Geospatial technology and structural analysis for geological mapping and tectonic evolution of Feiran–Solaf metamorphic complex,South Sinai,Egypt

The Sinai Peninsula constitutes an important district of the Egyptian lands where it forms a triangular portion in northeastern Egypt. The southern Sinai metamorphic complexes are the northern uppermost part of the Arabian–Nubian Shield revealing the upper and middle crust from the East African Orogeny, in which they tectonically evolved. The Feiran–Solaf metamorphic complex (FSMC) of Sinai, Egypt is one of the highest grades metamorphic complexes of a series of basement domes that trends NW and crops out throughout the Arabian–Nubian Shield. The main aim of the present study is to apply the geospatial technology and to represent the capability of the geospatial technology to estimate the combined influence of lithology and structure studies, and to construct the lithological and structural maps of FSMC. Furthermore, detailed structural analysis is carried out to reveal the different ductile and brittle deformational events and proposed the tectonic evolutionary model for the study area. Mainly geospatial technology and structural analysis software have been used to go well with the aim of the present study. Developing specific image processing of satellite images and structural analysis were succeeded to discriminate the various lithological rock units, and the geological structural features of the FSMC, using geographic information system tools to construct the different thematic maps, were extracted. The present detailed investigations of the enhanced satellite images, structural analysis, and field verification reveal that the FSMC reached its present tectonic setting through more than four deformational phases concluding that the Pan-African Najd Fault System continued in Sinai and was reactivated during Red Sea tectonics as indicated by the dextral shear zone (Rihba) bordering the northern side of the FSMC.     

Cenomanian–Turonian transition in a shallow water sequence of the Sinai, Egypt

Environmental and depositional changes across the Late Cenomanian oceanic anoxic event (OAE2) in the Sinai, Egypt, are examined based on biostratigraphy, mineralogy, δ¹³C values and phosphorus analyses. Comparison with the Pueblo, Colorado, stratotype section reveals the Whadi El Ghaib section as stratigraphically complete across the late Cenomanian–early Turonian. Foraminifera are dominated by high-stress planktic and benthic assemblages characterized by low diversity, low-oxygen and low-salinity tolerant species, which mark shallow-water oceanic dysoxic conditions during OAE2. Oyster biostromes suggest deposition occurred in less than 50 m depths in low-oxygen, brackish, and nutrient-rich waters. Their demise prior to the peak δ¹³C excursion is likely due to a rising sea-level. Characteristic OAE2 anoxic conditions reached this coastal region only at the end of the δ¹³C plateau in deeper waters near the end of the Cenomanian. Increased phosphorus accumulations before and after the δ¹³C excursion suggest higher oxic conditions and increased detrital input. Bulk-rock and clay mineralogy indicate humid climate conditions, increased continental runoff and a rising sea up to the first δ¹³C peak. Above this interval, a dryer and seasonally well-contrasted climate with intermittently dry conditions prevailed. These results reveal the globally synchronous δ¹³C shift, but delayed effects of OAE2 dependent on water depth.     

Geochemistry of sedimentary rocks from Permian–Triassic boundary sections of Tethys Himalaya: implications for paleo-weathering,provenance, and tectonic setting

The geochemical characteristics of two sections—the Permian–Triassic boundary (PTB) Guryul Ravine section, Kashmir Valley, Jammu and Kashmir, India; and the Attargoo section, Spiti Valley, Himachal Pradesh, India—have been studied in the context of provenance, paleo-weathering, and plate tectonic setting. These sections represent the siliciclastic sedimentary sequence from the Tethys Himalaya. The PTB siliciclastic sedimentary sequence in these regions primarily consists of sandstones and shales with variable thickness. Present studied sandstones and shales of both sections had chemical index of alteration values between 65 and 74; such values reveal low-to-moderate degree of chemical weathering. The chemical index of weathering in studied samples ranged from 71 to 94, suggesting a minor K-metasomatism effect on these samples. Plagioclase index of alteration in studied sections ranged from 68 to 92, indicating a moderate degree of weathering of plagioclase feldspars. The provenance discriminant function diagram suggests that the detritus involved in the formation of present studied siliciclastic sedimentary rocks fall in quartzose sedimentary and felsic igneous provenances. These sediments were deposited in a passive continental margin plate tectonic setting according to their location on a Si₂O versus K₂O/Na₂O tectonic setting diagram.     

Elemental and Sr–Nd isotopic systematics of the early Mesozoic volcanic sequence in southern Jiangxi Province, South China: petrogenesis and tectonic implications

Elemental and Sr–Nd isotopic results are presented for the early Mesozoic volcanic sequence (~172 Ma) in southern Jiangxi Province, South China. The sequence is voluminously composed of ~45% subalkaline basaltic rocks (group 1), <5% high-mg andesite–dacites (group 2) and ~50% rhyolites (group 3). The group 1 rocks are characterized by (La/Yb)_cn = 3.8–7.2, Eu/Eu* = 0.65–1.15, Nb/La = 0.64–0.99, ⁸⁷Sr/⁸⁶Sr(t) = 0.70602~0.70822 and _Nd(t) = –1.63 to +0.11, similar to those of an EMII-like source. The group 2 rocks have mg=0.42~0.60, SiO₂=60.24~66.71%, MgO=2.65~ 5.54%, Ni=24~102 ppm and Cr=84~266 ppm, classified as high-mg andesitic rocks. These rocks are more enriched in LILEs and LREE with more significant negative Eu anomaly (0.63~0.79), are more depleted in HFSEs with Nb/La ratios of 0.40–0.56 and have lower _Nd(t) (–9.44 to –7.78) and higher ⁸⁷Sr/⁸⁶Sr(t) (0.70985~0.71016), in comparison with the group 1 rocks. They most likely originated from metasomatised veins in the lithospheric mantle. The origination of the group 1 and group 2 magma suggests the development of a peridotite-plus-vein lithospheric mantle during early Mesozoic era beneath the interior of the Cathaysian block. The group 3 rhyolites are characterized by high SiO₂ (72.75~77.97%), Zr (99~290 ppm), Hf (3.9~9.7 ppm) and Ga/Al (2.76~3.87) and significant Nb–Ta, Ba–Sr and P–Ti depletions. These rhyolites exhibit Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) = 0.70962~0.71104, _Nd(t) = –4.63 to –5.80) similar to the contemporaneous Zhaibei and Pitou A-type granites in the area. Such characteristics suggest that they might be derived from the underplating basaltic magma contaminated by crustal materials. Therefore, an early Mesozoic rifting model in response to intracontinental lithospheric extension is proposed to account for the early Mesozoic volcanism in southern Jiangxi Province, South China.     

Geochemistry and magmatic setting of Wadi El-Markh island-arc gabbro–diorite suite,central Eastern Desert,Egypt

Wadi El-Markh gabbro–diorite complex is composed of pyroxene hornblende gabbros, hornblende gabbros, diorites and quartz diorites. According to their bulk rock geochemistry and mineral chemistry, the gabbroic and dioritic rocks represent fractionates along a single line of descent and crystallized from a calc-alkaline mafic magma. When compared to the primitive mantle, all members of the gabbroic–dioritic rock suite are enriched in the large ion lithophile elements relative to the high field strength elements and display distinctive negative Nb and P₂O₅ anomalies. This signals an arc setting. Fractionation modeling involving the major elements reveals that the hornblende gabbros were generated from the parent pyroxene hornblende gabbros by 61.86% fractional crystallization. The diorites were produced from the hornblende gabbros by fractional crystallization with a 58.97% residual liquid, whereas the quartz diorites were formed from the diorites by 26.58% fractional crystallization. According to geothermobarometry based on amphibole mineral chemistry, the most primitive pyroxene hornblende gabbros crystallized at ～830 °C/～5 kbar. The crystallization conditions of the quartz diorites were estimated at ～570 °C/～2 kbar. In consequence the Wadi El-Markh gabbro–diorite complex represents a single magmatic suite of which fractionates crystallized in progressively shallower levels of an arc crust.     

Geochemistry of Silurian–Carboniferous sedimentary rocks of the Ulaanbaatar terrane,Hangay–Hentey belt,central Mongolia: Provenance,paleoweathering, tectonic setting,and relationship with the neighbouring Tsetserleg terrane

The Hangay–Hentey belt is situated in the central Northern Mongolia, and forms part of the Central Asian Orogenic Belt (CAOB). It is internally subdivided into seven terranes, the largest of which are the neighbouring Ulaanbaatar and Tsetserleg terranes. These coeval terranes are mainly composed of Silurian–Devonian accretionary complexes and Carboniferous turbidites. Proposals for their depositional setting range from passive margin through to island arc. A suite of 19 Ulaanbaatar terrane sandstones and mudrocks (Gorkhi and Altanovoo Formations) were collected with the aim of constraining their provenance, source weathering, and depositional setting based on whole-rock major and trace element data, and for comparison with the neighbouring Tsetserleg terrane. New REE analyses were also made of 35 samples from the Ulaanbaatar and Tsetserleg terranes. Geochemically the Ulaanbaatar sandstones are classed as wackes, and most of the mudstones as shales. Geochemical parameters suggest an immature source, similar to that of the Tsetserleg terrane. Geochemical contrasts between sandstones and mudrocks in the Ulaanbaatar sediments are small, and trends on element – Al₂O₃ variation diagrams are weak. Comparison with average upper continental crust (UCC), major element discriminant scores, and immobile element ratios (Th/Sc, Zr/Sc, Ce/Sc, Ti/Zr) indicate a uniform average source composition between dacite and rhyolite. Maximum Chemical Index of Alteration value in the Ulaanbaatar terrane is ∼65 after correction for K-metasomatism, indicating minimal weathering in a tectonically active source, similar to that of the Tsetserleg terrane. REE data in both terranes show moderate LREE enrichment and flat HREE segments, with negative Eu anomalies somewhat less than those in UCC and PAAS. Chondrite-normalized patterns are very similar to that for average Paleozoic felsic volcanic rock, supporting the relatively felsic source indicated by immobile trace element ratios. Tectonic setting discriminants (K₂O/Na₂O–SiO₂/Al₂O₃, La–Th–Sc, Th–Sc–Zr) indicate an evolved continental island arc (CIA; A2) environment for both terranes, similar to several other CAOB suites of similar age. This common arc source was situated within the Mongol-Okhotsk Ocean during Silurian–Lower Carboniferous time. The present-day Aleutian arc is a possible modern analogue of the depositional setting.     

Age and tectonic setting of the Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide deposit, southern Iran

The Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide (VMS) deposit occurs within the Surian volcano-sedimentary complex in the Sanandaj–Sirjan zone (SSZ) of southern Iran. The Surian complex is comprised of pelite, sandstone, calcareous shale, basalt, gabbro sills, and thin-bedded limestone. Mineralization occurs as stratiform sheet-like and tabular orebodies hosted mainly by greenschist metamorphosed feldspathic and quartz feldspathic sandstone, basalt, and pelites. The basalts of the Surian complex show predominantly tholeiitic to transitional affinities, with a few samples that are alkalic in composition. Primitive mantle-normalized trace and rare earth element (REE) patterns of the Surian basalts display depletions in light REE, negative anomalies of Nb, Ta, and Ti, and positive anomalies of P. Positive P anomalies are indicative of minor crustal contamination. Furthermore, Th enrichments in the mid-ocean ridge basalt-normalized patterns of the Surian basalts are characteristic of rifted arc basalts emplaced in continental margin subduction zones. The high MgO content (>6?wt.%) of most Surian basalts and low TiO₂ content of two samples (0.53 and 0.62?wt.%) are characteristic of boninites. The aforementioned features of the basalts indicate arc tholeiites emplaced in intra-arc rift environments and continental margin subduction zones. U–Pb dating by laser ablation- inductively coupled plasma mass spectrometry of detrital zircons extracted from the host feldspathic and quartz feldspathic sandstone yields various ages that are predominantly Permian and Triassic; however, the youngest zircons give a mean Early Jurassic concordant U–Pb age of 191?±?12?Ma. This age, together with geological and petrochemical data, indicate that VMS mineralization formed in the Early Jurassic in pull-apart basins within the SSZ. These basins and the VMS mineralization may be temporally related to an intra-arc volcano–plutonic event associated with Neo-Tethyan oblique subduction.     

1989–1995 Earthquake sequences in the Galeras volcano region,SW Colombia,and possible volcano–earthquake interactions

The Galeras volcanic complex, located in the Nariño department, SW Colombia, includes the most historically active volcano in the country, Galeras, a 4276 m high stratovolcano located 9 km west of the city of San Juan de Pasto (400,000 inhabitants). The area is also affected by the continental faulting represented by the Buesaco, Aranda and Pasto faults belonging to one of the most seismically active structures in Colombia, the Romeral fault system. Several moderate to strong shallow earthquakes affected the city of San Juan de Pasto and its neighbouring region since the XVII century. The coexistence of an active volcanic complex and an active fault system complicates the study and interpretation of the different processes taking place in the region as well as the identification of any connection or interaction among them.The reactivation of the volcano in 1989 was characterized by three main magmatic events: (1) a series of Vulcanian eruptions during 4–9 May 1989, with semi-continuous ash emissions from a secondary crater; (2) the emplacement of an andesitic lava dome at the bottom of the main crater from September 1990 until December 1991; and (3) six Vulcanian eruptions from the main crater during 1992–1993, with destruction of most of the dome during the first one on 16 July 1992. During the same period, four earthquake sequences were located in a limited area N and NE of Galeras volcano on August–September 1989 (AUG1989), April–June 1993 (APR1993), November–December 1993 (NOV1993) and March–August 1995 (MAR1995). The last one included a Ml4.7 main shock on 4 March 1995 producing moderate to high damage in the epicentral region (MSK maximum intensity VIII), and in the city of San Juan de Pasto (VI–VII). The last damaging earthquake in the region was a MSK-intensity VIII–IX in 1947.A detailed analysis of the spatio-temporal characteristics of the four earthquake sequences allowed identifying their different origin and suggesting some interrelationship between the reactivated eruptive process and the contemporaneous seismic activity. The AUG1989 sequence presents a typical volcanic swarm-like pattern most probably related with the process of magma intrusion from depth at the beginning of the volcano's reactivation. The APR1993, the NOV1993 and the MAR1995 sequences show a clear tectonic origin with events occurring on rupture planes almost vertical that can be associated to the active faults in the area, The seismogenic process of these three sequences could have been activated or accelerated by the main eruptions during 1992–1993.These results suggest that constrains provided by improved relocations and the detailed analysis of the space–time characteristics of earthquake sequences in Galeras volcanic environment allow to establish the different generation mechanisms involved and to suggest feasible explanations on the possible interrelationships of the magmatic–volcanic processes and the seismicity observed.     

Geochemistry,petrogenesis and tectonic setting of Neoproterozoic mafic–ultramafic rocks from the western Jiangnan orogen,South China

The Jiangnan orogenic belt (JOB) has been interpreted as a suture zone between the Yangtze craton and Cathaysian terranes in South China. The Neoproterozoic mafic–ultramafic rocks are extensively exposed in the western JOB, providing an ideal opportunity to study the Neoproterozoic assembly and tectonic evolution of South China. We present integrated field and geochemical studies including LA-ICP-MS zircon U–Pb dating, and whole-rock major and trace element and Sm–Nd isotope analyses of the Neoproterozoic mafic–ultramafic rocks exposed in the northern Guangxi Province, South China. Geochronological results show that the magmatic events took place in two distinct periods: the early Neoproterozoic (861–834 Ma) and the late Neoproterozoic (770–750 Ma). Early Neoproterozoic ultramafic rocks of the Sibao Group have positive ε_Nd(t) values (+ 2.7 to + 6.6) whereas mafic rocks exhibit negative ε_Nd(t) values (− 5.8 to − 0.9). The basaltic rocks show TiO₂ contents of 0.62–0.69 wt.% and Mg-number of 59–65, and also display an enrichment of light rare earth elements (LREEs) and pronounced negative Nb, Ta and Ti anomalies on chondrite- and primitive mantle-normalized diagrams, consistent with subduction-related geochemical signatures. Late Neoproterozoic rocks of the Danzhou Group show ε_Nd(t) values (− 1.23 to + 3.19) for both ultramafic and mafic rocks. The basaltic rocks have TiO₂ contents of 1.01–1.33 wt.% and Mg-number of 57–60, and have a mixture of MORB- and arc-like geochemical affinities, inferred to have formed in an extensional arc environment. Geochemical signatures suggest that all rock types in this study were derived from subarc mantle wedge sources and underwent various degrees of crustal contamination. Thus, we suggest that subduction may have continued to ca. 750 Ma in the western JOB, implying that the amalgamation event between the Yangtze craton and Cathaysian terranes was later than 750 Ma.     

Pre-Cenozoic tectonic attribute and setting of the Song Da zone,VietnamEI北大核心CSCD

Rock association and regional unconformity are identified based on field survey and mapping for the stratigraphy, tectonics, metamorphic rock and igneous rocks in the Song Da zone, the northwestern Vietnam. Pre-Cenozoic in the Song Da zone is divided into three structural layers: (1) the Presinian crystalline basement, (2) the Cambrian-lower part of Upper Triassic, and (3) the upper part of Upper Triassic-Cretaceous. The Pre-Cenozoic structural successions of the Song Da zone show similar features with those of the Yangtze-South China plate: (1) In the Presinian, both of them have TTG complex and Khondalite series of similar ages and experienced similar tectonic evolution; (2) In the Cambrian-early Upper Triassic, the phosphorite and thick-layered limestone are comparable, and the Permian-Triassic basalt in the Song Da zone has genetic mechanism similar to that of the Emeishan basalt; (3) In the late Upper Triassic-Cretaceous, the volcanic-sedimentary faulted basins and thick continental red beds are comparable to those in East China. It can be concluded that the Song Da zone should have been part of the southwestern Yangtze-South China plate, and the boundary between the Yangtze-South China plate and Indochina plate is the Song Ma suture zone which contains ophiolite remnants. Tectonic settings of different structural layers indicate that the Song Da Zone experienced geological events such as the Columbia and Rodinia Supercontinent, sedimentation of the stable platform cover, closure of the Paleo-Tethys, and NW subduction of the Paleo-Pacific plate to the Eurasian plate. The Pre-Cenozoic basement of the Yinggehai Basin is the seaward extension of the Song Da zone, which shows similar tectonic features.     

Geochemistry,petrogenesis and tectonic setting of the peraluminous granites in the nacheng gold deposit,Yongning, Guangdong北大核心

The Nacheng granite locates in the Yong ning area, Guangdong Province. This paper studied petrographical and chronological characteristics of this granite as well as its petrogenesis and geological significance. The Nacheng granite mainly consists of quartz (40%-50%), orthoclase (25%-30%), palgioxlase (15%-20%) with minor accessory minerals of quartz apatite and magnetite. Geochemical analyses show that the manziying granite has high content of SiO2 (75. 56%) , K2O (4.72%), Al2O3 (13. 34%) and total alkali (Na2O+K2O=7. 49%), but relatively low MgO (0. 04%-1. 29%) and CaO (0. 39%-2. 21%). The ratios of K2O/Na 2O are generally higher than 1. The Rittmann indexes are between 1-2. 43, belonging to the high-K calc-alkaline series. The values of A/CNK vary from 1. 12 to 1. 32 with an average of 1. 10, showing the characteristics of peraluminous S type granites. Trace element analyses show that the Nacheng granite has relatively high REE content of 82. 6 × 10-6 225. 68 × 10-1, and displays right-inclined V-shape REE patterns with relatively high fractionations of LREE and HREE[(La/Yb)N = 1. 51-9. 66] and pronounced negative Eu anomalies (δEu = 0. 31-0. 74) in the chondrite-normalized REE diagrams, suggesting a typical crust-derived grandite. The magmas may be divided into two types: "low-temperature" type from mudstones and "high-temperature" type from sandstones. The Nacheng granites were formed from the post-orogenic tectonic setting.     

Petrology and geochemistry of sandstones in the southern Benue Trough of Nigeria： Implications for provenance and tectonic setting

Petrographic and geochemical analyses of three Cretaceous lithostratigraphic sandstone units were undertaken to constrain their provenance and tectonic setting. Petrographic analysis showed that there are differences in composition between the three sandstone bodies, which can be attributed to differences in provenance relief, transport distance and geology of the terrain. Composition of the three lithostratigraphic sandstone bodies fall within the craton interior field.
Framework mode and chemical features indicated their derivation from basaltic volcanics, source rocks during the early rifting stage, and felsic, intermediate and mafic igneous source rocks located at the southeast basement complex terrain, with minor sedimentary components from the uplifted and folded older Cretaceous strata.
The chemical composition of the sandstones is mainly related to source rocks, chemical weathering conditions and transport agents. The source rocks were derived mainly from the southeastern Precambrian basement of Nigeria. Through examination of the sandstones, the tectonic setting was modeled. The Benue Trough belongs to a continental sedimentary basin of the passive margin type.
The tectonic evolution from Albian to Maastrichtain of the trough is contributed to the difference in framework mode and chemical composition of the sandstones. The evolution of the basin was reconstructed in terms of sandstone petrology and geochemistry. The tectonic evolution can be subdivided into three stages from the petrology and geochemistry data. The first stage covers Albian; the second stage the Turonian-Coniacian, and the third stage the Campanian-Maastrichtain. These are the three mega discontinuities in the sandstone composition among these three stages. These three discontinuities signify the influence of tectonism.     

Geological–tectonic framework of Solomon Islands,SW Pacific: crustal accretion and growth within an intra-oceanic setting

The Solomon Islands are a complex collage of crustal units or terrains (herein termed the `Solomon block') which have formed and accreted within an intra-oceanic environment since Cretaceous times. Predominantly Cretaceous basaltic basement sequences are divided into: (1) a plume-related Ontong Java Plateau terrain (OJPT) which includes Malaita, Ulawa, and northern Santa Isabel; (2) a `normal' ocean ridge related South Solomon MORB terrain (SSMT) which includes Choiseul and Guadalcanal; and (3) a hybrid `Makira terrain' which has both MORB and plume/plateau affinities. The OJPT formed as an integral part of the massive Ontong Java Plateau (OJP), at c. 122 Ma and 90 Ma, respectively, was subsequently affected by Eocene–Oligocene alkaline and alnoitic magmatism, and was unaffected by subsequent arc development. The SSMT initially formed within a `normal' ocean ridge environment which produced a MORB-like basaltic basement through which two stages of arc crustal growth subsequently developed from the Eocene onwards. The Makira terrain records the intermingling of basalts with plume/plateau and MORB affinities from c. 90 Ma to c. 30 Ma, and a contribution from Late Miocene–present-day arc growth. Two distinct stages of arc growth occurred within the Solomon block from the Eocene to the Early Miocene (stage 1) and from the Late Miocene to the present day (stage 2). Stage 1 arc growth created the basement of the central part of the Solomon block (the Central Solomon terrain, CST), which includes the Shortland, Florida and south Isabel islands. Stage 2 arc growth led to crustal growth in the west and south (the New Georgia terrain or NGT) which includes Savo, and the New Georgia and Russell islands. Both stages of arc growth also added new material to pre-existing crustal units within other terrains. The Solomon block terrane collage records the collision between the Alaska sized OJP and the Solomon arc. Initial contact possibly first occurred some 25–20 Ma but it is only since around 4 Ma that the OJP has more forcefully collided with the Solomon arc, and has been actively accreting since that time, continuing to the present day. We present a number of tectonic models in an attempt to understand the mechanism of plateau accretion. One model depicts the OJP as splitting in two with the upper 4–10 km forming an imbricate stack verging to the northeast, over which the Solomon arc is overthrust, whilst deeper portions of the OJP (beneath a critical detachment surface) are subducted. The subduction of young (<5 Ma), hot, oceanic lithosphere belonging to the Woodlark basin at the SSTS has resulted in a sequence of tectonic phenomena including: the production of unusual magma compositions (e.g. Na–Ti-rich basalts, and an abundance of picrites); an anomalously small arc–trench gap between the SSTS and the Quaternary–Recent arc front; calc-alkaline arc growth within the downgoing Woodlark basin lithospheric plate as a consequence of calc-alkaline magma transfer along leaky NE–SW-trending faults; rapid fore-arc uplift; and rapid infilling of intra-arc basins. The present-day highly oblique collision between the Pacific and Australian plates has resulted in the formation of rhombohedral intra- and back-arc basins.     

Geochemistry,provenance and tectonic setting of the Late Cambrian–Early Ordovician Seydişehir Formation in the Çaltepe and Fele areas,SE Turkey

The major, trace and rare earth element (REE) contents of metapelite (MPL), metapsammite (MPS) and metamarl (MM) samples from the Cambro-Ordovician Seydi?ehir Formation were analyzed to investigate their provenance and tectonic setting. The MPS, MPL, and MM samples have variable SiO₂ concentrations, with average values of 72.36, 55.54, and 20.95 wt%, moderate SiO₂/Al₂O₃ ratios (means of 6.88, 3.23, and 3.80), moderate to high Fe₂O₃ + MgO contents (means of 5.14, 9.55, 3.56 wt%), and high K₂O/Na₂O ratios (means of 3.26, 3.64, 2.90), respectively. On average, the chemical index of alteration (CIA) values of the MPS and the MPL are 65.87 and 71.96, respectively, while the chemical index of weathering (CIW) values are 74.54 and 85.09, respectively. These data record an intermediate to high degree of alteration (weathering) of plagioclase to illite/kaolinite in the samples’ provenance. The chondrite-normalized REE patterns of all the sample groups are similar and are characterized by subparallel light rare earth elements (LREE)-enriched, relatively flat heavy rare earth elements (HREE) patterns with pronounced Eu anomalies (mean of 0.69) and moderate fractionation [average (La/Yb)_N = 8.7]. Plots of sediments in ternary diagrams of La, Th, Sc and elemental ratios (La/Sc, Th/Sc, Cr/Th, Eu/Eu*, La/Lu, Co/Th, La/Sc and Sc/Th), which are critical for determining provenance, and REE patterns indicate that the metaclastic units of the Seydi?ehir Formation were derived dominantly from felsic to intermediate magmatic rocks and not from a mafic source. The La–Sc–Th and Th–Sc–Zr/10 ternary diagrams of the Seydi?ehir Formation are typical of continental island arc/active continental margin tectonic settings. The geologic location and geochemistry of the Seydi?ehir Formation suggest that it was deposited in an Andean-type retroarc foreland basin during the Late Cambrian–Early Ordovician period. The Neoproterozoic intermediate to felsic magmatic rocks and metaclastic sediments with felsic origins of the Sand?kl?–Afyon Basement Complex (SBC) and their equivalent units, which are thought to be overlain by the younger units in the study area, may be the dominant source rocks for the Seydi?ehir Formation.     

Geochemistry of the low‐grade Early Proterozoic sedimentary sequence in the Pine Creek Geosyncline,Northern Territory

Abstract

The geochemistry of Early Proterozoic sedimentary rocks from the low‐grade metamorphic terrain W of the South Alligator Hinge Zone in the Pine Creek Geosyncline is reported and discussed in terms of the stratigraphy and differences in rock type. Major element trends are dominated by lithological and mineralogical variations; in particular, the dolomitic nature of pelites in the Mount Partridge and Namoona Groups, the presence of chlorite in Crater Formation pelites, and the volcanic affinity of pelites within the Gerowie Tuff. Concentration of Th, U, Zr, Y, Nb, Ce and La in the clastic sediments of the Finniss River and South Alligator Groups is probably related to the presence of felsic volcanics in these groups; high levels of Sn in these groups may be similarly related, and highlight the apparent volcanogenic source for this metal. The South Alligator Group is a preferred host for base‐metal mineralization, and the regional abundance of several metals in this group enhance its economic potential and support a syngenetic, possibly exhalative, origin for these deposits. Anomalous Co, Ni, and V values in Masson Formation pelites are probably related to the nearby mafic Stag Creek Volcanics. Detrital minerals derived from reworked Archaean basement account for high Zr and Th in the Crater Formation. The geochemical data support the shift in REE patterns related to changes in crustal composition about the Archaean‐Proterozoic boundary, though patterns within the Early Proterozoic have also been influenced by felsic volcanism in the South Alligator Group. The chemical index of alteration (which reflects the degree of weathering of sedimentary rocks) reflects the existence of a major unconformity between the Mount Partridge and Namoona Groups; however, other hiatuses observed in or inferred from the rock record are not evident. The dominant felsic volcanic component of the Gerowie Tuff pelites is also indicated by this technique.     

Provenance and tectonic setting of Neoproterozoic sedimentary sequences in the South China Block: evidence from detrital zircon ages and Hf–Nd isotopes

Neoproterozoic sedimentary sequences in the South China Block provide great opportunity to examine the tectonic evolution and crustal accretion during this period. This study presents U–Pb ages and Hf isotope composition of detrital zircons and Nd isotope composition of whole rocks of the Neoproterozoic sequences from the Yangtze Block, part of the South China Block. Age patterns of detrital zircons imply that the source area experienced three major periods of magmatic activity at 2,300–2,560, 1,900–2,100 and 770–1,000?Ma and two major episodes of juvenile crust accretion at 2,600–3,400 and 770–1,000?Ma. The maximum age of the Gucheng glaciation can be restricted at?~768?Ma from the youngest detrital zircon ages, probably corresponding to the Kaigas glaciation rather than to the Sturtian glaciation. High La/Sc ratio and low Cr/Th, Sc/Th and Co/Th ratios of the sedimentary rocks point to a derivation from dominantly felsic upper continental crustal sources, whereas large variation of ε_Nd(t) and ε_Hf(t) values indicates that mantle-derived magmatic rocks also provided material to the sedimentary sequences in different degrees. The shift in ε_Nd(t) values of whole rocks and U–Pb age spectra of detrital zircons records the evolution from a back-arc to retro-arc foreland to a rift basin. Age distribution of detrital zircons from the Neoproterozoic sequences, compared with those of the major crustal blocks of Rodinia, implies that the position of the Yangtze Block was probably adjacent to northern India rather than between Australia and Laurentia before the breakup of the Rodinia supercontinent.     

Geochemistry and Sm–Nd isotopic systematics of Ediacaran–Ordovician,sedimentary and bimodal igneous rocks in the western Acatlán Complex,southern Mexico: Evidence for rifting on the southern margin of the Rheic Ocean

Ordovician igneous rocks in the western Acatlán Complex (Olinalá area) of southern Mexico include a bimodal igneous suite that intrudes quartzites and gneisses of the Zacango Unit, and all these rocks were polydeformed and metamorphosed in the amphibolite facies during the Devono-Carboniferous. The Ordovician igneous rocks consist of the penecontemporaneous amphibolites, megacrystic granitoids and leucogranite, the latter dated at ca. 464 Ma. Geochemical and Sm–Nd data indicate that the amphibolites have a differentiated tholeiitic signature, and that its mafic protoliths formed in an extensional setting transitional between within-plate and ocean floor. The amphibolites are variably contaminated by a Mesoproterozoic crustal source, inferred to be the Oaxacan basement exposed in the adjacent terrane. The most primitive samples have εNdt (t = 465 Ma) values significantly below that of the contemporary depleted mantle and were probably derived from the sub-continental lithospheric mantle. The megacrystic granites were most probably derived by partial melting of an arc crustal source (similar to the Oaxacan Complex) and triggered by the ascent of mafic magma from the lithospheric mantle. Sm–Nd isotopic signatures suggest that metasedimentary rocks from Zacango Unit were derived from adjacent Oaxacan Complex. Trace elements relationships (e.g. La/Th vs. Hf) and REE patterns suggest provenance in felsic-intermediate igneous rocks with a calc-alkaline signature. The Ordovician bimodal magmatism is inferred to have resulted from rifting on the southern flank of the Rheic Ocean and is an expression of a major rifting event that occurred along much of the northern Gondwanan margin in the Ordovician.     

Nd-isotope and geochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite suite of rocks in the southern Bastar craton,central India: petrogenesis and tectonic significance

ABSTRACT

Nd-isotope and lithogeochemistry of an early Palaeoproterozoic high-Si high-Mg boninite–norite (BN) suite of rocks from the southern Bastar craton, central India, are presented to understand their nature, origin, and tectonic setting of emplacement. Various types of evidence, such as field relationships, radiometric metamorphic ages, and the global distribution of BN magmatism, suggest emplacement in an intracratonic rift setting, commonly around 2.4–2.5 Ga. On the basis of geochemistry these high-Si high-Mg rocks are classified as high-Ca boninites, high-Mg norites, and high-Mg diorites. Nd-isotope data indicate that the high-Mg norite and the high-Mg diorite samples are similar, whereas the high-Ca boninites have a different isotopic character. The high-Mg norite and the high-Mg diorite samples have younger T_DM model ages than the high-Ca boninites. Geochemical and Nd-isotopic characteristics of the studied rocks indicate some prospect of crustal contamination; however, the possibility of mantle metasomatism during ancient subduction event cannot be ignored. Trace-element modelling suggests that the high-Ca boninites may have crystallized from a magma generated by a comparatively greater percentage of melting of a lherzolite mantle source than the source for the other two varieties. Furthermore, the high-Ca boninite rocks are most likely derived from an Archaean subduction process (the Whundo-type), whereas the other two types are the products of the interaction of subduction-modified refractory mantle wedge and a plume, around the Neoarchaean–Palaeoproterozoic boundary. The emplacement of the high-Mg norites and the high-Mg diorites may be linked to crustal thickening and associated cratonization at the end of the Archaean.     

The Wadi Zaghra metasediments of Sinai,Egypt: new constraints on the late Cryogenian–Ediacaran tectonic evolution of the northernmost Arabian–Nubian Shield

ABSTRACT

The La Tinta mélange is a small but singular ultramafic mélange sheet that crops out in eastern Cuba. It is composed of dolerite-derived amphibolite blocks embedded in a serpentinite matrix. The amphibolite blocks have mid-ocean ridge basalt (MORB)-like composition showing little if any imprint of subduction zone component, similar to most forearc and MOR basalts worldwide. Relict Cr-spinel and olivine mineral chemistry of the serpentinized ultramafic matrix suggest a forearc position for these rocks. These characteristics, together with a hornblende ⁴⁰Ar/³⁹Ar age of 123.2 ± 2.2 Ma from one of the amphibolite blocks, suggest that the protoliths of the amphibolite blocks correspond to forearc basalt (FAB)-related rocks that formed during the earlier stage of subduction initiation of the Early Cretaceous Caribbean arc. We propose that the La Tinta amphibolites correspond to fragments of sills and dikes of hypoabyssal rocks formed in the earlier stages of a subduction initiation scenario in the Pacific realm (ca. 136 Ma). The forearc dolerite-derived amphibolites formed by partial melting of upwelling fertile asthenosphere at the beginning of subduction of the Proto-Caribbean (Atlantic) slab, with no interaction with slab-derived fluids/melts. This magmatic episode probably correlates with Early Cretaceous basic rocks described in Hispaniola (Gaspar Hernandez serpentinized peridotite-tectonite). The dikes and sills cooled and metamorphosed due to hydration at low pressure (ca. 3.8 kbar) and medium to high temperature (up to 720ºC) and reached ca. 500ºC at ca. 123 Ma. At this cooling stage, serpentinite formed after hydration of the ultramafic upper mantle. This process might have been favoured by faulting during extension of the forearc, indicating an early stage of dike and sill fragmentation and serpentinite mélanges formation; however, full development of the mélange likely took place during tectonic emplacement (obduction) onto the thrust belt of eastern Cuba during the latest Cretaceous.     

Geochemistry and petrogenesis of late Ediacaran (605–580 Ma) post-collisional alkaline rocks from the Katherina ring complex,south Sinai,Egypt

The Katherina ring complex (KRC) in the central part of south Sinai, Egypt, is a typical ring complex of late Neoproterozoic age (605–580 Ma). It was developed during the final tectono-magmatic stage of the north Arabian–Nubian Shield (ANS) during evolution of the Pan-African crust. The KRC includes Katherina volcanics, subvolcanic bodies, ring dykes and Katherina granitic pluton. The Katherina volcanics represent the earliest stage of the KRC, which was subsequently followed by emplacement of the subvolcanic bodies and ring dykes. The Katherina granitic pluton depicts as the latest evolution stage of the KRC that intruded all the early formed rock units in the concerned area. The Katherina volcanics are essentially composed of rhyolites, ignimbrite, volcanic breccia and tuffs. Mineralogically, the peralkaline rhyolites contain sodic amphiboles and aegirine. The rhyolite whole rock chemistry has acmite-normative character. The subvolcanic bodies of the KRC are represented by peralkaline microgranite and porphyritic quartz syenite. The ring dykes are semicircular in shape and consist mainly of quartz syenite, quartz trachyte and trachybasalt rock types. The Katherina subvolcanic rocks, volcanic rocks as well as the ring dykes are alkaline or/and peralkaline in nature. The alkaline granitic pluton forms the inner core of the KRC, including the high mountainous areas of G. Abbas Pasha, G. Bab, G. Katherina and G. Musa. These mountains are made up of alkaline syenogranite and alkali feldspar granite. The mantle signature recorded in the KRC indicates a juvenile ANS crust partial melting process for the generation of this system. The evolution of the KRC rocks is mainly dominated by crystal fractionation and crustal contamination. Mineral geothermometry points to the high temperature character of the KRC, up to 700–1100 °C.