Absolute spectrophotometry of Comet kohoutek 1973f during post-perihelion passage

Absolute spectrophotometry of the coma of Comet Kohoutek 1973f during post-perihelion period has been presented for seven nights in January 1984. Moderately wide range of heliocentric distance (0.436–0.799 AU) covered during observations allowed us to study the flux variation of emission bands with heliocentric distance. The emission features of CN, CH, C₂, C₃, and NaI have been identified in this comet. The abundances of CN and C₂ have been estimated and the production rates of CN, C₂ and C₃ have been derived. Production rates of CN and C₂ seem to vary as r ^–0.33 and r ^–3.50 respectively. The continuum of the comet became more and more redder as the heliocentric distance of the comet increased and phase angle decreased.     

Some bianchi type II universes with special free-gravitational fields

The paper considers a homogeneous Bianchi type II universe. Under each of the conditionsC _hijk C ^hijk =0 and^* C _hijk C ^hijk =0 different types of models have been studied and their physical and kinematical properties have been discussed.     

Spectroscopy of comet P/Schaumasse

Column density profiles for CN, C₃, C₂ and NH have been determined from a long-slit CCD spectrum of periodic comet P/Schaumasse (1992x). Comparisons of these profiles with Haser models indicate that the ratios of the CN, C₃ and C₂ production rates are typical for a short-period comet. Although the scale lengths for NH and its parent species are uncertain, the results indicate that the production rate for NH is much greater than for either C₂ or CN.     

Infrared polar brightening on Jupiter: III. Spectrometry from the Voyager 1 IRIS experiment

Spectra from the Voyager 1 IRIS experiment confirm the existence of enhanced infrared emission near Jupiter's north magnetic pole in March 1979. The spectral characteristics of the enhanced emission are consistent with a Planck source function. A temperature-pressure profile is derived for the region near the north magnetic pole, from which quantitative abundance estimates of minor species are made. Some species previously detected on Jupiter, including CH₃D, C₂H₂ and C₂H₆, have been observed again near the pole. Newly discovered species, not previously observed on Jupiter, include C₂H₄, C₃H₄, and C₆H₆. All of these species except CH₃D appear to have enhanced abundances at the north polar region with respect to midlatitudes. Upper limits are determined for C₄H₂ and C₃H₈. The quantitative results are compared with model calculations based on ultraviolet results from the IUE satellite. The plausibility of the C₆H₆ identification in discussed in terms of the literature on C₂H₂ polymerization. The relation of C₆H₆ to cuprene is also discussed.     

Spectrophotometry of P/Halley (1982i)

Spectral scans of the head of periodic Comet Halley (1982i) have been presented in the optical region (3200–7000 Å) for six nights. Emission features due to NH, CN, CH, C₃, C₂ and NH₂ molecules have been identified. It is found that the comet exhibits night-to-night variation of emission bands. The abundances and production rates of CN and C₂ species have been derived.     

An experimental study of the reaction kinetics of C2(XΣg) with hydrocarbons (CH4, C2H2, C2H4, C2H6 and C3H8) over the temperature range 24-300 K: Implications for the atmospheres of Titan and the Giant Planets

The reactivity of C₂(X¹Σ⁺_g) with simple saturated (CH₄, C₂H₆ and C₃H₈) and unsaturated (C₂H₂ and C₂H₄) hydrocarbons has been studied in the gas phase over the temperature range 24-300 K using the CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme or Reaction Kinetics in a Uniform Supersonic Flow) technique. All reactions have been found to be very rapid in this temperature range and the rate coefficients are typically ?10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ with the exception of methane for which the rate coefficient is one order of magnitude lower: ∼10⁻¹¹ cm³ molecule⁻¹ s⁻¹. These results have been analyzed in terms of potential destruction sources of C₂(X¹Σ⁺_g) in the atmospheres of Titan and the Giant Planets. It appears that the rate coefficient of the reaction ¹C₂ + CH₄ should be updated with our new data and that reactions with C₂H₂, C₂H₄ and C₂H₆ should also be included in the existing photochemical models.     

The Phobos gravitational field modeled on the basis of its topography

The parameters of the best-fitting ellipsoid have been derived using the latest spherical harmonics of the Phobos topography (Duxbury, 1989) by solution of non-linear overdetermined inverse problem. The lengths of the equatorial axes of the ellipsoid have been determined (a = 12.9 km, b = 11.4 km). They are nearly the same as established by Duxbury (ibid.) on the basis of the linearized relationship between the squared lengths of ellipsoidal axes and the topography coefficients C ₂₀ and C _22. The length of the polar axis (c = 9.1 km) differs of about 20% from Duxbury's value. Supposing mass homogeneity of Phobos, the Stokes parameters of the external gravitational field have been derived up to those of the sixth degree and order. The large irregularities in the Phobos figure cause the values of the Duxbury's potential coefficients be fairly inaccurate except the harmonics C ₂₀, C ₃₂, S ₄₃ and S ₅₁, i.e. linearized relationship between gravity and topography cannot be applied for Phobos. Finally, positions of the centre of figure and the directions of the principal axes of inertia have been established.     

Spectrophotometric study of comet Bradfield (1987s)

Spectrophotometric observations of head of comet Bradfield (1987s) during three nights in 1987 are presented. An estimate of the CN, C ₂, and C ₃ column densities and production rates have been made.     

Narrowband photometry of comet Okazaki-Levy-Rudenko 1989r

The results of the photoelectric photometry with the narrowband CN, C₃, C₂ and Blue Continuum (BC) IHW interference filters are presented. Observations were carried out with a set of diaphragms of different effective radii. On the base of the Haser model the production rates of the radicals have been obtained. The CN and C₂ molecules scale lengths (3.4 × 10⁵ km and 8.5 × 10⁴ km respectively for 1.0 AU heliocentric distance) have been also derived. The dust continuum spectrum is negligibly low in comparison with the molecular one, which stay in agreement with the results of other observations of comet Okazaki-Levy-Rudenko.     

Photopolarimetric studies of comet Austin

Photopolarimetric observations of comet Austin with the IAU/IHW filter system were obtained on the 2.34 m Vainu Bappu Telescope (VBT) of the Indian Institute of Astrophysics, at Kavalur, India, during pre-perihelion phase on February 20,1990 and on the 1.2 m telescope of the Physical Research Laboratory at Gurusikhar, Mount Abu during postperihelion phase on May 2 and 4, 1990. The comet appeared bluer than a solar analog during post-perihelion phase on May 2 and 4. The percent polarization shows a sharp increase towards the red on May 2 and 4. The dominant sizes of the dust particles appear to lie in a narrow range of 0.1 to 0.5 Μm. Regarding the molecular band emission, CN and C₂ bands are quite strong; C₃ emission was also found to be strong though the observations on May 2 and 4 show significant variation as compared to C₂ emission. Molecular band polarization for CN, C₃, C₂ and H₂ O+ have been calculated. It has been found that emission polarization in CN, C₂ and C₃ is between 1–7% (phase angle between 107.4–109 degrees). For CN and C₂ the polarization values are close to the theoretically predicted values, but for C₃ the polarization value falls much below the theoretically predicted value. A similar result was found for comet Halley.     

Scanner observations of comet Bradfield (1987 s)

Spectrophotometric observations of the head of comet Bradfield (1987 s) during three nights in 1987 are presented. An estimate of the CN, C₂ and C₃ column densities and production rates have been made.     

Rapid changes of brightness in P/Halley

Scanner observations of the coma of periodic comet Encke (P/Encke) are presented for four nights in March 1984 during its post-perihelion period. The strong emission features of CN and C₂ molecules have been identified and the abundances of CN and C₂ are estimated. The production rates of these molecules have also been derived from their band luminosities. No trace of sodium emission has been found in this comet.     

Spectrophotometric study of periodic Comet Halley (1982i)

Spectral scans of the head of periodic Comet Halley (1982i) have been presented and analysed in detail in the optical region (3200–7000 Å); for ten nights during pre-perihelion period. Emission features due to NH, CN, CH, C₃, and C₂ molecules have been identified. The behaviour of the variation of different emission lines strength as a function of heliocentric distance has been investigated. It is found that the comet exhibits night-to-night variation of brightness. The abundances and production rates of CN and C₂ species have also been derived.     

Crossed molecular beam study of gas phase reactions relevant to the chemistry of planetary atmospheres: The case of C2+C2H2

The reaction between dicarbon (C₂) and acetylene was recently suggested as a possible competitive reaction in the atmospheres of Titan, Saturn and Uranus by rate constant measurements at very low temperatures [see Canosa, A., Páramo, A., Le Picard, S.D., Sims, I.R., 2007. An experimental study of the reaction kinetics of C₂(X¹Σ_g⁺) with hydrocarbons (CH₄, C₂H₂, C₂H₄, C₂H₆ and C₃H₈) over the temperature range 24-300 K: implications for the atmospheres of Titan and the Giant Planets. Icarus 187, 558-568]. We have investigated the reaction of the two low lying electron states of C₂ and acetylene by the crossed molecular beam (CMB) technique with mass spectrometric detection. C₄H, already identified as a primary product in previous CMB experiments, is confirmed as such, even though the mechanism of formation is inferred to be partly different with respect to the previous study. An experimental setup has been devised to characterize the internal population of C₂ and refine the interpretation of the scattering results. The implications for the modelling of the atmospheres of Giant Planets and Titan, as well as cometary comae and the interstellar medium, are discussed.     

Models of the cometary coma in which abundances are calculated for various heliocentric distances

One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H₂O, OH, O, CN, C₂, C₃, CH, and NH₂. Whole-coma abundances are presented for NH₂, CH, C₂, C₃, CN, OH, CO⁺, H₂O⁺, CH⁺, N₂⁺, and CO₂⁺.     

Nonequilibrium chemical analysis of the coma of comet P/Stephan-Oterma

A computer code to calculate the time-dependent nonequilibrium chemistry taking place within the coma of a comet has been developed. This code incorporates 1249 chemical reactions involving 128 species. Models were fit to data on Comet P/Stephan-Oterma (A. L. Cochran and E. S. Barker, 1985, Icarus62, 72–81). It was shown that (1) HCN is the parent for CN; (2) C₂H₂ is a parent for C₂; (3) pure gas-phase chemistry with known species cannot adequately reproduce the observed C₃ but a single step process can; and (4) at least prior to perihelion, the vaporization rate seems to have been controlled by water vaporization.     

On the roche constants for Main-Sequence binaries

The ratiosC ₁/C ₂ of the constants defining the equipotential surfaces which describe the external forms of the components of a close binary system have been calculated on the basis of evolutionary models. Theoretical systems have been considered allowing for a wide range of input parameters (masses and separation) and taking into account the evolutionary effects on the radii of the stars during their Main-Sequence lifetime. The systems have not undergone any transfer of matter and are representative of detached binaries with Main-Sequence components. The ratios of the constants are confined in limited intervals and, for the highest values of the mass-ratio, they are clustered around the unit.     

Studies of some diatomic molecules in the F- and early G-type dwarf stars

A critical analysis of CH, NH, OH, C₂, and CN molecules/radicals has been made in twenty-four F- and early G-type dwarfs at different effective temperature as well as in new constructed model atmosphere. Molecular indices of bandheads ofA-X system of CH, NH, OH, C₂, and CN have been obtained by using the data available in the literature (thirteen-colour and eight-colour photometry).Besides, some interesting plots of the molecular indices vs _eff, molecular abundances and molecular indices vs dissociation energy, reduced equivalent widths and FCF's vs dissociation energy for respective molecules have also been enumerated. It is found that the molecular indices at bandheads ofA-X system of CH, NH, OH, C₂, and CN are approximately constant (5810–6570 K). It is to be noted that the molecular indices decrease in the order OH, NH, CH, C₂, and CN at a given temperature.The dissociation equilibrium of CH, NH, OH, C₂, and CN is considered at 5810, 6570, and 7160 K phases in model atmosphere. At standard scale of abundance the molecular abundance and molecular index decrease in the order OH, NH, CH, C₂, and CN at any given phase, however, CN abundance and index increase (_eff=0.867-0.767). The amplitude of abundance and index variation decrease in the order NH, OH, CH, C₂, and CN (_eff=0.767-0.704).The reduced equivalent width decrease in the order OH, NH, CH, and C₂ and FCF's decrease in the order CH, OH, NH, CN, and C₂.The confrontation of models and observations of spectra of F- and early G-type dwarfs of parent molecules is of primary importance to investigate the physical conditions within atmospheres. Reliable excitation models are also requisite for interpreting spectroscopic observations of parent molecules and deriving molecular abundances.     

Temperature dependence of HC3N,C6H2, and C4N2 mid-UV absorption coefficients. Application to the interpretation of Titan's atmospheric spectra

Three organic compounds (HC₃N, C₆H₂, and C₄N₂) relevant of Titan's atmosphere have been studied within the framework of the SIPAT (Spectroscopie UV d'Intérêt Prébiologique dans l'Atmosphère de Titan) program. Since this facility is still unable to reach the very low temperatures (170 K) of Titan's high atmosphere, spectra have to be obtained at several absorption-cell temperatures, and the data extrapolated towards lower temperatures. Previously published HC₃N and C₆H₂ absorption coefficient data are reviewed, while new spectroscopic data are presented on C₄N₂. Integrated intensity calculations over the vibrational bands are performed apart from the background continuum. Thus, only the band contrast is considered here. While, the temperature dependence of the hot-band integrated intensity follows a Boltzmann distribution, we have enhanced the fit through an empirical parametrisation to account for the observed temperature dependence of the C₄N₂ and HC₃N absorption coefficients, and to extrapolate those data to the low temperature conditions of Titan's high atmosphere. Finally, we discuss the implications of the results to possible detection by remote sensing observations of these minor compounds in Titan's atmosphere.     

Theoretical investigation of interstellar C–C–O and C–O–C bonding backbone molecules

There are numerous complex organic molecules containing carbon and oxygen atoms which show either C–C–O or C–O–C bonding backbone. This paper examines altogether 51 C–C–O and C–O–C bonding backbone molecules from ten different isomeric groups (C₂H₂O, C₃H₂O, C₂H₄O, C₂H₄O₂, C₃H₄O, C₂H₆O, C₂H₆O₂, C₃H₆O, C₃H₆O₂, C₃H₈O) to summarize the present astronomical status of these molecules. Accurate calculations of enthalpy of formation of these molecules show that the isomers with C–C–O backbone are more stable than the C–O–C backbone. Interestingly, a detailed analysis of relevant astromolecules indicates that most of the observed astromolecules have the C–C–O backbone. As a matter of fact, of all the molecules examined in this study, 80% of the astronomically observed species have the C–C–O backbone while only 20% have the C–O–C backbone. In general, interstellar abundance of a molecule is controlled by some factors such as kinetics, formation and destruction pathways,thermodynamics etc. A proper consideration of these factors could explain the observed abundances of these molecules. All these possible key factors are discussed in this paper.