The intrinsic acidity constants and specific surface area of marine solid particles I. A new method

This paper proposes a new method for determining the intrinsic acidity constantsK _a1 ^int andK _aj ^int . The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these constants is not dependent on the specific surface area of the marine solid particles. The new method was used to determineK _a1 ^int ,K _2a ^int and for the main inorganic components of marine solid particles, including illite, montmorillonite, kaolinite, goethite, γ-AlOOH. amorphous ferric oxide, δ-MnO₂, manganite, SiO₂ and calcium carbonate, and can facilitate the study on the effect of solution constituents, solution temperature, ionic strength, etc. on the value of .     

THE INTRINSIC ACIDITY CONSTANTS AND SPECIFIC SURFACE AREA OF MARINE SOLID PARTICLESII. THE RELATIONSHIP BETWEEN THE INTRINSIC ACIDITY CONSTANT AND THE TERNARY SURFACE COMPLEX

This paper deals with the infrared spectra of " amino acid- clay , calcium carbonate and y-AlOOH" and " Cu (II )-clay-amino acid" model systems, and shows that the model of the ternary surface complex is M-OHLCu (L = amino acid) for marine solid particle-Cu (II)-amino acid. Study of the formation mechanism of the ternary surface complex shows that the specific surface area , and especially the intrinsic acidity constant, determine whether the ternary surface complex is easily formed, and that factor, FTSC,quantifies the relationship between the promoting effect of organics on Mt-marine solid particle ion exchange and the intrinsic acidity constant and specific surface area.     

Viscosity of sea surface microlayer in Jiaozhou Bay and adjacent sea area

This study on the temporal and spatial variability of the viscosity and some chemical parameters in the sea surface microlayer (SML), the relationship between the viscosity and chemical parameters, and the influence of the viscosity on the mass transfer coefficient (K) in the flux of materials through the air-sea interface revealed that: The values of viscosity and some chemical parameters in the SML are higher than those in the sub-surface layer (SSL), and at daytime are higher than those at night. The viscosity has positive corelation with chemical oxygen demand (COD),dissolved organic carbon (DOC) and salinity. The “SML effect“ on K need not be considered because the SML effect on materials concentration is so small.     

ZOOPLANKTON COMMUNITY STRUCTURE OF THE SEA SURFACE MICROLAYER NEAR NUCLEAR POWER PLANTS AND MARINE FISH CULTURE ZONES IN DAYA BAY

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ANALYSIS OF SURFACE SINK OF EXPLORATION VACANCY IN GOLD MINING AREA OF ZHAOYUAN CTIY BASED ON RS AND GIS

1 IN T R O D U C T IO NZhaoyuan C ity, located in northeast of ShandongProvince,iscalled "G old C ity"and itisone ofim portantgold production bases in C hina.The exploitation ofthegold broughtoutthe extensive vacantareas,leading tolarge-scale ground subsi…     

The composition and origination of particles from surface water in the Chukchi Sea,Arctic Ocean

Suspended particle samples were collected at 11 stations on the shelf and slope regions of the Chukchi Sea and the central Arctic Ocean during the fifth Chinese National Arctic Research Expedition （summer 2012）. The particle concentration, total organic carbon （TOC）, total nitrogen （TN） and the isotopic composition of the samples were analyzed. The suspended particle concentration varied between 0.56 and 4.01 mg.Ll; the samples collected from the sea ice margin have higher concentrations. The organic matter content is higher in the shelf area （TOC： 9.78%-20.24%; TN： 0.91‰-2.31%）, and exhibits heavier isotopic compositions （δ13C： -23.29‰ to -26.33‰ PDB; δ15N： 6.14‰-7.78‰）, indicating that the organic matter is mostly marine in origin with some terrigenous input. In the slope and the central Arctic Ocean, the organic matter content is lower （TOC： 8.06%- 8.96%; TN： 0.46%-0.72%）, except for one sample （SR15）, and has lighter isotopic compositions （δ13C： -26.93‰ to -27.78‰ PDB; δ15N： 4.13‰-4.84‰）. This indicates that the organic matter is mostly terrestrially-derived in these regions. The extremely high amount of terrigenous organic matter （TOC： 27.94%; TN： 1.16%; δ13C： -27.43‰ PDB; δ15N： 3.81‰） implies that it was carried by transpolar currents from the East Siberian Sea. Material, including sea ice algae, carried by sea ice are the primary source for particles in the sea ice margins. Sea ice melting released a substantial amount of biomass into the shelf, but a large amount of detrital and clay minerals in the slope and the central Arctic Ocean.     

The inter-annual variability of the Yellow Sea Warm Current surface axis and its influencing factors

Based on the Pathfinder sea surface temperature(PFSST),the surface axis and its pattern of the Yellow Sea Warm Current(YSWC) are discussed.A structure of double-warm-tongue is found in February and it varies in different years.Two indexes are calculated to represent the westward shift(WSI) and northward extension(NEI) of the warm water in the Yellow Sea(YS).Wavelet analysis illustrates that the WSI and NEI have prominent periods of 3-6 years and 3-4 years,respectively.The Empirical Orthogonal Function(EOF) ...     

THE DIVERGENCE-CONVERGENCE EFFECT OF SURFACE CURRENT AND ITS ACTION ON THE BOHAI SEA

The action of the wind field and the influence of topography can cause divergence or convergence of surface current. The existence of the divergence-convergence effect is proved and the dynamical significance of the divergent or convergent state and its link with many marine phenomena are pointed out. Divergence fields of surface current in the Bohai Sea in winter and summer are obtained by numerical modelling describing the divergence-convergence character of seasonally wind-driven current. The relation between the effect and seasonal marine phenomena is discussed. Study on the divergence-convergence effect of surface current (DCESC)can be an indirect method for testing the calculated results.     

玻璃基质表面的气体润湿性与其表面自由能关系

针对气相中憎液表面的气体润湿性常常被忽略,但理论和实验证实气体的润湿性并不总是可以被忽略,凝析气藏气体润湿程度对气井产能具有重要影响,根据Owens双液法建立固体表面自由能计算模型,并且结合自定义的气体润湿性参数实现定量表征气体润湿性的大小,导出固体表面的气体润湿性与表面自由能的数学关系式.采用氟碳聚合物(Zonyl8740)实现空气中"空气/水/载玻片"体系载玻片表面的优先气湿,随Zonyl8740质量分数的增大"正十六烷/空气/载玻片"体系载玻片表面的气湿性增强.     

Seasonal and intraseasonal variations of the surface Taiwan Warm Current

To study seasonal and intraseasonal variations of the Taiwan Warm Current (TWC) in detail Rotated Empirical Orthogonal Function (REOF) and Extended Associate Pattern Analysis (EAPA) are jointly adopted with daily sea surface salinity (SSS), sea surface temperature (SST) and sea surface height (SSH) datasets covering 1126 days from American Navy Experimental Real-Time East Asian Seas Ocean Nowcast System in the present paper. Results show that the first and second REOFs of SST in the southern East China Sea (SECS) account for 50.8% and 39.8% of the total variance. The surface TWC contains persistent (multi-year mean), seasonal and intraseasonal components. The persistent one mainly inosculates with the Kuroshio but the seasonal and intraseasonal ones are usually active only on the continental shelf. Its persistent component is produced by inertial flow of the Kuroshio, however its seasonal and intraseasonal ones seems coming from seasonal and intraseasonal oscillations of monsoon force. The seasonal one reaches its maximum in late summer,lasting about four months and the intraseasonal one takes place at any seasons, lasting more than 40 days.     

Determination of the Current System on Isopycnal Surface Between Mindanao and New Guinea from GDEM

1 .INTRODUCTIONThewesternequatorialPacific ,particularlythesouthernmostPhilippineSea ,wascalled“watermasscrossroads”byFineetal.(1 994 )duetotheconfluencethereofseveralwatermassesfromhigherlatitudesofbothhemispheres (Wyrtki,1 96 1 ;Fineetal.,1 994 ) .Fineetal.(1 994 )de picted (Fig .1 )majorcurrentsintheIndonesianregion .AfterencounteringthewesternboundaryalongthePhilippinecoast,theNorthEquatorialCur rent (NEC)bifurcatesintothenorthwardflowingKuroshioandthesouthwardflowingMindanao…     

Distributions of surface sediments surrounding the Antarctic Peninsula and its environmental significance

We analyzed grain size composition to provide information on the types and distributions as well as depositional varieties of marine surface sediments from the area surrounding the Antarctic Peninsula. The samples retrieved from the study area contain gravel, sand, silt and clay. As suggested by bathymetry and morphology, the study area is characterized by neritic, hemipelagic and pelagic deposits. The glacial-marine sediments can be divided into two types, residual paratill and compound paratill, which are primarily transported by glaciers and as ice-rafted debris. Ocean current effects on deposition are more obvious, and the deposit types are distributed consistently with terrain variations.     

Composition and distribution of diatom assemblages in the surface sediments of the Bering Sea

Diatoms collected from the top 1 cm of the surface sediment layer at seven Bering Sea stations during the Fourth Chi- nese National Arctic Research Expedition （4th CH1NARE-Arctic） in 2010 were studied. In total, 101 taxa belonging to 38 genera were found. The species were divided into four groups： eurythermal species, boreal-temperate species, polar species, and sea-ice species. The diatom assemblages at the stations in the southwestern basin area were primarily composed of boreal-temperate species, such as Neodenticula seminae, Thalassiosira trifulta, Rhizosolenia hebetata f. hiemalis, and Actinocyclus curvatulus. The northeastern shelf stations were dominated by polar species, including Fragilariopsis oceanica, Thalassiosira antarctica spora, Thalassiosira nordensldoeldii, and Thalassiosira hyalina. The overall abundance was highest at the basin stations with 3.7 ×10^6 cells·g^-1 of wet sediment, whereas the eastern shelf stations had the lowest abundance of 0.7×10^6 cells·g^-1 of wet sediment （excluding the resting spores of Chaetoceros spp.）. The relationship between the distribution of the surface sediment diatom assemblages and the environment is discussed.     

The environmental implication of diatom fossils in the surface sediment of the Changjiang River estuary(CRE) and its adjacent area

In order to depict the distribution of diatom fossils in surface sediments and to establish a reliable reference data for further paleoenvironmental study in the Changjiang(Yangtze) River estuary and its adjacent waters, the diatom fossils from 34 surface sediment samples and their relationship with environmental variables were analyzed by principal component analysis and redundancy correspondence analysis. The diversity and abundance of diatom fossils were analyzed. Some annual average parameters of the overlying water(salinity, temperature, turbidity, dissolved oxygen, depth, dissolved inorganic nitrogen,dissolved inorganic phosphate and dissolved inorganic silicate) were measured at each sampling site. A total of 113 diatom taxa and one silicoflagellate species were identified in the investigation area. Diatom fossils were better preserved in fine sediments. The absolute abundance of diatom fossils did not significantly dif fer between inshore and of fshore areas, the species diversity decreased from inshore to of fshore. This may be because high nutrients and low salinity promoted the growth of more brackish species in coastal waters. The diatom taxa were divided into three groups, on the basis of their response and indication to environmental changes. For example, Actinocyclus ehrenbergii and Cyclotella stylorum were dominant in coastal waters(Group 1 and Group 3) with high nutrients and low salinity; the relative abundances of Paralia sulcata and Podosira stelliger were significantly higher in of fshore sites(Group 2, average 39.5%),which were characterized by high salinity and deep water. Four environmental variables(salinity, dissolved inorganic nitrogen, temperature and water depth) explained the composition and distribution of diatom taxa independently( P 0.05), this finding can be applied in further paleoenvironmental reconstruction research in this area.     

Interannual variability of SST,SLA and wind waves in the Hawaii area and their responses to ENSO

Time series of sea surface temperature (SST),wind speed and significant wave height (SWH) from meteorologicalbuoys of the National Data Buoy Center (NDBC) are useful for studying the interannual variability and trend of these quantities at the buoy areas.The measurements from 4 buoys (B51001,B51002,B51003 and B51004) in the Hawaii area are used to study theresponses of the quantities to EI Nino and Southern Oscillation (ENSO).Long-term averages of these data reflect precise seasonaland climatological characteristics of SST,wind speed and SWH around the Hawaii area.Buoy observations from B51001 suggest asignificant warming trend which is,however,not very clear from the other three buoys.Compared with the variability of SST andSWH,the wind speeds from the buoy observations show an increasing trend.The impacts of El Nifio on SST and wind waves arealso shown.Sea level data observed by altimeter during October 1992 to September 2006 are analyzed to investigate the variabilityof sea level in the Hawaii area.The results also show an increasing trend in sea level anomaly (SLA).The low-passed SLA in theHawaii area is consistent with the inverse phase of the low-passed Sol (Southern Oscillation Index).Compared with the low-passedSOl and PDO (Pacific Decadal Oscillation),the low-passed PNA (Pacific-North America Index) has a better correlation with thelow-passed SLA in the Hawaii area.     

Spatiotemporal features and possible mechanisms of seasonal changes in sea surface height south of Japan

Variations of sea surface height(SSH) in the Kuroshio south of Japan are addressed by analyzing 19-year(1993–2011) altimetry data from AVISO. Regionally averaged time series of observed SSH had a rising linear trend at 2.64±0.72 mm/a in this period. By analyzing the power spectra, several periods were recognized in temporal SSH variations, including those around 90 and 360 days. The seasonal cycle of SSH was minimum in winter(February) and maximum in summer(August), with peak-to-peak amplitude about 20.0 cm. The spatial distribution of linear trends was inhomogeneous, with a rising linear trend along the coastline and a tripole structure offshore. Spatial distributions of standard deviation of seasonal SSH show very dynamic activities in the southeast of Kyushu and south of Honshu. Seasonal variations of observed SSH are partially explained by surface buoyancy forcing, local wind forcing and the steric component related to subsurface water beneath the mixed layer. Results show different spatial distributions of correlation coefficient and estimation skill between seasonally observed and modeled SSH, which are calculated from surface buoyancy fl ux, local wind forcing and the steric component related to subsurface water. Of those three, the surface buoyancy fl ux has a greater contribution to variations of observed SSH on the seasonal time scale south of Japan.     

Annual and interannual variability of scatterometer ocean surface wind over the South China Sea

To investigate the annual and interannual variability of ocean surface wind over the South China Sea (SCS), the vector empirical orthogonal function (VEOF) method and the Hilbert-Huang transform (HHT) method were employed to analyze a set of combined satellite scatterometer wind data during the period from December 1992 to October 2009. The merged wind data were generated from European Remote Sensing Satellite (ERS)-1/2 Scatterometer, NASA Scatterometer (NSCAT) and NASA’s Quick Scatterometer (QuikSCAT) wind products. The first VEOF mode corresponds to a winter-summer mode which accounts for 87.3% of the total variance and represents the East Asian monsoon features. The second mode of VEOF corresponds to a spring-autumn oscillation which accounts for 8.3% of the total variance. To analyze the interannual variability, the annual signal was removed from the wind data set and the VEOFs of the residuals were calculated. The temporal mode of the first interannual VEOF is correlated with the Southern Oscillation Index (SOI) with a four-month lag. The second temporal interannual VEOF mode is correlated with the SOI with no time lag. The time series of the two interannual VEOFs were decomposed using the HHT method and the results also show a correlation between the interannual variability and El Niño-Southern Oscillation (ENSO) events.     

NUMERICAL SIMULATION OF INTERANNUAL AND INTERDECADAL VARIABILITY OF SURFACE WIND OVER THE TROPICAL PACIFIC

A global atmospheric general circulation model (L9R15 AGCMs) forced by COADS SST was integrated from 1945 to 1993. Interannual and interdecadal variability of the simulated surface wind over the tropical Pacific was analyzed and shown to agree vey well with observation. Simulation of surface wind over the central-western equatorial Pacific was more successful than that over the eastern Pacific. Zonal propagating feature of interannual variability of the tropical Pacific wind anomalies and its decadal difference were also simulated successfully. The close agreement between simulation and observation on the existence of obvious interdecadal variability of tropical Pacific surface wind attested to the high simulation capability of AGCM.     

Characteristics of Spatial and Temporal Variations of Monthly Mean Surface Air Temperature over Qinghai-Tibet Plateau

1 Introduction The Qinghai-Tibet Plateau, known as the highest plateau with the most complex topography in the world, covers an area of more than 200km2, with a mean elevation of more than 4000m a.s.l. (Ye and Gao, 1979). Surrounded by the Earth’s highest mountains, such as the Himalayas, Pamir, Kunlun Mountains, the plateau plays a significant role in climate change in China even in the world, thus attracted great attention of researchers. Up to now, many achievements have been gained by…