Formation of the Green Tuff,Pantelleria

The strongly peralkaline Green Tuff, Pantelleria, is an example of a thin, densely welded air-fall tuff which mantles an area of at least 85 km². Offshore the tuff is correlated with the Y-6 ash layer in the central Mediterranean Sea, and the total volume of the eruption is estimated at 7 km³ D.R.E. New petrological data suggests that the tuff was erupted from a zoned magma chamber containing a cooler, more fractionated upper zone relative to be bulk of the magma. Analysis of the distribution of accessory lithic fragments in terms of existing models of eruption dynamics indicates emplacement by a plinian-type eruption. It is shown that, due to the low viscosity of pantelleritic ejecta, dense welding can occur at moderate tephra accumulation rates and a rate of the order of 1 cm/minute is suggested for the Green Tuff; this yields an estimate for the eruption duration of rather less than one day. It is predicted that welded tuff should be formed during large plinian eruptions of pantelleritic magma, and therefore that welded airfall tuffs should be common in areas of peralkaline volcanism.     

Eruption and emplacement of a basaltic welded ignimbrite during caldera formation on Gran Canaria

The 14.1 Ma old composite ignimbrite cooling unit P1 (45 km³) on Gran Canaria comprises a lower mixed rhyolite-trachyte tuff, a central rhyolite-basalt mixed tuff, and a slightly rhyolite-contaminated basaltic tuff at the top. The basaltic tuff is compositionally zoned with (a) an upward change in basalt composition to higher MgO content (4.3–5.2 wt.%), (b) variably admixed rhyolite or trachyte (commonly <5 wt.%), and (c) an upward increasing abundance of basaltic and plutonic lithic fragments and cognate cumulate fragments. The basaltic tuff is divided into three structural units: (I) the welded basaltic ignimbrite, which forms the thickest part (c. 95 vol.%) and is the main subject of the present paper; (II) poorly consolidated massive, bomb- and block-rich beds interpreted as phreatomagmatic pyroclastic flow deposits; and (III) various facies of reworked basaltic tuff. Tuff unit I is a basaltic ignimbrite rather than a lava flow because of the absence of top and bottom breccias, radial sheet-like distribution around the central Tejeda caldera, thickening in valleys but also covering higher ground, and local erosion of the underlying P1 ash. A gradual transition from dense rock in the interior to ash at the top of the basaltic ignimbrite reflects a decrease in welding; the shape of the welding profile is typical for emplacement temperatures well above the minimum welding temperature. A similar transition occurs at the base where the ignimbrite was emplaced on cold ground in distal sections. In proximal sections the base is dense where it was emplaced on hot felsic P1 tuff. The intensity of welding, especially at the base, and the presence of spherical particles and of mantled and composite particles formed by accretion and coalescence in a viscous state imply that the flow was a suspension of hot magma droplets. The flow most likely had to be density stratified and highly turbulent to prevent massive coalescence and collapse. Model calculations suggest eruption through low pyroclastic fountains (<1000 m high) with limited cooling during eruption and turbulent flow from an initial temperature of 1160°C. The large volume of 26 km³ of erupted basalt compared with only 16 km³ of the evolved P1 magmas, and the extremely high discharge rates inferred from model calculations are unusual for a basaltic eruption. It is suggested that the basaltic magma was erupted and emplaced in a fashion commonly only attributed to felsic magmas because it utilized the felsic P1 magma chamber and its ring-fissure conduits. Evolution of the entire P1 eruption was controlled by withdrawal dynamics involving magmas differing in viscosity by more than four orders of magnitude. The basaltic eruption phase was initially driven by buoyancy of the basaltic magma at chamber depth and continued degassing of felsic magma, but most of the large volume of basalt magma was driven out of the reservoir by subsidence of a c. 10 km diameter roof block, which followed a decrease in magma chamber pressure during low viscosity basaltic outflow.     

Miocene hydrovolcanism in NW Colorado,USA, fuelled by explosive mixing of basic magma and wet unconsolidated sediment

The Yampa and Elkhead Mountains volcanic fields were erupted into sediment-filled fault basins during Miocene crustal extension in NW Colorado. Post-Miocene uplift and erosion has exposed alkali basalt lavas, pyroclastic deposits, volcanic necks and dykes which record hydrovolcanic and strombolian phenomena at different erosion depths. The occurrence of these different phenomena was related to the degree of lithification of the rocks through which the magmas rose. Hydrovolcanic interactions only occurred where rising basaltic magma encountered wet, porous, non-lithified sediments of the 600 m thick Miocene Brown's Park Formation. The interactions were fuelled by groundwater in these sediments: there was probably no standing surface water. Dykes intruded into the sediments have pillowed sides, and local swirled inclusions of sediment that were injected while fluidized in steam from heated pore water. Volcanic necks in the sediments consist of basaltic tuff, sediment blocks and separated grains derived from the sediments, lithic blocks (mostly derived from a conglomerate forming the local base of the Brown's Park Formation), and dykes composed of disaggregated sediment. The necks are cut by contemporaneous basalt dykes. Hydrovolcanic pyroclastic deposits formed tuff cones up to 100 m thick consisting of bedded air-fall, pyroclastic surge, and massive, poorly sorted deposits (MPSDs). All these contain sub-equal volumes of basaltic tuff and disaggregated sediment grains from the Brown's Park Formation. Possible explosive and effusive modes of formation for the MPSDs are discussed. Contemporaneous strombolian scoria deposits overlie lithified Cretaceous sedimentary rocks or thick basalt lavas. Volcanic necks intruded into the Cretaceous rocks consist of basalt clasts (some with spindle-shape), lithic clasts, and megacrysts derived from the magma, and are cut by basalt dykes. Rarely, strombolian deposits are interbedded with hydrovolcanic pyroclastic deposits, recording changes in eruption behaviour during one eruption. The hydrovolcanic eruptions occurred by interaction of magma with groundwater in the Brown's Park sediments. The explosive interactions disaggregated the sediment. Such direct digestion of sediment by the magma in the vents would probably not have released enough water to maintain a water/magma mass ratio sufficient for hydrovolcanic explosions to produce the tuff cones. Probably, additional water (perhaps 76% of the total) was derived by flow through the permeable sediments (especially the basal conglomerate to the formation), and into the vents.     

Partially melted lithic megablocks in the Yardea Dacite, Gawler Range Volcanics, Australia: implications for eruption and emplacement mechanisms

 Lithic megablocks ranging from <1 to 50 m in diameter occur in the Yardea Dacite, a widespread (12,000 km²), thick (>200 m) felsic volcanic unit in the Mesoproterozoic Gawler Range Volcanic Province (GRV) of South Australia. Throughout its vast extent, the Yardea Dacite shows typical lava-like features, in that it is massive, columnar jointed and evenly porphyritic with 30–40% crystals in a spherulitic and granophyric groundmass. In addition, flow banding is present at many locations. The megablocks are abundant at two sites 50 km apart, but isolated megablocks and smaller (<6 cm) lithic clasts are also scattered throughout the unit. At both sites the megablocks are matrix supported, non-graded, randomly oriented and show no evidence of being confined to a particular stratigraphic level in the dacite. The most abundant and largest megablocks are granitoids derived from older basement and from early-crystallised plutons of the Hiltaba Suite, which is broadly coeval and comagmatic with the GRV. The granitoid megablocks have been partially melted, most likely prior to eruption when resident in the thermal aureole of the Yardea Dacite magma chamber. The lithic megablock occurrences are unlike coarse pyroclastic breccias but are similar in distribution and abundance to xenoliths in lavas, consistent with the lava-like character of the host dacite. Using reasonable estimates of megablock density, magma density and magma viscosity, we show that the rise rate of the dacitic magma exceeded the settling velocity of the megablocks, implying that they could have been entrained and erupted effusively. All but the largest and least-melted megablocks would have remained suspended or else settled very slowly in the dacitic lava during outflow. The rapid rate of magma withdrawal required to produce such an extensive felsic sheet could have also triggered disintegration of the thermally stressed wallrock surrounding the magma chamber, dislodging megablocks that were later entrained and effusively erupted. Received: 11 November 1998 / Accepted: 18 April 1999     

The ground layer of Ata pyroclastic flow deposit,southwestern Japan — evidence for the capture of lithic fragments

Lithic fragments in the ground layer of the Ata pyroclastic flow deposit, southwestern Japan, were supplied from two different sources. One is the eruptive vent and the other is the basement rock exposed underneath the path of flow. Lithic fragments captured at the eruptive vent gradually decrease in size with distance from the source. Local increases of ML or Md are proportional to increased amounts of captured lithic fragments. The pyroclastic flow eroded basement formations on slopes dipping away from the source, and deposited the lithics within the ground layer on slopes dipping towards the source. The ground layer was found only in the western half of the Ata pyroclastic flow deposit. The absence of the ground layer in the eastern half of the pyroclastic flow deposit is interpreted to result from a selective loss of lithics when the flow traversed a bay or a lake located just east from the vent.     

Effusive eruptions from a large silicic magma chamber: the Bearhead Rhyolite,Jemez volcanic field,NM

Large continental silicic magma systems commonly produce voluminous ignimbrites and associated caldera collapse events. Less conspicuous and relatively poorly documented are cases in which silicic magma chambers of similar size to those associated with caldera-forming events produce dominantly effusive eruptions of small-volume rhyolite domes and flows. The Bearhead Rhyolite and associated Peralta Tuff Member in the Jemez volcanic field, New Mexico, represent small-volume eruptions from a large silicic magma system in which no caldera-forming event occurred, and thus may have implications for the genesis and eruption of large volumes of silicic magma and the long-term evolution of continental silicic magma systems.⁴⁰Ar/³⁹Ar dating reveals that most units mapped as Bearhead Rhyolite and Peralta Tuff (the Main Group) were erupted during an ∼540 ka interval between 7.06 and 6.52 Ma. These rocks define a chemically coherent group of high-silica rhyolites that can be related by simple fractional crystallization models. Preceding the Main Group, minor amounts of unrelated trachydacite and low silica rhyolite were erupted at ∼11–9 and ∼8 Ma, respectively, whereas subsequent to the Main Group minor amounts of unrelated rhyolites were erupted at ∼6.1 and ∼1.5 Ma.The chemical coherency, apparent fractional crystallization-derived geochemical trends, large areal distribution of rhyolite domes (∼200 km²), and presence of a major hydrothermal system support the hypothesis that Main Group magmas were derived from a single, large, shallow magma chamber. The ∼540 ka eruptive interval demands input of heat into the system by replenishment with silicic melts, or basaltic underplating to maintain the Bearhead Rhyolite magma chamber.Although the volatile content of Main Group magmas was within the range of rhyolites from major caldera-forming eruptions such as the Bandelier and Bishop Tuffs, eruptions were smaller volume and dominantly effusive. Bearhead Rhyolite domes occur at the intersection of faults, and are cut by faults, suggesting that the magma chamber was structurally vented preventing volatiles from accumulating to levels high enough to trigger a caldera-forming eruption.     

Reconstruction of a kimberlite eruption,using an integrated volcanological,geochemical and numerical approach: A case study of the Fox Kimberlite,NWT, Canada

An integrated approach involving volcanology, geochemistry and numerical modelling has enabled the reconstruction of the volcanic history of the Fox kimberlite pipe. The observed deposits within the vent include a basal massive, poorly sorted, matrix supported, lithic fragment rich, eruption column collapse lapilli tuff. Extensive vent widening during the climactic magmatic phase of the eruption led to overloading of the eruption column with cold dense country rock lithic fragments, dense juvenile pyroclasts and olivine crystals, triggering column collapse. > 40% dilution of the kimberlite by granodiorite country rock lithic fragments is observed both in the physical componentry of the rocks and in the geochemical signature, where enrichment in Al₂O₃ and Na₂O compared to average values for coherent kimberlite is seen. The wide, deep, open vent provided a trap for a significant proportion of the collapsing column material, preventing large scale run-away in the form of pyroclastic flow onto the ground surface, although minor flows probably also occurred. A massive to diffusely bedded, poorly sorted, matrix supported, accretionary-lapilli bearing, lithic fragment rich, lapilli tuff overlies the column collapse deposit providing evidence for a late phreatomagmatic eruption stage, caused by the explosive interaction of external water with residual magma. Correlation of pipe morphology and internal stratigraphy indicate that widening of the pipe occurred during this latter stage and a thick granodiorite cobble-boulder breccia was deposited. Ash- and accretionary lapilli-rich tephra, deposited on the crater rim during the late phreatomagmatic stage, was subsequently resedimented into the vent. Incompatible elements such as Nb are used as indicators of the proportion of the melt fraction, or kimberlite ash, retained or removed by eruptive processes. When compared to average coherent kimberlite the ash-rich deposits exhibit ~ 30% loss of fines whereas the column collapse deposit exhibits ~ 50% loss. This shows that despite the poorly sorted nature of the column collapse deposit significant elutriation has occurred during the eruption, indicating the existence of a high sustained eruption column. The deposits within Fox record a complex eruption sequence showing a transition from a probable violent sub-plinian style eruption, driven by instantaneous exsolution of magmatic volatiles, to a late phreatomagmatic eruption phase. Mass eruption rate and duration of the sub-plinian phase of the eruption have been determined based on the dimensions of milled country-rock boulders found within the intra-vent deposits. Calculations show a short lived eruption of one to eleven days for the sub-plinian magmatic phase, which is similar in duration to small volume basaltic eruptions. This is in general agreement with durations of kimberlite eruptions calculated using entirely different approaches and parameters, such as predictions of magma ascent rates in kimberlite dykes.     

Reconstructing the evolution of fault zone architecture: Field‐based study of the core region of the Atera Fault,Central Japan

In order to reconstruct the architectural evolution of a fault zone with heterogeneous structures, we studied the Atera Fault in Central Japan, and described the detailed mesoscopic and microscopic features of the zone. The fault zone studied consists of a 1.2‐m wide fault core of fault breccia mixed with fragments derived from welded tuff, granite, and mafic volcanic rocks. The 1.2‐m wide fault core is bordered by a western damage zone characterized by a welded tuff fault breccia and an eastern damage zone characterized by a granite cataclasite. A secondary fault core, a 30‐cm wide granite‐derived fault gouge, cross‐cuts the granite cataclasite. Although welded tuff fault breccia and granite cataclasite are also pervasively fractured and fragmented, the fault cores are significantly affected by fragment size reduction due to intense abrasive wear and comminution. The 1.2‐m wide fault core includes fragments and a sharp dark layer composed of mafic volcanic rocks, which can be correlated with neighboring 1.6 Ma volcanic rocks. This observation places a younger constraint on the age of the fault core formation. Carbonate coating on basalt fragments in the 1.2‐m wide fault core has also been fractured indicating the repetition of intense fragmentation. Bifurcated, black and gray veins near the 1.2‐m wide fault core are likely injection veins, formed by the rapid injection of fine material within fault zones during seismic events. The granite‐derived fault gouge, characterized by hard granite fragments without intense brecciation and microfracturing, in a kaolinite‐rich clay matrix, is interpreted as the most recent slip zone within the exposed fault zone. A preview of published geological and hydrological studies of several fault zones shows that clay‐rich fault cores can exhibit much lower permeability than the adjacent damage zones represented in this present case by the welded tuff fault breccia and granite cataclasite.     

Evolution of tuff ring-dome complex: the case study of Cerro Pinto, eastern Trans-Mexican Volcanic Belt

Cerro Pinto is a Pleistocene rhyolite tuff ring-dome complex located in the eastern Trans-Mexican Volcanic Belt. The complex is composed of four tuff rings and four domes that were emplaced in three eruptive stages marked by changes in vent location and eruptive character. During Stage I, vent clearing produced a 1.5-km-diameter tuff ring that was then followed by emplacement of two domes of approximately 0.2 km³ each. With no apparent hiatus in activity, Stage II began with the explosive formation of a tuff ring ~2 km in diameter adjacent to and north of the earlier ring. Subsequent Stage II eruptions produced two smaller tuff rings within the northern tuff ring as well as a small dome that was mostly destroyed by explosions during its growth. Stage III involved the emplacement of a 0.04 km³ dome within the southern tuff ring. Cerro Pinto’s eruptive history includes sequences that follow simple rhyolite-dome models, in which a pyroclastic phase is followed immediately by effusive dome emplacement. Some aspects of the eruption, however, such as the explosive reactivation of the system and explosive dome destruction, are more complex. These events are commonly associated with polygenetic structures, such as stratovolcanoes or calderas, in which multiple pulses of magma initiate reactivation. A comparison of major and trace element geochemistry with nearby Pleistocene silicic centers does not show indication of any co-genetic relationship, suggesting that Cerro Pinto was produced by a small, isolated magma chamber. The compositional variation of the erupted material at Cerro Pinto is minimal, suggesting that there were not multiple pulses of magma responsible for the complex behavior of the volcano and that the volcanic system was formed in a short time period. The variety of eruptive style observed at Cerro Pinto reflects the influence of quickly exhaustible water sources on a short-lived eruption. The rising magma encountered small amounts of groundwater that initiated eruption phases. Once a critical magma:water ratio was exceeded, the eruptions became dry and sub-plinian to plinian. The primary characteristic of Cerro Pinto is the predominance of fall deposits, suggesting that the level at which rising magma encountered water was deep enough to allow substantial fragmentation after the water source was exhausted. Isolated rhyolite domes are rare and are not currently viewed as prominent volcanic hazards, but the evolution of Cerro Pinto demonstrates that individual domes may have complex cycles, and such complexity must be taken into account when making hazard risk assessments.     

Geology, water geochemistry and geothermal potential of the jemez springs area, Canon de San Diego, new Mexico

Studies of the geology, geochemistry of thermal waters, and of one exploratory geothermal well show that two related hot spring systems discharge in Canõn de San Diego at Soda Dam (48°C) and Jemez Springs (72°C). The hot springs discharge from separate strands of the Jemez fault zone which trends northeastward towards the center of Valles Caldera. Exploration drilling to Precambrian basement beneath Jemez Springs encountered a hot aquifer (68°C) at the top of Paleozoic limestone of appropriate temperature and composition to be the local source of the fluids in the surface hot springs at Jemez Springs. Comparisons of the soluble elements Na, Li, Cl, and B, arguments based on isotopic evidence, and chemical geothermometry indicate that the hot spring fluids are derivatives of the deep geothermal fluid within Valles Caldera. No hot aquifer was discovered in or on top of Precambrian basement. It appears that low- to moderate-temperature geothermal reservoirs (< 100°C) of small volume are localized along the Jemez fault zone between Jemez Springs and the margin of Valles Caldera.     

Gabbro — quartz diorite inclusions from Izu-Hakone Region,Japan

Gabbro — quartz diorite inclusions, angular to rounded and up to 20 cm in size, have been found as accidental fragments in a mud flow of the Okata basalt group, O-shima Island and in a tuff breccia, Hakone. New analyses are represented for seventeen inclusions and three pyroxenes. It is reasonable to conclude from petrographic and chemical features that the olivine gabbro inclusions were produced by crystal settling from a quartztholeiite magma at the early stage of fractionation within a magma reservior. On the other hand, gabbro and quartz gabbro inclusions are fragments of a small intrusive body within the Tertiary volcanic formation and consist of various amounts of cumulus phases and liquid. Quartz diorite inclusions are also fragments of a plutonic equivalent, but represents a strongly-differentiated liquid phase of the quartz-tholeiite magma.     

A model for the origin of large silicic magma chambers: precursors of caldera-forming eruptions

The relatively low rates of magma production in island arcs and continental extensional settings require that the volume of silicic magma involved in large catastrophic caldera-forming (CCF) eruptions must accumulate over periods of 10 ⁵ to 10 ⁶ years. We address the question of why buoyant and otherwise eruptible high-silica magma should accumulate for long times in shallow chambers rather than erupt more continuously as magma is supplied from greater depths. Our hypothesis is that the viscoelastic behavior of magma chamber wall rocks may prevent an accumulation of overpressure sufficient to generate rhyolite dikes that can propagate to the surface and cause an eruption. The critical overpressure required for eruption is based on the model of Rubin (1995a). An approximate analytical model is used to evaluate the controls on magma overpressure for a continuously or episodically replenished spherical magma chamber contained in wall rocks with a Maxwell viscoelastic rheology. The governing parameters are the long-term magma supply, the magma chamber volume, and the effective viscosity of the wall rocks. The long-term magma supply, a parameter that is not typically incorporated into dike formation models, can be constrained from observations and melt generation models. For effective wall-rock viscosities in the range 10 ¹⁸ to 10 ²⁰ Pa s ^–1, dynamical regimes are identified that lead to the suppression of dikes capable of propagating to the surface. Frequent small eruptions that relieve magma chamber overpressure are favored when the chamber volume is small relative to the magma supply and when the wall rocks are cool. Magma storage, leading to conditions suitable for a CCF eruption, is favored for larger magma chambers (>10 ² km ³) with warm wall rocks that have a low effective viscosity. Magma storage is further enhanced by regional tectonic extension, high magma crystal contents, and if the effective wall-rock viscosity is lowered by microfracturing, fluid infiltration, or metamorphic reactions. The long-term magma supply rate and chamber volume are important controls on eruption frequency for all magma chamber sizes. The model can explain certain aspects of the frequency, volume, and spatial distribution of small-volume silicic eruptions in caldera systems, and helps account for the large size of granitic plutons, their association with extensional settings and high thermal gradients, and the fact that they usually post-date associated volcanic deposits.     

A combined rock magnetic and geochemical investigation of Upper Cretaceous volcanic rocks in the Pontides,Turkey

Upper Cretaceous volcanic rocks were collected at 24 sites along the Pontides, N-NE Turkey, for rock magnetic and geochemical studies. Rock magnetic and petrographic methods showed that the lavas are characterized predominantly by titanomagnetites with a mixture of pseudo-single and multi-domain grains, whereas in tephrite single domain titanohematite was dominant. Measurements of magnetic susceptibility and the geochemical properties on different volcanic rock types provide important knowledge about the magnetic stability of the rocks. The magnetic properties are interpreted in terms of the composition, concentration, magma generation. Tephrite and phonotephrites with the highest intensities (5200 mA/m) and high magnetic susceptibility values (2585 × 10⁻⁵), largest grain sizes and Fe/Ti values, showing minor or no alteration are the most magnetic stable samples in contrast to dacites with the lowest intensity-magnetic susceptibility (520 mA/m − 573 × 10⁻⁵) and high alteration degree. The basanite samples show very low NRM (48–165 mA/m) but very high magnetic susceptibility (2906–3100 × 10⁻⁵) values suggesting the alteration of Fe-Ti minerals. It is shown that the magnetic properties of the basic to acidic rocks show a systematic variation with magma differentiation and could be related to fractional crystallization. Major and trace elements revealed that the lavas are compatible with complex magma evolution, with mineral phases of olivine+magnetite+clinopyroxene in basic series, amphibole+ +clinopyroxene in intermediate rocks and plagioclase+clinopyroxene+biotite in acidic series.     

Characteristics of late Cenozoic volcanism along the Archibarca lineament from Cerro Llullaillaco to Corrida de Cori, northwest Argentina

The Archibarca lineament is one of several NW–SE-trending transverse lineaments that cut across the Central Andes of Argentina and Chile. Central Andean, Late Miocene–Quaternary subduction-related volcanism is mainly restricted to a 50-km-wide arc forming the approximately N–S axis of the Cordillera, but extends along the transverse lineaments for up to 200 km to the SE. Lineaments are interpreted to be deep-seated, long-lived basement structures or anisotropies, which can control the localization of magmatism and, in some cases, magmatic–hydrothermal ore deposits (e.g., the Escondida porphyry Cu deposit, Chile). As a first step towards exploring the regional-scale controls on magmatism and related mineralization exerted by such structures, the styles of volcanism and near-surface hydrothermal activity along a segment of the Archibarca lineament in the Puna of northwest Argentina are described here. Volcanic structures have been mapped and sampled along a 50-km transect from Cerro Llullaillaco, a large medium-K dacitic Quaternary stratovolcano, to Corrida de Cori, a range of Pliocene–Pleistocene high-K andesitic vents. Apart from a southeastward increase in K content and the predominance of dacitic lavas at Cerro Llullaillaco, the geochemical affinity of late Cenozoic volcanic rocks varies little in time or space. This uniformity extends further SE to Cerro Galán, where published data closely match the results from the study area. In detail, trace element compositions reveal the localized (in both time and space) effects of crustal contamination (recognized as Th>10 ppm), and depth of fractionation (1/Yb>0.7 ppm⁻¹, reflecting garnet residue). Explosive volcanic rocks such as ignimbrites show the strongest indications of crustal contamination, whereas the Cerro Llullaillaco dacite lavas mostly record significant garnet fractionation. Other lavas from the Llullaillaco area, including one flow from Cerro Llullaillaco, do not show garnet control, suggesting that different batches of magma stalled and fractionated at different levels in a thick (60-km) crust prior to eruption. The youngest volcanism in the Corrida de Cori area is represented by olivine–phyric basaltic andesite cinder cones and flows. The ascent of these relatively primitive magmas appears to have been controlled by late Quaternary normal faults, which directly tapped deeply derived melts. The Corrida de Cori volcanic range has experienced intense fumarolic alteration with deposition of abundant sulfate and native sulfur (previously mined at Mina Julia). Deeper levels of hydrothermal alteration have been sampled by an ignimbrite erupted from Cerro Escorial, which, among other lithic clasts, contains numerous fragments of vein quartz. Fluid inclusions in this quartz record evidence for a boiling, high-salinity fluid, which may represent a link between a high temperature magmatic–hydrothermal system at depth (i.e., a porphyry-type system) and shallow-level fumarolic activity. An ignimbrite erupted from Cerro Escorial preserves textures such as internal wave forms between flow units and surface wave morphologies at its distal limits that indicate flow as a series of dense turbulent pulses, which interdigitated and interfered with one another. Lithic lag breccias occur near the base of the flow proximal to the vent, but no air-fall deposits are preserved, probably due to transport of ash far from the vent by strong, high-altitude winds.     

Geology of the Heimaey volcanic centre, south Iceland: early evolution of a central volcano in a propagating rift?

Heimaey is the southernmost and also the youngest of nine volcanic centres in the southward-propagating Eastern Volcanic Zone, Iceland. The island of Heimaey belongs to the Vestmannaeyjar volcanic system (850 km²) and is situated 10 km off the south coast of Iceland. Although Heimaey probably started to form during the Upper Pleistocene all the exposed subaerial volcanics (10 monogenetic vents covering an area of 13.4 km²) are of Holocene age. Heimaey is composed of roughly equal amounts of tuff/tuff-breccias and lavas as most eruptions involve both a phreatomagmatic and an effusive phase. The compositions of the extrusives are predominantly alkali basalts belonging to the sodic series. Repeated eruptions on Heimaey, and the occurrence of slightly more evolved rocks (i.e. hawaiite approaching mugearite), might indicate that the island is in an early stage of forming a central volcano in the Vestmannaeyjar system. This is further substantiated by the development of a magma chamber at 10–20 km depth during the most recent eruption in 1973 and by the fact that the average volume of material produced in a single eruption on Heimaey is 0.32 km³ (dense rock equivalent), which is twice the value reported for the Vestmannaeyjar system as a whole. We find no support for the previously postulated episodic behaviour of the volcanism in the Vestmannaeyjar system. However, the oldest units exposed above sea level, i.e. the Norðurklettar ridge, probably formed over a 500-year interval during the deglaciation of southern Iceland. The absence of equilibrium phenocryst assemblages in the Heimaey lavas suggests that magma rose quickly from depth, without long-time ponding in shallow-seated crustal magma chambers. Eruptions on Heimaey have occurred along two main lineaments (N45°E and N65°E), which indicate that it is seismic events associated with the southward propagation of the Eastern Volcanic Zone that open pathways for the magma to reach the surface. Continuing southward propagation of the Eastern Volcanic Zone suggests that the frequency of volcanic eruptions in the Vestmannaeyjar system might increase with time, and that Heimaey may develop into a central volcano like the mature volcanic centres situated on the Icelandic mainland.     

The historic magmatic-hydrothermal eruption of the Breccia di Commenda, Vulcano, Italy

The historic Breccia di Commenda (BC) explosive eruption of Vulcano (Aeolian Islands, Italy) opened with a phase that generated a gray fine ash layer dispersed to the northwest (phase 1). The eruption continued with a dilute pyroclastic density current (PDC) that was dispersed to the east, followed by the emplacement of radially distributed, topographically controlled PDC deposits (phase 2). The last phase of the eruption produced a sequence of accretionary lapilli and gray fine ash dispersed toward the southeast (phase 3). The most impressive feature of the BC is its high lithic/juvenile clast ratio and the yellow color of the deposits of phase 2. Lithic fragments are mainly hydrothermally altered rocks, in the silicic and advanced argillic facies. Juvenile fragments, ranging from 20?% to 40?% by volume, are mainly confined to the ash component of the deposits and comprise rhyolitic to trachyandesite, poorly to non-vesicular fragments. The fine ash fraction of the deposits is richer in S, Cu, Zn, Pb, and As than the BC juvenile lapilli and bombs, and also the juvenile components of other La Fossa units, suggesting that the BC formed in the presence of an anomalously high amount of S and metals. Sulfur and metals may have been carried as aerosols by chloride- and sulfate-bearing micro-crystals, derived from the condensation of magmatic gas in the eruptive cloud. The high content of hydrothermally altered lithic clasts in the deposits suggests that explosions involved the fluid-saturated hydrothermally altered rocks residing in the conduit zone. However, the presence of a juvenile component in the deposits supports the idea that this explosion may have been triggered by the ascent of new magma. We categorize this eruption as magmatic-hydrothermal to emphasize that in this type of phreatomagmatic eruption the external water was an active hydrothermal system. Rock magnetic temperatures of non-altered lava lithic fragments indicate a uniform deposit temperature for the PDC deposits of between 200 and 260?°C, with a maximum at 280?°C. These homogeneous, relatively low temperatures are consistent with the idea that the phase 2 explosions involved the expansion of abundant steam from the flashing of the hydrothermal system. In addition, recent paleomagnetic dating of the BC provides an age of between 1000 and 1200?AD, younger than that reported in the previously published data, suggesting that previous interpretations and the recent history of La Fossa and Mt. Pilato require re-evaluation.     

A large K-foiditic hydromagmatic eruption from the early activity of the Alban Hills Volcanic District, Italy

In this paper we discuss the uncommon case of an energetic, pyroclastic-flow-forming eruption with a SiO₂-poor (42-45 wt.%), K-foiditic magma composition. The Trigoria-Tor de' Cenci Tuff (TTC; 561 ka) is the product of the first large-scale explosive event (of the order of 1-10 km³ of erupted products) in the Alban Hills Volcanic District, near the city of Rome, Italy. After an initial Plinian phase that produced a scoria fall horizon, pyroclastic current activity emplaced ash deposits with leucite-bearing juvenile scoria lapilli. The abundance of accretionary lapilli, the most distinctive feature of these deposits, together with the high degree of fragmentation, the abundance of minute lithic inclusions and the morphology of ash particles, indicates a hydromagmatic character for the most part of the eruption. The absence of vent-derived carbonate lithic clasts from the deep regional aquifer and the abundance of cognate lithic fragments suggest that the interaction with external water involved a surficial aquifer in the older Alban Hills volcanic terrains. Perhaps the most striking aspect of the TTC is the K-foiditic composition of the pre-eruptive melt, which, to our knowledge, is unique among explosive events of comparable size elsewhere in the world. The pre-eruptive magma system feeding the TTC was controlled mainly by leucite+clinopyroxene fractionation under a_H2O<1 conditions. The low SiO₂ activity prevented plagioclase and K-feldspar crystallization. The depth of the magma chamber can be estimated at 3-6 km within the carbonate substrate. In contrast to the other major pyroclastic-flow-forming eruptions of the Alban Hills, the juvenile volatile exsolution due to magma crystallization is not seen as the main mechanism driving the TTC eruption. We suggest that the explosive behaviour of the TTC magma in the early magmatic phase resulted from a rapid decompression due to a regional seismic event and from magma-water interaction in the succeeding phase.     

K/Ar dates of hydrothermal clays from core hole VC-2B, Valles caldera, New Mexico and their relation to alteration in a large hydrothermal system

Seventeen K/Ar dates were obtained on illitic clays within Valles caldera (1.13 Ma) to investigate the impact of hydrothermal alteration on Quaternary to Precambrian intracaldera and pre-caldera rocks in a large, long-lived hydrothermal system ( 1.0 Ma to present). Clay samples came from scientific core hole VC-2B (295°C at 1762 m) which was spudded in the Sulphur Springs thermal area and drilled into the boundary between the central resurgent dome and the western ring-fracture zone. Six illitic clays within Quaternary caldera-fill debris flow, tuffaceous sediment, and ash-flow tuff (48 to 587 m depth) yield ages from 0.35 to 1.09 Ma. Illite from Miocene pre-caldera sandstone (765 m) gives an age of 6.74 Ma. Two dates on illite from sandstones in Permian red beds (1008 and 1187 m) are 4.33 and 4.07 Ma, respectively. Surprisingly, three dates on illites from altered andesite pebbles within the red beds (1010–1014 m) are 0.95 to 1.06 Ma. Four illite dates on variably altered Precambrian quartz monzonite (1615–1762 m) range from 2.90 to 276 Ma.Post-Valles age illite is not correlated with alteration style (argillic to propylitic). Rather, post-Valles ages are uniformly obtained from illites in highly fractured, intensely altered, caldera-fill rocks and the Permian volcanic clasts. Generally, finer clay fractions from identical samples yield younger ages. Plots of ⁴⁰Ar/³⁶Ar versus ⁴⁰K/³⁶Ar and ⁴⁰Ar* versus ⁴⁰K for the illites in caldera-fill rocks lie close to a 1-Ma isochron. Most illite dates older than Valles caldera are difficult to interpret because they correspond to the ages of pre-Valles volcanic and hydrothermal episodes in the Jemez volcanic field ( 13 Ma). In addition, older dates may be caused by co-mingling of different illites during sample preparation, or by inherited argon or lost argon in illites from rocks with potentially complex hydrothermal histories. However, the range of ages obtained from illites in Permian sands and pebbles and from Precambrian crystalline rocks indicates that Valles hydrothermal activity is overwhelming illite produced by earlier geologic events.     

Evidence for magma hybridization for the voluminous 29.5 Ma Wah Wah Springs Formation, Utah and Nevada, U.S.A.

The 29.5 Ma Wah Wah Springs Formation which erupted from the Indian Peak Caldera has an estimated volume of > 3900 km³ making it one of the largest ignimbrites on earth. The magma was calc-alkaline, dacitic (68 wt. % SiO₂) and phenocryst-rich (38 vol.%). Phenocrysts include plagioclase (An 47), magnesio-hornblende, Mg-biotite, quartz, Fe-Ti oxides, diopsidic-augite, and rare Ca-poor pyroxene, in order of decreasing abundance. Apatite, zircon and pyrrhotite occurs as inclusions within phenocrysts. Atmospheric glass losses (1040 km³) account for bulk-rock compositions that have SiO₂ contents ranging from 63 to 67 wt.%. Glass compositions are high-silica rhyolite.Phenocrysts equilibrated at temperatures ranging from about 790 to 850°C and oxygen fugacities approximately 2.6 log units above the QFM buffer. Confining pressure estimates using the aluminum-in-hornblende geobarometer calibrated for calc-alkaline volcanic rocks suggest a mean pressure of 230±50 MPa corresponding to 7.5±1.5 km depth. These estimates are consistent with caldera formation accompanying emplacement.Crystal compositions for phenocrysts and mineral inclusions within phenocrysts are remarkably homogeneous throughout the outflow tuff, although minor zoning does occur. Given the dacitic composition of the magma, the weakly zoned phenocryst population cannot be modeled to produce the observed high-silica glass (melt) indicating open-system behavior for the magma. The high-silica rhyolite glass is interpreted to be an artifact of efficient magma mixing accompanying addition of highly evolved magma, or melt to intermediate composition magma. Mixing was followed by magma hybridization. Additional support for this hybridization model includes: (1) physically and chemically distinct populations of augite; (2) minor but unbiquitous resorbed plagioclase, biotite and hornblende phenocrysts; and (3) reverse zoning in some of the plagioclase euhedra within pumice lapilli.     

Subaqueous volcanism in the Paleo-Pacific Ocean based on Jurassic basaltic tuff and pillow basalt in the Raohe Complex,NE China

On-land records of subaqueous explosive volcanic eruptions are rarely reported.To understand this phenomenon and discuss its global significance,we studied the geochronology and geochemistry of basaltic tuff and pillow basalt in the Raohe Complex,NE China.The basaltic tuff consists of well-sorted vitreous,crystal(mostly clinopyroxene),and minor lithic fragments.It is characterized by a high Mg O(15.7–15.9%)content and zero Eu anomalies(Eu/Eu~*=99–102).The tuff erupted at 172±1 Ma based on SHRIMP zircon U-Pb dating,coeval with the previously reported age of the pillow basalt.The pillow basalt has intermediate Mg O content and weakly negative Eu anomalies(Eu/Eu~*=90–99).Based on immobile trace element discrimination,the basaltic tuff and pillow basalt belong to alkali basalt displaying an OIB-type trace element pattern,and consistent Nd isotope signatures ofε_(Nd)(t)=4.4–6.2,indicating an identical mantle source.The pillow basalt has coupled Sr-Nd isotopic values,whereas the basaltic tuff has significantly higher initial~(87)Sr/~(86)Sr values that are similar to synchronous seawater.This indicates that the elemental exchange between the mantle-derived material and seawater most likely occurred in a subaqueous explosive volcanic eruption,rather than in an effusive eruption.Detailed calculations suggest that the high efficiency of the Sr-isotope exchange between seawater and the mantle-derived material triggered by a subaqueous explosive volcanic eruption is likely one of the main reasons for the rapid decrease of the global seawater~(87)Sr/~(86)Sr value.