Fingerprinting the Late Pleistocene tephras of Ciomadul volcano,eastern–central Europe

Late Pleistocene tephras derived by large explosive volcanic eruptions are widespread in the Mediterranean and surrounding areas. They are important isochronous markers in stratigraphic sections and therefore it is important to constrain their sources. We report here tephrochronology results using multiple criteria to characterize the volcanic products of the Late Pleistocene Ciomadul volcano in eastern–central Europe. This dacitic volcano had an explosive eruption stage between 57 and 30 ka. The specific petrological character (ash texture, occurrence of plagioclase and amphibole phenocrysts and their compositions), the high-K calc-alkaline major element composition and particularly the distinct trace element characteristics provide a strong fingerprint of the Ciomadul volcano. This can be used for correlating tephra and cryptotephra occurrences within this timeframe. Remarkably, during this period several volcanic eruptions produced tephras with similar glass major element composition. However, they differ from Ciomadul tephras by glass trace element abundances, ratios of strongly incompatible trace elements and their mineral cargo that serve as discrimination tools. We used (U-Th)/He zircon dates combined with U-Th in situ rim dates along with luminescence and radiocarbon dating to constrain the age of the explosive eruptions of Ciomadul that yielded distal tephra layers but lack of identified proximal deposits.     

From sink to volcanic source: Unravelling missing terrestrial eruption records by characterization and high‐resolution chronology of lacustrine volcanic density flow deposits,Lake Inawashiro‐ko,Fukushima, Japan

Eruption records in the terrestrial stratigraphy are often incomplete due to erosion after tephra deposition, limited exposure and lack of precise dating owing to discontinuity of strata. A lake system and sequence adjacent to active volcanoes can record various volcanic events such as explosive eruptions and subaqueous density flows being extensions of eruption triggered and secondary triggered lahars. A lacustrine environment can constrain precise ages of such events because of constant and continuous background sedimentation. A total of 71 subaqueous density flow deposits in a 28 m long core from Lake Inawashiro‐ko reveals missing terrestrial volcanic activity at Adatara and Bandai volcanoes during the past 50 kyr. Sedimentary facies, colour, grain size, petrography, clay mineralogy, micro X‐ray fluorescence analysis and chemistry of included glass shards characterize the flow event deposits and clarify their origin: (i) clay‐rich grey hyperpycnites, extended from subaerial cohesive lahars at Adatara volcano, with sulphide/sulphate minerals and high sulphur content which point to a source from hydrothermally altered material ejected by phreatic eruptions; and (ii) clay‐rich brown density flow deposits, induced by magmatic hydrothermal eruptions and associated edifice collapse at Bandai volcano, with the common presence of fresh juvenile glass shards and low‐grade hydrothermally altered minerals; whereas (iii) non‐volcanic turbidites are limited to the oldest large slope failure and the 2011 Tohoku‐oki earthquake events. The high‐resolution chronology of volcanic activity during the last 50 kyr expressed by lacustrine event deposits shows that phreatic eruption frequency at Adatara has roughly tripled and explosive eruptions at Bandai have increased by ca 50%. These results challenge hikers, ski‐fields and downstream communities to re‐evaluate the increased volcanic risks from more frequent eruptions and far‐reaching lahars, and demonstrate the utility of lahar and lacustrine volcanic density flow deposits to unravel missing terrestrial eruption records, otherwise the recurrence rate may be underestimated at many volcanoes.     

STUDY OF ERUPTIONS AND EARTHQUAKES ORIGINATING FROM VOLCANOES (PART 1 OF 3)

Reports of volcanic eruptions and earthquakes originating from volcanoes indicate that seismic activity preceding the eruption is related not only to eruption magnitude and structure of the volcano, but also to viscosity of the lava at the time of eruption. This follows, since lava of higher viscosity meets greater resistance as it ascends from the magma chamber to the earth's surface and, consequently, greater stress will be produced within and beneath the volcano. The writer gives a condensed statistical breakdown of earthquakes and explosive eruptions of Asama Volcano. The Asama earthquakes treated in the report are mainly those of rather low magnitude (T = 1. 0 sec, V = 350) at the Asama Volcano Observatory, situated 4. 2 km east of the center of the summit crater. This investigation showed that most of the explosive eruptions were preceded by an increase in micro-earthquakes. In addition, an experimental formula for predicting volcanic eruptions, based on the statistical relation between frequency of earthquakes originating from Asama and its explosive eruptions. The forthcoming report (Part II) will discuss the same problem based on seismic observations by more sensitive instruments set nearer the summit crater. — A. Eustus     

Volcaniclastic resedimentation in distal fluvial basins induced by large-volume explosive volcanism: the Ebisutoge–Fukuda tephra, Plio-Pleistocene boundary, central Japan

The Ebisutoge–Fukuda tephra (Plio‐Pleistocene boundary, central Japan) has a well‐recorded eruptive style, history, magnitude and resedimentation styles, despite the absence of a correlative volcanic edifice. This tephra was ejected by an extremely large‐magnitude and complex volcanic eruption producing more than 400 km³ total volume of volcanic materials (volcanic explosivity index=7), which extended more than 300 km away from the probable eruption centre. Remobilization of these ejecta occurred progressively after the completion of a series of eruptions, resulting in thick resedimented volcaniclastic deposits in spatially separated fluvial basins, more than 100 km from the source. Facies analysis of resedimented volcaniclastic deposits was carried out in distal fluvial basins. The distal tephra (≈100–300 km from the source) comprises two different lithofacies, primary pyroclastic‐fall deposits and reworked volcaniclastic deposits. The resedimented volcaniclastic succession shows five distinct sedimentary facies, interpreted as debris‐flow deposits (facies A), hyperconcentrated flow deposits (facies B), channel‐fill deposits (facies C), floodplain deposits with abundant flood‐flow deposits (facies D) and floodplain deposits with rare flood deposits (facies E). Resedimented volcaniclastic materials at distal locations originated from unconsolidated deposits of a climactic, large ignimbrite‐forming eruption. Factors controlling inter‐ and intrabasinal facies changes are (1) temporal change of introduced volcaniclastic materials into the basin; (2) proximal–distal relationship; and (3) distribution pattern of pyroclastic‐flow deposits relative to drainage basins. Thus, studies of the Ebisutoge–Fukuda tephra have led to a depositional model of volcaniclastic resedimentation in distal areas after extremely large‐magnitude eruptions, an aspect of volcaniclastic deposits that has often been ignored or poorly understood.     

Geochemical characterization of marker tephra layers from major Holocene eruptions,Kamchatka Peninsula,Russia

Kamchatka Peninsula is one of the most active volcanic regions in the world. Many Holocene explosive eruptions have resulted in widespread dispersal of tephra-fall deposits. The largest layers have been mapped and dated by the ¹⁴C method. The tephra provide valuable stratigraphic markers that constrain the age of many geological events (e.g. volcanic eruptions, palaeotsunamis, faulting, and so on). This is the first systematic attempt to use electron microprobe (EMP) analyses of glass to characterize individual tephra deposits in Kamchatka. Eighty-nine glass samples erupted from 11 volcanoes, representing 27 well-identified Holocene key-marker tephra layers, were analysed. The glass is rhyolitic in 21 tephra, dacitic in two, and multimodal in three. Two tephra are mixed with glass compositions ranging from andesite/dacite to rhyolite. Tephra from the 11 eruptive centres are distinguished by their glass K₂O, CaO, and FeO contents. In some cases, individual tephra from volcanoes with multiple eruptions cannot be differentiated. Trace element compositions of 64 representative bulk tephra samples erupted from 10 volcanoes were analysed by instrumental neutron activation analysis (INAA) as a pilot study to further refine the geochemical characteristics; tephra from these volcanoes can be characterized using Cr and Th contents and La/Yb ratios.

Unidentified tephra collected at the islands of Karaginsky (3), Bering (11), and Attu (5) as well as Uka Bay (1) were correlated to known eruptions. Glass compositions and trace element data from bulk tephra samples show that the Karaginsky Island and Uka Bay tephra were all erupted from the Shiveluch volcano. The 11 Bering Island tephra are correlated to Kamchatka eruptions. Five tephra from Attu Island in the Aleutians are tentatively correlated with eruptions from the Avachinsky and Shiveluch volcanoes.     

Glacier Peak,Washington: A potentially hazardous cascade volcano

Recent field studies of postglacial volcanic deposits at Glacier Peak indicate the volcano has erupted more often, more voluminously, and more recently than previously thought. These past eruptions produced pyroclastic flows, extensive lahars, and widely distributed tephra falls. Analysis of the magnitude of past eruptions and the distribution of volcanic sediments indicates that future eruptions at Glacier Peak as large as those of the last several thousand years would dramatically affect people and property downstream and downwind from the volcano. Pyroclastic flows and lateral blasts would primarily affect uninhabited valleys within a few tens of kilometers of the volcano. Lahars and floods constitute the major hazard to populated areas from future eruptions, and could affect areas at low elevation along valley floors and in the Puget lowland as far as 100 km downvalley west of the volcano. Air-fall tephra from future eruptions will probably be deposited primarily east of Glacier Peak because of prevailing westerly winds.     

Tephra Discovered in High Resolution Peat Sediment and Its Indication to Climatic Event

Floating tephra was deposited together with ice core,snow layer,abyssal sediment,lake sediments,and other geological records.It is of great significance to interpret the impact on the climate change of volcanic eruptions from these geological records.It is the first time that volcanic glass was discovered from the peat of Jinchuan(金川)Maar,Jilin(吉林)Province,China.And it is in situ sediments from a near-source explosive eruption according to particle size analysis and identification results.The tephra were neither from Tianchi(天池)volcano eruptions,Changbai(长白)Mountain,nor from Jinlongdingzi(金龙顶子)volcano about 1 600 aBP eruption,but maybe from an unknown eruption of Longgang(龙岗)volcano group according to their geochemistry and distribution.Geochemical characters of the tephra are similar to those of Jingiongdingzi,which are poor in s.Jica,deficient in alkali,Na20 content is more than K20 content,and are similar to distribution patterns of REE and incompatible elements,which helps to speculate that they originated from the same mantle magma with rare condemnation,and from basaltic explosive eruption of Longgang volcano group.The tephra,from peat with age proved that the eruption possibly happened in 15 BC-26 AD,is one of Longgang volcano group eruption that was not recorded and is earlier than that of Jinglongdingzi about 1 600 aBP eruption.And the sedimentary time of tephra is during the period of low temperature alteration.which may be the influence of eruption toward the local climate according to the correlativity of eruption to local temperature curve of peat cellulose oxygen isotope.     

Mineral composition of tephra layers in the Quaternary deposits of the Sea of Okhotsk:: Heavy minerals associations and their geochemistry

Heavy mineral associations from tephra layers in the Quaternary deposits of the Sea of Okhotsk and their chemical characteristics were studied by various techniques. It was shown that such investigations may have a bearing on the problems of tephrostratigraphic correlation. We assessed the possibility of application of the mineral composition of distal tephra for identification and, in particular, estimation of the relation of tephras to the explosive volcanism of back-arc and frontal zones of island arcs. The investigation of the compositions of minerals and use of mineral geothermometers and geobarometers (two-pyroxene, magnetite–ilmenite, and amphibole) provided evidence on the physicochemical parameters of melt crystallization during the explosive volcanic eruptions that produced the distal tephra layers. It was established that the pyroclastic material of some tephra layers was supplied during explosive eruptions not only from shallow magma chambers but also from deeper and higher temperature reservoirs. Together with the geochemical signatures of volcanic glasses, the obtained results on mineral associations and the geochemistry of mineral inclusions are applicable for the comparative analysis and correlation of tephras from marine and continental sequences, as well as for the identification of explosive volcanic products in adjacent land areas.     

Kīlauea,Hawai’i,puts on a ‘once‐in‐a‐century’ show

Kīlauea is the youngest of five basaltic shield volcanoes on the island of Hawai’i. It is located to the south‐east of the much larger Mauna Loa volcano, and rose above sea level about 100 ka ago. Kīlauea is one of the most monitored, and arguably the best understood volcanoes on Earth, providing scientists with a good understanding of its current eruption, in which magma rises from depth and is stored beneath its 4 × 3.2 km summit caldera in an underground reservoir. The reservoir is connected to a lava lake within a crater called Halema’uma’u, which is situated on the floor of the caldera. When magma drains from the summit area it travels in underground conduits and emerges on the flanks of the volcano at a rift zone, where it erupts through fissures. The magma is sometimes stored in other reservoirs along the way. This link between summit magma storage and fissure eruptions on the flanks has occurred thousands of times at many Hawai’ian volcanoes. The current eruptive episode is, however, a ‘once‐in‐a‐century’ show, because it is the first time since 1924 that fissure‐fed lava flow eruptions have been accompanied by significant explosive eruptions within Halema’uma’u Crater. This gives scientists a unique opportunity to use modern methods to understand exactly how such hazardous explosions happen at Kīlauea, a volcano that receives about 2 million visitors a year.     

Merapi (Java,Indonesia): anatomy of a killer volcano

Merapi is Indonesia's most dangerous volcano with a history of deadly eruptions. Over the past two centuries, the volcanic activity has been dominated by prolonged periods of lava dome growth and intermittent gravitational or explosive dome failures to produce pyroclastic flows every few years. Explosive eruptions, such as in 2010, have occurred occasionally during this period, but were more common in pre‐historical time, during which a collapse of the western sector of the volcano occurred at least once. Variations in magma supply from depth, magma ascent rates and the degassing behaviour during ascent are thought to be important factors that control whether Merapi erupts effusively or explosively. A combination of sub‐surface processes operating at relatively shallow depth inside the volcano, including complex conduit processes and the release of carbon dioxide into the magmatic system through assimilation of carbonate crustal rocks, may result in unpredictable explosive behaviour during periods of dome growth. Pyroclastic flows generated by gravitational or explosive lava dome collapses and subsequent lahars remain the most likely immediate hazards near the volcano, although the possibility of more violent eruptions that affect areas farther away from the volcano cannot be fully discounted. In order to improve hazard assessment during future volcanic crises at Merapi, we consider it crucial to improve our understanding of the processes operating in the volcano's plumbing system and their surface manifestations, to generate accurate hazard zonation maps that make use of numerical mass flow models on a realistic digital terrain model, and to utilize probabilistic information on eruption recurrence and inundation areas.     

Tephrochronology of the Siple Dome ice core,West Antarctica: correlations and sources

A total of 24 tephra-bearing volcanic layers have been recognized between 550 and 987 m depth in the Siple Dome A (SDM-A) ice core, in addition to a number already recognized tephra in the upper 550 m (Dunbar et al., 2003, Kurbatov et al., 2006). The uniform composition and distinctive morphological of the particles composing these tephra layers suggest deposition as a result of explosive volcanic eruptions and that the layers therefore represent time-stratigraphic markers in the ice core. Despite the very fine grain size of these tephra (mostly less than 20 microns), robust geochemical compositions were determined by electron microprobe analysis. The source volcanoes for these tephra layers are largely found within the Antarctic plate. Statistical geochemical correlations tie nine of the tephra layers to known eruptions from Mt. Berlin, a West Antarctic volcano that has been very active for the past 100,000 years. Previous correlations were made to an eruption of Mt. Takahe, another West Antarctic volcano, and one to Mt. Hudson, located in South America (Kurbatov et al., 2006). The lowest tephra layer in the ice core, located at 986.21 m depth, is correlated to a source eruption with an age of 118.1 ± 1.3 ka, suggesting a chronological pinning point for the lower ice. An episode of anomalously high volcanic activity in the ice in the SDM-A core between 18 and 35 ka (Gow and Meese, 2007) appears to be related to eruptive activity of Mt. Berlin volcano. At least some of the tephra layers found in the SDM-A core appear to be the result of very explosive eruptions that spread ash across large parts of West Antarctica, off the West Antarctic coast, as well as also being recognized in East Antarctica (Basile et al., 2001, Narcisi et al., 2005, Narcisi et al., 2006). Some of these layers would be expected to should be found in other deep Antarctic ice cores, particularly ones drilled in West Antarctica, providing correlative markers between different cores. The analysis of the tephra layers in the Siple Dome core, along with other Antarctic cores, provides a timing framework for the relatively proximal Antarctic and South American volcanic eruptive events, allowing these to be distinguished from the tropical eruptions that may play a greater role in climate forcing.     

Volcanic eruptions in the Longgang volcanic field,northeastern China,during the past 15,000 years

The Longgang volcanic field, located in northeastern China, is volcanically active with a number of eruptions during the Quaternary but the chronology of the eruptions is poorly defined. Some tephra layers are well preserved in the annually laminated sediments of maar lakes in the region, and facilitate the construction of a much improved chronological framework for the volcanic history of the area. The results of our investigations reveal that three basaltic explosive eruptions occurred at AD 460, 11460 cal yr BP and 14000 cal yr BP, respectively. The largest explosive basaltic eruption (AD 460) produced a thick black scoria layer in the Longgang volcanic field, including lakes. The tephra distribution and chronological data suggest that this eruption is likely to be from the Jinlongdingzi volcano. Two basaltic flood eruptions occurred at Jinlongdingzi. The earlier basaltic eruption produced a lava flow that spread over a forest and encased standing trees. Two radiocarbon ages obtained from charcoal samples collected from the burned remains of these trees are 1828–1989 cal yr BP and 2164–2359 cal yr BP. In the most recent stage of volcanism, the lava flow extended only ca. 2 km, and flowed into Lake Dalongwan. From the present status of the forest ecosystem, which has not yet reached the fully mature successional stage, we estimate that this lava is very young (ca. a few hundreds years old). Jinlongdingzi is a potentially dangerous volcano. Monitoring and assessment of the potential hazards in the Longgang volcanic field should be carried out in the future.     

Late Pleistocene Eolian Sediments Related to Pyroclastic Eruptions of Mauna Kea Volcano, Hawaii

Loess and dune sands that mantle volcanic rocks on the northwest flank of Mauna Kea volcano consist predominantly of fine-grained pyroclasts of the alkalic Laupahoehoe Volcanics produced by explosive eruptions. The loess is divided into lower and upper units, separated by a well-developed paleosol, while older and younger dune sands are separated by loess. Four interstratified tephra marker horizons aid in regional stratigraphic correlation. Radiocarbon ages of charcoal fragments within the loess, U-series ages of rhizoliths in the dune sand, and K/Ar ages and relative stratigraphic positions of lava flows provide a stratigraphic and temporal framework. The lower loess overlies lava flows less than 103,000 ± 10,000 K/Ar yr old, and¹⁴C dates from the paleosol developed at its top average ca. 48,000 yr. Loess separating the dune sand units ranges from ca. 38,000 to 25,000¹⁴C yr old; the youngest ages from the upper loess are 17,000–18,000¹⁴C yr B.P. Dips of sand-dune foreset strata, isopachs on the upper loess, and reconstructed isopachs representing cumulative thickness of tephra associated with late-Pleistocene pyroclastic eruptions suggest that vents upslope (upwind) from the sand dunes were the primary source of the eolian sediments. Average paleowind directions during the eruptive interval (ca. 50,000–15,000 yr B.P.), inferred from cinder-cone asymmetry, distribution of tephra units, orientation of dune foreset strata, and the regional pattern of loess isopachs, suggest that Mauna Kea has remained within the trade-wind belt since before the last glaciation.     

The Pyroclastic deposits of Mount Etna volcano,Sicily

Throughout most of its geological evolution Etna has been characterized by the eruption of lava flows of a predominantly hawaiitic composition, but within the stratigraphical record there are four major sequences of pyroclastic materials: the Acireale tephra and lahars (˜100000 B.P.); the ‘lower tephra’ and Milo lahars (both ˜26000 B.P.); the Biancavilla ignimbrites (15–15500 B.P.) and the ‘upper tephra’ (˜5000–6000 B.P.). This paper reports investigations carried out on these deposits in order to determine their stratigraphy, petrology, sedimentology, and likely origins. Whereas the Biancavilla ignimbrites were generated when a more evolved, gas-charged magma (benmoreite) was being produced by the volcano, the other suites of pyroclastic deposits were erupted from hawaiitic magmas—similar to those that have characterized the volcano during historical times. These deposits resulted from two processes: violent strombolian activity producing lapilli-rich. coarse, but well-sorted sediments, and hydrovolcanism when the mixing of water and magma in the conduit, brought about more violently explosive activity, giving rise to highly fragmented, poorly sorted, airfall tephra and lahars. Conditions favouring hydrovolcanism occurred at times in the volcano's history when palaeoenvironment and palaeogeography were conducive to the retention of large amounts of surface and subsurface water. Although climates favouring the retention of water at high levels on the volcano have occurred on many occasions in the history of the volcano, at ˜26.000 and ˜5000-6000 B.P. these occurred in conjunction with a construct of sufficient height and suitable configuration to allow storage of water and give rise to hydrovolcanic activity. The nature of the mechanisms responsible for the emplacement of these hydrovolcanic deposits is considered and it is concluded that airfall is the most probable process. Finally, the implications of this research for the assessment of hazard are reviewed.     

Tephrochronological dating of varved interglacial lake deposits from Piànico‐Sèllere (Southern Alps,Italy) to around 400 ka

The sediment record from the Piànico palaeolake in the southern Alps is continuously varved, spans more than 15 500 years, and represents a key archive for interglacial climate variability at seasonal resolution. The stratigraphic position of the Piànico Interglacial has been controversial in the past. The identification of two volcanic ash layers and their microscopic analysis provides distinct marker layers for tephrochronological dating of these interglacial deposits. In addition to micro‐facies analyses reconstructing depositional processes of both tephra layers within the lake environment, their mineralogical and geochemical composition has been determined through major‐element electron probe micro‐analysis on glass shards. Comparison with published tephra data traced the volcanic source regions of the Piànico tephras to the Campanian volcanic complex of Roccamonfina (Italy) and probably the Puy de Sancy volcano in the French Massif Central. Available dating of near‐vent deposits from the Roccamonfina volcano provides a robust tephrochronological anchor point at around 400 ka for the Piànico Interglacial. These deposits correlate with marine oxygen isotope stage (MIS) 11 and thus are younger than Early to Middle Pleistocene previously suggested by K/Ar dating and older than the last interglacial as inferred from macrofloral remains and the geological setting. Copyright © 2006 John Wiley & Sons, Ltd.     

The 2011 eruption of Nabro volcano,Eritrea: perspectives on magmatic processes from melt inclusions

The 2011 eruption of Nabro volcano, Eritrea, produced one of the largest volcanic sulphur inputs to the atmosphere since the 1991 eruption of Mt. Pinatubo, yet has received comparatively little scientific attention. Nabro forms part of an off-axis alignment, broadly perpendicular to the Afar Rift, and has a history of large-magnitude explosive silicic eruptions, as well as smaller more mafic ones. Here, we present and analyse extensive petrological data obtained from samples of trachybasaltic tephra erupted during the 2011 eruption to assess the pre-eruptive magma storage system and explain the large sulphur emission. We show that the eruption involved two texturally distinct batches of magma, one of which was more primitive and richer in sulphur than the other, which was higher in water (up to 2.5 wt%). Modelling of the degassing and crystallisation histories demonstrates that the more primitive magma rose rapidly from depth and experienced degassing crystallisation, while the other experienced isobaric cooling in the crust at around 5 km depth. Interaction between the two batches occurred shortly before the eruption. The eruption itself was likely triggered by recharge-induced destabilisation of vertically extensive mush zone under the volcano. This could potentially account for the large volume of sulphur released. Some of the melt inclusions are volatile undersaturated, and suggest that the original water content of the magma was around 1.3 wt%, which is relatively high for an intraplate setting, but consistent with seismic studies of the Afar plume. This eruption was smaller than some geological eruptions at Nabro, but provides important insights into the plumbing systems and dynamics of off-axis volcanoes in Afar.     

Potential Hazards of Eruptions around the Tianchi Caldera Lake, China

Since the eruption of the Tianchi volcano about 1000 years ago, there have been at least 3 to 5 eruptions of small to moderate size. In addition, hazardous avalanches, rock falls and debris flows have occurred during periods between eruptions. A future eruption of the Tianchi volcano is likely to involve explosive interaction between magma and the caldera lake. The volume of erupted magma is almost in a range of 0.1-0.5 km3. Tephra fallout may damage agriculture in a large area near the volcano. If only 1% of the lake water were ejected during an eruption and then precipitated over an area of 200 km2, the average rainfall would be 100 mm. Moreover, lahars are likely to occur as both tephra and water ejected from the caldera lake fall onto flanks of the volcano. Rocks avalanching into the caldera lake also would bring about grave hazards because seiches would be triggered and lake water with the volume equal to that of the landslide would spill out of the existing breach in the caldera and cause flooding     

Trace element degassing and enrichment in the eruptive plume of the 2000 eruption of Hekla volcano, Iceland

During its last eruption in February 2000, Hekla volcano (Iceland) emitted a sub-Plinian plume that was condensed and scavenged down to the ground by heavy snowstorms, offering the unique opportunity to study the chemistry of the gaseous plume released during highly explosive eruptions. In this paper, we present results on trace element and minor volatile species (sulfates, chlorides, and fluorides) concentrations in snow samples collected shortly after the beginning of the eruption. The goal of this study is to better constrain the degassing and mobility of trace elements in gaseous emissions. Trace element volatility at Hekla is quantified by means of enrichment factors (EF) relative to Be. Well-known volatile trace elements (e.g., transition metals, heavy metals, and metalloids) are considerably enriched in the volcanic plume of Hekla. Their abundances are governed by the primary magmatic degassing of sulfate and/or halide compounds, which are gaseous at magmatic temperature. Their volatility is, however, slightly lower than in basaltic systems, most likely because of the lower magma temperature and higher magma viscosity at Hekla. More surprisingly, refractory elements (e.g., REE, Th, Ba, and Y) are also significantly enriched in the eruptive plume of Hekla where their apparent volatility is two orders of magnitude higher than in mafic systems. In addition, REE patterns normalized to the Hekla 2000 lava composition show a significant enrichment of HREE over LREE, suggesting the presence of REE fluorides in the volcanic plume. Such enrichments in the most refractory elements and REE fractionation are difficult to reconcile with primary degassing processes, since REE fluorides are not gaseous at magma temperature. REE enrichments at Hekla could be attributed to incongruent dissolution of tephra grains at low temperature by F-rich volcanic gases and aerosols within the eruptive plume. This view is supported by both leaching experiments performed on Hekla tephra and thermodynamic considerations on REE mobility in hydrothermal fluids and modeling of glass dissolution in F-rich aqueous solutions. Tephra dissolution may also explain the observed enrichments in other refractory elements (e.g., Th, Y, and Ba) and could contribute to the degassing mass balance of some volatile trace elements, provided they are mobile in F-rich fluids. It thus appears that both primary magmatic degassing and secondary tephra dissolution processes govern the chemistry of eruptive plumes released during explosive eruptions.     

Evolution of the middle Proterozoic Chandabooka Caldera,Gawler range acid volcano‐plutonic province,South Australia

Volcanism associated with the middle Proterozoic Gawler Range acid volcano‐plutonic province was initiated in the Kokatha area by the construction on Archaean basement of a large stratovolcano composed mainly of tholeiitic basalt and potassic basaltic‐andesite erupted possibly from a mantle‐derived ultramafic diapir.

Crustal melting above the diapir generated acid magma, rich in silica and potassium, which rose by major block‐stoping to form a subvolcanic magma chamber. Leakage from this chamber during the premonitory caldera phase gave rise to small explosive and effusive eruptions around an incipient ring‐fracture zone. In the caldera phase, the eruption of voluminous rhyodacite to dacite ignimbrite from the subvolcanic magma chamber resulted in collapse of the roof partway through the eruption to form the Chandabooka caldera, 15 x 10 km across: the ignimbrite comprises a thick compound cooling unit, the Chandabooka Dacite, of which both the caldera and outflow facies are preserved. Resurgent doming and subsequent uplift of the caldera block by 1 km followed in the post‐caldera phase, accompanied by minor acidic volcanism. Flat‐roofed stocks of the primitive S‐type Hiltaba Granite and a major dyke swarm intruded the volcanic pile to complete the volcano‐plutonic episode.     

Geoheritage values of one of the largest maar craters in the Arabian Peninsula: the Al Wahbah Crater and other volcanoes (Harrat Kishb, Saudi Arabia)

Al Wahbah Crater is one of the largest and deepest Quaternary maar craters in the Arabian Peninsula. It is NW-SE-elongated, ～2.3 km wide, ～250 m deep and surrounded by an irregular near-perpendicular crater wall cut deeply into the Proterozoic diorite basement. Very few scientific studies have been conducted on this unique site, especially in respect to understanding the associated volcanic eruption processes. Al Wahbah and adjacent large explosion craters are currently a research subject in an international project, Volcanic Risk in Saudi Arabia (VORiSA). The focus of VORiSA is to characterise the volcanic hazards and eruption mechanisms of the vast volcanic fields in Western Saudi Arabia, while also defining the unique volcanic features of this region for use in future geoconservation, geoeducation and geotourism projects. Al Wahbah is inferred to be a maar crater that formed due to an explosive interaction of magma and water. The crater is surrounded by a tephra ring that consists predominantly of base surge deposits accumulated over a pre-maar scoria cone and underlying multiple lava flow units. The tephra ring acted as an obstacle against younger lava flows that were diverted along the margin of the tephra ring creating unique lava flow surface textures that recorded inflation and deflation processes along the margin of the post-maar lava flow. Al Wahbah is a unique geological feature that is not only a dramatic landform but also a site that can promote our understanding of complex phreatomagmatic monogenetic volcanism. The complex geological features perfectly preserved at Al Wahbah makes this site as an excellent geotope and a potential centre of geoeducation programs that could lead to the establishment of a geopark in the broader area at the Kishb Volcanic Field.