The silicon isotopic composition of surface waters in the Atlantic and Indian sectors of the Southern Ocean

We report here the silicon isotopic composition (δ³⁰Si) of dissolved silicon (DSi) from 42 surface water samples from the Drake Passage, the Weddell Gyre, other areas south of the Southern Boundary of the Antarctic Circumpolar Current (ACC), and the ACC near the Kerguelen Plateau, taken between the beginning of February and the end of March 2007. From the beginning to end of the cruise (ANTXXIII/9), DSi diminished in the Antarctic by 50 μmol L⁻¹ while concentrations of nitrate + nitrite and phosphate showed no net decline, indicating that the high seasonal Si/N removal ratios well known for the Southern Ocean may be more related to the strength of the silicate pump in the Southern Ocean than to the instantaneous Si/N uptake ratio of diatoms. The δ³⁰Si of DSi in samples containing more than 20 μM DSi were strongly negatively correlated to DSi concentrations, supporting the use of δ³⁰Si as a proxy for DSi removal. The “open system” fractionation observed, ε = −1.2 ± 0.11‰, agrees well with results from previous work in other areas, and the estimate of the initial δ³⁰Si of DSi of +1.4‰ is not far off observations of the δ³⁰Si of DSi in Winter Water (WW) in this area. Results were used to model DSi draw down in the past from the δ³⁰Si of sediment cores, although isotopic fractionation during silica dissolution appeared to influence the δ³⁰Si of some surface water samples, inviting further study of this phenomenon.     

The British Lower Palaeolithic of the early Middle Pleistocene

The archaeology of Britain during the early Middle Pleistocene (MIS 19–12) is represented by a number of key sites across eastern and southern England. These sites include Pakefield, Happisburgh 1, High Lodge, Warren Hill, Waverley Wood, Boxgrove, Kent's Cavern, and Westbury-sub-Mendip, alongside a ‘background scatter’ lithic record associated with the principal river systems (Bytham, pre-diversion Thames, and Solent) and raised beaches (Westbourne–Arundel). Hominin behaviour can be characterised in terms of: preferences for temperate or cool temperate climates and open/woodland mosaic habitats (indicated by mammalian fauna, mollusca, insects, and sediments); a biface-dominated material culture characterised by technological diversity, although with accompanying evidence for distinctive core and flake (Pakefield) and flake tool (High Lodge) assemblages; probable direct hunting-based subsistence strategies (with a focus upon large mammal fauna); and generally locally-focused spatial and landscape behaviours (principally indicated by raw material sources data), although with some evidence of dynamic, mobile and structured technological systems. The British data continues to support a ‘modified short chronology’ to the north of the Alps and the Pyrenees, with highly sporadic evidence for a hominin presence prior to 500–600 ka, although the ages of key assemblages are subject to ongoing debates regarding the chronology of the Bytham river terraces and the early Middle Pleistocene glaciations of East Anglia.     

Geological and ecological perspectives on the Middle Pleistocene

This paper evaluates the geological and paleoecological implications of a Wenner-Gren symposium Stratigraphy and Patterns of Cultural Change in the Middle Pleistocene. The deep-sea, glacial-eustatic, loess, alluvial, and palynological records suggest between six and eight cold-warm cycles since the Brunhes-Matuyama magnetic reversal of 700,000 BP. Till and outwash stratigraphies are inadequate to provide a valid nomenclature for the numerous glacials preceding the Würm. Since at least five of the glacials since 700,000 BP were sufficiently severe to produce permafrost in midlatitude Europe, the “glacial Pleistocene” begins with the Brunhes-Matuyama. Although earlier cold-warm cycles extend well back into the early Pleistocene, with extensive glaciation and repeated floral decimations in higher latitudes, the first record of permafrost in the Rhine Basin 700,000 BP argues that major climatic oscillations of the Brunhes epoch were of glacial-interglacial amplitude. It is therefore recommended that a Lower-Middle Pleistocene boundary be linked to the practicable and universally applicable chronometric horizon provided by the Brunhes-Matuyama reversal, while the Middle-Upper Pleistocene limit can continue to be drawn at the base of the last, Eemian Interglacial (130,000 BP). The tropical African record presently contributes little to general understanding of the Middle Pleistocene, while the climatic cycles of higher latitudes are of limited value in analyzing mid-Pleistocene records of the tropical continents. Problems of stratigraphic control and environmental contexts for archeological sites are discussed.     

Evolution of neodymium isotopic signature of seawater during the Late Cretaceous: Implications for intermediate and deep circulation

Neodymium isotopic compositions (ε_Nd) have been largely used for the last fifty years as a tracer of past ocean circulation, and more intensively during the last decade to investigate ocean circulation during the Cretaceous period. Despite a growing set of data, circulation patterns still remain unclear during this period. In particular, the identification of the deep-water masses and their spatial extension within the different oceanic basins are poorly constrained. In this study we present new deep-water ε_Nd data inferred from the Nd isotope composition of fish remains and Fe–Mn oxyhydroxide coatings on foraminifera tests, along with new ε_Nd data of residual (partly detrital) fraction recovered from DSDP Sites 152 (Nicaraguan Rise), 258 (Naturaliste Plateau), 323 (Bellinghausen Abyssal Plain), and ODP Sites 690 (Maud Rise) and 700 (East Georgia Basin, South Atlantic). The presence of abundant authigenic minerals in the sediments at Sites 152 and 690 detected by XRD analyses may explain both middle rare earth element enrichments in the spectra of the residual fraction and the evolution of residual fraction ε_Nd that mirror that of the bottom waters at the two sites. The results point towards a close correspondence between the bottom water ε_Nd values of Sites 258 and 700 from the late Turonian to the Santonian. Since the deep-water Nd isotope values at these two sites are also similar to those at other proto-Indian sites, we propose the existence of a common intermediate to deep-water mass as early as the mid-Cretaceous. The water mass would have extended from the central part of the South Atlantic to the eastern part of proto-Indian ocean sites, beyond the Kerguelen Plateau. Furthermore, data from south and north of the Rio Grande Rise–Walvis Ridge complex (Sites 700 and 530) are indistinguishable from the Turonian to Campanian, suggesting a common water mass since the Turonian at least. This view is supported by a reconstruction of the Rio Grande Rise–Walvis Ridge complex during the Turonian, highlighting the likely existence of a deep breach between the Rio Grande Rise and the proto-Walvis Ridge at that time. Thus deep-water circulation may have been possible between the different austral basins as early as the Turonian, despite the presence of potential oceanic barriers. Comparison of new seawater and residue ε_Nd data on Nicaraguan Rise suggests a westward circulation of intermediate waters through the Caribbean Seaway during the Maastrichtian and Palaeocene from the North Atlantic to the Pacific. This westward circulation reduced the Pacific water influence in the Atlantic, and was likely responsible for more uniform, less radiogenic ε_Nd values in the North Atlantic after 80 Ma. Additionally, our data document an increasing trend observed in several oceanic basins during the Maastrichtian and the Palaeocene, which is more pronounced in the North Pacific. Although the origin of this increase still remains unclear, it might be explained by an increase in the contribution of radiogenic material to upper ocean waters in the northern Pacific. By sinking to depth, these waters may have redistributed to some extent more radiogenic signatures to other ocean basins through deep-water exchanges.     

The lithium isotopic composition of waters of the Mono Basin, California

Mono Lake, a major closed-basin alkaline salt lake in eastern California, derives its water from a mixture of creeks and springs, with the former providing in excess of 75% of the total. The Li isotopic composition of lake water has not varied significantly over a 4 year meromictic period (δ⁷Li ∼ +19.5). Springs are isotopically distinct: groundwater springs and seeps carry water enriched in isotopically heavy Li whereas thermal springs supply isotopically light (δ⁷Li < lake), but 10 times more Li-rich, water. Isotopic fractionation during crystallization of carbonate tufa and evaporitic salt appears to be insignificant, and thus cannot be called on as a principal control of the isotopic balance of Li of the lake. Isotopic differences between the end-member source components permit a water budget to be calculated, suggesting (1) springs provide > 50% of the Li to the lake; (2) the Li budget is sensitively balanced on small thermal spring contributions, < 3% of the total spring inflow; and (3) the residence time of Li in the lake is 28 ka. Other Great Basin closed lakes have variable Li isotopic compositions (δ⁷Li from +16.7 to +23.7), all of which differ significantly from those of several major lakes and seawater (homogeneously ∼ +32).     

A monograph on the Pleistocene history of the Middle Thames Valley

Book reviewed in this article:
Gibbard, P. L. 1985: The Pleisrocene History of the Middle Thames Valley.
Joakim Donner, Department of Geology, University of Helsinki, Snellmaninkaru     

Quantitative parameters of Pleistocene pelagic sedimentation in the Atlantic Ocean

Lithological–facies maps of Eopleistocene and Neopleistocene sediments (with 10 and 20 m isopachs) are compiled for the pelagic part of the Atlantic Ocean based on materials recovered by 283 ocean drilling sites. Data for both maps were calculated using A.B. Ronov’s volumetric method. The calculated results include such quantitative sedimentation parameters of major sediment types as the areas covered by these sediments, their volumes, masses of the dry sedimentary material, and masses of sedimentary material deposited per specified time unit. These parameters are compared for both Eopleistocene and Neopleistocene time, and the data are utilized to separately interpret the results for terrigenous, carbonate, and siliceous sediments. The supply of terrigenous material is proved to have been enhanced in the Pleistocene as a result of both tectonic uplift of continents and climatic changes, including intensification of continental glaciation at high latitudes in both hemispheres. The growth in the productivity of carbonate plankton was overridden by growing generation of bottom and deep water masses and ensuing intensification of the dissolution of pelagic carbonates. The productivity of siliceous plankton practically did not change, perhaps, because of a favorable combination of the supply of dissolved silica and other nutrients from both West and East Antarctica.     

The Cu isotopic signature of granites from the Lachlan Fold Belt,SE Australia

This contribution reports our preliminary work to determine Cu isotope ratios for various granite rocks and examine the Cu isotope systematics within granite suites. A chemical procedure, modified from Maréchal [Maréchal, C.N., Télouk, P. and Albarède, F., 1999. Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry. Chemical Geology, 156(1–4): 251–273.], was used to separate Cu from rock matrix. Quantitative recovery (100.6 ± 1.6%), with a low total procedural blank (2.65 ± 0.66 ng) for Cu, has been achieved, allowing Cu isotopic measurements on samples with as little as 10 ppm Cu. The Cu isotope ratios (δ⁶⁵Cu relative to NIST SRM 976) of 32 rock samples, ranging from mafic to felsic compositions, from 3 batholiths (2 I-type, 1 S-type) from the Lachlan Fold Belt in southeastern Australia, vary from ? 0.46‰ to 1.51‰. Most of them cluster around zero, with mean values for the I-type and S-type granites of 0.03 ± 0.15‰ and ? 0.03 ± 0.42‰ (2 sigma) respectively. These data, together with Cu isotope ratios of two loess samples, provide preliminary evidence that the baseline Cu isotopic composition of the crystalline part of upper continental crust is close to zero. The tight clustering of Cu isotope ratios of rocks from the I-type suites suggests that high-temperature magmatic processes do not produce significant Cu isotope fractionation. However, two granites with abnormally heavy Cu isotope signatures (up to 1.51‰) appears to be the result of localized hydrothermal alteration. Measurable variation in Cu isotopic composition of the S-type granite may reflect isotopic heterogeneity in the sedimentary source region as a result of redox processes or may be due to hydrothermal overprinting. Thus, Cu isotope geochemistry may be a useful tracer for studying hydrothermal alteration and source heterogeneity of granitic rocks.     

滇西腾冲中更新世英安质岩浆的爆发机制

本文对腾冲马站钻孔的中酸性火山岩进行了岩相学、锆石SIMS U-Pb年代学及地球化学研究,确定其岩石类型、形成时代及岩浆喷发前的岩浆状态,从而揭示腾冲火山喷发机制。根据矿物组成将腾冲钻孔的中酸性火山岩分为两层:上层灰白色角闪熔岩(矿物组合:单斜辉石+斜方辉石+角闪石+黑云母+斜长石+钾长石+钛磁铁矿+磁铁矿+石英);下层黑色辉石熔岩(矿物组合:单斜辉石+斜方辉石+斜长石+钛磁铁矿+磁铁矿)。腾冲钻孔中酸性火山岩的锆石均呈半自形-自形,振荡环带明显,为岩浆成因。测年结果表明,灰白色角闪熔岩的结晶年龄为0.7Ma,黑色辉石熔岩中最年轻的锆石为0.6Ma;结合上覆中更新世粗面岩,我们推断其喷发时代为中更新世。地球化学显示角闪熔岩和辉石熔岩都为高钾钙碱性英安岩。相似的全岩和斑晶核部的地化特征,指示角闪英安岩和辉石英安岩来自同一个岩浆房。综合斑晶的地化特征及平衡结晶的温压条件,我们认为早期的岩浆房经历一次基性岩浆补给事件,导致火山爆发产生黑色辉石英安岩,后期岩浆房又经历一次酸性岩浆补给事件,导致火山爆发产生灰白色角闪英安岩。两次岩浆补给事件是导致火山爆发的直接原因。     

Contamination of deep formation waters by drilling fluids: correction of the chemical and isotopic composition and evaluation of errors

Contamination of deep formation waters by drilling fluids is a problem that concerns most types of drilling operations (petroleum wells, geothermal boreholes) and is crucial in the course of feasibility and safety studies of potential radioactive-waste repositories. Residual contamination of formation-water samples has an important impact on the accuracy of the characterisation of the natural hydrogeochemical background of the study sites. Based on a literature review and on experience acquired on the sites of the French Agency for Nuclear Waste Disposal (ANDRA), this article proposes a general method for the correction of residual contamination, including estimates of the associated errors. The quantification of the contamination is based on tracing techniques and on a geochemical survey during the pumping test preceding sampling. The correction and estimation of errors require repeated measurements of the tracer(s) and the chemical and isotopic species during pumping. The method is applied to a pumping test in a research well in deep granite of the Vienne district (France) where multi-tracing of drilling fluids has been used.     

The isotopic composition of strontium in some South African kimberlites

Strontium isotopic studies of kimberlites reveal no significant differences between the respective whole-rock Sr⁸⁷/Sr⁸⁶ ratios of fissure and pipe kimberlites. Kimberlites from the Swartruggens fissure (calcareous micaceous kimberlite) have Sr⁸⁷/Sr⁸⁶ ratios of from 0.709 to 0.716, whilst those from the Wesselton pipe have Sr⁸⁷/Sr⁸⁶ ratios of from 0.708 to 0.715. Other kimberlites range from 0.706 to 0.715. Samples are considered to be late Cretaceous to early Tertiary and thus the ratios are approximately initial ratios. The Sr⁸⁷/Sr⁸⁶ ratios bear no relation to the Rb or Sr content of individual kimberlite bodies. The high initial ratios are not due to bulk assimilation of granitic material in either a kimberlite or carbonatitic magma. Rb-Sr data for garnet peridotites and eclogite xenoliths in kimberlite are not compatible with production of kimberlite by eclogite fractionation from a melt derived from garnet lherzolite. The Sr isotopic composition of kimberlite is compatible with partial melting of garnet mica peridotite. The isotopic composition of liquids formed by partial melting of this rock can be modified by (i) gross contamination with material of low Sr⁸⁷/Sr⁸⁶ ratio or (ii) selective diffusion of material of high Sr⁸⁷/Sr⁸⁶ ratio into kimberlitic fluids.     

东昆仑东段中更新世以来的成山作用及其动力转换

对东昆仑造山带东段第四纪构造及与地貌关系的分析表明，现代山盆相间的地貌格局成型于中更新世，且在中更新世以来发生了多次构造变形体制的转换。根据布青山北部查干额热格地区第四系剖面的构造、地层时代及地层与构造关系的分析表明，中更新世时期为伸展构造体制，昆仑山内部开始发生了差异隆升，布青山开始崛起。中更新世末应力体制发生急剧变化，由伸展体制转为收缩事件，又急速转为伸展构造体系，短暂的收缩事件造成了中更新世冲洪积层的褶皱，随后的伸展则导致了影响深刻的向北依次断落的阶地状正断层系统。晚更新世应力体系再度发生重大转换，伸展正断层体系被左旋走滑运动体系所代替，并一直延续至今。中更新世以来多次隆升构造变形体制的转换说明东昆仑地区的成山过程受控于多种动力背景，而非单一的挤压抬升。隆升构造变形体系的确定及其时代约束为深入刻划青藏高原东北缘隆升作用的动力过程提供了重要信息。     

Effect of aridity and rainfall seasonality on vegetation in the southern tropics of East Africa during the Pleistocene/Holocene transition

Fossil pollen analyses from northern Lake Malawi, southeast Africa, provide a high-resolution record of vegetation change during the Pleistocene/Holocene transition (~ 18–9 ka). Recent studies of local vegetation from lowland sites have reported contrasting rainfall signals during the Younger Dryas (YD). The Lake Malawi record tracks regional vegetation changes and allows comparison with other tropical African records identifying vegetation opening and local forest maintenance during the YD. Our record shows a gradual decline of afromontane vegetation at 18 ka. Around 14.5 ka, tropical seasonal forest and Zambezian miombo woodland became established. At ~ 13 ka, drier, more open formations gradually became prevalent. Although tropical seasonal forest taxa were still present in the watershed during the YD, this drought-intolerant forest type was likely restricted to areas of favorable edaphic conditions along permanent waterways. The establishment of drought-tolerant vegetation followed the reinforcement of southeasterly tradewinds resulting in a more pronounced dry winter season after ~ 11.8 ka. The onset of the driest, most open vegetation type was coincident with a lake low stand at the beginning of the Holocene. This study demonstrates the importance of global climate forcing and local geomorphological conditions in controlling vegetation distribution.     

Biostratigraphy of the Late Middle Pleistocene (Middle Neopleistocene) of the Southern Urals region

A summary of published and unpublished materials on the stratigraphy of the Late Middle Pleistocene (Middle Neopleistocene according to the Russian stratigraphic scheme) of the Southern Urals region is given. Deposits of different origin in the regional stratigraphic units are characterized. The results of mammalian investigations provide the basis for the stratigraphical subdivision. Mollusca and palynology are used for the reconstruction of the palaeoenvironments. The stratigraphical positions of the main Middle Neopleistocene localities and precise definitions of the stratigraphical scheme of the Southern Urals region are discussed. The Southern Urals subdivisions are correlated with the Western European stratigraphical schemes (Holsteinian–Saalian interval).     

Middle Pleistocene climate and habitat change at Zhoukoudian, China, from the carbon and oxygen isotopic record from herbivore tooth enamel

The Pleistocene deposits at Zhoukoudian, often referred to as the “Peking Man” site, contain dental remains from a diverse group of herbivores, including Equus sanmeniensis, Cervus elaphus, Cervus nippon, Megaloceros pachyosteus, Sus lydekkeri, and Dicerorhinus choukoutienensis. The carbon and oxygen isotopic compositions of structural carbonate within the enamel of these teeth are used to reconstruct the paleodiet and paleoenvironment of the mammals. The δ¹³C values of enamel from Zhoukoudian range from −2.3‰ to −13.0‰, indicating that these mammals consumed between 25% and 100% C₃ plants. The presence of significant amounts of C₄ plants in the diets of some herbivore species indicates that at the onset of the Middle Pleistocene local habitats included mixed C₃/C₄ vegetation. By approximately 470,000 yr ago, C₃ plants dominated the diets of herbivores studied, suggesting that the abundance of C₄ flora had decreased in the area. For all deer analyzed in this study, the values of δ¹³C and δ¹⁸O decrease substantially from about 720,000 to 470,000 yr ago. This trend may be due to a strengthening of the winter monsoon during the Middle Pleistocene.     

The isotopic composition of waters from the El Tatio geothermal field,Northern Chile

On the basis of isotopic and chemical analyses of 45 spring, well and meteoric water samples from the El Tatio geothermal field in Northern Chile, four main processes giving rise to the formation of a wide range of thermal discharges can be distinguished. (1) Deep dilution of a predominant, primary high chloride (5500 mg/l, 260°) supply water derived from precipitation some 15 km east of El Tatio with local groundwater produces a secondary chloride water. (4750 mg/l, 190°) feeding springs over a limited area. (2) Single step steam separation from these two waters leads to isotopic shifts and increases in chloride contents to 8000 and 6000 mg/l respectively. (3) Absorption of this separated steam and carbon dioxide into local ground water and mixing with chloride waters at shallow levels produces a series of intermediate temperature (160°), low chloride, high bicarbonate waters. (4) Absorption of steam containing H₂S into surface waters leads to the formation of zero chloride, high sulfate waters; the isotopic enrichment observed is governed by a kinetic, steady state evaporation process.     

Re-evaluation of the Middle Pleistocene stratigraphy of Herefordshire,England

Lithostratigraphical analysis of remnants of high-level, poorly sorted gravel remnants in northeast Herefordshire has allowed the revision and expansion of the existing regional Middle Pleistocene stratigraphical sequence to incorporate two new formations. The oldest Pleistocene sediments in the region, the Humber Formation, represents part of a major, northerly derived, cold-stage fluvial system, which incorporated the ancestors of the rivers Lugg and Wye and tributaries of the Severn. The Risbury Formation consists of glacigenic sediments, which were deposited by a large ice-lobe emanating from a Welsh ice-cap. The Risbury Formation is correlated with glacigenic deposits in the Cradley Brook Valley on the west side of the Malvern Hills, which were formerly ascribed to a pre-Hoxnian, Severn Valley ice-sheet. © 1998 John Wiley & Sons, Ltd.