Paleoenvironmental reconstruction of a Late Quaternary lagoon system in southern Brazil (Jaguaruna region,Santa Catarina state) based on multi‐proxy analysis

This paper provides a paleoenvironmental reconstruction of a Late Quaternary lagoon system in the Jaguaruna region of Santa Catarina state, southern Brazil. Integrated results of bulk sedimentary organic matter characterization (δ¹³C, δ¹⁵N and C/N), microfossil (pollen and diatom) and grain‐size analysis from three shallow cores (～2.5 m depth) allowed us to propose an evolving paleogeographic scenario in this coastal region for the last ca. 5500 cal a BP. The lagoonal system in this area was more extensive during the mid‐Holocene than today, with a gradual and continuous lagoon–sea disconnection until the present. We add to the debate regarding relative sea‐level (RSL) variations for the Brazilian coast during the Holocene and discuss the importance of sedimentary dynamics for interpreting changes in coastal ecosystems. The multi‐proxy analysis suggests that changes in coastal ecosystems could be directly related to local sedimentary processes, which are not necessarily linked to RSL fluctuations and/or to climatic variations. Copyright © 2011 John Wiley & Sons, Ltd.     

Grain‐size distributions on high‐energy sandy beaches and their relation to wave dissipation

Grain size and sorting represent two key parameters when characterizing sediments or modelling beach morphology and sediment transport. Traditionally, an average value for grain size or sorting is often assumed for the entire area, determined from only a few sediment samples, ignoring any spatial (or temporal) variability in sediment characteristics. This contribution uses a data set of physical surface sediment samples from 53 beach locations around the south‐west peninsula of the United Kingdom, in addition to bi‐monthly, high spatial resolution (mean 240 samples) digital grain‐size surveys from a high‐energy, oceanic, sandy beach (Perranporth, North Cornwall). Systematic spatial variations in grain size and sorting were consistently observed in the seaward direction across the intertidal zone of sandy beaches, with grain‐sizes coarsening and sorting improving by up to 51·7% and 64·3%, respectively. This variability was deterministically related to the time‐averaged, antecedent‐adjusted energy dissipated by breaking waves, with the observed maximum grain‐size and sorting values correlating with the location of peak wave energy dissipation (r² = 0·998, P < 0·01).     

Three‐dimensional modelling and sequence stratigraphy of a carbonate ramp‐to‐shelf transition,Permian Upper San Andres Formation

This study highlights three‐dimensional variability of stratigraphic geometries in the ramp crest to basin of mixed carbonate–siliciclastic clinoforms in the Permian San Andres Formation. Standard field techniques and mapping using ground‐based lidar reveal a high degree of architectural complexity in channellized, scoured and mounded outer ramp stratigraphy. Development of these features was a function of location along the ramp profile and fluctuations in relative sea‐level. Deposition of coarse‐grained and fine‐grained turbidites in the distal outer ramp occurred through dilute and high‐density turbidity flows and was the result of highstand carbonate shedding within individual cycles. In this setting, high‐frequency cycles of relative sea‐level are interpreted on the basis of turbidite frequency, lateral extent and composition. Submarine siliciclastic sediment bypass during lowstand cycles resulted in variable degrees of siliciclastic preservation. Abundant siliciclastic material is preserved in the basin and distal outer ramp as point‐sourced lowstand wedges and line‐sourced early transgressive blankets. In mounded topography of the outer ramp, siliciclastic preservation is minimal to absent, and rare incised channels offer the best opportunity for recognition of a sequence boundary. Growth of mounded topography in the outer ramp began with scouring, followed by a combination of bioherm construction, fusulinid mound construction and isopachous draping. Intermound areas were then filled with sediment and continued mound growth was prevented by an accommodation limit. Mound growth was independent of high‐frequency cycles in relative sea‐level but was dependent on available accommodation dictated by low‐frequency cyclicity. Low‐angle ramp clinoforms with mounded topography in the outer ramp developed during the transgressive part of a composite sequence. Mound growth terminated as the ramp transformed into a shelf with oblique clinoform geometries during the highstand of the composite sequence. This example represents a ramp‐to‐shelf transition that is the result of forcing by relative sea‐level fluctuations rather than ecologic or tectonic controls.     

From a river valley to a ria: Evolution of an incised valley (Ría de Ferrol,north‐west Spain) since the Last Glacial Maximum

The evolution of incised valleys is an important area of research due to the invaluable data it provides on sea‐level variations and depositional environments. In this article the sedimentary evolution of the Ría de Ferrol (north‐west Spain) from the Last Glacial Maximum to the present is reconstructed using a multidisciplinary approach, combining seismic and sedimentary facies, and supported by radiocarbon data and geochemical proxies to distinguish the elements of sedimentary architecture within the ria infill. The main objectives are: (i) to analyse the ria environment as a type of incised valley to evaluate the response of the system to the different drivers; (ii) to investigate the major controlling factors; and (iii) to explore the differentiation between rias and estuaries. As a consequence of the sea‐level rise subsequent to the Last Glacial Maximum (ca 20 kyr bp ), an extensive basin, drained by a braided palaeoriver, evolved into a tide‐dominated estuary and finally into a ria environment. Late Pleistocene and Holocene high‐frequency sea‐level variations were major factors that modulated the type of depositional environments and their evolution. Another major modulating factor was the antecedent morphology of the ria, with a rock‐incised narrow channel in the middle of the basin (the Ferrol Strait), which influenced the evolution of the ria as it became flooded during Holocene transgression. The strait acted as a rock‐bounded ‘tidal inlet’ enhancing the tidal erosion and deposition at both ends, i.e. with an ebb‐tidal delta in the outer sector and tidal sandbanks in the inner sector. The final step in the evolution of the incised valley into the modern‐defined ria system was driven by the last relative sea‐level rise (after 4 kyr bp ) when the river mouths retreated landward and a single palaeoriver was converted into minor rivers and streams with scattered mouths in an extensive coastal area.     

Late Quaternary submarine bedforms and ice‐sheet flow in Gerlache Strait and on the adjacent continental shelf,Antarctic Peninsula

Geophysical data from Gerlache Strait, Croker Passage, Bismarck Strait and the adjacent continental shelf reveal streamlined subglacial bedforms that were produced at the bed of the Antarctic Peninsula Ice Sheet (APIS) during the last glaciation. The spatial arrangement and orientation of these bedforms record the former drainage pattern and flow dynamics of an APIS outlet up‐flow, and feeding into, a palaeo‐ice stream in the Western Bransfield Basin. Evidence suggests that together, they represent a single ice‐flow system that drained the APIS during the last glaciation. The ice‐sheet outlet flowed north/northeastwards through Gerlache Strait and Croker Passage and converged with a second, more easterly ice‐flow tributary on the middle shelf to form the main palaeo‐ice stream. The dominance of drumlins with low elongation ratios suggests that ice‐sheet outlet draining through Gerlache Strait was comparatively slower than the main palaeo‐ice stream in the Western Bransfield Basin, although the low elongation ratios may also partly reflect the lack of sediment. Progressive elongation of drumlins further down‐flow indicates that the ice sheet accelerated through Croker Passage and the western tributary trough, and fed into the main zone of streaming flow in the Western Bransfield Basin. Topography would have exerted a strong control on the development of the palaeo‐ice stream system but subglacial geology may also have been significant given the transition from crystalline bedrock to sedimentary strata on the inner–mid‐shelf. In the broader context, the APIS was drained by a number of major fast‐flowing outlets through cross‐shelf troughs to the outer continental shelf during the last glaciation. Copyright © 2004 John Wiley & Sons, Ltd.     

External controls on the distribution,fabrics and mineralization of modern microbial mats in a coastal hypersaline lagoon,Cayo Coco (Cuba)

Active, carbonate‐mineralizing microbial mats flourish in a tropical, highly evaporative, marine‐fed lagoonal network to the south of Cayo Coco Island (Cuba). Hypersaline conditions support the development of a complex sedimentary microbial ecosystem with diverse morphologies, a variable intensity of mineralization and a potential for preservation. In this study, the role of intrinsic (i.e. microbial) and extrinsic (i.e. physicochemical) controls on microbial mat development, mineralization and preservation was investigated. The network consists of lagoons, forming in the interdune depressions of a Pleistocene aeolian substratum; they developed due to a progressive increase in sea‐level since the Holocene. The hydrological budget in the Cayo Coco lagoonal network changes from west to east, increasing the salinity. This change progressively excludes grazers and increases the saturation index of carbonate minerals, favouring the development and mineralization of microbial mats in the easternmost lagoons. Detailed mapping of the easternmost lagoon shows four zones with different flooding regimes. The microbial activity in the mats was recorded using light–dark shifts in conjunction with microelectrode O₂ and HS^? profiles. High rates of O₂ production and consumption, in addition to substantial amounts of exopolymeric substances, are indicative of a potentially strong intrinsic control on mineralization. Seasonal, climate‐driven water fluctuations are key for mat development, mineralization, morphology and distribution. Microbial mats show no mineralization in the permanently submersed zone, and moderate mineralization in zones with alternating immersion and exposure. It is suggested that mineralization is also driven by water‐level fluctuations and evaporation. Mineralized mats are laminated and consist of alternating trapping and binding of grains and microbially induced magnesium calcite and dolomite precipitation. The macrofabrics of the mats evolve from early colonizing Flat mats to complex Cerebroid or Terrace structures. The macrofabrics are influenced by the hydrodynamic regime: wind‐driven waves inducing relief terraces in windward areas and flat morphologies on the leeward side of the lagoon. Other external drivers include: (i) storm events that either promote (for example, by bioclasts covering) or prevent (for example, by causing erosion) microbial mat preservation; and (ii) subsurface degassing, through mangrove roots and desiccation cracks covered by Flat mats (i.e. forming Hemispheroids and Cerebroidal structures). These findings provide in‐depth insights into understanding fossil microbialite morphologies that formed in lagoonal settings.     

Subduction and exhumation mechanisms of ultra‐high and high‐pressure oceanic and continental crust at Makbal (Tianshan,Kazakhstan and Kyrgyzstan)

The Makbal Complex in the northern Tianshan of Kazakhstan and Kyrgyzstan consists of metasedimentary rocks, which host high‐P (HP) mafic blocks and ultra‐HP Grt‐Cld‐Tlc schists (UHP as indicated by coesite relicts in garnet). Whole rock major and trace element signatures of the Grt‐Cld‐Tlc schist suggest a metasomatized protolith from either hydrothermally altered oceanic crust in a back‐arc basin or arc‐related volcaniclastics. Peak metamorphic conditions of the Grt‐Cld‐Tlc schist reached ~580 °C and 2.85 GPa corresponding to a maximum burial depth of ~95 km. A Sm‐Nd garnet age of 475 ± 4 Ma is interpreted as an average growth age of garnet during prograde‐to‐peak metamorphism; the low initial εΝd value of ?11 indicates a protolith with an ancient crustal component. The petrological evidence for deep subduction of oceanic crust poses questions with respect to an effective exhumation mechanism. Field relationships and the metamorphic evolution of other HP mafic oceanic rocks embedded in continentally derived metasedimentary rocks at the central Makbal Complex suggest that fragments of oceanic crust and clastic sedimentary rocks were exhumed from different depths in a subduction channel during ongoing subduction and are now exposed as a tectonic mélange. Furthermore, channel flow cannot only explain a tectonic mélange consisting of various rock types with different subduction histories as present at the central Makbal Complex, but also the presence of a structural ‘dome’ with UHP rocks in the core (central Makbal) surrounded by lower pressure nappes (including mafic dykes in continental crust) and voluminous metasedimentary rocks, mainly derived from the accretionary wedge.     

Fluid pathways and high‐P metasomatism in a subducted continental slice (Mt. Emilius klippe,W. Alps)

The Mt. Emilius klippe (Western Alps, Italy) corresponds to a segment of the stretched Adriatic continental margin metamorphosed at granulite facies during Permian. This slice was subducted during the early Cenozoic Alpine subduction with the underlying eclogite facies remnants of the Tethyan seafloor (Zermatt‐Saas zone). Near the base of the Mt. Emilius massif, there is a shear zone with eclogite facies hydrofracture systems associated with deformation‐induced re‐equilibration of granulites during high‐P metamorphism. In the basal part of the massif, a pluri‐hectometre domain of sheared mafic boudins is hosted in the granulitic paragneiss. In these mafic boudins, there are garnetites, garnet veins and clinopyroxenites, as well as clinozoisite and calcite veins. These features record multiple events of fracture opening, brecciation, boudinage and parallelization of structures coevally with fluid–rock interaction, metasomatism and volume change. This integrated petrological, micro‐textural and geochemical investigation illustrates the multiplicity and the chemical variability of fluid sources during prograde to peak metamorphic evolution in the lawsonite–eclogite‐facies field (at ~2.15–2.4 GPa, 500–550 °C) during subduction of the Mt. Emilius slice. The calcite veins crosscutting the garnetites have relatively low δ¹⁸O_VSMOW values (～+6.5‰) near those for marble layers (and nearby calcsilicates) embedded within the metasomatized granulites (+8 to +10‰). It is proposed that infiltration of externally‐derived H₂O‐rich fluids derived from the plate interface flushed the marbles, promoting decarbonation followed by short‐distance transport and re‐precipitation along garnetite fractures. This study highlights the importance of inherited structural heterogeneities (such as mafic bodies or sills) in localizing deformation, draining fluids from the downgoing plate and creating long‐lasting mechanical instabilities during subduction zone deformation.     

From river to shelf,anatomy of a high‐frequency depositional sequence: The Late Pleistocene to Holocene Tiber depositional sequence

The Late Pleistocene/Holocene Tiber delta succession represents the most recent and one of the best preserved, high‐frequency/low‐rank depositional sequences developed along the Latium continental margin of the Italian peninsula. Several previous studies have established a robust data set from which it has been possible to describe the stratigraphic architecture of the entire Tiber depositional sequence from the landward to seaward sectors and over a distance of 60 km. The Tiber depositional sequence shows many characteristics found in other Late Pleistocene to Holocene deltaic and coastal successions of the Mediterranean area. The stratigraphic architecture of the Tiber depositional sequence is controlled mainly by glacioeustasy, although factors such as tectonic uplift, volcanism and subsidence, exert an influence at a local scale. The resulting depositional model allowed discussion of some important points such as: (1) the genesis of the Tiber mixed bedrock‐alluvial valley, extending from the coastal plain to the innermost portion of the shelf, recording (i) multiple episodes of incision during relative sea‐level fall, and (ii) a downstream increase of depth and width of the valley during the base‐level fall and the subsequent base‐level rise; (2) the different physical expression of the Tiber depositional sequence boundary from landward to seaward, and its diachronous and composite character; (3) the maximum depth reached by the Tiber early lowstand delta at the end of the sea‐level fall is estimated at ca 90 m below the present sea‐level and not at 120 m as suggested by previous works; (4) the backward position of the Tiber late lowstand delta relative to the deposit of early lowstand; (5) the change of the channel pattern and of the stacking pattern of fluvial deposits within the Lowstand Systems Tract, Transgressive Systems Tract and Highstand Systems Tract. All of these features indicate that the Late Pleistocene/Holocene Tiber delta succession, even if deposited in a short period of time from a geological point of view, represents the result of the close interaction among many autogenic and allogenic factors. However, global eustatic variations and sediment supply under the control of climatic changes can be considered the main factors responsible for the stratigraphic architecture of this sedimentary succession, which has been heavily modified by human activity only in the last 3000 years.     

Marine geophysical evidence for former expansion and flow of the Greenland Ice Sheet across the north‐east Greenland continental shelf

High‐resolution swath bathymetry and TOPAS sub‐bottom profiler acoustic data from the inner and middle continental shelf of north‐east Greenland record the presence of streamlined mega‐scale glacial lineations and other subglacial landforms that are formed in the surface of a continuous soft sediment layer. The best‐developed lineations are found in Westwind Trough, a bathymetric trough connecting Nioghalvfjerdsfjorden Gletscher and Zachariae Isstrøm to the continental shelf edge. The geomorphological and stratigraphical data indicate that the Greenland Ice Sheet covered the inner‐middle shelf in north‐east Greenland during the most recent ice advance of the Late Weichselian glaciation. Earlier sedimentological and chronological studies indicated that the last major delivery of glacigenic sediment to the shelf and Fram Strait was prior to the Holocene during Marine Isotope Stage 2, supporting our assertion that the subglacial landforms and ice sheet expansion in north‐east Greenland occurred during the Late Weichselian. Glacimarine sediment gravity flow deposits found on the north‐east Greenland continental slope imply that the ice sheet extended beyond the middle continental shelf, and supplied subglacial sediment direct to the shelf edge with subsequent remobilisation downslope. These marine geophysical data indicate that the flow of the Late Weichselian Greenland Ice Sheet through Westwind Trough was in the form of a fast‐flowing palaeo‐ice stream, and that it provides the first direct geomorphological evidence for the former presence of ice streams on the Greenland continental shelf. The presence of streamlined subglacially derived landforms and till layers on the shallow AWI Bank and Northwind Shoal indicates that ice sheet flow was not only channelled through the cross‐shelf bathymetric troughs but also occurred across the shallow intra‐trough regions of north‐east Greenland. Collectively these data record for the first time that ice streams were an important glacio‐dynamic feature that drained interior basins of the Late Weichselian Greenland Ice Sheet across the adjacent continental margin, and that the ice sheet was far more extensive in north‐east Greenland during the Last Glacial Maximum than the previous terrestrial–glacial reconstructions showed. Copyright © 2008 John Wiley & Sons, Ltd.     

Microstructural and metamorphic evolution of a high‐pressure granitic orthogneiss during continental subduction (Orlica–Śnieżnik dome,Bohemian Massif)

A microstructural and metamorphic study of a naturally deformed medium‐ to high‐pressure granitic orthogneiss (Orlica–?nie?nik dome, Bohemian Massif) provides evidence of behaviour of the felsic crust during progressive burial along a subduction‐type apparent thermal gradient (～10 °C km^?1). The granitic orthogneisses develops three distinct microstructural types, as follows: type I – augen orthogneiss, type II – banded orthogneiss and type III – mylonitic orthogneiss, each representing an evolutionary stage of a progressively deformed granite. Type I orthogneiss is composed of partially recrystallized K‐feldspar porphyroclasts surrounded by wide fronts of myrmekite, fully recrystallized quartz aggregates and interconnected monomineralic layers of recrystallized plagioclase. Compositional layering in the type II orthogneiss is defined by plagioclase‐ and K‐feldspar‐rich layers, both of which show an increasing proportion of interstitial minerals, as well as the deformation of recrystallized myrmekite fronts. Type III orthogneiss shows relicts of quartz and K‐feldspar ribbons preserved in a fine‐grained polymineralic matrix. All three types have the same assemblage (quartz + plagioclase + K‐feldspar + muscovite + biotite + garnet + sphene ± ilmenite), but show systematic variations in the composition of muscovite and garnet from types I to III. This is consistent with the equilibration of the three types at different positions along a prograde P?T path ranging from <15 kbar and <700 °C (type I orthogneiss) to 19–20 kbar and >700 °C (types II and III orthogneisses). The deformation types thus do not represent evolutionary stages of a highly partitioned deformation at constant P?T conditions, but reflect progressive formation during the burial of the continental crust. The microstructures of the type I and type II orthogneisses result from the dislocation creep of quartz and K‐feldspar whereas a grain boundary sliding‐dominated diffusion creep regime is the characteristic of the type III orthogneiss. Strain weakening related to the transition from type I to type II microstructures was enhanced by the recrystallization of wide myrmekite fronts, and plagioclase and quartz, and further weakening and strain localization in type III orthogneiss occurred via grain boundary sliding‐enhanced diffusion creep. The potential role of incipient melting in strain localization is discussed.     

Theoretical Prediction of Gibbs Free Energies of Formation for Crystalline α-MOOH and α-M2O3 Based on a Linear Free-Energy Relationship

In the present study, the modified Sverjensky–Molling equation, derived from a linear-free energy relationship, is used to predict the Gibbs free energies of formation of crystalline phases of α-MOOH (with a goethite structure) and α-M2O3 (with a hematite structure) from the known thermodynamic properties of the corresponding aqueous trivalent cations (M3+). The modified equation is expressed as ΔG0f,MVX=aMVXΔG0n,M3++bMVX+βMVXγM3+, where the coefficients aMVX, bMVX, and βMVX characterize a particular structural family of MvX (M is a trivalent cation [M3+] and X represents the remainder of the composition of solid); γ3+ is the ionic radius of trivalent cations (M3+); ΔG0f,MVX is the standard Gibbs free energy of formation of MvX; and ΔG0n,M3+ is the non-solvation energy of trivalent cations (M3+). By fitting the equation to the known experimental thermodynamic data, the coefficients for the goethite family (α-MOOH) are aMVX=0.8838, bMVX=?424.4431 (kcal/mol), and βMVX=115 (kcal/mol.?), while the coefficients for the hematite family (α-M2O3) are aMVX=1.7468, bMVX=?814.9573 (kcal/mol), and βMVX=278 (kcal/mol.?). The constrained relationship can be used to predict the standard Gibbs free energies of formation of crystalline phases and fictive phases (i.e. phases that are thermodynamically unstable and do not occur at standard conditions) within the isostructural families of goethite (α-MOOH) and hematite (α-M2O3) if the standard Gibbs free energies of formation of the trivalent cations are known.     

Integration of sedimentology and ground‐penetrating radar for high‐resolution imaging of a carbonate platform

Ground‐penetrating radar has not been applied widely to the recognition of ancient carbonate platform geometries. This article reports the results of an integrated study performed on an Upper Jurassic outcrop from the south‐east Paris basin, where coral bioherms laterally change into prograding depositional sequences. Ground‐penetrating radar profiles illustrate the different bedding planes and major erosional unconformities visible at outcrop. A ground‐penetrating radar profile conducted at the base of the cliff displays a palaeotopographic surface on which the outcropping bioherms settled. The excellent penetration depths of the ground‐penetrating radar (20 m with a monostatic 200 MHz antenna) images the carbonate platform geometries, ranging between outcrop workscale (a few metres) and seismic scale (several hundreds of metres). This study supports recent evidence of icehouse conditions and induced sea‐level fluctuations controlling the Upper Jurassic carbonate production.     

Anatomy of an Upper Triassic continental to marginal‐marine system: the mixed siliciclastic–carbonate Travenanzes Formation (Dolomites,Northern Italy)

The Travenanzes Formation is a terrestrial to shallow‐marine, siliciclastic–carbonate succession (200 m thick) that was deposited in the eastern Southern Alps during the Late Triassic. Sedimentary environments and depositional architecture have been reconstructed in the Dolomites, along a 60 km south–north transect. Facies alternations in the field suggest interfingering between alluvial‐plain, flood‐basin and shallow‐lagoon deposits, with a transition from terrestrial to marine facies belts from south to north. The terrestrial portion of the Travenanzes Formation consists of a dryland river system, characterized by multicoloured floodplain mudstones with scattered conglomeratic fluvial channels, merging downslope into small ephemeral streams and sheet‐flood sandstones, and losing their entire discharge subaerially before the shoreline. Calcic and vertic palaeosols indicate an arid/semi‐arid climate with strong seasonality and intermittent discharge. The terrestrial/marine transition shows a coastal mudflat, the flood basin, which is usually exposed, but at times is inundated by both major river floods and sea‐water storm surges. Locally coastal sabkha deposits occur. The marine portion of the Travenanzes Formation comprises carbonate tidal‐flat and shallow‐lagoon deposits, characterized by metre‐scale shallowing‐upward peritidal cycles and subordinate intercalations of dark clays from the continent. The depositional architecture of the Travenanzes Formation suggests an overall transgressive pattern organized in three carbonate–siliciclastic cycles, corresponding to transgressive–regressive sequences with internal higher‐frequency sedimentary cycles. The metre‐scale sedimentary cyclicity of the Travenanzes Formation continues without a break in sedimentation into the overlying Dolomia Principale. The onset of the Dolomia Principale epicontinental platform is marked by the exhaustion of continental sediment supply.     

Enhancement of regional variations in salinity and temperature in a coral reef lagoon, New Caledonia

The variability in salinity and temperature in the southwest lagoon of New Caledonia (2100 km²) under non-storm conditions is analysed using a 4-year dataset (1997–2001). Seasonal and interannual variations in salinity are amplified nearshore. Temperature is larger in bays than in the open lagoon during summer, the reverse is true in winter. El Niño Southern Oscillation (ENSO) related nearshore temperature variations parallel those at regional scale, but with seasonal variations amplified. Haline stratification, if any, is enhanced in coastal areas. To cite this article: S. Ouillon et al., C. R. Geoscience 337 (2005).     

Evolution of an incised valley coastal plain estuary under low sediment supply: a ‘give‐up’ estuary

The literature on incised river valley sedimentology is dominated by studies of sediment‐rich systems in which the valley has been filled during and/or shortly after drowning. In contrast, the Holocene evolution of the Kosi Lagoon, South Africa (an incised coastal plain river valley) took place under very low sedimentation rates which have produced a distinctive stratigraphy and contemporary sedimentary environments. The findings are based on a synthesis of the results of studies of seismic stratigraphy, sediment distribution, morphodynamics and geomorphology. Barrier migration was prevented by a high pre‐Holocene dune barrier against which Holocene coastal deposits accumulated in an aggradational sequence. Holocene evolution of the back barrier involved: (i) drowning of the incised valley; (ii) wave‐induced modification of the back‐barrier shoreline leading to segmentation during the highstand; and (iii) marine sedimentation adjacent to the tidal inlet. Segmentation has divided the estuary into a series of geochemically and sedimentologically distinctive basins connected by channels in the estuarine barriers. The seismic stratigraphy of the back barrier essentially lacks a transgressive systems tract, shoreline modification and deposition having been accomplished during the highstand. The lack of historical geomorphological change suggests that the system has achieved morphological equilibrium with ambient energy conditions and low sediment supply. This study presents a classification for estuarine incised valley fills based on the balance between sea‐level rise and sedimentation in which Kosi represents a ‘give‐up’ estuary where much of the relict incised channel form is drowned and preserved. It exhibits a fundamentally different set of evolutionary processes and stratigraphic sequences to those of the better known incised valley systems in which sedimentation either keeps pace with sea‐level (‘keep‐up’ estuaries) or occurs after initial drowning (‘catch‐up’ estuaries).     

Accurate and High‐Precision Determination of Boron Isotopic Ratios at Low Concentration by MC‐ICP‐MS (Neptune)

We report an approach for the accurate and reproducible measurement of boron isotope ratios in natural waters using an MC‐ICP‐MS (Neptune) after wet chemistry sample purification. The sample matrix can induce a drastic shift in the isotopic ratio by changing the mass bias. It is shown that, if no purification is carried out, the direct measurement of a seawater diluted one hundred times will induce an offset of ?7‰ in the isotopic ratio, and that, for the same concentration, the greater the atomic mass of the matrix element, the greater the bias induced. Whatever the sample, it is thus necessary to remove the matrix. We propose a method adapted to water samples allowing purification of 100 ng of boron with a direct recovery of boron in 2 ml of 3% v/v HNO₃, which was our working solution. Boron from the International Atomic Energy Agency IAEA‐B1 seawater reference material and from the two groundwater reference materials IAEA‐B2 and IAEA‐B3, was chemically purified, as well as boron from the certified reference material NIST SRM 951 as a test. The reproducibility of the whole procedure (wet chemistry and MC‐ICP‐MS measurement) was ± 0.4‰ (2s). Accuracy was verified by comparison with positive‐TIMS values and with recommended values. Seawater, being homogeneous for boron isotope ratios, is presently the only natural water material that is commonly analysed for testing accuracy worldwide. We propose that the three IAEA natural waters could be used as reference samples for boron isotopes, allowing a better knowledge of their isotopic ratios, thus contributing to the certification of methods and improving the quality of the boron isotopic ratio measurements for all laboratories.     

Metamorphic petrology of a high‐T/low‐P granulite terrane (Damara belt,Namibia) – Constraints from pseudosection modelling and high‐precision Lu–Hf garnet‐whole rock dating

Migmatites comprise a minor volume of the high‐grade part of the Damara orogen of Namibia that is dominated by granite complexes and intercalated metasedimentary units. Migmatites of the Southern Central Zone of the Damara orogen consist of melanosomes with garnet+cordierite+biotite+K‐feldspar, and leucosomes, which are sometimes garnet‐ and cordierite‐bearing. Field evidence, petrographic observations, and pseudosection modelling suggest that, in contrast to other areas where intrusion of granitic magmas is more important, in situ partial melting of metasedimentary units was the main migmatite generation processes. Pseudosection modelling and thermobarometric calculations consistently indicate that the peak‐metamorphic grade throughout the area is in the granulite facies (~5 kbar at ~800°C). Cordierite coronas around garnet suggest some decompression from peak‐metamorphic conditions and rare andalusite records late, near‐isobaric cooling to <650°C at low pressures of ~3 kbar. The inferred clockwise P–T path is consistent with minor crustal thickening through continent–continent collision followed by limited post‐collisional exhumation and suggests that the granulite facies terrane of the Southern Central Zone of the Damara orogen formed initially in a metamorphic field gradient of ~35–40°C/km at medium pressures. New high‐precision Lu–Hf garnet‐whole rock dates are 530 ± 13 Ma, 522.0 ± 0.8 Ma, 520.8 ± 3.6 Ma, and 500.3 ± 4.3 Ma for the migmatites that record temperatures of ~800°C. This indicates that high‐grade metamorphism lasted for c. 20–30 Ma, which is compatible with previous estimates using Sm–Nd garnet‐whole rock systematics. In previous studies on Damara orogen migmatites where both Sm–Nd and Lu–Hf chronometers have been applied, the dates (c. 520–510 Ma) agree within their small uncertainties (0.6–0.8% for Sm–Nd and 0.1–0.2% for Lu–Hf). This implies rapid cooling after high‐grade conditions and, by implication, rapid exhumation at that time. The cause of the high geothermal gradient inferred from the metamorphic conditions is unknown but likely requires some extra heat that was probably added by intrusion of magmas from the lithospheric mantle, i.e., syenites that have been recently re‐dated at c. 545 Ma. Some granites derived from the lower crust at c. 545 Ma are the outcome rather than the cause of high‐T metamorphism. In addition, high contents of heat‐producing elements K, Th, and U may have raised peak temperatures by 150–200°C at the base of the crust, resulting in the widespread melting of fertile crustal rocks. The continuous gradation from centimetre‐scale leucosomes to decametre‐scale leucogranite sheets within the high‐grade metamorphic zone suggests that leucosome lenses coalesced to form larger bodies of anatectic leucogranites, thereby documenting a link between high‐grade regional metamorphism and Pan‐African magmatism. In view of the close association of the studied high‐T migmatites with hundreds of synmetamorphic high‐T granites that invaded the terrane as metre‐ to decametre‐wide sills and dykes, we postulate that crystallization of felsic lower crustal magma is, at least partly, responsible for heat supply. Late‐stage isobaric cooling of these granites may explain the occurrence of andalusite in some samples.     

Widespread overspill from a saline density‐current channel and its interaction with topography on the south‐west Black Sea shelf

Seaward of the Bosphorus Strait, the south‐west Black Sea shelf is dominated by the world's largest channel network maintained by a quasi‐continuous saline (ca 35 → 31 psu) underflow. Calculations indicate that >85% of the initial discharge of ca 10⁴ m³s^?1 spills overbank before the shelf edge. This paper documents interaction of the overspill with sea bed topography using multibeam bathymetry, echo‐sounder images of the water column, conductivity–temperature–depth profiles and sediment cores. Overbank spill is widespread, particularly through crevasse channels and on the middle shelf where confinement by channel banks is negligible. Towards the outer shelf, the wind‐driven Rim Current advects mud along the shelf, contributing to levée successions and deposition on stoss sides of elongate transverse ridges. Echo‐sounder profiles reveal metre‐scale eddies over megaflutes, and breaking lee waves and internal hydraulic jumps over ridges. Megaflutes reach 600 m long and 7 m deep, yet form where the underflow, outside the flute, is no thicker than ca 2 to 5 m. Two types of elongate seaward‐facing ridges are recognized. Type 1 ridges, 2 to 5 m high, consist of bivalve‐rich muddy sand in low‐angle (3·5° to 6°) cross‐sets created by the underflow. Type 2 ridges, ca 5 m high, have crests up to 2 km long and a buried wedge‐shaped foundation (the ‘ridge‐core’) comprised of facies similar to Type 1 ridges. These ridge‐cores are blanketed on the landward side by stratified muds, and are capped by obliquely oriented ribs supporting a diverse benthic community. This facies distribution is interpreted to result from stoss‐side and lee‐side velocity and turbulence fluctuations induced by internal hydraulic jumps and breaking lee waves in overspilling portions of the underflow. Experimental results published by W.H. Snyder and co‐workers effectively explain ridge evolution and flow across the ridges, and therefore can be applied with confidence to less easily studied deep‐marine settings swept by turbidity currents.     

Tectonometamorphic evolution of the Atbashi high‐P units (Kyrgyz CAOB,Tien Shan): Implications for the closure of the Turkestan Ocean and continental subduction–exhumation of the South Kazakh continental margin

The South Tien Shan (STS) belt results from the last collision event in the western Central Asian Orogenic Belt (CAOB). Understanding its formation is of prime importance in the general framework of the CAOB. The Atbashi Range preserves high‐P (HP) rocks along the STS suture, but still, its global metamorphic evolution remains poorly constrained. Several HP units have been identified: (a) a HP tectonic mélange including boudins of mafic eclogites in a sedimentary matrix, (b) a large (>100 km long) high‐P metasedimentary unit (HPMU) and (c) a lower blueschist facies accretionary prism. Raman Spectroscopy on carbonaceous material combined with phengite and chlorite multiequilibria and isochemical phase diagram modelling indicates that the HPMU recorded homogeneous P–T conditions of 23–25 kbar and 560–570°C along the whole unit. ⁴⁰Ar/³⁹Ar dating on phengite from the HPMU ranges between 328 and 319 Ma at regional scale. These ages are interpreted as (re‐) crystallization ages of phengite during T_max conditions at a pressure range of 20–25 kbar. Thermobarometry on samples from the HP tectonic mélange provides similar metamorphic peak conditions. Thermobarometry on the blueschist to lower greenschist facies accretionary prism indicates that it underwent P–T conditions of 5–6 kbar and 290–340°C, highlighting a 17–20 kbar pressure gap between the HPMU‐tectonic mélange units and the accretionary prism. Comparison with available geochronological data suggests a very short time span between the prograde path (340 Ma), HP metamorphic peak (330 Ma), the T_max (328–319 Ma) and the final exhumation of the HPMU (303–295 Ma). Extrusion of the HPMU, accommodated by a basal thrust and an upper detachment, was driven by buoyant forces from 70–75 km up to 60 km depth, which directly followed continental subduction and detachment of the HPMU. At crustal depths, extrusion was controlled by collisional tectonics up to shallow levels. Lithological homogeneity of the HPMU and its continental‐derived character from the North Tien Shan suggest this unit corresponds to the hyper‐extended continental margin of the Kazakh continent, subducted southward below the north continental active margin of the Tarim craton. Integration of the available geological data allows us to propose a general geodynamic scenario for Tien Shan during the Carboniferous with a combination of (a) N‐dipping subduction below the Kazakh margin of Middle Tien Shan until 390–340 Ma and (b) S‐dipping subduction of remaining Turkestan marginal basins between 340 and 320 Ma.