U.S.G.5. II Revisited*

Based on the most recent compilation of analytical data, a new set of “usable values” is calculated for six of the best known silicate rock reference samples produced by the U.S. Geological Survey. The latest version of the “best laboratories” method is described and results are compared with other recently published values.     

Recent developments and the future of low‐T calorimetric investigations in the Earth sciences: Consequences for thermodynamic calculations and databases

Low‐T calorimetry is an experimental science that measures the thermodynamic function heat capacity, C_p(T), from which the standard third‐law entropy (298.15 K), S°, is calculated. The recent technological development of relaxation calorimetry allows both new experimental strategies and types of C_p investigations to be made, which were previously not possible. The C_p measurements are fast and automated and can be made on mg‐sized mineralogical samples between 2 and 400 K. These advantages, when careful measurement procedures are used, permit better determinations of C_p(T) behaviour. The C_p of synthetic single‐crystal MgO was measured between 5 and 302 K, and S° calculated using relaxation calorimetry to further investigate the method's precision and accuracy. A number of synthetic and natural end‐member or nearly end‐member compositions of silicate garnet were investigated in the past via adiabatic calorimetry, an old and established technique, and more recently and extensively with the relaxation method. First C_p(T) and S° results, using relaxation calorimetry, have been obtained on spessartine (Mn₃Al₂Si₃O₁₂) and knorringite (Mg₃Cr₂Si₃O₁₂). Furthermore, reinvestigations on pyrope (Mg₃Al₂Si₃O₁₂), almandine (Fe₃Al₂Si₃O₁₂), grossular (Ca₃Al₂Si₃O₁₂) and andradite (Ca₃Al₂Si₃O₁₂), often on multiple samples, have resolved uncertainties and certain problems with published thermodynamic data. S° can be affected by various low‐T physical phenomena, such as cooperative magnetic phase transitions or Schottky anomalies at temperatures of <15 K, which were not described fully in some older adiabatic calorimetric studies. New C_p results show that small differences in the thermodynamic behaviour between some natural and synthetic silicates may exist as demonstrated by extensive work on grossular. Important and “new” research questions on the thermodynamic behaviour of minerals are coming to light and are being investigated. The C_p behaviour and S° values for six silicate garnet end‐members are analysed and the latter are compared to the “best fit or optimized” S° values given in various internally consistent thermodynamic databases. Conclusions are drawn on what types and directions of calorimetric study are required in order to obtain better thermodynamic property determinations of minerals, as well as achieving a better understanding of the underlying microscopic physical behaviour that determines the macroscopic C_p and S° functions.     

U – Pb zircon ages from leucogneiss in the Etheridge Group and their significance for the early history of the Georgetown region,north Queensland

The Timbarra Tablelands pluton is an extensive (～550 km²) complexly zoned intrusion forming one of many predominantly monzogranite I‐type plutons, which constitute the Moonbi Supersuite in northern New South Wales, Australia. It comprises an outer rim of Rocky River monzogranite (Zones 1–3), an intermediate zone of Sandy Creek syenogranite (Zones 4A–4C), surrounding a core of Surface Hill syenogranite (Zones 5–7). The suite is calc‐alkaline, high‐K, and varies from mildly metaluminous to weakly peraluminous with increasing fractionation. Average Rb/Sr ratios range from 0.4 in the least evolved very coarse‐grained monzogranite (Zone 3) to 46 in the most evolved very fine‐grained biotite microgranite (Zone 6). Trace‐element modelling indicates that the observed compositional variation could have been produced by crystal fractionation. New bulk rock major‐ and trace‐element data for 71 samples are presented, and indicate that a compositional continuum exists that varies between 63 and 78 wt% SiO₂. Importantly, there is no systematic chemical variation with spatial distribution of samples from the core of the pluton to its margin, requiring multiple separate pulses of an evolving magma to explain compositional discontinuities. The pluton is interpreted to have been emplaced at mesozonal levels (～180 ± 60 MPa, 5–10 km depth) and crystallised at temperatures between 620 and 820°C under moderately oxidising conditions (log fO₂ = ‐11.5 to ‐19). The association of gold‐molybdenite mineralisation at Timbarra with moderately oxidised I‐type magmas is consistent with fractionation‐redox controls on ore‐element behaviour in magmatic systems in other studies.     

Visco‐elastic load transfer models for axially loaded piles

Viscoelastic or creep behaviour can have a significant influence on the load transfer (t–z) response at the pile–soil interface, and thus on the pile load settlement relationship. Many experimental and theoretical models for pile load transfer behaviour have been presented. However, none of these has led to a closed‐form expression which captures both non‐linearity and viscoelastic behaviour of the soil. In this paper, non‐linear viscoelastic shaft and base load transfer (t–z) models are presented, based on integration of a generalized viscoelastic stress–strain model for the soil. The resulting shaft model is verified through published field and laboratory test data. With these models, the previous closed‐form solutions evolved for a pile in a non‐homogeneous media have been readily extended to account for visco‐elastic response. For 1‐step loading case, the closed‐form predictions have been verified extensively with previous more rigorous numerical analysis, and with the new GASPILE program analysis. Parametric studies on two kinds of commonly encountered loading: step loading, ramp (linear increase followed by sustained) loading have been performed. Two examples of the prediction of the effects of creep on the load settlement relationship by the solutions and the program GASPILE, have been presented. Copyright © 2000 John Wiley & Sons, Ltd.     

Distribution Characteristics and Accumulation Model for the Coal‐formed Gas Generated from Permo‐Carboniferous Coal Measures in Bohai Bay Basin,China: A Review

Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin, offshore eastern China. However, the proven gas reserves from this source rock remain low to date, and the distribution characteristics and accumulation model for the coal-formed gas are not clear. Here we review the coal-formed gas deposits formed from the Permo-Carboniferous coal measures in the Bohai Bay Basin. The accumulations are scattered, and dominated by middle-small sized gas fields, of which the proven reserves ranging from 0.002 to 149.4×108 m3 with an average of 44.30×108 m3 and a mid-point of 8.16×108 m3. The commercially valuable gas fields are mainly found in the central and southern parts of the basin. Vertically, the coal-formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic, among which the Paleogene and PermoCarboniferous are the main reservoir strata. According to the transporting pathway, filling mechanism and the relationship between source rocks and reservoir, the coal-formed gas accumulation model can be defined into three types: "Upward migrated, fault transported gas" accumulation model, "Laterally migrated, sandbody transported gas" accumulation model, and "Downward migrated, sub-source, fracture transported gas" accumulation model. Source rock distribution, thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal-formed gas. The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.     

Glacier Relics of the Last Glacial and Holocene Periods Discovered in the Middle‐low Mountains of Eastern China: Sedimentary Sequences and Environmental Evolution of Mengshan Mountain in Shandong Province since 80 ka

The goal of this research study is to describe academic issues which have been debated in the field of Chinese geosciences for a century. In 1922, Jonquei S. Lee(Li Siguang) discovered Quaternary glacial relics at Taihang Mountainin eastern China. In 1947, he published his research findings in the magazine Mount Lushan in Glacial Age. The research results had established three Ice Ages: Poyang(Gonzi), Dagu(Minde), and Lushan(Lisi). However, at that time, no Wurm glacial relics of the last Ice Age had been found in Lushan Mountain. Since then, the research team represented by Shi Yafeng, who is considered to be "the father of glaciers in China", questioned Jonquei S. Lee's research results and concluded that "Professor Jonquei S. Lee's Quaternary glacier research in Lushan Mountain having misread the debris flow". In 2005, the "middle-low mountains" in eastern China were finally defined as follows: "We clearly and unambiguously believe that there were no glacial activities in the middle-low mountainous areas of eastern China(east of 102° to 104°E; below 3,000 and 2,500 m) during the Quaternary Period". Currently, the long-standing academic debate appears to have come to a conclusion. As of 2015, the author and others began to investigate and study the Quaternary glacial relics in Mengshan Mountain(1,156 m above sea level), Shandong Province, one of the "middle-low mountains" of eastern China. The relics have been observed to posses the systematic features of glacial erosion, trough and valley striations, and moraine deposits. The applied dating method shave confirmed that there were not only glacial relics of the last Ice Age(Wurm), but also Holocene glacial relics in the Mengshan Mountain area. Therefore, in order to further establish the corresponding relationship between the glacier, loess, stream sediment series, and MIS in the Mengshan Mountain area, a large number of chronological studies have been carried out regarding the various types of sediments in the area, and 24 dating datahave been obtained using OSL, CRN, and 14 Cmethods.On this basis, the corresponding relationship between the sedimentary sequences and the MIS was established for the first time in eastern China, which in dicates the environmental changes which had occurred in eastern China since 80 ka. These discoveries s and chronological study results confirm the existence of the Last Ice Age, as well as Holocene glacial relics at Mengshan Mountain, there by confirming that Quaternary glaciation had occurred in the middle-low mountain areas of eastern China.     

Petrological,geochemical and geochronological evidence for a Neoproterozoic ocean basin recorded in the Marlborough terrane of the northern New England Fold Belt

Petrological, geochemical and radiogenic isotopic data on ophiolitic‐type rocks from the Marlborough terrane, the largest (～700 km²) ultramafic‐mafic rock association in eastern Australia, argue strongly for a sea‐floor spreading centre origin. Chromium spinel from partially serpentinised mantle harzburgite record average Cr/(Cr + Al) = 0.4 with associated mafic rocks displaying depleted MORB‐like trace‐element characteristics. A Sm/Nd isochron defined by whole‐rock mafic samples yields a crystallisation age of 562 ± 22 Ma (2σ). These rocks are thus amongst the oldest rocks so far identified in the New England Fold Belt and suggest the presence of a late Neoproterozoic ocean basin to the east of the Tasman Line. The next oldest ultramafic rock association dated from the New England Fold Belt is ca530 Ma and is interpreted as backarc in origin. These data suggest that the New England Fold Belt may have developed on oceanic crust, following an oceanward migration of the subduction zone at ca540 Ma as recorded by deformation and metamorphism in the Anakie Inlier. Fragments of late Neoproterozoic oceanic lithosphere were accreted during progressive cratonisation of the east Australian margin.     

Zinc Isotopic Compositions of NIST SRM 683 and Whole‐Rock Reference Materials

In this study the homogeneity of the zinc isotopic composition in the NIST SRM 683 reference material was examined by measuring the Zn isotopic signature in microdrilled sample powders from two metal nuggets. Zinc was purified using AG MP‐1M resin and then measured by MC‐ICP‐MS. Instrumental mass bias was corrected using the “sample‐standard bracketing” method and empirical external normalisation with Cu doping. After evaluating the potential effects of varying acid mass fractions and different matrices, high‐precision Zn isotope data were obtained with an intermediate measurement precision better than ± 0.05‰ (δ⁶⁶Zn, 2s) over a period of 5 months. The δ⁶⁶Zn_JMC‐Lyon mean values of eighty‐four and fourteen drilled powders from two nuggets were 0.11 ± 0.02‰ and 0.12 ± 0.02‰, respectively, indicating that NIST SRM 683 is a good isotopic reference material with homogeneous Zn isotopes. The Zn isotopic compositions of seventeen rock reference materials were also determined, and their δ⁶⁶Zn values were in agreement with most previously published data within 2s. The δ⁶⁶Zn values of most of the rock reference materials analysed were in the range 0.22–0.36‰, except for GSP‐2 (1.07 ± 0.06‰, n = 12), NOD‐A‐1 (0.96 ± 0.03‰, n = 6) and NOD‐P‐1 (0.78 ± 0.03‰, n = 6). These comprehensive data should serve as reference values for quality assurance and interlaboratory calibration exercises.     

From London to Liverpool: Evidence for a Limehouse–Reid porcelain connection based on the analysis of sherds from the Brownlow Hill (ca. 1755–1767) factory site

The diversity of Brownlow Hill porcelains of the W^m Reid & Co. era is due to the remarkably wide range in the composition of their pastes and glazes and inferred firing conditions relative to the initial vitrification temperature. Sixteen of 21 analyzed sherds from the factory site are bone‐ash wares that display large variations in their bulk chemical composition. The remaining samples have silicious‐aluminous (akin to “stone china” sensu Richard Pococke in 1750) and silicious‐aluminous‐calcic (“S‐A‐C”) compositions that resemble Limehouse (London) and Pomona (Staffordshire) porcelains produced during the 1740s. The mineralogy of the Brownlow Hill S‐A‐C sherds suggests firing at a relatively high temperature (T_max approaching 1400°C, based on relations on the SiO₂‐Al₂O₃‐CaO phase diagram), thereby obscuring the identity of some of the ingredients (e.g., the source of CaO) used in their manufacture. Limehouse and Brownlow Hill may have been linked through the activities of William Ball, who is mentioned in connection with both factories, or indirectly via former Limehouse staff later employed at the Pomona factory, located not far from a W^m Reid & Co. branch factory in Shelton, Stoke‐on‐Trent. In terms of a time line, knowledge of these pastes appears to have spread first from London to Staffordshire, and then to Liverpool. © 2003 Wiley Periodicals, Inc.     

Systematics and biology of some desmodont bivalves from the Australian Permian

The Australian Permian bivalves Megadesmus, Astartila, Pyramtis, and Myonia have previously been grouped in either the Family Pachydomidae (Fischer, 1887) or the Family Edmondiidae (King, 1850). Because of similarities in their musculature (in addition to those in dentition, micro‐ornament, and to some extent, shape) they can now be included in the same family as the deep‐burrowing bivalve Vacunella (previously Chaenomya). Vacunella is closely related to the living genus Pholadomya which has existed at least since the Mesozoic, and the two can be placed in the same family — Pholadomyidae (Fleming, 1828). Because of these similarities between Pholadomya, Vacunella, and the “Pachydomidae” it seems likely that the middle and upper Palaeozoic edmondioid bivalves gave rise to the Mesozoic and Cainozoic pholadomyoids, and that these two groups together constitute a major division of the Class Bivalvia — a division that may have been relatively distinct since Ordovician time.     

Alkali-feldspars: Which solvus?

Variation in published alkali-feldspar solvus curves is discussed in the light of the concept of complete (crystal-crystal) and exchange (crystal-fluid-crystal) equilibrium. Exchange equilibrium may lead to very regular solvus-like two-phase curves differing substantially from the true binodal solvus; certain experimental strategies tend to favour the attainment and persistence of the exchange equilibrium condition. New long duration experiments under “alkali excess” and “alkali+silica excess” conditions did not yield fledspar pairs significantly off the bracketed binodal obtained by Smith and Parsons (1974) but exchange equilibrium behaviour is shown to influence the course of equilibration in peralkaline experiments. Agreement in solvus curves obtained by bracketing experiments by several workers is excellent (±2 mol. % Or) with a straight linear relationship between T _crit and P such that dT _crit/dP≈16°/Kbar. These curves do not exhibit breaks or sensitivity to chemical environment, and there is no evidence that the solvus changes shape with increasing P.     

K‐Ar dating of Permian and Tertiary igneous activity in the Southeastern Sydney Basin,New South Wales

The southern part of the Sydney Basin of New South Wales is comprised mainly of Permian and Triassic marine to freshwater clastic sedimentary rocks. Within this sequence there are six latite extrusive units, several medium‐sized monzonite intrusions and a large number of small to medium‐sized basic to intermediate intrusions. Thin basaltic flows were extruded onto the Tertiary topographic surface. All of these rocks are relatively undeformed.

Radiometric (K‐Ar) dating has previously been carried out on Mesozoic and Tertiary intrusions and flows of the southwestern portion of the Sydney Basin. However, relatively few Permian, and no post‐Permian, K‐Ar dates have been published for the southeastern portion of the basin. The present investigation provides nine K‐Ar dates from the latter area.

Four extrusive and intrusive units have been confirmed as Permian in age (238 ± 6; 241 ± 4; 245 ± 6; and 251 ± 5 m.y.). Five post‐Permian (on stratigraphic criteria) intrusions yielded Tertiary ages (26.2 ± 3.0; 47.9 ± 2.5; 49.0 ± 4.0; 49.4 ± 2.0; and 58.8 ± 3.5 m.y.). The Permian ages agree with previously published K‐Ar data from the southeastern Sydney Basin, and the Tertiary ages complement and extend the data from the southwestern portion of the basin. However, no Mesozoic K‐Ar dates were obtained from the southeastern Sydney Basin. The Tertiary intrusions may have been emplaced as a result of rifting between Australia and New Zealand, or between Australia and Antarctica, or both.     

Cenomanian-Coniacian Sea-level Change and Dissolved Oxygen Fluctuations in Tethys-Himalaya: Evidences from Benthic Foraminifera of Gamba, Tibet

Benthic foraminifera, preserved in the Late Cretaceous organic carbon-rich sediments of Gamba, southern Tibet, provide high-resolution proxies for sea-level changes and dissolved oxygen fluctuations of southeastern Tethys. The fossils were statistically analyzed and divided into three faunas of "Cenomanian fauna", "Turonian fauna", and "Coniacian fauna". A middle neritic-upper bathal environment (50-250m) was estimated considering the ratios of planktonic and epifaunal benthic foraminifera (P/(P+E)), the morphological analysis according to the studies of recent foraminifera and the abundant distributions of depth-related species such as Alabamina creta, Laevidentalina sp., Praebulimina spp., Pleurostomella cf. naranjoensis, Pyrulina sp., Quinqueloculina spp., Haplophragmoides spp., etc. The result shows an almost parallel trend with the global transgressive and regressive cycles, but the former fluctuates more frequently at upper Cenomanian, which probably indicates tectonic instability of the continental margin. According to the benthic foraminiferal richness (BFN), Shannon-Weiner diversity (H(s)), as well as benthic foraminiferal oxygen index (BFOI), five periods of oxygen depleted conditions (dysoxic-anoxic) have been recognized. They correspond to the OAE2, the lower Turonian, the upper Turonian, the Turonian-Caniacian boundary event and the probably OAE3. In addition, the oxygen fluctuations in Gamba might be controlled directly by sea-level changes, while the paleoproductivity and oxygen conditions interacted with each other under oxygen deficiency environments.     

Long‐Term Reaction Characteristics of CO2–Water–Rock Interaction: Insight into the Potential Groundwater Contamination Risk from Underground CO2 Storage

CO₂ sequestration into saline aquifers is considered to be one of the most promising options for reducing industrial CO₂ emissions to the atmosphere. However, there are still many uncertainties regarding the storage of CO₂ in the subsurface because of a lack of knowledge about CO₂–water–rock interaction within CO₂ reservoirs and the potential risk of CO₂ leakage. In this study, we construct a semi‐open type experimental system that can reproduce the interactions under conditions close to those of actual CO₂ reservoirs. Using the system, we conduct CO₂–water–rock interaction experiments for 8 months to monitor the long‐term reaction and the mobilization of harmful metal elements. Altered tuffaceous rock is used in the experiment because these tuffaceous rock formations (called “Green Tuff”) are a potential candidate for CO₂ storage in Japan. The results show that the major‐element water composition will converge to the point where host rock dissolution and secondary mineral precipitation are balanced; then, the interaction will proceed under a certain groundwater composition. In addition, we found that groundwater contamination by some metal elements (Ni, Ba, and Mn) may reach unsafe levels for drinking water as a result of CO₂‐water–rock interaction.     

Evidence for Holocene Aeolian Activity at the Close of the Middle Bronze Age in the Eastern Carpathian Basin: Geoarchaeological Results from the Mureş River Valley,Romania

While extensive Pleistocene loess deposits have been identified across Eurasia, Holocene age loess (typically nonglaciogenic) is rarely recognized. We explore possible loess deposits in the Mureş River Valley of western Romania, providing a regional signal of increased aridity during the mid‐late Holocene. This proposed aridity may be responsible for the abandonment of Middle Bronze Age tell settlements along the major drainages of the eastern Carpathian Basin (Pannonian plain). This hypothesis centers on a proposed aeolian deposit (the “Pecica deposit”), a ca. 50–80 cm thick, relatively homogeneous, gray layer blanketing the top of the Bronze Age tell of Pecica—Şanţul Mare. Comparing the morphological, geochemical, and physical characteristics of this specific tell deposit with two representative profiles near the site containing glaciogenic calcareous loess and potential Holocene loess deposits developed in Chernozems, we find significant similarities to support this hypothesis. We then review various forms of proxy data published from elsewhere in Central and Eastern Europe suggesting a warming trend during this period. The temporal placement of the Pecica deposit is bracketed using diagnostic artifacts, radiocarbon dates, and the degree of soil development, suggesting a period of increased aridity likely occurring soon after the 17th century B.C.     

Age and sources of the anorthosites of the Neoarchean Kolmozero-Voron’ya greenstone belt (Fennoscandian Shield)

New data are reported on U-Pb (SHRIMP-II) age (2662 ± 7 Ma), isotope (Sm-Nd) and geochemical compositions of the anorthosites of the Patchemvarek Massif and “ovoidal” anorthosite sills of the Neoarchean Kolmozero-Voron’ya greenstone belt. Mesoarchean (2938 ± 8 Ma) zircons found in the Patchemvarek anorthosite have low Th/U ratio, are overgrown by a thin rim, and may be interpreted as xenogenic crystals assimilated by primary melts of the gabbro-anorthosite massifs from host Mesoarchean tonalites during crystallization in a magmatic chamber. The “ovoidal” anorthosite sills are dated at 2730–2740 Ma on the basis of U-Pb local zircon isotope analysis. The sills of the “ovoidal” anorthosites in the Kolmozero-Voron’ya GSB represent the older (2730–2740 Ma) rock group, which differs from the Patchemvarek anorthosites in strongly depleted Nd isotope composition and some geochemical features. In terms of age and Sm-Nd isotope characteristics, the “ovoidal” anorthosites are close to the komatiites of the lower volcanogenic sequence (ε_Nd(Т) + 3.0–3.2), and metaandesites (2778 ± 5.4 Ma, U-Pb TIMS, ε_NdТ + 3.5) and metatholeiites of the upper volcanogenic sequence (ε_Nd(Т) + 3.5–3.7) of the supracrustal complex of the Kolmozero-Voron’ya GSB.     

Bearing capacity of foundations on rock mass using the method of characteristics

The method of stress characteristics has been used for computing the ultimate bearing capacity of strip and circular footings placed on rock mass. The modified Hoek‐and‐Brown failure criterion has been used. Both smooth and rough footing‐rock interfaces have been modeled. The bearing capacity has been expressed in terms of nondimensional factors N_σ0 and N_σ, corresponding to rock mass with (1) γ = 0 and (2) γ ≠ 0, respectively. The numerical results have been presented as a function of different input parameters needed to define the Hoek‐and‐Brown criterion. Slip line patterns and the pressure distribution along the footing base have also been examined. The results are found to compare generally well with the reported solutions.     

Evidence for Palaeozoic magmatism recorded in the Late Neoproterozoic Marlborough ophiolite,New England Fold Belt,central Queensland

The ultramafic‐mafic complex in the Marlborough terrane of the northern New England Fold Belt is dominated by members of a Neoproterozoic (ca 560 Ma) ophiolite (V1). The ophiolite has been intruded by the products of three Palaeozoic tectonomagmatic episodes (V2, V3 and V4). The V2 magmatic episode is represented by tholeiitic and calc‐alkaline basalts and gabbros of island‐arc affinities. Sm/Nd isotopes give a whole‐rock isochron age of 380 ± 19 Ma (2σ) to this episode, some 180 million years younger than the V1 ophiolitic rocks. The V3 magmatic episode includes tholeiitic and alkali basalts with enriched geochemical signatures characteristic of intraplate volcanism. A whole‐rock Sm/Nd isochron age of 293 ± 35 Ma is obtained for this event. A fourth magmatic event (V4) is represented by basaltic andesites and siliceous intrusives with geochemical features similar to modern adakites. This event has its type locality in the Percy Isles. These data provide tectonic and geochronological constraints for the previously enigmatic Marlborough terrane and as such contribute to the ever‐evolving understanding of New England Fold Belt development.     

Ultrahigh‐temperature metamorphism in the Tuguiwula area,Khondalite Belt,North China Craton

In this study, sapphirine‐bearing granulites and sapphirine‐absent garnet–sillimanite gneisses from the Tuguiwula area in the eastern segment of the Khondalite Belt, North China Craton (NCC) are interpreted to show a P–T evolution involving cooling at pressures of 8–9 kbar from >960°C to the solidus (~820°C) and late subsolidus decompression. This interpretation is based on the sequence of mineral appearance and thermodynamic modelling of phase equilibria. Sapphirine is observed to coexist with spinel within the peak assemblages. This observation conflicts with the traditional view that spinel generally appears prior to sapphirine and thus indicates pre‐T_max compression. For ultrahigh‐temperature (UHT) metapelites at Tuguiwula, a clockwise P–T path may be more likely, which would be consistent with the clockwise P–T evolution of the extensive “normal” granulites (T_max <900°C) and UHT granulites at other localities in the eastern segment of the Khondalite Belt. At Tuguiwula, for UHT metapelites with low bulk‐rock Mg/(Mg+Fe^T), the oxidation state/Fe³⁺ content is interpreted to be a significant factor in controlling the mineral assemblages. We find that these compositions tend to contain sapphirine under oxidized conditions but spinel (without sapphirine) under reduced conditions. This difference may account for the simultaneous presence of both sapphirine‐bearing UHT granulites and sapphirine‐absent garnet–sillimanite UHT gneisses at Tuguiwula. LA‐ICP‐MS U–Pb dating of metamorphic zircon in the UHT metapelites yields mean ²⁰⁷Pb/²⁰⁶Pb ages of c. 1.92 Ga (two samples), which are interpreted to record the timing of cooling of the UHT rocks to the solidus. The UHT metamorphism is interpreted to have been generated by mantle upwelling and emplacement of mafic magmas within a post‐orogenic setting.