Tolerance of allogromiid Foraminifera to severely elevated carbon dioxide concentrations: Implications to future ecosystem functioning and paleoceanographic interpretations

Increases in the partial pressure of carbon dioxide (pCO₂) in the atmosphere will significantly affect a wide variety of terrestrial fauna and flora. Because of tight atmospheric–oceanic coupling, shallow-water marine species are also expected to be affected by increases in atmospheric carbon dioxide concentrations. One proposed way to slow increases in atmospheric pCO₂ is to sequester CO₂ in the deep sea. Thus, over the next few centuries marine species will be exposed to changing seawater chemistry caused by ocean–atmospheric exchange and/or deep-ocean sequestration. This initial case study on one allogromiid foraminiferal species (Allogromia laticollaris) was conducted to begin to ascertain the effect of elevated pCO₂ on benthic Foraminifera, which are a major meiofaunal constituent of shallow- and deep-water marine communities. Cultures of this thecate foraminiferan protist were used for 10–14-day experiments. Experimental treatments were executed in an incubator that controlled CO₂ (15 000; 30 000; 60 000; 90 000; 200 000 ppm), temperature and humidity; atmospheric controls (i.e., ~ 375 ppm CO₂) were executed simultaneously. Although the experimental elevated pCO₂ values are far above foreseeable surface water pCO₂, they were selected to represent the spectrum of conditions expected for the benthos if deep-sea CO₂ sequestration becomes a reality. Survival was assessed in two independent ways: pseudopodial presence/absence and measurement of adenosine triphosphate (ATP), which is an indicator of cellular energy. Substantial proportions of A. laticollaris populations survived 200 000 ppm CO₂ although the mean of the median [ATP] of survivors was statistically lower for this treatment than for that of atmospheric control specimens. After individuals that had been incubated in 200 000 ppm CO₂ for 12 days were transferred to atmospheric conditions for ~ 24 h, the [ATP] of live specimens (survivors) approximated those of the comparable atmospheric control treatment. Incubation in 200 000 ppm CO₂ also resulted in reproduction by some individuals. Results suggest that certain Foraminifera are able to tolerate deep-sea CO₂ sequestration and perhaps thrive as a result of elevated pCO₂ that is predicted for the next few centuries, in a high-pCO₂ world. Thus, allogromiid foraminiferal “blooms” may result from climate change. Furthermore, because allogromiids consume a variety of prey, it is likely that they will be major players in ecosystem dynamics of future coastal sedimentary environments.     

Molecular cores of the high-latitude cloud MBM 40

Towards the high-latitude cloud MBM 40, we identify 3 dense molecular cores of M0.2–0.5 M, and sizes of 0.2 pc in diameter embedded in the H I cloud of 8 M which is observed to be extended along the northeast–southwest direction. The molecular cloud is located almost perpendicularly to the H I emission. We confirm the previous result of Magnani et al. that MBM 40 is not a site for new star formations. We found a very poor correlation between the H I and the IRAS 100 μm emissions, but the CO (1–0) and 100 μm emissions show a better correlation of W_CO/I₁₀₀=1±0.2 K km s⁻¹ (MJy sr⁻¹)⁻¹. This ratio is larger by a factor of ≥5 than in dense dark clouds, which may indicate that the CO is less depleted in MBM 40 than in dense dark clouds.     

Effects of a 2 × CO2 climate on two large lake systems: Pyramid Lake, Nevada, and Yellowstone Lake, Wyoming

The possible effects of trace-gas induced climatic changes on Pyramid and Yellowstone Lakes are assessed using a model of lake temperature. The model is driven by years of hourly meteorological data obtained directly from the output of double-CO₂ experiments (2 × CO₂) conducted with a regional climate model nested in a general circulation model. The regional atmospheric model is the climate version of the National Center for Atmospheric Research/Pennsylvania State University mesoscale model, MM4.Average annual surface temperature of Pyramid Lake for the 2 × CO₂ climate is 15.5 ± 5.4°C (±1 σ), 2.8°C higher than the control. Annual overturn of the lake ceases as a result of these higher temperatures for the 2 × CO₂ climate. Evaporation increases from 1400 mm yr⁻¹ in the control to 1595 mm yr⁻¹ in the 2 × CO₂ simulation, but net water supplied to the Pyramid Lake basin increases from −6 mm yr⁻¹ in the control to +27 mm yr⁻¹ in the 2 × CO₂ simulation due to increased precipitation.For the open water periods, the average annual surface temperature of Yellowstone Lake is 13.2 ± 5.1°C for the 2 × CO₂ climate, a temperature 1.6°C higher than the control. The annual duration of ice cover on the lake is 152 days in the 2 × CO₂ simulation, a reduction of 44 days relative to the control. Warming of the lake for the 2 × CO₂ climate is mostly confined to the near-surface. Simulated spring overturn for the 2 × CO₂ climate occurs earlier in the year and fall overturn later than in the control. Evaporation increases from 544 mm yr⁻¹ to 600 mm yr⁻¹ in the 2 × CO₂ simulation, but net water supplied to the Yellowstone Lake basin increases from +373 mm yr⁻¹ in the control to +619 mm yr⁻¹ due to increased precipitation. The effects of these climatic changes suggest possible deterioration of water quality and productivity in Pyramid Lake and possible enhancement of productivity in Yellowstone Lake.     

Stable carbon isotope ratios in tree rings of co-occurring species from semi-arid tropics in Africa: Patterns and climatic signals

Although several proxies have been proposed to trace the course of environmental and climatological fluctuations, precise paleoclimate records from the tropics, notably from Africa are still sorely lacking today. Stable carbon isotopes (δ¹³C) in tree rings are an attractive record of climate. In this study, the patterns and climatic signals of δ¹³C ratios were determined on tree rings of deciduous (Acacia senegal, Acacia tortilis, Acacia seyal) and an evergreen (Balanites aegyptiaca) species, from a semi-arid Acacia Woodland in Ethiopia. δ¹³C inter-annual patterns are synchronous among the co-occurring species. A declining trend with time was observed in δ¹³C, notably for B. aegyptiaca, which could be due to anthropogenic increases in atmospheric CO₂ concentration and decrease in atmospheric δ¹³C. Tree ring δ¹³C values of all the species revealed significant negative correlation with precipitation amount but not with temperature and relative humidity. The δ¹³C series of the deciduous species shows a higher correlation (r = − 0.70 to − 0.78) with precipitation than the evergreen species (r = − 0.55). A master δ¹³C series, composed of the average of the three Acacia species, displayed stronger significant correlation (r = − 0.82) than any of the individual species δ¹³C series. The weak relationship between temperature and δ¹³C in this study indicates that photosynthetic rate is not a significant factor. Moisture stress, however, may have a direct impact on the stomatal conductance and explain the strong negative relationship between δ¹³C and precipitation. The results demonstrate the potential of δ¹³C in tree rings to reflect physiological responses to environmental changes as a vehicle for paleoclimatic reconstruction, which is important to understand tree response to past and future climate change.     

The significance of coral reefs as global carbon sinks— response to Greenhouse

Coral reefs are net sinks for C, principally as CaCO₃ accretion. It is possible to predict quite accurately the rate of production, given adequate information about any particular reef environment. The best data set for an extensive region is that for the Great Barrier Reef (GBR). Careful analysis of this region and the incorporation of previously documented present day system calcification rates suggest net production (G) from G = 1 (kg CaCO₃ m⁻² yr⁻¹) for fringing reefs, to G = 1.9 for planar (infiled platform) reefs, G = 3 for ribbon reefs and lagoonal reefs. The 20,055 km² of reefs in the GBR are thus estimated to average G = 2.4, resulting in a total production of 50 million tonnes yr⁻¹. In a 50–100 year Greenhouse scenario of rising sealevel, we predict that recolonisation of present day reef flats will be extensive and prolific. Production will increase substantially, and this could be by as much as 40% (ranging from 0% for deep shoals to 180% for fringing reefs) to give 70 million tonnes yr⁻¹ if the rate of sealevel rise reaches or exceeds 6–8 mm yr⁻¹We estimate 115,000 km² of oceanic atolls worldwide. Drawing on points equivalence from the detailed analysis of the GBR, we estimate the atolls presently produce 160 million tonnes yr⁻¹. We predict that a similar 40% increase could be possible in the next 100 years or so resulting in a production of 220 million tonnes.Accepting an existing estimate of 617,000 km² for reefs worldwide, drawing from our projections from the GBR and the atolls, and making some assumptions about the remaining reef types (we suggest fringing reefs to dominate) we estimate global reef production at the present time to be 900 million tonnes yr⁻¹. Within the next 100 years or so, we suggest this rate could almost double to 1800 million tonnes. In the long term (several centuries) we predict that the continuing trend of recolonisation, particularly of fringing and planar reefs could result in the production of > 3000 million tonnes yr⁻¹ if rates of sealevel rise approaching or exceeding 6–8 mm yr⁻¹ are achieved. Eventually (> 500 yr), reefs could actually “drown” due to inability to match the rate of sealevel increase if that rate significantly exceeds 6–8 mm yr⁻¹.Thus, coral reefs at present act as a sink for 111 million tonnes C yr⁻¹, the equivalent of 2% of present output of anthropogenic CO₂. In the short term Greenhouse scenario (100 yr) we predict this could increase to the equivalent of 4% of the present CO₂ output. In the much longer term (several centuries), if all trends continue, this could increase to the equivalent of as much as 9% of the present CO₂ output.Unfortunately, we also predict that this considerable sink for C will be most likely of negative value in alleviating Greenhouse because of the immediate effect of CaCO₃ precipitation is to raise the P_CO2 of the surface oceans — ie, ot encourage CO₂ efflux to the atmosphere. We do not attempt to quantify this effect.Other Greenhouse changes such as seawater temperature increase, changes in cloud cover, increased rainfall and runoff, increased storm activity, and changes in dissolved CO₂ concentration and surface ocean circulation may complicate the reef response. However, we suggest that sealevel rise will be the dominant influence, at least during the next 100 years or so.     

Greenhouse gas emissions from a managed grassland

Managed grasslands contribute to global warming by the exchange of the greenhouse gases carbon dioxide, nitrous oxide and methane. To reduce uncertainties of the global warming potential of European grasslands and to assess potential mitigation options, an integrated approach quantifying fluxes from all three gases is needed. Greenhouse gas emissions from a grassland site in the SE of Scotland were measured in 2002 and 2003. Closed static chambers were used for N₂O and CH₄ flux measurements, and samples were analysed by gas chromatography. Closed dynamic chambers were used for soil respiration measurements, using infrared gas analysis. Three organic manures and two inorganic fertilizers were applied at a rate of 300 kg N ha⁻¹ a⁻¹ (available N) and compared with a zero-N control on grassland plots in a replicated experimental design. Soil respiration from plots receiving manure was up to 1.6 times larger than CO₂ release from control plots and up to 1.7 times larger compared to inorganic treatments (p<0.05). A highly significant (p<0.001) effect of fertilizer and manure treatments on N₂O release was observed. Release of N₂O from plots receiving inorganic fertilizers resulted in short term peaks of up to 388 g N₂O–N ha⁻¹ day⁻¹. However losses from plots receiving organic manures were both longer lasting and greater in magnitude, with an emission of up to 3488 g N₂O–N ha⁻¹ day⁻¹ from the sewage sludge treatments. During the 2002 growing season the cumulative total N₂O flux from manure treatments was 25 times larger than that from mineral fertilizers. CH₄ emissions were only significantly increased (p<0.001) for a short period following applications of cattle slurry. Although soil respiration in manure plots was high, model predictions and micrometeorological flux measurements at an adjacent site suggest that all plots receiving fertilizer or manure acted as a sink for CO₂. Therefore in terms of global warming potentials the contribution of N₂O from manure treatments becomes particularly important. There were considerable variations in N₂O and CO₂ fluxes between years, which was related to annual variations in soil temperature and rainfall.     

The natural latitudinal distribution of atmospheric CO2

Although poorly understood, the north–south distribution of the natural component of atmospheric CO₂ offers information essential to improving our understanding of the exchange of CO₂ between the atmosphere, oceans, and biosphere. The natural or unperturbed component is equivalent to that part of the atmospheric CO₂ distribution which is controlled by non-anthropogenic CO₂ fluxes from the ocean and terrestrial biosphere. Models should be able to reproduce the true north–south gradient in CO₂ due to the natural component before they can reliably estimate present-day CO₂ sources and sinks and predict future atmospheric CO₂. We have estimated the natural latitudinal distribution of atmospheric CO₂, relative to the South Pole, using measurements of atmospheric CO₂ during 1959–1991 and corresponding estimates of anthropogenic CO₂ emissions to the atmosphere. Key features of the natural latitudinal distribution include: (1) CO₂ concentrations in the northern hemisphere that are lower than those in the southern hemisphere; (2) CO₂ concentration differences that are higher in the tropics (associated with outgassing of the oceans) than those currently measured; and (3) CO₂ concentrations over the southern ocean that are relatively uniform. This natural latitudinal distribution and its sensitivity to increasing fossil fuel emissions both indicate that near-surface concentrations of atmospheric CO₂ in the northern hemisphere are naturally lower than those in the southern hemisphere. Models that find the contrary will also mismatch present-day CO₂ in the northern hemisphere and incorrectly ascribe that region as a large sink of anthropogenic CO₂.     

The effect of upwelling on the distribution and stable isotope composition of Globigerina bulloides and Globigerinoides ruber (planktic foraminifera) in modern surface waters of the NW Arabian Sea

Hydrographic changes in the NW Arabian Sea are mainly controlled by the monsoon system. This results in a strong seasonal and vertical gradient in surface water properties, such as temperature, nutrients, carbonate chemistry and the isotopic composition of dissolved inorganic carbon (δ¹³C_DIC). Living specimens of the planktic foraminifer species Globigerina bulloides and Globigerinoides ruber, were collected using depth stratified plankton tows during the SW monsoon upwelling period in August 1992 and the NE monsoon non-upwelling period in March 1993. We compare their distribution and the stable isotope composition to the seawater properties of the two contrasting monsoon seasons. The oxygen isotope composition of the shells (δ¹⁸O_shell) and vertical shell concentration profiles indicate that the depth habitat for both species is shallower during upwelling (SW monsoon period) than during non-upwelling (NE monsoon period). The calcification temperatures suggest that most of the calcite is precipitated at a depth level just below the deep chlorophyll maximum (DCM), however above the main thermocline. Consequently, the average calcification temperature of G. ruber and G. bulloides is lower than the sea surface temperature by 1.7±0.8 and 1.3±0.9 °C, respectively. The carbon isotope composition of the shells (δ¹³C_shell) of both species differs from the in situ δ¹³C_DIC found at the calcification depths of the specimens. The observed offset between the δ¹³C_shell and the ambient δ¹³C_DIC results from (1) metabolic/ontogenetic effects, (2) the carbonate chemistry of the seawater and, for symbiotic G. ruber, (3) the possible effect of symbionts or symbiont activity. Ontogenetic effects produce size trends in Δδ¹³C_shell–DIC and Δδ¹⁸O_shell–w: large shells of G. bulloides (250–355μm) are 0.33‰ (δ¹³C) and 0.23‰ (δ¹⁸O) higher compared to smaller ones (150–250 μm). For G. ruber, this is 0.39‰ (δ¹³C) and 0.17‰ (δ¹⁸O). Our field study shows that the δ¹³C_shell decreases as a result of lower δ¹³C_DIC values in upwelled waters, while the effects of the carbonate system and/or temperature act in an opposite direction and increase the δ¹³C_shell as a result lower [CO₃²⁻] (or pH) values and/or lower temperature. The Δδ¹³C_shell–DIC [CO₃²⁻] slopes from our field data are close to those reported literature from laboratory culture experiments. Since seawater carbonate chemistry affects the δ¹³C_shell in an opposite sense, and often with a larger magnitude, than the change related to productivity (i.e. δ¹³C_DIC), higher δ¹³C_shell values may be expected during periods of upwelling.     

Phytolith indices as proxies of grass subfamilies on East African tropical mountains

The main objective of this paper is to provide researchers that investigate fossil phytolith assemblages and model/data comparisons a new tool for estimating C₃/C₄ grass composition over time. We tested the reliability of modern soil phytolith assemblages and phytolith indices for tracing the dominance of different grass subfamilies and tree cover density. We analyzed modern soil phytolith assemblages from sites over elevation gradients on Mount Kenya (Kenya), Mount Rungwe and around Lake Masoko (southern Tanzania). These data were compared with available botanical data. A phytolith index named Ic, proved to be an effective proxy of the proportions of Pooideae, Arundinoideae and Bambusoideae grasses (mainly C₃ grasses) versus Panicoideae grasses (mainly C₄ grasses), increasing with elevation in East-Africa. When tropical mountains are covered by open habitats (e.g. grasses and shrublands), Ic should be a reliable proxy of the C₃/C₄ grass composition. These results highlight the value of the phytolith index Ic, when interpreting paleo-environmental records from tropical mountains, to: 1) better understand past local and regional C₃/C₄ grass distributions and associated climatic changes and 2) increase the set of C₃/C₄ data available for model/data comparisons.     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

Simulated responses of Pinus halepensis forest productivity to climatic change and CO2 increase using a statistical model

Tree ring chronologies provide long-term records of growth in natural environmental conditions and may be used to evaluate impacts of climatic change and CO₂ increase on forest productivity. This study focuses on 21 Pinus halepensis forest stands in calcareous Provence (in the south-east of France). A chronology of net primary productivity (NPP) both for the 20th century and for each stand was estimated using tree ring data (width and density). The response of each stand to climate in terms of NPP was statistically modelled using response functions. Anomalies between estimated NPP and NPP reconstructed by response functions were calculated to evaluate the fertilising effect of CO₂ increase on tree growth. The changes in anomalies during the 20th century were attributed to the effect of CO₂ increase. A multiplying factor (β) linking CO₂ concentration and stand productivity was then calculated, on the basis of the trend observed during the 20th century. In this study, the value of the β factor obtained under natural conditions (β=0.50) is consistent with those from controlled CO₂ enrichment experiments. Both response functions and the β factor were used to predict NPP changes for a 2×CO₂ scenario. The 2×CO₂ climate was obtained using predictions from Météo France's ARPEGE atmospheric general circulation model (AGCM) downscaled to Marseilles meteorological station. NPP increased significantly for nine stands solely when the climatic effect was taken into account. The main factors responsible for this enhancement were increased winter and early spring temperatures. When the fertilising effect of the CO₂ increase was added, NPP was significantly enhanced for 14 stands (i.e. NPP enhancement ranged from 8% to 55%). Although the effects of global change were slightly detectable during the 20th century, their acceleration is likely to lead to great changes in the future productivity of P. halepensis forests.     

A model of Titan's haze of fractal aerosols constrained by multiple observations

We use Titan's geometric albedo to constrain the vertical distribution of the haze. Microphysical models incorporating fractal aggregates do not readily fit the methane features at 0.62 μm band and the dark 0.88 μm of the albedo spectrum simultaneously. We take advantage of this apparent discrepancy to constrain the haze vertical profile.We used the geometric albedo and several results and constraints from other works to better constrain the vertical haze extinction profile, especially in the low stratosphere. The objective of this model is to give a solution that simultaneously fits the main constraints known to apply to the haze.We find that the haze extinction increases with decreasing altitude with a scale height about equal to the atmospheric scale height down to 100 km. Below this altitude, extinction must decrease down to 30 km. This is necessary in order to have enough haze to sustain a relatively high albedo (0.076) in the dark 0.88 μm methane band and to show the 0.62 μm band in the haze continuum. We set the haze production rate around 7×10⁻¹⁴ kgm⁻² s⁻¹, and the aerosols production altitude around 400 km (or at pressure 1.5 Pa).The physical processes which generate such a profile are not clear. However, purely one-dimensional effects such as condensation, sedimentation, and rainout can be ruled out, and we believe that this relative clearing in Titan's troposphere and lower stratosphere is due to particle horizontal transport by the mean circulation.     

A peat core based estimate of Late-glacial and Holocene methane emissions from northern peatlands

We estimate the intensity of Late-glacial and Holocene methane emissions from peatlands based on their paleo net primary production (PNPP). The PNPP is derived from the carbon accumulation rates of the studied bog profile (Etang de la Gruère, Switzerland), which are corrected for the degree of peat degradation. The obtained PNPP curve is taken as a proxy for methane emissions. It shows relatively high values (90 g C m^− 2 yr^− 1) early in the Bolling/Allerod and drops to low values (40 g C m^− 2 yr^− 1) during the Younger Dryas cold period. With the onset of the Holocene the PNPP increases strongly up to 150 g C m^− 2 yr^− 1 around ca. 10,000 Cal. yr bp. This is followed by a decline to minimum values (30 to 40 g C m^− 2 yr^− 1) between 6500 and 4000 Cal. yr bp. Thereafter, the PNPP starts to increase again to reach its highest value (175 g C m^− 2 yr^− 1) around 1000 Cal. yr bp.The PNPP curve correlates well with the evolution of the atmospheric methane concentrations as derived from Greenland ice-cores. For example, minima in atmospheric methane reported during the Younger Dryas and around 5200 Cal. yr bp are coinciding with the lowest values of PNPP and the negative atmospheric methane peak at 8200 Cal. yr bp corresponds to a marked decrease in PNPP.Our PNPP curve suggests that the methane emissions from northern peatlands evolved similar to those of low latitude wetlands and together they largely determined the evolution of atmospheric methane throughout the Late-glacial and the Holocene. The abruptness of the rise of atmospheric methane at the end of the Younger Dryas probably points to an additional source (e.g. marine gas hydrates), but very early in the Holocene the peatlands have likely become the dominant source of atmospheric methane.     

Estimation of net accumulation rate at a Patagonian glacier by ice core analyses using snow algae

Snow algae in a 45.97-m-long ice core from the Tyndall Glacier (50°59′05″S, 73°31′12″W, 1756 m a.s.l.) in the Southern Patagonian Icefield were examined for potential use in ice core dating and estimation of the net accumulation rate. The core was subjected to visual stratigraphic observation and bulk density measurements in the field, and later to analyses of snow algal biomass, water isotopes (¹⁸O, D), and major dissolved ions. The ice core contained many algal cells that belonged to two species of snow algae growing in the snow near the surface: Chloromonas sp. and an unknown green algal species. Algal biomass and major dissolved ions (Na⁺, K⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻) exhibited rapid decreases in the upper 3 m, probably owing to melt water elution and/or decomposition of algal cells. However, seasonal cycles were still found for the snow algal biomass, ¹⁸O, D-excess, and major ions, although the amplitudes of the cycles decreased with depth. Supposing that the layers with almost no snow algae were the winter layers without the melt water essential to algal growth, we estimated that the net accumulation rate at this location was 12.9 m a^− 1 from winter 1998 to winter 1999, and 5.1 m from the beginning of winter to December 1999. These estimates are similar to the values estimated from the peaks of ¹⁸O (17.8 m a^− 1 from summer 1998 to summer 1999 and 11.0 m from summer to December 1999) and those of D-excess (14.7 m a^− 1 from fall 1998 to fall 1999 and 8.6 m a^− 1 from fall to December 1999). These values are much higher than those obtained by past ice core studies in Patagonia, but are of the same order of magnitude as those predicted from various observations at ablation areas of Patagonian glaciers.     

The chemical evolution in a model of contracting cloud

The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm^–3 diffuse initial cloud model to a dense cloud with central density number of n >- 10⁵ cm^–3 after a time of 1.2 × 10⁷ yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C₂H, CN, SO₂, CO₂, H₂O, C₂, NH₃, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.     

The dust environment at Titan

To explain the observed abundances of CO₂ in Titan's atmosphere, a relatively high water deposition into the atmosphere needs to be invoked due to the importance of H₂O photolysis in CO₂ production. A likely source of H₂O is icy dust particles from space. This paper considers the direct dust input to Titan's atmosphere from the interplanetary environment, and also ejecta particles from micrometeoroid impacts with the icy satellites Hyperion, Iapetus and Phoebe. It is found that the likely mass influx to Titan is 10^–16 to 10^–15 kg m^–2 s^–1. This mass influx is an order of magnitude too low to explain the observed levels of CO₂ in Titan's atmosphere in the context of a recent photochemical model. This leads one to speculate as to the likelihood of one large impact to Titan in the recent past;i.e., that the atmosphere is not in equilibrium but is cnrrently losing CO₂.     

Production of nitrogen and carbon species by thunderstorms on Venus

The effects of the newly discovered thunderstorms on Venus upon the nitrogen and carbon species in its atmosphere were calculated. An Earth-like lightning frequency of 100 sec^?1 was used for Venus, in accord with recent optical measurements by Pioneer-Venus (W. J. Borucki, J. W. Dyer, G. Z. Thomas, J. C. Jordon, and D. A. Comstock, submitted for publication). The rate of NO production by thunder shock waves, 2.5 × 10¹¹ g year^?1, is about an order of magnitude smaller than on the Earth. But on Venus, in the absence of precipitation, which is the major removal mechanism of odd nitrogen from the Earth's atmosphere, the mixing ratios of odd nitrogen species might be considerably higher. The global CO production is governed by CO₂ photolysis rather than by CO₂ pyrolysis by lightning. However, thunderstorms produce about 2.5 × 10¹¹ g year^?1 of CO in the cloud layer, far from the high altitude CO₂ photolysis region.     

High-resolution bispectrum speckle interferometry and two-dimensional radiative transfer modeling of the Red Rectangle

We present the first diffraction-limited K-band image of the Red Rectangle with 76 mas resolution, an H-band image with 75 mas resolution, and an RG 715 filter image ( 800 nm wavelength) with 78 mas resolution (corresponding to 25 AU for a distance of 330 pc). The H and K images were reconstructed from 6 m telescope speckle data and the RG 715 image from 2.2 m telescope data using the speckle masking bispectrum method. At all wavelengths the images show a compact, highly symmetric bipolar nebula, suggesting a toroidal density distribution of the circumstellar material. No direct light from the central binary can be seen as it is obscured by a dust disk or circumbinary torus. Our first high-resolution H−K color image of the nebula shows a broad red plateau of H−K≈ 2^m in the bright inner regions.The optical and near-infrared images and the available photometric continuum observations in a wide range of ultraviolet to centimeter wavelengths enabled us to model the Red Rectangle in detail using a two-dimensional radiative transfer code. Our model matches both the high-resolution images and the spectral energy distribution of this object very well, making the following picture much more certain. The central close binary system with a total luminosity of 3000 L is embedded in a very dense, compact circumbinary torus which has an average number density n_H ≈5×10¹² cm⁻³, an outer radius of the dense inner region of R≈30 AU (91 mas), and a ρ∝r⁻² density distribution. The full opening angle of the bipolar outflow cavities in our model is 70°. By comparing the observed and theoretical images, we derived an inclination angle of the torus to the line of sight of 7°±1°.The radiative transfer calculations show that the dust properties in the Red Rectangle are spatially inhomogeneous. The modeling confirms that the idea of large grains in the long-lived disk around the Red Rectangle (Jura et al., 1997 [ApJ, 474, 741]) is quantitatively consistent with the observations. In our models, unusually large, approximately millimeter-sized grains dominate the emission of the compact, massive torus. Models with smaller average grain sizes can possibly be found in future studies, for instance, if it turns out that the radio spectrum is not mainly caused by continuum dust emission. Therefore, the large grains suggested by our models require further confirmation by both new observations and radiative transfer calculations. Assuming a dust-to-gas ratio ρ_d/ρ_g of 0.005, the dense torus mass is 0.25 M. The model gives a lower limit of 0.0018 M, for the mass of the large particles, which produce a gray extinction of A≈ 28^m, towards the center. A much smaller mass of submicron-sized dust grains is presumably located in the polar outflow cavities, their conical surface layers, and in the outer low-density parts of the torus (where ρ∝r⁻⁴, in the region of 30 AUr 2000 AU corresponding to 0.^′′09–6^′′).     

Climate forced atmospheric CO2 variability in the early Holocene: A stomatal frequency reconstruction

The dynamic climate in the Northern Hemisphere during the early Holocene could be expected to have impacted on the global carbon cycle. Ice core studies however, show little variability in atmospheric CO₂. Resolving any possible centennial to decadal CO₂ changes is limited by gas diffusion through the firn layer during bubble enclosure. Here we apply the inverse relationship between stomatal index (measured on sub-fossil leaves) and atmospheric CO₂ to complement ice core records between 11,230 and 10,330 cal. yr BP. High-resolution sampling and radiocarbon dating of lake sediments from the Faroe Islands reconstruct a distinct CO₂ decrease centred on ca. 11,050 cal. yr BP, a consistent and steady decline between ca. 10,900 and 10,600 cal. yr BP and an increased instability after ca. 10,550 cal. yr BP. The earliest decline lasting ca. 150 yr is probably associated with the Preboreal Oscillation, an abrupt climatic cooling affecting much of the Northern Hemisphere a few hundred years after the end of the Younger Dryas. In the absence of known global climatic instability, the decline to ca. 10,600 cal. yr BP is possibly due to expanding vegetation in the Northern Hemisphere. The increasing instability in CO₂ after 10,600 cal. yr BP occurs during a period of increasing cooling of surface waters in the North Atlantic and some increased variability in proxy climate indicators in the region.The reconstructed CO₂ changes also show a distinct similarity to indicators of changing solar activity. This may suggest that at least the Northern Hemisphere was particularly sensitive to changes in solar activity during this time and that atmospheric CO₂ concentrations fluctuated via rapid responses in climate.     

VLBI observations of high-opacity HI gas in NGC 5793

We report on observations, with sub-parsec resolution, of neutral hydrogen seen in absorption in the λ=21 cm line against the nucleus of the active spiral galaxy NGC 5793. The absorption line consists of three components separated in both location as well as velocity. We derive HI column densities of 2×10²² cm⁻² assuming a gas spin temperature of 100 K. For the first time we are able to reliably estimate the HI cloud sizes (≈15 pc) and atomic gas densities (≈200 cm⁻³). Our results suggest that the HI gas is not associated with the <10 pc region which presumably contains the H₂O masers, but it is more distant from the nucleus, and is probably associated with the r1 kpc gas seen in CO.