Frozen Hydrocarbon Particles as a Luminescent Dust Component of Nebular Matter

This paper is a continued examination of luminescence of cosmic dust, in particular the dust in reflecting nebulae. A model of frozen hydrocarbon particles in the form of a nucleus with a polycrystalline mantle is proposed. The basic properties of these particles, as well as the technique for obtaining spectra of the nebula CED 201 on the 2 meter TLS telescope with a Naismith focus spectrograph, are described. Part of the detected unknown emission in the spectrum of CED 201 is identified as photoluminescence of frozen hydrocarbon particles that form part of the dust component of the nebular matter.__________Translated from Astrofizika, Vol. 48, No. 3, pp. 445–453 (August 2005).     

On the nature of unidentified cometary emission lines

The nature of unidentified cometary emission lines is discussed. A model of ice particles in cometary halos as a mixture of frozen polycyclic aromatic hydrocarbons (PAHs) and acyclic hydrocarbons is considered. The properties of frozen hydrocarbon particles are described and 5–7% of the unidentified cometary emission lines are considered as the photoluminescence of frozen hydrocarbons. The positions of unidentified emission lines in the spectrum of Comet 19P/Borrelly are compared with the positions of quasi-lines in the photoluminescence spectra of PAHs that were dissolved in acyclic hydrocarbons at a temperature of 77 K and that constitute a polycrystalline solution.     

Unidentified cometary emission lines as the photoluminescence of frozen hydrocarbon particles

We discuss the possible nature of unidentified cometary emission lines. We propose a model of the ice particles in cometary halos as a mixture of frozen polycyclic aromatic hydrocarbons (PAHs) and acyclic hydrocarbons. We describe the general properties of frozen hydrocarbon particles (FHPs) and suggest interpreting some of the unidentified cometary emission lines as the photoluminescence of FHPs. We compare the positions of unidentified emission lines in the spectrum of Comet 122P/de Vico with the positions of quasi-lines in the photoluminescence spectrum of PAHs that were dissolved in acyclic hydrocarbons at a temperature of 77 K and that constituted a polycrystalline solution. We estimate the detectability of FHP photoluminescence in cometary spectra.     

Organic component of cometary ice

Investigations of the luminescence of frozen hydrocarbon particles of icy cometary halo have been made. The process of luminescence of icy particles in shortwavelength solar radiation field is considered. The comparative analysis of observed and laboratory data leads of 72 luminescent emission lines in the spectrum of 153P/Ikeya-Zhang comet. Several aspects of the problem are discussed.     

Mid-infrared imaging of WL 16: the spatial distribution of the hydrocarbon emission features

We present arcsec-resolution images at 8.2, 10.0 and 11.3 μm of the unusual young object WL 16 in Ophiuchus, which has an extended envelope of fluorescing hydrocarbon molecules. To the limit of achieved sensitivity, the faint 10.0-μm continuum has a surface-brightness distribution that is not distinguishable from those at 8.2 and 11.3 μm, where the luminosity is known to be dominated by the polycyclic aromatic hydrocarbon (PAH) emission features. We conclude that the 10-μm continuum either arises from non-equilibrium heating of small dust grains that are well mixed with the hydrocarbons or is quasi-continuous emission from the PAH particles themselves, rather than thermal equilibrium emission from macroscopic dust grains, and that there is no significant silicate absorption variation across the source. The extended hydrocarbon emission may trace a flattened, equatorial distribution of circumstellar material or arise in bipolar lobes. The former case is slightly favoured, based on currently available data, and would imply that WL 16 is a relatively evolved Herbig Ae star, the equatorial plane of which has been almost cleared of normal dust, leaving only fluorescing hydrocarbons and larger coagulated particles as a possibly transient fossil of the original circumstellar disc.     

Frozen hydrocarbon particles of cometary halos as carriers of unidentified emissions

The possible nature of unidentified cometary emissions is under discussion. We propose a new model of the ice particles in cometary halos as a mixture of frozen polycyclic aromatic hydrocarbons and acyclic hydrocarbons. We describe principal properties of frozen hydrocarbon particles (FHPs) and suggest interpreting some of the unidentified cometary emission lines as the photoluminescence of FHPs. The results of comparative analysis are present.     

Microwave emission from aligned dust

Polarized microwave emission from dust is an important foreground that may contaminate polarized CMB studies unless carefully accounted for. We discuss potential difficulties associated with this foreground, namely, the existence of different grain populations with very different emission/polarization properties and variations of the polarization yield with grain temperature. In particular, we discuss observational evidence in favor of rotational emission from tiny PAH particles with dipole moments, i.e. “spinning dust”, and also consider magneto-dipole emission from strongly magnetized grains. We argue that in terms of polarization, the magneto-dipole emission may dominate even if its contribution to total emissivity is subdominant. Addressing polarized emission at frequencies larger than 100 GHz, we discuss the complications arising from the existence of dust components with different temperatures and possibly different alignment properties.     

On the possible luminescence nature of unidentified cometary emissions

New investigations of the photoluminescence of frozen hydrocarbon particles of icy cometary halo have been made. The process of photoluminescence of icy particles in the ultraviolet solar radiation field is considered. The comparative analysis of laboratory and observed data leads to the preliminary identification of some sixty eight photoluminescent emission features in the spectra of 109P/Swift–Tutle and 23P/Brorsen–Metcalf comets. Formulae are given for the calculation of the efficiency of the photoluminescence of icy organic particles in the cometary halo.     

Identification of “small” dust impacts in the Ulysses dust detector data

Since October 1990, 3 weeks after the launch of the Ulysses spacecraft, the dust detector onboard recorded impacts of cosmic dust particles. Besides dust impacts, the detector recorded noise from a variety of sources. So far, a very rigid scheme had been applied to eliminate noise from impact data. The data labeled “big” dust impacts previously led to the identification of interstellar dust and of dust streams from Jupiter. The analysis presented here is concerned with data of signals of small amplitudes which are strongly contaminated by noise. Impacts identified in this data set are called “small” impacts. It is shown that dust impacts can be clearly distinguished from noise for most of the events due to the multi-coincidence characteristics of the instrument. 516 “small” impacts have been identified. For an additional 119 events, strong arguments can be given that they are probably small dust impacts. Thereby, the total number of dust impacts increases from 333 to 968 in the time period from 28 October 1990 to 31 December 1992. This increase permits a better statistical analysis, especially of the Jupiter dust streams which consist mostly of small and fast particles. Additional dust streams have been identified between the already known streams before and after Jupiter flyby. The dependence of the deflection from the Jupiter direction, the stream intensity and width on Jupiter distance support the assertion that they have been emitted from the Jovian system. The masses of the 635 “small” dust particles range from 6 × 10⁻¹⁷ to 3 × 10⁻¹⁰ g with a mean value of 1 × 10⁻¹² g, which compares to a range from 1 × 10⁻¹⁶ to 4 × 10⁻⁹ g with a mean value of 2 × 10⁻¹¹ g for the previously identified 333 “big” dust particles.     

The 3.4-μm absorption feature towards three obscured active galactic nuclei

The results of 3–4-μm spectroscopy towards the nuclei of NGC 3094, 7172, and 7479 are reported. In ground-based 8–13-μm spectra, all the sources have strong absorption-like features at ∼10 μm, but they do not have detectable polycyclic aromatic hydrocarbon (PAH) emission features. The 3.4-μm carbonaceous dust absorption features are detected towards all nuclei. NGC 3094 shows a detectable 3.3-μm PAH emission feature, while NGC 7172 and 7479 do not. Nuclear emission whose spectrum shows dust absorption features but no PAH emission features, is thought to be dominated by highly obscured active galactic nuclei (AGNs) activity. For NGC 7172, 7479, and three other such nuclei in the literature, we investigate the optical depth ratios between the 3.4-μm carbonaceous dust and 9.7-μm silicate dust absorption     The     ratios towards three highly obscured AGNs with face-on host galaxies are systematically larger than the ratios in the Galactic diffuse interstellar medium or the ratios for two highly obscured AGNs with edge-on host galaxies. We suggest that the larger ratios can be explained if the obscuring dust is so close to the central AGNs that a temperature gradient occurs in it. If this idea is correct, our results may provide spectroscopic evidence for the presence of the putative 'dusty tori' in the close vicinity of AGNs.     

The mid-infrared spectrum of the zodiacal and exozodiacal light

The zodiacal light is the dominant source of the mid-infrared sky brightness seen from Earth, and exozodiacal light is the dominant emission from planetary and debris systems around other stars. We observed the zodiacal light spectrum with the mid-infrared camera ISOCAM over the wavelength range 5-16 μm and a wide range of orientations relative to the Sun (solar elongations 68°-113°) and the ecliptic (plane to pole). The temperature in the ecliptic ranged from 269 K at solar elongation 68° to 244 K at 113°, and the polar temperature, characteristic of dust 1 AU from the Sun, is 274 K. The observed temperature is exactly as expected for large (>10 μm radius), low-albedo (<0.08), rapidly-rotating, gray particles 1 AU from the Sun. Smaller particles (<10 μm radius) radiate inefficiently in the infrared and are warmer than observed. We present theoretical models for a wide range of particle size distributions and compositions; it is evident that the zodiacal light is produced by particles in the 10-100 μm radius range. In addition to the continuum, we detect a weak excess in the 9-11 μm range, with an amplitude of 6% of the continuum. The shape of the feature can be matched by a mixture of silicates: amorphous forsterite/olivine provides most of the continuum and some of the 9-11 μm silicate feature, dirty crystalline olivine provides the red wing of the silicate feature (and a bump at 11.35 μm), and a hydrous silicate (montmorillonite) provides the blue wing of the silicate feature. The presence of hydrous silicate suggests the parent bodies of those particles were formed in the inner solar nebula. Large particles dominate the size distribution, but at least some small particles (radii ∼1 μm) are required to produce the silicate emission feature. The strength of the feature may vary spatially, with the strongest features being at the lowest solar elongations as well as at high ecliptic latitudes; if confirmed, this would imply that the dust properties change such that dust further from the Sun has a weaker silicate feature. To compare the properties of zodiacal dust to dust around other main sequence stars, we reanalyzed the exozodiacal light spectrum for β Pic to derive the shape of its silicate feature. The zodiacal and exozodiacal spectra are very different. The exozodiacal spectra are dominated by cold dust, with emission peaking in the far-infrared, while the zodiacal spectrum peaks around 20 μm. We removed the debris disk continuum from the spectra by fitting a blackbody with a different temperature for each aperture (ranging from 3.7″ to 27″); the resulting silicate spectra for β Pic are identical for all apertures, indicating that the silicate feature arises close to the star. The shape of the silicate feature from β Pic is nearly identical to that derived from the ISO spectrum of 51 Oph; both exozodiacal features are very different from that of the zodiacal light. The exozodiacal features are roughly triangular, peaking at 10.3 μm, while the zodiacal feature is more boxy, indicating a different mineralogy.     

IRAS 12311−3509: a carbon star with SiC2 emission

The optical spectrum of the carbon star IRAS 12311−3509 is dominated by the Merrill–Sanford emission bands of SiC₂, by absorption and emission in the Swan system of C₂, and by resonance emission lines of neutral metals. The infrared energy distribution is flat from 1 to 60 μm. These observations are interpreted as arising from a star with a cool dusty disc which is edge-on to the observer and obscures direct starlight. The infrared continuum is caused predominantly by absorption of stellar light by dust in the disc and re-emission at longer wavelengths. The optical stellar spectrum is seen by reflection off dusty material which lies out of the plane of the disc, and the molecular and atomic emission arises in the same geometry through resonance fluorescence. The object has similarities to the J-silicate stars, but may have a carbon-rich rather than oxygen-rich disc. A full spectroscopic assignment and discussion of the SiC₂ bands and their intensities are given. Modelling of the rotational contours of the     band yields a rotational temperature of 250 K, indicating very cool gas.     

The dust coma of Comet P/Giacobini-Zinner in the infrared

We present 1-20 micrometers photometry of P/Giacobini-Zinner obtained at the NASA Infrared Telescope Facility, during 1985 June-September (r = 1.57-1.03 AU). A broad, weak 10 micrometers silicate emission feature was detected on August 26.6; a similar weak emission feature could have been hidden in the broadband photometry on other dates. The total scattering and emitting cross section of dust in the inner coma was similar to that in other short-period comets, but a factor of 10 (r = 1.56 AU) to 100 (r = 1.03 AU) lower than the amount of dust in Comet Halley. The thermal emission continuum can be fit with models weighted toward either small or large absorbing grains. The dust production rate near perihelion was approximately 10(5) g/s (small-grain model) to approximately 10(6) g/s (large-grain model). The corresponding dust/gas mass ratio on August 26 was approximately 0.1-1. A silicate-rich heterogeneous grain model with an excess of large particles is compatible with the observed spectrum of Giacobini-Zinner on August 26. Thus, weak or absent silicate emission does not necessarily imply an absence of silicates in the dust, although the abundance of silicate particles < or = 1 micrometer radius must have been lower than in Comet Halley.     

Polarization models of young stellar objects – II. Linear and circular polarimetry of R Coronae Australis

Near-infrared linear imaging polarimetry of the young stellar objects R CrA and T CrA in the J , H and K n bands, and circular imaging polarimetry in the H band, is presented. The data are modelled with the Clark and McCall scattering model. The R CrA and T CrA system is shown to be a particularly complex scattering environment. In the case of R CrA there is evidence that the wavelength dependence of polarization changes across the nebula. MRN dust grain models do not explain this behaviour. Depolarization by line emission is considered as an alternative explanation. The dust grain properties could also be changing across the nebula.
Although surrounded by reflection nebulosity, there is a region of particularly low polarization surrounding R CrA that is best modelled by the canonical bipolar outflow being truncated by an evacuated spherical cavity surrounding the star. The symmetry axis of the nebula appears inclined by 50° to the plane of the sky.
The H -band circular polarimetry of R CrA clearly shows a quadrupolar structure of positive and negative degrees of circular polarization that reach peak magnitudes of ∼5 per cent within our limited map. It is shown that spherical MRN grains are incapable of producing this circular polarization given the observed linear polarization of the R CrA system. Instead, scattering from aligned non-spherical grains is proposed as the operating mechanism.
T CrA is a more archetypical bipolar reflection nebula, and this object is modelled as a canonical parabolic reflection nebula that lies in the plane of the sky. The wavelength independence of linear polarization in the T CrA reflection nebula suggests that the scattering particles are Rayleigh sized. This is modelled with the MRN interstellar grain size distribution.     

The infrared emission bands. II. A spatial and spectral study of the Orion Bar

We have studied the spectral and spatial distribution across the Orion Bar of the 3-14 micrometers emission, including hydrogen Brackett alpha and 12.8 micrometers [Ne II] emission lines and several "dust" emission features. The data indicate that the "dust" consists of three components; (1) "classical" dust with a temperature of approximately 60 K accounting for emission longward of 20 micrometers, (2) amorphous carbon particles or polycyclic aromatic hydrocarbon (PAH) clusters (approximately 400 C atoms) which produce broad emission features in the 6-9 and 11-13 micrometers bands, and (3) free PAHs which emit in sharper bands (most strongly at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometers). The 3.3 and 11.3 micrometers features, which are due to C-H modes, are well correlated spatially, while the 7.7 micrometers band, due to C=C modes, has a different distribution than the 3.3 and 11.3 micrometers bands. We conclude that the sharp emission bands arise in the photodissociation transition region between the H II region and the molecular cloud and are not present in the H II region. The broad continuum feature extending from 11-13 micrometers is strong in both regions. Previous broad-band observations of the 10 and 20 micrometers flux distributions, which show that the 10 micrometers radiation extends farther into the neutral gas to the south than the 20 micrometers radiation, suggest that some of the 10 micrometers flux is supplied via a nonthermal mechanism, such as fluorescence.     

Hydrodynamic Aspects of Modeling of the Mass Transfer and Coagulation Processes in Turbulent Accretion Disks

This paper considers, in the context of modeling the evolution of a protoplanetary cloud, the hydrodynamic aspects of the theory of concurrent processes of mass transfer and coagulation in a two-phase medium in the presence of shear turbulence in a differentially rotating gas–dust disk and of polydisperse solid particles suspended in a carrying flow of solid particles. The defining relations are derived for diffuse fluxes of particles of different sizes in the equations of turbulent diffusion in the gravitational field, which describe the convective transfer, turbulent mixing, and sedimentation of disperse dust grains onto the central plane of the disk, as well as their coagulation growth. A semiempirical method is developed for calculating the coefficients of turbulent viscosity and turbulent diffusion for particles of different kinds. This method takes into account the inverse effects of dust transfer on the turbulence evolution in the disk and the inertial differences between disperse solid particles. To solve rigorously the problem of the mutual influence of the turbulent mixing and coagulation kinetics in forming the gas–dust subdisk, the possible mechanisms of gravitational, turbulent, and electric coagulation in a protoplanetary disk are explored and the parametric method of moments for solving the Smoluchowski integro-differential coagulation equation for the particles' size distribution function is considered. This method takes into account the fact that this distribution belongs to a definite parametric class of distributions.     

Dynamics of dust in a plasma sheath and injection of dust into the plasma sheath above Moon and asteroidal surfaces

We have examined single dust particle dynamics in a plasma sheath near the surface of solid bodies in space, considering conditions which resemble those of planetary system bodies, when photoelectric effect can be neglected. The forces on the dust particles are assumed to be from the electric field in the sheath and from gravitation only. As the dust particles will charge negatively in the sheath, these forces will act in opposite directions and may balance.The charge delay of a moving dust particle is responsible for many of the interesting dynamical properties, and we show that for a stationary plasma, dust motion is unstable to about one Debye length out from the surface of the solid body. This part of the sheath will therefore be devoid of dust particles as they will either fall down, escape completely from the solid body or collect and make damped oscillations at stable positions in the outer part of the sheath. With increasing plasma bulk speed towards the surface, the inner unstable part of the sheath will decrease in thickness.The sources for the dust in the sheath are assumed to be mainly ejecta from meteorites and micrometeorites, but may also, for the smallest solid bodies, be from electrostatic levitation of very small dust particles. We have for different sizes of solid bodies calculated the sizes of ejecta that can be floated in the sheath. For the solar wind plasma, the suspended dust particles range from less than 1 m for the Moon to about 80 m for an asteroid with radius 1 km. These particles create a dust atmosphere.The results in this paper hold when the dust particle density is so low that the charges on the dust particles do not contribute significantly to the total space charge; a higher density will lead to a modification of the sheath.Our calculations show that ejecta below a certain size will be accelerated in the sheath and totally escape from the body even if they have near zero initial vertical velocity, while ejecta above this size will need a much larger velocity to escape. This is especially significant for the small solid bodies (radius of order km and less) which will therefore act as important sources of micronsized dust. This could be of significance for the dust production and the size distribution of dust in planetary ring systems.     

Airborne and groundbased spectrophotometry of comet P/Halley from 5-13 micrometers

Spectrophotometry from 5-10 micrometers (delta lambda/lambda approximately 0.02) of comet Halley was obtained from the Kuiper Airborne Observatory on 1985 December 12.1 and 1986 April 8.6 and 10.5, UT. 8-13 micrometers data were obtained on 17.2 December 1985 from the Nickel Telescope at Lick Observatory. The spectra show a strong broad emission band at 10 micrometers and a weak feature at 6.8 micrometers. We do not confirm the strong 7.5 micrometers emission feature observed by the Vega 1 spacecraft. The 10 micrometers band, identified with silicate materials, has substructure indicative of crystalline material. The band can be fitted by combining spectra data from a sample of interplanetary dust particles. The primary component of the silicate emission is due to olivine. The 6.8 micrometers emission feature can be due either to carbonates or the C-H deformation mode in organic molecules. The lack of other emission bands is used to place limits on the types of organic molecules responsible for the emission observed by others at 3.4 micrometers. Color temperatures significantly higher than the equilibrium blackbody temperature indicate that small particles are abundant in the coma. Significant spatial and temporal variations in the spectrum have been observed and show trends similar to those observed by the spacecraft and from the ground. Temporal variability of the silicate emission relative to the 5-8 micrometers continuum suggests that there are at least two physically separated components of the dust.     

Strict Limits on the Ionizing Luminosity in NGC 1068 from Jet-Axis Molecular Clouds

The radio jet axis of NGC 1068 is characterised by energetic activity from x-ray to radio wavelengths. Detailed kinematic and polarization studies have shown that this activity is confined to bipolar cones centered on the AGN which intersect the plane of the disk. Thus, molecular clouds at 1 kpc distance along this axis are an important probe of the nuclear ionizing luminosity and spectrum. Extended 10.8μm emission coincident with the clouds is reasonably understood by dust heated to high temperatures by the nuclear radiation field. This model predicts that the nuclear spectrum is quasar-like (power law + blue excess) with a luminosity 2-5 times higher than inferred by Pier et al. (1994). Consequently, there is little or no polyaromatic hydrocarbon (PAH) emission associated with the radio-axis molecular clouds. We review this model in the light of new observations. A multi-waveband collage is included to illustrate the possible orientations of the double cones to our line of sight and the galaxian plane. This revised version was published online in July 2006 with corrections to the Cover Date.     

Composition of cometary dust from polarization spectra

The wavelength dependence of the polarization (“polarization spectra”) of cometary dust is discussed. It is shown that, in the case of large phase angles, the wavelength dependence of the polarization is mainly controlled by the complex refractive index of the particle material, whereas the spectral dependence of the intensity is also sensitive to the size of the particles. This suggests that observations of “polarization spectra” may determine the composition of cometary dust. An attempt is made to find the composition of the cometary dust material by comparing the observed polarimetric data with laboratory measurements of complex refractive indices of possible cometary constituents. Silicates, graphite, metals, organics, water ice and their mixtures are considered. It is shown that astronomical silicate must be the most abundant constituent of cometary dust in the range of heliocentric distances from 0.8 to 1.8 AU, whereas the volume fraction of pure graphite or pure metals is less then 1%. A substance similar to that of F-type asteroids may be present in comets. There is evidence for an organic material that is being destroyed between heliocentric distances of 0.8–1.8 AU.