase of groundwater into cellars beneath buildings in the urban areas. In addition, a rise in the groundwater table could have negative impact on existing sanitation facilities, in particular in the areas which are served with septic tanks. The impacts of increasing the headpond level were assessed using a three-dimensional groundwater model. The mechanisms of interactions between the Nile River and the underlying Quaternary aquifer system as they affect the recharge/discharge processes are comprehensively outlined. The model has been calibrated for steady state and transient conditions against historical data from observation wells. The mitigation measures for the groundwater rise in the urban areas have been tested using the calibrated mode.     

Groundwater Recharge and Mixing in Arid and Semiarid Regions: Heihe River Basin, Northwest China

A sound understanding of groundwater recharged from various sources occurring at different time scales is crucial for water management in arid and semi-arid river basins. Groundwater recharge sources and their geochemical evolution are investigated for the Heihe River Basin(HRB) in northwest China on the basis of a comprehensive compilation of geochemical and isotopic data. Geochemical massbalance modeling indicates that mountain-block recharge accounts for a small fraction(generally less than 5%) of the shallow and deep groundwater sustaining the oasis, whereas infiltration of rivers and irrigation water contribute most of the groundwater recharge. Dedolomitization is the primary process responsible for the changes in groundwater chemical and carbon isotope compositions from the piedmont to the groundwater discharge zone, where the dedolomitization is very likely enhanced by modern agricultural activities affecting the shallow groundwater quality. Analysis of radioactive isotopes suggests that these primary recharge sources occur at two different time scales. Radiocarbon-derived groundwater age profiles indicate a recharge rate of approximately 12 mm/year, which probably occurred during 2000–7000 years B.P., corresponding to the mid-Holocene humid period. The recharge of young groundwater on the tritium-dated time scale is much higher, about 360 mm/year in the oasis region. Infiltration from irrigation canals and irrigation return flow are the primary contributors to the increased young groundwater recharge. This study suggests that groundwater chemistry in the HRB has been influenced by the complex interaction between natural and human-induced geochemical processes and that anthropogenic effects have played a more significant role in terms of both groundwater quantity and quality.     

The effects of agricultural land use and cotton production on tributaries of the Darling River, Australia

Intensive agricultural development in the Murray-Darling Basin, Australia, has been achieved at a high cost to the natural environment. This paper assess the hydrological, water quality and ecological changes which have occurred as a result of agricultural land use and particularly, cotton production, in major tributaries of the upper Darling River, using the Namoi Valley, the cradle of the Australian cotton industry, as a case study. Three aspects of cotton production have had detrimental effects in these catchments — extensive vegetation clearing on floodplains and in the riparian zone, water abstraction from regulated and unregulated river flows and intensive chemical use for pest control. The paper outlines the new initiatives in progress to improve the condition of these rivers, including management of pesticide runoff from cotton farms, nutrient reductions in surface waters and restoration of natural patterns of river flow. Constraints on water use off-stream and restrained regional development appear to be inevitable if river health is to be improved.     

渤海海退典型区——吴桥县污水灌溉对土壤污染调查

近20年来进入沧州区域内的地表废污水逐渐增多,为解决农业灌溉问题,沿河大量使用污水灌溉,对地下水和土壤产生污染。对渤海海退和古黄河冲积沉积形成的吴桥县土壤污染情况进行典型监测,评价污水灌溉对类似区域土壤影响,提出防治地下水和土壤污染的措施和建议。     

Arizona Hydrogeology And Water Supply

Arizona hydrogeology and water supply zones are classified into the Basin and Range Lowlands, the Central Highlands, and Plateau Uplands Hydrogeologic Provinces. Average annual precipitation for the state ranges from about five to more than 25 inches; average annual total is about 80 million acre-feet. More than 95 percent of rain and snowfall is lost to evaporation and transpiration. Evaporation potential ranges from about 48 to 86 inches per year and exceeds precipitation at all locations. Most water use is in the agricultural areas and large cities that lie in the Basin and Range Lowlands Province. Groundwater circulation and storage in the Basin and Range Lowlands Province occur chiefly in the extensive alluvial basins. Total groundwater in storage in the basins is more than 1.2 billion acre-feet. Because water use exceeds the rate of replenishment in these basins, groundwater levels have declined, and streamflow from the province is small. The Central Highlands Province provides large amounts of surface-water runoff to the Gila River system where the water is stored in large reservoirs and is used chiefly for agricultural and municipal purposes in the lowlands. Except for large groundwater supplies in fractured rock aquifers at a few locations, groundwater resources in the highlands are small. The Plateau Uplands Province is characterized by extensive flat-lying sandstone and limestone aquifers and by meager surface-water runoff. About 250,000 acre-feet of groundwater are yielded annually from springs that discharge to the Colorado River in the Grand Canyon and to tributaries of the Gila River system along the Mogollon Rim. Largest groundwater yields to wells and to springs occur from abundantly fractured rocks along large faults. The Colorado River flows westward across the northern part of the state and forms the boundary between Arizona and California. Average annual flow in the Colorado River at Lees Ferry is about 12 million acre-feet. The river flow is regulated by reservoirs capable of storing more than 50 million acre-feet. All but about 2.7 million acre-feet per year of the river flow is used in Arizona and California or is lost to evaporation and transpiration.     

A preliminary assessment of hydrogeological features and selected anthropogenic impacts on an alluvial fan aquifer system in Greece

An investigation was carried out to delineate the hydrogeologic framework and to understand groundwater quality of the Kompsatos River fan aquifer system, northeastern Greece, as well as to assess environmental impact induced by human activities. As groundwater is the only major source of water in this area, it is important to know the effect of geological formations, and anthropogenic activities on groundwater chemistry and environment. A thorough hydrogeological study was performed during the period 2004–2007. The differential river gauging method was used for estimating the volume of water leaking from (or discharging into) the river. Groundwater samples were collected from 89 monitoring wells, during the summer period of 2007, and analyzed for major ions and trace elements. A potential reservoir of groundwater is formed within the Kompsatos River fan. The aquifer system/Kompsatos River interaction is the outstanding feature of this area. Ca–Mg–HCO₃–SO₄ is the dominant water type as a result of dissolving carbonate salts. B, Ba, Mn, Li, Sr, and Zn are the most abundant trace elements in groundwater. Both the major-ion chemistry and trace element enrichment of the groundwater are controlled by mineral dissolution and water–rock interaction. Nitrate contamination of groundwater is related to agricultural practices. An improperly constructed drainage system led locally to salinization of groundwater. Channelization has caused considerable disruption to the river ecosystem. The eventual construction of a dam on the river will adversely affect the environment and the aquifer system. The lack of managerial policy for water is putting environmental resources and water supply in jeopardy.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

Contaminants from cretaceous black shale: II. Effect of geology,weathering, climate,and land use on salinity and selenium cycling,Mancos Shale landscapes,southwestern United States

The Cretaceous Mancos Shale (MS) is a known nonpoint source for a significant portion of the salinity and selenium (Se) loads in the Colorado River in the southwestern United States and northwestern corner of Mexico. These two contaminants pose a serious threat to rivers in these arid regions where water supplies are especially critical. Tuttle et al. (companion paper) investigates the cycling of contaminants in a Colorado River tributary watershed (Uncompahgre River, southwestern Colorado) where the MS weathers under natural conditions. This paper builds on those results and uses regional soil data in the same watershed to investigate the impact of MS geology, weathering intensity, land use, and climate on salt and Se storage in and flux from soils on the natural landscape, irrigated agriculture fields, areas undergoing urban development, and wetlands. The size of salinity and Se reservoirs in the MS soils is quantified. Flux calculations show that during modern weathering, natural landscapes cycle salt and Se; however, little of it is released for transport to the Uncompahgre River (10% of the annual salinity and 6% of the annual Se river loads). When irrigated, salinity and Se loads from the MS soil increase (26% and 57% of the river load, respectively), causing the river to be out of compliance with Federal and State Se standards. During 100 years of irrigation, seven times more Se has been removed from agricultural soil than what was lost from natural landscapes during the entire period of pedogenesis. Under more arid conditions, even less salt and Se are expected to be transported from the natural landscape. However, if wetter climates prevail, transport could increase dramatically due to storage of soluble phases in the non-irrigated soil. These results are critical input for water-resource and land-use managers who must decide whether or not the salinity and Se in a watershed can be managed, what sustainable mitigation strategies are possible, and what landscapes should be targeted. The broader implications include providing a reliable approach for quantifying nonpoint-source contamination from MS and other rock units elsewhere that weather under similar conditions and, together with results from our companion paper, address the complex interplay of geology, weathering, climate, and land use on contaminant cycling in the arid Southwest.     

漳州盆地水热系统氚同位素研究

本文依据26个天然水样品的氚同位素测试数据,分析了漳州盆地地下热水及其它天然水的氚值特征及其形成条件;利用“活塞模型”方法计算了漳州盆地地下水和地下热水的年龄;为弄清全盆地地下水的补给、迳流和排泄的总体格局和揭示地下热水的成因提供了依据。