Jurassic plutonism and crustal evolution in the central Mojave Desert,California

Middle to Late Jurassic plutonic rocks in the central Mojave Desert represent the continuation of the Sierran arc south of the Garlock fault. Rock types range from calc-alkaline gabbro to quartz monzonite. Chemical and isotopic data indicate that petrologic diversity is attributable to mixing of crustal components with mantle melts. Evidence for magma mixing is scarce in most plutons, but emplacement and injection of plutons into preexisting wallrocks (e.g. pendants of metasedimentary rocks) suggests that assimilation may be locally important. Field and petrographic evidence and major and trace element data indicate that the gabbros do not represent pure liquids but are, at least partly, cumulates. The cumulate nature of the gabbros coupled with field evidence for open-system contamination means that trace element contents of gabbros cannot be used to fingerprint the Jurassic mantle source, nor can isotopic data be unequivocally interpreted to reflect the isotopic composition of the mantle. Correlation of Sr and Nd isotropic composition with bulk composition allows some constraints to be placed on the mantle isotopic signature. Gabbros and mafic inclusions from localities north of Barstow, CA have the most depleted mantle-like isotopic signatures (Sr _{( i )}≈0.705 and ɛNd _(t)=≈0 to +1). However, these rocks have likely seen some contamination as well, so the mantle source probably has an even more depleted character. Gabbros with the lowest Sr( _i ) and highest ɛNd _(t) are also characterized by the highest ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁶Pb/²⁰⁴Pb in the entire data set. This may be a feature of the mantle component in the Jurassic arc indicative of minor source contamination with subducted sediment as has been observed in modern continental arcs. Locally exposed Precambrian basement and metasedimentary rocks have appropriate Sr, Nd and Pb isotopic signatures for the crustal end members and are possible contaminants. Incorporation of these components through combined anatexis and assimilation can explain the observed spread in isotopic composition. Evidence for a depleted mantle component in these gabbros contrasts with the enriched subcontinental mantle component in Jurassic arc plutons further to the east and suggests there may have been a major mantle lithosphere boundary between the two areas as far back as the Late Jurassic. Crustal boundaries and isotopic provinces defined on the basis of initial isotopic composition (Sr( _i )=0.706 isopleth) are difficult to delineate because of the correlation of bulk composition with Sr and Nd isotopic composition and because values may differ depending on the age of the rocks sampled within a given area. Data from plutons intruded into rocks known or inferred to be Precambrian are, however, shifted dramatically (highest Sr_{( i )} and lowest ɛNd_(t)) toward Precambrian values. The least isotopically evolved rocks (lowest Sr( _i ) and highest ɛNd_(t)) occur within the eugeoclinal belt of the Mojave Desert. This zone has been previously identified as a Precambrian rift zone but more likely represents a zone where mantle magmas have been intruded into isotopically similar crustal rocks of the eugeocline with minor input from old Precambrian crust. Received: 12 August 1993/Accepted: 8 July 1994     

87Sr/86Sr and 18O/16O isotopic systematics and geochemistry of granitoid plutons across a steeply-dipping boundary between contrasting lithospheric blocks in western Idaho

A spatially abrupt geochemical boundary is preserved within four plutonic complexes along the western margin of the Cretaceous Idaho Batholith near McCall, Idaho. These intrusives ranging in composition from tonalite to granite were emplaced across a regional boundary between accreted oceanic-arc terranes and the continental margin, and their isotopic, major-element, and trace-element geochemistry provide detailed information about this change in crustal characteristics at depth, indicating that the boundary is nearly vertical and extends deep into the lithosphere. The Hazard Creek complex, emplaced west of the transition in wall-rock lithology, has initial ⁸⁷Sr/⁸⁶Sr (R_i) less than 0.7045 and ¹⁸O greater than 7.5, indicating little or no continental crust in its source region; however, elevated ¹⁸O requires some incorporation of rocks formed or altered at the earth's surface. A large shift in R_i and ¹⁸O is observed across the 5–8 km wide Little Goose Creek complex, which was emplaced across the wall-rock boundary. This is interpreted as mixing between: (1) a basaltic or andesitic magma with low K₂O and high Na₂O, Al₂O₃, and Sr, similar to that forming the Hazard Creek complex; and (2) materials similar to Precambrian sedimentary sedimentary rocks with low Sr, high ¹⁸O (+15) and high R_i (0.83 at 100 Ma). The Payette River complex, emplaced east of the wall-rock boundary, exhibits at least one additional component with low ¹⁸O (+6), moderate R_i (0.708) and mafic composition. This component is inferred to be old basaltic material in the lower crust or upper mantle similar to that inferred to be a minor part of the Peninsular Ranges Batholith in SE California (Silver et al. 1979; Hill et al. 1986). The easternmost complex in the Idaho transect is made up of granites that may contain a component of granitic cratonal basement. The entire west-to-east geochemical transition from oceanic-arc magmas to cratonal magmas takes place over a lateral distance of less than 20 km. Although the zone of transitional protolith dominated by metasedimentary rocks is unusually narrow and may have been in part tectonically removed, the striking geochemical similarities between this traverse and several other transects across much broader areas of Nevada and California suggest that the craton itself was not rifted apart, but that juxtaposition of the accreted oceanic-arc terranes occurred along the preexisting craton margin. The data confirm that the isotopic geochemistry of granitoid plutons can be used as a probe of deep lithospheric character, and that major lateral variations in the lithosphere on the order of one to two kilometers in width can be recognized in favorable circumstances.     

Strontium and oxygen isotopic evidence for strike/slip movement of accreted terranes in the Idaho Batholith

The oxygen and strontium isotope compositions of granitic rocks of the Idaho Batholith provide insight into the magma source, assimilation processes, and nature of the suture zone between the Precambrian craton and accreted arc terranes. Granitic rocks of the Idaho Batholith intrude basement rocks of different age: Triassic/Jurassic accreted terranes to the west of the Salmon River suture zone and the Precambrian craton to the east. The age difference in the host rocks is reflected in the abrupt increase in the initial ⁸⁷Sr/⁸⁶Sr ratios of granitic rocks in the batholith across the previously defined 0.706 line. Initial ⁸⁷Sr/⁸⁶Sr ratios of granitic rocks along Slate Creek on the western edge of the batholith jump from less than 0.704 to greater than 0.707 along an approximately 700 m transect normal to the Salmon River suture. Initial ⁸⁷Sr/⁸⁶Sr ratios along the Slate Creek transect do not identify a transition zone between accreted arcs and the craton and suggest a unique tectonic history during or after suturing that is not documented along other transects on the west side of the Idaho Batholith. The lack of transition zone along Slate Creek may be a primary structure due to transcurrent/transpressional movement rather than by contractional thrust faulting during suturing or be the result of post-imbrication modification.     

The Anfeg post-collisional Pan-African high-K calc-alkaline batholith (Central Hoggar, Algeria), result of the LATEA microcontinent metacratonization

The Anfeg batholith (or composite laccolith) occupies a large surface (2000 km²) at the northern tip of the Laouni terrane, just south of Tamanrasset in Hoggar. It is granodioritic to granitic in composition and comprises abundant enclaves that are either mafic microgranular enclaves (MME) or gneissic xenoliths. It intruded an Eburnian (≈2 Ga) high-grade basement belonging to the LATEA metacraton at approximately 608 Ma (recalculated from the U–Pb dating of [Tectonics 5 (1986) 955]) and cooled at approximately 4 kbar, with a temperature of about 750 °C. This emplacement occurred mainly along subhorizontal thrust planes related to Pan-African subvertical mega-shear zones close to the attachment zone of a strike-slip partitioned transpression system. Although affected by some LILE mobility, the Anfeg batholith can be ascribed to a high-K calc-alkaline suite but characterized by low heavy REE contents and high LREE/HREE ratios. The MME belong to the Anfeg magmatic trend while some xenoliths belong to Neoproterozoic island arc rocks.The Anfeg batholith defines a Nd–Sr isotopic initial ratios trend (_Nd/(⁸⁷Sr/⁸⁶Sr)_i from −2.8/0.7068 to −11.8/0.7111) pointing to a mixing between a depleted mantle and an old Rb-depleted granulitic lower crust. Both sources have been identified within LATEA and elsewhere in the Tuareg shield (_Nd/⁸⁷Sr/⁸⁶Sr)_i of +6.2/0.7028 for the depleted mantle, −22/0.708 for the old lower crust.The model proposed relates the above geochemical features to a lithospheric delamination along the subvertical mega-shear zones that dissected the rigid LATEA former passive margin without major crustal thickening (metacratonization) during the general northward tectonic escape of the Tuareg terranes, a consequence of the collision with the West African craton. This delamination allowed the uprise of the asthenosphere. In turn, this induced the melting of the asthenosphere by adiabatic pressure release and of the old felsic and mafic lower crust due to the high heat flow. A gradient in the mantle/crust ratio within the source of the Pan-African magmatism is observed in LATEA from the northeast (Egéré-Aleksod terrane) where rare plutons are rooted within the Archaean/Eburnian basement to the southwest (Laouni terrane) where abundant batholiths, including Anfeg, have a mixed signature. Some mantle melts with only slight crustal contamination (Laouni troctolitic layered intrusions) are even present. This suggests that the southern boundary of LATEA microcontinent is not far south of the Tuareg shield.     

Elemental and Sr–Nd–Pb isotopic geochemistry of Late Paleozoic volcanic rocks beneath the Junggar basin, NW China: Implications for the formation and evolution of the basin basement

The basement beneath the Junggar basin has been interpreted either as a micro-continent of Precambrian age or as a fragment of Paleozoic oceanic crust. Elemental and Sr–Nd–Pb isotopic compositions and zircon Pb–Pb ages of volcanic rocks from drill cores through the paleo-weathered crust show that the basement is composed mainly of late Paleozoic volcanic rock with minor shale and tuff. The volcanic rocks are mostly subalkaline with some minor low-K rocks in the western Kexia area. Some alkaline lavas occur in the central Luliang uplift and northeastern Wulungu depression. The lavas range in composition from basalts to rhyolites and fractional crystallization played an important role in magma evolution. Except for a few samples from Kexia, the basalts have low La/Nb (<1.4), typical for oceanic crust derived from asthenospheric melts. Zircon Pb–Pb ages indicate that the Kexia andesite, with a volcanic arc affinity, formed in the early Carboniferous (345 Ma), whereas the Luliang rhyolite and the Wucaiwan dacite, with syn-collisional to within-plate affinities, formed in the early Devonian (395 and 405 Ma, respectively). Positive ε_Nd(t) values (up to +7.4) and low initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of the intermediate-silicic rocks suggest that the entire Junggar terrain may be underlain by oceanic crust, an interpretation consistent with the juvenile isotopic signatures of many granitoid plutons in other parts of the Central Asia Orogenic Belt. Variation in zircon ages for the silicic rocks, different Ba, P, Ti, Nb or Th anomalies in the mafic rocks, and variable Nb/Y and La/Nb ratios across the basin, suggest that the basement is compositionally heterogeneous. The heterogeneity is believed to reflect amalgamation of different oceanic blocks representing either different evolution stages within a single terrane or possibly derivation from different terranes.     

Nd and Pb Isotopic Composition of Granitoids in the Khangai Batholith as an Indicator of Crust-Forming Processes in the Terranes of the Central Asian Orogenic Belt

The Khangai batholith is one of the largest groups of granitoid plutons produced in Central Asia in the Late Permian–Early Triassic, at 270–240 Ma. The batholith occurs in the Khangai collage of Precambrian terranes, which include Early Precambrian crustal blocks (Dzabkhan and Tarbagatai) and Early to Late Neoproterozoic structures of the Songino block in their surroundings. The axial zone of this collage is overprinted by a basin filled with Devonian volcanic–siliceous rocks and Early to Middle Carboniferous terrigenous rocks. The isotopic parameters (Nd and Pb) of granitoids in the Khangai batholith indicate that the melts were derived from compositionally contrasting crustal sources and a single mantle one. The massifs hosted in the Precambrian blocks were produced with the involvement of lower crustal material, with various ages of the origin of the crust and its differentiation into upper and lower ones. The crust of the Tarbagatai and Dzabkhan blocks was produced in the Early Archean and was differentiated at the Archean–Proterozoic boundary. The crust of the Songino block was formed in the Paleoproterozoic and differentiated in the Early Neoproterozoic. According to the Pb and Nd isotopic parameters of granitoids in the Khangai Basin, the regional continental crust was close to the juvenile one, i.e., the continental crust of the Khangai Basin had still not been differentiated by the time when the Khangai batholith was produced. A single mantle source was involved in the origin of the melts of granitoids of the Khangai batholith in various tectonic blocks. The evolution of the Pb isotopic composition of this sources is consistent with the Stacey–Kramers model at µ = 9.5. This source can be identified with the enriched mantle, which has a higher U/Pb ratio than the depleted mantle and lower ε_Nd(T) of 0 to +2.     

Deciphering the source and contamination history of peraluminous magmas using δ18O of accessory minerals: examples from garnet-bearing plutons of the Sierra Nevada batholith

Peraluminous granitoids provide critical insight as to the amount and kinds of supracrustal material recycled in the central Sierra Nevada batholith, California. Major element concentrations indicate Sierran peraluminous granitoids are high-SiO₂ (68.9–76.9) and slightly peraluminous (average molar Al₂O₃/(CaO + Na₂O + K₂O)=1.06). Both major and trace element trends mimic those of other high-silica Sierran plutons. Garnet (Grt) in the peraluminous plutons is almandine–spessartine-rich and of magmatic origin. Low grossular contents are consistent with shallow (<4 kbar) depths of garnet crystallization. Metasediments of the Kings Sequence commonly occur as wallrocks associated with the plutons, including biotite schists that are highly peraluminous (A/CNK=2.25) and have high whole rock (WR) δ¹⁸O values (9.6–21.8‰, average=14.5±2.9‰, n=26). Ultramafic wallrocks of the Kings–Kaweah ophiolite have lower average δ¹⁸O (7.1±1.3‰, n=9). The δ¹⁸O(WR) of the Kings Sequence is variable from west to east. Higher δ¹⁸O values occur in the west, where quartz in schists is derived from marine chert; values decrease eastward as the proportion of quartz from igneous and metamorphic sources increases. Peraluminous plutons have high δ¹⁸O(WR) values (9.5–13‰) consistent with supracrustal enrichment of their sources. However, relatively low initial ⁸⁷Sr/⁸⁶Sr values (0.705–0.708) indicate that the supracrustal component in the source of peraluminous magmas was dominantly altered ocean crust and/or greywacke. Also, plutons lack or have very low abundances (<1% of grains) of inherited zircon (Zrc) cores. Average δ¹⁸O(Zrc) is 7.9‰ in peraluminous plutons, a higher value than in coeval metaluminous plutons (6–7‰). Diorites associated with peraluminous plutons also have high δ¹⁸O(Zrc), 7.4–8.3‰, which is consistent with the diorites being derived from a similar source. Magmatic garnet has variable δ¹⁸O (6.6–10.5‰, avg.=7.9‰) due to complex contamination and crystallization histories, evidenced by multiple garnet populations in some rocks. Comparison of δ¹⁸O(Zrc) and δ¹⁸O(Grt) commonly reveals disequilibrium, which documents evolving magma composition. Minor (5–7%) contamination by high δ¹⁸O wallrocks occurred in the middle and upper crust in some cases, although low δ¹⁸O wallrock may have been a contaminant in one case. Overall, oxygen isotope analysis of minerals having slow oxygen diffusion and different times of crystallization (e.g., zircon and garnet), together with detailed textural analysis, can be used to monitor assimilation in peraluminous magmas. Moreover, oxygen isotope studies are a valuable way to identify magmatic versus xenocrystic minerals in igneous rocks. Electronic Supplementary Material Supplementary material is available for this article at     

THE PETROCHEMISTRY OF ANCIENT GRANITOIDS OF THE SOUTHERN SIBERIAN CRATON AND ITS MARGINAL FOLD BELTS

The geochemistry of Laramide granitic rocks from central Sonora was studied to relate possible compositional variations to the assimilation of different crustal sources. Most of the studied rocks are granodiorites collected near the southern boundary of the Paleozoic North American continent. North of this boundary, the Laramide plutons intruded a thick section of Upper Proterozoic and Paleozoic miogeoclinal strata, whereas south of it, the intrusives were emplaced in Lower Ordovician to Permian eugeoclinal rocks accreted to the continental margin between Late Permian and Middle Triassic times. Whole-rock Na₂O, TiO₂, and P₂O₅ contents are slightly higher in plutons intruded in cratonic and miogeoclinal rocks, whereas MgO and CaO seem to be higher in plutons emplaced in eugeoclinal rocks. The samples located in the north are characterized by steeper chondrite-normal-ized REE slopes and generally well developed negative europium anomalies, whereas the group of granitoids in the south have flatter REE slopes and generally smaller negative europium anomalies. Available isotope data show ⁸⁷Sr/⁸⁶Sr initial ratios above 0.7070, and ε_Nd initial values between ?4.6 and ?4.2 in plutons to the north. In a narrow E-W region just south of the Paleozoic continental margin, the samples yielded similar ⁸⁷Sr/⁸⁶Sr ratios but unexpectedly low ε_Nd values between ?5.4 and ?5.1. South of this region, the isotope signatures are slightly more primitive, with ⁸⁷Sr/⁸⁶Sr initial ratios between 0.7067 and 0.7057 and initial ε_Nd values between ?3.9 and ?3.7. The results of this study suggest that the nature of the assimilated crust may have influenced the final composition of the Laramide granitic rocks of central Sonora.     

Rb-Sr and K-Ar geochronologic and isotopic studies,Llano Uplift,central Texas

Two major episodes are evident in the metamorphic and igneous Precambrian basement of the Llano Uplift, central Texas. Dynamothermal metamorphism was accompanied by minor basaltic and tonalitic syntectonic plutonism. This was followed by a second period of thermal overprinting accompanying emplacement of high-K₂O, high-level major granite plutons. Extensive isotopic age work by Zartman, published in the mid-1960s, suggests that development of the basement complex, spanning an interval of 150 m.y. or more, began with deposition of Valley Spring Gneiss (the lowest unit) and terminated about 1,050 m.y. ago with final postmetamorphic cooling (indicated by retention ages of Ar and Sr in biotite). We have supplemented these data with more than 50 new K-Ar and Rb-Sr analyses.Two foliated plutons in the southeast are 1,167±12m.y. (2) old, with distinctly different initial ⁸⁷Sr/⁸⁶Sr ratios. Field relationships and isotopic data indicate that these plutons are the earliest yet known in the Uplift. Metamorphosed basalt dikes and gabbro bodies were emplaced immediately preceding and following the syntectonic plutons. Eleven of these rocks had extremely uniform initial ⁸⁷Sr/ ⁸⁶Sr=0.7029±0.0005. A Rb-Sr whole-rock isochron of the unfoliated Enchanted Rock pluton indicates an age of 1,048±34 m.y. with initial ⁸⁷Sr/⁸⁶Sr= 0.7048±0.0007. One of the northern unfoliated granites, the Lone Grove pluton, gives a whole-rock isochron age of 1,056±12 m.y., with initial ⁸⁷Sr/⁸⁶Sr = 0.7061±0.0003. All of the intrusive rocks have initial ⁸⁷Sr/⁸⁶Sr ratios consistent with a source in the mantle or lower crust, but not in ancient remobilized continental crust. Six K-Ar hornblende ages from metabasalts are 1,078±19 m.y. (1), in general agreement with K-Ar and Rb-Sr mineral ages elsewhere in the eastern Llano Uplift. A metasedimentary Valley Spring Gneiss sample from the western Uplift has a whole rock-muscovite Rb-Sr age of 1,129±9 m.y. Field and isotopic data are now sufficiently numerous to permit a moderately detailed reconstruction of the Precambrian history of the area.     

Multiple crustal sources for post-tectonic I-type granites in the Hercynian Iberian Belt

A post-tectonic plutonic array of felsic I-type granites crops out in the western Hercynian Iberian Belt. Isotope (Sr, Nd, Pb) data favour the absence of an important input of juvenile magmas in late- to post- tectonic Hercynian felsic magmatism in western Iberia, but suggest a reworking of different crustal protoliths, including oceanic metabasic rocks accreted to mid-to-lower crustal levels during the early stages of the collision. I-type granites were derived from different meta-igneous protoliths ranging from metabasic to felsic compositions depending on their geographical position from the external (e.g. Galicia—N Portugal, GNP) to the innermost continental areas (Spanish Central System and Los Pedroches Batholiths). The GNP I-type plutons related to eo-Hercynian accretional terranes have lower initial ⁸⁷Sr/⁸⁶Sr ratios, lower negative εNd values, and higher ²⁰⁶Pb/²⁰⁴Pb ratios than other I-type granites of the Central Iberian zone. These more isotopically primitive Hercynian I-type granites are important in tracking pre-Hercynian accreted oceanic lithosphere terranes.     

Early Permian plutons from the northern North China Block: constraints on continental arc evolution and convergent margin magmatism related to the Central Asian Orogenic Belt

Recent zircon dating identified several late Carboniferous to early Permian hornblende gabbro–diorite–quartz diorite–granodiorite–tonalite–granite plutons in lithological assemblages at the northern margin of the North China Block (NCB) that were previously regarded as Archaean to Palaeoproterozoic. Our geochronological results indicate that emplacement of these plutons was a continuous process during the late Carboniferous to early Permian, from 324 ± 6 to 274 ± 6 Ma, and lasted for at least 50 Ma. In this paper, the early Permian components with compositions from gabbro to granite within the intrusive complex were studied. The early Permian plutons exhibit calc-alkaline or high-K calc-alkaline, metaluminous geochemical features and highly variable SiO₂ contents. They have no significant Eu anomaly in their REE patterns, and in primitive-mantle-normalized spidergrams they display depletion in Th, U, Nb, Ta, P and Ti, and enrichment in Ba, K, Pb and Sr. The granitoid bodies within these plutons display I-type and adakitic geochemical signatures. The early Permian rocks exhibit low whole-rock initial ⁸⁷Sr/⁸⁶Sr ratios from 0.70520 to 0.70615 and have negative whole-rock ε _Nd(t) values ranging from −17.4 to −9.3 and zircon ε _Hf(t) values of −23.2 to −10.5. The gabbros exhibit higher ε _Nd(t) values from −11.1 to −9.3 and ε _Hf(t) values from −16.5 to −10.5, and one granodiorite exhibits an even lower ε _Nd(t) value of −17.4 and zircon ε _Hf(t) values of −23.2 to −15.1. Geochemical, Sr–Nd and in situ zircon Hf isotopic compositions suggest that the hornblende gabbros were derived from a metasomatized lithospheric mantle, and the diorite and quartz diorite were generated from a gabbroic magma by fractional crystallization, coupled with differential assimilation of ancient lower crustal material. The granodiorite was likely derived from partial melting of ancient lower crust with involvement of some mantle components. Involvement of both lithospheric mantle and ancient lower crust in the generation of the early Permian plutons indicates strong crust–mantle interaction in the northern NCB. Petrological associations as well as geochemical and Sr–Nd–Hf isotopic results show that the early Permian plutons were emplaced along an Andean-type active continental margin during southward subduction of the Palaeo-Asian oceanic plate beneath the NCB. Integration of our results with previously published data for late Carboniferous and late Permian to middle Triassic intrusions suggests that the continental arc on the northern margin of the NCB existed for at least 50 Ma during the late Palaeozoic, and final amalgamation of the Mongolian arc terranes with the northern NCB likely occurred during a period from ~270 to ~250 Ma, i.e, in the late Permian to earliest Triassic.     

The Sierra Crest Magmatic Event: Rapid Formation of Juvenile Crust during the Late Cretaceous in California

The Late Cretaceous was a period of extremely voluminous magmatism and rapid crustal growth in the western United States. From approximately 98 to 86 Ma, greater than 4000 km² of exposed granodioritic to granitic crust, including the largest composite intrusive suites in the Sierra Nevada batholith, were emplaced in eastern California. Plutons intruded during this period include the highest peaks in the Sierra; we informally refer to this as the Sierra Crest magmatic event. Field, petrologic, geochemical, and geochronologic data indicate that, although they comprise an insignificant volume of exposed rocks (less than 100 km²), mafic magmas were intruded contemporaneously with each episode of intermediate and high-silica magmatism in the event. This observation attests to the fundamental importance of high-alumina basaltic magmas during crustal-growth episodes in continental arcs. Geochemical data for suites of coeval plutonic rocks of the Sierra Crest magmatic event, ranging in composition from basalt to high-silica rhyolite, demonstrate that recycling of pre-existing crust locally played a minor role in the growth of new crust. Thus, major chemical and isotopic characteristics of Sierra Crest plutons, such as variable isotopic compositions, were inherited from the mantle source of the high-alumina basalts and are not necessarily the result of interaction with the overlying crust. Consequently, we interpret isotopic boundaries in the western United States, such as the ⁸⁷Sr/⁸⁶Sr = 0.706 isopleth, to be largely features of the continental lithospheric mantle. Furthermore, isotopic data demonstrate that enrichment of the lithospheric mantle in the western United States probably occurred in the Precambrian during assembly of the North American craton. Geophysical and xenolith investigations by other workers support the hypothesis presented here that Cretaceous magmatism in the Sierra Nevada may have locally restructured most, if not all, of the crustal column. The timing of Sierra Crest magmatism correlates with voluminous magmatism elsewhere in the Cordilleran arc. We speculate that this intense episode of magmatism may have played a role in the global marine geochemical excursions and extinctions at the Cenomanian-Turonian boundary.     

The age and origin of a thick mafic–ultramafic keel from beneath the Sierra Nevada batholith

We present evidence for a thick (∼100 km) sequence of cogenetic rocks which make up the root of the Sierra Nevada batholith of California. The Sierran magmatism produced tonalitic and granodioritic magmas which reside in the Sierra Nevada upper- to mid-crust, as well as deep eclogite facies crust/upper mantle mafic–ultramafic cumulates. Samples of the mafic–ultramafic sequence are preserved as xenoliths in Miocene volcanic rocks which erupted through the central part of the batholith. We have performed Rb-Sr and Sm-Nd mineral geochronologic analyses on seven fresh, cumulate textured, olivine-free mafic–ultramafic xenoliths with large grainsize, one garnet peridotite, and one high pressure metasedimentary rock. The garnet peridotite, which equilibrated at ∼130 km beneath the batholith, yields a Miocene (10 Ma) Nd age, indicating that in this sample, the Nd isotopes were maintained in equilibrium up to the time of entrainment. All other samples equilibrated between ∼35 and 100 km beneath the batholith and yield Sm-Nd mineral ages between 80 and 120 Ma, broadly coincident with the previously established period of most voluminous batholithic magmatism in the Sierra Nevada. The Rb-Sr ages are generally consistent with the Sm-Nd ages, but are more scattered. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd intercepts of the igneous-textured xenoliths are similar to the ratios published for rocks outcroping in the central Sierra Nevada. We interpret the mafic/ultramafic xenoliths to be magmatically related to the upper- and mid-crustal granitoids as cumulates and/or restites. This more complete view of the vertical dimension in a batholith indicates that there is a large mass of mafic–ultramafic rocks at depth which complement the granitic batholiths, as predicted by mass balance calculations and experimental studies. The Sierran magmatism was a large scale process responsible for segregating a column of ∼30 km thick granitoids from at least ∼70 km of mainly olivine free mafic–ultramafic residues/cumulates. These rocks have resided under the batholith as granulite and eclogite facies rocks for at least 70 million years. The presence of this thick mafic–ultramafic keel also calls into question the existence of a “flat” (i.e., shallowly subducted) slab at Central California latitudes during Late Cretaceous–Early Cenozoic, in contrast to the southernmost Sierra Nevada and Mojave regions. Received: 27 December 1997 / Accepted: 11 June 1998     

Petrogenesis of the Neogene volcanic units in the NE–SW-trending basins in western Anatolia,Turkey

The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline (HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly enriched in large ion lithophile elements (LILE), have high ⁸⁷Sr/⁸⁶Sr_(i) (0.70631–0.71001), low ¹⁴³Nd/¹⁴⁴Nd_(i) (0.512145–0.512488) and high Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb = 18.838–19.148; ²⁰⁷Pb/²⁰⁴Pb = 15.672–15.725; ²⁰⁸Pb/²⁰⁴Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization processes in the upper crust, such that have undergone a two-stage petrogenetic evolution.     

Age, composition, sources, and geodynamic environments of the origin of granitoids in the northern part of the Ozernaya zone, western Mongolia: Growth mechanisms of the Paleozoic continental crust

The paper presents data on the structure, composition, and age of granitoid associations (Tokhtogeshil’skii Complex) composing the Kharanur and Sharatologoi polychronous plutons in the northern part of the Ozernala zone in western Mongolia. The Tokhtogeshil’skii Complex was determined to consist of a number of independent magmatic associations, which were formed at 540–450 Ma, within three age intervals (540–520, 510–485, and 475–450 Ma), have different composition, were derived from different sources, and were emplaced in different geodynamic environments. During the first, island-arc stage (540–520 Ma), high-Al plagiogranites were produced, which belong to tonalite-plagiogranite (531 ± 10 Ma) and diorite (529 ±6 Ma) associations in the Kharanur pluton, low-Al plagiogranites of the tonalite-plagiogranite association (519 ± 8 Ma) in the Sharatologoi pluton, and rocks of the Khirgisnur peridotite-pyroxenite-gabbronorite complex (Kharachulu and Dzabkhan massifs). The rocks of the diorite and plagiogranite associations of the Kharanur pluton have ɛ_Nd(T) from +7.9 to +7.4, T_Nd(DM) = 0.65 Ga, and (⁸⁷Sr/⁸⁶Sr)₀ = 0.7038–0.7039. The plagiogranites of the Sharatologoi pluton (tonalite-plagiogranite association) are characterized by ɛ_Nd(T) from +6.5 to +6.6, T_Nd(DM) = 0.73–0.70 Ga, and (⁸⁷Sr/⁸⁶Sr)₀ = 0.7038–0.7039, which suggest predominantly juvenile subduction sources of the parental melts at a subordinate role of ancient crustal material. During the second, accretionary stage (510–485 Ma), low-Al plagiogranites of the diorite-tonalite-plagiogranite association of the Sharatologoi pluton (494 ± 10 Ma, M type) were formed. The Sr-Nd isotopic characteristics of these rocks ɛ_Nd(T) = +6.6, (⁸⁷Sr/⁸⁶Sr)₀ = 0.7039 are analogous to those of the plagiogranitoids of the early type. This suggests that the melted sources were similar in composition. During the third, postcollisional stage (475–450 Ma), rocks of the diorite-granodiorite-granite association were formed (459 ± 10 Ma, type I) in the Kharanur pluton. These rocks have ɛ_Nd(T) = +5.1, T_Nd(DM) = 0.74 Ga, and (⁸⁷Sr/⁸⁶Sr)₀ = 0.7096. The parental melts were supposedly derived by means of partial melting of “the Caledonian” juvenile crust with the addition of more ancient crustal material.     

Effects of basement composition and age on silicic magmas across an accreted terrane-Precambrian crust boundary,Sierra Madre Occidental,Mexico

Trace element and isotopic compositions of mid-Tertiary siliceous magma sequences from two localities of the Sierra Madre Occidental, northern Mexico, display differences that reflect the composition and age of the basement through which they erupted. The crust beneath the section at San Buenaventura is thicker and more evolved and forms part of the North American basement, while that under El Divisadero consists of allochthonous terranes of island arc/oceanic? crust accreted during the Mesozoic.The volcanics are highly differentiated and range in composition from basalt to rhyolite (SiO₂=50–76%). Those erupted through the accreted terranes display a small range of isotope ratios and have lowest initial (age-corrected) Sr isotope ratios (>0.7044) and the highest Nd (<0.5126) and Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb ∼18.9). Isotope ratios of the continental suite are more variable and form an array which trends away from that of the accreted terrane suite toward compositions more typical of old crust (to ⁸⁷Sr/⁸⁶Sr ∼0.710 and ¹⁴³Nd/¹⁴⁴Nd ∼0.5123). The volcanics in the continental zone are relatively more enriched in moderately incompatible elements compared with those within the accreted terranes (Ce/Yb=25–45 vs. 13–33, respectively), but are depleted in some highly incompatible elements such as U and Rb (e.g., Th/U=3.8–7.5 vs. 2.5–4.0, respectively). Those higher in the stratigraphic sections have higher ⁸⁷Sr/⁸⁶Sr, ²⁰⁸Pb/²⁰⁴Pb, and Th/U ratios, and lower ¹⁴³Nd/¹⁴⁴Nd ratios than those lower in the sections.The data have implications for the nature of the sources and the petrogenesis of these volcanics. The isotope ratios of both suites fall between those of mafic magma compositions from the Sierra Madre Occidental, and intermediate and felsic lower crustal xenoliths in northern Mexico and the southwestern USA. The relationship between the isotope ratios of the sequences and the age of the basement, combined with the fact that the overall data set forms well-defined isotopic arrays, demonstrates the strong effects of the crust on the chemistry of the silicic magmas. In the continental suite, isotope ratios covary with Th/Pb and U/Pb ratios, approaching the compositions found in the intermediate and felsic granulite facies xenoliths, strongly indicating that they are not anatectic melts of the lower crust but rather reflect interaction between mantle-derived basaltic parental magmas and the crust. Crustal contributions appear to be large, on the order of 20–70%. The small range of isotope ratios in the accreted terrane suite appears to reflect interaction of the basaltic parent with relatively juvenile crust whose isotopic composition is similar to the mantle-derived magmas. High Th/U and Th/Rb ratios indicate that the crustal contamination occurs in the lower crust. Moreover, the less radiogenic ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb ratios in the continental suite indicate that the depletion in highly incompatible elements in the continental lower crust is an old feature. The secular changes in the isotope ratios within the stratigraphic sections indicate increasingly shallow crustal contributions with time, initially by predominantly mafic deep lower crust and later by more felsic middle crust. Using lavas from outside of the two heavily sampled stratigraphic sections, the differences in the isotopic compositions between volcanics erupted through the accreted terranes and the continental basement help to delineate the location of the boundary.     

New Zealand's Geological Foundations

New Zealand is a fragment of Gondwana that, before Late Cretaceous sea floor spreading, was contiguous with Australia and Antarctica. Only about 10% of the area of continental crust in the wider New Zealand region (Zealandia) is emergent above sea level as the North and South Islands. No Precambrian cratonic core is exposed in onland New Zealand. The Cambrian to Early Cretaceous basement can be described in terms of nine major volcano-sedimentary terranes, three composite regional batholiths, and three regional metamorphic-tectonic belts that overprint the terranes and batholiths.The terranes (from west to east) are: Buller, Takaka, Brook Street, Murihiku, Maitai, Caples, Bay of Islands (part of former Waipapa), Rakaia (older Torlesse) and Pahau (younger Torlesse). The western terranes are intruded by three composite batholith (>100 km²) sized belts of plutons: Karamea-Paparoa, Hohonu and Median, as well as by numerous smaller plutons. Median Batholith (including the Median Tectonic Zone) is a recently-recognised Cordilleran batholith that represents the site of subduction-related magmatism from ca. 375–110 Ma. Parts of the terranes and batholiths are variably metamorphosed and deformed: Devonian and Cretaceous amphibolite-granulite facies gneisses are present in Buller, Takaka, Median and Karamea-Paparoa units; Jurassic-Cretaceous subgreenschist-amphibolite facies Haast Schist overprints the Caples, Bay of Islands and Rakaia Terranes; Cretaceous subgreenschist facies Esk Head and Whakatane Mélanges bound the Pahau Terrane. In the South Island, small areas (<5 km² total) of Devonian, Permian, Triassic and Jurassic Gondwana sequences have been identified. In the North Island a widespread Late Jurassic overlap sequence, Waipa Supergroup (part of former Waipapa Terrane), has recently been proposed.     

Late Triassic U-bearing and barren granites in the Miao'ershan batholith,South China: Petrogenetic discrimination and exploration significance

The Miao'ershan uranium ore district is one of the most important granite-hosted uranium producers in South China. There are several Triassic granite plutons in the Miao'ershan batholith, but uranium ore deposits mainly occur within the Douzhashan granitic body. Precise zircon U–Pb dating indicated that these Triassic granite plutons were emplaced during 204 to 215 Ma. The Douzhashan U-bearing granite lies in the central part of the Miao'ershan batholith, and has higher U contents (8.0 to 26.1 ppm, average 17.0 ppm) than the nearby Xiangcaoping granite (5.0 to 9.3 ppm, average 7.0 ppm) and the Yangqiaoling granite (6.4 to 18.3 ppm, average 11.5 ppm) in the south part of the batholith. The Douzhashan granite is composed of medium-grained two-mica granite, whereas the Xiangcaoping and Yangqiaoling granites are composed of porphyritic biotite granite. Both the Xiangcaoping and Douzhashan granites have high A/CNK ratios (> 1.10), high (⁸⁷Sr/⁸⁶Sr)_i ratios (> 0.720) and low ε_Nd(t) values (− 11.3 to − 10.4), suggesting that they belong to strongly peraluminous S-type granites. The Douzhashan granite has low CaO/Na₂O ratios, high Rb/Sr and Rb/Ba ratios, indicating a partial melting origin of clay-rich pelitic rocks. In contrast, the Xiangcaoping granite formed from clay-poor psammite-derived melt. The Yangqiaoling granite shows different geochemical characteristics with the Douzhashan and Xiangcaoping granites, indicating a different magma source. The Yangqiaoling granite has higher ε_Nd(t) of − 9.4 to − 8.3 and variable A/CNK values from 0.98 to 1.19, suggesting a mixture source of meta-sedimentary rocks and meta-igneous rocks. Crystallization fractionation is not the main mechanism for U enrichment in the Douzhashan granite. We suggest that U-rich pelitic rock sources may be the key factor to generate peraluminous U-bearing granites in South China. Searching for those granites which are reduced, strongly peraluminous and were derived from U-rich pelitic rocks, is the most effective way for exploring granite-hosted U deposits.     

Adakite-like volcanism of Ecuador: lower crust magmatic evolution and recycling

In the Northern Andes of Ecuador, a broad Quaternary volcanic arc with significant across-arc geochemical changes sits upon continental crust consisting of accreted oceanic and continental terranes. Quaternary volcanic centers occur, from west to east, along the Western Cordillera (frontal arc), in the Inter-Andean Depression and along the Eastern Cordillera (main arc), and in the Sub-Andean Zone (back-arc). The adakite-like signatures of the frontal and main arc volcanoes have been interpreted either as the result of slab melting plus subsequent slab melt–mantle interactions or of lower crustal melting, fractional crystallization, and assimilation processes. In this paper, we present petrographic, geochemical, and isotopic (Sr, Nd, Pb) data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic centers (Pululagua, Pichincha, Ilalo, Chacana, Sumaco) forming a NW–SE transect at about 0° latitude and encompassing the frontal (Pululagua, Pichincha), main (Ilalo, Chacana), and back-arc (Sumaco) chains. All rocks display typical subduction-related geochemical signatures, such as Nb and Ta negative anomalies and LILE enrichment. They show a relative depletion of fluid-mobile elements and a general increase in incompatible elements from the front to the back-arc suggesting derivation from progressively lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab. We observe widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene- and/or amphibole-bearing cumulates and of magma mixing at all frontal and main arc volcanic centers. Within each volcanic center, rocks display correlations between evolution indices and radiogenic isotopes, although absolute variations of radiogenic isotopes are small and their values are overall rather primitive (e.g., ε_Nd = +1.5 to +6, ⁸⁷Sr/⁸⁶Sr = 0.7040–0.70435). Rare earth element patterns are characterized by variably fractionated light to heavy REE (La/Yb_N = 5.7–34) and by the absence of Eu negative anomalies suggesting evolution of these rocks with limited plagioclase fractionation. We interpret the petrographic, geochemical, and isotopic data as indicating open-system evolution at all volcanic centers characterized by fractional crystallization and magma mixing processes at different lower- to mid-crustal levels as well as by assimilation of mafic lower crust and/or its partial melts. Thus, we propose that the adakite-like signatures of Ecuadorian rocks (e.g., high Sr/Y and La/Yb values) are primarily the result of lower- to mid-crustal processing of mantle-derived melts, rather than of slab melts and slab melt–mantle interactions. The isotopic signatures of the least evolved adakite-like rocks of the active and recent volcanoes are the same as those of Tertiary ”normal” calc-alkaline magmatic rocks of Ecuador suggesting that the source of the magma did not change through time. What changed was the depth of magmatic evolution, probably as a consequence of increased compression induced by the stronger coupling between the subducting and overriding plates associated with subduction of the aseismic Carnegie Ridge.     

Magmatic zircon oxygen isotopes of 1.88–1.87 Ga orogenic and 1.65–1.54 Ga anorogenic magmatism in Finland

Summary Oxygen isotope ratios of igneous zircon from magmatic rocks in Finland provide insights into the evolution and growth of the Precambrian crust during the Svecofennian orogeny. These data preserve magmatic δ¹⁸O values and correlate with major discontinuities in the lower crust. Oxygen isotope ratios of zircon across the 1.88–1.87 Ga Central Finland granitoid complex (CFGC) range from 5.50‰ to 6.84‰, except for three plutons in contact with the adjacent greenstone and metasedimentary belts (δ¹⁸O(Zrc) = 7.60‰–7.78‰). There is a systematic variation in δ¹⁸O(Zrc) with respect to geographic location in the CFGC, ranging from 6.60±0.23‰ (σ) in the northeast to 5.90±0.40‰ in the west-southwest. These values correlate with a change in crustal thickness and shift in geochemical composition. The oxygen isotope composition of the 1.65–1.54 Ga rapakivi granites and related rocks in southern Finland show a decreasing trend from north to south, independent of their emplacement age. The southern anorogenic granite group has an average δ¹⁸O in zircon of 6.14±0.07‰ and the northern anorogenic group has an average δ¹⁸O in zircon of 8.14±0.59‰. This difference reflects the boundary between island arc terrains accreted during the Paleoproterozoic. Deceased