东海沉积物中磷的存在形态及其环境意义

By means of SEDEX, ASPILA and XRF, depth-dependent changes of different phosphorus forms in sediment cores from specific areas of the offshore Changjiang Estuary (Yangtze Estuary) in 1998 were analyzed. Results show that contents of total phosphorus (TP), organic-phosphorus (OP) and iron-phosphorus (Fe-P) decreased down-core, while those of absorbed-phosphorus (Ad-P) andcalcium-phosphorus (Ca-P) increased. The distribution tendency of detritus-phosphorus (De-P) is not obvious. Results also show that TP, Fe-P and OP contents at Meso station of the Changjiang Estuary and Hangzhou Bay are higher than that of the other stations. This suggests that the pollutants carried by the Changjiang and the Qiantang rivers from inland have affected the natural environment inoffshore area. TP, Fe-P and OP contents of each station become higher from bottom to top, indicating the amount of the terrestrial pollutants carried by the two rivers has been enhanced since the last 30-50 years. Ad-P, Ca-P, Fe-P and OP are all active phosphorus in sediments, and their re-cycling in sediment is closely related to each other.     

扎龙湿地表层沉积物磷的赋存形态及空间分布特征

沉积物中不同形态的磷具有不同的地球化学行为和生物有效性,其含量和分布特征包含着许多环境地球化学信息。该文利用SMT法对扎龙湿地表层沉积物中总磷(TP)及各形态磷进行了分析,探讨其空间分布特征及控制因素。结果表明,扎龙湿地表层沉积物TP含量高,接近于富营养化严重的太湖和巢湖,主要分布于核心区和东北部;无机磷(IP)含量稍高于有机磷(OP),其分布特征都与TP相似。IP中的钙结合态磷(Ca-P)和铁铝结合态磷(Fe/Al-P)空间分布差异性较小,Ca-P含量占IP的59.2%。TP及各形态磷含量受粒度、有机质、pH及溶解氧等环境因子的影响,造成扎龙湿地水体富营养化的污染物质主要来自外源;但随着湿地盐碱化加重、生态环境破坏及植被覆盖度下降,沉积物内源磷的释放将成为扎龙湿地水体富营养化的重要来源,将直接加剧水体富营养化程度,尤其增加核心区水体富营养化的风险。     

库布齐沙漠恩格贝沙样中磷的化学赋存形态

通过采用七步连续萃取法对库布齐沙漠恩格贝沙样磷形态的分析,揭示了恩格贝沙样中磷的各种存在形态及含量分布。结果表明：所取沙样中总磷 (TP) 含量在94.33~251.04 μg·g-1 之间,且含量随沙样粒径的减小而增大。无机磷（IP）含量在 88.75~234.83 μg·g-1 之间,占TP含量的 94.08%~93.54%,其中以自生钙结合磷（Ca-P）和原生碎屑磷（De-P）为主,二者占到TP 含量的82.81%~86.13%。有机磷（Or-P）含量在5.58~16.21 μg·g-1之间,占总磷的5.91%~6.46%。在所有不同粒径沙样中各形态磷含量的高低顺序为：原生碎屑磷（De-P）、自生钙结合磷（Ca-P）、有机磷（Or-P）、吸附态磷（Ads-P）、铁磷（Fe-P）、铝磷（Al-P）、闭蓄态磷（Obs-P）,其中Obs-P含量极微。在所取沙样中 Ads-P、Fe-P、De-P、Or-P、Al-P、Obs-P 各自含量都随颗粒物粒径的减小而增大,但Al-P和Obs-P的变化幅度很小。而Ca-P含量受粒径影响较小,粗颗粒沙样中含量略高一些。     

准噶尔盆地灰漠土无机磷形态及磷吸附特性研究

选择新疆准噶尔盆地灰漠土作为研究对象,通过测定灰漠土中不同形态的无机磷素含量并进行土壤磷素等温吸附实验,研究灰漠土中各形态无机磷素的有效性和土壤磷吸附特征。结果表明,灰漠土中无机磷形态主要是Ca-P,占全磷含量75%以上,且以Ca₁₀-P形式为主,其次为Ca₈-P和Ca₂-P,无机磷中Al-P、Fe-P和O-P含量较少。全剖面中随着土层深度增加,Ca₂-P、Ca₈-P和Al-P占全磷总量的比例减少,Ca₁₀-P占全磷总量则有所增加,0~20 cm土层全磷和Olsen-P含量最高,分别平均为926 mg·kg^-1和51.54 mg·kg^-1。统计分析表明Ca₂-P、Al-P是最有效的磷源,Ca₈-P和Fe-P是第二有效磷源,O-P和Ca₁₀-P则是作物的潜在磷源。利用Langmuir方程拟合灰漠土的磷等温吸附曲线,得出土壤最大吸磷量（Xm）为957±629 mg·kg^-1,吸附参数（K）为149.285±89.225;灰漠土的粘粒含量对Xm影响最大,其次是有机质,pH值影响最小。     

长江中游网湖沉积物营养元素变化特征及其影响因素

在放射性核素¹³⁷Cs和²¹⁰Pb精确计年的基础上,建立了长江中游网湖近代沉积物年代序列。通过对沉积物中TOC、TN、TP、孢粉、重金属元素、粒度等指标的测定,结合相关文献资料,分析了百年来网湖沉积物中营养元素的分布特征,物源变化以及主控因子。结果表明:百年来网湖沉积物中TN和TOC含量显著相关,呈不断上升趋势,存在2个明显的演化阶段,主控因子为流域人类活动强度,气候波动对其有影响,但影响不大。TP的变化与TN和TOC明显不同,波动较大,规律不明显,主要受人类活动强度以及径流侵蚀输移入湖物质变化两大因子控制。     

长江河口最大浑浊带水沙输运机制分析

本文根据大量的实测资料，运用机理的分析方法，讨论了长江口最大浑浊带中各输沙项的作用。结果表明，平均流输沙、斯托克斯漂流效应、潮汐捕集以及垂向不流是净输沙的主要部分。     

长江口泥质区的季节性沉积效应

1IntroductionThe continental shelf of the East China Sea (ECS) is one of the widest shelves in the world. There are several mud areas distributing like patches on a background of widespread coarser ambient sediments of silt and sand on the continental shelf of the ECS. The coastal mud area can be divided into two parts, namely, the Changjiang Estuary mud area (CEMA) in the north and Zhejiang coastal mud area in the south. Between these two parts there is a silt area (Figure 1). The CE…     

Seasonal variation of sedimentation in the Changjiang Estuary mud area

Seasonal distributions of suspended matter and their sedimentary effect on the Changjiang Estuary mud area of the East China Sea were discussed, based on three cruise data of total suspended matter, temperature and salinity collected from the Changjiang Estuary and its adjacent area in summer and winter. The results show that the basic pattern of distributions of suspended matter in the study area is almost the same in winter and in summer. Sediments from Changjiang (Yangtze River) to the sea are chiefly trapped to the west of 123o15'E due to a strong obstruction of the Taiwan Warm Current. This suggests that these sediments are mainly transported and deposited in the inner shelf. The sediment supply, Taiwan Warm Current, and Zhejiang Coastal Current show a strong seasonal variation, which results in a strong seasonal variation of the sedimentary effect on this mud area. This mud area is a "sink" of the Changjiang's sediment discharge to the sea and its sedimentation is stronger in summer and weaker in winter.     

泥沙解吸重金属污染物动力学模式研究

从吸附动力学方程和质量守恒出发,导得静态试验中泥沙解吸重金属污染时,单位重量泥沙剩余吸附量和水相浓度随时间变化的计算公式,进而导得单位重量泥沙剩余平衡吸附量和水相平衡浓度的计算公式。在此基础上,结合试验进一步研究了泥沙解吸重金属污染物的动力学模式。     

Linking subaerial erosion with submarine geomorphology in the western Ionian Sea (south of the Messina Strait), Italy

Sediment supplied by continental sources is commonly suspected to have exerted a strong influence on the development of canyons and other morphological features on the continental slopes, but rarely is the sediment supply known sufficiently quantitatively to test this link. Here, we outline an area where offshore morphology, in the western Ionian Sea, may be linked to estimated sediment fluxes produced by subaerial erosion in NE Sicily and SW Calabria. Shelves in this area are narrow (<1 km), and the bathymetry shows that rivers and adjacent submarine channels are almost directly connected with each other. Integrated topographic analyses were performed on a merged digital elevation model (DEM) of ASTER data for subaerial topography and multibeam sonar data for submarine bathymetry. Spatial variations in sediment fluxes from onshore erosion were assessed using a variety of methods, namely: long‐term sediment flux from Pleistocene uplift rates, decadal sediment flux from landslide occurrences and published long‐term exhumation rates from ¹⁰Be cosmogenic nuclide concentrations. Submarine channels associated with rivers delivering larger sediment fluxes have broad channels, high relief and smooth concave‐upward longitudinal profiles. Conversely, submarine channels that lie offshore small‐flux rivers have straight longitudinal profiles, low relief and steep gradients. Where river catchments supply a greater sediment flux offshore, shelves tend to be wider (ca. 400 m) and submarine channels have gentler gradients. In contrast, where catchments supply less sediment flux, shelves are narrow (250–300 m) and offshore channel gradients are steeper. The variation of submarine morphology with tectonic uplift rate was also studied, but we find that, unlike onshore terrains where tectonics is commonly an important factor influencing channel morphology, in the submarine landscapes, sediment flux appears to dominate here.     

未来长江口流量和潮位变化及其对河口水质的影响

本文通过长江口实测氯度与流量和潮位资料的相关分析,预估了未来河口水质的变化。计算表明,当大通站下泄流量不足13×10³m³/s时,未来东线调水及海平面上升,将使长江口南支河段水质严重恶化;三峡水库建成后,枯季1-3月增加下泄水量虽可抵消东线调水的影响,但在水库蓄水的10月遇枯水年分,水质将大幅度下降。     

长江口外海滨悬沙分布及扩散特征

长江口外海滨地区是陆海相互作用显著的区域,该区域复杂的水流等动力因素和地形条件决定了悬沙分布和扩散的特点。本文利用大量实测资料,对口外海滨地区悬沙的分布特征进行了综合分析,研究结果表明,平面分布不均,西高东低,南高北低,高低相差悬殊是长江口外水域悬沙平面分布的主要特点。枯季自西向东含沙量均匀减小,等值线分布较为稀疏。垂向涨落潮含沙量也表现出不同的分布特征,在口外的中西部水域垂向扩散系数较大,水体垂向混合程度均匀;垂向混合程度加强,水体含沙量也随之显著增加,这也造就了口外的南北两个高含沙区。     

长江口泥质区的季节性沉积效应

利用长江口泥质区及其邻近海域夏季和冬季的悬浮体、温度和盐度资料,就长江口泥质区悬浮体的季节性分布和沉积效应进行探讨。由于台湾暖流的强烈阻隔作用,夏季和冬季长江入海的泥沙基本滞留在123^o15'E以西的内陆架进行搬运和沉积。长江入海沉积物供应量、台湾暖流、浙江沿岸流和长江冲淡水具有明显的季节性变化规律,致使长江口泥质区的沉积效应具有强烈的季节性,冬季沉积作用弱,夏季沉积作用强。该泥质区是长江入海沉积物的“汇聚区”,其中冬季的沉积物汇聚量显著小于夏季。长江口泥质区和济州岛西南泥质区的沉积过程变化都具有季节性,但有其各自的鲜明特色。     

长江口外海域沉积物中有机物的来源及分布

通过分析长江口外海域不同区域有机碳和氮的分布特征及其影响因素,了解了底部沉 积物中有机碳和氮同位素的生物地球化学特征,探讨二者对长江口外海域底部沉积物中有机 物来源的指示意义。运用质量混合模型,计算了长江输入的陆源有机物的贡献及其空间变化。结果表明,长江口外海域沉积物中TOC 和TN 的分布和东海陆架的环流体系有着密切关系, 与环流的分布相对应,如果大致沿31^oN 和123^oE 作为分界线, 整个研究区的TOC 和TN 的分布可划分为4 个具有不同分布特征的区域。TOC、TN、δ¹³C 和δ¹⁵N 分别与沉积物的平均粒 径呈线性相关关系,因此,粒度效应是控制长江口外海域沉积物中有机物分布和稳定同位素 碳、氮的一个重要因素。研究区内的C/N 比值能够在一定程度上体现有机物的来源信息,但δ¹⁵N 表现出了与C/N 和δ¹³C 不同的区域分布和变化特征。陆源有机物来源比重较高的区域与 长江口外海域赤潮突发频率最高的地区相对应。长江口附近沉积物中的陆源有机物来源最高, 超过了50%,且等值线呈舌状向东北方向凸出,表明了长江冲淡水的影响。陆源颗粒态有机物沉海底后,要不断经历早期成岩作用和生物作用,因此在在相同地点,陆源有机物对沉积物中有机物的贡献,要明显小于对悬浮颗粒态有机物的贡献。     

温州三垟湿地底泥氮、磷含量及其对水质的影响

为探讨温州三垟湿地底泥中氮、磷营养盐含量及其对水质的影响,测定了三垟湿地水体、底泥中的氮、磷含量。结果表明,三垟湿地底泥中富含氮、磷等营养盐,当氧化还原环境发生变化时,底泥可成为水体的主要污染源;底泥中的全氮、全磷若有1％释放,则会使水体中的总氮增加0．63—3．10mg／L,总磷增加0．94—4．70mg／L;若一次释放,则会使水体中的总氮增加62．50～310．00mg／L,总磷增加94．13～470．00mg/L;因此在当前情况下,即便切断外源污染,三垟湿地水体仍将长期处于富营养化状态。     

A geochemical record of recent anthropogenic nutrient loading and enhanced productivity in Lake Nansihu, China

Total organic carbon (TOC), total nitrogen (TN), stable carbon and nitrogen isotopes (δ¹³C, δ¹⁵N), total phosphorus (TP) and organic phosphorus (OP) were measured in surface sediments and two short cores (DU-3 and WS-4) from Lake Nansihu, China to infer historical changes in anthropogenic nutrient inputs and corresponding shifts in lake primary productivity. Results indicate that organic matter preserved in the sediments is mainly autochthonous and that analyzed sediment variables were affected little by post-burial diagenesis. Increasing TOC, TN, OP and TP concentrations since the 1940s reflect increased P loading and elevated lake productivity. The δ¹³C values varied from ?21.5 to ?26.6‰ in the two sediment cores. Values were relatively more negative before the 1940s, but thereafter increased until the mid-1980s, reflecting elevated lake productivity. Since the mid-1980s, δ¹³C values remained relatively constant in core WS-4 and decreased in core DU-3, perhaps reflecting a change in the phytoplankton community. The δ¹⁵N values ranged from ?0.5 to 1.3‰ in core DU-3 and from 1.2 to 2.5‰ in core WS-4 before the mid-1980s, and increased to between 2.1 and 8.0‰ and 5.2 and 7.8‰, respectively, thereafter. Topmost sediments in the two cores display δ¹⁵N values similar to those recorded in the surface sediments (5.5–7.5‰). Higher δ¹⁵N values in recent deposits correspond to greater nitrogen concentration in water, and likely indicate anthropogenic nitrogen input, mainly from human and animal wastes.     

长江上游重点产沙区产沙量对人类活动的响应

对金沙江屏山站、嘉陵江北碚站、宜昌站20世纪50年代以来的输沙量和含沙量进行分析。结果表明,在年径流量相同的情况下,由于大规模矿山、钢铁工业、交通建设增加水土流失,屏山站1976~1996年年产沙量要高于1954~1976年。与此相反,由于修筑水库、塘坝拦沙,修建梯田、恢复植被减少侵蚀,北碚站1983~1996年年产沙量要大大低于1954~1982年;宜昌站1985~1996年年产沙量也低于1954~1984年。北碚、宜昌两站都存在一个使水利、水土保持减沙量为0的年径流量临界值,北碚站和宜昌站这一临界值分别为1142×10⁸m³和4800×10⁸m³。     

长江口水沙入海通量的观测与分析

在长江口用声学多普勒流速剖面仪（ADCP）进行走航式断面观测,结果表明,采集水样获取的悬沙浓度与ADCP记录的声学信号（后向散射强度）之间存在显著相关关系,因此可据ADCP声学数据获得沿观测断面的高时空分辨率的悬沙浓度剖面。分析结果表明．在徐六泾附近断面以往复流占优势．大潮期间单位时间最大水、悬沙通量值出现于涨潮期．落潮历时较长．落潮期水、悬沙通量分别大于涨潮期水、悬沙通量,净通量向海。长江口南槽拦门沙外侧主要为旋转流．涨潮期间内的水、悬沙通量均分别大于落潮期间的水、悬沙通量。2003年11月12日的观测结果表明．潮周期内通过徐六泾断面向海输运的水与悬沙通量分别为10^9m^3和10^8kg量级：径流量与悬沙输运率分别为10^4m^3／s和10^3kg／s量级。1998年以来徐六泾ADCP流量观测数据与同时间的大通径流量之间存在着显著的相关关系．故可由大通径流量估算徐六泾径流量。作为长江人海径流量．以作为历史资料整编的一种手段。结果表明,长江人海年径流总量略大于大通年径流总量：而在枯水期间人海径流量小于大通径流量。     

黄河口海岸线演变时空特征及其与黄河来水来沙关系

黄河是世界上含沙量最高的河流 ,每年向河口三角洲及附近海域输送数亿吨泥沙 ,使得黄河口地区成为世界上海岸线变迁最快的地区。本文以 1976年黄河改道清水沟流路以来 2 0景多时相遥感影像为主要数据源 ,经过几何精校正与配准 ,形成相对完整时间序列的遥感影像集。在此基础上 ,对影像进行监督分类处理后自动提取海岸线 ,通过GIS叠加分析 ,剖析了现行黄河河口地区海岸线演变的时空动态特征。最后 ,结合利津水文站水文统计资料 ,探讨了黄河口海岸线演变与黄河来水来沙条件之间的关系 ,并就黄河口未来水沙条件初步预测了其演变趋势     

长江上游干支流近期水沙变化及其与水库修建的关系

基于水文站实测的长系列水沙资料,运用统计方法研究了长江上游干支流的近期水沙变化.屏山站年输沙量的变化自1999年以后开始减小,扭转了1980～1998年的增加趋势.高场站年输沙量由1990～2000年的减小趋势,变化为2000～2007年的增大趋势.北碚站的年输沙量呈进一步减少的趋势.武隆站年输沙量改变了1990～2000年的增加趋势,2000～2007年显著减小.宜昌站的年输沙量延续了从20世纪80年代中期以来的减少趋势,2002～2007年急剧减小.采用输沙量-径流最双累积曲线方法进行了分析,发现各站双累积曲线上最近一次转折点的出现,均与水库的修建有关.基于双累积曲线估算了近期各站的减沙量(或增沙量).研究还发现,近期屏山、北碚、武隆、宜昌4站含沙量均呈现减小趋势,与水库的拦沙作用密切相关.但是,岷江近期水电梯级开发的大规模展开,巨量弃土、弃渣进入河道,导致了2002～2007年间含沙量的增大.建立了宜昌站年输沙量与长江上游流域内累计水库库容量及宜昌站年径流量之间的回归方程,估算出它们对于长江上游产沙量变化的贡献率分别为71.4%和28.6%.这表明,水库拦沙是导致长江上游产沙量减小的主要原因.