松辽盆地东南隆起区营城组一段熔浆胶结复成分砾岩特征及其成因分析

对野外剖面实际测量及室内薄片鉴定等资料研究表明,松辽盆地营城组一段复成分砾岩共有4种胶结成岩类型：熔浆胶结、灰泥球胶结、凝灰质胶结和砂泥质胶结。其中以熔浆胶结发育最为广泛。砾岩中砾石成分复杂,以基底花岗岩及二叠系变质岩为主,原地火山岩次之。砾石整体分选性差,磨圆度中等-好,以次圆状-次棱角状最为发育。自基底向火山活动中心,砾岩中外来砾石逐渐减少,原地火山岩砾石逐渐增多。基质成分由底部的砂泥质向上过渡为凝灰质并最终完全过渡到熔浆质胶结。砾岩是冲积扇或辫状河等沉积环境下已经堆积但未固结或半固结的砂砾质沉积物,在火山活动期被火山碎屑流或熔浆流再搬运,这种碎屑流、熔浆流和水介质构成的多相混合物通过岩浆冷凝和压实复合成岩作用而形成的岩石,实质是爆发相热碎屑流亚相的另一种表现形式。由于该类砾岩主要见于断陷盆地边缘火山岩序列下部靠近基底一侧,说明其形成与构造-岩浆活动密切相关,是火山旋回早期所特有的产物。     

对某地熔结凝灰岩中自然铁(α-Fe)的确定及其形成的初步探讨

一、自然铁的产状和特征该矿物产于广西省某地黄铁矿区熔结凝灰岩中,岩石呈褐黑色,具熔结凝灰结构,塑性玻屑和浆屑构成假流纹构造。玻屑和浆屑多数脱玻化后形成水云母、玉髓及铁的氢氧化物的混合物。岩石中含少量黄铁矿、磁黄铁矿和白铁矿。该矿物反光镜下:亮白色、略带淡粉红色色调。呈定     

试论熔结凝灰岩中塑性碎屑内晶质结构的成因

本文在岩相学研究的基础上,将熔结凝灰岩中的各种晶质结构分成两类,即浆屑和塑变玻屑等塑性碎屑中的晶质结构及刚性玻屑和火山微尘中的晶质结构。依据过冷结晶理论,结晶实验成果,本文重点讨论了浆屑和塑变玻屑等塑性碎屑中晶质结构的成因,指出它们不是由脱玻化形成的,而是由过冷结晶形成的。     

地壳深熔条件下的转熔矿物研究进展

地壳深熔作用有两种形式,即流体相缺乏的脱水熔融和流体相存在的加水熔融。由于地壳岩石中水含量的差异(岩石中含水矿物的丰度和外来水的加入量),岩石发生不同形式的部分熔融所需要的温度和压力条件有很大差异。转熔矿物是岩石发生不一致熔融的产物,在形成过程中携带了地壳深熔源区物质和熔体的大量信息,是追溯高温变质岩石经历深熔作用的最可靠依据。它们与高级变质岩中残留的变质矿物和岩浆或熔体中结晶的岩浆矿物具有明显不同的来源,分别代表了岩石曾经历的不同演化历史。通过对不同成因的矿物进行矿物结构、包裹体、主量元素、微量元素和同位素以及共生矿物组合等多方面的综合考察,可以有效识别出高级变质岩中的转熔矿物、变质残余矿物和岩浆矿物。准确识别高温-超高温变质岩以及花岗岩中不同成因的矿物相,是研究高温变质作用的前提条件,对研究混合岩和S型花岗岩的成因都起着非常重要的作用。     

青海南部熔积岩的发现:对寻找VMS型矿床的重要启示

熔积岩指的是侵入、混合到未固结或弱固结的湿沉积物中的熔浆分解、原位形成的一类特殊岩石。正确地认识该类岩石,有利于增进人们对岩浆-水(沉积物)相互作用过程的理解,恢复古环境。在青海南部沱沱河地区发现了一套角砾为撕片状、锯齿状及浑圆状的安山岩,胶结物为铁硅质组合的特殊熔积岩。研究表明,该熔积岩的角砾为岩浆遇水后快速淬火、裂解的产物,铁硅质组合为海底喷气沉积形成的含铁建造;且安山岩与含铁建造发生混合时,含铁建造尚未固结。该套熔积岩的发现,改变了长期以来对开心岭铁矿为火山热液交代安山岩而形成的认识,对于在矿区寻找VMS型矿床、区域内寻找海底热水喷流沉积型矿床具有重要的启示意义。     

吉林南部太古宙TTG岩类的深熔作用及深熔熔体的分凝聚集

研究表明,吉林南部太古宙ＴＴＧ岩类中的部分岩石发生了深熔作用。深熔作用发生于ＴＴＧ岩类遭受高角闪相变质作用条件下,其温度为６６０～６７０℃,压力为０．６ＧＰａ左右。同时南北向韧性剪切变形作用促进了ＴＴＧ岩类的深熔作用,并为深熔体就位提供了主要空间。深熔岩浆分凝聚集结晶形成了淡色块状花网岩类。发生深熔作用的ＴＴＧ岩石和淡色块花网岩类中均有两个世代的矿物组合,第一世代矿物代表ＴＴＧ岩石原有的矿物,第二     

浙江熔结凝灰岩的特征

国内外学者,诸如M.A.彼德罗娃、H.A.塔齐耶夫、陶奎元、周新民、邸瑞和谢家荣等对熔结凝灰岩的特点作过许多独树见解的研究,归纳起来有下列几点:(1)分布面积相当大(数百至数千km~2);(2)厚度、体积亦很大(厚度在数百m,体积在10～100km~3之间);(3)与凝灰岩一样,岩石全由火山碎屑物质组成,成分复杂;(4)有较多的晶屑和岩屑,有时具残余凝友结构;(5)以细粒级多见;(6)存在着大量的火焰石(浆屑)、塑变玻屑和塑变撕屑,由此构成了独具一格的假流纹构造;(7)部分成层性差,部分具良好的柱状和板状节理;(8)通常以酸性、中酸性为主,碱性和中性的较少,基性的罕见,即它的出现与酸度成正比;(9)区域上产于火山构造洼地中,与火山颈和破火     

火山岩中囊状体的特征及其鉴别

熔岩和火山碎屑岩是两类最主要的火山岩,分别代表了两种不同的火山喷发方式和成岩过程,是火山岩分类命名中首先要注意区分的。囊状体具有与浆屑很相似的形态和结构,但对其研究还相当不足,易导致富含囊状体的流纹质—英安质熔岩与富含浆屑的熔结凝灰岩相混淆,产生熔岩与火山碎屑岩分类上的错误。本文首次介绍囊状体的基本特征并分析其与浆屑之区别。囊状体由矿物集合体(结晶内带)和外围脱玻体(脱玻外带)构成,因形态总体似囊状而得名,可呈条带状、透镜状,两端呈撕裂状或须状等,有时也呈斑块状消光和脱玻褪色体;它们是火山岩中微小的高温气相或液相长英质组份结晶、并释热诱发周围玻璃质脱玻形成的一种原生岩石结构。正确区分囊状体和浆屑对火山岩的分类命名及成因研究有重要作用,并避免火山碎屑岩的人为扩大化。     

英安流纹质岩浆的熔离实验

该实验用江西相山英安流纹岩加一定量的氟化物作为初始材料。在温度达875～900℃、压力0.5×10~8～1.0×10~8Pa时,含F和H_2O的英安流纹质岩浆的淬火产物中,有两种玻璃生成。其中一种玻璃呈小球出现,其成分相对富FeO、MgO、TiO_2。另一种玻璃,分布于小球之间,相对富SiO_2和Al_2O_3。实验表明,富含挥发分的酸性火山岩浆是比较容易熔离的。在流纹质火山岩中常见的长英质条带大多数不是浆屑,而是流纹质岩浆熔离的产物。     

河北西北部熔积岩特征及其地质意义

熔积岩是火山碎屑岩的一种特殊类型，由熔浆和未固结的湿沉积物两种组分掺杂混合而成。熔积岩的形成主要受炽热熔浆与未固结的湿沉积物接触时引起的淬碎或蒸汽爆炸作用以及寄主沉积物流体化作用控制，通常分布于熔岩流底部或前缘，也可分布于超浅成侵人体周围。据熔浆碎屑物的结构特征，冀西北熔积岩可分为流状和块状两种类型。流状熔积岩多是熔浆与细粒沉积物混合的结果，块状熔积岩大多与粗粒沉积物相关。正确鉴别熔积岩对确定沉积作用与岩浆作用的时序、研究盆地发展演化历史具有重要意义。     

Liquid immiscibility between trachyte and carbonate in ash flow tuffs from Kenya

Three thin, syn-caldera ash flow tuffs of the Suswa volcano, Kenya, contain pumiceous clasts and globules of trachytic glass, and clasts rich in carbonate globules, in a carbonate ash matrix. Petrographic and textural evidence indicates that the carbonate was magmatic. The trachyte is metaluminous to mildly peralkaline and varies from nepheline- to quartz-normative. The carbonate is calcium-rich, with high REE and F contents. The silicate and carbonate fractions have similar ¹⁴³Nd/¹⁴⁴Nd values, suggesting a common parental magma. Chondrite-normalized REE patterns are consistent with a carbonate liquid being exsolved from a silicate liquid after alkali feldspar fractionation. Sr isotopic and REE data show that the carbonate matrix of even the freshest tuffs interacted to some degree with hydrothermal and/or meteoric water. A liquid immiscibility relationship between the trachyte and carbonate is indicated by the presence of sharp, curved menisci between them, the presence of carbonate globules in silicate glass and of fiamme rich in carbonate globules separated by silicate glass, and by the fact that similar phenocryst phases occur in both melts. It is inferred that the carbonate liquid separated from a carbonated trachyte magma prior to, or during, caldera collapse. Viscosity differences segregated the magma into a fraction comprising silicate magma with scattered carbonate globules, and a fraction comprising carbonate globules in a silicate magmatic host.Explosive disruption of the magma generated silicate-and carbonate-rich clasts in a carbonate matrix. The silicate liquid was disaggregated by explosive disruption and texturally appears to have been budding-off into the carbonate matrix. After emplacement, the basal parts of the flows welded slightly and flattened. The Suswa rocks represent a rare and clear example of a liquid immiscibility relationship between trachyte and carbonate melts.     

The relationship between carbonate facies, volcanic rocks and plant remains in a late Palaeozoic lacustrine system (San Ignacio Fm, Frontal Cordillera, San Juan province, Argentina)

The San Ignacio Fm, a late Palaeozoic foreland basin succession that crops out in the Frontal Cordillera (Argentinean Andes), contains lacustrine microbial carbonates and volcanic rocks. Modification by extensive pedogenic processes contributed to the massive aspect of the calcareous beds. Most of the volcanic deposits in the San Ignacio Fm consist of pyroclastic rocks and resedimented volcaniclastic deposits. Less frequent lava flows produced during effusive eruptions led to the generation of tabular layers of fine-grained, greenish or grey andesites, trachytes and dacites. Pyroclastic flow deposits correspond mainly to welded ignimbrites made up of former glassy pyroclasts devitrified to microcrystalline groundmass, scarce crystals of euhedral plagioclase, quartz and K-feldspar, opaque minerals, aggregates of fine-grained phyllosilicates and fiammes defining a bedding-parallel foliation generated by welding or diagenetic compaction. Widespread silicified and silica-permineralized plant remains and carbonate mud clasts are found, usually embedded within the ignimbrites. The carbonate sequences are underlain and overlain by volcanic rocks. The carbonate sequence bottoms are mostly gradational, while their tops are usually sharp. The lower part of the carbonate sequences is made up of mud which appear progressively, filling interstices in the top of the underlying volcanic rocks. They gradually become more abundant until they form the whole of the rock fabric. Carbonate on volcanic sandstones and pyroclastic deposits occur, with the nucleation of micritic carbonate and associated production of pyrite. Cyanobacteria, which formed the locus of mineral precipitation, were related with this nucleation. The growth of some of the algal mounds was halted by the progressive accumulation of volcanic ash particles, but in most cases the upper boundary is sharp and suddenly truncated by pyroclastic flows or volcanic avalanches. These pyroclastic flows partially destroyed the carbonate beds and palaeosols. Microbial carbonate clasts, silicified and silica-permineralized tree trunks, log stumps and other plant remains such as small branches and small roots inside pieces of wood (interpreted as fragments of nurse logs) are commonly found embedded within the ignimbrites. The study of the carbonate and volcanic rocks of the San Ignacio Fm allows the authors to propose a facies model that increases our understanding of lacustrine environments that developed in volcanic settings.     

地球初期壳幔演化的物理过程

原始地幔处于全球性的高温熔融状态,其上层的冷却演化过程可大致分为3个阶段：高熔点矿物结晶沉降阶段、岩浆不混溶阶段和固化成壳阶段。在此过程中,原始地幔逸出挥发性物质,形成了地球的超临界流体圈。通过岩浆不混溶作用所形成的富Si—Al质岩浆最终固化为原始大陆壳。超临界流体圈的分解,分别形成酸性H2O圈和CO2大气圈。     

Prediction of Liquid Immiscibility in Silicate Melts in Special Reference to Their Free Energies

Currie proposed a cirterion for predicting liquid immiscibility in silicate melts with reference to their free energies efore and after crystal fractionization of a melt.The present authors have calculated the rock analysis data given by Philpotts and proved the validity of Currie‘s method.The authors are particularly interested in the study of immiscibility in the magma in relation with iron deposits.Therefore,they have also calculated the data for artificial silicate melts as well as the data from the famous Kirunavaara iron deposit.     

Multiphase carbonate-salt immiscibility in carbonatite melts: data on melt inclusions from the Krestovskiy massif minerals (Polar Siberia)

Minerals of olivine–melilite and olivine–monticellite rocks from the Krestovskiy massif contain primary silicate-salt, carbonate-salt, and salt melt inclusions. Silicate-salt inclusions are present in perovskite I and melilite. Thermometric experiments conducted on these inclusions at 1,230–1,250°C showed silicate–carbonate liquid immiscibility. Globules of composite carbonate-salt melt rich in alkalies, P, S, and Cl separated in silicate melt. Carbonate salt globules in some inclusions from perovskite II at 1,190–1,200°C separated into immiscible liquid phases of simpler composition. Carbonate-salt and salt inclusions occur in monticellite, melilite, and garnet and homogenize at close temperatures (980–780°C). They contain alkalies, Ca, P, SO₃, Cl, and CO₂. According to the ratio of these components and predominance of one of them, melt inclusions are divided into 6 types: I—hyperalkaline (CaO/(Na₂O+K₂O)≤1) carbonate melts; II—moderately alkaline (CaO/(Na₂O+K₂O)>1) carbonate melts; III—sulfate-alkaline melts; IV—phosphate-alkaline melts; V—alkali-chloridic melts, and VI—calc-carbonate melts. Joint occurrence of all the above types and their syngenetic character were established. Some inclusions demonstrated carbonate-salt immiscibility phenomena at 840–800°C. A conclusion in made that the origin of carbonate melts during the formation of intrusion rocks is related to silicate–carbonate immiscibility in parental alkali-ultrabasic magma. The separated carbonate melt had a complex alkaline composition. Under unstable conditions the melt began to decompose into simpler immiscible fractions. Different types of carbonate-salt and salt inclusions seem to reflect the composition of these spatially isolated immiscible fractions. Liquid carbonate-salt immiscibility took place in a wide temperature range from 1,200–1,190°C to 800°C. The occurrence of this kind of processes under macroconditions might, most likely, cause the appearance of different types of immiscible carbonate-salt melts and lead to the formation of different types of carbonatites: alkali-phosphatic, alkali-sulfatic, alkali-chloridic, and, most widespread, calcitic ones.     

The problem of equilibrium and disequilibrium in thermodynamic methods of analysis of metasomatism dynamics

The compositions of silicic obsidian and perlite glasses do not extend the differentiation trend of the basalt-andesite-rhyolite late orogenic series, but clearly split into distinct sodic and potassic branches, originat-ing through liquid immiscibility in the melts. The contrasting compositions of these glasses are matched by the compositions of spherulites and matrix in silicic lavas, pointing to an origin by liquid immiscibility for these as well.     

Liquid immiscibility in deep-seated magmas and the generation of carbonatite melts

This paper reviews the results of investigations of melt inclusions in minerals of carbonatites and spatially associated silicate rocks genetically related to various deep-seated undersaturated silicate magmas of alkaline ultrabasic, alkaline basic, lamproitic, and kimberlitic compositions. The analysis of this direct genetic information showed that all the deep magmas are inherently enriched in volatile components, the most abundant among which are carbon dioxide, alkalis, halides, sulfur, and phosphorus. The volatiles probably initially served as agents of mantle metasomatism and promoted melting in deep magma sources. The derived magmas became enriched in carbon dioxide, alkalis, and other volatile components owing to the crystallization and fractionation of early high-magnesium minerals and gradually acquired the characteristics of carbonated silicate liquids. When critical compositional parameters were reached, the accumulated volatiles catalyzed immiscibility, the magmas became heterogeneous, and two-phase carbonate-silicate liquid immiscibility occurred at temperatures of ≥1280–1250°C. The immiscibility was accompanied by the partitioning of elements: the major portion of fluid components partitioned together with Ca into the carbonate-salt fraction (parental carbonatite melt), and the silicate melt was correspondingly depleted in these components and became more silicic. After spatial separation, the silicate and carbonate-silicate melts evolved independently during slow cooling. Differentiation and fractionation were characteristic of silicate melts. The carbonatite melts became again heterogeneous within the temperature range from 1200 to 800–600°C and separated into immiscible carbonate-salt fractions of various compositions: alkali-sulfate, alkali-phosphate, alkali-fluoride, alkali-chloride, and Fe-Mg-Ca carbonate. In large scale systems, polyphase silicate-carbonate-salt liquid immiscibility is usually manifested during the slow cooling and prolonged evolution of deeply derived melts in the Earth’s crust. It may lead to the formation of various types of intrusive carbonatites: widespread calcite-dolomite and rare alkali-sulfate, alkali-phosphate, and alkali-halide rocks. The initial alkaline carbonatite melts can retain their compositions enriched in P, S, Cl, and F only at rapid eruption followed by instantaneous quenching.     

微量元素在河北阳原球状黑云辉石正长岩的球体和基体间分配的意义

河北阳原辉石岩-正长岩杂岩体的球状黑云辉石正长岩是岩浆不混熔的产物。本文研究了微量元素、REE在球状岩石的球体相—基体相间的分配。提出控制元素在不混溶的两液相间分配的三种因素,建立了分配系数D_(M/O)~i与不混溶两液相的相对聚合度(NBO/T)_(M/O)之间的函数关系。这些研究可用于区分岩浆不混溶作用与其他作用,确定岩石成因。     

Compositions of magmas and carbonate–silicate liquid immiscibility in the Vulture alkaline igneous complex, Italy

This paper presents a study of melt and fluid inclusions in minerals of an olivine-leucite phonolitic nephelinite bomb from the Monticchio Lake Formation, Vulture. The rock contains 50 vol.% clinopyroxene, 12% leucite, 10% alkali feldspars, 8% hauyne/sodalite, 7.5% nepheline, 4.5% apatite, 3.2% olivine, 2% opaques, 2.6% plagioclase, and < 1% amphibole. We distinguished three generations of clinopyroxene differing in composition and morphology. All the phenocrysts bear primary and secondary melt and fluid inclusions, which recorded successive stages of melt evolution. The most primitive melts were found in the most magnesian olivine and the earliest clinopyroxene phenocrysts. The melts are near primary mantle liquids and are rich in Ca, Mg and incompatible and volatile elements. Thermometric experiments with the melt inclusions suggested that melt crystallization began at temperatures of about 1200 °C. Because of the partial leakage of all primary fluid inclusions, the pressure of crystallization is constrained only to minimum of 3.5 kbar. Combined silicate–carbonate melt inclusions were found in apatite phenocrysts. They are indicative of carbonate–silicate liquid immiscibility, which occurred during magma evolution. Large hydrous secondary melt inclusions were found in olivine and clinopyroxene. The inclusions in the phenocrysts recorded an open-system magma evolution during its rise towards the surface including crystallization, degassing, oxidation, and liquid immiscibility processes.     

广东省梅县嵩溪银锑矿地质特征及成因探讨

根据嵩溪银锑矿V2、V4、V5、V6号矿脉的产状、形态和矿化特征,分析了矿体沉积环境,控矿构造,成矿物质来源等因素,探讨了矿床的成因;初步认为早侏罗系海底安山玄武岩熔浆,沿寨岗上盆地边缘扩张性断裂上涌,在喷溢过程中,大量含Fe、Ag、Sb及多金属元素从喷口溢在富含有机质的局限-半局限海盆中沉积,形成矿源层或矿胚层。由于海盆中不断地接受上涌基性熔浆,在带来新的矿质来源的同时,含矿热水溶液流经含矿层问破碎裂隙,促使矿源层或矿胚层中矿化组分活化、迁移,在有利的物理化学和构造条件下沉淀富集成矿。其矿床成因应属海底火山喷流沉积-热液改造型矿床。