Dynamics of stream nitrate sources and flow pathways during stormflows on urban,forest and agricultural watersheds in central Pennsylvania,USA

Understanding the influence of storm events on nitrate (NO₃^?) dynamics is important for efficiently managing NO₃^? pollution. In this study, five sites representing a downstream progression of forested uplands underlain by resistant sandstone to karst lowlands with agricultural, urban and mixed land‐use were established in Spring Creek, a 201 km² mixed land‐use watershed in central Pennsylvania, USA. At each site, stream water was monitored during six storm events in 2005 to assess changes in stable isotopes of NO₃^? (δ¹⁵N‐NO₃^? and δ¹⁸O‐NO₃^?) and water (δ¹⁸O‐H₂O) from baseflow to peakflow. Peakflow fractions of event NO₃^? and event water were then computed using two‐component mixing models to elucidate NO₃^? flow pathway differences among the five sites. For the forested upland site, storm size appeared to affect NO₃^? sources and flow pathways. During small storms (<35 mm rainfall), greater event NO₃^? fractions than event water fractions indicated the prevalence of atmospheric NO₃^? source contributions at peakflow. During larger storms (>35 mm rainfall), event NO₃^? fractions were less than event water fractions at peakflow suggesting that NO₃^? was flushed from stored sources via shallow subsurface flow pathways. For the urbanized site, wash‐off of atmospheric NO₃^? was an important NO₃^? source at peakflow, especially during short‐duration storms where event water contributions indicated the prevalence of overland flow. In the karst lowlands, very low fractions of event water and even lower fractions of event NO₃^? at peakflow suggested the dominance of ground water flow pathways during storms. These ground water flow pathways likely flushed stored NO₃^? sources into the stream, while deep soils in the karst lowlands also may have promoted NO₃^? assimilation. The results of this study illustrated how NO₃^? isotopes and δ¹⁸O‐H₂O could be combined to show key differences in water and NO₃^? delivery between forested uplands, karst valleys and fully urbanized watersheds. Copyright © 2009 John Wiley & Sons, Ltd.     

Impact of the magnitude and frequency of debris‐flow events on the evolution of an alpine alluvial fan during the last two centuries: responses to natural and anthropogenic controls

The dynamics and the surface evolution of a post‐LGM debris‐flow‐dominated alluvial fan (Tartano alluvial fan), which lies on the floor of an alpine valley (Valtellina, Northern Italy), have been investigated by means of an integrated study comprising geomorphological field work, a sedimentological study, photointerpretation, quantitative geomorphology, analysis of ancient to modern cartography and consultation of historical documents and records. The fan catchment meteoclimatic, geological and geomorphological characteristics result in fast rates of geomorphic reorganization of the fan surface (2 km²). The dynamics of the fan are determined by the alternation of low‐return period catastrophic alluvial events dominated by non‐cohesive debris flows triggered by extreme rainstorms which caused aggradation and steepening of the fan and avulsion of its main channel, with periods of low to moderate streamflow discharge punctuated by low‐ to intermediate‐magnitude flood events, causing slower but steady topographic reworking. The most ancient parts of the fan surface date back at least to the first half of the 19th century, but most of the fan surface has been restructured after 1911, mainly during the debris‐flow‐dominated events of 1911 and 1987. Phases of rapid fan toe incision and fan degradation have been recognized; since the 1930s or 1940s, the Tartano fan has been subjected to a state of deep entrenchment and narrowing of the main trunk channel and distributary area. Post‐Little Ice Age climate change and present‐day surface uplift rates have been considered as possible explanations for the observed geomorphic evolution, but tectonic or climatic controls cannot account for the order of magnitude of the erosional pace. Anthropogenic controls plausibly override the natural ones: in particular, the building of a dam in the late 1920s, about 2 km upstream of the fan, seems to have triggered fan dissection, having altered the sediment discharge through sediment retention. Copyright © 2011 John Wiley & Sons, Ltd.