Diagenesis of early Permian high‐latitude limestones,Lower Parmeener Supergroup,Tasmania

The Darlington (Sakmarian) and Berriedale (Artinskian) Limestones are neritic deposits that accumulated in high‐latitude environments along the south‐eastern margin of Pangea in what is now Tasmania. These rocks underwent a series of diagenetic processes that began in the marine palaeoenvironment, continued during rapid burial and were profoundly modified by alteration associated with the intrusion of Mesozoic igneous rocks. Marine diagenesis was important but contradictory; although dissolution took place, there was also coeval precipitation of fibrous calcite cement, phosphate and glauconite, as well as calcitization of aragonite shells. These processes are interpreted as having been promoted by mixing of shelf and upwelling deep ocean waters and enabled by microbial degradation of organic matter. In contrast to warm‐water carbonates where meteoric diagenesis is important, the Darlington and Berriedale Limestones were largely unaffected by meteoric diagenesis. Only minor dissolution and local cementation took place in this diagenetic environment, although mechanical compaction was ubiquitous. Correlation with burial history curves indicates that chemical compaction became important as burial depths exceeded 150 m, promoting precipitation of extensive ferroan calcite. This effect resulted from burial by rapidly deposited, overlying, thick, late Permian and Triassic terrestrial sediments. This diagenetic pathway was, however, complicated by the subsequent intrusion of massive Mesozoic diabases and associated silicifying diagenetic fluids. Finally, fractures most probably connected with Cretaceous uplift were filled with late‐stage non‐ferroan calcite cement. This study suggests that both carbonate dissolution and precipitation occur in high‐latitude marine palaeoenvironments and, therefore, the cold‐water diagenetic realm is not always destructive in terms of diagenesis. Furthermore, it appears that for the early Permian of southern Pangea at least, there was no real difference in the diagenetic pathways taken by cool‐water and cold‐water carbonates.     

Deep‐burial alteration of early‐diagenetic carbonate concretions formed in Palaeozoic deep‐marine greywackes and mudstones (Bardo Unit,Sudetes Mountains,Poland)

Carbonate concretions formed in bathyal and deeper settings have been studied less frequently than those formed in shallow‐marine deposits. Similarly, concretions affected by catagenetic conditions have rarely been reported. Calcite concretions in deep‐marine mudstones and greywackes of the Bardo Unit (Sudetes Mountains, Poland) formed during early diagenesis and were buried to significant depths. Petrographic and geochemical (elemental and stable C and O isotopic) analyses document their formation close to the sediment–water interface, prior to mechanical compaction within the sulphate reduction zone and their later burial below the oil window. Although the concretions were fully formed during early diagenesis, the effects of increased temperature and interaction with late‐diagenetic interstitial fluids can be discerned. During maximum burial, the concretions underwent thorough recrystallization that caused alteration of fabric and elemental and O isotope composition. The initial finely crystalline cement was replaced by more coarsely crystalline, sheaf‐like, poikilotopic calcite in the concretions. These large calcite crystals engulf and partially replace unstable detrital constituents. The extremely low δ¹⁸O values (down to ?21·2‰ Vienna Pee Dee Belemnite) in the concretions are the result of the increased temperature in combination with alteration of volcanic glass, both causing a significant ¹⁸O‐depletion of bicarbonate dissolved in the interstitial fluids. Recrystallization led to uniform O isotope ratios in the concretions, but did not affect the C isotope signature. The δ¹³C values of the late‐diagenetic cements precipitated in the greywacke and in cracks cutting through concretions imply crystallization in the catagenetic zone and decarboxylation as a source of the bicarbonate. These late‐diagenetic processes took place in a supposedly overpressured setting, as suggested by clastic dykes and hydrofractures that cut through both concretions and host rock. All of these features show how the effects of early and late diagenesis can be distinguished in such rocks.     

Diagenetic alterations of the upper Jurassic scleractinian corals,Hanifa Formation,Jabal Al-Abakkayn,central Saudi Arabia

During diagenetic stages, the aragonitic skeletons and the inter/intra-corallite cement of the upper Jurassic corals of Hanifa Formation either dissolved or subjected to diagenetic alterations including cementation, micritization, recrystallization, silicification, dolomitization and dedolomitization. The proposed sequence of diagenetic stages is as follows: early marine diagenesis, early meteoric and mixing zone diagenesis, late meteoric diagenesis, and shallow burial diagenesis. Each stage is characterized by certain diagenetic processes. The source of sulfate solutions for dedolomitization in the studied corals is the dissolved anhydrite deposits of the Arab–Hith Formations, sometime before their erosion. A possible source of silica, needed for the formation of chert and chalcedony, is the sponge spicules dispersed in many carbonates of the Hanifa Formation.     

准噶尔盆地玛湖凹陷下二叠统古老碱湖成因探究：来自全球碱湖沉积的启示

碱湖沉积在全球范围内均有分布,在特定的构造背景、火山活动、热液作用及气候条件下形成。我国准噶尔盆地玛湖凹陷风城组发育的碱湖沉积形成年代老且埋藏较深,在完整的沉积-成岩演化研究中具有独特优势。此外,风城组碱湖沉积的分布与页岩油藏的分布具有密切关系,其形成演化对碱湖页岩油藏研究提供重要支持。通过全球尺度下碱湖及碱湖沉积主要特征分析,总结碱湖沉积特征和成因,为准噶尔盆地玛湖凹陷风城组碱湖沉积成因分析提供借鉴。综合分析表明,同期火山活动和特定气候条件均可主控碱湖沉积的形成。此外,碱湖沉积形成需湖盆水文封闭、充足的溶质供给、低硫酸盐占比及强蒸发环境条件。汇总分析全球碱湖沉积矿物种类与埋深关系,发现成岩作用下矿物转变规律:单斜钠钙石随成岩作用增强依次转变为钙水碱、碳钠钙石,苏打石和天然碱转变为碳酸氢钠石。通过与全球碱湖沉积实例对比分析可知,玛湖凹陷风城组碱湖沉积中碳酸氢钠石和碳钠钙石经成岩作用形成,钠硅酸盐矿物和特征矿物与火山活动及热液作用有关。碳酸氢钠石生长形态及磁黄铁矿指示玛湖凹陷风城组碱湖沉积中心为高盐度分层且底部缺氧的常年生湖泊。下二叠统风城组碱湖沉积形成与周缘火山岩及同沉积火山活动密切相关,受气候、构造背景、火山活动和后期成岩作用的共同控制。     

The ordovician (caradoc) volcanic rocks of montgomery,Powys, N. Wales

The Ordovician (Caradoc, Soudleyan) rocks of Montgomery, Powys are shales interbedded with locally conglomeratic volcaniclastic sediments composed of andesitic detritus. New formal lithostratigraphic units are proposed: Montgomery Volcanic Group comprising in ascending order: Castle Hill Shale Formation, Castle Hill Conglomerate Formation and Quarry Sandstone and Shale Formation. The volcaniclastic strata are reinterpreted as deposits of a submarine volcaniclastic fan system sourced by contemporaneous andesitic island volcanism. The observed diagenetic sequence is typical of marine volcanic sandstones and was dominated by hydration reactions related to the degradation of abundant unstable volcanic detritus. Diagenesis has resulted in the virtual destruction of original porosity in the volcaniclastic rocks.     

Neogene evaporites in desert volcanic environments: Atacama Desert, northern Chile

The Upper Miocene and Pliocene evaporite deposits of the Atacama Desert of northern Chile (Hilaricos and Soledad Formations) are among the few non‐marine evaporites in which aridity not only formed the deposits, but has also preserved them almost unaltered under near‐surface conditions. These deposits are largely composed of displacive Ca sulphate and halite together with minor amounts of glauberite, thenardite and polyhalite. However, at the base and top of these deposits, there are also beds of gypsum crystal pseudomorphs that originally formed as free‐growth forms within shallow brine bodies, rather than as displacive sediments. The halite is present as interstitial cement, displacive cubes and shallow‐water, bottom‐growth chevron crusts. Most of the calcium sulphate is presently anhydrite, pseudomorphous after gypsum, that was the primary depositional sulphate mineral. The secondary anhydrite formed under early diagenetic conditions after slight burial (some metres) resulting from the effect of strongly evolved pore brines. The anhydrite has been preserved without rehydration during late diagenetic and exhumation stages on account of the arid environment of the Atacama Desert. Both the Hilaricos and the Soledad Formations contain geochemical markers indicating that these Neogene evaporites had a largely non‐marine origin. Bromine content in the halite is very low (few p.p.m.), indicating neither a sedimentological relation with sea water nor the likelihood of direct recycling of prior marine halites. Moreover, the δ³⁴S of sulphates (+4·5‰ to +9‰) also reflects a non‐marine origin, with a strong volcanic influence, although some recycling of Mesozoic marine sulphates cannot be ruled out. δ³⁴S of dissolved sulphate from hot springs and streams in the area commonly displays positive values (+2‰ to +10‰). Leaching of oxidized sulphur and chlorine compounds from volcanoes and epithermal ore bodies, very common in the associated drainage areas, have been the main contribution to the accumulation of evaporites. The sedimentary and diagenetic evolution of the Hilaricos and Soledad evaporites (based on lithofacies analysis) provides information about the palaeohydrological conditions in the Central Depression of northern Chile during the Neogene. In addition, the diagenesis and exhumation history of these evaporites confirms the persistence of strongly arid conditions from Late Miocene until the present. A final phase of tectonism took place permitting the internal drainage to change and open to the sea, resulting in dissolution and removal of a significant portion of these deposits. Despite the extensive dissolution, the remaining evaporites have undergone little late exhumational hydration.     

华南地区栖霞组菊花状天青石的交代及其地质意义

本文在收集大量菊花石标本的基础上，通过岩石薄片镜下鉴定及X射线衍射分析，识别了华南地区栖霞组菊花石假象内矿物的成因类型，建立了矿物交代序列，并通过对菊花石假象内各种矿物成分的电子探针分析和对交代方解石，脉方解石及其围岩的氧，碳同位素分析，探讨了菊花石交代过程中的成岩环境,合理地解释了菊花石内正延性玉髓和栖霞组内海泡石的成因。     

http://www.sciencedirect.com/science/article/pii/S1674987112000035

The well SK-I in the Songliao Basin is the first scientific borehole targeting the continental Cretaceous strata in China.Oval concretions,thin laminae and beds of dolostone are found intercalated within mudstone and organic-rich black shale in the Nenjiang Formation of Campanian age.Low ordered ferruginous dolomite is composed of euhedral-subhedral rhombs with cloudy nucleus and light rims formed during the diagenesis.which are typical features of replacement.The heavy carbon isotopes (δ¹³C_PDB-1.16-16.0) are results of both the fermentation of organic matter by microbes and degassing of carbon dioxide during the period of diagenesis,and the presence of light oxygen isotopes(δ¹⁸O_Pdb- 18.53～-5.1) is a characteristic feature of fresh water influence which means the carbonate may have been altered by ground water or rainwater in the late diagenesis.Marine water incursions into the normally lacustrine basin have been proved by both the salinity of Z value and the occurrence of foraminifera in the same strata where dolomite occurs.Pyrite framboids observed by SEM are usually enclosed in the dolomite crystals or in the mudstones,supporting the sulfate reducing bacteria（SRB）.The formation of both dolomite and pyrite are associated with marine water incursions,which not only supply magnesium ion for dolomite,but also result in limited carbonate precipitation in the basin.The presence of pyrite tramboids indicates the development of an anoxic environment associated with salinity stratification in the lake.The dolomite in the Nenjiang Formation is the results of marine water incursions,diagenetic replacement of calcareous carbonate and sulfate reducing bacteria（SRB）.     

Very early diagenesis in a calcareous,organic-rich mudrock from Jordan

The diagenesis in the organic-rich Cretaceous to Eocene Al Hisa Phosphorite Formation (AHP), Muwaqqar Chalk Marl Formation (MCM) and Umm Rijam Chert-Limestone Formation (URC) formations of Jordan can be linked directly to the fluctuating sedimentary environment of this shelf depositional system in the Middle to Late Eocene, and its influence on the composition of the deposited sediment and the early burial diagenetic environment. Most cementation was early, mostly within the first 10 m of burial, perhaps entirely within the first 100 m of burial. We propose that the siliceous cements are derived from biogenic silica, probably of diatoms, deposited in a shelf of enhanced productivity. Volumetrically, the most important processes were the redistribution of biogenic opal-A (diatoms) and calcite to form pervasive, layered and nodular cements. The formation of the silica and carbonate cements is closely linked through the effects their dissolution and precipitation have on pore fluid chemistry and pH. The chert beds have a biogenic silica origin, formed through replacement of diatoms and radiolaria by opal-CT, and subsequently by quartz. Calcite cement has carbonate derived from microbial diagenesis of organic matter and calcium derived from seawater. The Mg for early dolomite may have been generated by replacement of opal-CT by quartz, ore dissolution of unstable high Mg calcite bioclasts. The silica and carbonate diagenetic processes are both linked to microbial diagenesis of organic matter, and are intimately linked in both time and space, with pH possibly influencing whether a silica or a carbonate mineral precipitates. The paucity of metal cations capable of precipitating as sulphides is crucial to the creation of acidic pore water favourable to silica precipitation, either as opal-CT, chalcedony or quartz. The lack of clay minerals as a sink for the Mg required for opal-CT polymerisation is the principal factor responsible for the remarkably early silica cementation. All the diagenetic processes, with the probable exception of the opal-CT to quartz transition are early, almost certainly within the first 10 m of burial, possibly much less. A paragenetic sequence is presented here based on these two cores that should be tested against a wider core distribution to see whether this diagenetic history can be generalised throughout the basin. Warm bottom water temperatures probably led to silica diagenesis at much shallower burial depths than occurs in many other sedimentary basins. Silicified layers, in turn, commonly host fractures, suggesting that mechanical properties of the strata began to differentiate at a very early stage in the burial cycle. This has wide implications for processes linking diagenesis to deformation.     

Cenozoic phosphatic deposits in North Patagonia,Argentina: Phosphogenesis,sequence-stratigraphy and paleoceanography

Paleoenvironmental analysis of the Cenozoic marine section cropping out near Gaiman (Chubut Province, Argentina) shows that most of the local succession was deposited in a shallow, storm-dominated marine environment, bearing well preserved Ophiomorpha fossil traces. Sequence-stratigraphic interpretation records the effect of three sea-level oscillations. Phosphatic strata are related to mostly in situ concretions developed within transgressive-early highstand system tracts (Type 1) and to reworked and winnowed lags associated with transgressive surfaces (Type 2) which display a concentration of phosphatic concretions, ooids, vertebrate bones, teeth and shells. Close association of Callianasid bioturbation (Ophiomorpha) and phosphatic levels suggest a genetic link for both, via improved early-diagenetic water circulation and Fe and P early-diagenetic cycling. Phosphogenesis would have taken place after cold and corrosive water, probably similar to the present Antarctic Intermediate Water (AAIW), flooded the continental shelf and mixed with warmer surficial waters. This mixing could explain the contrasting indications from the marine vertebrate fauna together with the general corrosion and replacement processes that are common in the Gaiman strata. The development of the phosphorites would have occurred at times of global climatic transition and increased oceanic circulation, probably during the Late Oligocene–Early Miocene.     

歧口凹陷沙河街组火山岩成岩作用及对储集性能的控制

根据岩心观察资料,利用偏光显微镜、扫描电镜等对歧口凹陷沙河街组火山岩的成岩作用进行了详细地研究,把成岩作用类型分为早期和晚期两个阶段、13种成岩作用类型。根据成岩作用阶段划分依据,结合盆地埋藏-热演化史和烃类充注史等资料,将歧口凹陷沙河街组火成岩成岩作用阶段划分为早期和晚期两个阶段。火成岩共发生了3期溶蚀作用、2期构造作用、2期油气充注作用,以及绿泥石、硅质、碳酸盐等胶结作用。主要成岩序列为溶蚀作用Ⅰ→构造作用Ⅰ→栉壳状绿泥石→细纤维状绿泥石→硅质Ⅰ→较粗纤维状绿泥石→烃类充注Ⅰ→硅质充填Ⅱ→亮晶方解石Ⅰ→构造作用Ⅱ→溶蚀作用Ⅱ→烃类充注Ⅱ→亮晶方解石Ⅱ→铁方解石→硅质充填Ⅲ→溶蚀作用Ⅲ。成岩作用对储集性能的控制具有改善和破坏的双重作用,对储集性能具有改善作用的成岩作用类型有挥发分逸出作用、熔蚀作用、冷凝收缩作用、脱玻化作用、机械压实破裂作用、风化淋滤溶蚀作用、次生溶蚀作用。对储集性能具有破坏作用的成岩作用类型有熔结作用、充填作用、机械压实压溶作用、胶结作用。     

Sedimentation, depositional environment and diagenesis of Eocene biosiliceous deposits in Gafsa basin (southern Tunisia)

The sedimentary rocks of the Metlaoui Formation in the Gafsa basin (southern Tunisia), which may be grouped in three units: the basal (Thèlja), middle (Chouabine) and upper unit (Kef Eddour), provide a record of preserved sedimentary, authigenic and biological processes. This paper presents the findings of sedimentological investigations of the biosiliceous deposits of the middle unit. This unit contains either well-preserved (Opal-A) or diagenetically altered (Opal-CT, clinoptilolite, quartz and even clays) diatom frustules. Such diagenetic changes are commonly described in marine and lacustrine biosiliceous deposits. The fossil content of theses diatomaceous layers implies shallow-marine conditions.The opal-rich sediments, and the associated facies record the transgressive transitions associated with high organic productivity, probably enhanced by seasonal input of nutrients, and high sea level stands, and a close association with stratified water column conditions. The formation of bedded diatomaceous sediments is known to require either high organic productivity or anoxic conditions in bottom/intermediate water, and eventually both processes. The initial organic content of the biogenic deposits was impoverished in early stages of sedimentation and diagenesis. A large part of the organic matter could have been destroyed during early diagenetic processes and from further oxidation in outcrops.     

塔里木盆地西北地区震旦系苏盖特布拉克组潮坪相碎屑岩成岩作用与成岩演化研究

塔里木盆地西北地区苏盖特布拉克组发育一套潮坪相沉积,是该层系油气勘探的主要目标。基于什艾日克剖面、奇格布拉克剖面、肖尔布拉克剖面的地质测量,采用薄片鉴定、阴极发光、扫描电镜、流体包裹体测温及黏土矿物X衍射等分析手段开展海相碎屑岩成岩作用和成岩演化研究,为塔里木盆地苏盖特布拉克组进一步开展油气勘探部署和甜点储层预测提供地质依据。结果表明：（1）研究区苏盖特布拉克组发育潮坪沉积环境的砂体,砂岩类型以岩屑石英砂岩、岩屑砂岩为主,偶见长石岩屑砂岩,成分成熟度和结构成熟度中等;（2）苏盖特布拉克组砂岩经历了压实（溶）作用、胶结作用、溶蚀作用及交代作用等成岩作用,压实作用是造成储层致密的直接原因,钙质胶结和硅质胶结是储层致密化的根本因素;（3）苏盖特布拉克组砂岩的成岩演化阶段已达到中成岩B期,成岩演化序列为：压实作用/自生黏土矿物（绿泥石）环边—第一期长石、岩屑溶蚀作用—第一期硅质胶结—第一期泥微晶方解石胶结/压溶作用/黏土矿物的伊利化—第二次硅质胶结/第二期铁方解石胶结—钙质胶结物溶蚀。据此建立的成岩演化模式为塔里木盆地超深层致密砂岩中甜点储层预测提供可靠的地质依据。     

Geochemistry of phosphate bearing sedimentary rocks in parts of Sonrai block,Lalitpur District,Uttar Pradesh,India

Major, trace and rare earth elements of phosphatic rocks around Sonrai block of Paleo-Mesoproterozoic age having phosphatic breccia, quartzite, shale, sandstone, limestone and ironstone, have been determined to evaluate their correlation, relationship with the phosphorus content, the nature of possible substitution of various elements and regional distribution pattern over the area. The study indicates that the number of elements is substituted in the apatite structures; few of them are associated with phosphate and carbonate minerals. The variable concentration of major, trace and rare earth elements in the phosphatic rocks has been influenced by various physico-chemical processes involved during weathering and leaching of the source rocks. The distribution of the major, trace and rare earth elements is controlled by the environmental variations in the sediment water interface. The majority of trace elements were mainly influenced by the principle adsorbents like the phosphate minerals in addition to clay, iron oxides and silicate minerals. The PAAS normalized REE patterns of Sonrai block of phosphorites are characterized by negative Ce anomalies and Positive Eu anomalies. It is inferred from the distribution and interrelationship of major, trace and rare earth elements that the deposition of phosphate minerals might have occurred in highly oxidizing to slightly reducing conditions in supratidal to intertidal continental margins and shallow marine environment. The deposition was controlled by marine upwelling leading to excess charge of phosphate in certain zones of phosphogenic basins, lithologic facies variations in restricted circulations of basinal waters and electrochemical factors such as negative Eh, pH and other factors, which influenced the deposition of phosphates. The replacement, precipitation in voids and fissures and diagenesis were also important mechanisms of phosphate generation in Sonrai basin. The main source for various elements may be the minerals of cratonic mass of Bundelkhand Granitic Complex, a basement of Bijawar Basin, which also provided land derived phosphorus through weathering of the terrestrial cover.     

Structural CO2 in the Apatite of the Late Cretaceous Phosphorite Resources in Egypt: Effect on the Crystal Chemistry and Geologic Implications

Abstract: Phosphorite deposits in Egypt, known as the Duwi Formation, are a part of the Middle East to North Africa phospho‐genic province of late Cretaceous to Paleogene age. Based on the petrographical observation, the phosphatic grains in the phosphorites are classified into phosphatic mudclasts and phosphatic bioclasts. Both of them are composed of francolite. The structural CO₂ contents in the francolite range from 3.3 to 7.2 % with an average of 5.3 %. Results indicated that the substitution with CO₃^2‐ of PO₄^3‐ in the francolite decreases the unit cell volume and a‐cell dimension, and increases the c/a ratio. Effect is more obvious in the a‐cell dimension; therefore, it is more significant in distinction between the different apatite species. Lack of covariance between structural CO₂ contents in the francolite and the carbonate minerals contents may render the supposition that the phosphorites formed as a result of replacement of preexisting calcareous sediments is doubtful. Similarity in CO₂ content in both weathered and fresh samples indicates that the structural CO₂ content in the phosphorites is not affected by weathering, and reflects the conditions and CO₂ concentration of the depositional environment. Similarity in mineralogy and CO₂ contents in the different phosphatic grains and higher CO₂ content in the Egyptian phosphorites compared with the authigenic phosphates of Peru margin, which formed by the same mechanism as the Duwi phosphorites, suggest that the phosphatic grains in the Duwi Formation were francolitized during diagenesis by introducing CO₂ from the surrounding pore water and diagenesis took place at an elevated temperature. Scattered values of structural CO₂ contents suggest the reworking origin of the phosphatic grains in the late Cretaceous phosphorites in Egypt.     

湖北省巴东栖霞组沉积成岩作用地球化学特征研究

在详细的沉积作用、成岩作用研究基础上,利用多元统计分析方法重点对湖北省巴东水布垭剖面栖霞组碳酸盐岩地球化学特征进行了分析。研究表明,该组碳酸盐岩中 CaO 、Al₂O₃ 、K₂O 、Fe₂O₃ 、P、Ba 和 Mn的含量主要与沉积环境或原岩岩性有关,地层中SiO₂、MgO 、Sr 和 Na 的含量主要与成岩作用有关。建立了栖霞组沉积成岩作用地球化学模式。该研究合理地解释了本组岩石特殊的地球化学特征,深化了对该组岩石形成环境,特别是成岩环境的认识,区分了沉积作用和成岩作用对该组岩石地球化学特征的影响,对合理地选取有关地球化学参数研究该组岩石及类似地层的沉积作用和成岩作用具参考价值。     

吉林伊通盆地莫里青断陷古近系双阳组储集层成岩作用研究

古近系双阳组是在吉林省伊通盆地莫里青断陷中，油气赋存的主要层位,储层主要为湖底扇和扇三角洲的砂体。依据双阳组储层的大量薄片、扫描电镜、粘土矿物分析的资料研究了该储集层的成岩作用。研究结果表明双阳组储集层：成岩作用经历了压实、压溶、胶结、交代和溶解6方面的作用。双储集层中的自生粘土矿物蒙皂石向伊利石转化具有明显的特征：主要演化过程经历了蒙皂石渐变带，第一迅速转化带和第二迅速转化带，相应的成岩作用阶段可划分为早成岩阶段B期、晚成岩阶段A1期和晚成岩阶段A2期。依据在垂向上的成岩变化,建立了莫里青断陷双阳组储集层的成岩作用演化序列。在垂向上成岩作用的类型和强度均存在明显的差异，造成了储层物性的垂向分带。     

Silicification of sulphate evaporites and their carbonate replacements in Eocene marine sediments, Tunisia: two diagenetic trends

Samples of chert nodules, diagenetic carbonates and evaporites (gypsum/anhydrite) collected from the gypsiferous limestones of the Kef Eddour Member (Ypressian‐Priabonian) near Metlaoui and Sehib (Tunisia) show selective silicification with great variety in the silicified by‐products. Based on δ¹³C values, which support an organic origin for the carbon, carbonates replaced evaporites microbially through bacterial sulphate reduction. Observations and results suggest two scenarios for chert formation that are related to the rate and timing of diagenetic carbonate replacement of the evaporites (anhydrite/gypsum). In the absence of early diagenetic carbonate phases, silica with δ¹⁸O values from +25 to +28·6‰ [standard mean ocean water (SMOW)] replaced the outer parts of anhydrite nodules at pH < 9. In contrast, pore‐fluid pH values > 9 in the innermost parts of the anhydrite nodules prevented silica precipitation. The record of this chemical barrier is preserved in the microquartz rims and geode features that formed in the inner parts of the nodules after dissolution of the anhydrite nucleus. The microbial diagenetic replacement of evaporites (bacterial sulphate reduction) by carbonates (calcite, aragonite and dolomite) favoured silica replacement of carbonates rather than evaporites. Silica, with δ¹⁸O signature of +21 to +26‰ (SMOW), replaced carbonates on a volume‐for‐volume basis, yielding a more siliceous groundmass, and accounting for 90–95% of the nodules. The relatively higher δ¹⁸O values of quartz replacing anhydrite can be explained by a diagenetic fluid in equilibrium with mixed (meteoric/marine) to marine water. The lower δ¹⁸O values of the quartz that replaced the diagenetic carbonates are ascribed to flushing by meteoric water in a later diagenetic stage. The silica supply for chert formation could be derived from the reworked bio‐siliceous deposits (diatomites) to the west of the basin [vestiges of an opal‐CT precursor undetectable by X‐ray diffraction (XRD) were revealed by δ²⁹Si magic‐angle‐spinning nuclear magnetic resonance investigations], diagenesis of the extraformational and overlying clay‐rich beds (the host limestones are clay‐poor as shown by XRD measurements), and minor volcanogenic and hydrothermal contributions during early diagenetic stages.     

渤海湾盆地埕岛东斜坡地区东三段油气成岩成藏模式

通过分析埕岛东斜坡地区东三段砂岩成岩作用特征 ,以及对该地区油气成藏系统的研究 ,总结出东三段砂岩体的成岩成藏模式。东三段上部砂体成藏于馆陶组沉积期 ,对应于早成岩 B期阶段 ,油气过早进入砂岩体 ,充填了孔隙 ,抑制了成岩作用的进行 ,使原生孔隙得以良好的保存。目前该砂体位于晚成岩 A期阶段 ,伴随形成了次生孔隙 ,并正处于第二次成藏期     

富磷矿三阶段动态成矿模式:黔中开阳式高品位磷矿成矿机制

震旦系陡山沱组沉积期形成的黔中开阳、瓮安富磷矿沉积区,矿石产量大、品位高,是国内外重要的磷矿资源产区。黔中磷矿主要分布于黔中古陆周缘的滨浅海环境中,矿石类型以碎屑状磷块岩为主,间夹原生泥晶磷块岩、生物结构磷块岩和次生土状结构磷块岩。开阳式高品位磷块岩的动态沉积成矿过程通常为“三阶段成矿”: 第一阶段为初始成磷作用阶段,在新元古代大规模成磷背景下,上升洋流携带深部富磷海水进入滨浅海地区,并通过生物化学作用使磷质聚集并形成原生磷块岩沉积;第二阶段为簸选成矿作用阶段,高能波浪、风暴水流对原生磷块岩持续的破碎、磨蚀、搬运和再沉积过程中,簸选去除了原生沉积物中的陆源细碎屑、砂泥质成分,保留并聚集磷质碎屑颗粒,形成品位较高的碎屑状矿石;第三阶段为淋滤作用阶段,海平面升降变化使之前形成矿石受暴露事件影响,遭受强烈的风化淋滤作用,碎屑状磷矿石内的碳酸盐岩胶结物和白云石条带被淋滤运移,导致矿层发育大量溶蚀孔洞,甚至形成土状磷块岩,矿石品位再次得到大幅度提升。三阶段成矿作用随古地理条件和海平面变化在沉积成岩过程中多期次、动态进行,最终形成工业价值极高的磷矿石。