余庆县小腮钒矿地质特征及工业利用性能评价

余庆县小腮地区的钒矿赋存于下寒武统牛蹄塘组近底部,具有品位低、厚度大的特点,矿石类型属炭质泥岩型钒矿.钒在原矿中的价态主要以V^3＋形式存在,其次为V^4＋和V^5＋,其中V^3＋主要以类质同象形式取代Al^3＋、Fe^3＋等氧化矿物及硅酸盐矿物,而V^4＋、V^5＋则全部以吸附状态赋存于云母类矿物中.矿石通过“原矿—破碎—磨矿—浸出—固液分离—萃取—反萃—沉钒—脱铵—五氧化二钒成品”提钒工艺,其五氧化二钒浸出率达85％,五氧化二钒总回收率为79.20％,在环境保护上能得到较好的控制,所得产品质量达GB3283-87冶金用V20599牌号标准.     

高温炉燃烧-红外吸收法测定重铀酸盐中硫质量分数

建立了高温燃烧红外碳硫仪测定重铀酸盐中硫质量分数的分析方法。样品以五氧化二钒为助熔剂,在高温炉燃烧后,用红外吸收测定重铀酸盐中的硫,样品分析重现性好,精密度高,相对标准偏差为0.26%;样品加标回收率在97.1%~103%之间。     

湖北杨家堡石煤中钒的价态研究

我国南方石煤是一种低热值能源,同时它伴生有品位较高的钒。含钒石煤已列为我国一种新类型钒矿资源。近年来我国从石煤中提取生产高纯五氧化二钒(V_2O_3>98％)已出口西德、日本等国,国外已有报道。     

浙江石煤钒赋存状态研究

浙江石煤钒赋存状态研究孙智永（昆明冶金研究院，昆明６５００１１）关键词含钒石煤赋存状态浙江遍及南方１０多个省（区）的含钒石煤，为巨大的矾矿资源。仅浙江省含钒石煤中五氧化二钒（Ｖ２Ｏ５＞０．５％）的估算储量就达１３７４．８万ｔ。通过对已有资料的分析，确...     

石煤钒矿成分分析标准物质的研制

石煤钒矿资源的开发和合理利用需要对其成分进行准确的分析测试和质量控制.目前,国内外尚未有石煤钒矿成分分析的标准物质,现有钒成分分析标准物质无论是其五氧化二钒含量,还是定值成分都无法满足我国对石煤钒矿勘查、开发和研究需要.本文对采自湖北省崇阳县小源冲钒矿、湖南省芷江县牛牯坪钒矿、湖南省古丈县岩头寨钒矿和湖南省凤凰县黑冲钒...     

海绵钛生产中铜丝除钒废弃物的回收实验与分析

四氯化钛精制除钒是海绵钛生产中的重要工艺环节,铜丝除钒是目前应用得较多的技术之一,其产生的废弃物的处置与资源化利用是生产中亟需解决的难题。本文利用化学分析、X射线衍射分析和扫描电镜分析等手段,对铜丝除钒工艺产生的废弃物及其综合回收工艺中各种产物的化学成分、物相组成和微观形貌特征进行了分析,结果表明废弃物的主要成分是铜和钒,通过适当的工艺处理可获得电解铜、五氧化二钒等产物。     

X射线荧光光谱法同时测定钛精矿中主次量组分

采用铁矿标准样品和高纯二氧化钛混合配制钛精矿的校准样品,X射线荧光光谱法同时测定钛精矿中氧化镁、三氧化二铝、二氧化硅、磷、硫、氧化钙、二氧化钛、五氧化二钒、锰、铁等主次量成分,并对熔剂选择、熔融条件、钒Kα峰位确定及基体效应校正等进行了探讨。测定结果与标准样品标称值吻合,相对标准偏差(RSD,n=7)除低含量的磷、硫外均在5%以下,能满足钛精矿的检测需要。     

硫酸铈容量法测定含锑试样中的亚铁

岩石中亚铁测定应用最广泛的是重铬酸钾容量法^[1]，还有测定铬铁矿中亚铁的五氧化二钒一硫酸亚铁铵容量法^[2]。本文着重试验和探讨含锑矿物岩石中亚铁测定的硫酸铈容量法。试样以硫酸、氢氟酸分解，加硼酸消除氟的影响，以二苯胺磺酸钠为指示剂，用标准硫酸铈溶液进行滴定，直接测定含锑矿物岩石中的亚铁。试验表明，在硫磷混合酸的冷溶液中，三价锑高达100mg，五价锑达30mg对亚铁测定基本没有影响。方法适用于含锑矿物岩石中亚铁的测定，手续简便，终点清晰，结果满意。     

V—5-Br-PADAP—H_2O_2三元络合物分光光度法测定矿石中的微量钒

2—(5—溴—吡啶偶氮)—5—二乙氨基苯酚(简称5-Br-PADAP)已成功地用作分光光度法测定钒的灵敏试剂。 文献[3]报告在过氧化氢存在下,用一氯醋酸控制酸度(pH1.5～2.0),钒与5-Br-PADAP生成1∶1的络合物进行比色测定,但我们在实验中发现在该体系中络合物不太稳定,故改用磷酸-磷酸氢二钠缓冲液控制溶液酸度(pH2.0～2.25)显色测定,效果良好;并进一步证实此有色络合物为V、5-Br-PADAP、H_2O_2三元络合,其络合比为1∶1∶1。对其他条件也做了些试验,并拟定了一个简便的分析流程。测定下限为10ppm。适用于五氧化二钒含量,在0.00X％以上的矿样。     

Distribution of Selected Critical Elements in the Carboniferous Coal-bearing Series of the Upper Silesian and Lublin Coal Basins (Poland)

The distribution of selected critical elements in the sedimentary rocks of the Carboniferous coal-bearing series within the Polish Coal Basins is presented.Critical elements such as Be,Mg,Si,P,Sc,V,Co,Y,Nb,In,Sb,La,Ce,Hf,Ta,W,Bi were analysed using inductively-coupled plasma mass spectrometry(ICP/MS).Concentrations of elements such as Sb,Bi,In and,to a slightly lesser extent,Nb,as well as Sc,show average concentrations higher than those from the upper continental crust.The average concentrations of elements like Hf,Mg,P,Y,La,and Ce are slightly lower than in the upper continental crust.Other elements,such as Be,Co,Si,Ta,W and V have average concentrations that are similar,but slightly enriched or slightly depleted,relative to the upper continental crust.The research showed enrichment of some critical elements in the analysed samples,but not high enough that extraction would be economically viable.Statistical methods,which include correlation coefficients between elements and cluster analysis,reveal a strong positive correlation between elements like Be,Bi,Nb,Sc,Ta,W and V.Very high,almost total,positive correlation is also noted between La and Ce.     

影响燃烧中和法测定黄铁矿中全硫诸因素的探讨

用燃烧中和法测定黄铁矿中硫含量是一简捷的方法,但也存在一些问题有待以研究。第一,硫转化率低是一个普遍性问题。不少资料用补正值来解决,而未涉及到,样品内部矛盾,实际上关系到矿物中硫的赋存状态,硫酸盐越高则转化率越低。燃烧法定硫如果采用理论值计算势必形成系统偏低。为此必须以标样来标定滴定液。第二,国内外介绍     

石煤中钒的氧化动力学初步研究

含钒石煤是我国一种新类型钒矿资源,钒的氧化是石煤提钒的基础。本文对钒的氧化动力学作了初步工作,通过试验数据处理结果表明,采用Ерофеев综合动力学公式:描述石煤中钒的氧化过程:2VO2固+1/2O2=Y2O5固简明可行,较为适宜。 钒氧化反应初期阶段以动力学方式进行:n1=1,属一级反应过程;继之,n2=0.2,反应受扩散制约。测定了由动力学过程转换为扩散过程所需的反应时间及其钒氧化率,计算了这两种过程的速率常数和表观活化能。     

Environmentally geochemical characteristics of vanadium in the topsoil in the Panzhihua mining area,Sichuan Province,China

Vanadium is a trace element, which may be biologically beneficial and possibly essential but certainly harmful to human beings and some living organisms if excessive. After over 40 years of development, the mining industry has caused serious environmental problems in the Panzhihua mining area. Vanadium is significantly accu-mulated in the soil of the Panzhihua area. Human activities have intensified the pollution and release of vanadium and caused serious damages to the ecological system there. In the past few years, the authors have made investiga-tions into and assessments on the geochemical distribution, chemical speciation, adsorption characteristics and transfer behavior of vanadium in the topsoil in the Panzhihua mining area. The results showed that: (1) the difference in the contents of vanadium in soil between premonsoon and monsoon is insignificant; (2) the adsorption isotherms of vanadium on soil in the Panzhihua mining area ate well described by the Langmuir type; (3) the transfer ability of vanadium in soil is interrelated to soil properties; and (4) the chemical speciation of vanadium shows an order of insoluble residue > oxidizable=reducible > soluble component. According to the above results, some countermea-sures to control pollution of vanadium in soil should be put forward.     

对壤中钒、硒、钼测量方法的观察与思考

本文简要介绍了钒、硒、钼的地球化学性质。根据我国西北业已查实的3个层间氧化带砂岩型铀矿床中钒、硒、钼与铀的展布特征,认为,按已知铀矿床中铀与钒、硒、钼的存在及相互关系,试图用壤中钒、硒、钼测量对层间氧化带砂岩型铀矿实施伴生元素找矿或进行“空间定位”的依据尚不足。     

陕西山阳县黑色岩系中中村—银花钒矿床地质特征

秦岭黑色岩系中带的钒矿构成超大型规模,中村-银花钒矿是大型钒矿的典型代表,产于下寒武统水沟口组中段硅质板岩-泥板岩-粘土质泥板岩岩性转换过渡层位中.矿石根据岩性划分为硅板岩型、粘土质泥板岩型和硅质泥板岩型3种类型.矿层延长及厚度稳定,V2O5品位为0.70%～1.17%.研究查明,钒与粘土质、泥质板岩密切相关,钒在粘土泥板岩中相对富集.钒与铝、钾、铁存在较密切的地球化学共生关系.钒以钒酸盐、磷酸盐及吸附状态存在于高岭石、水云母中.研究认为,含钒黑色岩系是扬子大陆向华北大陆俯冲启动下,于早寒武世扬子大陆北缘斜坡出现在拉伸裂谷式沉积环境,发育滞留深水环境下的炭-泥-灰-重晶石-硅质含钒沉积建造,含钒的炭质硅板岩-炭质泥板岩层具有热水沉积产物的特征.     

Environmental geochemistry and ecological risk of vanadium pollution in Panzhihua mining and smelting area, Sichuan, China

1 Introduction Vanadium (V) is a relatively abundant elemenwhich is widely distributed in nature; howeverworkable V deposits are very rare (World HealthOrganization, 2001). Vanadium is a trace elementwhich may be beneficial and possibly essential fohuman…     

Vanadium mineralization in ore of the Vihanti massive sulfide base-metal deposit,Finland

A series of vanadium oxides—shcherbinaite, karelianite, kyzylkumite, coulsonite, and berdesinskiite—was found in association with pyrrhotite in pyrite-pyrrhotite ore from the Paleoproterozoic Vihanti massive sulfide deposit of the Kuroko-type. It is suggested that enrichment in vanadium of massive sulfide ore from the Vihanti deposit is a result of their metamorphogenic regeneration and pyrrhotinization at the expense of rocks and ore enriched in vanadium. The list of rare minerals in massive sulfide ore has been extended.     

宁陕县大构园沟钒矿床地质特征及矿床成因探讨

大构园沟钒矿是近年来陕西境内新发现的中型钒矿床,属于南秦岭多金属成矿带黑色岩系中带成矿的一部分。笔者从成矿地质环境、矿床地质特征、成矿作用综合信息研究入手,对大构园沟钒矿床成因进行了分析,认为寒武系水沟口组是区内钒、金的主要赋矿层位,碳泥质板岩、含碳质石英砂岩(炭硅质岩)是赋矿的有利岩性,也是找矿的直接标志。矿床成因属有机质参与的海底热水沉积(改造)型矿床。