青藏高原西北缘祁漫塔格山中新世快速抬升 的磷灰石裂变径迹证据

对祁漫塔格山体不同海拔高度所取的9个磷灰石样品的裂变径迹分析结果表明,东昆仑西段中新世早中期为主要的隆升期且隆升速率较高,早期隆升速率为111m／Ma,晚期隆升速率为98m／Ma,总体隆升速率为100m／Ma。样品显示出磷灰石裂变径迹长度大致分2类,一类磷灰石裂变径迹长度为（12．21±10．20）-（13．75±0．30）μm,径迹长度分布图基本上为窄而对称的正态分布,反映具有快的剥露冷却速率,未受到后期热事件的干扰。另一类磷灰石裂变径迹长度为（11．88±0．33）～（13．32±0．27）μm,较前一类具有稍慢的剥露冷却速率,并且受到了后期热事件的干扰。     

天山、西昆仑山中、新生代幕式活动的磷灰石裂变径迹记录

通过对天山独山子—库车公路、西昆仑山新疆—西藏公路出露的7个花岗岩样品的磷灰石裂变径迹分析，研究了天山、西昆仑山脉低温（＜110℃）热历史。磷灰石裂变径迹年龄范围为（9.6±0.8）～（89.2±2.3）Ma，平均裂变径迹长度变化范围为（7.9±3.7）～（11.6±1.9）μm。磷灰石裂变径迹年龄反映冷却作用时代，地质资料和磷灰石裂变径迹分析数据表明，天山在白垩纪存在一次抬升作用，天山和西昆仑山在中新世发生另一次抬升作用。     

伊通盆地渐新世以来构造活动历史的裂变径迹分析

运用裂变径迹分析方法,针对岔路河断陷与鹿乡断陷5个样品的磷灰石进行裂变径迹分析并结合盆地模拟研究表明,伊通盆地岔路河断陷自渐新世以来曾经历两期构造热事件,发生的时间约为24．9Ma～19．1Ma和6．9Ma～4．9Ma;鹿乡断陷自渐新世以来也经历了两期构造热事件,发生的时间约为30Ma～27．8Ma和22．6Ma～11．1Ma。伊通盆地在渐新世以来发生的二次抬升剥蚀均是从中部迁移至北部。岔路河断陷和鹿乡断陷磷灰石裂变径迹与样品高程均具正相关性,其中岔路河断陷21．8Ma以来的平均隆升剥露速率为7．034×10^-2mm／y,鹿乡断陷18．9Ma以来的平均隆升剥露速率为6．033×10^-2mm／y。上述热年代学认识同时得到了盆地地球动力学背景、地层划分与对比及火山活动等方面证据的支持,说明应用磷灰石裂变径迹技术可有效地分析伊通走滑-伸展盆地的构造活动历史。     

高喜马拉雅地区聂拉木花岗岩快速抬升的裂变径迹证据

笔者对西藏高喜马拉雅地区聂拉木花岗岩样品进行了磷灰石裂变径迹分析。聂拉木淡色花岗岩4个不同高程(395～4200m)的裂变径迹年龄范围为3.79±0.34～8.17±0.47Ma,混合花岗岩4个不同高程(3260～3720m)的裂变径迹年龄范围为0.85±0.09～1.71±0.34Ma。结合已有的热年代学资料,提出整个高喜马拉雅造山带在上新世—第四纪时为快速抬升期。     

苏鲁超高压变质岩的构造热历史：中国大陆科学钻探工程(CCSD)主孔（MH）和先导孔（PP2）的磷灰石裂变径迹约束

本文包括中国大陆科学钻（CCSD）主孔（MH）0~5000m和先导孔（PP2）0~1000m的磷灰石裂变径迹分折结果,先导孔PP2的裂变径迹表观年龄变化范围为79.5±5.1~50.4±6.2Ma,主孔的裂变径迹表观年龄变化范围为98.6±17.0~2.9±2.0Ma,主孔在4200m以下,磷灰石样品中实际上已不存在自发裂变径迹,表明裂变径迹时钟已经“置零”。实验资料表明,裂变径迹表观年龄值随样品深度的增加而逐渐减少,直到一定深度,即达到磷灰石的裂变径迹封闭温度（~120℃）以后,年龄值为零。根据主孔0~2000m和先导孔0~1000m的裂变径迹年龄剖面,作为一级近似,计算出超高压变质岩体在90~30Ma期间,平均隆升速度为~35m/Ma。对主孔测定了9个样品的约束径迹（Confined track）长度,样品约束径迹平均长度的变化范围约为13.1~7.4μm,总的变化趋势是：约束径迹平均长度随样品深度的增加而逐渐减少。样品的约束径迹长度分布都具有双峰型特征。根据裂变径迹年龄和约束径迹长度的资料,应用计算机模拟得到了样品的时间-温度（t-T）轨迹。结果表明,岩体从早白垩世（~120Ma）快速冷却以后,在晚白垩世和始新世又经历了两次加热作用,始新世末岩体所达到的温度大约是80℃,随后岩体则一直上升和缓慢冷却到现今所处的位置。在最后~30Ma岩体的平均隆升速度为~53m/Ma。     

阿尔金断裂带东端40Ar/39Ar和裂变径迹定年及其地质意义

通过对酒西盆地北缘阿尔金构造岩中3件钾长石加40Ar/39Ar同位素和沿赤金堡到下天津卫石油河剖面花岗岩磷灰石、锆石裂变径迹定年研究,获得了断裂带内构造岩220～207Ma的钾长石40Ar/39Ar激光探针概率年龄,其中锆石裂变径迹定年也获得了233±19Ma以及192±26Ma的近似同时的年龄,代表了晚三叠世到早侏罗世快速的冷却事件,其可能与羌塘和昆仑地块的碰撞有关.锆石裂变径迹定年记录的149～135Ma年龄,也可能反映了晚侏罗世到早白垩世的冷却事件的存在,这一冷却剥露伴随而来的早白垩世的广泛沉积作用.磷灰石裂变径迹中值年龄主要介于42～28Ma,这一年龄结果和热史模拟表明晚始新世到渐新世,40～30Ma的冷却事件.研究区经历了类似于青藏高原北缘地区的冷却降温历史,其隆升和剥露演化受控于欧亚板块南部昆仑、羌塘、拉萨地体的碰撞拼合和印度碰撞后持续挤压作用.     

青藏高原东部雀儿山地区新近纪隆升速率探讨——来自雀儿山花岗岩体磷灰石裂变径迹证据

通过青藏高原东部川西地区雀儿山花岗岩体磷灰石裂变径迹分析,新获得了4个磷灰石裂变径迹年龄值,分别为4. 9±0. 3Ma、6. 2±0. 5 Ma、7. 2±0. 4 Ma和7. 3±0. 7 Ma。运用径迹年龄-地形高差法计算出雀儿山花岗岩体新近纪的隆升速率,为0. 15～2 mm/a,平均隆升速率为0. 78mm/a。隆升速率在每个阶段有所不同,但呈现出一种快速隆升→缓慢隆升的过程,为整个青藏高原东缘的隆升过程提供了约束条件。     

青藏高原西北缘祁漫塔格山中新世快速抬升的磷灰石裂变径迹证据

对祁漫塔格山体不同海拔高度所取的9个磷灰石样品的裂变径迹分析结果表明,东昆仑西段中新世早中期为主要的隆升期且隆升速率较高,早期隆升速率为111m／Ma,晚期隆升速率为98m／Ma,总体隆升速率为100m／Ma。样品显示出磷灰石裂变径迹长度大致分2类,一类磷灰石裂变径迹长度为（12．21±10．20）-（13．75±0．30）μm,径迹长度分布图基本上为窄而对称的正态分布,反映具有快的剥露冷却速率,未受到后期热事件的干扰。另一类磷灰石裂变径迹长度为（11．88±0．33）～（13．32±0．27）μm,较前一类具有稍慢的剥露冷却速率,并且受到了后期热事件的干扰。     

班公湖- 怒江缝合带东段八宿地区花岗岩体差异性隆升：来自锆石和磷灰石裂变径迹证据

班公湖- 怒江缝合带为青藏高原内部分隔羌塘和拉萨两地块的构造边界,是研究青藏高原构造演化的重要窗口之一。该缝合带自西向东分为西段（班公湖至改则）、中段（安多至东巧）和东段（丁青至怒江）,其中东段的研究程度较低。本次以东段八宿县郭庆乡一条花岗岩高程剖面为研究对象,采用激光剥蚀电感耦合等离子体质谱仪（LA- ICPMS）法对锆石和磷灰石开展裂变径迹测试。花岗岩锆石U- Pb年龄为~180 Ma,指示其结晶时代为早侏罗世。锆石和磷灰石裂变径迹年龄分别为180～130 Ma、86～61 Ma,对应的年龄- 海拔曲线分别为负斜率和正斜率。QTQt模拟显示花岗岩高程剖面顶部在130～60 Ma时剥蚀冷却速率快,中部在130～40 Ma时剥蚀冷却速率居中,而底部在~130 Ma之后一直保持最低的剥蚀冷却速率。这种差异性隆升源自班公湖- 怒江缝合带东段的南向俯冲板片断离早于北向俯冲板片断离。     

青藏高原西北缘高原面与陡坡地貌形成过程的裂变径迹热年代学约束

对青藏高原西北缘高原内部和陡坡地貌带2个花岗岩体10件磷灰石裂变径迹年龄测定表明,高原内部大红柳滩—郭扎错逆冲断裂上盘磷灰石裂变径迹年龄为24.8±4.9～14.0±1.3Ma,此外,一个玄武岩烘烤的热事件年龄为7.9±0.8Ma;而陡坡地貌带的西昆仑中间逆冲断裂上盘的磷灰石裂变径迹年龄为2.9±0.5～0.9±0.3Ma。进一步的热历史模拟结果显示,高原内部自渐新世以来经历了2期隆升-剥露,分别是渐新世—早中新世(30～16Ma)和上新世以来(≤5Ma),而陡坡带只记录了晚中新世以来(≤8Ma)的隆升-剥露,暗示他们经历了不同的热演化历史。结合前人在该区的磷灰石裂变径迹年龄数据和野外地质现象,认为现今高原边缘陡坡地貌带可能是自晚中新世以来(≤8Ma)高原边界断裂伴有向塔里木盆地后展式叠瓦逆冲产生的构造抬升的结果;现今高原面有可能是由高原边界断裂系于大约5～2Ma以来强烈活动逐渐形成的,其隆升-剥蚀幅度>2000～3000m。这对自晚中新世以来青藏高原西北缘高原面与陡坡地貌形成过程提供了磷灰石裂变径迹热年代的重要约束。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。