Detecting thermal anomalies within the Molasse Basin, southern Germany

The groundwater flow regime at great depth within the Molasse Basin (SW Germany) was studied. Data relevant for a flow model at 600–1,600 m depth are sparse in the western part of the basin. However, temperature measurements are available covering much of the area at a wide range of depths. Therefore, a thermal 3D steady-state model was set up with the aim of comparing modeled with observed subsurface temperatures. Stratigraphic information from many boreholes was also available, but only a few values of rock thermal conductivity and heat-production rate could be obtained. Some strong thermal residual anomalies were identified with respect to the purely conductive model, especially along fault zones, and within stratigraphic layers with high hydraulic conductivity. These anomalies can be explained by various advective heat-transport mechanisms, yet most explanations can be eliminated. The most plausible constellation explaining the major positive thermal anomalies of 10 Kelvin and more is a fault zone of E–W strike, intersected by an aquifer with flow parallel to the fault zone. This concept was investigated by using a simplified type model. In spite of some shortcomings, the method presented here can be used to identify temperature anomalies, and to identify possible explanations.     

Shallow high-resolution seismics and reprocessing of industry profiles in southern Bavaria: The Molasse and the northern Alpine front

The purpose of this seismic investigation in the Upper Bavarian Miesbach area, as part of the international TRANSALP project, was to study the tectonic contact between the autochthonous Foreland Molasse and the allochthonous Folded Molasse marking the tectonic front of the Alpine orogen. Another specific target was the dip of the frontal emerging main thrust of the tectonic units Helveticum/Ultrahelveticum and Rhenodanubian Flysch overriding the Folded Molasse. Twelve seismic profiles obtained from the hydrocarbon industry were reprocessed. From the Foreland Molasse southward to the Autochthonous Molasse in the subsurface of the overthrust Folded Molasse conspicuous features such as steep normal faults at the Molasse base, S-directed thickening of Molasse sediments or sedimentary discordant base of Upper Marine Molasse can be recognized.Shallow high-resolution seismic measurements were conducted along two profiles across the tectonic contact between Foreland Molasse and Folded Molasse, as well as along a profile across the frontal emerging main thrust of the Helveticum/Ultrahelveticum and the Rhenodanubian Flysch. Geological structures could be identified in the top 300–500 ms two-way traveltime interval, which is hardly possible with the usual deep-seismic method. The method thus provides a bridge between deep-reflection seismics and surface geology.In contrast to the western Bavarian Molasse zone, the tectonic boundary between the Foreland Molasse and the Folded Molasse in the investigated area is not characterized by a large blind-thrust triangle zone but by a simple south-dipping thrust plane. Adjacent to the S follow several steeply south-dipping inverse Molasse thrust slices and the Miesbach syncline. The inverse thrust slices are interpreted as the overturned and sheared northern limb of a fault propagation fold, which linked the Folded Molasse to the Foreland Molasse during a final orogenic phase.The main thrust of the Helveticum/Ultrahelveticum and the Rhenodanubian Flysch are well imaged in the near-surface interval of the high-resolution reflection seismic data. In contrast to previously published results, these thrust planes show a gentle dip to the S from the surface down to at least 500–1000 m depth.     

Constraints on Variscan granite emplacement in north-east Bavaria,Germany: further clues from a petrogenetic study of the Mitterteich granite

Petrochemical and Rb-Sr, K-Ar and Sm-Nd isotopic data presented for the Mitterteich granite provide information on whole rock and mineral compositional characteristics, intrusion and cooling history, and protolith nature and put further constraints on the Variscan magmatic evolution in north-east Bavaria.The compositional characteristics classify the Mitterteich granite as a peraluminous (monzo-)granite (SiO₂ 67.3–73.5 wt.% ). Values for K₂O/Na₂O (> 1.2 and Al₂O₃/(CaO + N₂O + K₂O) (>1.1) are in the range of S-type granites. The rare earth elements show fractionated chondrite-normalized patterns (La _N /Yb _N =24–19) with negative Eu anomalies (Eu _N /Eu _N ^*=0.35–0.19). The micas have restricted ranges of major element composition, but reveal notable variations in trace element concentrations. Different biotite fractions of single specimens show a trend to lower concentrations of compatible elements in the finer fraction which can be explained as a result of asynchronous growth during the fractionation process. The PT conditions of crystallization of the magma based on muscovite and biotite is 600–640°C at 3 kbar. Regression of the whole rock samples gives an isochron corresponding to a ⁸⁷Rb-⁸⁷Sr age of 310 ± 7 Ma, initial ⁸⁷Sr/⁸⁶Sr of 0.7104±0.0010 (2 errors) and MSWD =0.03. Muscovite and biotite yield concordant K-Ar ages between 310 and 308 Ma, indicating a fast cooling rate of the granite intrusion. _{Nd T310}values average –4.2±1.0. Nd model ages of 1.4 Ga suggest a source region of mid-Proterozoic age.The Rb-Sr isochron age and initial Sr ratio of the Mitterteich granite are indistinguishable from those of the adjacent Falkenberg granite, establishing a genetic link. However, the K-Ar mica ages suggest that the Mitterteich granite must have undergone a faster uplift or cooling history than Falkenberg. Confronted with the geochronological record of granite emplacement in north-east Bavaria, the new results substantiate the view of three key periods of magmatic activity around 330–325, 315–305 and 290 Ma.     

碳酸盐岩台内滩储层沉积特征、分布规律及主控因素研究:以阿姆河盆地台内滩气田为例

近年来,台内滩成为碳酸盐岩油气勘探的重点领域,并取得了一系列重大进展。本文以阿姆河盆地右岸地区中上侏罗统碳酸盐岩台内滩气田为例,在地震、测井、录井、岩心、薄片及分析化验等资料详细研究的基础上,对台内滩类型、沉积特征及储层特征进行了分析,并重点研究了影响台内滩储层发育及分布的控制因素。结果表明:(1)研究区台内滩主要包括生屑滩、内碎屑滩、球粒滩、藻粒滩和鲕粒滩等5种类型。(2)剩余原生粒间孔,次生的粒间、粒内溶孔及溶蚀孔洞为主要储集空间,形成以孔隙型和孔洞型为主的两类台内滩储层。(3)储层发育及分布明显受古地貌、相对海平面变化及溶蚀作用等多种因素控制:(1)古地貌是台内滩发育的重要基础,在基底古隆起发育的古地貌高部位滩体连片分布,形成规模型台内滩储集体;(2)相对海平面变化对台内滩储层的发育层位及滩体类型具有重要的控制作用,台内滩储层主要发育于高位域准层序组中上部,由下至上呈现出厚度增大、物性变好等特征,海平面高频震荡导致台内滩垂向上多期叠置;(3)包括同生期淡水淋滤及埋藏期溶蚀等多期次、多类型溶蚀作用是台内滩储层形成的关键,次生溶蚀孔隙、孔洞成为台内滩重要的储集空间,最终形成优质的孔隙(洞)型台内滩储层。     

Water leakage from the power tunnel of Gezende Dam,southern Turkey: a case study

This study covers the investigations of the reasons of deformations and leakages in the energy tunnels of Gezende Dam constructed in 1990 for hydroelectric energy and the recommendations for treatments of the problems. Gezende Dam is located 30 km southwest of Mut county/Mersin in southern Turkey. The dam is concrete arch type with a height of 72 m. The energy tunnel with an approximate length of 9 km passes through six different geological units in age of Mesozoic to Cenozoic. After a short period of time of the operation of the tunnel, leakage has started from the section of gypsum, which is intercalated with dolomitic limestone between chainage from 5,970 to 6,840 m. The deformations have occurred in the concrete tunnel and springs have been detected at different places and times through the Ermenek Canyon since 1996. The preventive precautions of the water effect caused by groundwater effect on gypsum are as follows: (1) contact and consolidation grouting in the tunnel between chainage from 5,910 to 6,840 m, (2) removal of damage on the tunnel line, (3) reinforcement of the tunnel again, and (4) application of new concrete lining. Besides, a drainage gallery of 320 m was excavated in the 23 m lower and 15 m left part of tunnel base elevation in order to diminish the effect of groundwater in the section where the deformation occurred.     

Nitric oxide emissions from soils: a case study with temperate soils from Saxony, Germany

Nitrogen oxides (NO _x ) are involved in acid rain and ozone formation, as well as destruction. NO _x are climate-relevant trace gases in the atmosphere. Atmospheric NO _x originate from anthropogenic emissions (mainly combustion processes). NO from natural processes derives from thunderstorms and soil microbial processes. They may play a crucial role in soil?Catmosphere feedback processes. This study aims to investigate NO _x -emissions from soils under different land use, geographical and meteorological conditions. NO _x -emissions were quantified in both field and laboratory experiments with a closed static chamber. Disturbed soil samples have been used for laboratory experiments. A climate chamber was used to regulate soil temperature of the samples. Field experiments showed that NO-soil emissions strongly depend on soil temperature. NO-emissions from a soil under meadow showed significant daily variations, unlike soil below spruce forest. Peak emission values were 18???g NO?CN?m^?2?h^?1 above meadow and 1.3???g NO?CN?m^?2?h^?1 under forest canopy. In addition, NO-emissions of meadow and forest soil were studied in a climate chamber, enhanced by an additional experiment with agricultural soil. These experiments revealed strong exponential correlations of NO-emissions and soil temperature. Maximum values reached above 400???g NO?CN?m^?2?h^?1 from agricultural soils at soil temperatures above 50°C. This study shows that soil NO-emissions strongly depend on temperature, vegetation type and geographical position. Consequently, NO-emissions may have a positive feedback effect on climate change.     

Elemental characteristics and paleoenvironment reconstruction: a case study of the Triassic lacustrine Zhangjiatan oil shale,southern Ordos Basin,China

Using trace elements to reconstruct paleoenvironment is a current hot topic in geochemistry. Through analytical tests of oil yield, ash yield, calorific value, total sulfur, major elements, trace elements, and X-ray diffraction, the quality, mineral content, occurrence mode of elements, and paleoenvironment of the Zhangjiatan oil shale of the Triassic Yanchang Formation in the southern Ordos Basin were studied. The analyses revealed relatively high oil yield (average 6.63%) and medium quality. The mineral content in the oil shale was mainly clay minerals, quartz, feldspar, and pyrite; an illite–smectite mixed layer comprised the major proportion of clay minerals. Compared with marine oil shale in China, the Zhangjiatan oil shale had higher contents of quartz, feldspar, and clay minerals, and lower calcite content. Silica was mainly in quartz and Fe was associated with organic matter, which is different from marine oil shale. The form of calcium varied. Cluster analyses indicated that Fe, Cu, U, V, Zn, As, Cs, Cd, Mo, Ga, Pb, Co, Ni, Cr, Sc, P, and Mn are associated with organic matter while Ca, Na, Sr, Ba, Si, Zr, K, Al, B, Mg, and Ti are mostly terrigenous. Sr/Cu, Ba/Al, V/(V + Ni), U/Th, AU, and δU of oil shale samples suggest the paleoclimate was warm and humid, paleoproductivity of the lake was relatively high during deposition of the shale—which mainly occurred in fresh water—and the paleo-redox condition was dominated by reducing conditions. Fe/Ti ratios of the oil shale samples suggest clear hydrothermal influence in the eastern portion of the study area and less conspicuous hydrothermal influence in the western portion.     

Sealing of fluid pathways in overpressure cells: a case study from the Buntsandstein in the Lower Saxony Basin (NW Germany)

We studied veins in the Triassic Buntsandstein of the Lower Saxony Basin (NW Germany) with the aim of quantifying the evolution of in-situ stress, fluids and material transport. Different generations of veins are observed. The first generation formed in weakly consolidated rocks without a significant increase in fracture permeability and was filled syntectonically with fibrous calcite and blocky to elongate-blocky quartz. The stable isotopic signature (δ¹⁸O and δ¹³C) indicates that the calcite veins precipitated from connate water at temperatures of 55–122°C. The second vein generation was syntectonically filled with blocky anhydrite, which grew in open fractures. Fluid inclusions indicate that the anhydrite veins precipitated at a minimum temperature of 150°C from hypersaline brines. Based on δ³⁴S measurements, the source of the sulphate was found in the underlying Zechstein evaporites. The macro- and microstructures indicate that all veins were formed during subsidence and that the anhydrite veins were formed under conditions of overpressure, generated by inflation rather than non-equilibrium compaction. The large amount of fluids which are formed by the dehydrating gypsum in the underlying Zechstein and are released into the Buntsandstein during progressive burial form a likely source of overpressures and the anhydrite forming fluids.     

基于多元逐步回归分析的煤储层含气量预测模型——以沁水盆地为例

以沁水盆地为例,运用多元逐步回归分析方法,建立了以Langmuir体积和含气饱和度为参数的含气量预测模型;复相关系数、F检验、t检验结果表明,该模型满足线性与方差齐性的假设,拟合效果较好。运用此模型,结合多因素权重分析确定的含气饱和度和实测的Langmuir体积数据,实现了沁水盆地山西组主煤层含气量预测。对比分析显示,该含气量预测模型有一定的可行性。     

Modelling seasonal variations of natural radioactivity in soils: A case study in southern Italy

The activity of natural radionuclides in soil has become an environmental concern for local public and national authorities because of the harmful effects of radiation exposure on human health. In this context, modelling and mapping the activity of natural radionuclides in soil is an important research topic. The study was aimed to model, in a spatial sense, the soil radioactivity in an urban and peri-urban soils area in southern Italy to analyse the seasonal influence on soil radioactivity. Measures of gamma radiation naturally emitted through the decay of radioactive isotopes (potassium, uranium and thorium) were analysed using a geostatistical approach to map the spatial distribution of soil radioactivity. The activity of three radionuclides was measured at 181 locations using a high-resolution ?-ray spectrometry. To take into account the influence of season, the measurements were carried out in summer and in winter. Activity data were analysed by using a geostatistical approach and zones of relatively high or low radioactivity were delineated. Among the main processes which influence natural radioactivity such as geology, geochemical, pedological, and ecological processes, results of this study showed a prominent control of radio-emission measurements by seasonal changes. Low natural radioactivity levels were measured in December associated with winter weather and moist soil conditions (due to high rainfall and low temperature), and higher activity values in July, when the soil was dry and no precipitations occurred.     

Determination of horizontal extension from fissure-ridge travertines: a case study from the Denizli Basin,southwestern Turkey

Travertine deposits reflect some aspects of the regional tectonics because of the close association between travertine deposits and active fractures, that later of which provide conduits along which travertine-depositing waters may rise. Fissure-ridge travertines form above extensional fissures which are located in the hanging walls of normal faults, in step-over zones between fault segments, or in active or recently active) volcanic provinces. Numerous active and inactive fissure-ridge travertines are located in the hanging walls of normal faults in the Denizli Basin. A typical fissure-ridge comprises a central fissure along its long axis and flanking bedded travertines dipping away from the fissure. Central fissures of travertine ridges have been dilating since the initiation of the fissures. Samples from both the margins and centres of banded travertine deposits were dated by Th/U methods in order to determine dilation rates. Individual fissures have been dilating at average rates of between 0.008 and 0.1 mm yr^–1 during travertine deposition, and ~ 0.001 and 0.007 mm yr^–1 after cessation of travertine deposition. There is a noticable decrease in dilation rate from west to east in the Denizli Basin, and this decrease in dilation rate may be related to decrease in overall extension in southwest Turkey, which decreases eastward.     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

Growth-strata geometry in fault-propagation folds: a case study from the Gafsa basin, southern Tunisian Atlas

The structural and sedimentological study of fault-propagation folds in Southern Tunisia highlights a special geometry of the growth strata (strata deposited simultaneously with the formation or growth of a fold). This distinct geometry is visible in the uppermost growth-strata beds and consists of one flank with unconformity as opposed to the other flank with perfect conformity. This geometry can be explained by the mechanism of fault-propagation folding, with asymmetrical flank dips and hinge migration kinematics. This kinematics was originally predicted by the fault-propagation fold model, which facilitates the study of this special geometry in a narrow domain of sedimentation-to-shortening ratios. A plot projection provides a generalisation of the results of all types of fault-propagation folds by revealing the expected geometry of the growth strata. This study constitutes one of the most complete examples of kinematic model validation on a field scale.     

柴达木盆地石灰沟地区 下古生界碳酸盐岩储层特征及控制因素

基于对柴达木盆地石灰沟地区下古生界野外剖面的踏勘实测及样品采集,综合应用薄片观察、扫描电镜,以及常规物性分析方法,对下古生界碳酸盐岩储层的储集特征及控制因素进行了研究。研究结果表明:储层原生孔隙不发育,物性相对较差,但次生孔隙,如溶蚀性孔洞、裂缝及孔洞-裂缝等孔隙类型优势发育;储层性质的控制因素主要为岩石组构、成岩演化和构造运动等。通过对各种因素的综合分析,认为储层的孔喉结构是以原生孔隙为基础,经后期复杂的成岩作用及多期构造叠加改造而成的;先期的溶蚀是受岩石组构控制的选择性溶蚀,而后期构造运动产生的缝隙是溶蚀性储层发育的关键因素。     

Spatial response patterns of subtropical forests to a heavy ice storm: a case study in Poyang Lake Basin,southern China

Natural Hazards - In early 2008, an unexpected ice storm hits southern China, severely affected the subtropical forest ecosystems. We used the moderate resolution imaging spectroradiometer products...     

Geochemical diagnostics of metasedimentary dark enclaves: a case study from the Peninsular Ranges Batholith,southern California

Dark enclaves rich in amphibole and biotite are ubiquitous in granitoid rocks and typically represent fragments of mafic magmas, cumulates, restites, or country rocks. To develop criteria for identifying dark enclaves of non-magmatic origin, we investigated dark enclaves from a complete spectrum of light (carbonate- or feldspar-rich) to dark (amphibole-rich, biotite-rich, or composite) enclaves, reflecting progressive thermal and chemical equilibration with the host tonalite, the Domenigoni Valley pluton in the Peninsular Ranges Batholith, California. Metasedimentary dark enclaves have geochemical characteristics that overlap those of literature-compiled igneous dark enclaves. When compared with modelled igneous differentiation paths, metasedimentary enclaves can have anomalous CaO and K₂O contents for a given SiO₂, but other major-element systematics may not deviate noticeably from igneous differentiation trends. In addition, the fact that literature-compiled mafic enclaves trend towards high K₂O + CaO suggests that not all mafic enclaves are of igneous origin. In this work, we provide criteria for identifying enclaves of possible metasedimentary origin.     

Environmental degradation assessment in arid areas: a case study from Basra Province, southern Iraq

Evaluation of recent land degradation affecting Basra Province, Iraq, resulted in the identification of five prominent environmental degradation processes: desertification, secondary salinization, urbanization, vegetation degradation, and loss of wetlands. This analysis was carried out using ‘3S’ technologies [remote sensing, geographic information system (GIS), and global position system], with the layers extracted and manipulated from available topographic, climatic, and soil maps, as well as satellite image (thematic mapping in 1990 and enhanced thematic mapping in 2003) and field survey data analyses. Rates of conversion were calculated and distribution patterns were mapped with the aid of a GIS. The results revealed that land use changes have affected the wider environment and accelerated land degradation, with severe damage located in southwestern Basra Province representing 28.1 % of the total area. Areas of high to moderate degradation characterize the rest of the south, representing 52.7 % of the total area; while the north of the study region is characterized by very low and low degradation levels accounting for 8.5 and 10.7 %, respectively. Iraq faces serious environmental degradation problems that must be addressed immediately; failure to do so will greatly compound the cost and complexity of later remedial efforts, with environmental degradation beginning even now to pose a major threat to human well-being, especially among the poor.     

Electrofacies in gas shale from well log data via cluster analysis: A case study of the Perth Basin,Western Australia

Identifying reservoir electrofacies has an important role in determining hydrocarbon bearing intervals. In this study, electrofacies of the Kockatea Formation in the Perth Basin were determined via cluster analysis. In this method, distance data were initially calculated and then connected spatially by using a linkage function. The dendrogram function was used to extract the cluster tree for formations over the study area. Input logs were sonic log (DT), gamma ray log (GR), resistivity log (IND), and spontaneous potential (SP). A total of 30 reservoir electrofacies were identified within this formation. Integrated geochemical and petrophysics data showed that zones with electrofacies 3, 4, 9, and 10 have potential for shale gas production. In addition, the results showed that cluster analysis is a precise, rapid, and cost-effective method for zoning reservoirs and determining electrofacies in hydrocarbon reservoirs.