天气现象露的判定之刍见

根据多年的工作经验,总结出4点观测、判断露的注意事项。     

天气现象露的判定之刍见

根据多年的工作经验,总结出4点观测、判断露的注意事项。     

广西2002年寒露风天气对晚稻的影响与防御对策分析

针对2002年9～10月份广西出现的寒露风天气对晚稻的影响作分析、评价,并就如何防御寒露风害提出了几点对策。     

毛乌素沙地南缘凝结水观测实验分析

采用称重法对2007年8月期间毛乌素沙地南缘不同地表类型（改良沙地、生物结皮、物理结皮和流沙）、沙丘不同部位的凝结水形成动态过程进行了系统观测。结果表明：改良沙地凝结水量达0．206mm／d,显著大于生物结皮、物理结皮和流沙,生物结皮凝结水量为0．100mm／d,显著高于流沙,而其他两者之间凝结水量无显著性差异;沙丘不同部位凝结水量差异显著,丘间地凝结水量最大,沙丘坡面次之,沙丘顶部最少,日凝结水量分别为0．0873mm／d、0．0768mm／d和0．0674mm／d;从凝结水形成过程看出凝结水一般在每天17：00产生,次日7：00结束,在夜晚21：00和凌晨3：00左右出现2个凝结水较大值;凝结水的形成与气象因子密切相关,凝结水量与地表温度、大气和地表温度差以及净辐射具有显著相关性。     

降水中甲酸和乙酸研究综述

对大气降水中甲酸和乙酸的相关研究进行了综述。介绍了过去曾采用的研究降水样品中两种有机酸的处理和分析方法,以及目前最常用的实验室分析方法。对降水中两种有机酸的浓度范围、全球时空分布以及受影响因素等相关研究工作进行了系统归纳,并且结合理论计算说明了有机酸对降水酸度的影响是不可忽视的。介绍了历史研究工作中得出的降水中两种有机酸的来源,包括天然源、人为源和有机物的二次化学转化等,以及有机酸源研究对于开展其它降水有机酸工作的研究意义。     

长沙地区寒露风气候特征及初日预测模型

根据1959—2015年长沙地区4个气象站的日平均气温资料、湖南省寒露风等级标准和构建的寒露风初日时间序列,利用数理统计分析、均生函数、最优子集回归等方法,分析了长沙地区寒露风气候特征,建立了寒露风初日预测模型。结果表明:长沙地区1959—2015年发生寒露风共97次,宁乡、望城坡、马坡岭和浏阳分别为38、28、19和12次;发生中度以上寒露风次数自西向东分别为15、10、8和5次。寒露风平均初日在9月19—22日。≤20℃的开始日期最早为9月3日(2013年),最迟为10月28日(2014年),极差为56天。9月上、中及下旬发生寒露风的概率分别为6%、32%和62%,下旬发生概率显著增加。西部宁乡约2 a一遇,东部浏阳约5 a一遇,西部宁乡频率及影响程度远高于东部浏阳的。预测模型拟合率均在89%以上,2011—2016年预测结果较好。     

Solubility of HOCl in water and aqueous H2SO4 to stratospheric temperatures

Henry's law constants K_H (mol kg^–1 atm^–1) for the reaction HOCl_(g)=HOCl_(aq) near room temperature, literature data for the associated enthalpy change, and solubilities of HOCl in aqueous H₂SO₄ (46 to 60 wt%) at temperatures relevant to the stratosphere (200 KT230 K) are shown to be thermodynamically consistent. Effective Henry's law constants [H*=mHOCl/pHOCl, in mol kg^–1 atm^–1] of HOCl in aqueous H₂SO₄ are given by: ln(H*)=6.4946–mH₂SO₄(–0.04107+54.56/T)–5862 (1/T_o–1/T) where T(K) is temperature and T_o=298.15K. The activity coefficient of HOCl in aqueous H₂SO₄ has a simple Setchenow-type dependence upon H₂SO₄ molality.     

The Henry's Law Constants of the Haloacetic Acids

Henry's law constants K_H (mol kg^-1 atm^-1) have been measured between 278.15 K and 308.15 K for the following organic acids: CH₂FCOOH (ln(K_H[298.15 K]) = 11.3 ± 0.2), CH₂ClCOOH (11.59 ± 0.14), CH₂BrCOOH (11.94 ± 0.21), CHF₂COOH (10.32 ± 0.10), CHCl₂COOH (11.69 ± 0.11), CHBr₂COOH (12.33 ± 0.29), CBr₃COOH (12.61 ± 0.21), and CClF₂COOH (10.11 ± 0.12). The variation of K_H with temperature was determined for all acids except CH₂FCOOH and CBr₃COOH, with _r H° for the dissolution reaction ranging from –85.2 ± 2.6 to –57.1 ± 2.5 kJ mol^-1, meaning that their solubility is generally more sensitive to temperature than is the case for the simple carboxylic acids. The Henry's law constants show consistent trends with halogen substitution and, together with their high solubility compared to the parent (acetic) acid (ln(K_H[298.15 K]) = 8.61), present a severe test of current predictive models based upon molecular structure. The solubility of haloacetic acids and strong dissociation at normal pH mean that they will partition almost entirely into cloud and fog in the atmosphere (0.05–1.0 g H₂O m^-3), but can reside in both phases for the liquid water contents typical of aerosols (10^-5-10^-4 g H₂O m^-3).     

Measurements of the Henry's Law Coefficients of 2-Methyl-3-buten-2-ol, Methacrolein, and Methylvinyl Ketone

Using an equilibrium headspace technique, Henry's law coefficients were measured for methacrolein (H = 6.5 ± 0.7 M atm-1) and methylvinyl ketone (41 ± 7.0 M atm-1) in water at 25 °C. In addition, 2-methyl-3-buten-2-ol was studied at 30 °C in water and in an aqueous ionic solution representative of plant tissue. Similar values were found in deionized water (65 ± 3.5 M atm-1) and in a 0.05 mol kg-1 Ca2+, K+, NO3-, SO42- solution (62 ± 0.8 M atm-1). These Henry's Law coefficients are too small to allow for significant partitioning of methacrolein, methylvinyl ketone or methylbutenol into cloud water under equilibrium conditions.     

The effect of metal complexation on hydrogen sulfide transport across the sea-air interface

Hydrogen sulfide dissolved in surface seawater is distributed into free forms which include the volatile neutral H₂S and its conjugate anions, and also into a set of involatile metal complexes. Calculation of the sulfide fraction capable of supporting sea-air flux is sensitive to large uncertainties in complexation equilibrium relationships, both for the sulfides themselves, and for organic ligands competing with them to coordinate dissolved copper. Saturation can be achieved relative to the troposphere if metal interactions are minimized, or if strong sulfide binders are titrated.     

Effect of atmospheric humic-like substances on the enhanced dissolution of volatile organic compounds into dew water

Simultaneous sampling of chlorinated hydrocarbons (CHs) and monocyclic aromatic hydrocarbons (MAHs), potentially harmful to humans and/or responsible for the formation of ozone and secondary particles, in dew water and in the ambient air was carried out from August 2004 to July 2005 in Hino City, situated in the western part of Greater Tokyo, Japan. CHs were less contained in dew water than MAHs. Toluene (volume-weighted mean concentration, VWM: 4.77 nM) and m,p-Xylenes (VWM: 5.07 nM) except dichloromethane, which was abnormally high (VWM: 1.14 μM), were abundant among eleven VOCs determined in dew water. Chloroform, carbon tetrachloride, 1,2-dichloroethane, and benzene were not detected in dew water during the study period. Dew water contained higher amounts of VOCs than would have been expected from the ambient gas-phase concentrations and the temperature-corrected Henry's law constants. Following the determination method of humic substances in river water proposed by Hiraide et al. [Hiraide, M., Shima, T., Kawaguchi, H., 1994. Separation and determination of dissolved and particulate humic substances in river water. Mikrochim. Acta 113, 269–276], the VWM of soluble humic and fulvic acid fractions in dew water was found to be 1.00 mg/L and 0.87 mg/L (n = 20), respectively, while the VWM of particulate humic and fulvic acid fractions was found to be 0.61 mg/L and 0.42 mg/L (n = 20), respectively. Surface tension decreased with an increase in dissolved fulvic acid fraction in dew water, indicating that humic-like substances with relatively lower molecular weight, which is soluble in acid solution, could be an effective surface-active species within dew water. The enrichment factors, which were defined as the ratio of the observed VOCs concentration to the estimated, were over 10² for MAHs except for benzene and increased as the increment of total humic-like substances (HULIS) concentration (the sum of humic and fulvic acid fractions in both dissolved and particulate form) normalized by total inorganic ion concentration in dew water. Our results indicate that total HULIS in dew water could enhance the dissolution of atmospheric VOCs into dew droplets.     

Henry's law and the behavior of weak acids and bases in fog and cloud

Experimental data from two field experiments on ground based clouds were used to study the distribution of formic acid, acetic acid, ammonia and S(IV) species between liquid and gas phase. The ratio of the concentrations of these compounds between the phases during concurrent measurements was compared to ratios expected according to Henry's law (considering the pH influence). Large discrepancies of several orders of magnitude were seen. Three hypotheses have been investigated to explain the observed discrepancies: The existence of a microscale equilibrium which does not persist in a bulk sample, a thermodynamic shift of the equilibrium due to competing reactions, and nonequilibrium conditions due to mass transfer limitations. Approximate quantitative calculations show that none of these hypotheses is sufficient to explain all of the discrepancies, so a combination of different effects seems to be responsible for this observation. The same theoretical considerations also suggest that mass transfer limitation may be an important factor for highly soluble compounds. The data presented here indicates that it is not possible to simply extrapolate interstitial gas phase composition from measured bulk liquid phase concentrations of a fog or cloud.Notation [r _max] liquid phase molar uptake rate (mol l^–1 s^–1) - [A _g ] concentration ofA in gas phase (atm) - [A _l ] concentration ofA in liquid phase (mol l^–1) - [A _g , 0] concentration ofA in gas phase (atm) at time 0 - LWC liquid water content (g m^–3) - R universal gas constant (0.082 l atm mol^–1 K^–1 - D _g diffusivity (for all gases 0.1 cm² s^–1 was used) - K _H ^* effective Henry's law coefficient (mol l^–1 atm^–1) - t _f lifetime of fog droplet (s) - a droplet radius (cm) - accommodation coefficient - R factor of discrepancy - T temperature (K) - v mean molecular speed (cm s^–1) formic acid: 35 000 acetic acid: 31 000 ammonia: 58 000     

Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds

Although organic compounds typically constitute a substantial fraction of the fine particulate matter (PM) in the atmosphere, their molecular composition remains poorly characterized. This is largely because atmospheric particles contain a myriad of diverse organic compounds, not all of which extract in a single solvent or elute through a gas chromatograph; therefore, a substantial portion typically remains unanalyzed. Most often the chemical analysis is performed on a fraction that extracts in organic solvents such as benzene, ether or hexane; consequently, information on the molecular composition of the water-soluble fraction is particularly sparse and incomplete.This paper investigates theoretically the characteristics of the water-soluble fraction by splicing together various strands of information from the literature. We identify specific compounds that are likely to contribute to the water-soluble fraction by juxtaposing observations regarding the extraction characteristics and the molecular composition of atmospheric particulate organics with compound-specific solubility and condensibility for a wide variety of organics. The results show that water-soluble organics, which constitute a substantial fraction of the total organic mass, include C2 to C7 multifunctional compounds (e.g., diacids, polyols, amino acids). The importance of diacids is already recognized; our results provide an impetus for new experiments to establish the atmospheric concentrations and sources of polyols, amino acids and other oxygenated multifunctional compounds.     

华东沿海地带台风风廓线特征的观测个例分析

利用2007年的“韦帕”、2009年的“莫拉克”、2010年的“凡亚比”和2011年的“梅花”四个台风的GPS探空数据,本文对华东近海和沿海地带的台风风廓线特征进行分析。首先求出梯度风速及其对应的高度,在此基础上利用指数律和对数律对风廓线进行拟合,并对幂指数、10米高度的地表风速和梯度风速的风速比,以及由对数律定义的常通量层高度等参数进行计算,并对梯度风高度和常通量层高度进行比较。结果表明:登陆台风沿海地带风廓线的梯度风高度和常通量层高度有明显差异。本文还对登陆台风平均风廓线的各参数进行了计算,并对梯度风高度以下风廓线偏离对数律的原因进行了讨论。     

Modelling of the nighttime nitrogen and sulfur chemistry in size resolved droplets of an orographic cloud

A chemistry module has been incorporated into a Lagrangian type model that computes the dynamics and microphysics of an orographical cloud formed in moist air flowing over the summit of Great Dun Fell (GDF) in England. The cloud droplets grow on a maritime aerosol which is assumed to be an external mixture of sea-salt particles and ammonium-sulfate particles. The dry particle radii are in the range 10 nm<r<1 µm. The gas-phase chemical reaction scheme considers reactions of nitrogen compounds that are important at night. The treatment of scavenging of gases into the aqueous phase in the model takes into account the different solubilities and accommodation coefficients. The chemistry in the aqueous phase focusses on the oxidation of S(IV) via different pathways.Sensitivity analyses have been performed to investigate deviations from gas-liquid equilibria according to Henry's law and also to study the influence of iron and of nitrogen compounds on the aqueous-phase oxidation of dissolved SO₂. When addressing these questions, special attention has been given to the dependence on the droplet size distribution and on the chemical composition of the cloud condensation nuclei on which the droplets have formed. It was found that the oxidation of S(IV) via a chain reaction of sulfur radicals can be important under conditions where H₂O₂ is low. However, major uncertainties remain with respect to the interaction of iron with the radical chain. It was shown that mixing of individual cloud droplets, which are not in equilibrium according to Henry's law, can result in a bulk sample in equilibrium with the ambient air. The dependence of the aqueous-phase concentrations on the size of the cloud droplets is discussed for iron, chloride and NO₃.     

河南长葛南席一次龙卷成因分析及雷达预警初探

利用常规气象资料、四要素自动气象站和多普勒天气雷达资料,对发生在2010 年7 月19 日05 时30 分左右长葛东部南席镇一次罕见龙卷天气成因进行分析,初步探讨如何应用多普勒天气雷达对类似强对流天气进行有效预警。结果表明：此次龙卷天气发生在中空急流与中低层辐合、高层辐散相互配置的有利环境背景下,中低空露点锋和强湿度梯度带为龙卷产生提供触发机制,龙卷产生于干、湿空气交界并靠近湿区一侧;龙卷发生前中气旋表现出较低的底高、逐渐变小的最强切变高度、降低的顶高、较小的方位角方向直径和较强的垂直风切变等特征,初步总结出识别龙卷的雷达探测中气旋预警指标。     

The solubility and behaviour of acid gases in the marine aerosol

The following Henry's law constants (K _H/mol²kg^-2atm^-1) for HNO₃ and the hydrohalic acids have been evaluated from available partial pressure and other thermodynamic data from 0°–40°C, 1 atm total pressure: HNO ₃ , 40°C–5.85×10⁵; 30°C–1.50×10⁶; 25°C–2.45×10⁶; 20°C–4.04×10⁶; 10°C–1.15×10⁷; 0°C–3.41×10⁷. HF, 40°C–3.2; 30°C–6.6; 25°C–9.61; 20°C–14.0; 10°C–32.0; 0°C–76. HCl, 40°C–4.66×10⁵; 30°C–1.23×10⁶; 25°C–2.04×10⁶; 20°C–3.37×10⁶; 10°C–9.71×10⁶; 0°C–2.95×10⁷. HBr, 40°C–2.5×10⁸; 30°C–7.5×10⁸; 25°C–1.32×10⁹; 20°C–2.37×10⁹; 10°C–8.10×10⁹; 0°C–3.0×10¹⁰. HI, 40°C–5.2×10⁸; 30°C–1.5×10⁹; 25°C–2.5×10⁹; 20°C–4.5×10⁹; 10°C–1.5×10¹⁰; 0°C–5.0×10¹⁰. Simple equilibrium models suggest that HNO₃, CH₃SO₃H and other acids up to 10x less soluble than HCl displace it from marine seasalt aerosols. HF is displaced preferentially to HCl by dissolved acidity at all relative humidities greater than about 80%, and should be entirely depleted in aged marine aerosols.     

南宁市夏季不同下垫面温度特征分析与预报研究

对2000年至2002年4～9月南宁市下垫面表面温度观测资料的分析表明，下垫面温度明显高于百叶箱气温，尤其是日最高温度差异更大。而不同下垫面之间的温度变化，也有较大不同。下垫面温度的变化与其它气象因子密切相关。在上述分析的基础上，应用统计学方法建立了几种下垫面表面温度的预报方程。     

藏东南地区复杂下垫面能量收支特征分析

利用公益性行业（气象）科研专项项目＂藏东南地区复杂下垫面地气交换观测研究＂在藏东南地区进行的地气交换观测实验数据,分析典型晴天和阴天条件下不同下垫面能量过程的特征及其差异。结果表明：在典型晴空状态下,不同下垫面的地表净辐射均具有明显的日变化特征,在典型阴天的情况下,不同下垫面地表净辐射日均值显著减小;在典型晴空天气下,4种类型下垫面上潜热均随着净辐射的增加而表现为增加的趋势,在典型阴天的情况下,潜热通量明显比晴空天气小;不同下垫面感热通量的日变化存在显著的差异,不同下垫面感热的变化特征在典型晴空和阴天条件下的差异不明显;不同下垫面土壤热通量与净辐射的变化趋势基本一致,阴天夜晚土壤热流的交换与晴天夜晚的差异不大,四种下垫面土壤均存在能量损失,土壤处于降温状态。     

Characterization of Organic Aerosol at a Rural Site in the North China Plain Region: Sources,Volatility and Organonitrates

The North China Plain(NCP) is a region that experiences serious aerosol pollution. A number of studies have focused on aerosol pollution in urban areas in the NCP region; however, research on characterizing aerosols in rural NCP areas is comparatively limited. In this study, we deployed a TD-HR-AMS(thermodenuder high-resolution aerosol mass spectrometer) system at a rural site in the NCP region in summer 2013 to characterize the chemical compositions and volatility of submicron aerosols(PM_1). The average PM_1 mass concentration was 51.2 ± 48.0 μg m~(-3) and organic aerosol(OA) contributed most(35.4%) to PM_1. Positive matrix factorization(PMF) analysis of OA measurements identified four OA factors, including hydrocarbon-like OA(HOA, accounting for 18.4%), biomass burning OA(BBOA, 29.4%), lessoxidized oxygenated OA(LO-OOA, 30.8%) and more-oxidized oxygenated OA(MO-OOA, 21.4%). The volatility sequence of the OA factors was HOA BBOA LO-OOA MO-OOA, consistent with their oxygen-to-carbon(O:C)ratios. Additionally, the mean concentration of organonitrates(ON) was 1.48-3.39 μg m~(-3), contributing 8.1%–19% of OA based on cross validation of two estimation methods with the high-resolution time-of-flight aerosol mass spectrometer(HRToF-AMS) measurement. Correlation analysis shows that ON were more correlated with BBOA and black carbon emitted from biomass burning but poorly correlated with LO-OOA. Also, volatility analysis for ON further confirmed that particulate ON formation might be closely associated with primary emissions in rural NCP areas.