摩洛哥伊米泰尔(Imiter)浅成低温热液型银矿床地质特征与成因

伊米泰尔(Imiter)银矿床位于摩洛哥小阿特拉斯山地区,是世界级超大型浅成低温热液银矿床。矿区内矿化主要受伊米泰尔断裂带控制,矿化期可以分为以下两期:(1)贱金属矿化期(BME),与Taouzzakt花岗闪长岩(572±5Ma)有关,(2)浅成低温热液矿化期(ESE),与Takhatert流纹岩(550±3Ma)有关。通过He、S、Os同位素研究,伊米泰尔矿床的成矿物质和成矿流体都具有幔源的特征,其成矿模式表现出地幔来源的浅成低温热液成矿模式。     

Modèle de formation du gisement d'argent d'Imiter (Anti-Atlas oriental,Maroc). Nouveaux apports de l'analyse structurale et minéralogique

Based on a combined geometrical and mineralogical analysis, a three-stage model of formation of the mineralized veins of the giant Imiter silver deposit (Anti-Atlas, Morocco) is herein proposed. A first episode is characterized by the development of quartz, pink dolomite and Ag-rich minerals veins formed during a dextral transpressive event. The second episode is associated with a normal left-lateral motion that re-opens previous structures, filled by pink dolomite gangue. Alteration stages contribute to a local Ag enrichment. To cite this article: J. Tuduri et al., C. R. Geoscience 338 (2005).     

Mineralogy, Geochemistry, and Age Constraints on the Beni Bou Ifrour Skarn Type Magnetite Deposit, Northeastern Morocco

Abstract: The Beni Bou Ifrour deposit of northeastern Morocco is a skarn type magnetite deposit. K-Ar age determination suggests that the mineralization occurred at 7.040.47 Ma. The spatial relationship between skarn and dikes of microgran-odiorite derived from the batholith of Wiksane Granodiorite, and the similarity of age (8.020.22 Ma), confirms that the Wiksane Granodiorite is the igneous rock most probably related to mineralization. The skarn is distributed asymmetrically in the limestone, and magnetite ore was developed just below the calc-silicate skarn as two parallel beds separated by 100 m of barren limestone and schist.
The mineralization can be divided into three stages. The early stage is characterized by the formation of calc-silicate minerals, mainly clinopyroxene (80–70 % diopside) and garnet (early almost pure andradite to the late 60 % andradite). The main stage is characterized by the formation of a large amount of magnetite. Epidote and quartz formed simultaneously with magnetite. Fluid temperatures exceeded 500 C during the early to main stages. Fluid with very high salinity (50–75 wt% NaCl equiv.) was responsible for the formation of the magnetite ore. The oxygen isotope composition, together with the fluid inclusion data, suggests that magmatic fluid was significant for the formation of calc-silicate skarn minerals and magnetite. Low temperature (-230C) and low salinity (-10 % NaCl equiv.) hydrothermal fluids dominated by meteoric water were responsible for the late stage quartz and calcite formation.     

Gold–palladium mineralization at Bleïda Far West, Bou Azzer–El Graara Inlier, Anti-Atlas, Morocco

The structurally controlled Au–Pd mineralization at Bleïda Far West occurs in a volcano-sedimentary rock sequence in altered amphibolites and chlorite schists of the Neoproterozoic Bou Azzer–El Graara inlier. The Au–Pd mineralization is virtually sulfide-free; instead, gold is associated with hematite, barite, quartz, and calcite. The gold grains are silver- and palladium-bearing (up to 19 wt% Ag and 6.3 wt% Pd) and are intergrown with a distinct suite of mainly Pd-dominated platinum group minerals, namely mertieite-I/isomertieite, merenskyite, keithconnite, kotulskite, palladseite, and sperrylite, defining a Au–Pd–As–Sb–Se–Te chemical signature. Stable isotope and fluid inclusion studies indicate a wide range of fluid compositions with a prominent saline component. In conjunction with the mineral association, oxidizing fluids are indicated, and Au and PGE transport and deposition likely took place by chloride complexes in the epithermal range, at elevated f O₂ and/or low pH. It is still speculative whether the mineralization is late Pan-African (～600–550 Ma) in age, or connected with the Variscan orogeny (～330–300 Ma), or related to some other hydrothermal event. Common to all Au–Pd mineralizations worldwide (Brazil, Australia, UK), including Bleïda Far West, is their formation in the epithermal (<300°C) range; deposition mainly in brittle structures; sulfide-poor mineral assemblages comprising hematite, sulfate minerals, and selenides; and metal transport by, and deposition from, oxidized, chloride-rich fluids. These deposits are further characterized by noble metal abundances in the order Au>Pd>Pt and the chemical signature Au–Pd–Se–Te (±As, Sb, Bi). As such, the Au–Pd association represents a discrete style of gold mineralization distinct from other classes of gold deposits.     

Petrology and geodynamic significance of the post-collisional Pan-African magmatism in the Eastern Saghro area (Anti-Atlas, Morocco)

The Saghro Group consists of a thick volcanic-sedimentary sequence with intercalated basaltic lavas, the first magmatic event in eastern Saghro area. Nd isotopes of basaltic pillow lavas show T_DM model ages ranging from 640 to 580 Ma, which represent a maximum age for basalt eruption.Granitoids within the Saghro Group consist of a charnockitic suite, tonalites, granodiorites and monzogranites. They are high-K calc-alkaline (HKCA) with a post-collisional character, and were emplaced at high-levels in the crust. Their ages of emplacement are within the 580–560 Ma bracket, implying that the entire Saghro Group is slightly older than or partly coeval to granitoid emplacement and implying a common geodynamical setting. Sr–Nd isotopic compositions and Nd T_DM model ages point to a mixed origin, combining a juvenile mantle source and an Eburnean crustal component, which could be the West African Craton (WAC). The juvenile component in the Saghro granitoids could be the depleted upper mantle that has sourced the earlier basalts.Field observations, geochemical and geochronological data together support that, during the Pan-African orogeny, the Anti-Atlas was subjected to a regional transpressional to transtensional event. This event would have been responsible for the dissection of the northern margin of the WAC into several blocks, the development of deep sedimentary basins and the emplacement of HKCA magmas.     

Development of igneous layering during growth of pluton: The Tarçouate Laccolith (Morocco)

We discuss the significance of igneous layering with respect to pluton growth processes. The case study is the Tarçouate Laccolith (Morocco), whose core consists of modally layered hornblende granodiorites with high amount of monzodioritic enclaves, contrasting with peripheral, non-layered biotite granodiorites with low amount of enclaves. Rhythmic layering, with modal grading, cross-stratification and trough layering is associated with monzodioritic layers and wraps around mafic enclaves. Its steep dips ≥ 45° result from tilting that occurred above solidus conditions, as indicated by sub-vertical and synmagmatic granite, aplite and monzodiorite dykes cutting across the layering.The systematic association of igneous layering with mafic enclaves in calc-alkaline plutons suggests that layering originates from recurrent injection of mafic magma. Viscosity calculations suggest that the physicochemical properties of magma alone cannot account for the presence of layering in the central hornblende granodiorite and its coeval absence in the peripheral biotite granodiorite of the Tarçouate Laccolith. Intermittent pulses of hot mafic magma into crystallizing granodiorite likely produced thermal perturbations able to trigger local convection, formation of mafic enclaves and development of igneous layering through protracted crystallization.     

Magma–host interactions during differentiation and emplacement of a shallow-level, zoned granitic pluton (Tarçouate pluton, Morocco): implications for magma emplacement

The Tarçouate pluton (Anti-Atlas, Morocco) is an inversely zoned laccolith emplaced 583 Ma ago into low-grade metasediments, with the following succession: leucocratic granites, biotite–granodiorites (±monzodiorites), hornblende–granodiorites (±monzodiorites) and monzodiorites syn-plutonic dykes. These rocks form two distinct, chemically coherent, units:

(1) A main unit consists of layered (572<59 wt.%) and homogeneous (632<67%) hornblende–granodiorites, biotite–granodiorites (672<72%) and aplites (702<76%). All these rocks are metaluminous to peraluminous and display fractionated HREE depleted patterns (La/Yb_N=14–61; Yb_N=0.7–6.8). Initial ⁸⁷Sr/⁸⁶Sr ratios (0.7072 to 0.7080) increase, whereas _Nd(t) values (−1.7 to −2.8) decrease from the hornblende– to the biotite–granodiorites. Monzodiorites occur as mafic microgranular enclaves or syn-plutonic dykes.

(2) A subordinate unit consists of leucocratic, distinctly peraluminous, muscovite-bearing granites (722<75%) occurring at the northern edge of the pluton and as dykes in the surrounding schists towards the top of the pluton. These rocks are free of monzodioritic enclaves. They display less fractionated patterns with higher HREE contents (La/Yb_N=2–19; Yb_N=11–18), a distinct _Nd(t) value (−11.8) and a ⁸⁷Sr/⁸⁶Sr initial ratio (0.7480) within those of the surrounding schists (0.7393–0.7819).

Magma–host interactions are closely related to differentiation and occurred at different levels, but mainly before emplacement. Field relationships and petrogenetic modelling show that the bt–granodiorites formed at levels deeper than the level of emplacement, by fractional crystallisation (0.65

These data preclude any significant material transfer process for the emplacement of the Tarçouate pluton, but rather suggest assembly of successive pulses of variably differentiated crystal-poor magmas. These shallow level granitic plutons can be considered as an end-member of magma emplacement with minimum interactions with the country rocks.     

Calc-alkaline Arc I-type Granitoid Associated with S-type Granite in the Pan-African Belt of Eastern Anti-Atlas (Saghro and Ougnat, South Morocco)

The Sidi Flah and Ougnat inliers are located in the eastern Anti-Atlas antiform between the Anti-Atlas Major Fault (AAMF) and South Atlas Fault (SAF). They consist of many granitoid intrusions emplaced into Neoproterozoic metasedimentary rocks and surmounted by upper Neoproterozoic A-type granites. The Sidi Flah (Saghro) and Ougnat granitoids are part of the Neoproterozoic magmatic activity related to northwards subduction of an oceanic plate beneath the Saghro continental margin. They are post-orogenic I- and S-type granitoids related to the ending of the compressional deformation in this Pan-African belt. A petrographic, geochemical and zircon typology study leads us to subdivide these rocks into three magmatic groups: (1) a medium- to high-K calc-alkaline group formed by quartz diorites and amphibole granodiorites is found in both Sidi Flah and Ougnat inliers; (2) a high-K calc-alkaline group is present in Sidi Flah. These two groups have a (deeper and) hybrid mantle-crust origin; (3) a peraluminous group in Ougnat is linked to the post-collisional setting and has a shallow crustal source. On a primitive mantle-normalized trace-element diagram, almost all of these rocks show a significant Nb depletion relative to K and La, which is typical of the calc-alkaline magmatism from the subduction-zone environment. Absence of structural marks of thrusting upon the West African craton (WAC) of this arc system and the ophiolitic suite in Bou-Azzer, and the presence of Imiter muscovite-bearing granite as part of Pan-African belt do not support the localization of northern limit of WAC at the level of SAF.     

Geological mapping and mining prospecting in the Aouli inlier (Eastern Meseta,Morocco) based on remote sensing and geographic information systems (GIS)

Landsat 8 Oli, ASTER, and Sentinel 2A satellite images processing was used to map geological formations, lineaments and hydrothermal alteration minerals in the Aouli inlier, as a case study to illustrate the application of digital images processing and Geographic Information System (GIS) in geological mapping and mining prospecting. Principal Component Analysis (PCA) applied to the Landsat images allowed good lithological discrimination and contributed to the updating of available geological maps. The Automatic lineament extraction from Sentinel images revealed the main tectonic structures affecting Aouli inlier. The ratio bands (b5+b7)/b6 and the false color composite (b4/b6, b2/b1, b3/b2) allowed the hydrothermal alteration minerals mapping from Aster images. Combined with available geological data and field observations, the satellite derived data were integrated and analyzed in a GIS software to establish mining prospecting guides. The results showed that the anomaly zones are intimately linked to NNE –SSW and NW –SE oriented faults and to highly fractured areas developing argillic and Fe rich alterations. Verified via field survey, this approach was successfully applied to the Aouli inlier to rapidly target potential areas to be explored in the tactical phase. This provides a model for future prospecting efforts for similar mineral deposits in other areas.©2022 China Geology Editorial Office.     

The Anti-Atlas Pan-African Belt (Morocco): Overview and pending questions

Between the High Atlas and the Saharan platform, the Anti-Atlas of Morocco offers large exposures of Precambrian rocks beneath the moderately folded Paleozoic series. These inliers allow reconstructing a segment of the Pan-African Belt and of its foreland at the northern outskirts of the West African Craton (WAC). From ∼ 885 Ma to ∼ 540 Ma, three periods are recognized in the Pan-African cycle. The Tonian–Cryogenian period ends with the obduction of supra-subduction ophiolite and oceanic arc material at ∼ 640 Ma. The Early Ediacaran period is marked by the development and subsequent closure of a wide marginal basin next to a likely Andean-type arc. The Late Ediacaran period is recorded by subaerial molasse deposits associated with post-collisional high-K calc-alkaline to shoshonitic magmatism. Although a wide consensus has been reached based on the number of new robust datings, several questions still remain pending, which we address taking into account relevant African and European correlations.     

The Neoproterozoic volcanic complex of the Boumalne inlier (Saghro massif,Eastern Anti-Atlas; Morocco): petrological and geochemical characteristics

Neoproterozoic volcanic series are exposed in the northern edge of the Saghro massif (Eastern Anti-Atlas, Morocco). Four volcanic rock types (basalt, andesite, dacite, and rhyolite) were distinguished in the Boumalne inlier within the so-called Saghro volcanic sequences based on petrographic and geochemical observations. Boumalne volcanic rocks contain high Al₂O₃, Fe₂O₃, Ba, Sr, Zr, Rb, and Nb contents, including calc-alkaline affinity in composition. Boumalne volcanic rocks are similar to other lower-Neoproterozoic volcanic rocks such Agouiniy formation in Sirwa inlier and in other parts of Bou-Azzer inlier. Indeed, they indicate an active subduction signature. The geochemical data show a LREE enrichment compared to HREE. The fractional crystallization has played a major role during the evolution of the magma. The less-siliceous dacitic rocks could have been formed after a low degree of partial melting of mafic parental magma source, whereas the rich-siliceous rhyolite may have been derived from dacitic magma source by a higher degree of fractional crystallization.     

Contribution to a geodynamic reconstruction of the Anti-Atlas (Morocco) during Pan-African times with the emphasis on inversion tectonics and metallogenic activity at the Precambrian–Cambrian transition

New geochronological analyses (U–Pb SIMS zircon ages) have yielded ages of 552 ± 5 Ma for the Bou Madine rhyolitic dome (Ougnat, eastern Anti-Atlas), 543 ± 9 Ma for the Tachkakacht rhyolitic dyke (Saghro–Imiter, eastern Anti-Atlas), and 531 ± 5 Ma for the Aghbar trachytic sill (Bou Azzer, central Anti-Atlas). Inherited zircon cores from the Aghbar trachytic sill and from the Bou Madine rhyolitic dome have been shown to be of Statherian age (ca. 1600–1800 Ma) and Palæoproterozoic (>2100 Ma) age, respectively, suggesting that a significantly older protolith underlies the Pan-African rocks in the Central and Eastern Anti-Atlas. Granodiorites and rhyolites from the Saghro–Imiter area have similar low ⁸⁷Sr/⁸⁶Sr (0.702–0.706) and ¹⁴³Nd/¹⁴⁴Nd (0.5116–0.5119) initial ratios, suggesting a mixture of mantle and lower crust sources. This can also be inferred from the low ¹⁸⁷Os/¹⁸⁸Os ratios obtained on pyrite crystals from the rhyolites.A recently published lithostratigraphic framework has been combined with these new geochemical and geochronological data, and those from the literature to produce a new reconstruction of the complex orogenic front that developed at the northern edge of the Eburnian West African craton during Pan-African times. Three Neoproterozoic magmatic series can be distinguished in the Anti-Atlas belt, i.e., high-K calc-alkaline granites, high-K calc-alkaline to shoshonitic rhyolites and andesites, and alkaline-shoshonitic trachytes and syenites, which have been dated at 595–570, 570–545 and 530 Ma, respectively.The accretion of the Pan-African Anti-Atlas belt to the West African super continent (WAC) was a four-stage event, involving extension, subduction, moderate collision and extension. The calc-alkaline magmatism of the subduction stage was associated with large-scale base metal and gold mineralisation. Metallogenic activity was greatest during the final extensional stage, at the Precambrian–Cambrian boundary. It is characterised by world-class precious metal deposits, base–metal porphyry and SEDEX-type occurrences.     

四川会理拉拉IOCG矿床萤石氢氧同位素特征研究

正氢、氧(H、O)同位素在地质学领域被广泛应用于成矿流体的来源与演化方面的研究(郑永飞等,2000, Deng J et al., 2009),其同位素值可用于直接与自然界水组成范围进行比较,由此指示从成矿早阶段到晚阶段流体的混合特征(徐九华等,2011)。四川拉拉IOCG矿床位于扬子地块西南缘,矿区地层主要包括:下元古界河口群(Pt_1hk)、会理群通安组(Pt_1t)、上三叠统白果湾组(T_3b,图1)。     

埃达克岩与皖中沙溪斑岩铜矿的成矿作用

埃达克岩是一组从安山质到长英质系列岩石,具有高硅(≥56%)、富钠(3.5%≥Na2O≥7.5%)及低的K2O/Na2O(～0.42),高Mg#(～0.51)和高Ni(20×10-6～40×10-6和Cr(30×10-6～50×10-6)的岩浆岩;其主要特点还有高锶(>400×10-6,最高可以达到3000×10-6,轻重稀土强烈分异((La/Yb)N＞10)以及非常低的重稀土元素含量(Yb＜1.8×10-6,Y≤18×10-6,具有明显Nb、Ta负异常的火山岩和侵入岩.埃达克岩构造环境仍存在很多争议.主要的观点:(1)年轻的俯冲洋壳(＜25 Ma)在俯冲过程中脱水熔融;2)加厚下地壳环境下的镁铁质下地壳(如榴辉岩和石榴辉石岩)底垫岩浆作用或拆沉作用下熔融.与埃达克岩石有关的矿产资源主要为铁、铜、金、钼矿床.在对安徽省沙溪斑岩型铜金矿床岩石和同位素地球化学资料分析和处理基础上,笔者认为沙溪侵入岩属于埃达克岩,其成因是燕山晚期西太平洋板块俯冲至扬子地块深部所导致的洋壳板片熔融作用有关,洋壳俯冲过程的大量流体参与,所携带的幔源大离子亲石元素及铜金物质在地壳浅部形成adakite岩石,同时形成该区斑岩型铜金矿床.     

Refining the Stratigraphy of the Taghdout Group by Using the U-Pb Geochronology of the Taghdout Sill(Zenaga inlier,Anti-Atlas,Morocco)

正The Anti-Atlas belt of southern Morocco is situated on the northern edge of the West African craton(WAC).It corresponds to a broad anticlinorium some 800 km long and 200 km wide,trending ENE-WSW,parallel to the     

The polymetallic Au–Ag-bearing veins of Bou Madine (Jbel Ougnat, eastern Anti-Atlas, Morocco): tectonic control and evolution of a Neoproterozoic epithermal deposit

The Bou Madine ore deposit is located SW of Jbel Ougnat, the easternmost inlier of the Anti-Atlas Pan-African belt in Morocco. The host rocks are high-K calc-alkaline volcanic rocks, that are part of the Neoproterozoic Tamerzaga-Timrachine Formation (TTF, lower PIII). The TTF consists of ignimbrites of rhyolitic to dacitic compositions, andesite flows and hypovolcanic bodies (andesite dykes and rhyolite chonoliths) emplaced along N160°E tension gashes associated with a regional N30°E sinistral fault system. The mineralization is related to a high enthalpy geothermal system, eventually evolving into a low temperature epithermal system. A regional propylitisation (T around 260 °C) overprinted the TTF rocks prior to the emplacement of the mineralization. There were two main hydrothermal stages. During the first stage, massive veins with pyrite, arsenopyrite and minor pyrrhotite and cassiterite were formed. The veins were emplaced along N160°E-trending en echelon joints related to N120°E dextral arrays. A quartz-sericite-pyrite alteration overprinted the propylites around the veins (“bleached haloes”), at temperatures up to 300–310 °C. The second stage of mineralization was coeval with dextral re-activation of the N160°E veins, in relation with a NE-ward shift of the shortening direction. First, polymetallic sulphides (sphalerite, chalcopyrite, stannite, galena) were deposited at temperatures 260 °C. Younger quartz veinlets contain arsenopyrite and minor micrometre-size sulphides and sulpho-salts, hosting the precious metals. This was the low temperature epithermal stage (≈150 °C), in relation with invading meteoric water.     

秘鲁阿雷基帕省阿蒂科铁氧化物铜金矿床成矿流体特征及来源

秘鲁阿蒂科矿床是一个铁氧化物铜金矿床。含矿石英脉的流体包裹体均一温度为107~389℃,盐度为2.2%~23.18%NaCl。均一温度数据呈近似正态分布,但是,盐度数据总体不呈正态分布,且盐度较低,主要集中于0~10%NaCl和20%~30%NaCl之间。矿床δD_(V-SMOW)和δ ~(18)O_(H_2O)的组成投影点靠近雨水线,反映该矿床成矿流体为大气降水来源。     

Pyroxenite xenoliths and clinopyroxene megacrysts from the Cenozoic Jbel Saghro Volcanic Field (Anti-Atlas,Morocco): Petrography,mineral chemistry and equilibration conditions

A suite of mafic pyroxenite xenoliths and clinopyroxene megacrysts was brought to the surface by Cenozoic nephelinites of the Jbel Saghro Volcanic Field (Anti-Atlas, Morocco). The large population of samples was subdivided into five groups: (i) clinopyroxenites sensu stricto; (ii) olivine clinopyroxenites; (iii) mica-bearing clinopyroxenites; (iv) kaersutite-bearing clinopyroxenites; (v) clinopyroxene megacrysts. These xenoliths display a cumulate texture (adcumulate, heteradcumulate with poikilitic clinopyroxene including olivine). The clinopyroxenes have the composition of augite and show an appreciable variation of MgO (7.02–14.80 wt.%), TiO₂ (0.58–5.76 wt.%) and Al₂O₃ (2.81–12.38 wt.%) contents in grains. The clinopyroxenes are characterized by convex upward chondrite-normalized REE patterns, they display very similar trace element compositions with low contents of incompatible elements such as Rb (0−0.9 ppm), Ba (0.1–8.3 ppm), Th (0.1−0.3 ppm), U (0.01−0.04 ppm) and Nb (1.3–3.2 ppm). REE contents of the calculated melts in equilibrium with the clinopyroxene megacrysts and clinopyroxene from pyroxenite xenoliths are similar to those of the nephelinites exposed in Jbel Saghro. Crystallization temperatures of pyroxenite xenoliths and clinopyroxene megacrysts range from 950 °C to 1150 °C. Clinopyroxene barometry yielded pressure of crystallization ranging from 0.4 to 0.8 GPa for pyroxenite xenoliths and 0.3 to 0.7 GPa for clinopyroxene megacrysts. This pressure range is in agreement with pyroxenite xenoliths and clinopyroxene megacrysts being crystallized from their parental melts at the lower and upper crust.     

Les microbialites de l'Anti-Atlas occidental (Maroc) : marqueurs stratigraphiques et témoins des changements environnementaux au Cambrien inférieur

Three microbialite forms are recognized in the Lower-Cambrian succession of Irherm area in the western Anti-Atlas (Morocco). Stromatolites, which correspond to non-calcified shallow marine laminated microbialites, are well developed in the basal Lower-Cambrian succession. Occurrence of calcified microbial thrombolites, in the middle part of this succession, reflects an increasing sea level from the peritidal zone to the subtidal environment. In the upper part of this succession, a second increasing water depth event and the development of branching archaeocyathan reefal framework lead to dendritic microbialite emergence. To cite this article: M. Benssaou, N. Hamoumi, C. R. Geoscience 336 (2004).