The source of midlatitude metallic ions at F-region altitudes

A survey of metallic ions detected by the Bennett Ion Mass Spectrometers flown on the Atmosphere Explorer satellites, including both circular and eccentric orbital configurations, shows that patches of these ions of meteoric origin are frequently present during magnetically active periods on the bottomside of the F-layer at middle and high latitudes. In particular the F-region metals statistically tend to appear at night in the vicinity of the main ionospheric trough (in a band of invariant latitudes approx. 10 degrees wide) and on the day side of the polar cap. These distributions were previously associated with the expected dynamics of ions in the F-region above 140 km where meridional neutral wind drag and convection electric fields are the dominant ion transport mechanisms. However, the main meteor deposition layer—the presumed source region of the metals—is located below 100 km where these transport mechanisms do not prevail. It is demonstrated that the Pedersen ion drifts driven by intense electric fields such as those associated with sub-auroral ion drifts (SAID) are sufficient to transport the long-lived metallic ions upward from the main meteor layer to altitudes where the drag of equatorial directed neutral winds and electric field convection can support them against the downward pull of gravity and transport them to other locations. The spatial and temporal distribution of the middle and high latitude F-region metals are consistent with the known characteristics of the electric fields and with the expected F-region ion dynamics.     

Combined mass spectrometric composition measurements of positive and negative ions in the lower ionosphere—I. Positive ions

Recent improvements in rocket-borne mass spectrometer technology have made it possible to measure lower ionospheric ions with greater sensitivity and to extend the measurements to lower heights. The improvements made to the instrument and positive ion results from a flight of this instrument will be reported here. In addition to the previously known ions, such as NO⁺(H₂O)_n and H⁺(H₂O)_n, new ion species were found. The total fractional count rate of these ions was found to be constant with height indicating an upper altitude source. Possible identifications of these ions are proposed along with possible production mechanisms.     

Response of Venus ions to solar wind dynamic pressure

Orbiter ion mass spectrometer measurements, as available in the UADS data files are used to study the response of dayside Venus ions at various altitudes to solar wind dynamic pressure, P _sw. Ion densities below about 200 km are not affected by changes in P _sw. At altitudes above 200 km the ions get abruptly depleted with increase in P _sw, and this abrupt depletion occurs at lower altitudes when P _sw is high. At lower P _sw, the depletion occurs at higher altitudes. The effect is similar for all ions. These results are also compared with the empirical relationship observed by Brace et al. (1980) between the ionopause altitude and P _sw from electron density measurements on orbiter electron temperature probe.     

Measurements of low energy auroral ions

This paper summarizes ion meaurements in the energy range 0.1–30keV observed during the campaigns “Substorm Phenomena” and “Porcupine”. For a clear survey of the physical processes during extraordinary events, sometimes ion meaurements of higher energies are also taken into account. Generally, the pitch angle distributions were isotropic during all flights except some remarkable events. In general the ion and electron flux intensities correlated, but sometimes revealed a spectral anti-correlation.

Acceleration of the ions by an electrostatic field aligned parallel to the magnetic field could be identified accompanied by intense electron precipitation. On the other hand deceleration of the ions was observed in other field-aligned current sheets which are indicated by the electron and magnetic field measurements. Temporal successive monoenergetic ion variations pointed to energy dispersion and to the location of the source region at 9 R_E. Furthermore, ion fluxes higher than those of the electrons were measured at pitch angles parallel to the magnetic field. Each of the examples was observed during different flights. The integral down-going number and energy flux of the ions contributed to the total particle or energy influx between 65% and less than 7% and did not clearly characterize the geophysical launch conditions or auroral activities.     

Mass spectrometric measurements of fractional ion abundances in the stratosphere—Positive ions

Measured fractional abundances for stratospheric positive ions are reported for the first time. The measurements which were obtained from balloon-borne ion mass spectrometer experiments relied on recent simulation studies of electric field induced cluster ion dissociation conducted at our laboratory.The ion abundance data provide strong support for identifications of the observed ions as H⁺(H₂O)_n and Hx⁺x_L(H₂O)_m proposed previously. Moreover, it is found that x most likely cannot be identified as NaOH or MgOH which implies that gaseous metal compounds do not exist in the middle stratosphere in significant abundances.Implications of the present findings for the composition and chemistry of stratospheric ions as well as for stratospheric aerosols are discussed.     

Steady-state observations of geomagnetically trapped energetic heavy ions and their implications for theory

Measurements of energetic heavy ions using the Explorer 45 and ATS-6 satellites are reviewed and the resulting implications for theory are evaluated. The measured ions are basically protons and helium ions in the energy range from 0.1 to 1 MeV/nucleon. The equatorial energetic ion distributions inside L = 4.5 are found to be very stable for extended periods of time. These ions are very closely confined to the equatorial plane and are sharply peaked as a function of L around a value designated as L_max. Beyond L = 5.0 the fluxes of these ions are more variable with order of magnitude variations being observed at L = 6.6 on the time scales of minutes, hours, or days. The region inside L = 4.5 appears to be well described by radial diffusive transport driven by fluctuations in the geomagnetic field coupled with losses due to charge exchange and Coulomb interactions with ambient hydrogen geocorona and terrestrial plasma environment. From an analysis relating the position in L-value of the maximum intensity, L_max, observed for a given ion species and energy, it is argued that the influence of fluctuations in the convection electric field as discussed by Cornwall (1972) are not effective in radially diffusing in L ions with energies greater than a few hundred kiloelectron volts per nucleon. The source of these ions remains basically undetermined and its determination must await further measurements.     

Observations of outflowing ion beams on auroral field lines at altitudes of many earth radii

The composition, energy and angular characteristics of upward flowing ionospheric ions at altitudes greater than ～ 20,000 km have been studied by means of the PROGNOZ-7 ion composition experiment. Very narrow beams, having widths corresponding to a mirroring altitude of the order a few thousand kilometers or less, may be found up to altitudes exceeding 30,000 km on the nightside. At much higher altitudes and in regions connected to the dayside/flank boundary layer and plasma mantle, the beams are much broader than expected from adiabatic particle motions from an ionospheric source/acceleration region, suggesting that pitch angle scattering or transverse acceleration processes are present there. Considerable mass dispersion effects have also been observed in some upward flowing ionospheric ion beams. The peak energy for the O⁺ ions may differ by several keV compared to that for the H⁺ ions in one and the same ion beam at altitudes above ～ 20,000 km. The O⁺ ions in these beams have gained considerably more energy than H⁺ in the acceleration process. Many examples with a much higher O⁺ than H⁺ content in the beam have been observed. Possible mechanisms giving rise to the observed effects are discussed, one being several kV of potential drop below the neutral H, O-crossover altitude (500–1500 km). At altitudes where the upflowing ionospheric ions are intermixed with magnetosheath ions, mass dispersion effects are also observed. This dispersion often appears to be the result of a velocity filtering effect caused by the dawn-dusk electric field (earthward convection).     

Electrostatic ion-cyclotron waves in a plasma with heavy negative ions

Results of a laboratory study of electrostatic ion-cyclotron (EIC) waves in a plasma containing K⁺ (39 amu) positive ions, electrons and C₇F₁₄⁻ (350 amu) negative ions are presented. Excitation of the fundamental and higher harmonic light and heavy ion EIC modes was observed. The presence of heavy negative ions in the plasma has a significant effect on the excitation of the light ion EIC modes. The results may be relevant to the understanding of plasma wave properties in plasmas containing negative ions, such as those found in the Earth's ionosphere, the solar system, and, in particular, near Saturn's moon Titan, where an abundance of heavy negative ion species has recently been discovered [Coates, et al., 2007. Discovery of heavy negative ions in Titan's ionosphere. Geophys. Res. Lett. 34, L22103].     

Properties of energetic water-group ions in the extended pick-up region surrounding comet Giacobini-Zinner

The properties of energetic (65–95 keV) cometary water-group ions in the extended solar wind pick-up region surrounding comet Giacobini-Zinner are examined using data from the EPAS instrument on the ICE spacecraft. In the outer part of this region, extending from cometocentric distances of several hundred thousand to a few million kilometres (the limit of pick-up ion detectability), it is found that large modulations of the ion flux occur (with J_MAX/J_MIN 10²-10³) which are related to the direction of the magnetic field. It is also found that the ions stream in a direction which is intermediate between the directions of the solar wind flow and the E × B drift, and that ions are present at energies somewhat above the local pick-up energy. These properties indicate that the waves which are excited by the unstable “ring-beam” pick-up ion velocity distributions do result in significant scattering of the ions in this region, both in pitch angle and in energy, but that they have insufficient amplitude to scatter the ions into near isotropy in the solar wind frame. Closer to the comet (but still upstream from the bow shock), the ion flux modulations are considerably reduced in amplitude and the ions respond less to the E × B drift, indicating that the ions are scattered nearer to isotropy in this region. Inbound, this transition takes place relatively abruptly at a distance of 4 × 10⁵ km in association with an increase in the solar wind speed, after which the ion flux increases, and ceases to be modulated by the field direction, while the streaming direction is continuously antisolar and unmodulated by the direction of the E × B drift. Outbound, weak vestiges of the ring-beam ion anisotropy are present in the region immediately upstream from the bow shock (at −1 × 10⁵ km), but these become more marked at distances in excess of t4 × 10⁵ km, increasing gradually with increasing distance from the comet. It is shown that the evolution of the ion properties is qualitatively consistent with expectations based on quasi-linear diffusion of the ions by the magnetosonic waves observed during the encounter.     

Mass spectrometric measurements of fractional ion abundances in the stratosphere—Negative ions

Fractional abundances of stratospheric negative ions are for the first time explicitly reported. The measurements made by balloon-borne ion mass spectrometers also rely on recent studies of electric field induced collisional dissociation of negative cluster ions conducted at our laboratory. These indicate that the negative ion composition measurements around 36 km conducted by our group do not suffer from any significant dissociation. The new composition data support ion identifications NO₃^?(HNO₃)_b and HSO₄^?(H₂SO₄)_c(HNO₃)_d and the underlying ion reactions propo previously. Moreover, it is found that HSO₄^?(H₂SO₄)_g-ions appear to be particularly stable and that H₂SO₄-association is very fast. Implications of the ion composition data for ion processes are discussed.     

First composition measurements of positive ions in the upper troposphere

First mass-spectrometric composition measurements of atmospheric ions between 3250 and 11700 m altitude are reported. They reveal the presence of very massive cluster ions, the majority of which cannot be attributed to a single hydrated ion family like, for example H⁺(H₂O)_n. The observed fraction of very massive ions increases with decreasing altitude. Masses as large as about 540 amu were observed at 8200 m altitude. Implications of the observations for ion and nucleation processes are discussed.     

GEOS-2 measurements of cold ions in the magnetosheath

The Suprathermal Plasma Analysers on GEOS-2 are able to make differential energy measurements of plasma particles down to sub-eV energies because the entire sensor package can be biased relative to the spacecraft. When the package is biased negatively with respect to space potential, low energy positive ions are sucked in and are more easily detected against the background. Large fluxes of ions with temperatures of the order of 1 eV or less were consistently detected at space potential when the spacecraft was in the magnetosheath though not when it was in the nearby magnetosphere. This apparent geophysical correlation, suggesting that the ions were part of the magnetosheath ion population, was contradicted by the fact that the ions showed no signs of the large drift velocity associated with the electric field in the magnetosheath. We conclude, after further investigation, that the observed ions were probably sputtered as neutrals from the spacecraft surface by the impact of solar wind ions and subsequently ionized by sunlight or electron impact. The effect of sputtering by solar wind ions has not been previously observed, although it could have consequences for the long-term stability of spacecraft surfaces.     

Observations of solar wind stream with high abundance of heavy ions and relation with coronal conditions

Long intervals, during which heavy ions were detected in the high energy tail of the energy spectra of solar wind ions, were recorded by the plasma spectrometer SCS onboard the Prognoz-7 satellite. In particular, such a region with unusual features—low velocity, high density, low temperature of protons and, especially, low temperature of α-particles—was observed during 10–13 December 1978. The time dependence of these parameters makes it possible to recognize this event as “noncompressive density enhancement”. In this region heavy ions such as O⁺⁶, O⁺⁷, Si⁺⁷, Si⁺⁸, Si⁺⁹ and a group of iron from Fe⁺⁶ to Fe⁺¹³ were identified by the electrostatic analyzer.The abundance of these ions relative to protons was about ten times higher than had previously been observed. The coronal temperature, estimated from the ratios of the ion fluxes with different ionization states, is higher than that estimated earlier for the oxygen ions.     

Expected heliospheric attributes of Jovian pickup ions from the extended neutral gas disk

The MIMI CHEMS Instrument on the Cassini Orbiter detected Jovian pickup ions almost an AU upstream of Jupiter during the 2001 flyby. The clue to their planetary origin is the presence of singly ionized sulfur ions in quantities exceeding those expected from the interstellar gas entering the heliosphere (Nature 415 (2002) 994). Earlier modeling of the extended Jovian neutral gas disk suggested how the combination of the orbiting, localized Jovian source and interplanetary ionization processes should combine to produce a distinctive reservoir for heliospheric pickup ion production, different from its interstellar gas counterpart. Here the expected characteristics of pickup ions from the Jovian source are considered using a simplified model. The results provide an idea of the signatures in physical and phase space that reflect both the initial velocities and directionalities of the parent neutral population. Long-term measurements can easily test for these attributes given sufficient spatial and ion energy coverage.     

Ion escape from Mars as a function of solar wind conditions: A statistical study

The influence of solar EUV and solar wind conditions on ion escape at Mars is investigated using ion data from the Aspera-3 instrument on Mars Express, combined with solar wind proxy data obtained from the Mars Global Surveyor (MGS) spacecraft. A solar EUV flux proxy based on data from the Earth position, scaled and shifted in time for Mars, is used to study relatively long time scale changes related to solar EUV variability. Data from May 2004 until November 2005 has been used. A clear dependence on the strength of the subsolar magnetic field as inferred from MGS measurements is seen in the ion data. The region of significant heavy ion flows is compressed and the heavy ion flux density is higher for high subsolar magnetic field strength. Because of the difference in outflow area, the difference in estimated total outflow is somewhat less than the difference in average flux density. We confirm previous findings that escaping planetary ions are mainly seen in the hemisphere into which the solar wind electric field is pointed. The effect is more pronounced for the high subsolar magnetic field case.The average ion motion has a consistent bias towards the direction of the solar wind electric field, but the main motion is in the antisunward direction. The antisunward flow velocity increases with tailward distance, reaching above at 2 to 3 martian radii downtail from Mars for O⁺ ions. Different ion species reach approximately the same bulk flow energy. We did not find any clear correlation between the solar EUV flux and the ion escape distribution or rate, probably because the variation of the solar EUV flux over our study interval was too small. The results indicate that the solar wind and its magnetic field directly interacts with the ionosphere of Mars, removing more ions for high subsolar magnetic field strength. The interaction region and the tail heavy ion flow region are not perfectly shielded from the solar wind electric field, which accelerates particles over relatively large tail distances.     

Observations of energetic ions in inverted V events

Simultaneous measurements of keV ions and electrons with the ESRO 1A satellite have shown the following ion characteristics among others. Ions of about 6 keV energy are strongly field-aligned on the flanks of the inverted V events (mainly through the disappearance of the ion flux near 90° pitch angle). Field-aligned electron fluxes are often found in the same regions of the inverted V events where the ions are field-aligned. At the centre of inverted V events isotropization occurs (except in some small events). The 1 keV ion flux at large pitch angles (80°) is generally not reduced very much when the 6 keV, 80° ion flux shows strongly decreased values. The ratio of the 1 to 6 keV ion flux has a maximum near the centre of an inverted V event where the electron spectrum is hardest and the 6 keV ions are isotropic (or nearly isotropic).The observations are interpreted in terms of a model with two oppositely directed field-aligned electrostatic potential drops: one upper accelerating electrons downward and one lower, produced by the electron influx, which accelerates ions downward. Ion scattering in turbulent wave fields is proposed to be responsible for the observation that the 1 keV ion flux at large pitch angles does not decrease strongly where the 6 keV ion flux does and as an explanation of the isotropization at the centre of the event. The source problem for the ions is eliminated by the precipitating electrons ionizing continuously the thin neutral atmosphere even at altitudes of a few thousand kilometers.     

Observations of water vapor ions at the lunar surface

The Apollo 14 Suprathermal Ion Detector Experiment observed a series of bursts of 48.6 eV water vapor ions at the lunar surface during a 14-h period on March 7, 1971. The maximum flux observed was 10⁸ ions cm^–2 s^–1 sr^–1. These ions were also observed at Apollo 12, 183 km to the west. Evaluation of specific artificial sources including the Apollo missions and the Russian Lunokhod leads to the conclusion that the water vapor did not come from a man-made source. Natural sources exogenous to the Moon such as comets and the solar wind are also found to be inadequate to explain the observed fluxes. Consequently, these water vapor ions appear to be of lunar origin.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

The effect of heavy ions on the formation and structure of cometary bow shocks

We investigate the interaction of heavy cometary ions with the solar wind and the formation of a bow shock in front of a comet by means of a hybrid (particle ion, fluid electron) simulation code that solves self-consistently for the electromagnetic fields and the motion of the charged particles. This kinetic treatment of the solar wind protons and the heavy cometary ions allows us to examine two important issues. One is the effect of the velocity distribution function of the heavy ions on the shock formation and structure, and the other is the degree of coupling between the two ion species. The result of this study indicate that at high Mach numbers the shock structure is highly dependent upon the velocity distribution of the heavy ions. For example, when the newly created ions comprise a ring distribution in the solar wind frame, most of them turn around downstream of the shock surface and reenter the upstream region to form a large foot that extends about a heavy ions gyroradius upstream of the shock. On the other hand, heavy ions which have been picked up by the solar wind and possesses a Maxwellian distribution can mostly penetrate the shock without returning upstream and affecting the shock structure as much. In either case, however, at high Mach numbers the shock strength is the same. At low Mach numbers, where the shock is weak, the velocity distribution of heavy ions has a smaller effect on the formation of shock and its structure. In this regime, the degree of coupling between the cometary ions and the solar wind protons and the corresponding critical Mach number (at which a shock should begin to form) are determined from a set of Rankine-Hugoniot relations. The results of the simulations suggest that some coupling does occur (evidently, through the electromagnetic fields, since there are no particle collisions in the calculations), but less than that expected from magnetohydrodynamics. For low Mach numbers, it is also shown that shocks have a transitory nature, where they are continuously formed by the protons and subsequently destroyed by the heavy ions.     

Silicon negative ion chemistry in the atmosphere-in situ and laboratory measurements

The results of a rocket-borne mass spectrometer measurement indicate that large concentrations of negative ions exist above the bottom of the atmospheric atomic oxygen layer. A large majority of these ions have a mass greater than 100 amu. In addition, an ion at mass 76 was observed with concentrations too large to be CO₄^?. In order to explain these features, a number of reactions involving silicon oxide negative ions have been measured in a flowing afterglow system. The ion SiO₃^? is produced by reaction of O₃^?, and CO₃^?, with SiO. The SiO₃^? ion is extremely stable and does not react measurably with NO, NO₂, CO, CO₂, O₃ or O. Since meteoroid ablation produces a large silicon input into the atmosphere, it appears possible that the ions observed at mass 76 may be SiO₃^?. Possible production mechanisms for this ion as well as the heavy ions are discussed.