塔里木西克尔基性麻粒岩捕虏体的发现及其地质意义

在塔里木西部新生代碧玄岩中新发现了基性麻粒岩捕虏体。其原生矿物组合为Cpx+Opx+Pl (An=30~50)+Sp+Ilm+Tim,次生矿物组合为Ol+Pl (An>50)+alkaline feldspar+glass。原生矿物组合的温度和压力分别为1005~1059℃ 和 0.6~1.1GPa; 次生矿物组合形成于近等温减压过程和固相线上熔融以及之后的近地表快速冷却。这些麻粒岩捕虏体代表了早期底侵到塔里木板块下地壳的幔源岩浆。     

塔里木西克尔新生代碧玄岩中辉石岩捕虏体的发现及其地质意义

首次在塔里木西克尔地区新生代碧玄岩中发现了辉石岩捕虏体。其主要矿物为ol+opx+cpx+pl+sp,含少量次生amp和phl。辉石岩中单斜辉石和斜方辉石普遍发育出溶结构。尖晶石明显分为晶形和产状不同的两个世代。变质成因的斜长石包裹大量高度自形的微小尖晶石颗粒。通过结构分析,出溶成份恢复,矿物温压计投图和P-T视剖面图分析确定:辉石岩捕虏体最初可能为无斜长石的尖晶石二辉岩,在降压至~1.5GPa,温度为1100~1200℃的过程中新生变质斜长石包裹了第二世代的自形尖晶石微晶;进一步的降温降压过程导致单斜和斜方辉石出溶和斜长石、橄榄石的生长,最终斜方辉石所记录的压力为 ~0.9GPa,温度为800~900℃。该变质作用过程说明辉石岩从尖晶石二辉岩稳定深度(>45km, A'点)抬升至斜长石二辉岩稳定深度(~28km,B点)并发生冷却,该过程可能代表了塔里木板块的壳幔过渡带曾发生了较大幅度的抬升,可能与地幔上涌造成的大陆岩石圈伸展、减薄有关。     

塔里木盆地石炭系烃源岩成熟演化研究

尽管塔里木盆地石炭系富含有机质且已发现其生成的原油,但关于石炭系烃源岩热演化研究却很薄弱。根据基础地质资料、古地温梯度和实测镜质体反射率数据,本文定量模拟了塔里木盆地6口典型井的石炭系烃源岩热演化史和这套烃源岩底界、顶界在二叠纪末期、三叠纪末期、白垩纪末期及现今成熟度的平面分布规律。塔北隆起南部、塔西南坳陷和阿瓦提凹陷在石炭-二叠纪作为沉降中心接受了巨厚的沉积物,造成这些地区石炭系烃源岩底界成熟度在二叠纪末期达到0.9%～1.3%（中-高成熟）,顶界为0.5%～0.9%（低-中成熟）,成为有利生油区。中生代时期,塔里木盆地中、东部长期处于沉降状态,石炭系烃源岩处于成熟演化阶段。白垩纪末期,塔中低凸起和满加尔凹陷的石炭系底界成熟度为0.7%～0.9%（中成熟）,顶界为0.5%～0.7%（低成熟）,而塘古孜巴斯坳陷底界成熟度为0.9%～1.1%（中-高成熟）,顶界为0.7%～0.9%（中成熟）。受羌塘地体、拉萨地体、印度板块分别与欧亚板块南缘碰撞远程效应的影响,塔西南坳陷和巴楚隆起在中生代一直处于隆升剥蚀状态,烃源岩热演化进入停滞状态。新生代以来,塔西南坳陷和阿瓦提凹陷演化为前陆盆地,再次接受了巨厚沉积物,致使石炭系烃源岩快速成熟演化,底-顶界成熟度现今已超过2.0%,进入干气阶段。满加尔凹陷石炭系烃源岩自石炭纪至今一直处于成熟演化阶段,现今达到最大,为0.8%～1.0%。另外,热史研究表明塔西南坳陷和阿瓦提凹陷石炭系烃源岩具有二次生烃潜力。本研究不仅丰富了塔里木盆地石炭系烃源岩热史研究成果,而且对油气勘探与开发具有重要的指导意义。     

Petrology and geochemistry of granulite xenoliths from Central Hoggar (Algeria) — Implications for the lower crust

Granulitic xenoliths, enclosed in Neogene alkali basalts from the Atakor and Adrar N'Addjer volcanic massifs in Central Hoggar, southern Algeria, include mafic metaigneous and felsic metasedimentary rocks. The main mineral phases of metaigneous xenoliths are plagioclase and pyroxenes whereas quartz, feldspars, sillimanite, garnet and sapphirine occur in metasedimentary granulites. The metaigneous xenoliths represent a magmatic sequence of cumulitic and non-cumulitic rocks which resembles gabbroic bodies associated with anorthosites and has calc-alkaline affinities. Similar types and distributions of granulitic xenoliths are widespread and are probably characteristic of the lower crust in general, suggesting its homogeneity on a large scale but heterogencity on a local scale.     

Platinum-group element geochemistry of mafic rocks from the Dongchuan area,southwestern China

Mafic intrusions and dykes are well preserved in the Yinmin and Lanniping districts, located within the western margin of the Yangtze Block, SW China. Although these mafic rocks from the two areas formed during different periods, they share similar ranges of PGE concentration. Most of the Yinmin gabbroic dykes contain relatively high PGE concentrations (PGEs = 13.9–87.0 ppb) and low S contents (0.003 %–0.020 %), higher than the maximum PGE concentrations of mafic magmas melting from the mantle. Two exceptional Yinmin samples are characterized by relatively low PGE (PGEs = 0.31–0.37 ppb) and high S (0.114 %–0.257 %) contents. In contrast, most samples from the Lanniping gabbroic intrusion have low PGE concentrations (PGEs = 0.12–1.02 ppb) and high S contents (0.130 %–0.360 %), except that the three samples exhibit relatively high PGE (PGEs = 16.3–34.8 ppb) and low S concentrations (0.014 %–0.070 %). All the Yinmin and Lanniping samples are characterized by the enrichment of PPGE relative to IPGE in the primitive-mantle normalized diagrams, and the high-PGE samples exhibit obvious Ru anomalies. This study suggests that during the ascent of the parental magma, removal of Os–Ir–Ru alloys and/or chromite/spinel leads to high Pd/Ir ratios and Ru anomalies for the Yinmin high-PGE samples and relatively lower Pd/Ir ratios and Ru anomalies for the Lanniping low-PGE samples. We propose that the magmas parental to the Yinmin gabbroic dykes are initially S-unsaturated, and subsequently, minor evolved magma reached sulfur saturation and led to sulfide segregation. Although the Lanniping parental magmas are originally not saturated in S, the high Cu/Pd ratios (3.8 × 10⁴ to 3.2 × 10⁶) for most of the Lanniping samples indicate the S-saturated state and sulfide segregation. A calculation shows that the PGE-poor magmas might have experienced 0.01 %–0.1 % sulfide segregation in the magma chamber. Therefore, our study provides a possible opportunity to discover PGE-enriched sulfide mineralization somewhere near or within the Lanniping mafic intrusion.     

滇西六合正长斑岩和花岗岩包体中锆石U-Pb年代和微量元素地球化学研究

六合正长斑岩是滇西新生代富碱斑岩的典型代表,以发育各类深浅不一的岩石包体而闻名,其中包括了同期的花岗岩包体;主岩和包体所蕴含的深部地质过程对于富碱岩浆的形成和演化具有重要约束作用。本文以六合正长斑岩和其中花岗岩包体的锆石微量元素地球化学为研究重点,结合主岩主量元素、锆石U-Pb年龄、Ti温度、锆石氧逸度的对比研究,分析和探讨富碱岩浆的形成和演化过程。研究表明:锆石U-Pb年龄所限定的六合富碱岩浆活动时限为(37.89±0.96)~(35.87±0.58) Ma;而花岗岩包体代表的同期富硅酸性岩浆活动时限为(38.21±0.44)~(36.21±0.36) Ma;两者几乎同步活动。锆石微量元素成因判别图显示主岩锆石主要位于钾镁煌斑岩范围,暗示富碱岩浆源区具地幔属性;花岗岩包体锆石大多位于花岗岩范围,两者在花岗岩范围有部分重叠,证实了主岩锆石和花岗岩包体锆石结晶时存在共同的生长环境。Ce^(Ⅳ)/Ce^(Ⅲ)比值估算和Ti温度计算显示,在36.42~36.41 Ma范围内富碱岩浆氧逸度和锆石结晶温度发生突变,指示在该时限内富碱岩浆及所裹挟的花岗质岩浆发生了混合作用;氧逸度的振荡降低反映了后期幔源岩浆的补充。综合研究认为,六合地区来自富集地幔的喜山期富碱岩浆底侵熔化上覆深部地壳长英质岩石形成花岗质岩浆,随即以富碱岩浆为主与少量花岗质岩浆不均一混合并同步结晶成岩形成含有花岗岩包体的正长斑岩。     

Platinum-group element geochemistry of peridotite xenoliths from the Sierra Nevada and the Basin and Range, California

The nature of PGE-Re (PGE = Pt, Pd, Os, Ir, Ru) behavior in subcontinental lithospheric mantle was investigated using new, high precision PGE-Re abundance measurements and previously published Re-Os isotopic analyses of peridotite xenoliths from the Sierra Nevada and Mojave Province, California. Ru/Ir ratios and Ir concentrations are constant over a wide range in S content and major-element fertility indices (e.g., Mg/(Mg+Fe)), indicating that Ru and Ir are not only compatible during partial melting, but also that their partitioning behaviors may not be controlled entirely by sulfide. Pt/Ir, Pd/Ir, Os/Ir, and Re/Ir ratios range from slightly superchondritic to distinctly subchondritic for all xenoliths except for one anomalous sample (1026V), which is characterized by radiogenic ¹⁸⁷Os/¹⁸⁸Os, low Re/Os ratio, and large enrichments in Cu, Os, Pt, Pd, and S relative to Ir (COPPS metasomatism). Assuming chondritic initial relative abundances, the magnitudes of some of the depletions in Pt, Pd, Os, and Re relative to Ir and Ru require incompatible behavior or substantial secondary loss. In detail, some samples, which are otherwise characterized by fertile major-element indices, exhibit low S contents and subchondritic Os/Ir and Pd/Ir ratios, indicating that depletions in Pd and Os relative to Ir are not simple functions of the degree of melting as inferred from major elements. Possible mechanisms for depleting Pt, Pd, Os, and Re relative to Ir and Ru include partitioning into chromian spinels and alloys, partitioning between sulfide and sulfide liquids, mobilization by aqueous fluids, or secondary loss associated with late-stage sulfide breakdown. However, it is not possible to explain all of the depletions in Pt, Pd, Os, and Re by any single mechanism.The preferential enrichment in Os over Re and Ir in sample 1026V is somewhat paradoxical because this sample’s radiogenic ¹⁸⁷Os/¹⁸⁸Os requires a metasomatic agent, originating from a source with a high time-integrated Re/Os ratio. The abundant garnet websterite xenoliths may be a suitable source because they have high Re/Os ratios, radiogenic Os, and abundant garnet, which may sequester Re over Os during partial melting. However, their extremely low Os contents require the processing of large amounts of garnet websterite to concentrate enough Os into the metasomatic sulfides needed to enrich sample 1026V in Os. The homogeneity in ¹⁸⁷Os/¹⁸⁸Os ratio in the remaining xenoliths suggest that their Os isotopic compositions were not significantly affected by PGE metasomatism. The singular nature of 1026V’s composition emphasizes the rarity of COPPS metasomatism.     

The Permian mafic intrusive events in the northwestern margin of the Tarim Basin and their tectonic significanceSCIEI北大核心CSCD

塔里木大火成岩省是我国境内发现的两个重要的二叠纪大火成省之一,不仅有大规模的溢流相玄武岩喷发,还有复杂多样的侵入岩及其组合。以往的研究主要集中在二叠系等显生宙地层发育区,对于前寒武系等古老层系中是否存在二叠纪岩浆侵入未引起重视。本文通过野外地质调查,在阿克苏地区前寒武系中识别出数条侵入南华系的基性岩墙和较大规模侵入震旦系的基性岩床。岩墙、岩床与围岩之间均显示出典型的侵入接触关系,包括岩体内部结晶粗、边部结晶细的淬冷边结构、岩床顶底面显著的切层现象以及包裹围岩团块等;显微镜下观察表明,辉绿岩具有典型的辉绿结构和嵌晶含长结构。锆石U-Pb年代学结果表明,侵入下震旦统的辉绿岩岩床和侵入南华系的辉绿岩岩墙的侵位时代在误差范围内基本一致,约为290Ma。岩石地球化学特征表明,辉绿岩岩床具有与洋岛玄武岩(OIB)相似的稀土及微量元素配分模式,结合Sr-Nb-Pb同位素测试结果,认为它们来源于碳酸盐化的富集型岩石圈地幔部分熔融,而辉绿岩岩墙具有Nb、Ta、Zr、Hf等负异常的地球化学特征,可能来自曾被俯冲相关流体/熔体交代的岩石圈地幔源区。本文的早二叠世辉绿岩岩床和岩墙的形成时代、岩浆源区和岩浆演化...     

Cryptic sediment-hosted critical element mineralization from eastern Yunnan Province,southwestern China: Mineralogy,geochemistry, relationship to Emeishan alkaline magmatism and possible origin

A previous study briefly described the occurrence of a new type of Nb(Ta)-Zr(Hf)-REY-Ga (REY: rare earth elements and yttrium) polymetallic mineralization in eastern Yunnan, southwest China. In this paper, the mineralogical and geochemical features have been further advanced through a study of two regionally extensive and relatively flat-lying mineralized layers from No. XW drill core. The layers are clay-altered volcanic ash and tuffaceous clay, and are dominated by clay minerals (mixed layer illite/smectite, kaolinite, berthierine, and chamosite); with lesser amounts of quartz and variable amounts of anatase, siderite and calcite; along with trace pyrite, barite, zircon, ilmenite, galena, chalcopyrite, and REE-bearing minerals. The mineralized samples have higher Al₂O₃/TiO₂ values (13.7–41.4) and abundant rare metal elements (Nb, Ta, Zr, Hf, REE, Ga, Th, and U) whereas less mineralized samples are rich in V, Cr, Co, and Ni and have lower Al₂O₃/TiO₂ values (2.32–7.67). The mineralized samples also have strong negative δEu in chondrite-normalized REE patterns. Two processes are most likely responsible for the geochemical and mineralogical anomalies of the mineralized samples: airborne volcanic ash and multi-stage injection of low-temperature hydrothermal fluids. Based on paragenetic analysis, this polymetallic mineralization is derived from the interaction between alkaline volcanic ashes and subsequent percolation of low-temperature fluids. The intense and extensive alkaline volcanism of the early Late Permian inferred from this study possibly originated from the coeval Emeishan large igneous province (ELIP). This unique Nb(Ta)-Zr(Hf)-REE-Ga mineralization style has significant economic and geological potential for the study of mineralization of the lowest Xuanwei Formation.     

Sedimentation Rate Rhythms: Evidence from Filling of the Tarim Basin, Northwest China

Variations of sedimentation rate within a basin over geologic time are a time series that can be filtered into several cyclic wave curves. Based on back-stripping and the empirical mode decomposition method, the cores from 14 wells in the Tarim Basin were selected to do filtering analysis. Four cycles or quasi-cycles (33 Ma, 64.4 Ma, 103.6 Ma, and 224 Ma) were obtained. Among these, the 33 Ma period, which was related to the internal earth activity, an external force, or a combination of the two, was the most obvious. The 64.4 Ma period corresponded to the solar system crossing the galaxy plane or the periodic melting of inner-earth material. The 103.6 Ma period was related with plate collisional tectonism around the Tarim Plate. The 224 Ma period was related to one galaxy year and may also be related to the aesthenospherical convection cycle.     

Sedimentation Rate Rhythms: Evidence from Filling of the Tarim Basin, Northwest China

Variations of sedimentation rate within a basin over geologic time are a time series that can be filtered into several cyclic wave curves. Based on back-stripping and the empirical mode decomposition method, the cores from 14 wells in the Tarim Basin were selected to do filtering analysis. Four cycles or quasi-cycles (33 Ma, 64.4 Ma, 103.6 Ma, and 224 Ma) were obtained. Among these, the 33 Ma period, which was related to the internal earth activity, an external force, or a combination of the two, was the most obvious. The 64.4 Ma period corresponded to the solar system crossing the galaxy plane or the periodic melting of inner-earth material. The 103.6 Ma period was related with plate collisional tectonism around the Tarim Plate. The 224 Ma period was related to one galaxy year and may also be related to the aesthenospherical convection cycle.     

湘南中生代钨锡大规模成矿控制因素：锆石年龄和微量元素的启示

以湘南地区震旦系、泥盆系、石炭系和白垩系碎屑岩中碎屑锆石及印支期—燕山期花岗岩中岩浆锆石为对象,通过锆石U-Pb年龄和微量元素地球化学研究,探讨湘南地区中生代钨锡大规模成矿的控制因素。锆石年龄结果表明,碎屑锆石年龄缺乏2.0 Ga左右的谱峰,显示湘南地区震旦纪和晚古生代沉积盆地物源具有华夏陆块的亲缘性,不具扬子陆块亲缘性,可以代表研究区华夏地块岩浆活动的记录;碎屑锆石年龄峰值记录了华夏陆块2.5 Ga、1.3~1.1 Ga、950 Ma、800 Ma、650 Ma和430 Ma六期前中生代构造-岩浆事件,对应早前寒武纪陆壳形成、Grenville碰撞造山运动及Rodinia超大陆的聚合-裂解过程。锆石微量元素分析结果表明,同一构造-岩浆事件锆石的δEu、LREE/HREE、Y/Ho、Nb/Ta值变化幅度均较大,LREE/HREE和Nb/Ta值不随时代变新而变小(反而有变大的趋势),表明岩浆分异程度与时代无关。但是,锆石∑REE、Y、Th、U、Nb和Ta含量,以及LREE/HREE和Nb/Ta值随时代变新而增高,表明岩浆源区的成分成熟度逐渐增高。湘南地区钨锡矿化规模随着时代变新而增大,在中生代达到顶峰,这一趋势与地壳成熟度的不断增高密切相关。锆石微量元素特征可作为示踪钨锡成矿规模的重要指标。     

Petrological and geochemical characteristics of mafic rocks from the Neoproterozoic Sugetbrak Formation in the northwestern Tarim Block,China

The Neoproterozoic Sugetbrak Formation in the Aksu area, which is located at the northwest margin of Tarim Block, comprises mafic rocks and provides key records of the evolution of the Rodinia supercontinent. However, the genetic relationship among these mafic rocks exposed in different geographical sections are still unclear. In this study, the petrology, geochemistry, and Sr-Nd-Pb isotope geochemistry of the mafic rocks exposed in the Aksu-Wushi and Yuermeinark areas have been studied in some ...     

The trace element geochemistry of clinopyroxenes from pyroxenites in the Lewisian of NW Scotland: insights into light rare earth element mobility during granulite facies metamorphism

Clinopyroxenes from layered pyroxenites and from pyroxenite pods in felsic gneisses of the Lewisian granulite complex, NW Scotland, have distinctive chemistries suggestive of different origins. Clinopyroxenes in the layered pyroxenites crystallised from mafic melts in a magma chamber located in the middle to shallow crust, whereas clinopyroxenes in pods in the felsic gneisses crystallised from the tonalitic protolith to the felsic gneisses. In detail clinopyroxenes in the layered pyroxenites are variably enriched in the light REE. Inversion modelling shows that this is not a primary feature inherited from their parent magmas. Rather selective light rare earth element enrichment took place through reaction with a felsic melt generated by the localised partial melting of the hornblende pyroxenites during granulite facies metamorphism. Published isotopic evidence suggests that the light REE mobilisation took place at ca 2.7 Ga, about 200 Ma after the time of crust formation. This observation provides an explanation for the scattered pattern of whole-rock isochron ages from the Lewsian granulites.     

闽东南基性岩脉成因及动力学背景研究：Sr-Nd同位素、元素地球化学

闽东南的海边斜闪煌斑岩脉和赤湖辉长岩脉分别形成于晚白垩世和古新世,为高钾钙碱性和钙碱性系列岩石,具有高Al、Na2O＞K2O的特征;岩浆演化过程中可能经历了以橄榄石、单斜辉石为主的结晶分异作用.海边和赤湖基性岩脉具有相对富集大离子亲石元素和轻稀土元素,亏损高强场元素特征,不相容元素蛛网图显示出大陆边缘弧的地球化学特征,以Nb、Ta、Ti负异常为特征;海边和赤湖明显富集轻稀土元素,（La/Yb）N分别为5.0～10.9和11.2～12.0.具有高Sr同位素初始值和低εNd（t）值,海边的（^87Sr/^86Sr）i：0.70577～0.707574,εNd（t）：-8.1～-1.8,赤湖的（^87Sr/^86Sr）i：0.70547～0.70552,εNd（t）：-0.2～0.6.根据Sr、Nd同位素、微量元素研究及野外地质观察,本区基性岩脉的岩浆在上升侵位过程中未发生地壳物质混染.通过Sr、Nd同位素和微量元素等研究,认为地幔源区的演化与古太平洋板块俯冲密切相关,俯冲流体交代地幔楔、消减洋壳携带的海洋与陆源沉积物参与地幔源区的混合,形成本区基性岩脉的富集地幔源区,大离子亲石元素和轻稀土元素特别富集是俯冲流体与沉积物共同参与源区演化的结果.海边和赤湖基性岩脉形成的构造背景属于活动大陆边缘弧,构造性质应为活动陆缘拉张带（或裂谷带）.晚白垩世和古新世,闽东南发生了地壳拉张事件,与中国东南部晚白垩世以来的地壳拉张期次是一致.     

安徽女山橄榄岩包体的氧同位素比值和微量元素组成：地幔交代作用

1本文的研究对象是9个来自安徽女山新生代玄武岩的橄榄岩包体,利用激光氟化技术系统分析了橄榄石、单斜辉石和斜方辉石的氧同位素比值;利用LA-ICPMS技术分析了单斜辉石的微量元素组成,结果显示,女山橄榄岩存在辉石与橄榄石之间的氧同位素不平衡分馏现象,其中△Cpx-O1^18O（=δ^18OCpx-δ^18OO1））出现低至-0．5‰的负值;合角闪石包体中的单斜辉石明显富集大离子亲石元素（LILE,如Sr、Th、LREE）和亏损高场强元素（HFSE,如Nb、Zr、Ti）,氧同位素的数据表明,女山上地幔曾经经历过俯冲洋壳流体参与的交代作用,根据单斜辉石和橄榄石之间氧同位素分馏值△Cpx-O1^18O与包体形成深度之间的负相关性,提出了一个“上升＋缓冲”的流体交代模型,虽然微量元素特征也表明女山上地慢受到过地壳流体的影响,但是氧同位素的不平衡分馏和LILE的富集／HFSE的亏损并不是同步的,对这种现象的可能解释是：引起氧同位素不平衡分馏的交代作用和造成女山单斜辉石微量元素特征的交代作用不是同一期的,即女山上地幔曾经发生过至少2次交代事件.     

华北克拉通怀安杂岩中“MORB”型高压基性麻粒岩的成因及其构造意义

古元古代是华北克拉通重要的构造演化阶段,现已识别出多条碰撞造山带,但这些造山带的构造边界、演化时限以及地球动力学过程仍存在争议。本文报道了在怀安杂岩中新发现的一套高压基性麻粒岩-大理岩-富铝片麻岩表壳岩组合,原岩为一套基性火山岩-碳酸盐岩-砂/泥岩建造。高压基性麻粒岩记录了峰期高压麻粒岩相变质和麻粒岩相-角闪岩相退变质过程;地球化学研究表明其原岩为亚碱性拉斑玄武岩,具有平坦的稀土元素配分模式((La/Yb)_N=1. 35～1. 79),轻稀土相对亏损((La/Sm)_N=0. 83～1. 13),弱的正铕异常(δEu=1. 0～1. 22),无Nb、Ta负异常,与洋中脊玄武岩(MORB)地球化学特征类似;岩石组合和产状特征与晋冀蒙交界地区广泛分布的具有岛弧拉斑玄武岩性质的岩墙型高压基性麻粒岩明显不同。高压基性麻粒岩锆石εHf(t)为正值(+2. 6～+11. 5),单阶段模式年龄(t_(DM))介于2065～2250Ma之间,可能来源于尖晶石稳定域的浅层地幔源区。综合来看,这套含高压基性麻粒岩组合可能是古洋壳残片。SHRIMP U-Pb定年和Hf同位素研究表明,高压基性麻粒岩的原岩可能形成于2. 15～2. 2Ga,峰期高压麻粒岩相变质年龄为～1. 95Ga,1. 83～1. 82Ga代表麻粒岩相退变质作用和减压熔融时限。本文研究表明,该套表壳岩组合记录了古元古代俯冲-碰撞-折返等一系列造山构造演化过程,可为恢复古元古代造山带早期构造环境提供证据。     

汉诺坝幔源橄榄岩包体的微量元素和Re-Os同位素地球化学：SCLM的性质和形成时代

本文报道了汉诺坝新生代碱性玄武岩中地幔橄榄岩包体的主量、微量元素和Re-Os同位素。14个尖晶石橄榄岩Re、Os含量分别为0.022～0.193ng/g和1.237～4.304ng/g，^187Os/^188Os比值为0.1183～0.1244，与^187Os/^188Os比值相关性不好，但与熔体亏损指标如重稀土元素Yb的含量、全岩Al2O3的百分含量有很好的线性关系，可能反映了地幔熔融后的Re或/和Os的活动。全岩Al2O3、CaO、TiO2含量均与MgO有很好的负相关性，全岩原始地幔标准化REE丰度模式呈现了LREE亏损，表明该区橄榄岩包体是由软流圈地幔经过部分熔融，亏损了玄武质组分后形成的。由Os同位素代理等时线得到该区陆下岩石圈地幔的形成年龄为1.7～2.0Ga，表明尖晶石相橄榄岩所代表的岩石圈地幔是中元古代的陆下岩石圈地幔减薄后的残留体。     

滇西北兰坪盆地李子坪铅锌矿床微量元素地球化学特征

闪锌矿中的稀土元素、微量元素蕴含着与成岩、成矿密切相关的地球化学信息.李子坪铅锌矿床位于兰坪盆地北部,矿体呈脉状、似层状产出于侏罗系花开佐组碎屑岩及碳酸盐岩夹泥质岩组合建造中.微量元素地球化学特征显示,该矿床闪锌矿形成于中低温环境,以富含 Ga、Ge、Ag、Cd、Tl、Ni、Cu 和 As 等微量元素,亏损 Fe、In、Sn、Mn 和 Co 等元素为特征.总体上,该矿床闪锌矿中 Ag、Ga 和 Fe 等微量元素组成明显不同于喷流沉积铅锌矿床(如白牛厂、老厂和大宝山),更不同于夕卡岩型矿床(如核桃坪与鲁子园),而与一般 MVT 型矿床(墨西哥 Tre Marias、云南会泽和贵州牛角塘)和金顶铅锌矿床类似,但 Cd 含量明显低于 MVT 型矿床和云南金顶铅锌矿床,暗示其独特的成矿机制.稀土元素研究显示,闪锌矿与赋矿围岩的REE 分布模式表现出相同的变化趋势,而不同于兰坪盆地富碱岩体,暗示该矿床闪锌矿的 REE 分布模式受围岩地层的影响.     

Geochemistry of mafic and ultramafic xenoliths from Fidra (Southern Uplands, Scotland): implications for lithospheric processes in Permo-Carboniferous times

Several types of xenoliths occur in a Permian basanite sill in Fidra, eastern central Scotland. One group consists of spinel lherzolites, which have geochemical and isotopic characteristics similar to those of lithospheric upper mantle from elsewhere in western Europe, with both LREE-depleted and LREE-enriched compositions. A separate group comprises pyroxenites and wehrlites, some of which contain plagioclase; these have compositions and textures that indicate that they are cumulates from mafic magmas. In terms of Sr and Nd isotope compositions, the pyroxenites closely resemble the host basanite and most likely formed by high-pressure fractionation of Permo-Carboniferous alkaline magmas at lower crustal depths. They also have mantle-like δ¹⁸O values. A third group is composed of granulite xenoliths that vary between plagioclase-rich and clinopyroxene-rich compositions, some of which probably form a continuum with the pyroxenites and wehrlites. They are all LREE-enriched and most have positive Eu anomalies; thus, they are also mostly cumulates from mafic magmas. Many of the granulites also have Sr and Nd radiogenic isotope ratios similar to those of the host basanite, indicating that they have formed from a similar magma. However, several of the granulites show more enriched isotopic compositions, including higher δ¹⁸O values, trending towards an older crustal component. Thus, the pyroxenites and granulites are largely cogenetic and are mainly the product of a mafic underplating event that occurred during the widespread magmatism in central Scotland during Permo-Carboniferous times.