An OSL, radiocarbon and tephra isochron-based chronology for Birdlings Flat loess at Ahuriri Quarry, Banks Peninsula, Canterbury, New Zealand

OSL, radiocarbon dating of pedogenic carbonate and tephrochronology have been used in an attempt to provide a detailed and reliable chronology for Birdlings Flat loess, a thick, proximal loess found on the lower flanks of Banks Peninsula, Canterbury, New Zealand. In a ca 15 m thick section at Ahuriri Quarry the Kawakawa tephra isochron of 26,500 cal. yr BP is identified at a depth of ca. 1.35 m on the basis of glass counting and electron microprobe fingerprinting. Radiocarbon ages of filamentous or root pseudomorph carbonate increase down section from ca. 10,000 cal. yr BP at 2.80 m to ca. 30,000 ¹⁴C yr BP at 10.90 m. Ages from carbonate lining cracks are often out of sequence, indicating deep percolation by bypass flow down preferential flow paths. OSL ages show reversals with respect to each other, carbonate radiocarbon ages, and with the position and accepted age of Kawakawa tephra. Coincident radiocarbon and OSL ages at 3.85 m depth indicate that OSL ages are underestimates by at least 20%. Before OSL can be deemed a high accuracy dating method of the quatzo-feldspathic loess of South Island, New Zealand, more research into the causes of age underestimation and age reversals must be carried out. The last major episode of loess accumulation on the flanks of Banks Peninsula in Canterbury began before ca. 30,000 ¹⁴C yr BP (ca. 35,000 cal. yr BP) and possibly before 43,000 yr based on OSL.     

Comparison of TL multiple aliquot, single grain GLSL SAR and C-14 ages for the Puritjarra, Australia, rock shelter

We report single-grain quartz luminescence ages for the Puritjarra rock shelter, with the aim of resolving an apparent discrepancy between ages obtained by ¹⁴C and a variety of luminescence methods, previously reported. Ages now found at all depths to 75 cm (ages to 30 ka) can be interpreted as largely resolving the differences. This implied caveat arises because single-grain methods are statistically inefficient. As a consequence, a degree of interpretation is inevitable in analysing the data. The emphasis in the present paper is an analysis making use of weighted histograms. The measurements by single grain OSL and ¹⁴C, including ABOX–SC, taken together, can be regarded as compatible. They indicate human occupation of the Puritjarra rock shelter at least as early as 30 ka BP.     

Link between SSZ ophiolite formation, emplacement and arc inception, Northland, New Zealand: U–Pb SHRIMP constraints; Cenozoic SW Pacific tectonic implications

New U–Pb age-data from zircons separated from a Northland ophiolite gabbro yield a mean ²⁰⁶Pb/²³⁸U age of 31.6 ± 0.2 Ma, providing support for a recently determined 28.3 ± 0.2 Ma SHRIMP age of an associated plagiogranite and  29–26 Ma ⁴⁰Ar/³⁹Ar ages (n = 9) of basalts of the ophiolite. Elsewhere, Miocene arc-related calc-alkaline andesite dikes which intrude the ophiolitic rocks contain zircons which yield mean ²⁰⁶Pb/²³⁸U ages of 20.1 ± 0.2 and 19.8 ± 0.2 Ma. The ophiolite gabbro and the andesites both contain rare inherited zircons ranging from 122–104 Ma. The Early Cretaceous zircons in the arc andesites are interpreted as xenocrysts from the Mt. Camel basement terrane through which magmas of the Northland Miocene arc lavas erupted. The inherited zircons in the ophiolite gabbros suggest that a small fraction of this basement was introduced into the suboceanic mantle by subduction and mixed with mantle melts during ophiolite formation.

We postulate that the tholeiitic suite of the ophiolite represents the crustal segment of SSZ lithosphere (SSZL) generated in the southern South Fiji Basin (SFB) at a northeast-dipping subduction zone that was initiated at about 35 Ma. The subduction zone nucleated along a pre-existing transform boundary separating circa 45–20 Ma oceanic lithosphere to the north and west of the Northland Peninsula from nascent back arc basin lithosphere of the SFB. Construction of the SSZL propagated southward along the transform boundary as the SFB continued to unzip to the southeast. After subduction of a large portion of oceanic lithosphere by about 26 Ma and collision of the SSZL with New Zealand, compression between the Australian Plate and the Pacific Plate was taken up along a new southwest-dipping subduction zone behind the SSZL. Renewed volcanism began in the oceanic forearc at 25 Ma producing boninitic-like, SSZ and within-plate alkalic and calc-alkaline rocks. Rocks of these types temporally overlap ophiolite emplacement and subsequent Miocene continental arc construction.     

Formation of Paleoproterozoic eclogitic mantle, Slave Province (Canada): Insights from in-situ Hf and U–Pb isotopic analyses of mantle zircons

In-situ Hf isotope analyses and U–Pb dates were obtained by laser ablation-MC-ICP-MS for a zircon-bearing mantle eclogite xenolith from the diamondiferous Jericho kimberlite located within the Archean Slave Province (Nunavut), Canada. The U–Pb zircon results yield a wide range of ages (2.0 to 0.8 Ga) indicating a complex geological history. Of importance, one zircon yields a U–Pb upper intercept date of 1989 ± 67 Ma, providing a new minimum age constraint for zircon crystallization and eclogite formation. In contrast, Hf isotope systematics for the same zircons display an intriguing uniformity, and corresponding Hf depleted mantle model ages range between 2.1 ± 0.1 and 2.3 ± 0.1 Ga; the youngest Hf model age is within error to the oldest U–Pb date.

The Jericho eclogites have previously been interpreted as representing remnants of metamorphosed oceanic crust, and their formation related to Paleoproterozoic subduction regimes along the western margin of the Archean Slave craton during the Wopmay orogeny. Hf isotope compositions and U–Pb results for the Jericho zircons reported here are in good agreement with a Paleoproterozoic subduction model, suggesting that generation of oceanic crust and eclogite formation occurred between 2.0 and 2.1 Ga. The slightly older Hf depleted mantle model ages (2.1 to 2.3 Ga) may be reconciled with this model by invoking mixing between ‘crustal’-derived Hf from sediments and more radiogenic Hf associated with the oceanic crust during the 2 Ga subduction event. This results in intermediate Hf isotope compositions for the Jericho zircons that yield ‘fictitiously’ older Hf model ages.     

Dating ancient wood by high-sensitivity liquid scintillation counting and accelerator mass spectrometry—Pushing the boundaries

It is critical that a comprehensive terrestrial radiocarbon (¹⁴C) calibration curve is developed beyond 26 ka for high-precision calibration and correlation of climatic, environmental and archaeological records. Abundant sub-fossil New Zealand kauri (Agathis australis) wood, preserved in Oxygen Isotope Stage-2 and 3 peat swamps, provides an important resource for ¹⁴C calibration; nowhere else in the world does such an extensive collection of ancient wood exist. Although finite ¹⁴C ages beyond 50 ka are becoming routinely reported, few attempts have been made to demonstrate their accuracy or precision. Finite ages beyond 50 ka require optimization of all elements involved in sample preparation and ¹⁴C analysis. Here we discuss the methodology employed for optimizing the ¹⁴C dating of near-background wood samples by both benzene synthesis for liquid scintillation counting (LSC) or graphite synthesis for accelerator mass spectrometry (AMS). We report the mean background blank activities for both methods and present a statistical model for assigning blank standard errors when blank activity variation is over and above counting statistics. We also present duplicate analyses (using LSC and AMS) of nine successive samples of wood obtained from a sub-fossil kauri log near-background in age to investigate the significance of the measured blank levels and variability.     

Groundwater recharge and palaeoclimate in the Sirte and Kufra basins, Libya

Stable and radio-isotope results (C, H, O) for groundwaters from the Sirte and northern Kufra basins are used to determine the recharge history during the Holocene and late Pleistocene. Radiocarbon ages have been corrected on the basis of their stable carbon isotope ratios and on environmental samples from the areas, and two groups may be recognised: (1) low ¹⁴C activity groundwaters (13000–34000 yr. BP) with δ ¹³C-5.6 to −11.7‰; and (2) higher ¹⁴C activity groundwaters (5000–7800 yr. BP) enriched in ¹³C up to δ ¹³C = −3.2‰. There is a general correlation of age with depth.

A well defined freshwater (< 50 mg/l Cl⁻) channel can be traced within the aquifer for some 130 km through the region, which is considered to represent recharge from a former wadi. This water with an age of ± 7800 yr. BP is chemically and isotopically distinct from the regional groundwaters and provides direct evidence of a significant recharge event during the Holocene.

The stable isotope (O and H) composition of groundwater from the Kufra and Sirte basins are all related by an evaporative line with slope δ D = 4.5δ ¹³O − 35 with an intercept on the meteoric line of -11‰. This suggests a recharge source continuing into the Holocene from air masses, analogous to current heavy monsoon rain derived from south of the Sahara. The spatial and temporal distribution of groundwaters in relation to the evaporative line suggests a progressive change in character of the recharge which is controlled by a shift towards strongly convective rainfall during the Holocene.

The direct hydrogeological and geochemical evidence supports climatic models proposed by several workers in which discrete humid episodes during the Holocene are inferred.     

Bomb C time history recorded in two modern stalagmites — importance for soil organic matter dynamics and bomb C distribution over continents

Carbon 14 activity measurements made by Accelerator Mass Spectrometry on two modern stalagmites from the Han-sur-Lesse cave (Belgium) and from the Postojna Cave (Slovenia) permit the construction of ¹⁴C activity (a¹⁴C) time series over the last 50 years. A high precision chronology is given by annual laminae in the first stalagmite and by a specific mark (explosion in the Postojna Cave in 1944) in the second one. In both stalagmites, ¹⁴C activity increase due to nuclear tests in the atmosphere is remarkable. However, instead of a sharp peak like the one observed in the atmosphere around 1963–1964, the ¹⁴C activities of the stalagmite CaCO₃ show an abrupt increase, with an offset of 1–10 years, followed by a high activity plateau for the Han-sur-Lesse sample and a slight decrease for the Postojna sample. For both stalagmites, the variation of the a¹⁴C amplitude between pre- and post-bomb period is much lower than the atmospheric record, which demonstrates the damping effect of the soil carbon reservoir. We have modeled the CaCO₃ activities using fractionation processes between atmosphere CO₂, soil CO₂ and organic matter (OM), dissolved inorganic carbon and stalagmite CaCO₃. In both cases studied, the model and former soil studies suggest that CO₂ from soil organic matter (SOM) decomposition, which has a slow turnover (i.e. >1 y), is of major importance in winter, when the development of speleothem is the most important. Combined with the fact that 80–90% of the stalagmite carbon comes from soil CO₂, this produces a damping effect on the speleothem a¹⁴C. Consequently, the ‘geochemical time resolution', at least for speleothem carbon, is much lower than the structural resolution given by annual laminae alternations and is mainly controlled by soil carbon dynamics: a¹⁴C and δ¹³C are smoothed over several years. Differences between the ¹⁴C time series of the Han-sur-Lesse and Postojna stalagmites are likely to be due to the double amount of precipitation in Postojna, which produces a faster soil OM turnover and thus a ‘system' which is more sensitive to atmospheric changes.     

Ice core record of Be over the past millennium from Dome Fuji, Antarctica: A new proxy record of past solar activity and a powerful tool for stratigraphic dating

The cosmogenic nuclide ¹⁰Be was analyzed by using accelerator mass spectrometry on an ice core drilled at the Dome Fuji station, inland Antarctica, for 700–1900 yr CE. The measured concentration of ¹⁰Be in the Dome Fuji ice core and the derived ¹⁰Be flux show similar fluctuations, with both increasing at known solar-activity minima over the last millennium in agreement with earlier observations of ¹⁰Be and ¹⁴C. Based on the similar nature of the ¹⁰Be flux to the reconstructed ¹⁴C production rate patterns, a ¹⁰Be–¹⁴C correlation age model for the Dome Fuji ice core was successfully constructed. This age model agrees well with the initial version of the tephrochronology of the core. The ¹⁰Be-flux record contains information on variability in the amount of cosmic radiation incident on the atmosphere, which is mainly attributable to high-frequency change in solar activity and low-frequency background intensity adjustment of the geomagnetic field. High-resolution ¹⁰Be analyses of the Dome Fuji ice cores promise to provide potentially important information on the history of cosmic radiation intensity over the past several hundred thousand years.     

Establishing a chronology for lacustrine sediments using a multiple dating approach—A case study from the Frickenhauser See, central Germany

In order to establish a reliable chronology for lacustrine sediments of the Frickenhauser See (central Germany) different dating methods have been applied. A total of 17 AMS ¹⁴C dates, all within the last 2000 years, were supplemented with ¹³⁷Cs/²¹⁰Pb dating and varve counting of the uppermost sediments (131 years). The age–depth model for the Frickenhauser See has to cope with highly variable sedimentation rates and overlapping probability distributions of calibrated ¹⁴C dates. The uncertainty of calibrated ¹⁴C dates could be considerably reduced by including the stratigraphic relationship of the dated samples, the age information derived from short-lived isotopes and varve counting as well as an upper and lower limit of realistic sedimentation rates as ‘a priori’ information in the calibration procedure. Sets of possible age combinations obtained by repeated sampling from the modified probability distributions were used to calculate continuous age–depth relationships based on monotonic smoothing splines. The obtained age–depth model for the sediment record of the Frickenhauser See represents the average of over 16,000 such model runs and suggests a drastic increase in sedimentation rates from around 1–2 mm a⁻¹ (200–1000 AD) to over 25 mm a⁻¹ for the period between 1100 and 1300 AD. From then on, sedimentation rates exhibit relatively stable values around 3–9 mm a⁻¹. ‘Conventional’ age–depth models such as general polynomial regression or cubic splines either do not include the obtained age-information in a satisfying manner (the model being too “stiff”) or exhibit “swings” causing age-reversals in the model. Although the age–depth relationships obtained for monotonic smoothing splines and mixed-effect regression are generally very similar, they differ in their respective sedimentation rates as well as in their uncertainties. Mixed-effect regression resulted in much higher sedimentation rates of more than 37 mm a⁻¹. These results suggest that monotonic smoothing splines give better control of the age–depth model characteristics and are well suited in situations, where the integrity of ¹⁴C dates is high, i.e. the dated material represents the age of the respective layer.     

Isotope geochemistry of Pantelleria volcanic fluids, Sicily Channel rift: a mantle volatile end-member for volcanism in southern Europe

Chemical and isotopic ratio (He, C, H and O) analysis of hydrothermal manifestations on Pantelleria island, the southernmost active volcano in Italy, provides us with the first data upon mantle degassing through the Sicily Channel rift zone, south of the African–European collision plate boundary. We find that Pantelleria fluids contain a CO₂–He-rich gas component of mantle magmatic derivation which, at shallow depth, variably interacts with a main thermal (100°C) aquifer of mixed marine–meteoric water. The measured ³He/⁴He ratios and δ¹³C of both the free gases (4.5–7.3 R_a and −5.8 to −4.2‰, respectively) and dissolved helium and carbon in waters (1.0–6.3 R_a and −7.1 to −0.9‰), together with their covariation with the He/CO₂ ratio, constrain a ³He/⁴He ratio of 7.3±0.1 R_a and a δ¹³C of ca. −4‰ for the magmatic end-member. These latter are best preserved in fluids emanating inside the active caldera of Pantelleria, in agreement with a higher heat flow across this structure and other indications of an underlying crustal magma reservoir. Outside the caldera, the magmatic component is more affected by air dilution and, at a few sites, by mixing with either organic carbon and/or radiogenic ⁴He leached from the U–Th-rich trachytic host rocks of the aquifer. Pantelleria magmatic end-member is richer in ³He and has a lower (closer to MORB) δ¹³C than all fluids yet analyzed in volcanic regions of Italy and southern Europe, including Mt. Etna in Sicily (6.9±0.2 R_a, δ¹³C=−3±1‰). This observation is consistent with a south to north increasing imprint of subducted crustal material in the products of Italian volcanoes, whose He and C (but also O and Sr) isotopic ratios gradually evolve towards crustal values northward of the African–Eurasian plate collision boundary. Our results for Pantelleria extend this regional isotopic pattern further south and suggest the presence of a slightly most pristine or ‘less contaminated’, ³He-richer mantle source beneath the Sicily Channel rift zone. The lower than MORB ³He/⁴He ratio but higher than MORB CO₂/³He ratio of Pantelleria volatile end-member are compatible with petro-geochemical evidence that this mantle source includes an upwelling HIMU–EM1-type asthenospheric plume component whose origin, according to recent seismic data, may be in the lower mantle.     

Landscape development in an hyperarid sandstone environment along the margins of the Dead Sea fault: Implications from dated rock falls

In this study, we explored the spatial and temporal relations between boulders and their original in-situ locations on sandstone bedrock cliffs. This was accomplished by combining field observations with dating methods using cosmogenic isotopes (¹⁰Be and ¹⁴C) and optically stimulated luminescence (OSL). Our conclusions bear both on the landscape evolution and cliff retreat process in the hyperarid region of Timna and on the methodology of estimating exposure ages using cosmogenic isotopes.

We recognize three discrete rock fall events, at 31 ka, 15 ka, and 4 ka. In this hyperarid region, the most plausible triggering mechanism for rock fall events is strong ground acceleration caused by earthquakes generated by the nearby Dead Sea fault (DSF). Our record, however, under represents the regional earthquake record implying that ongoing development of detachment cracks prior to the triggering event might be slower than the earthquake cycle.

Cliff retreat rates calculated using the timing of rock fall events and estimated thickness of rock removed in each event range between 0.14 m ky^− 1 and 2 m ky^− 1. When only full cycles are considered, we derive a more realistic range of 0.4 m ky^− 1 to 0.7 m ky^− 1. These rates are an order of magnitude faster than the calculated rate of surface lowering in the area. We conclude that sandstone cliffs at Timna retreat through episodic rock fall events that preserve the sharp, imposing, landscape characteristic to this region and that ongoing weathering of the cliff faces is minor.

A 10%–20% difference in the ¹⁰Be concentrations in samples from matching boulder and cliff faces that have identical exposure histories and are located only a few meters apart indicates that cosmogenic nuclide production rates are sensitive to shielding and vary spatially over short distances. However, uncertainties associated with age calculations yielded boulder and matching cliff face ages that are similar within 1 σ . The use of external constraints in the form of field relations and OSL dating helped to establish each pair's age. The agreement between calculated ¹⁴C and ¹⁰Be ages indicates that the accumulation of ¹⁰Be at depth by the capture of slow deep-penetrating muons was properly accounted for in the study.     

Ages and composition of gas trapped in Allan Hills and Byrd core ice

Gas is extracted from large (6–31 kg) Antarctic ice samples to obtain sufficient CO₂ for¹⁴C measurements with small low-level proportional counters. The¹⁴C ages of Byrd core ice are in accord with glaciological estimates ranging from (2.2_−1.1^+1.4)×10³ yr at 271 m depth to more than 8 × 10³ yr at 1071 m depth. The CO₂ abundances in gas extracted from Byrd core ice range from 0.0216 to 0.051%, with below present-day atmosphere CO₂ abundances for ice from 1068 and 1469 m depths. The CO₂ abundance in gas from Allan Hills surface ice samples ranges between four and six times the atmospheric value and the CO₂ had a specific activity three times that of contemporary carbon. A possible explanation for the anomalously high specific activity is surface melting with the incorporation into CO₂ of¹⁴C produced by cosmic ray spallation of oxygen in ice. The CO₂ abundance in gas extracted from subsurface Allan Hills ice ranged from 0.030 to 0.065%, and the specific activities are below contemporary carbon, indicating ages greater than 5×10³ yr. The¹⁸O/¹⁶O ratio of oxygen in the trapped gas is the same as that of atmospheric oxygen and differs markedly from the¹⁸O/¹⁶O ratio in the ice. The O₂, N₂, and Ar abundances and isotopic compositions are similar to those in contemporary air, except for positive¹⁵N/¹⁴N ratios in a few samples.     

Holocene thermal optimal and climate variability of East Asian monsoon inferred from forest reconstruction of a subalpine pollen sequence, Taiwan

The East Asian monsoon Holocene optimal period has been debated both about duration and whether conditions were a maximum in thermal conditions or in precipitation. In this study we show Holocene climate variability inferred by a forest reconstruction of a subalpine pollen sequence from peat bog deposits in central Taiwan, based on modern analogues of various altitudinal biomes in the region. A warmer interval occurred between 8 and 4 ka BP (calibrated ¹⁴C years) when the subtropical forests were more extensive. The Holocene thermal optimum is represented by an altitudinal tropical forest at 6.1–5.9 ka BP and 6.9 ka BP and only the latter was accompanied by wet conditions, indicating decoupling of thermal and precipitation mechanism in the middle Holocene. Abrupt and relative severe cold phases, shown by biome changes, occurred at about 11.2–11.0 ka BP; 7.5 ka BP; 7.2 ka BP; 7.1 ka BP; 5.2 ka BP, 5.0 ka BP and 4.9 ka BP. A spectral analysis of pollen of a relatively cold taxon — Salix, reveals that the time series is dominated by a 1500 yr periodicity and similar to the cold cycle reported in the marine records of Indian and western Pacific Oceans. The cold–warm conditions inferred by the change of forests show close relationship to solar energy in comparison with the production rate of Be-10.     

Ra or Ra/Ba dating of Holocene volcanic rocks: application to Mt. Etna and Merapi volcanoes

This paper shows how ²²⁶Ra–²³⁰Th disequilibria can be used to date Holocene volcanic rocks from some well selected volcanoes. A systematic study of these disequilibria on historical or well-dated volcanic samples is indeed first required to test the applicability of this method. Two examples are described here to illustrate its potential. In the case of Mt. Etna, the good correlation observed between (²²⁶Ra)₀ activities at the time of eruption and Th contents in lava flows from the last two millennia [M. Condomines, J.C. Tanguy, V. Michaud, Magma dynamics at Mt. Etna: constraints from U–Th–Ra–Pb radioactive disequilibria and Sr isotopes in historical lavas, Earth Planet. Sci. Lett. 132 (1995) 25–41] is used to infer the ages of several newly analysed lava flows. The calculated ages are in good agreement with those deduced from the archaeomagnetic curve describing the variation of the geomagnetic field direction in southern Italy [J.C. Tanguy, I. Bucur, J.F.C. Thompson, Geomagnetic secular variation in Sicily and revised ages of historic lavas from Mt. Etna, Nature 318 (1985) 453–455, J.C. Tanguy, M. Le Goff, V. Chillemi, A. Paiotti, C. Principe, S. La Delfa, G. Patane, Variation séculaire de la direction du champ géomagnétique enregistrée par les laves de l'Etna et du Vésuve pendant les deux derniers millénaires, C. R. Acad. Sci. Paris 329 (1999) 557–564, J.C. Tanguy, M. Le Goff, C. Principe, S. Arrighi, V. Chillemi, A. Paiotti, S. La Delfa, G. Patane, Archaeomagnetic dating of Mediterranean volcanics of the last 2100 years: validity and limits. Earth Planet. Sci. Lett. 211 (2003) 111–124]. We also present a whole set of new U-series data on historical, recent, and older samples from Merapi (Indonesia), and show that the (²²⁶Ra)/Ba ratio has probably maintained a quasi-steady state value during at least the past four millennia, and can be used to infer the (²²⁶Ra)₀/Ba ratio of old volcanics at the time of eruption, and thus their ages. Comparison with ¹⁴C ages available on three samples [R. Gertisser, J. Keller, Temporal variations in magma composition at Merapi volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity, J. Volcanol. Geotherm. Res. 123 (2003) 1–23] shows an excellent agreement. These dating methods, based on the post-eruptive decrease of ²²⁶Ra excesses can be confidently used to date young rocks on both volcanoes, an important step to infer their recent eruptive history and magmatic evolution. It also opens the possibility to extend the geomagnetic field variation curve back into the past few millennia. The promising results obtained in this work should encourage new systematic U-series studies to test the applicability of such methods to other permanently active volcanoes showing ²²⁶Ra excesses.     

Anomalously nucleogenic neon in North Chile Ridge basalt glasses suggesting a previously degassed mantle source

Fresh basalt glasses from the North Chile Ridge (NCR) in the southeastern Pacific have Ne isotopic compositions distinctly different from typical mid-ocean ridge basalts (MORB). In a three-isotope plot of ²⁰Ne/²²Ne vs. ²¹Ne/²²Ne, the NCR data define a correlation line with a slope smaller than that of the MORB correlation line, i.e. their Ne composition is more nucleogenic than that of MORB. ³He/⁴He ratios are slightly lower than the MORB average, whereas in a few stepwise heating fractions very high ⁴⁰Ar/³⁶Ar ratios up to 28,000 are found. One model to explain the data assumes contamination of the NCR mantle source by material from the continental or oceanic crust, but in addition to difficulties with quantitatively reconciling the noble gas patterns with such a model it seems unable to account for some geochemical characteristics of NCR basalts reported earlier [Bach et al., Earth Planet. Sci. Lett. 142 (1996) 223–240], such as depletions in highly incompatible elements and unradiogenic Sr isotope compositions. Therefore we favor the scenario of a mantle source which was depleted and degassed previously, possibly as a residue from mantle melting beneath the southern East Pacific Rise that was transported to the NCR and melted again. The time during which such a depleted reservoir would have to be separated from the MORB mantle is estimated at 10–100 Ma based on U/Th–Ne systematics, in reasonable agreement with the time scale deduced from the formation history of the NCR and the temporal evolution of the southeast Pacific.     

OSL chronology for a sediment core from the southern Baltic Sea: A continuous sedimentation record since deglaciation

A chronology based on optically stimulated luminescence (OSL) dating is presented for the late- and post-glacial evolution of the southern Baltic Sea (15 ka to present). During this period, large water level and salinity changes occurred in the Baltic Basin due to opening and closing of connections to the North Atlantic. Previous attempts to establish a chronology for these palaeoenvironmental changes have mainly been conducted in coastal settings where organic material for ¹⁴C dating is abundant. Many of these records are, however, discontinuous due to the large water level fluctuations. In contrast, in the relatively deep water of the Arkona Basin, the sediment record is expected to be more or less continuous. The single aliquot regenerative dose (SAR) procedure was used to date 32 samples of fine quartz sand from a 10.86 m long sediment core from the centre of this basin (45 m water depth). Tests of luminescence characteristics confirmed the suitability of the material for OSL dating and the ages agree well with the available AMS ¹⁴C ages on shells. The Baltic Ice Lake drainage to the North Atlantic appears to occur 11.6 ka, agreeing with other published evidence. However, we suggest that the main marine Littorina transgression appears in the Arkona Basin at about 6.5 ka, rather than at 8.5 ka, as previously thought.     

REVIEW ON IN-SITU COSMOGENIC 14C DATING AND POTENTIAL APPLICATION IN PALEOEARTHQUAKE

Over the last two decades, in-situ cosmogenic ¹⁴C dating has become an import tool in Quaternary geology and is recognized to geoscientists because of its potential to provide information on exposure age and process rate estimates for geomorphic studies. The in-situ cosmogenic radiocarbon has a relatively short half-life(5730 yr)and is substantially more sensitive than all the other cosmogenic nuclides used so far. It is therefore particularly useful to determine surface-exposure ages of Holocene landforms and quantify erosion rates in rapidly denuding landscapes during the past few tens of thousands of years. Moreover, in situ ¹⁴C is produced in quartz which is both highly resistant to weathering and common in nature, so it can be used in combination with other in-situ cosmogenic nuclides such as ³He, ¹⁰Be,²¹Ne,²⁶Al, and ³⁶Cl to constrain complex exposure histories involving burial and/or erosion occurring over the past 25ka. The age and slip rate of Holocene normal fault have been undoubtedly a challenge for seismologists to be faced with as result from lack of appropriate late Quaternary sediment. Recently, the cosmogenic nuclides such as ³⁶Cl of preserved, seismically exhumed normal fault scarps were used to identify the last few major earthquakes and recover their ages and displacements through the modeling of the content of ³⁶Cl in the scarp rocks. This paper mainly summarizes the development of in-situ ¹⁴C dating, including its research history, production rate estimate, production mechanism, chemical behavior and experimental method. The potential application of in-situ ¹⁴C dating to recovering past earthquakes, their timing, and the regularity of their recurrence for preserved, seismically exhumed normal fault scarps is also introduced.     

Solar modulation of cosmogenic nuclide production over the last millennium: comparison between C and Be records

For about the last 30 years it has been recognized that the high frequency component of the tree rings ¹⁴C/¹²C record is dominated by the modulation of the cosmic ray flux by the solar wind. In particular, it has been demonstrated that the three most recent periods of low sunspot occurrence were characterized by high values of atmospheric ¹⁴C/¹²C. During the last millennium other periods of high ¹⁴C/¹²C values were observed but their solar origin is still debatable. In the present work we compare these fluctuations with an independent record of cosmogenic ¹⁰Be measured in ice from the South Pole to check the solar origin of the observed ¹⁴C/¹²C variations. In order to compare quantitatively the results obtained on ¹⁰Be and ¹⁴C, it is necessary to take into account the different behaviour of these two cosmogenic isotopes, and especially the damping effect of the carbon cycle in the case of ¹⁴C. As an input to a 12-box numerical model we used the relative fluctuations of the ¹⁰Be concentrations record measured in South Pole ice and converted it into a synthetic ¹⁴C record. We took into account the fact that ¹⁰Be modulation is enhanced in polar regions due to the orientation of the geomagnetic field. As expected, the fluctuations of the modelled ¹⁴C record are much smaller (a factor of 20) than those observed for the raw ¹⁰Be record. In addition, the variations are smoother and shifted in time by a few decades. The ¹⁰Be-based ¹⁴C variations closely resemble the ¹⁴C measurements obtained on tree rings (R = 0.81). In particular, it is easy to identify periods of maximal ¹⁴C/¹²C which correspond to solar activity minima centred at about 1060, 1320 (Wolf), 1500 (Spörer), 1690 (Maunder) and 1820 (Dalton) yr A.D. Cross-correlation calculations suggest that there is no significant lag between the ¹⁰Be-based ¹⁴C and the tree-ring ¹⁴C records. Our study strongly suggests the dominance of the solar modulation on the cosmonuclide production variations during the last millennium.     

Annual and seasonal fluctuations of precipitation and streamflow in the Aconcagua River basin, Chile

The El Niño-Southern Oscillation (ENSO) phenomenon has been shown to influence dramatically precipitation and streamflow in tropical western South America. The statistical properties of annual and winter precipitation totals and streamflow characteristics in the Aconcagua River basin, in temperate central Chile, are investigated in such a way as to permit the identification of flood- and drought-generating processes and their possible linkages to upset behavior in the tropical Pacific. Despite the considerable distance to those regions generally associated with ENSO events, the phenomenon produces marked effects upon the various physical processes which govern the surface hydrometeorology of the study area. El Niño years result in significant increases in annual and winter precipitation, particularly along the coastal margin. The likelihood of rain or rain-on-snow flooding, in the succeeding winter, increases, as does the size of spring snowmelt in the southern summer, 1 year after the upset conditions in the tropical region. Annual low flows are of higher magnitude and occur earlier in the year than is usual.     

Alkaline syenites in eastern Cathaysia (South China): link to Permian–Triassic transtension

Two alkaline syenite plutons, the Tieshan and Yangfang plutons, have recently been recognized within NE-trending fault zones in eastern Cathaysia, South China. The rocks are very enriched in K₂O (6.28–9.39 wt.%), rare earth elements (REE; particularly light REE) and large ion lithophile elements, but are relatively low in high field strength elements. Isotopically, they are characterized by high initial ⁸⁷Sr/⁸⁶Sr (0.7093 to 0.7123) and low _Nd(t) values (−5.64 to −10.63). The geochemical data suggest that the alkaline syenites most likely formed via fractional crystallization of enriched mantle-derived magmas. Sensitive High-Resolution Ion Microprobe zircon U–Pb dating indicates that these two intrusions have Late Permian (254±4 Ma) and Early Triassic (242±4 Ma) crystallization ages, respectively. Our data suggest that a tectonic regime dominated by transtension probably existed from at least the latest Permian into the Triassic and was responsible for the formation of the Tieshan and Yangfang alkaline syenites. When combined with previous paleomagnetic, structural, and sedimentology data, we suggest that the transtension along the NE-trending strike-slip fault zones was related to oblique subduction of the Pacific plate underneath South China.