Two series of copper-gold deposits in the middle and lower reaches of the Yangtze River area (MLYRA) and the hydrogen,oxygen, sulfur and lead isotopes of their ore-forming hydrothermal systems

Based on studies on the geological characteristics of the copper-gold deposits in the middle and lower reaches of the Yangtze River area (MLYRA) and their hydrogen, oxygen, sulfur and lead isotope compositions, it is concluded that there existed two series of copper-gold deposits. They are evolutional products of two ore-forming hydrothermal systems in different geodynamic settings and geological era. Series I is stratiform or stratabound copper-gold deposits. These deposits were formed by submarine exhalation and sedimentation of hydrothermal solutions in Hercynian tensional tectonic environment after bot brine ascending along contemporaneous faults and exhaled into the sea-floor. Series II consists of copper-gold deposits related to medium and acidic magmatic intrusions. Their mineralizations took place in Yanshanian in a tensional or a transitional period to the tensional tectonic environment from the composite of the tethys tectonic regime and the Paleo-Pacific ocean tectonic regime, as well as in the upper mantle doming and crustal thinning environment. Copper-gold deposits were formed from the hydrothermal fluids, mixtures of magmatic water and part of meteoric water, by complex water-rock interactions and coupling dynamic processes of transport-chemical reactions. Superposition is an important condition for the formation of the large-scale copper-gold ore deposits.

     

Geochemistry of ore-forming fluids and geological significance of the Kuoerzhenkuola gold field in Xinjiang, China

The Kuoerzhenkuola gold field (including the Kuo- erzhenkuola and the Buerkesidai gold deposits), lo- cated 68 km east of Jimunai County in northern Xing- jiang, China, is an important component of the Sawuer gold belt which is the eastward extending part of the Zarma-Sawur gold-copper belt in Kazakhstan. Some studies are concerned with the geology of the gold ores[1―3], the associated volcanic rocks[4], radiogenic isotope[5―8], and the ore-forming environment[8]. Most researchers inferr…     

The characteristics,origins, and geodynamic settings of supergiant gold metallogenic provinces

There are six distinct classes of gold deposits, each represented by metallogenic provinces, having 100's to >1000 tonne gold production. The deposit classes are: (1) orogenic gold; (2) Carlin and Carlin-like gold deposits; (3) epithermal gold-silver deposits; (4) copper-gold porphyry deposits; (5) iron-oxide copper-gold deposits; and (6) gold-rich volcanic hosted massive sulfide (VMS) to sedimentary exhalative (SEDEX) deposits. This classification is based on ore and alteration mineral assemblages; ore and alteration metal budgets; ore fluid pressure(s) and compositions; crustal depth or depth ranges of formation; relationship to structures and/or magmatic intrusions at a variety of scales; and relationship to the P-T-t evolution of the host terrane. These classes reflect distinct geodynamic settings. Orogenic gold deposits are generated at mid-crustal (4–16 km) levels proximal to terrane boundaries, in transpressional subduction-accretion complexes of Cordilleran style orogenic belts; other orogenic gold provinces form inboard, by delamination of mantle lithosphere, or plume impingement. Carlin and Carlin-like gold deposits develop at shallow crustal levels (<4 km) in extensional convergent margin continental arcs or back arcs; some provinces may involve asthenosphere plume impingement on the base of the lithosphere. Epithermal gold and copper-gold porphyry deposits are sited at shallow crustal levels in continental margin or intraoceanic arcs. Iron oxide copper-gold deposits form at mid to shallow crustal levels; they are associated with extensional intracratonic anorogenic magmatism. Proterozoic examples are sited at the transition from thick refractory Archean mantle lithosphere to thinner Proterozoic mantle lithosphere. Gold-rich VMS deposits are hydrothermal accumulations on or near the seafloor in continental or intraoceanic back arcs.

The compressional tectonics of orogenic gold deposits is generated by terrane accretion; high heat flow stems from crustal thickening, delamination of overthickened mantle lithosphere inducing advection of hot asthenosphere, or asthenosphere plume impingement. Ore fluids advect at lithostatic pressures. The extensional settings of Carlin, epithermal, and copper-gold porphyry deposits result from slab rollback driven by negative buoyancy of the subducting plate, and associated induced convection in asthenosphere below the over-riding lithospheric plate. Extension thins the lithosphere, advecting asthenosphere heat, promotes advection of mantle lithosphere and crustal magmas to shallow crustal levels, and enhances hydraulic conductivity. Siting of some copper-gold porphyry deposits is controlled by arc parallel or orthogonal structures that in turn reflect deflections or windows in the slab. Ore fluids in Carlin and epithermal deposits were at near hydrostatic pressures, with unconstrained magmatic fluid input, whereas ore fluids generating porphyry copper-gold deposits were initially magmatic and lithostatic, evolving to hydrostatic pressures. Fertilization of previously depleted sub-arc mantle lithosphere by fluids or melts from the subducting plate, or incompatible element enriched asthenosphere plumes, is likely a factor in generation of these gold deposits. Iron oxide copper-gold deposits involve prior fertilization of Archean mantle lithosphere by incompatible element enriched asthenospheric plume liquids, and subsequent intracontinental anorogenic magmatism driven by decompressional extension from far-field plate forces. Halogen rich mantle lithosphere and crustal magmas likely are the causative intrusions for the deposits, with a deep crustal proximal to shallow crustal distal association. Gold-rich VMS deposits develop in extensional geodynamic settings, where thinned lithosphere extension drives high heat flow and enhanced hydraulic conductivity, as for epithermal deposits. Ore fluids induced hydrostatic convection of modified seawater, with unconstrained magmatic input. Some gold-rich VMS deposits with an epithermal metal budget may be submarine counterparts of terrestrial epithermal gold deposits. Real time analogs for all of these gold deposit classes are known in the geodynamic settings described, excepting iron oxide copper-gold deposits.

     

Geochemistry of ore-forming fluids and geological significance

The Kuoerzhenkuola gold field (including the Kuoerzhenkuola and the Buerkesidai gold deposits) is the most important one in the Sawuer gold belt, northern Xinjiang, China. Isotopic studies including D, O, He, C, S, Pb and Sr reveal that the ore-forming fluids of the Kuoerzhenkuola and the Buerkesidai deposits shared the same source: the water of ore fluids was magmatic water and minor meteoric water; the mineralizers and ore materials derived mainly from mantle beneath the island arc, and partially from crust. The ore-forming fluids of two deposits are a mixture of mantle-derived fluids incorporated by crust-derived fluid, and meteoric water. Based on these results, combined with the consideration of the tectonic setting and geological features, we suggest that the two gold deposits in the Kuoerzhenkuola gold field, Sawur gold belt share the same genesis, and are volcanogenic hydrothermal gold deposits occurring in the same caldera.     

Geo-tectonic conditions of the formation of Proterozoic large and superlarge ore deposits along northwestern margin of North China Plate

Four large and superlarge copper-multimetal ore deposits hosted in the Mid-Proterozoic Zhartaishan Group along northwestern margin of North China Plate are stratabound hydrothermal sedimentary deposits, and these deposits formed in mid-late stage of the Mid-Proterozoic Langshan-Zhartaishan rifting system. Four necessary conditions are proposed for the formation of these large and superlarge ore deposits: (i) favorable geological background and tectonic environment; (ii) abundant sources of metallogenic material; (iii) favorable sedimentary lithofacies and paleogeographic conditions; (iv) sudden change events during metallogenic processes.     

Metallogenic model of the copper deposit

The copper deposits in the mid-lower reaches of the Changjiang River consist mainly of porphyry, skarn and massive sulphide deposits. According to the geological background, the types of ore deposits and the mineralization, the metallogenic model of the copper deposits is discussed. It is pointed out that the ore-forming hydrothermal fluids came mainly from magmatic water and were related to the intermediate-acid intrusions, and that the formation of skarn arid massive sulphide deposits coincided with the mineralization of porphyry deposits. Project supported by Doctorate Foundation of the State Education Commission of China.     

Bio-reef-chert suite and superlarge ore deposits

The bio-reef-chert suite is an important ore-bearing rock assemblage and one of the metallogenic rock suites of superlarge ore deposits. It is formed as a fixed and ordered suite in space and time, and composed of different rocks formed by different geological processes. It is the product of basin evolution at special stage in a special geological setting. It is also the comprehensive product of normal sedimentary process, biological process in basin, hydrothermal sedimentary process under basin base and magmatic process in the deep lithosphere.     

广东潮安四望坪铜矿区断裂控矿特征

广东潮安四望坪铜矿以岩浆期后热液交代充填成矿为特征,在其三位一体（岩浆岩、断裂/层间滑动破碎带、围岩）的控矿组合中,以流纹斑岩、晶屑凝灰岩的层间滑动破碎带为最佳。本文从矿区资料的综合研究入手,深入剖析了岩浆岩、断裂、围岩圈闭条件与矿体规模、富集程度的关系;旨在通过对矿区地质环境与矿床成因的深入分析,建立火山期后热液矿床的断裂控矿模式,为粤东火山岩地区该类矿床的发现提供理论上的启示。     

Analysis of tectonic settings of global superlarge porphyry copper deposits

About three quarters of superlarge porphyry copper deposits throughout the world occur along the eastern Pacific basin rim, most of which were formed during the Mesozoic-Cenozoic. Porphyry copper deposits often occur in the upper parts of a subduction zone and in a within-plate orogenic belt. Some porphyry copper deposits are inconsistent with plate subduction with respect to their formation time, and most of them in the world are associated with tensional environment. Metallogenic porphyries originated from the mantle, and the involvement of the lower-crust or oceanic crust materials have played an important role. Based on the geochemical characteristics and tectonic settings of the ore-bearing porphyries in the Gandise and Yulong metallogenic zones, it is proposed that delamination may be the important mechanism of formation of porphyry copper deposits.     

Analysis of tectonic settings of global superlarge porphyry copper deposits

About three quarters of superlarge porphyry copper deposits throughout the world occur along the eastern Pacific basin rim, most of which were formed during the Mesozoic-Cenozoic. Porphyry copper deposits often occur in the upper parts of a subduction zone and in a within-plate orogenic belt. Some porphyry copper deposits are inconsistent with plate subduction with respect to their formation time, and most of them in the world are associated with tensional environment. Metallogenic porphyries originated from the mantle, and the involvement of the lower-crust or oceanic crust materials have played an important role. Based on the geochemical characteristics and tectonic settings of the ore-bearing porphyries in the Gandise and Yulong metallogenic zones, it is proposed that delamination may be the important mechanism of formation of porphyry copper deposits.     

The distribution,characteristics and fluid sources of lode gold deposits: An overview

Lode gold deposits are among the most economically important types of gold deposits in the world. Globally, they formed mainly in three time intervals, 2.8 to 2.5 Ga, 2.1 to 1.8 Ga, and 700 Ma to the present. Sources of ore-forming fluids and other components are of critical importance in a better understanding of the genesis and the geodynamic controls of these deposits. Although ore-forming fluids were mostly derived from devolatization of sedimentary and/or volcanic sequences during greenschist to amphibolite facies metamorphism associated with orogenic deformation, magmatic hydrothermal fluids have been increasingly shown to be important in many gold deposits in various regions. In this review paper, we summarize the major features of lode gold deposits, possible sources of ore-forming fluids, and mechanisms of gold mineralization. While we acknowledge the critical role of metamorphically derived fluids in the genesis of such deposits worldwide, we emphasize that mantle-or basaltic magma-derived fluids may have been much more important than commonly thought. We use the Liaodong peninsula of the North China Craton as an example to demonstrate the significance of mantle-derived fluids. Integrating earlier studies and new data, we show that some of the late Mesozoic lode gold deposits in the North China Craton may have formed from magmatic hydrothermal fluids due to the extension and partial melting of the hydrated, metasomatized subcontinental lithosphere mantle, as best exemplified by the Wulong gold deposit.     

初论华北东部中生代金成矿的地球动力学背景——以胶东金矿为例

山东金矿研究的最新成果表明 ,胶东众多金矿床 (无论矿化类型、产出空间、地质背景的不同)的成矿时代主要集中在 1 1 5± 1 5Ma(早白垩世 )前后这一狭短的时段内 ,暗示它们都受某一次统一的重大地质事件的制约 .金矿石中碳酸盐矿物的碳氧同位素组成显示成矿流体中的CO2 很可能来自深部 (岩石圈地幔甚或更深 ) .1 1 5± 1 5Ma(早白垩世 )前后正是华北东部中生代动力学体制转折的关键时段 ,此时古太平洋板块向欧亚大陆斜向快速俯冲、华北东部岩石圈剧烈减薄、郯庐断裂发生强烈左行走滑、区域构造应力场转变为强烈引张、火山 -岩浆活动也最为强烈、尤其是深源(幔源 )岩浆活动最为强烈 .同时 ,这也与部分学者提出的超级地幔柱的高潮时段 (1 2 5～ 1 0 0Ma)相吻合 ,暗示可能有深部物质 (不仅是上地幔物质 ,还可能包括下地幔物质 )和热能的大规模强烈上涌 .因此 ,胶东金矿 (以及华北东部的许多其它金矿床 )的形成有可能是 1 1 5± 1 5Ma前后华北东部动力学体制转折过程中一次大规模的深部物质和深部能量上涌的结果     

Differentation of magmatic emanation

Chemical properties of magmatic emanation can be estimated roughly by i) volatiles from rocks by heating at various temperatures, ii) volcanic emanations, iii) residual magmatic emanations, iv) calculation from chemical equilibrium between volatile matters and magmas. Magmatic emanation is assumed to consist all of the volatile matters in magmas such asH ₂ O, HCl, HF, SO ₂ H ₂ S, H ₂,CO 2,N ₂ and others (halides, etc.) at about 1200°C, although various kinds of magmatic emanations can be formed at different conditions. Magmatic emanation separated from magmas will change their chemical properties by many factors such as changes of temperature and pressure (displacement of chemical equilibrium), and reactions with other substances and it will differentiate into volcanic gases, volcanic waters, volcanic sublimates, and hydrothermal deposits (hot spring deposits). At temperatures above the critical point of water, separation of solid phase (sublimates), liquid phase, and displacement of chemical equilibrium may take place, and gaseous phase will gradually change their chemical properties as will be seen at many fumaroles. Chloride, hydrogen, andSO ₂ contents will gradually decrease along with lowering temperature. Once aqueous liquid phase appears below the critical point of water, all the soluble materials may dissolve into this hydrothermal solution. Consequently, the gaseous phase at this stage must have usually a little hydrogen chloride as is observed at many fumaroles. Aqueous solutions must be of acidic nature by dissolution of acid forming components, and by hydrolysis (Chloride type). When a self-reduction-oxidation reaction of sulfurous acid takes place, an aqueous solution of sulfate type will be formed. At this stage, solid phases consist of the remained sublimates which are difficultly soluble in aqueous solution, and deposits formed by reaction in the hydrothermal solutions. The gaseous phases below the boiling point of water, have usually a little water, and consist mainly ofCO ₂ type,H ₂ S type,N ₂ type, and mixed type owing to elimination or addition of components by reactions with waters or wall rocks according to their geological conditions. Aqueous solutions which was of acidic nature must be changed into alkaline solutions by reaction with wall rocks for a long time. When the oxidation of sulfur compounds takes place, an aqueous solution of sulfate type will be formed. Hydrogen sulfide type of water will be formed by reaction of sulfides with acid waters or absorption of hydrogen sulfide. Carbonate type of water will be formed whenCO ₂ is absorbed. Solid phases at this stage consist usually of hydrothermal deposits except for that at solfatara or mofette. The course of differentiation of magmatic emanation could take place in more complicated ways than that of magmatic differentiation.     

冲绳海槽南段与中、北段构造活动性对比的热模拟研究

受新生代太平洋板块弧后扩张剧烈活动的地缘特性影响,冲绳海槽构造特征复杂,南、中、北段在热液活动、断裂性质、火成岩特性、扩张时代等方面存在显著不同,因此认识该区各段构造活动性对查清其复杂地质特征具有重要意义.本文依据前人通过磁异常反演得到的居里面深度资料,利用热模拟的方法,对冲绳海槽各段深、浅构造活动性进行了探讨.模拟结果表明,南段软流层构造活动强度约为中、北段的6倍,而岩石圈浅层构造活动却相对较弱.该结论与前人所得到的地质地球物理资料相符,主要表现为:相对于中、北段,南段在海槽总体演化历程上裂陷较深;海底火成岩岩浆源区较深,结晶分异程度较弱,同化混染程度较强;切穿沉积基底的大型断裂较为发育,而沉积层内部的小型断裂分布相对稀疏;沉积层岩浆侵入活动较弱,海底所呈现出的热液活动区数量较少;现代地震活动较多,震源深度较大.根据模拟结果与实际资料的对比分析我们可以推测:(1)冲绳海槽北段可能还有一些热液区没有被探测到,也可能在历史演化进程中失去活力,或者被第四系沉积物覆盖;(2)南段存在孕育更多热液活动区的潜力.     

Evolution of the Taebaeksan Basin,Korea: II,late Paleozoic sedimentation in a retroarc foreland basin and assembly of the proto‐Korean Peninsula

The Taebaeksan Basin comprises the lower Paleozoic Joseon Supergroup and the upper Paleozoic Pyeongan Supergroup, which are separated by a disconformity representing a 140 myr‐long hiatus. This paper deals mainly with the late Paleozoic paleogeographical and tectonic evolution of the Taebaeksan Basin on the basis of updated stratigraphy, sedimentation, and geochronology of the Pyeongan Supergroup. Late Paleozoic sedimentation in the Taebaeksan Basin recommenced at ~ 320 Ma and formed a thick siliciclastic succession of marginal marine and non‐marine alluvial deposits, the Pyeongan Supergroup. The Pyeongan Supergroup was deposited in a retroarc foreland basin formed by build‐up of a magmatic arc along the northern margin of the Sino‐Korean Craton. The formation of sedimentary deposits ceased at ~ 250 Ma due to the collision of the Sino‐Korean Craton and South China Craton that generated the Triassic Songnim orogeny in Korea. Diverse tectonic models have been proposed for assembly of the proto‐Korean Peninsula, but the indented wedge model is considered to best explain the geological features of the peninsula. The indented wedge model entails northward subduction of the central block of the Korean Peninsula (part of the South China Craton) beneath the northern block of the Korean Peninsula (part of the Sino‐Korean Craton) along the Sulu‐Imjingang Belt.     

S,C, O,H, and Pb isotopic studies for the Shuiyindong Carlin-type gold deposit,Southwest Guizhou,China: constraints for ore genesis

The Shuiyindong gold deposit is one of the most famous and largest Carlin-type gold deposits in China and is located in southwest Guizhou, in the eastern part of the Huijiabao anticline. The Shuiyindong's gold mineralization occurred in bioclastic limestone of the Permian Longtan Formation. Sulfur, carbon, hydrogen, oxygen, and lead isotopic compositions are reported in this paper. The properties and sources of ore-forming fluid have been discussed and a metallogenic model for the Shuiyindong gold deposit has been proposed. The d34 S values of stibnite, realgar, orpiment, pyrite from orebodies, and pyrite from quartz veins are similar to or slightly higher than the d34 S values of mantle sulfur. It is suggested that the sulfur of hydrothermal sulfides was likely of magmatic origin with minor heavy sulfur contributed from the country rocks. The measured d D values and calculated d18OH2 O values of inclusion fluid in quartz plotted within or below a magmatic hydrothermal fluid field far from the meteoric water line. This indicates that the ore-forming fluid for the main-stage gold mineralization could have been derived mainly from a magmatic source and mixed with a small amount of meteoric water. The carbon and oxygen isotopic compositions of calcites in the d18 O vs. d13 C diagram suggest that the CO2 in ore-forming fluid was derived from dissolution of bioclastic limestone and oxidation of sedimentary organic carbon in limestone. However, the d13 C values of ore-related calcites, which contain intergrown realgar and/or orpiment, are similar to those of mantle carbon. Although no igneous intrusive rock has been observed in the vicinity of the gold deposits, the possibility of mantle fluid integrated into the ore-forming fluid cannot be eliminated based on the d13 C values of ore-related calcites. The lead isotopes of sulfides are distributed near the growth curves of upper crust and orogenic belt in the plumbotectonic diagram. Their calculated Dc and Db values plotted within the magmatism field of crust-mantle subduction zone in the Dc- Db diagram. This suggests that the lead of sulfides has an intimate connection with magmatism. Our S, H, O, C, and Pb isotopic studies for the Shuiyindong Carlin-type gold deposit in Guizhou manifest a concordant possibility that the ore-forming fluid was mainly derived from magmatic fluid with minor contribution from the surrounding strata. With the integration of comprehensive geology and isotopic geochemistry, we have proposed a magmatic hydrothermal model for the origin of the Shuiyindong gold deposit.     

A theoretical study of hydrothermal convection and the origin of the ophiolitic sulphide ore deposits of Cyprus

Hydrothermal circulation of seawater has been suggested as a mass transport mechanism for the formation of sulphide ore deposits in the ophiolitic rocks of Cyprus. Since ophiolitic sequences are generally regarded as fragments of oceanic crust and upper mantle, hydrothermal circulation of a form inferred from geological observations on Cyprus may be analogous to that thought to occur in oceanic crust at spreading ridges. The hypothesis that ore deposits were formed in ascending plumes of hot, buoyant fluid is examined by considering thermal convection in a permeable medium. To match the inferred pattern of circulation, finite amplitude convection in a cylindrical geometry is studied using finite difference approximations. These results combined with available geological and geochemical data are applied to understand better the physical controls on mineralisation.A simple model for the formation of the hydrothermal ore deposits of Cyprus is discussed. The model is semi-quantitatively reasonable in terms of vertical fluid flow rate, thermal structure, permeability and basal heat flow, and predicts volumes of maximum mineralisation similar to those observed. Three factors are identified which were important in confining mineralisation to a small volume immediately beneath the sea water/rock boundary: (1) hot fluid was confined to a narrow core zone of a rising plume, (2) the upward fluid flux was greatest in this same core zone, and (3) significant temperature decrease occurred within a thin surface boundary layer.     

Salt-bearing fumarole deposits in the summit crater of Oldoinyo Lengai, Northern Tanzania: interactions between natrocarbonatite lava and meteoric water

Oldoinyo Lengai in the Northern Tanzania rift is the only active nephelinite–carbonatite stratovolcano. We report the discovery of thermonatrite, aphthitalite, halite and sylvite fumarole deposits on recent natrocarbonatite lava flows erupted in the summit crater during the wet season. These salt deposits occur as delicate, concave fringes or tubes that line the cooling cracks in the lava flows and consist of intergrowths of euhedral crystals. The presence of a dark altered zone, depleted in halides and alkalies, adjacent to cooling cracks and observations of steam fumaroles emanating from the fractures suggest that the salts are formed by sublimation from saturated vapours generated by the extrusion of lavas over meteoric water. The crystallisation sequence recorded in the salts suggests that mixing between meteoric steam and magmatic CO₂ and H₂S occurs at high temperatures resulting in the sublimation of carbonates and sulphates. At lower temperatures the vapours are dominated by meteoric steam and sublimate halides. The high solubility of the fumarole salts within meteoric water and their formation only during the wet season implies that these are ephemeral deposits that are unlikely to be preserved in the geological record.     

青岛沧口断裂的地质构造特征与第四纪活动性研究

本文根据青岛市活断层探测与地震危险性评价项目初查阶段第四纪地层分析、遥感影像解译、地球化学探测、地质地貌调查与探槽开挖、浅层地震勘探与钻孔探测、地质年代测定等获得的丰富的第一手资料,对青岛沧口断裂的地质构造特征和第四纪活动性进行了详细分析与综合研究,结果表明:沧口断裂经历多期构造变动,是本区的重要断裂之一,它由多支断层组成,控制了中生代的火山活动、盆地沉积和岩浆侵入以及晚第四纪的盆地沉积、山体隆升和水系发育;第四纪以来,沧口断裂的主要活动发生于中更新世晚期至晚更新世早期,表现出中高角度向南东倾的逆冲活动特点,错断了上更新统底面1—6m,而最新活动时代为晚更新世中期,以走滑活动为主,垂直错距0.2—1.1m。     

江西武夷成矿带铜多金属矿产资源远景评价与展望

华南武夷山地区处于扬子、华夏两大构造单元交接叠加地段,构造变形复杂,中生代岩浆活动强烈,具有十分优越的成矿条件,矿产资源潜力巨大。本文以正在武夷山成矿带开展的矿产远景调查工作和资源评价工作所取得的阶段性成果为基础,分析了武夷山成矿带的成矿地质背景、主要矿床类型及近几年的找矿勘查成果,并对武夷成矿带江西省境内铜多金属矿产资源潜力进行了初步评价,划分了十七个找矿远景区。