首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
Radionuclide activities (210Pb, 210Bi, 210Po) were investigated in Mount Etna plume from 1983 to 1995. At SE crater the long-term observation (12 years) of the 210Po/210Pb ratio shows that it can behave as a degassing vent not directly related to the main magma reservoir depending on the magma level inside the volcano. Since 1992, the simultaneous determination of radionuclides and sulfur in the main plume results in new constraints on the degassing model of Lambert et al. (Earth Planet. Sci. Lett., 76 (1986) 185). The 210Po/SO2 and 210Pb/SO2 ratios enable us to identify two sources of 210Po in the plume: one is magmatic, correlated with SO2, the other one is an additional component issued from the decay of 210Pb in the shallow degassing cell, and depends directly on the residence time of the gases before their emission. Estimations of the volume of degassing magma, the residence time of the gases and the proportion of undegassed magma renewing the shallow degassing cell are given for the period 1992–1995. During the 1992 eruption, the rate of degassing magma volume is estimated to have been as high as 5×106 m3/day, and the volume of the shallow degassing magma reservoir about 0.5 km3. In 1994 and 1995 the rate of non-erupted degassing magma volume was estimated to have been about 0.18 km3/year. During the entire 1983–1995 period, only 15–20% of the degassed magma was erupted.  相似文献   

2.
K lauea Volcano, Hawai‘i, currently hosts the longest running SO2 emission-rate data set on the planet, starting with initial surveys done in 1975 by Stoiber and his colleagues. The 17.5-year record of summit emissions, starting in 1979, shows the effects of summit and east rift eruptive processes, which define seven distinctly different periods of SO2 release. Summit emissions jumped nearly 40% with the onset (3 January 1983) of the Pu‘u ‘ ‘ -K paianaha eruption on the east rift zone (ERZ). Summit SO2 emissions from K lauea showed a strong positive correlation with short-period, shallow, caldera events, rather than with long-period seismicity as in more silicious systems. This correlation suggests a maturation process in the summit magma-transport system from 1986 through 1993. During a steady-state throughput-equilibrium interval of the summit magma reservoir, integration of summit-caldera and ERZ SO2 emissions reveals an undegassed volume rate of effusion of 2.1×105 m3/d. This value corroborates the volume-rate determined by geophysical methods, demonstrating that, for K lauea, SO2 emission rates can be used to monitor effusion rate, supporting and supplementing other, more established geophysical methods. For the 17.5 years of continuous emission rate records at K lauea, the volcano has released 9.7×106 t (metric tonnes) of SO2, 1.7×106 t from the summit and 8.0×106 t from the east rift zone. On an annual basis, the average SO2 release from K lauea is 4.6×105 t/y, compared to the global annual volcanic emission rate of 1.2×107 t/y.  相似文献   

3.
The correlation spectrometer (COSPEC), the principal tool for remote measurements of volcanic SO2, is rapidly being replaced by low-cost, miniature, ultraviolet (UV) spectrometers. We compared two of these new systems with a COSPEC by measuring SO2 column amounts at Kīlauea Volcano, Hawaii. The two systems, one calibrated using in-situ SO2 cells, and the other using a calibrated laboratory reference spectrum, employ similar spectrometer hardware, but different foreoptics and spectral retrieval algorithms. Accuracy, signal-to-noise, retrieval parameters, and precision were investigated for the two configurations of new miniature spectrometer. Measurements included traverses beneath the plumes from the summit and east rift zone of Kīlauea, and testing with calibration cells of known SO2 concentration. The results obtained from the different methods were consistent with each other, with <8% difference in estimated SO2 column amounts up to 800 ppm m. A further comparison between the COSPEC and one of the miniature spectrometer configurations, the ‘FLYSPEC’, spans an eight month period and showed agreement of measured emission rates to within 10% for SO2 column amounts up to 1,600 ppm m. The topic of measuring high SO2 burdens accurately is addressed for the Kīlauea measurements. In comparing the foreoptics, retrieval methods, and resultant implications for data quality, we aim to consolidate the various experiences to date, and improve the application and development of miniature spectrometer systems.  相似文献   

4.
A numerical simulation was conducted to predict the change of pCO2 in the ocean caused by CO2 leaked from an underground aquifer, in which CO2 is purposefully stored. The target space of the present model was the ocean above the seafloor. The behavior of CO2 bubbles, their dissolution, and the advection-diffusion of dissolved CO2 were numerically simulated. Here, two cases for the leakage rate were studied: an extreme case, 94,600 t/y, which assumed that a large fault accidentally connects the CO2 reservoir and the seafloor; and a reasonable case, 3800 t/y, based on the seepage rate of an existing EOR site. In the extreme case, the calculated increase in ΔpCO2 experienced by floating organisms was less than 300 ppm, while that for immobile organisms directly over the fault surface periodically exceeded 1000 ppm, if momentarily. In the reasonable case, the calculated ΔpCO2 and pH were within the range of natural fluctuation.  相似文献   

5.
We measured SO2 emission rate from six volcanoes in Latin America (Santa Ana, El Salvador; San Cristóbal and Masaya, Nicaragua; Arenal and Poás, Costa Rica; Tungurahua and Sierra Negra, Ecuador) and from Mt. Etna, Italy, using two different remote sensing techniques: COSPEC (COrrelation SPECtrometer) and miniDOAS (miniaturized Differential Optical Absorption Spectroscopy). One of the goals of this study was to evaluate the differences in SO2 emission rates obtained by these two methods. The observed average SO2 emission rates measured during this study were 2688 t·d−1 from Tungurahua in July 2006, 2375 t·d−1 in September 2005 and 480 t·d−1 in February 2006 from Santa Ana, 1200 t·d−1 in May 2005 from Etna, 955 t·d−1 in March 2006 and 1165 t·d−1 in December 2006 from Masaya, 5400 t·d−1 of March 7, 2006 and 265 t·d−1 in March 2006 from San Cristobal, 113 t·d−1 in April 2006 from Arenal, 104 t·d−1 in April 2006 from Poás and 11 t·d−1 in July 2006 from Sierra Negra volcano. Most of the observed relative differences of SO2 emission measurements from COSPEC and miniDOAS were lower than 10%.  相似文献   

6.
三峡水库澎溪河消落区土-气界面CO2和CH4通量初探   总被引:1,自引:0,他引:1  
李哲  张利萍  王琳  郭劲松  高旭  方芳  蒋滔 《湖泊科学》2013,25(5):674-680
水库近岸湿地(消落区)温室气体(CO2、CH4)产汇是水库温室气体效应问题的重要组成部分.本文以三峡水库支流澎溪河的白家溪、养鹿两处大面积消落区为研究对象,于2010年6 9月水库低水位运行期间,对近岸消落区土-气界面CO2、CH4通量进行监测.白家溪消落区土-气界面CO2通量均值为12.38±2.42 mmol/(m2·h);CH4通量均值为0.0112±0.0064 mmol/(m2·h).养鹿消落区CO2、CH4通量均值分别为10.54±5.17、0.14±0.16 mmol/(m2·h).总体上,6 9月土-气界面CO2通量呈增加趋势,而CH4通量水平呈现显著的递减趋势.消落区土地出露后植被恢复,在一定程度上促进了土壤有机质含量的增加,使得6 9月CO2释放通量的总体趋势有所增加.消落区退耕后,其甲烷氧化菌的活性得到恢复,加之在土地出露曝晒过程中土壤透气性增强,使得消落区土壤对大气中CH4吸收氧化潜势增强.尽管如此,仍需进一步的研究以明晰消落区土-气界面CO2、CH4产汇的主要影响因素.  相似文献   

7.
Near-surface soil CO2 gas-phase concentration (C) and concomitant incident rainfall (Pi) and through-fall (Pt) depths were collected at different locations in a temperate pine forest every 30 min during the 2005 and 2006 growing seasons (and then averaged to the daily timescale). At the daily scale, C temporal variations were well described by a sequence of monotonically decreasing functions interrupted by large positive jumps induced by rainfall events. A stochastic model was developed to link rainfall statistics responsible for these jumps to near-surface C dynamics. The model accounted for the effect of daily rainfall variability, both in terms of timing and amount of water, and permitted an analytical derivation of the C probability density function (pdf) using the parameters of the rainfall pdf. Given the observed positive correlation between daily C and soil CO2 fluxes to the atmosphere (Fs), the effects of various rainfall regimes on the statistics of Fs can be deduced from the behavior of C under different climatic conditions. The predictions from this analytical model are consistent with flux measurements reported in manipulative experiments that varied rainfall amount and frequency.  相似文献   

8.
A portable multi-sensor system was developed to measure volcanic plumes in order to estimate the chemical composition and temperature of volcanic gases. The multi-sensor system consists of a humidity–temperature sensor, SO2 electrochemical sensor, CO2 IR analyzer, pump and flow control units, pressure sensor, data logger, and batteries; the whole system is light (∼5 kg) and small enough to carry in a medium-size backpack. Volcanic plume is a mixture of atmosphere and volcanic gas; therefore volcanic gas composition and temperature can be estimated by subtracting the atmospheric gas background from the plume data. In order to obtain the contrasting data of the plume and the atmosphere, measurements were repeated in and out of the plume. The multi-sensor technique was applied to measure the plume of Tarumae, Tokachi, and Meakan volcanoes, Hokkaido, Japan. Repeated measurements at each volcano gave a consistent composition with ±10–30% errors, depending on the stability of the background atmospheric conditions. Fumarolic gas samples were also collected at the Tokachi volcano by a conventional method, and we found a good agreement (the difference <10%) between the composition estimated by the multi-sensor technique and conventional method. Those results demonstrated that concentration ratios of major volcanic gas species (i.e., H2O, CO2, and SO2) and temperature can be estimated by the new technique without any complicated chemical analyses even for gases emitted from an inaccessible open vent. Estimation of a more detailed gas composition can be also achieved by the combination of alkaline filter techniques to measure Cl/F/S ratios in the plume and other sensors for H2S and H2.  相似文献   

9.
Continuous monitoring of soil CO2 dynamic concentration (which is proportional to the CO2 flux through the soil) was carried out at a peripheral site of Mt. Etna during the period November 1997–September 2000 using an automated station. The acquired data were compared with SO2 flux from the summit craters measured two to three times a week during the same period. The high frequency of data acquisition with both methods allowed us to analyze in detail the time variations of both parameters. Anomalous high values of soil CO2 dynamic concentration always preceded periods of increased flux of plume SO2, and these in turn were followed by periods of summit eruptions. The variations were modeled in terms of gas efflux increase due to magma ascent to shallow depth and its consequent depressurization and degassing. This model is supported by data from other geophysical and volcanological parameters. The rates of increase both of soil CO2 dynamic concentration and of plume SO2 flux are interpreted to be positively correlated both to the velocity of magma ascent within the volcano and to lava effusion rate once magma is erupted at the surface. Low rates of the increase were recorded before the nine-month-long 1999 subterminal eruption. Higher rates of increase were observed before the violent summit eruption of September-November 1999, and the highest rates were observed during shorter and very frequent spike-like anomalies that preceded the sequence of short-lived but very violent summit eruptions that started in late January 2000 and continued until late June of the same year. Furthermore, the time interval between the peaks of CO2 and SO2 in a single sequence of gas anomalies is likely to be controlled by magma ascent velocity.Editorial responsibility: H. Shinohara  相似文献   

10.
Soil CO2 concentration data were collected periodically from July 2001 to June 2005 from sampling site grids in two areas located on the lower flanks of Mt. Etna volcano (Paternò and Zafferana Etnea–Santa Venerina). Cluster analysis was performed on the acquired data in order to identify possible groups of sites where soil degassing could be fed by different sources. In both areas three clusters were recognised, whose average CO2 concentration values throughout the whole study period remained significantly different from one another. The clusters with the lowest CO2 concentrations showed time-averaged values ranging from 980 to 1,170 ppm vol, whereas those with intermediate CO2 concentrations showed time-averaged values ranging from 1,400 to 2,320 ppm vol, and those with the highest concentrations showed time-averaged values between 1,960 and 55,430 ppm vol. We attribute the lowest CO2 concentrations largely to a biogenic source of CO2. Conversely, the highest CO2 concentrations are attributed to a magmatic source, whereas the intermediate values are due to a variable mixing of the two sources described above. The spatial distribution of the CO2 values related to the magmatic source define a clear direction of anomalous degassing in the Zafferana Etnea–Santa Venerina area, which we attribute to the presence of a hidden fault, whereas in the Paternò area no such oriented anomalies were observed, probably because of the lower permeability of local soil. Time-series analysis shows that most of the variations observed in the soil CO2 data from both areas were related to changes in the volcanic activity of Mt. Etna. Seasonal influences were only observed in the time patterns of the clusters characterised by low CO2 concentrations, and no significant interdependence was found between soil CO2 concentrations and meteorological parameters. The largest observed temporal anomalies are interpreted as release of CO2 from magma batches that migrated from deeper to shallower portions of Etna’s feeder system. The pattern of occurrence of such episodes of anomalous gas release during the observation period was quite different between the two studied areas. This pattern highlighted an evident change in the mechanism of magma transport and storage within the volcano’s feeder system after June 2003, interpreted as magma accumulation into a shallow (<8 km depth) reservoir.  相似文献   

11.
The nitrogen-doped TiO2 nanotube (N-TNT) thin films were synthesized using ZnO nanorods as the template and doped with urea at 623 K. Under ultraviolet (UV) and visible light irradiation, the efficiencies for photocatalytic degradation of methylene blue is as high as 30%. About 10% of toluene (representing aromatics in the spill oils) in sea water can be photocatalytically degraded under visible light radiation for 120 min. The aliphatic model compound (1-hexadecene) has, on the contrary, a less efficiency (8%) on the N-TNT photocatalyst. On the average, under visible light radiation, the effectnesses of the N-TNT for photocatalytic degradation of model compounds in the spill oils in sea water are 0.38 mg toluene/gN-TNT h and 0.25 mg 1-hexadecene/gN-TNT h. It is expected that spill oils in the harbors or seashores can be adsorbed and photocatalytically degraded on the N-TNT thin films that are coated onto levee at the sea water surface level.  相似文献   

12.
This paper presents the first remote measurements of La Soufrière gas emissions since the fumarolic and seismic reactivation in 1992. The chemical composition of the plumes has been measured from May 2003 to September 2004 using an Open Path Fourier Transform InfraRed (OP-FTIR) spectrometer, up to 15 m downwind the South Crater. HCl is clearly detected (concentration between 2.4 and 12 ppmv) whereas SO2 and H2S generally remain below the detection limit of the OP-FTIR. Direct measurements of SO2 and H2S near the South Crater with a Lancom III analyzer show a fast decrease of their concentrations with the distance. Calculated Cl / S mass ratios are high: from 9.4 ± 1.7 at 15 m from the vent to 2.8 ± 0.6 at 140 m. The enrichment in HCl of the gas emitted at La Soufrière, observed since 1998, corresponds to the degassing of a magma enriched in Cl and depleted in S. This result agrees with isotopic measurements which suggest a magmatic origin of the gases. Readjustments inside the volcanic system may have taken place during the seismic activity beginning in 1992 and enhance the transfer of magmatic gases to the summit.  相似文献   

13.
We have studied the temperature response to changes in the CO2 concentration in the middle and upper atmosphere using the Coupled Middle Atmosphere–Thermosphere Model 2 (CMAT2). We have performed simulations with a range of CO2 concentrations and three different ways of accounting for the effects of gravity waves, to allow for comparison with previous studies and sensitivity analyses. We initially find that the response of the model to the changes in CO2 concentration which took place between 1965 and 1995 (320–360 ppm) is strongly dependent on the gravity wave parameterization that is used, but this is to a large degree due to steps or kinks in an otherwise nearly linear curve describing the temperature as a function of CO2 concentration. We have not been able to identify the cause of these steps as part of the present study, which is a limitation and must be studied in future work. Here we treated the steps as model noise and rather focused on correcting for their effects by fitting straight lines to the temperature–CO2 curves to estimate the overall slope of the curves. From these slopes we were able to obtain more robust trend estimates than can be obtained by comparing only two model simulations, as is normally done in other, similar studies. The corrected temperature responses to a 40 ppm change in CO2 concentration still show up to 15–17% sensitivity to the gravity wave parameterization in the mesosphere and thermosphere. This remaining sensitivity is likely to be related to the fundamental differences in the way a change in temperature modifies the propagation and dissipation characteristics of gravity waves in each parameterization, which is particularly different for linear and non-linear schemes. The corrected trends we find are largely in agreement with other modelling studies, and therefore do not fully explain observed trends, which are typically larger than those predicted by modelling studies. However, modelling results could be similarly sensitive to other model parameters and settings, for example to gravity wave characteristics or solar activity level, and this should be further investigated as well.  相似文献   

14.
为揭示岩溶湿地表层水体二氧化碳分压(pCO2)的时空分布规律及其扩散通量,以我国最大的岩溶湿地贵州威宁草海为研究对象,分别于2019年7月(丰水期)和12月(枯水期)通过网格布点法,系统采集草海表层湿地水体,测定水样理化指标和离子组成,利用PHREEQCI软件计算水体pCO2,并基于Cole提出的气体扩散模型估算水-气界面二氧化碳(CO2)的扩散通量.结果表明:草海湿地表层水体丰水期pCO2的变化范围为0.44~645.65μatm,平均值为(55.94±124.73)μatm;枯水期变化范围为35.48~707.95μatm,平均值为(310.46±173.54)μatm;丰水期水体整体pCO2低于枯水期,空间上两期水体均呈现东部区域及河流入湖口处pCO2较高,而中西部区域pCO2欠饱和的特征.水-气界面CO2的扩散通量在丰水期变化范围为-43.27~27.16 mmol/(m2·d),平均值(-34.49±12.93)mmol/(m2·d),枯水期变化范围为-33.36~28.15 mmol/(m2·d),平均值(-8.02±15.85)mmol/(m2·d),与其他岩溶湖库相比,水生植物丰富的草海在两个极端水文期CO2扩散通量相对较低,总体表现为大气CO2的汇.  相似文献   

15.
The inclination (I), declination (D) and total intensity (F) of the geomagnetic field were measured on Mount Etna in 1989-1991 at a dozen sites previously sampled for archeomagnetic studies. The purpose of the work was to determine the variations of these parameters at 30 cm above ground level, and how the distortion from the main field can affect the archeomagnetic record of volcanic rocks. Ten measurements were usually performed at each site with a three-component flux-gate magnetometer, whose estimated precision is ±0.2° on direction and ±50 nT on intensity. This was considered sufficient on volcanic areas with highly magnetized rocks and where the geomagnetic gradient may be in excess of 1000 nT/m. Results averaged for each site generally show small variations in intensity (±3% of the total field) and direction (±1.5°). The averaged values of the 12 sites (I=52.6°, D=0.3°, F=44010 nT) are very close to those measured in sedimentary terrain away from the volcano (I=52.9°, D=0.35°, F=44110 nT), themselves consistent with the interpolated IGRF in eastern Sicily. The largest deviations of the geomagnetic direction have been observed on four sites, three of them located on the South flank between 1900 and 700 m elevation. It is suggested that these anomalies are mainly related to dyke swarms which are common within the South Rift Zone of Mount Etna. Our findings show that reliable archeomagnetic results can be obtained from volcanic rocks, provided that lavas of the same eruption are sampled on several sites distributed over the largest possible area.  相似文献   

16.
Nitrogen oxide (NOx) emissions from marine diesel engines pose a hazard to human health and the environment. From 2021, demanding emissions limits are expected to be applied to sea areas that the Royal Navy (RN) accesses. We analyze how these future constraints affect the choice of NOx abatement systems for RN ships, which are subject to more design constraints than civilian ships. A weighted matrix approach is used to facilitate a quantitative assessment.  相似文献   

17.
Soil H2 and CO2 surveys were carried out along seven active faults and around the aftershock region of the 2000 Tottori-ken Seibu earthquake in Japan. Diffuse CO2 effluxes were also measured along one fault and around the 2000 aftershock region. The results show highly variable H2 concentration in space and time and it seems that the maximum H2 concentration at each active fault correlates with fault activity as exemplified by the time of the latest big earthquakes. Even though observed H2 concentrations in four faults were markedly lower than those collected previously in the latter half of the 1970s, it is evident that the higher H2 concentrations in this study are due to the addition of the fault gases. Comparing the chemical composition of trapped gases (H2: 5–20% and CO2/H2: 0.5–12) in fractured rocks of drill cores bored at the Nojima fault, a soil gas sample with the highest H2 concentration showed large amounts of the trapped fault gas, diluted with atmospheric component. The profile experiment across a fracture zone at the Yamasaki fault showed higher H2 concentrations and lower CO2/H2 ratios as was observed in soil gas from the fracture zone. A few days after the 2000 Tottori-kei Seibu earthquake, no CO2 effluxes related to the occurrence of earthquakes were observed at the aftershock region. However, only above the epicenter zone, relatively high H2 concentrations in soil gases were observed.  相似文献   

18.
A system is proposed for the monitoring of changes in the underground structure of an active volcano over time by applying a transient electromagnetic method. The monitoring system is named ACTIVE, which stands for Array of Controlled Transient-electromagnetics for Imaging Volcano Edifice. The system consists of a transmitter dipole used to generate a controlled transient electromagnetic (EM) field and an array of receivers used to measure the vertical component of the transient magnetic field at various distances, with automatic operation of both units. In order to verify the performance of the proposed system, numerical and field experiments were carried out by application of the system to the Izu-Oshima volcano, where a remarkable change in the apparent DC resistivity over time had been detected in association with the eruption in 1986.  相似文献   

19.
The Alban Hills volcanic region (20 km south of Rome, in the Roman Province) emitted a large volume of potassic magmas (> 280 km3) during the Quaternary. Chemical interactions between ascending magmas and the ∼ 7000–8000-m-thick sedimentary carbonate basement are documented by abundant high temperature skarn xenoliths in the eruptive products and have been frequently corroborated by geochemical surveys. In this paper we characterize the effect of carbonate assimilation on phase relationships at 200 MPa and 1150–1050 °C by experimental petrology. Calcite and dolomite addition promotes the crystallization of Ca-rich pyroxene and Mg-rich olivine respectively, and addition of both carbonates results in the desilication of the melt. Furthermore, carbonate assimilation liberates a large quantity of CO2-rich fluid. A comparison of experimental versus natural mineral, glass and bulk rock compositions suggests large variations in the degree of carbonate assimilation for the different Alban Hills eruptions. A maximum of 15 wt.% assimilation is suggested by some melt inclusion and clinopyroxene compositions; however, most of the natural data indicate assimilation of between 3 and 12 wt.% carbonate. Current high CO2 emissions in this area most likely indicate that such an assimilation process still occurs at depth. We calculate that a magma intruding into the carbonate basement with a rate of ∼ 1 – 2 · 106 m3/year, estimated by geophysical studies, and assimilating 3–12 wt.% of host rocks would release an amount of CO2 matching the current yearly emissions at the Alban Hills. Our results strongly suggest that current CO2 emissions in this region are the shallow manifestation of hot mafic magma intrusion in the carbonate-hosted reservoir at 5–6 km depth, with important consequences for the present-day volcanic hazard evaluation in this densely populated and historical area.  相似文献   

20.
The method of reconstructing a phase space with higher dimensions can be applied to analysing the observaiton data for studying the dynamic behavior of seismic processes and earthquake prediction. It is found that seismic processes are chaotic. So earthquakes could be determinately predicted only within the predictable period. Here, some related problems (e.g. several primary parameters and the relations among them, the relation between the quality of used data and analytical results, the relation between a reductive process of the fractal dimensions and earthquake prediction and so on) are discussed. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,15, 470–476, 1993. This study was sponsored by the Chinese Joint Seismological Science Foundation under Contract NO. 9000007.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号