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1.
可尔因地区是松潘?甘孜成矿带的大型稀有金属矿集区之一,围绕可尔因岩体分布了大量花岗伟晶岩脉,如何在数百平方千米伟晶岩田中定位稀有金属矿脉一直是该区伟晶岩型锂稀有金属矿找矿难点之一。通过对可尔因岩体二云母花岗岩、伟晶相微斜钠长花岗岩、不同类型伟晶岩及典型矿床开展系统的岩石地球化学分析,总结了可尔因地区伟晶岩地球化学元素空间分布和变化规律,提出了寻找锂矿的特征元素指标、指示指标和品位指标等地球化学指标。特征元素指标包括Li、B、Sn、Rb、Be、Nb、Ta等元素;平面指示指标包括Cs、Tl、F、Zr、Y、ΣREE等元素及TiO2/Ta、Zr/Hf、Ta/Zr、Nb/Ta、K/Na等值;垂向指示指标包括B、U、Zr、Be、Sn、Rb、Sr、Ba、Tl、In等元素。通过特征元素指标及指示指标的值和变化规律,可辅助定位稀有金属矿化伟晶岩位置,指示矿体深部延伸情况。品位指标主要包括铝饱和指数(A/CNK、A/NK)、里特曼指数(σ)、K+Na和K/Na值等,Li品位与铝饱和度呈正相关、与碱度呈负相关,品位指标的变化趋势指示了矿体中锂的富集部位。   相似文献   

2.
苟树林  于津海  蔡元峰  蒋威  毛志奇 《地质学报》2023,97(11):3696-3714
内容提要:江南造山带是我国重要的稀有金属成矿带,已发现多处与锂相关的花岗伟晶岩型稀有金属矿床。锂等稀有金属元素在源区基底岩石中的富集是花岗伟晶岩型锂稀有金属矿床成矿的物质基础,但是江南造山带基底岩石中锂的分布及其富集机制仍不清楚。本文详细调查研究了江南造山带东段新元古代冷家溪群、双桥山群、溪口岩群和板溪群变质沉积岩和星子杂岩。这些基底变质岩的岩石类型包括变质砂岩、泥质板岩、千枚岩和云母片岩以及少量片麻岩。地球化学分析结果显示,冷家溪群、双桥山群和溪口岩群变质沉积岩具有相似的成分,变质砂岩和云母片岩-片麻岩整体上比泥质板岩和千枚岩具有较高的Si O2含量,较低的Ti O2、Al2O3、K2O、Mg O和TFe2O3含量。泥质板岩和千枚岩含有更高的稀有金属元素含量,其中锂含量达到61.8×10-6,而变质砂岩的锂丰度为44.9×10-6。板溪群具有最低的稀有金属元素含量(Li=30.8×10  相似文献   

3.
三十里岩体位于西昆仑造山带东段甜水海地体北缘,本文对三十里岩体黑云母二长花岗岩及其暗色包体进行了锆石U-Pb年代学和全岩地球化学、同位素地球化学研究。结果表明:黑云母二长花岗岩SiO2含量为67.84%~68.95%, Al2O3含量为14.77%~15.28%,铝饱和指数A/CNK为1.02~1.06,属于弱过铝质岩石;强烈富集LREE,具有轻微Eu负异常;富集Rb、Th、K、La、Ce等大离子亲石元素,亏损Nb、Ta、Ti和P等高场强元素。锆石U-Pb测年结果显示,黑云母二长花岗岩及其暗色包体均形成于约216Ma,二者有相似的Sr-Nd同位素特征及二阶段模式年龄。暗色包体为岩浆混合作用的产物。Sr-Nd同位素数据表明,黑云母二长花岗岩可能由前寒武纪变质火成岩和变质沉积岩的混合物部分熔融形成。结合区域地质和本次研究成果,三十里岩体应属于碰撞后阶段的产物。  相似文献   

4.
北喜马拉雅花岗岩位于特提斯喜马拉雅的中部,对其研究不仅有助于认识和理解碰撞造山过程中地壳物质的熔融行为和机制, 而且对探讨部分熔融作用与相关构造的关系也具有重要意义.通过对北喜马拉雅佩枯花岗岩开展系统的LA-MC-ICP-MS锆石U-Pb年代学和地球化学研究,结果表明佩枯花岗岩的结晶时间较长,从23.9 Ma持续到16.5 Ma,并记录了22.3±0.6 Ma和17.3±0.3 Ma两期深熔作用.全岩地球化学分析结果显示,佩枯花岗岩具有高含量的SiO2(71.87%~75.56%)、Al2O3(13.57%~15.49%)和K2O(3.34%~4.59 %),以及高的K2O/Na2O比值(1.02~1.39) 和A/CNK值(1.21~1.23),属于高钾钙碱性过铝质花岗岩.岩石强烈富集大离子亲石元素Rb和放射性生热元素Th、U,亏损Ba、Nb、Sr、Zr等元素;轻重稀土元素分馏较强((La/Yb)N=10.76~16.60),几乎无或弱的负Eu异常(δEu=0.76~0.97).样品的(87Sr/86Sr)i值和εNd(t)值变化范围分别为0.736 184~0.741 258和-14.6~-14.3,与大喜马拉雅变质沉积岩的Sr-Nd同位素组成一致,表明其源岩可能为大喜马拉雅变质沉积岩.样品(87Sr/86Sr)i值较低而Sr浓度较高,且随着Ba浓度的增加,Rb/Sr比值基本不变,与水致白云母部分熔融的特征和趋势一致,表明佩枯花岗岩是水致白云母部分熔融的产物,部分熔融作用可能与藏南拆离系的活动密切相关.   相似文献   

5.
粤东北基底变质岩的组成和形成时代   总被引:23,自引:0,他引:23  
基底变质岩的成分和形成时代对揭示地壳演化至关重要.利用锆石U-Pb-Hf研究和全岩成分分析, 发现粤东北及邻区的许多基底变质岩是晚新元古代形成的沉积岩, 它们具有高的SiO2、Rb、Zr、Y和过渡金属元素含量以及相对低的Al2O3、CaO、Na2O、Sr、Nb含量.它们沉积于活动大陆边缘环境.盆地的形成与Rodinia超大陆裂解时的张性背景相关.粤东北龙川地区新元古代沉积岩主要由新太古代和中元古代碎屑物质组成, 并含少量中太古代和新元古代物质, 明显不同于闽西南和粤北地区新元占代沉积岩.粤东北这些变质岩没有受到加里东运动的强烈影响, 而是在印支期发生变质-重熔作用.   相似文献   

6.
龙里丰源铝土矿床属黔中铝土矿带龙里早石炭世杜内晚期铝土矿成矿亚带,矿体产于丰源铝矿层(FYB),矿床类型属沉积型铝土矿床。本文通过系统采集钻孔岩心样,进行铝土矿床元素地球化学研究。主量元素结果显示,含铝岩系以Al2O3、SiO2、TFe2O3及LOI为主,Cr2O3、K2O、Na2O、P2O5、SrO、V2O5、ZrO2等含量相对较低;微量元素Sr、Zr、Cr、V、Li、B、Ga、Ba等含量相对较高,Be、Pb、Sc、Hf、Nb、Rb、Cs、Ta、Th、U等含量相对较低;CIA指数=69.00~99.74,平均97.58,总体介于80~100,说明丰源铝矿层形成时,化学风化强度强烈,古气候条件显示为炎热、潮湿的气候环境。元素B含量55×10-6~143×10  相似文献   

7.
北山地区是中亚造山带的组成部分,记录了重要的新元古代构造演化信息。对甘肃北山咸水沟原1:25万区域地质调查所划的泥盆纪侵入岩开展研究,新解体出新元古代二长花岗岩体,对该二长花岗岩进行LA-ICP-MS锆石U-Pb测年,其206Pb/238U加权年龄为(787 ±15)Ma。岩石富SiO2、低TiO2、高Al2O3、富碱,里特曼指数σ和铝饱和指数A/CNK均大于1.05,轻稀土相对于重稀土富集,(La/Yb)N值为15.20~23.28,表明轻重稀土高度分异,(La/Sm)N比值为3.14~4.22,指示轻稀土分馏较大,具明显的负Eu异常,富集Rb、Th、La,亏损Nb、P、Ti、Sr,表现出S型花岗岩特征。北山地区的新元古代二长花岗岩形成于大陆碰撞构造环境,位于Rodinia超大陆边缘,该期岩浆事件反映了新元古代北山地区发生了板块碰撞。  相似文献   

8.
骑田岭岩体位于湖南省郴州市,为一中生代复式岩体。本文运用电感耦合等离子质谱技术(ICP-MS)对穿越骑田岭岩体的大剖面上的花岗岩样品,进行了稀有金属Li、Rb、Sr、Cs、Nb、Ta、Be、Zr、Hf含量分析测试。结果表明:(1)岩体明显富集Li、Rb、Cs、Be、Zr,高于华南燕山期花岗岩平均值,Sr、Nb、Ta则相对亏损;(2)Li、Rb、Cs等稀有金属自西向东逐渐升高,Sr则逐渐降低,Nb、Ta、Hf等除了个别地方出现"特高值"之外,基本保持稳定;(3)相比于同时期的邻区香花岭岩体,骑田岭岩体虽然富集了一定量的稀有金属,但要形成或找到香花岭这样的稀有金属矿床还要注意剥蚀、保存条件。结合地球物理特征和岩体地质特征,认为骑田岭岩体自南东向北西斜向侵位的可能性很大,这可能也是造成骑田岭岩体稀有金属元素分带的原因。  相似文献   

9.
湖南晚侏罗世金鸡岭花岗岩体是南岭地区典型W—Sn成矿岩体之一,内部发育黑云母花岗质伟晶岩团块和文象花岗质条带状伟晶岩脉。金鸡岭花岗岩和黑云花岗伟晶岩中的黑云母具有相似的地球化学特征,均表现出高的FeO、TiO2、Al2O3含量和低的MgO、CaO、Na2O、MnO含量,以及富集成矿元素Nb、Ta、W、Sn,亏损Sr、Ce、Eu等微量元素特征,从花岗岩体到黑云花岗伟晶岩,岩浆的形成温度和氧逸度降低,云母中Al2O3、Li2O*含量升高,TiO2、MgO含量降低,黑云母由铁叶云母演变为黑鳞云母。结合前人资料,金鸡岭花岗岩与黑云花岗伟晶岩均源于元古宙地壳的深熔作用,伟晶岩为花岗岩浆在晚期分异演化的产物,形成于岩浆—热液转化阶段。伟晶岩阶段是稀有金属元素显著富集,乃至进一步成矿的重要阶段。  相似文献   

10.
北喜马拉雅恰芒巴二云母花岗岩的年龄及形成机制   总被引:3,自引:0,他引:3       下载免费PDF全文
恰芒巴二云母花岗岩体位于特提斯喜马拉雅的西部, 岩石发育片麻状构造, 主要矿物组成为石英、钾长石、白云母和黑云母。LA-MC-ICP-MS U-Pb定年显示, 锆石年龄分布范围为35.1~17.3 Ma, 暗示较长时间的深熔作用过程, 其中最年轻的年龄(18.1±0.4 Ma)代表了花岗岩的最终结晶年龄。地球化学分析表明, 岩石具有高的SiO2(73.06%~73.79%)、Al2O3(14.73%~15.06%)和CaO(1.18%~1.24%)含量, 以及高的K2O/Na2O值(1.16~1.25)和A/CNK值(1.16~1.20), 属于高钾钙碱性过铝质花岗岩。岩石强烈富集Rb、Th、U和K, 而亏损Ba、Nb、Sr和Zr, 轻重稀土分馏较强(La/Yb)N=9.98~11.35, 并显示较弱的负Eu异常(δEu=0.70~0.74)。(87Sr/86Sr)i和εNd(t)值分别为0.742 298~0.743 092和-14.1~-14.0, 可与大喜马拉雅结晶杂岩(GHC)中变质沉积岩对比, 推测源岩为GHC变质沉积岩或与之成分相当的岩石。岩石(87Sr/86Sr)i值较低而Sr浓度较高, 随着Ba浓度的增加, Rb/Sr值基本不变, 与水致白云母部分熔融的趋势一致, 推测恰芒巴二云母花岗岩可能是水致白云母部分熔融的产物, 部分熔融作用可能与藏南拆离系的活动密切相关。  相似文献   

11.
东濮凹陷北部沙三中亚段广泛发育盐岩和烃源岩,这两个看似不能共存的物质却在这里互层共生。该时期研究区沉积特征为多盐韵律与多层烃源岩互层共生、连续沉积,单个盐韵律厚度从几米到十几米,烃源岩有机质丰度高、类型好。平面上,两者在湖盆沉积沉降中心共生;垂向上,高有机质丰度、好干酪根类型与高盐度地层具有较好的对应关系。因而成为恢复古气候和古环境的重要研究对象。通过岩石学、古生物学以及Sr/Ba、B/Ga、(V+Ni+Mn)、Fe/Mn、Sr/Cu、Mg/Ca、V/(V+Ni)、稀土元素含量和氯同位素等方法对凹陷北部沙三中亚段的沉积环境进行研究。结果表明,凹陷北部沙三中亚段为深水沉积的还原环境,古盐度较高,达到半咸水-咸水沉积;微量元素和孢粉化石特征表明研究区沙三中亚段为温暖潮湿的环境。  相似文献   

12.
In order to characterise the influence of the heavyrains on the observed landslides during the 1996–1997hydrological cycle, rainfall records for the last 100years are analysed from 104 stations in easternAndalusia. Regarding the amounts of rain recordedbetween October 1996 and March 1997 in the 104stations studied, 31 presented new all-time records;15 presented values that were 80–100% of thepre-1995 record; 49 stations, 80–50%; and 9stations, < 50%. A map has been devised of thesusceptibility of the materials through which thesouth-eastern Andalusian road network crosses,together with an inventory of the damage caused byinstability phenomena on banks and cuttings of theroad network during the winter of 1996–1997. Therelationships between the rainfall during the studyperiod, the damage caused to the road network and thesusceptibility of the materials affected are analysed.The results indicate that there is a clearcorrespondence between the rainfall recorded and thesusceptibility of the materials with the inventorieddamage. It is concluded that the widespread seriousdamage caused in early 1997 to the roads andsurrounding areas in the Alpujarra region and thecoast of the Province of Granada was mainly caused bythe extraordinarily heavy rains. However, considerablyless damage was observed where the susceptibility ofthe terrain is low, thus highlighting the extremeusefulness of terrain-susceptibility maps for riskprevention and territorial planning.  相似文献   

13.
郯庐断裂南段研究进展与断裂性质讨论   总被引:13,自引:3,他引:13  
据1:5万区域地质调查和专题研究资料,就郯庐断裂带是否南延与消失的原因,其与大别—苏鲁造山带交截形成的假位错效应,以及与中新生代沉积盆地形成演化的关系等作了新的阐述。在此基础上,讨论了郯庐断裂带是否为巨大的左行平移断层或转换断层。认为郯庐断裂带可能是在“古郯庐带”的基础上于早侏罗世重新活动、白垩纪强烈活动的地堑型枢纽断裂带。  相似文献   

14.
塘口水电站大坝基础座落在断层和裂隙较发育的龟裂纹灰岩上,岩体完整性差、透水性强,多年运行后,大坝灌浆廊道和排水廊道出现多处集中性漏水,为确保大坝安全和电站正常发电,根据渗漏性质和成因,采用对灌浆廊道补充帷幕灌浆,对排水廊道进行固结+帷幕+回填灌浆。通过灌浆处理后,效果良好,表明灌浆工程有效的将导致坝基渗漏的上下游的裂隙通道封闭,并顺利的经受了随后的汛期洪水考验,大坝安全得到保障。  相似文献   

15.
International unity is becoming ever stronger in this country owing to an increasing similarity in the development of the cultural environment. This comprises the provision of all the country's republics with a sufficient number of schools, theatres, and other institutions and cultural information media in accordance with the needs of the population. An important part is played by the rise in ‘the general educational level, as well as the level of professional qualifications and skills. Among all the Soviet nations and nationalities, this rise being more rapid among formerly backward peoples. Prominent among the factors of internationalization is the progressive development of the nationalities’ cultural resources, while professional culture is being increasingly brought within the reach of the masses.The implementation of the nationalities policy promotes the all-round development of all Soviet nations and nationalities, their drawing together, the upsurge of the individual capabilities of every Soviet citizen.  相似文献   

16.
In reservoir characterization, the covariance is often used to describe the spatial correlation and variation in rock properties or the uncertainty in rock properties. The inverse of the covariance, on the other hand, is seldom discussed in geostatistics. In this paper, I show that the inverse is required for simulation and estimation of Gaussian random fields, and that it can be identified with the differential operator in regularized inverse theory. Unfortunately, because the covariance matrix for parameters in reservoir models can be extremely large, calculation of the inverse can be a problem. In this paper, I discuss four methods of calculating the inverse of the covariance, two of which are analytical, and two of which are purely numerical. By taking advantage of the assumed stationarity of the covariance, none of the methods require inversion of the full covariance matrix.  相似文献   

17.
某高速公路下伏煤矿采空区稳定性分析   总被引:10,自引:0,他引:10  
在论述某高速公路下伏砦脖煤矿采空区地质、采矿和工程地质特征的基础上, 进行了稳定性数值模拟分析, 定性与定量地分析与评价了该煤矿采空区的地表变形特征及稳定性。研究结果表明: 该煤矿采空区的变形尚未完成, 对拟建的高速公路将产生很大的危害, 必须采取相应的工程治理措施。   相似文献   

18.
The Global Stratotype Section and Point (GSSP) for the base of the Silurian System was defined in 1985. Since that time, a number of researchers have suggested that this section has serious deficiencies for use as a GSSP. As a result, in 2000, the Subcommission on Silurian Stratigraphy (SSS) proposed undertaking a formal restu@ of this GSSP, which was subsequently approved by the International Commission of Stratigraphy (ICS). The result of this restudy was the formal proposal that the current GSSP, at 1.6 m above the base of the Birkhill Shale, at Dob's Linn, Scotland, should be maintained as the same locality and stratigraphic level, but the bios- tratigraphical definition of the boundary should be revised. The previously defined, basal Silurian grapto- lite zone, the Parakidograptus acuminatus Zone, should be subdivided into a lower Akidograptus ascensus Zone and a higher E acuminatus Zone. The base of the A. ascensus Zone, marked by the first appearance of A. ascensus, should be regarded as the biostratigraphic mark for the base of the Silurian. This proposal has now been formally approved by the SSS and ICS, and ratified by International Union of Geological Sciences. This is the first GSSP to undergo formal restudy and redefini- tion, and the proposal also included a recommended procedure for restudy of GSSPs.  相似文献   

19.
It is known from observations that the center of mass of the Moon does not coincide with the geometric center of its figure, and the line connecting these two centers is not aligned with the direction toward the center of the Earth, instead deviating toward the Southeast. This stationary deviation of the axis of the inertia ellipsoid of the Moon to the South of the direction toward the Earth is analyzed. A system of five linear differential equations describing the physical libration of the Moon in latitude is considered, and these equations are derived using a new vector method taking into account perturbations from the Earth and partly from the Sun. The characteristic equation of this system is obtained, and all five oscillation frequencies are found. Special attention is paid to the fifth (zero) frequency, for which the solution of the latitude libration equations are stationary and represents a previously unknown additional motion of the rotational axis of theMoon in a cone with a small opening angle. In contrast to the astronomical precession of the Earth, the rotation of the angular-velocity vector is in the positive direction (counter-clockwise), with the period T 3 = 27.32 days. On this basis, this phenomenon has been named “quasi-precession.” This quasi-precession leads to a stationary inclination of the major axis of the inertia ellipsoid of theMoon to the South (for an observer on Earth), making it possible to explain one component of the observed deviation of the center of mass of the Moon from the direction toward the Earth. The opening angle of the quasiprecession cone is approximately 0.834″.  相似文献   

20.
Important tendencies in development of the world mineral-resources sector at the beginning of the 21st century were an increase in production and consumption of mineral materials differentiated by types of metals and nonmetallic mineral raw materials, by countries and regions, as well as the concentration of the production of mineral raw materials in a small number of countries, and a reduction in industrial reserves of minerals in the world economy, even at the current stage of their extraction. These tendencies should be taken into account in working out a strategy for development of the Russian mineral raw-material base.  相似文献   

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