Effects of reduced salt concentrations on plant communities in the River Werra (Germany)

The reduction and equalization of the salt concentrations in the River Werra have resulted in a gradual recovery of the aquatic flora. Spatial high-resolution macrophyte mappings document the spread of the aquatic vascular plants in the middle and lower River Werra. Simultaneously, the plankton blooms have declined. Changes in the composition of the algal communities including diatoms also indicated lower salinity. In addition to the salinity, high nutrient concentrations, waste water discharges and structural degradation are important stressors in the River Werra as shown by e.g. low species richness of vascular plants and the common occurrence of pollution tolerant diatoms. From the existing data it is clear that an encompassing improvement of the ecological conditions in the River Werra can only be achieved by further restoration measures considering all stressors.     

Rapid formation of hyperpycnal sediment gravity currents offshore of a semi-arid California river

Observations of sediment dispersal from the Santa Clara River of southern California during two moderately sized river discharge events suggest that river sediment rapidly formed a negatively buoyant (hyperpycnal) bottom plume along the seabed within hours of peak discharge. An array of acoustic and optical sensors were placed at three stations 1 km from the Santa Clara River mouth in 10-m water depth during January–February 2004. These combined observations suggest that fluid mud concentrations of suspended sediment (>10 g/l) and across-shore gravity currents (∼5 cm/s) were observed in the lower 20–40 cm of the water column 4–6 h after discharge events. Gravity currents were wave dominated, rather than auto-suspending, and appeared to consist of silt-to-clay sized sediment from the river. Sediment mass balances suggest that 25–50% of the discharged river sediment was transported by these hyperpycnal currents. Sediment settling purely by flocs (∼1 mm/s) cannot explain the formation of the observed hyperpycnal plumes, therefore we suggest that some enhanced sediment settling from mixing, convective instabilities, or diverging plumes occurred that would explain the formation of the gravity currents. These combined results provide field evidence that high suspended-sediment concentrations from rivers (>1 g/l) may rapidly form hyperpycnal sediment gravity currents immediately offshore of river mouths, and these pathways can explain a significant portion of the river-margin sediment budget. The fate of this sediment will be strongly influenced by bathymetry, whereas the fate of the remaining sediment will be much more influenced by ocean currents.     

On the history of chloride concentrations in the River Lippe (Germany) and the impact on the macroinvertebrates

The River Lippe is situated at the northern part of the rhenish-westphalian coal mining area, Germany and has a long history of being affected by mining water discharge. There has, however, been a massive decrease in the discharge of mining water over the past few decades. While early in the last century concentrations of up to 3500 mg l⁻¹ of chloride were observed, the mean concentration is now below 400 mg l⁻¹. At the same time the water quality has improved greatly so factors other than chloride concentration may be influencing the macroinvertebrate community.Macroinvertebrate data collected from three sites along the River Lippe was analyzed for a change in the occurrence of salt tolerant species in an area where mining water discharge ended in 2000. It was found that also during the period of discharges the macroinvertebrate community was dominated by freshwater species and therefore the impact of mining water discharges in the upper River Lippe is considered to be minor.It was also found that for some species (Nais elinguis, Bithynia tentaculata and Gammarus tigrinus) their proposed salinity preference did not correlate with their occurrence in the field. This may be an area that requires further research.     

The relationship of Irgarol and its major metabolite to resident phytoplankton communities in a Maryland marina, river and reference area

The objectives of this study were to: (1) measure water column concentrations of Irgarol 1051 and its major metabolite GS26575 annually (2004-2006) during mid-June and mid-August at 14 sites in a study area comprised of three sub-regions chosen to reflect a gradient in Irgarol exposure (Port Annapolis marina, Severn River and Severn River reference area); (2) use a probabilistic approach to determine ecological risk of Irgarol and its major metabolite in the study area by comparing the distribution of exposure data with toxicity-effects endpoints; and (3) measure both functional and structural resident phytoplankton parameters concurrently with Irgarol and metabolite concentrations to assess relationships and determine ecological risk at six selected sites in the three study areas described above. The three-year summer mean Irgarol concentrations by site clearly showed a gradient in concentrations with greater values in Back Creek (400-500 ng/L range), lower values in the Severn River sites near the confluence with Back Creek (generally values less than 100 ng/L) and still lower values (<10 ng/L) at the Severn River reference sites at the confluence with Chesapeake Bay. A similar spatial trend, but with much lower concentrations, was also reported for GS26575. The probability of exceeding the Irgarol plant 10th centile of 193 ng/L and the microcosm NOEC (323 ng/L) suggested high ecological risk from Irgarol exposure at Port Annapolis marina sites but much lower risk at the other sites. There were no statistically significant differences among the three site types (marina, river and reference) with all years combined or among years within a site type for the following functional and structural phytoplankton endpoints: algal biomass, gross photosynthesis, biomass normalized photosynthesis, chlorophyll a, chlorophyll a normalized photosynthesis and taxa richness. Therefore, based on the above results, Irgarol adverse effects predicted from the plant 10th centile and the microcosm NOEC in the high Irgarol exposure area (Back Creek/Port Annapolis marina) were not confirmed with the actual field data for the receptor species (phytoplankton). These results also highlight the importance of unconfined field studies with a chemical gradient in providing valuable information regarding the responses of resident phytoplankton to herbicides.     

Perfluorinated compounds in estuarine and coastal areas of north Bohai Sea, China

Perfluorinated compounds (PFCs) in water, sediment, soil, and biota collected from estuarine and coastal areas of the north Bohai Sea, China, were determined by use of HPLC-MS/MS. Significant concentrations of PFCs were found in water (mean: 18.4 ng/l) and biologic samples (fish: 265 ng/g dw), while concentrations of PFCs in soils and sediments were less. The predominately detected compound was perfluorooctanesulfonate (PFOS), with a maximum concentration of 30.9 ng/l in water and 791 ng/g dw in fish. Concentrations of PFCs were significantly greater in the Liaohe River system than other locations, which suggests point sources in this urbanized and industrialized region. PFOS concentrations in water and biota were both less than the reported threshold concentrations. Detection of PFCs at relatively great concentrations in various environmental matrices from this region suggested that further studies characterizing concentrations of PFCs, their sources and potential risk to both humans and wildlife are needed.     

Desalinization of running waters: III. Changes in the structure of diatom assemblages caused by a decreasing salt load and changing ion spectra in the river Wipper (Thuringia, Germany)

Salt-loaded effluents were introduced into the river Wipper during the mining period for almost a century. Beginning with the year 1990, the waste water load was strongly reduced due to the termination of the potash industry. Prior to 1990, monthly means of the chloride concentrations at times exceeded 6,000 mg l⁻¹ in the strongly polluted sections. Maximum concentrations reached twice these values. Up to 1998, mean annual chloride concentrations decreased to values below 2,000 mg l⁻¹. This led to more balanced fluctuations in salinity which had been pronounced before, depending on discharge and short-term changes in production. Similarly, the physiologically adverse ion conditions improved due to decrasing potassium and increasing calcium proportions.

In 1963/64, 1986 and 1998, samples of epilithic, epiphytic and epipsammic diatoms were taken at locations of different salinities along the river and examined for the effects of the salinization on the structure of the diatom assemblages. These structures changed in dependence on salinity. Increasing salt concentrations coincided with decreasing oligohalophilic and increasing mesohalophilic and polyhalophilic species numbers. Above a chloride concentration of about 3,000 mg l⁻¹, the proportion of the latter exceed that of the former (halobion index > 50). Corresponding to different conditions of salinization along the river, characteristic diatom assemblages occur differring from each other and which are specific for the river section. Spring and autumn aspects of the diatom assemblages show also salt-dependent differences. The assemblages found in 1998 after decrease of salinization have changed markedly in comparison to those from 1963/64 and 1986. Halobiontic species predominating formerly occurred only occasionally or not at all. They were replaced by oligohalobic-indifferent forms.

An ecological assessment of the changes was performed based on the halobion index calculated from all the samples. For the strongly salinized section of the river Wipper, a shift from -mesohalobic/polyhalobic conditions in 1963/64 and 1986 to -oligohalobic/β-mesohalobic conditions in 1998 was found. However, constant -oligohalobic conditions are still not given. With regard to the transition from -oligohalobic (limnetic) to β-mesohalobic (brackish) conditions, a maximum chloride concentration of 600 mg l⁻¹ was found. To guarantee -oligohalobic conditions, a maximum chloride concentration of 400 mg l⁻¹ should not be exceeded.     

Salt pollution of the middle and lower sections of the river Werra (Germany) and its impact on benthic macroinvertebrates

In two survey phases (2003 and 2008) organic, nutrient and salt contamination parameters have been investigated in the lower Werra in order to estimate the importance of these different kinds of pollution for the quality component of macroinvertebrates according to the European Water Framework Directive. The chemical and biological investigations have been carried out comparing a “reference” section without salt contamination with the salt contaminated section due to the potash mining industry from Vacha to Hannoversch Münden close to the mouth of the Werra. The results show that the drastic differences between the macroinvertebrate assemblages of the Werra upstream and downstream the salt contaminated sections are clearly caused by the salt load. The other kinds of chemical impacts are not responsible for the observed fundamental change within the composition of the benthic invertebrate assemblage. General degradation of stream morphology, indicated by macroinvertebrates, shows a good ecological status for the non-salt-contaminated part of the river and a bad status for the salt contaminated sites of the lower Werra.     

Recovery of interior brackish marshes seven years after the chalk point oil spill

Seven years after the April 2000 spill of 140,000 gallons of a mixture of No. 6 and No. 2 fuel oils in the Patuxent River, Maryland, heavily oiled brackish marshes showed continuing effects. Stem density and stem height were significantly lower in oiled versus unoiled sites for Spartina alterniflora but not Spartina cynosuroides habitats. In contrast, belowground biomass was significantly lower in S. cynosuroides habitats but not S. alterniflora habitats. Total PAH concentrations were up to 453 mg/kg in surficial soils (0-10 cm) and 2921 mg/kg with depth (10-20 cm). The oil had lost 22-76% of its initial PAH content after seven years, although the oil in marsh soils has undergone little to no additional weathering since Fall 2000. Based on amphipod acute toxicity tests and sediment quality guidelines, 25% of the soils in the marsh are expected to be toxic (ESB-TU_FCV values > 3.0; P_Max > 0.65).     

Three-dimensional flow patterns at the river–aquifer interface — a case study at the Danube

The three-dimensional groundwater flow patterns in a gravel bar at the Danube east of Vienna were investigated and are discussed in this paper. The observed groundwater level gradients are highly dynamic and respond very quickly to changes in the river water levels. A variably saturated groundwater model was calibrated to the data to describe the complex dynamics of flow in the gravel bar. The model results suggest that short-term (6–48 h) fluctuations of river water levels cause variations in the exchange flow rates from − 35 l/s to 82 l/s. The highest rates occur during brief infiltration after rapidly rising river water levels. Simulations of different scenarios indicate that riverbank clogging will decrease the exchange fluxes by up to 80%, while clogging of both riverbank and riverbed essentially stops the flow exchange. The groundwater model is also used to simulate the transport of a conservative tracer. The variation of river water levels over time is shown to increase the extent of the active river–aquifer mixing zone in the gravel bar. These dynamic factors significantly enhance the dilution of conservative tracer concentrations in this zone.     

The distribution of dissolved lead in the coastal waters of the East China Sea

The distribution of dissolved lead in the coastal waters of the East China Sea was investigated seasonally. The average concentrations in surface waters during the spring and autumn were 0.52 nM and 0.27 nM, respectively. In the spring, the concentration of dissolved Pb in the surface waters and bottom waters ranged from 0.13 to 1.86 nM and from 0.15 to 0.94 nM, respectively. For both the surface water and the bottom water, the highest values were observed at the Yangtze River Estuary. Seasonal variability of D-Pb between spring and autumn in the ECS was observed. These results suggested that riverine inputs and atmospheric inputs may be the main sources of lead in this area, while adsorption and co-precipitation on suspended particles at the river estuary and biological process may be the major sinks.     

Veränderungen der Diatomeenflora der Werra unter dem Einfluß des Salzgehaltes

Under the influence of the wastewaters of the potash industry the Werra river shows considerably varying salt contents (0.47 … 28.2 g/l Cl^?, annual means 4.4 … 11.4 g/l Cl^?) in dependence on the hydrological situation. Between 1982 and 1988 a total of 112 taxa of diatoms were observed. Of special interest is the occurrence of Stauroneis constricta (EHRENBERG) CLEVE, which is new for the river Werra. Its spreading upstream was observed. Compared with earlier findings as well as within each annual cycle there are observed clear changes in the species present and in the colonization structures in dependence on the salt content. The close relations between the salt content and the diatom communities are truly expressed by the index of halobic organisms. Diversity indices of 1.048 … 3.259 as well as values of 0.074 … 0.817 for evenness verify the imbalance of the colonization, without, however, revealing a relation to the salt content, except for variations of concentration which may be too sudden.     

Sediment delivery,resuspension, and transport in two contrasting canyon environments in the southwest Gulf of Lions

Multiple canyons incise the continental slope at the seaward edge of the continental shelf in the Gulf of Lions and are actively involved in the transfer of sediment from shelf to deep sea. Two canyons in the southwest region of the Gulf of Lions, Lacaze-Duthiers Canyon and Cap de Creus Canyon, were instrumented with bottom-boundary-layer tripods in their heads to evaluate the processes involved in sediment delivery, resuspension and transport. In both canyons, intense cold, dense-water flows carry sediment across the slope. In the Lacaze-Duthiers canyon head (located ∼35 km from the shoreline), dense-water cascading into the canyon was episodic. Currents were highly variable in the canyon head, and responded to interactions between the along-slope Northern Current and the sharp walls of the canyon. Inertial and other high-frequency fluctuations were associated with suspended-sediment concentrations of ∼5 mg/l. In Cap de Creus canyon head (located ∼14 km from the shoreline), downslope currents were higher in magnitude and more persistent than in Lacaze-Duthiers canyon head. Greater suspended-sediment concentrations (peaks up to 20 mg/l) were observed in Cap de Creus Canyon due to resuspension of the canyon seabed during dense-water cascading events. The similarities and contrasts between processes in these two canyon heads emphasize the importance of the interaction of currents with sharp canyon bathymetry. The data also suggest that cold, dense-water flows have more potential to carry sediment to the slope on narrow shelves, and may more efficiently transfer that sediment to the deep sea where a smooth transition between shelf and slope exists.     

Estimation of nearshore groundwater discharge and its potential effects on a fringing coral reef

Radon (²²²Rn) measurements were conducted in Shiraho Reef (Okinawa, Japan) to investigate nearshore submarine groundwater discharge (SGD_nearshore) dynamics. Estimated average groundwater flux was 2-3 cm/h (maximum 7-8 cm/h). End-member radon concentration and gas transfer coefficient were identified as major factors influencing flux estimation accuracy. For the 7-km long reef, SGD_nearshore was 0.39-0.58 m³/s, less than 30% of Todoroki River’s baseflow discharge. SGD_nearshore was spatially and temporally variable, reflecting the strong influence of subsurface geology, tidal pumping, groundwater recharge, and hydraulic gradient. SGD_nearshore elevated nearshore nitrate concentrations (0.8-2.2 mg/l) to half of Todoroki River’s baseflow -N (2-4 mg/L). This increased nearshore Chl-a from 0.5-2 μg/l compared to the typically low Chl-a (<0.1-0.4 μg/l) in the moat. Diatoms and cyanobacteria concentrations exhibited an increasing trend. However, the percentage contributions of diatoms and cyanobacteria significantly decreased and increased, respectively. SGD may significantly induce the proliferation of cyanobacteria in nearshore reef areas.     

Field experiments on remediation of coastal sediments using granulated coal ash

Field experiments were carried out to evaluate the effect of Granulated Coal Ash (GCA) on remediation of coastal sediments in terms of removing phosphates and hydrogen sulfide. Phosphate concentrations in the sediment were kept below 0.2 mg/l after the application of GCA, whereas those in the control sites increased up to 1.0 mg/l. The concentration of hydrogen sulfide in the sediment was maintained at almost zero in the experimental sites (GCA application sites) for over one year, whereas it ranged 0.1–2.4 mg S L⁻¹ in control sites. Meanwhile, individual number of benthos increased in the experimental sites by several orders of magnitude compared to the control sites. The major process involved in hydrogen sulfide removal by GCA was thought to be the increase in pH, which suppresses hydrogen sulfide formation. From our findings, we concluded that GCA is an effective material for remediating organically enriched coastal sediment.     

Responses of a coastal phytoplankton community to increased nutrient input from the Changjiang (Yangtze) River

Nutrient input from the Changjiang River (Yangtze River) has been increasing dramatically since the 1960s. At the mouth of the Changjiang River, the nitrate concentration has increased about three-fold in 40 years, from 20.5 μmol/L in the 1960s to 59.1 μmol/L in the 1980s and to 80.6 μmol/L in 1990–2004. Phosphate concentration increased by a factor of 30%, from 0.59 μmol/L in the 1980s to 0.77 μmol/L in 1990–2004. The increasing nitrate input has arisen mostly from the mid and lower reaches of the Changjiang River, where the river meets one of the most strongly developed agriculture areas in China. Responses of the coastal phytoplankton community to the increasing nutrient inputs are also seen in the available monitoring data. First, a trend of increasing phytoplankton standing stock from 1984 to 2002 appeared in the Changjiang River estuary and adjacent coastal waters, especially in late spring. Secondly, the proportion of diatoms in the whole phytoplankton community showed a decreasing trend from about 85% in 1984 to about 60% in 2000. Finally, red tides/harmful algal blooms increased dramatically in this area in terms of both number and scale. About 30–80 red tide events were recorded each year from 2000 to 2005 in the East China Sea. The scale of some blooms has been in excess of 10,000 km².     

Effects of chronic exposure to dispersed oil on selected reproductive processes in adult blue mussels (Mytilus edulis) and the consequences for the early life stages of their larvae

Mussels (Mytilus edulis) were continuously exposed to dispersed crude oil (0.015-0.25 mg/l) for 7 months covering the whole gamete development cycle. After 1 month exposure to 0.25 mg oil/l, the level of alkali-labile phosphates (ALP) and the volume density of atretic oocytes in female gonads were higher than those in the gonads of control females, indicating that oil affected the level of vitellogenin-like proteins and gamete development. Spawning of mussels was induced after 7 months oil exposure. Parental oil exposure did not affect subsequent fertilization success in clean seawater but this was reduced in 0.25 mg oil/l. Parental exposure to 0.25 mg oil/l caused both slow development and a higher percentage of abnormalities in D-shell larvae 2 days post-fertilization; reduced growth 7 days post-fertilization. These effects were greatly enhanced when larval stages were maintained at 0.25 mg oil/l. Similar studies are warranted for risk assessment prognosis.     

Diel variation of dissolved organic carbon during large flow events in a lowland river

Diel variation in dissolved organic carbon (DOC) within lotic systems has been reported on numerous occasions. However, to our knowledge there has been no published work on diel DOC variation within lowland rivers during high flow events. We sampled DOC at 4 h intervals from two sites across two distinct flow regimes in the regulated lower Namoi River, Australia. This included a large flood (mean flow 224 m³ s⁻¹ and a peak flow of 376 m³ s⁻¹) sampled every 4 h for 10 consecutive days. DOC concentrations were significantly greater at night than during the day (P < 0.05) and the mean DOC concentration was 23.4 mg L⁻¹ at night compared to 18.9 mg L⁻¹ during daylight hours. The magnitude and duration of flow within this lowland river system and the mobilisation of large quantities of allochthonous carbon appeared to play a role in increasing DOC concentration and the diel difference.     

Background aspects of lake restoration: water balance,heavy metal content,phosphorus homeostasis

Perturbations of the lake water balance, inputs of heavy metals to lakes, and intensifying fertilization of lakes through input and accumulation of phosphorus—these three classes of phenomena are among the more important background processes in lake restoration. Lake restoration consists of a series of measures animed at producing a homeostatic response of a lake system to external perturbations. The success of its implementation is affected by the morphometric and edaphic parameters of different types of lakes. The relationship between the volume (V) and mean-depth of fresh-water lakes indicates a trend of . Glacial lakes occuring on or near crystalline shields have relatively shallow depths, whereas volcanic lakes, rift valley and deep valley lakes have relatively greater depths for the same volume. For saline lakes (21 lakes, V>1 km³) that undergo cycles of expansion and shrinkage, the V to relationship is closer to power 1. Water residence times (τ) of small and big fresh-water lakes show a trend of τ approximately linear in or τ∝V^0.3. Volcanic lakes and Maare have longer residence times in comparison to other lakes of similar volumes. For the major inorganic chemical species and heavy metals, the regulatory upper-limit concentrations in drinking water in the USA and EEC are from several times to more than 100 times higher than their concentrations in a global mean river water. Only three elements (Fe, P, and Al) occur in river water at concentrations approaching such upper-limit recommendations. Rates of accumulation of phosphorus in lake water and sediments, computed as the difference between input and ouflow removal rates for 23 fresh-water lakes, are generally lower for lakes of longer water residence time. The rate of accumulation is a measure of homeostatic response of the lake system to input load: it is equivalent to the rate of all the removal processes needed to maintain phosphorus concentration in lake water at a steady state.     

Determination of transport rates in the Yellow River–Bohai Sea mixing zone via natural geochemical tracers

In light of the current problems facing the Yellow River and surrounding areas (e.g., periods of zero river discharge, increasing nitrate concentrations of the Bohai Sea), we examined the coastal mixing dynamics around the mouth of the Yellow River. Naturally occurring radium isotopes (²²³Ra, ²²⁴Ra, ²²⁶Ra, and ²²⁸Ra) and other geochemical tracers (Ba, Si, and salinity) were employed to determine river plume transport scales and rates. Barium and radium exhibit elevated concentrations within the salinity gradient where they are desorbed from particles via ion-exchange. Once they are added to the system, they decrease offshore from dilution with lower concentration Bohai Sea water, and in the case of ²²⁴Ra and ²²³Ra, by radioactive decay. Using radium “ages” to assess the dissolved material transport scales and rates proved to be a useful tool in this environment. The ages based on the ²²⁴Ra/²²⁸Ra activity ratio increased gradually until salinities reached ∼25 when they rapidly increased due to decreased mixing at higher salinities. Integrated net transport rates through the salinity front ranged from 1.4 to 1.6 cm/s and did not vary significantly with river discharge. Thus, tidal mixing appears to dominate in this system, at least over the range of discharges investigated (80–600 m³/s). Determining the temporal scale of flow across the coastal zone in this region is a valuable first step toward examining whether the Yellow River is contributing to the increasing inorganic nitrogen concentrations in the central Bohai Sea.     

Effects of suspended particles on the growth of two dominant phytoplankton species of Bohai Bay,China

Suspended particles (SP) are increasing dramatically in Bohai Bay, China and may affect the growth and composition of phytoplankton assembly. To determine the effects of SP on the growth of two dominant phytoplankton species, Phaeodactylum tricornutum Bohlin and Gymnodinium sp., we cultured and tested their growth characteristics under SP concentrations ranging from 0 g L⁻¹ to 0.8 g L⁻¹. Our results show that the increase in the SP concentrations results in significant decrease in the maximum cell densities and the maximum specific growth rates of these two species. The half maximal inhibitory concentration (IC₅₀) of SP to P. tricornutum and Gymnodinium sp. were 1.07 g L⁻¹ and 0.68 g L⁻¹ respectively, indicating the inhibitory effect of SP on Gymnodinium sp. was greater than on P. tricornutum. These results suggest that SP inhibits the growth of the two algal species and P. tricornutum is more tolerant to SP than Gymnodinium sp.