Extensive normal faulting during exhumation revealed by the spatial variation of phengite K–Ar ages in the Sambagawa metamorphic rocks,central Shikoku,SW Japan

Metamorphic rocks experience change in the mode of deformation from ductile flow to brittle failure during their exhumation. We investigated the spatial variation of phengite K–Ar ages of pelitic schist of the Sambagawa metamorphic rocks (sensu lato) from the Saruta River area, central Shikoku, to evaluate if those ages are disturbed by faults or not. As a result, we found that these ages change by ca 5 my across the two boundaries between the lower‐garnet and albite–biotite, and the albite–biotite and upper‐garnet zones. These spatial changes in phengite K–Ar ages were perhaps caused by truncation of the metamorphic layers by large‐scale normal faulting at D₂ phase under the brittle‐ductile transition conditions (ca 300°C) during exhumation, because an actinolite rock was formed along a fault near the former boundary. Assuming that the horizontal metamorphic layers and a previously estimated exhumation rate of 1 km/my before the D₂ phase, the change of 5 my in phengite K–Ar ages is converted to a displacement of about 10 km along the north‐dipping, low‐angle normal fault documented in the previous study. Phengite ⁴⁰Ar–³⁹Ar ages (ca 85 to 78 Ma) in the actinolite rock could be reasonably comparable to the phengite K–Ar ages of the surrounding non‐faulted pelitic schist, because the K–Ar ages of pelitic schist could have been also reset at temperatures close to the brittle–ductile transition conditions far below the closure temperature for thermal retention of argon in phengite (about 500–600°C).     

A new occurrence of retrogressed eclogite from the Sanbagawa belt of southwest Japan and its significance

The present paper reports, for the first time, the occurrence of an omphacite‐bearing mafic schist from the Asemi‐gawa region of the Sanbagawa belt (southwest Japan). The mafic schist occurs as thin layers within pelitic schist of the albite–biotite zone. Omphacite in the mafic schist only occurs as inclusions in garnet, and albite is the major Na phase in the matrix, suggesting that the mafic schist represents highly retrogressed eclogite. Garnet grains in the sample show prograde‐type compositional zoning with no textural or compositional break, and contain mineral inclusions of omphacite, quartz, glaucophane, barroisite/hornblende, epidote and titanite. In addition to the petrographic observations, Raman spectroscopy and focused ion beam system–transmission electron microscope analyses were used for identification of omphacite in the sample. The omphacite in the sample shows a strong Raman peak at 678 cm^?1, and concomitant Raman peaks are all consistent with those of the reference omphacite Raman spectrum. The selected area electron diffraction pattern of the omphacite is compatible with the common P2/n omphacite structure. Quartz inclusions in the mafic schist preserve high residual pressure values of Δω₁ > 8.5 cm^?1, corresponding to the eclogite facies conditions. The combination of Raman geothermobarometries and garnet–clinopyroxene geothermometry gives peak pressure–temperature (P–T) conditions of 1.7–2.0 GPa and 440–540 °C for the mafic schist. The peak P–T values are comparable to those of the schistose eclogitic rocks in other Sanbagawa eclogite units of Shikoku. These findings along with previous age constraints suggest that most of the Sanbagawa schistose eclogites and associated metasedimentary rocks share similar simple P–T histories along the Late Cretaceous subduction zone.     

Geological and mineralogical study of eclogite and glaucophane schists in the Naga Hills Ophiolite,Northeast India

A variety of low‐ to high‐pressure metamorphic assemblages occur in the metabasic rocks and metachert in the Upper Cretaceous–Eocene ophiolite belt of the central part of the Naga Hills, an area in the northern sector of the Indo–Myanmar Ranges in the Indo–Eurasian collision zone. The ophiolite suite includes peridotite tectonite containing garnet lherzolite xenoliths, layered ultramafic–mafic cumulates, metabasic rocks, basaltic lava, volcaniclastics, plagiogranite, and pelagic sediments emplaced as dismembered and imbricated bodies at thrust contacts between moderately metamorphosed accretionary rocks/basement (Nimi Formation/Naga Metamorphics) and marine sediments (Disang Flysch). It is overlain by coarse clastic Paleogene sediments of ophiolite‐derived rocks (Jopi/Phokphur Formation). The metabasic rocks, including high‐grade barroisite/glaucophane‐bearing epidote eclogite and glaucophane schist, and low‐grade greenschist and prehnite–clinochlore schist, are associated with lava flows and ultramafic cumulates at the western thrust contact. Chemically, the metabasites show a low‐K tholeiitic affinity that favors derivation from a depleted mantle source as in the case of mid‐ocean ridge basalt. Thermobarometry indicates peak P–T conditions of about 20 kb and 525°C. Retrogression related to uplift is marked by replacement of barroisite and omphacite by glaucophane followed by secondary actinolite, albite, and chlorite formation. A metabasic lens with an eclogite core surrounded by successive layers of glaucophane schist and greenschist provides field evidence of retrogression and uplift. Presence of S‐C mylonite in garnet lherzolite and ‘mica fish’ in glaucophane schist indicates ductile deformation in the shear zone along which the ophiolite was emplaced.     

Geochemistry of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex,South Sulawesi,Indonesia: Protolith origin and tectonic setting

We present the first data on bulk‐rock major and trace element compositions for a suite of eclogite‐ and blueschist‐facies rocks from the Bantimala Complex, Indonesia, with the aim of better constraining the protolith origins and nature of the subducted crust. The eclogites can be classified into two groups: glaucophane‐rich eclogite and glaucophane‐free eclogite, whereas the blueschists are divided into albite–epidote glaucophanite and quartz–glaucophane schists. SiO₂ contents of the eclogites are 43.3–49.6 wt%, with Na₂O + K₂O contents 3.7–4.7 wt%. The blueschists show a wider range of compositions, with SiO₂ = 40.7–63.8 wt% and Na₂O + K₂O = 2.7–4.5 wt%. Trace element data suggest that the eclogite protoliths include both enriched and normal mid‐oceanic ridge basalt (E‐MORB and N‐MORB) and also gabbroic cumulates. The blueschists show more variation in protoliths, which include N‐MORB, Oceanic Island Basalt (OIB) and Island Arc Basalt (IAB). Plots of element concentrations against the immobile Zr show considerable mobility of large ion lithophiles but not of high field‐strength elements during high‐pressure metamorphism, and indicate that the high SiO₂ content of some blueschists is probably due to metasomatism by a LILE‐rich siliceous aqueous fluid. Strong correlations between K, Rb, Ba and Cs suggests that enrichment of these elements occurred by a single process. All the protoliths were subducted, metamorphosed to blueschist/eclogite‐facies and subsequently exhumed. It is noteworthy that the samples deduced to have come from thicker‐crust environments (OIB, IAB) were subducted to shallower depths (blueschist‐facies) than MORB‐derived samples, all except one of which reached eclogite‐facies conditions. The geochemical data of this study demonstrate the variety of ocean floor types that were subducted under the southeast margin of Sundaland in the late Jurassic period.     

Eclogites of southern Henan and northern Hubei Provinces, central China

Abstract According to field occurrence and P-T condition, eclogites of southern Henan and northern Hubei Provinces can be divided into two types: medium temperature (MT) and low temperature (LT) eclogites. MT eclogite occurs as layers or lenticular bodies within migmatized gneiss of the Dabie Group. This study is the first to report an occurrence of the assemblages coesite and kyanite + talc in this area. Garnet exhibits a distinct prograde compositional zoning and has mineral inclusions with rotational textures indicating syntectonic growth. Five evolutionary stages are outlined. (1) Pre-eclogite stage, determined by the inclusions of barroisite + zoisite + quartz in the cores of zoned garnets. (2) Eclogite stage, characterized by garnet + omphacite + kyanite ± talc + coesite + rutile, represents the peak metamorphism. The peak conditions are estimated to be T = 600-700°C, P >27 kb. (3) Glaucophane stage, without an appearance of plagioclase, is assigned to a transitional stage. Blades of glaucophane form rims around garnet grains as a result of the reaction talc + jadeite = glaucophane. This marks the beginning of retrograde metamorphism. (4) Symplectite stage, where eclogitic minerals break down, and Amp + Pl symplectite develops around garnet or omphacite; (5) Later retrograde stage is represented by epidote-amphibolite assemblages. Low temperature eclogite appears as blocks in the Qijiaoshan Formation (part of the Susong Group). Four stages can be identified: (1) Pre-eclogite stage, amphibole + epidote + sphene inclusions occur in garnet core; (2) Eclogite stage, consists of garnet + omphacite + rutile + quartz + phengite + glaucophane + zoisite. The peak conditions are T = 490-560°C, P <15 kb; (3) Symplectitic stage, is characterized by the breakdown of eclogitic minerals; (4) Greenschist facies stage, is recorded by a greenschist facies assemblage. The difference between the two types of eclogites suggests contrasting processes. A model is proposed whereby partial melting of continental crust and the emplacement of tonalite occurs during the exhumation of ultrahigh-pressure eclogite terrain.     

The versatility of petrological modeling: Thermobarometry of high-pressure metabasites from the Renge and Sanbagawa belts and phase evolution during warm subduction at Nankai

Petrological modeling is a powerful technique to address different types of geological problems via phase-equilibria predictions at different pressure–temperature-composition conditions. Here, we show the versatility of this technique by (1) performing thermobarometrical calculations using phase equilibrium diagrams to explore the petrological evolution of high-pressure (HP) metabasites from the Renge and Sanbagawa belts, Japan and (2) forward-modeling the mineral–melt evolution of the subducted fresh and altered oceanic crust along the Nankai subduction zone geotherm at the Kii peninsula, Japan. In the first case, we selected three representative samples from these metamorphic belts: a glaucophane eclogite and a garnet glaucophane schist from the Renge belt (Omi area) and a quartz eclogite from the Sanbagawa belt (Besshi area). We calculated the peak metamorphic conditions at ~2.0–2.3 GPa and ~550–630 °C for the HP metabasites from the Renge belt, whereas for the quartz eclogite, the peak equilibrium conditions were calculated at 2.5–2.8 GPa and ~640–750 °C. According to our models, the quartz eclogite experienced partial melting after peak metamorphism. In terms of the petrological evolution of the subducted uppermost portion of the oceanic crust along the warm Nankai geotherm, our models show that fluid release occurs at ~20–60 km, likely promoting high pore-fluid pressure, and thus, seismicity at these depths; dehydration is controlled by chlorite breakdown. Our petrological models predict partial melting at >60 km, mainly driven by phengite and amphibole breakdown. According to our models, the melt proportion is relatively small, suggesting that slab anatexis is not an efficient mechanism for generating voluminous magmatism at these conditions. Modeled melt compositions correspond to high-SiO₂ adakites; these are similar to compositions found in the Daisen and Sambe volcanoes, in southwest Japan, suggesting that the modeled melts may serve as an analog to explain adakite petrogenesis.     

Petrology and retrograde P-T path for eclogites of the Maksyutov Complex, Southern Ural Mountains, Russia

Abstract The Maksyutov Complex, situated in the southern Ural Mountains of Russia, is the first location where quartz aggregates within garnets exhibiting radial fractures were identified as coesite pseudomorphs (Chesnokov & Popov 1965). The complex consists of two tectonic units: a structurally lower eclogite-bearing schist unit and an overlying meta-ophiolite unit. Both units show evidence for multiple stages of metamorphism and deformation. The high-pressure metamorphism of the eclogite-bearing schist unit, discussed in this report, is suspected to be related to a collision between the Russian platform and a fragment of the Siberian continent during the early Cambrian. At least three stages of metamorphism (M_1-3) and two stages of deformation (S₁ and S₂) were observed in thin sections: M₁) garnet (Alm_55-60, Prp_22-28, Grs_16-20) + omphacite (Jd_46-56) + phengite (Si ≅ 3.5) + rutile; M₂) garnet + glaucophane ± lawsonite + white mica; and M₃) epidote + chlorite ± albite ± actinolite + white mica. Observed mineral parageneses define a retrograde P-T path for the eclogite. Mineral assemblages within the most representative eclogite from the lower unit of the Maksyutov Complex indicate minimum peak pressures of 15 kbar at temperatures of approximately 600°C. If the presence of coesite pseudomorph is confirmed, the peak ultrahigh-pressure metamorphism may be as high as 27 kbar at 615°C.     

Thermobaric structure of the Kokchetav ultrahigh-pressure–high-pressure massif deduced from a north–south transect in the Kulet and Saldat–Kol regions, northern Kazakhstan

Abstract To investigate the regional thermobaric structure of the diamondiferous Kokchetav ultrahigh‐pressure and high‐pressure (UHP–HP) massif and adjacent units, eclogite and other metabasites in the Kulet and Saldat–Kol regions, northern Kazakhstan, were examined. The UHP–HP massif is subdivided into four units, bounded by subhorizontal faults. Unit I is situated at the lowest level of the massif and consists of garnet–amphibolite and acidic gneiss with minor pelitic schist and orthogneiss. Unit II, which structurally overlies Unit I, is composed mainly of pelitic schist and gneiss, and whiteschist locally with abundant eclogite blocks. The primary minerals observed in Kulet and Saldat–Kol eclogites are omphacite, sodic augite, garnet, quartz, rutile and minor barroisite, hornblende, zoisite, clinozoisite and phengite. Rare kyanite occurs as inclusions in garnet. Coesite inclusions occur in garnet porphyroblasts in whiteschist from Kulet, which are closely associated with eclogite masses. Unit III consists of alternating orthogneiss and amphibolite with local eclogite masses. The structurally highest unit, Unit IV, is composed of quartzitic schist with minor pelitic, calcareous, and basic schist intercalations. Mineral assemblages and compositions, and occurrences of polymorphs of SiO₂ (quartz or coesite) in metabasites and associated rocks in the Kulet and Saldat–Kol regions indicate that the metamorphic grades correspond to epidote–amphibolite, through high‐pressure amphibolite and quartz–eclogite, to coesite–eclogite facies conditions. Based on estimations by several geothermobarometers, eclogite from Unit II yielded the highest peak pressure and temperature conditions in the UHP–HP massif, with metamorphic pressure and temperature decreasing towards the upper and lower structural units. The observed thermobaric structure is subhorizontal. The UHP–HP massif is overlain by a weakly metamorphosed unit to the north and is underlain by the low‐pressure Daulet Suite to the south; boundaries are subhorizontal faults. There is a distinct pressure gap across these boundaries. These suggest that the highest grade unit, Unit II, has been selectively extruded from the greatest depths within the UHP–HP unit during the exhumation process, and that all of the UHP–HP unit has been tectonically intruded and juxtaposed into the adjacent lower grade units at shallower depths of about 10 km.     

Talc-phengite-albite assemblage in piemontite-quartz schist of the Sanbagawa metamorphic belt, central Shikoku, Japan

Abstract The talc (Tlc) + phengite (Phn) + albite (Ab) assemblage is newly confirmed in MnO^total-rich (1.65 wt% in average) piemontite-quartz schists from the intermediate- and high-grade part of the Sanbagawa belt, central Shikoku, Japan. Talc is in direct contact with Phn, Ab and chlorite (Chl) with sharp boundaries, suggesting that these four phases mutually coexist. Other primary constituents of the Tlc-bearing piemontite-quartz schist are spessartine, braunite, hematite (Ht), crossite/barroisite and dolomite. Phlogopite (Phl) rarely occurs as a later stage mineral developing along the rim of Phn. The studied piemontite-quartz schist has mg# (= Mg/(Mg + Fe²⁺)) ~ 1.0, because of its high oxidation state. Schreinemakers' analysis in the KNMASH system and the mineral assemblage in the Sanbagawa belt propose a possible petrogenetic grid, in which the Tlc–Phn assemblage is stable in a P-T field surrounded by the following reactions: lower-pressure limit by Chl + Phl + quartz (Qtz) = Phn + Tlc + H₂O as proposed by previous workers; higher-pressure limit by glaucophane + Qtz = Tlc + Ab + H₂O; and higher-temperature limit by Tlc + Phn + Ab = Phl + paragonite + Qtz + H₂O. Thermodynamic calculation based on the database of Holland & Powell (1998) , however, suggests that the Tlc–Phn stability field defined by these reactions is unrealistically limited around 580–600 °C at 11.6–12.0 (± 0.7) kbar. Schreinemakers' analysis in the KNMA-Fe³⁺-SH system and the observed mineral assemblage predict that Chl + crossite = Tlc + Ab + Ht + H₂O is a preferable Tlc-forming reaction in the intermediate-grade part of the Sanbagawa belt and that excess Ab + hematite narrows the stability field of the Tlc–Phn assemblage.     

Phase equilibria and metamorphic evolution of garnet‐mica‐plagioclase gneisses from the Qiliping terrane in the western Dabie Orogen,central China

The extensive gneisses in the high‐pressure and ultrahigh‐pressure metamorphic terrane in the Dabie‐Sulu orogen usually show no evidence of eclogite‐facies metamorphism. The garnet‐mica‐plagioclase gneisses from the Qiliping region in the western Dabie Orogen, comprise garnet, phengite, biotite, plagioclase, quartz, rutile, ilmenite, chlorite, epidote, and hornblende. The garnet porphyroblasts, with inclusions of quartz, epidote, and rutile, exhibit slight compositional zonations, from core to mantle with an increase in pyrope and a decrease in spessartine, and from mantle to rim with a decrease in pyrope and grossular and an increase in spessartine. The high‐Si phengite indicates that the gneisses may be subjected to a high‐pressure metamorphism. By the P–T pseudosections calculated in a system NCKMnFMASHTO (Na₂O‐CaO‐K₂O‐MnO‐FeO‐MgO‐Al₂O₃‐SiO₂‐H₂O‐TiO₂‐O) for two representative samples, the metamorphic P–T path, reconstructed by the compositionally zoned garnet, shows that the prograde metamorphism is characterized by a temperature increase with a slight pressure increase from the conditions of 17.6 ± 1.5 kbar at 496 ± 15°C to the peak‐pressure ones of 21.8 ± 1.5–22.7 ± 1.5 kbar at 555 ± 15–561 ± 15°C; the early retrograde stage is dominated by decompression with a temperature increase to the maximum of 608 ± 15–611 ± 18°C at 10.3 ± 1.5–11.0 ± 1.5 kbar; and the late retrograde one is predominated by pressure and temperature decreases. The mineral assemblages in the prograde metamorphism are predicted to contain garnet, glaucophane, jadeite, lawsonite, phengite, quartz, rutile, and/or chlorite, which is different from those observed at present. Such high‐pressure metamorphism can partly be reconstructed by the P–T pseudosection in combination with the high‐Si phengite and garnet compositions in the core and mantle. This provides an important constraint on the subduction and exhumation of the terrane during the continent–continent collision between the Yangtze and Sino‐Korean cratons.     

Pressure‐temperature history of titanite‐bearing eclogite from the Western Iratsu body,Sanbagawa Metamorphic Belt,Japan

Evidence for eclogite‐facies metamorphism is widespread in the Western Iratsu body of the oceanic subduction type Sanbagawa Belt, Southwest Japan. Previous studies in this region focused on typical mafic eclogites and have revealed the presence of an early epidote‐amphibolite facies metamorphism overprinted by a phase of eclogite facies metamorphism. Ca‐rich and titanite‐bearing eclogite, which probably originated from a mixture of basaltic and calc‐siliceous sediments, is also relatively common in the Western Iratsu body, but there has been no detailed petrological study of this lithology. Detailed petrographic observations reveal the presence of a relic early epidote‐amphibolite facies metamorphism preserved in the cores of garnet and titanite in good agreement with studies of mafic eclogite in the area. Thermobarometric calculations for the eclogitic assemblage garnet + omphacite + epidote + quartz + titanite ± rutile ± phengite give peak‐P of 18.5–20.5 kbar at 525–565°C and subsequent peak‐T conditions of about 635°C at 14–16 kbar. This eclogite metamorphism initiated at about 445°C/11–15 kbar, implying a significantly lower thermal gradient than the earlier epidote‐amphibolite facies metamorphism (～650°C/12 kbar). These results define a P–T path with early counter‐clockwise and later clockwise trajectories. The overall P–T path may be related to two distinct phases in the tectono‐thermal evolution in the Sanbagawa subduction zone. The early counter‐clockwise path may record the inception of subduction. The later clockwise path is compatible with previously reported P–T paths from the other eclogitic bodies in the Sanbagawa Belt and supports the tectonic model that these eclogitic bodies were exhumed as a large‐scale coherent unit shortly before ridge subduction.     

Prograde pressure-temperature path of jadeite-bearing eclogites and associated high-pressure/low-temperature rocks from western Tianshan, northwest China

Abstract Jadeite‐bearing eclogites and associated blueschists locally crop out in a greenschist facies area at Kuldkourla, near the Akeyazhi River in the western Chinese Tianshan region, northwestern China. Garnet in these metamorphic rocks shows prograde zoning with increasing Mg and decreasing Mn from the crystal center towards the rim, and is divided into Ca‐poor/Fe‐rich core and Ca‐rich/Fe‐poor mantle parts. The garnet cores include the assemblages of (i) jadeite/omphacite (X_jd = 0.34–0.96) + barroisite/taramite; and (ii) omphacite + barroisite/pargasite, with paragonite, epidote, rutile and quartz as major phases with rare albite. The garnet mantles rarely contain inclusions of omphacite, glaucophane, epidote, rutile and quartz. Major matrix phases of the pre‐exhumation stage are omphacite, glaucophane, paragonite, rutile and quartz. These mineral parageneses give pressure (P)‐temperature (T) conditions of 0.9 GPa/390°C?1.4 GPa/560°C for the stage of the garnet core formation, 1.8 GPa/520°C for the stage of the garnet mantle formation, and 2.2 GPa/495°C‐2.4 GPa/535°C for the peak eclogite facies assemblage in the matrix. The estimated P‐T conditions and continuous changes of mineral parageneses imply a counterclockwise P‐T path which is a combination of (i) an early prograde stage of high‐pressure/low‐temperature (HP/LT) blueschist facies and/or LP/LT eclogite facies; (ii) a later prograde stage involving compression with minimal heating; and (iii) a climax‐of‐subduction stage characterized by a slight decrease of temperature with increasing pressure. The negative dP/dT of the latest subduction stage is possibly a record of the following events after a continuous subduction and ridge approach: (i) material migration within the upper part of the subducting slab, which has an inverse thermal gradient caused by ductile flow and/or slab break during subduction; and/or (ii) temporary cooling of the wedge mantle–slab interface by continuous subduction of a relatively cold slab following subduction of a hotter ridge.     

Eclogites from the Chinese continental scientific drilling borehole, their petrology and different P-T evolutions

Abstract Four phengite‐bearing eclogites, taken from different depths of the Chinese continental scientific drilling (CCSD) borehole in the Sulu ultrahigh pressure terrane, eastern China, were studied with the electron microprobe. The compositional zonations of garnet and omphacite are moderate, whereas phengite compositions generally vary significantly in a single sample from core to rim by decrease of the Si content. Various geothermobarometric methods were applied to constrain the P‐T conditions of these eclogites on the basis of the compositional variability of the above minerals. The constrained P‐T path for sample B218 is characterized by pressure decrease from ca 3.0 GPa (ca 600°C) to 1.3 GPa (ca 550°C). Eclogite B310 yielded P‐T conditions of 3.0 GPa and 750°C. The path for eclogite B1008 starts at about 650°C and 3.6–3.9 GPa (stage I) followed by a pressure decrease to 2.8–3.0 GPa and a significant temperature rise (stages II and IIIa, 750–810°C). Afterwards, this rock cooled down to 620–660°C at still high pressures (2.5–2.7 GPa, stage IIIb). Retrograde conditions were about 670°C and 1.3 GPa (stage IV). Eclogite B1039 yielded a P‐T path starting at ca 600°C and 3.3–3.9 GPa (stage I). A pressure decrease to about 3.0 GPa (stage II, 590–610°C) and then a moderate isobaric temperature increase to ca 630°C (stage III) followed. Stage IV is characterized by temperatures of 650°C at pressures close to 1.3 GPa. During and after this stage (hydrous) fluids partially rich in potassium penetrated the rocks causing minor changes. Relatively high oxygen fugacities led to andradite and magnetite among the newly formed minerals. We think that the above findings can be best explained by mass flow in a subduction channel. Thus, we conclude that the assembly of UHP rocks of the CCSD site, eclogites, quartzofeldspathic rocks, and peridotites, cannot represent a crustal section that was already coherent at UHP conditions as it is the common belief currently. The coherency was attained after significant exhumation of these UHP rocks.     

Origin of the Tonaru body in the Sanbagawa metamorphic belt,SW Japan

Zircon U–Pb dating of the Tonaru metagabbro body in the Sanbagawa metamorphic belt, southwest Japan, suggests that igneous events at ca 200–180 Ma were involved in the protolith formation. The trace element compositions of the Tonaru zircons are enriched in U (a fluid‐mobile element) and Sc (an amphibole‐buffered element), and depleted in Nb (a fluid‐immobile element), suggesting that the parental magmas related to the Tonaru metagabbros formed in an arc setting. Integration of our results with previous studies of the metasedimentary rocks in the Tonaru body clearly indicates that the protoliths of the Tonaru body were produced by oceanic‐arc magmatism. With the previous geochronological and geological studies, the tectono‐magmatic–metamorphic history of the Tonaru and other mafic bodies in the Sanbagawa metamorphic belt may be summarized as follows: (i) the protolith formation by the oceanic‐arc magmatic event had occurred at 200–180 Ma; (ii) the protoliths were accreted in the trench at ca 130–120 Ma; and (iii) they were completely subducted into the depth of the eclogite‐facies condition after 120 Ma.     

K–Ar age–chemistry–fabric relations of phengite from the Sanbagawa high-pressure schists, Japan

The Sanbagawa high-pressure schists from central Shikoku in Southwest Japan have experienced high-strain ductile deformation during exhumation and cooling. This study examines the effects of high-strain ductile deformation on K–Ar ages of phengites on the basis of fabric, chemistry and K–Ar ages of phengites from the pelitic, psammitic and quartzose (or albitic) schists collected from the same outcrop in the albite–biotite zone. Phengites in the pelitic and psammitic schists generally occur forming aggregates consisting of fine-grained phengite crystals and are extremely fine-grained in domains close to relatively rigid garnet and albite porphyroblasts, indicating that deformation-induced grain-size reduction had taken place in phengite during the ductile deformation accompanying the exhumation of host schists. We suggest that the grain-size reduction of phengite is due to strain-induced recrystallization or dynamic recrystallization. The matrix phengites in schists are chemically heterogeneous on the thin-section scale but the phengites from pelitic and psammitic schists from the same outcrop have similar chemical range. Phengite included in garnet has a high Si value and its Na/(Na + K) and Mg/(Mg + Fe) ratios are significantly low in comparison with those in matrix. The phengite included in garnet records the chemistry in equilibrium with other major silicate phases during the higher pressure stage of the P–T–t history of the schists. In contrast, the matrix phengites having low Si values are likely to have been formed during retrograde metamorphism in extremely restricted equilibrium domains. The two or three different types of schists from the same outcrop, which have a similar grain size of phengite, have similar K–Ar ages, suggesting that the closure temperature does not depend on chemistry. However, the hematite-rich quartzose schist with strong grain-size reduction of both phengite and quartz has a significantly younger K–Ar phengite age than the pelitic and quartzose schists in the same outcrop that do not show grain-size reduction. We suggest that the exhumation tectonics of the schists, which have experienced strong ductile deformation at temperatures less than ~350°C, played an important role resulting in the observed variation in age.     

Metamorphism, partial preservation, and exhumation of ultrahigh-pressure belts

The Dabie-Sulu belt of east-central China, the Kokchetav Complex of northern Kazakhstan, the Maksyutov Complex of the South Urals, the Dora Maira Massif of the Western Alps, and the Western Gneiss Region of southwestern Norway lie astride intracontinental suture zones. All represent collisional mountain belts. Adjoining Eurasian regions exhibit little or no evidence of a coeval calc-alkaline arc. Each metamorphic complex contains mineralogic and textural relics of the presence or former existence of coesite ± diamond. Other ultrahigh-P, moderate-T metamorphic phases, including K-rich clinopyroxene, Mg-rich garnet, ellenbergerite, lawsonite, Al-rutile, glaucophane, high-Si phengite, and associations such as coesite + dolomite, magnesite + diopside, and talc + kyanite, diopside, jadeite, or phengite also testify to pressures approaching or exceeding 2.8 GPa. Each of the five well-studied Eurasian ultrahigh-pressure complexes consists chiefly of old, cool continental crust. Deep-seated recrystallization took place during the Phanerozoic. Subduction zones constitute the only known plate-tectonic environment where such high-P, low-T conditions exist. A model involving underflow of a salient of continental crust imbedded in oceanic crust-capped lithosphere explains the ultrahigh- pressure metamorphism. Partly exhumed ultrahigh-pressure terranes consist of relatively thin sheets 7 ± 5 km thick. During early stages of plate descent, hydration of relatively anhydrous units occurs, and volatiles are expelled from hydrous rocks. If present, aqueous fluids markedly catalyze reactions. Experimental studies on MORB bulk compositions demonstrate that, for common subduction-zone P–T trajectories, amphibole (the major hydrous phase in metabasaltic rocks) dehydrates at less than ~ 2.0 GPa; accordingly, mafic blueschists and amphibolites expel H₂O at great depth and, except for some coarse-grained, dry metagabbros, tend to recrystallize to eclogite. Serpentinized mantle beneath the oceanic crust devolatilizes at comparable pressures. In contrast, phengite and biotite remain stable to pressures exceeding 3.5 GPa in associated quartzofeldspathic rocks. So, under ultrahigh-pressure conditions, the micaceous lithologies that dominate the continental crust fail to evolve significant H₂O, and may transform incompletely to eclogitic assemblages. Although hydrous rocks expel volatiles during compaction and shallow burial, very deep underflow of partly hydrated oceanic crust + mantle generates most of the volatile flux along and above a subduction zone prior to continental collision. As large masses of sialic crust enter the convergent plate junction, fluid evolution at deep levels severely diminishes, and both convergence and dehydration terminate. After cessation of ultrahigh-pressure recrystallization, tectonic slices of sialic massifs return to shallow depths along the subduction channel, propelled by buoyancy; collisional sheets that retain ultrahigh-pressure effects lose heat efficiently across both upper (extensional, normal fault) and lower (subduction, reverse fault) tectonic contacts. These sheets ascend to midcrustal levels rapidly at average exhumation rates of 2–12 mm/year. Surviving ultrahigh-pressure relics occur as micro-inclusions encased in dense, strong, impermeable, unreactive mineralogic hosts, and are shielded during return towards conditions characteristic of midcrustal levels. Rehydration attending decompression is incomplete; its limited extent reflects the coarse grain size and relative impermeability of the rocks undergoing retrogression, as well as declining temperature and lack of aqueous fluids.     

Thermal histories of Cretaceous basins in Korea: Implications for response of the East Asian continental margin to subduction of the Paleo‐Pacific Plate

Thermal histories of Cretaceous sedimentary basins in the Korean peninsula have been assessed to understand the response of the East Asian continental margin to subduction of the Paleo‐Pacific (Izanagi) Plate. The Izanagi Plate subducted obliquely beneath the East Asian continent during the Early Cretaceous and orthogonally in the Late Cretaceous. First, the Jinan Basin, a pull‐apart basin, was studied by illite crystallinity and apatite fission‐track analyses. Analytical results indicate that Jinan Basin sediment was heated to a maximum temperature of approximately 287°C by burial. The sediment experienced two cooling episodes during ca 95–80 Ma and after ca 30 Ma, with a quiescent period between them. A similar cooling pattern is recognized in the Gyeongsang Basin, the largest Cretaceous basin in Korea. The Jinan and Gyeongsang Basins were cooled mainly by exhumation between ca 95 and 80 Ma, but the former was exhumed slightly earlier than the latter by transpressional force due to the subduction direction change of the Izanagi Plate. Comparison of thermal history of Korean Cretaceous basins with those of granitoids in northeastern China and the accretionary complexes in southwestern Japan reveals that the Upper Cretaceous regional exhumation of the East Asian continental margin including the Korean peninsula during ca 95–80 Ma was facilitated by the subduction of the Izanagi–Pacific ridge, which migrated northeastwards with time, resulting in the end of regional exhumation at ca 80 Ma in this region.     

In situ LA-ICP-MS zircon U-Pb age of ultrahigh-pressure eclogites in the Yukahe area,northern Qaidam Basin

Zircon grains were selected from two types of ultrahigh-pressure (UHP) eclogites, coarse-grained phengite eclogite and fine-grained massive eclogite, in the Yukahe area, the western part of the North Qaidam UHP metamorphic belt. Most zircon grains show typical metamorphic origin with residual cores in some irregular grains and sector, planar or misty internal textures on the cathodoluminescence (CL) images. The contents of REE and HREE of the core parts of grains range from 173 to 1680 μg/g and 170 to 1634 μg/g, respectively, in phengite eclogite, and from 37 to 2640 μg/g and 25.7 to 1824 μg/g, respectively, in massive eclogite. The core parts exhibit HREE-enriched patterns, representing the residual zircons of protolith of the Yukahe eclogite. The contents of REE and HREE of the rim parts and the grains free of residual cores are much lower than those for the core parts. They vary from 13.1 to 89.5 μg/g and 12.5 to 85.7 μg/g, respectively, in phengite eclogite, and from 9.92 to 45.8 μg/g and 9.18 to 43.8 μg/g, respectively, in massive eclogite. Negative Eu anomalies and Th/U ratios decrease from core to rim. Positive Eu anomalies are shown in some grains. These indicate that the presence of garnet and the absence of plagioclase in the peak metamorphic mineral assemblage, and the zircons formed under eclogite facies conditions. LA-ICP-MS zircon U-Pb age data indicate that phengite eclogite and massive eclogite have similar metamorphic age of 436±3Ma and 431±4Ma in the early Paleozoic and magmatic protolith age of 783–793 Ma and 748–759 Ma in the Neo-proterozoic. The weighted mean age of the metamorphic ages (434±2 Ma) may represent the UHP metamorphic age of the Yukahe eclogites. The metamorphic age is well consistent with their direct country rocks of gneisses (431±3 Ma and 432±19 Ma) and coesite-bearing pelitic schist in the Yematan UHP eclogite section (423–440 Ma). These age data together with field observation and lithology, allow us to conclude that the Yukahe eclogites were Neo-proterozoic igneous rocks and may have experienced subduction and UHP metamorphism with continental crust at deep mantle during the early Paleozoic, therefore the metamorphic age of 434±2 Ma of the Yukahe eclogites probably represents the continental deep subduction time in this area.

     

Amphibolitization within the lower crust in the termination area of the Godzilla Megamullion,an oceanic core complex in the Parece Vela Basin

Gabbroic rocks and amphibolites were collected from the KR03‐01‐D10 dredge site located on the West Arm Rise of the Godzilla Megamullion, close to the Parece Vela Rift which appears to correspond to the termination area of a detachment fault, the Philippine Sea. The gabbroic rocks and amphibolites reveal the occurrence of a high hydrothermal activity in the lower crust close to a paleo‐ridge. In the gabbroic rocks, plagioclase compositions of both porphyroclasts and matrix were transformed into sodium‐rich compositions close to albite. Amphiboles are of secondary rather than igneous origin based on their microstructural occurrences. In the amphibolites, anorthite contents of porphyroclasts and matrix plagioclase are relatively lower than those of the gabbroic rocks, whereas the chemical compositions of amphibole within the amphibolites are similar to those of amphibole within the gabbroic rocks. Amphibolites represent the product of retrograde metamorphism associated with hydrothermal alteration of the gabbroic body by the reaction: clinopyroxene + calcic plagioclase + fluid → amphibole + sodic plagioclase. The estimated temperatures of the amphibolites derived from the amphibole thermobarometer and the gabbroic rocks derived from the hornblende–plagioclase geothermometer show ～700–950°C and 650–840°C, respectively. The hydrothermal alteration recorded in the gabbroic rocks possibly occurred under high‐T conditions; the rocks were then metamorphosed to the amphibolites during a retrogressive stage. Our study indicates that amphibolitization took place with various degrees of deformation. It may imply that the hydrothermal activity increased as the Godzilla Megamullion developed as an oceanic core complex in the paleo‐ridge.     

Progressive changes in lithological association of the Sanbagawa metamorphic complex,Southwest Japan: Relict clinopyroxene and detrital zircon perspectives

The main tectono‐stratigraphic unit (Shirataki unit) of the Sanbagawa metamorphic complex in central Shikoku is characterized by abundant mafic schist layers that show the mid‐ocean ridge basalt (MORB) affinity. These MORB‐derived schist layers are absent in a southern (structurally lower) domain within the unit. Instead, sporadic occurrences of small metabasite lenses that contain relict igneous minerals (Ti‐rich augite and kaersutite) indicative of alkali basalt magmatism are newly recognized in the southern domain. Compositions of relict clinopyroxene in metabasalt are useful to identify the tectonic setting and origin of the protolith basalt, and those in each unit of the Sanbagawa metamorphic complex are presented. The metamorphic grade of the Shirataki unit generally increases structurally upwards in the southern side of the highest‐grade zone, and metamorphic zonation is subparallel to lithostratigraphic succession. The protolith assemblage of the Shirataki unit shows a distinct change from the southern low‐grade domain (lower Shirataki subunit) composed of terrigenous sedimentary rocks (mudstone and sandstone) with minor alkali basalt to the northern higher‐grade domain (upper Shirataki subunit) consisting of terrigenous and pelagic sedimentary rocks with abundant MORB. The youngest detrital zircon U–Pb ages (ca 95–90 Ma) suggest that both domains have Late Cretaceous depositional ages at the trench. Progressive peeling of oceanic plate stratigraphy during subduction can account for the observed change of lithological association in the Shirataki unit.