Quantitative evaluation of the rainfall influence on streamflow in an inland mountainous river basin within Central Asia

Stable isotopes of water have been widely used in understanding the hydrological functions of alpine inland catchments. This study identifies dominant runoff generation mechanisms based on isotopic data (δ¹⁸O and δ²H) of 487 rainwater and river-water samples from three tributaries in the Tarim River Basin in China for the period May–September 2013. The isotope hydrograph separation results provide a comprehensive overview of the rainfall influence on hydrological processes. Stream water and groundwater have varied responses to different intensities of rainfall events. Only a small proportion of rainfall is directly transported to the stream during such events. An inconsistent temporal trend of event water contribution is observed in the three catchments. The average fractional contributions of rainfall for the Tizinafu, Kumalak and Huangshuigou rivers are 10.3% (±1.1%), 9.7% (±2.9%) and 8.7% (±2.4%), respectively.     

Identifying evaporation fractionation and streamflow components based on stable isotopes in the Kaidu River Basin with mountain–oasis system in north‐west China

Based on stable isotopes in stream water, groundwater, and meltwater in the Kaidu River Basin, NW China, we estimated the evaporation enrichment of stable oxygen isotopes in different types of water and separated the contribution of each streamflow component in river run‐off. Our results indicated that δ¹⁸O and δ²H in stream water did not vary with altitude regularly but with seasons, with low concentrations in spring and high concentrations in summer. However, the seasonal variations of δ¹⁸O and δ²H in groundwater were not as obvious. The mean evaporation enrichment was between 26% and 44% for δ¹⁸O. Of the various water types under investigation, we found glaciers were influenced the most, showing an evaporation enrichment of 44%, followed by oasis groundwater (37%), stream water (36%), and mountain groundwater (26%). Overall, meltwater and groundwater were the predominant streamflow components, with their contributions were governed by temperature, and varied both temporally and specially. In the oasis region, groundwater was the predominant contributor (64% in spring, 50% in summer, and 66% in autumn), whereas in the mountains, groundwater was the dominant in spring (53%) and autumn (51%), and meltwater contributed the most in summer (52%). Precipitation contributed less than 15% to the streamflow.     

Estimation of actual evapotranspiration from an alluvial aquifer of the Kouris catchment (Cyprus) using continuous streamflow records

The Kouris catchment is located in the south of the Troodos massif in Cyprus. The hydrology is driven by a Mediterranean climate, a mountainous topography, and a complex distribution of hydrogeological properties resulting from complex geology. To quantify the regional water balance further, a simple method using continuous streamflow records in the River Limnatis (Kouris catchment) was applied to calculate the actual evapotranspiration rate in the dry seasons. It was found that daily cycles of streamflow, recorded by automatic pressure logger, were caused by direct evaporation from the groundwater table and by transpiration of riparian forest. The daily amounts of ‘missing’ streamflow were calculated for the period 30 October–4 November 2001 and were extrapolated to the entire dry season and to the whole Kouris catchment. The actual evapotranspiration rate from the alluvial aquifer of the region is 2·4 ± 0·5 Mm³ for April–September 2001. The validity of the assumptions and the uncertainties in the estimates used in the method are discussed. Copyright © 2005 John Wiley & Sons, Ltd.     

Diurnal dynamics of streamflow in an upland forested micro‐watershed during short precipitation‐free periods is altered by tree sap flow

Diurnal variations in streamflow are becoming acknowledged as a way of analysing how changing climatic conditions and land use affects watersheds but also as a way to understand watersheds as a whole. Yet not many studies from uplands below 900 mm mean annual precipitation zone are available from European countries. During the 2012 growing season, a sampling campaign took place in an upland forested micro‐watershed, Czech Republic (65 ha). Tree sap flow, rainfall and temperature were measured continuously, while streamflow at the discharge point and soil moisture were estimated from short‐term measurements. Short precipitation‐free periods lasting several days were identified for evaluation of trends in diurnal dynamics of both sap flow and streamflow. The results demonstrated that during these periods, the main factor altering streamflow was almost exclusively tree sap flow. A decrease in streamflow was observed during the day and an increase at night. The decline in sap flow after sunset was accompanied by a continuous increase in streamflow throughout the night up to its initial maximum in the morning. The amplitude in diurnal variations reached 18%. The observed time lag between the diurnal variations of sap flow and streamflow was approximately 2 h. Relatively low changes in diurnal dynamics of streamflow pointed out a strong regulatory role of the forest in buffering water discharge from the catchment. Copyright © 2015 John Wiley & Sons, Ltd.     

Seasonal and spatial variations in the scaling and correlation structure of streamflow data

Seasonal and spatial variability in scaling, correlation and wavelet variance parameter of daily streamflow data were investigated using 56 gauging stations from five basins located in two different climate zones. Multifractal temporal scaling properties were detected using a multiplicative cascade model. The wavelet variance parameter yielded persistence properties of the streamflow time series. Seasonal variations were found to be significant in that winter and spring seasons where large‐scale frontal events are dominant showed higher long‐term correlations and less multifractality than did summer and fall seasons. Coherent spatial variations were apparent. The Neches River basin located in a subtropic humid climate zone exhibited high persistence and long‐term correlation as well as less multifractality as compared with other basins. It is found that larger drainage areas tend to have smaller multifractality and higher persistence structure, and this tendency becomes apparent in regions that receive large amounts of precipitation and decreases towards arid regions. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of land cover change on streamflow in the interior Columbia River Basin (USA and Canada)

An analysis of the hydrological effects of vegetation changes in the Columbia River basin over the last century was performed using two land cover scenarios. The first was a reconstruction of historical land cover vegetation, c. 1900, as estimated by the federal Interior Columbia Basin Ecosystem Management Project (ICBEMP). The second was current land cover as estimated from remote sensing data for 1990. Simulations were performed using the variable infiltration capacity (VIC) hydrological model, applied at one‐quarter degree spatial resolution (approximately 500 km² grid cell area) using hydrometeorological data for a 10 year period starting in 1979, and the 1900 and current vegetation scenarios. The model represents surface hydrological fluxes and state variables, including snow accumulation and ablation, evapotranspiration, soil moisture and runoff production. Simulated daily hydrographs of naturalized streamflow (reservoir effects removed) were aggregated to monthly totals and compared for nine selected sub‐basins. The results show that, hydrologically, the most important vegetation‐related change has been a general tendency towards decreased vegetation maturity in the forested areas of the basin. This general trend represents a balance between the effects of logging and fire suppression. In those areas where forest maturity has been reduced as a result of logging, wintertime maximum snow accumulations, and hence snow available for runoff during the spring melt season, have tended to increase, and evapotranspiration has decreased. The reverse has occurred in areas where fire suppression has tended to increase vegetation maturity, although the logging effect appears to dominate for most of the sub‐basins evaluated. Predicted streamflow changes were largest in the Mica and Corralin sub‐basins in the northern and eastern headwaters region; in the Priest Rapids sub‐basin, which drains the east slopes of the Cascade Mountains; and in the Ice Harbor sub‐basin, which receives flows primarily from the Salmon and Clearwater Rivers of Idaho and western Montana. For these sub‐basins, annual average increases in runoff ranged from 4·2 to 10·7% and decreases in evapotranspiration ranged from 3·1 to 12·1%. In comparison with previous studies of individual, smaller sized watersheds, the modelling approach used in this study provides predictions of hydrological fluxes that are spatially continuous throughout the interior Columbia River basin. It thus provides a broad‐scale framework for assessing the vulnerability of watersheds to altered streamflow regimes attributable to changes in land cover that occur over large geographical areas and long time‐frames. Copyright © 2000 John Wiley & Sons, Ltd.     

On the contribution of groundwater to streamflow in laterite catchments of the Darling Range,south-western Australia

In deeply weathered laterite catchments of the Darling Range in south-western Australia, the direct contribution (i.e., discharge) of permanent groundwater to streamflow has long been considered as minor. Instead, downslope shallow throughflow was thought to dominate, generating more than 90% of streamflow. We used a chemical hydrograph separation approach to estimate annual groundwater discharge for three catchments over periods of up to 39 years, and found that direct groundwater contributions to streamflow were far more variable across catchments and through time than has previously been acknowledged. The estimated proportion of annual streamflow sourced directly from groundwater ranged from 0 to 93% and was related linearly to the size of the groundwater discharge area in the catchment valley floor. In contrast, contributions from shallow sources including shallow throughflow varied primarily and linearly with annual rainfall. However, the response to rainfall was “amplified” in a predictable way by the size of the groundwater discharge area, consistent with the variable source area concept. We derived a functional relationship between catchment annual rainfall-runoff ratio and groundwater discharge area and successfully applied this to a further four catchments, inferring that the results were broadly applicable across the Darling Range. The implications for an improved understanding of streamflow generating processes in the study region, and for laterite catchments generally, are discussed.     

Characteristics of water stable isotopes and hydrograph separation in Baishui catchment during the wet season in Mt.Yulong region,south western China

Glaciers are of crucial importance for the livelihood of the local populations, which depend on their meltwater for water and energy supplies. For this reason, seasonal variations of oxygen‐18 of glacial stream water and their sources within a small glacial catchment in south western China were investigated during the wet season. The results showed significant difference of oxygen‐18 existed among meltwater, rainwater, ground water and stream water, and significantly seasonal variation of precipitation occurred during the observed period. The streamflow of Baishui catchment was separated into components of ice‐snowmelt and precipitation using oxygen‐18. As shown by the result of the two‐component mixing model, on average, 53.4% of the runoff came from ice‐snowmelt during the wet season, whereas the remaining 46.6% were contributed by precipitation in the catchment. According to monthly hydrograph, the contribution of snow and glacier meltwater varied from 40.7% to 62.2%, and that of precipitation varied from 37.8% to 59.3% in wet season. Uncertainties for this separation were mainly caused by the variation of tracer concentrations. The roles of glacier and snow meltwater should be noticed in water resource management in those glacial regions in south western China. Copyright © 2012 John Wiley & Sons, Ltd.     

Characteristics of water isotopes and hydrograph separation during the wet season in the Heishui River, China

Runoff generation and dynamics is an important issue in watershed and water resource management, but the mechanism in large scale is unclear and site-dependent. For this reason, spatial variations of δD and δ¹⁸O of river water and their sources within large-area of the Heishui Valley of the upper Yangtze River in western China were investigated during the wet season. A total 117 river water samples were collected at 13 sampling sites located at the junction of the principal river course and its tributaries. The results showed no spatial variations of either δD or δ¹⁸O values existed among tributary sampling sites A, B, E, F, H and I during the wet season, and significantly spatial variation occurred between tributary sampling sites A, B, E, F, H, I and site K; which indicated different proportions of rain entering river water should lead to spatial variation of water isotopes. The hydrograph separation analysis, based on the isotope data of river water, meltwater and rain water samples, showed the contribution of snow and glacier meltwater varied from 63.8% to 92.6%, and that of rain varied from 7.4% to 36.2%; which meant that snow and glacier meltwater was the main supplying water source of baseflow in the Heishui Valley. And the roles of glacier and snow meltwater should be significantly noticed in water resource management in this alpine valley at the rim of the Tibetan Plateau.     

Patterns in the linkage of water quantity and quality during low‐flows

This study investigates 72 catchments across the federal state of Baden‐Wuerttemberg, Germany, for changes in water quality during low‐flow events. Data from the state's water quality monitoring network provided seven water quality parameters (water temperature, electrical conductivity, concentrations of chloride, sodium, sulfate, nitrate, and phosphate), which were statistically related to streamflow variability. Water temperature changes during low‐flow showed seasonal dependence. Nitrate concentrations revealed high spatial heterogeneity with about one third of the stations showing decreasing values during low discharge. For most other parameters, concentrations increased during low‐flow. Despite consistent trend directions, the magnitudes of changes with streamflow differed markedly across the state. Both multiple linear regression and a multiple analysis of variances were applied to explain these differences with the help of catchment characteristics. Results indicated that for sulfate and conductivity, geology of the catchments was the most important control, whereas for chloride, sodium, and nitrate, sewage treatment plants had the largest influence. For phosphate, no clear control could be identified. Independent from the applied method, land use was a less important control on river water quality during low‐flow than geology or inflow from sewage treatment plants. These results show that the effects of diffuse and point sources, as well as those of natural and anthropogenic sources differ for different water quality parameters. Overall, a high diversity of potential water quality deterioration signals needs to be considered when the ecological status of rivers is to be protected during low‐flow events.     

Quantifying contributions of snowmelt water to streamflow using graphical and chemical hydrograph separation

In this study, we characterize the snowmelt hydrological response of nine headwater watersheds in southeast Wyoming by separating streamflow into three components using a combination of tracer and graphical approaches. First, continuous 15-min records of specific conductance (SC) from 2016 to 2018 were used to separate streamflow into annual contributions, representing water that contributes to streamflow in a given year that entered the watershed in the same year being considered, and perennial contributions, representing water that contributes to streamflow in a given year that entered the watershed in previous years. Then, diurnal streamflow cycles occurring during the snowmelt season were used to graphically separate annual contributions into rapid diurnal snowmelt contributions, representing water with the relatively fastest hydrological response and shortest residence time, and delayed annual contributions, representing water with relatively longer residence time in the watershed before becoming streamflow. On average, mean annual total streamflow was comprised of between 22% and 46% perennial contributions, 7% and 14% rapid diurnal snowmelt contributions, and 46% and 55% delayed annual contributions across the watersheds. A hysteresis index describing SC-discharge patterns indicated that, annually, most watersheds showed negative, concave, anti-clockwise hysteretic direction suggesting faster flow pathways dominate streamflow on the rising limb of the annual hydrograph relative to the falling limb. At the daily timescale during snowmelt-induced diurnal streamflow cycles, hysteresis was negative, but with a clockwise direction, implying that rapid diurnal snowmelt contributions generated from the concurrent daily snowmelt, with lower SC, arrived after delayed annual contribution peaks and preferentially contributed on the falling limb of diurnal cycles. South-facing watersheds were more susceptible to early season snowmelt at slower rates, resulting in less annual and more perennial contributions. Conversely, north-facing watersheds had longer snow persistence and larger proportions of annual contributions and rapid diurnal snowmelt contributions. Watersheds with surficial geology dominated by glacial deposits had a lower proportion of rapid diurnal snowmelt contributions compared to watersheds with large percentages of bedrock surficial geology.     

太湖流域上游平原河网区水质空间差异与季节变化特征

在太湖流域上游的宜溧—洮滆水系主要河道设置67个监测点,分别于2014年1月(冬季)、4月(春季)、8月(夏季)、11月(秋季)进行水质监测,采用多元统计方法分析了水质的空间差异性和季节性变化,并利用水质标识指数法对水环境质量进行评价.结果表明,宜溧—洮滆水系污染程度较严重,总氮(TN)、总磷(TP)和高锰酸盐指数(CODMn)浓度年均值分别为4.93、0.26和7.63 mg/L;单因素多元方差分析和聚类分析显示污染物浓度具有显著时空差异性,时间上冬、春季污染程度较高而夏、秋季较低,空间上无锡和常州氮、磷污染较为严重,宜兴和溧阳市有机污染程度较高;水质标识评价结果显示流域内水质基本为IV类或V类,其中TN、TP及CODMn是关键污染指标.     

Impacts of climate change on water resources in the Mediterranean Basin: a case study in Catalonia,Spain

Abstract

Most climate change projections show important decreases in water availability in the Mediterranean region by the end of this century. We assess those main climate change impacts on water resources in three medium-sized catchments with varying climatic conditions in northeastern Spain. A combination of hydrological modelling and climate projections with B1 and A2 IPCC emission scenarios is performed to infer future streamflows. The largest reduction (34%) in mean streamflows (for 2076–2100) is expected in the headwaters of the two wettest catchments, while lower decreases (25% of mean value for 2076–2100) are expected in the drier one. In all three catchments, autumn and summer are the seasons with the most notable projected decreases in streamflow, of 50% and 30%, respectively. Thus, ecological flows in the study area might be noticeably influenced by climate change, especially in the headwaters of the wet catchments.     

Simulated soil water storage effects on streamflow generation in a mountainous snowmelt environment,Idaho, USA

Although soil processes affect the timing and amount of streamflow generated from snowmelt, they are often overlooked in estimations of snowmelt‐generated streamflow in the western USA. The use of a soil water balance modelling approach to incorporate the effects of soil processes, in particular soil water storage, on the timing and amount of snowmelt generated streamflow, was investigated. The study was conducted in the Reynolds Mountain East (RME) watershed, a 38 ha, snowmelt‐dominated watershed in southwest Idaho. Snowmelt or rainfall inputs to the soil were determined using a well established snow accumulation and melt model (Isnobal). The soil water balance model was first evaluated at a point scale, using periodic soil water content measurements made over two years at 14 sites. In general, the simulated soil water profiles were in agreement with measurements (P < 0·05) as further indicated by high R² values (mostly > 0·85), y‐intercept values near 0, slopes near 1 and low average differences between measured and modelled values. In addition, observed soil water dynamics were generally consistent with critical model assumptions. Spatially distributed simulations over the watershed for the same two years indicate that streamflow initiation and cessation are closely linked to the overall watershed soil water storage capacity, which acts as a threshold. When soil water storage was below the threshold, streamflow was insensitive to snowmelt inputs, but once the threshold was crossed, the streamflow response was very rapid. At these times there was a relatively high degree of spatial continuity of satiated soils within the watershed. Incorporation of soil water storage effects may improve estimation of the timing and amount of streamflow generated from mountainous watersheds dominated by snowmelt. Copyright © 2008 John Wiley & Sons, Ltd.     

Future land cover and climate may drive decreases in snow wind-scour and transpiration,increasing streamflow at a Colorado,USA headwater catchment

Understanding how land cover change will impact water resources in snow-dominated regions is of critical importance as these locations produce disproportionate runoff relative to their land area. We coupled a land cover evolution model with a spatially explicit, physics-based, watershed process model to simulate land cover change and its impact on the water balance in a 5.0 km² headwater catchment spanning the alpine–subalpine transition on the Colorado Front Range. We simulated two potential futures both with greater air temperature (+4°C/century) and more precipitation (+15%/century, MP) or less precipitation (−15%/century, LP) from 2000 to 2100. Forest cover in the catchment increased from 72% in 2000 to 84% and 83% in 2050 and to 95% and 92% in 2100 for MP and LP, respectively. Surprisingly, increases in forest cover led to mean increases in annual streamflow production of 12 mm (6%) and 2 mm (1%) for MP and LP in 2050 with an annual control streamflow of 208 mm. In 2100, mean streamflow production increased by 91 mm (44%) and 61 mm (29%) for MP and LP. This result counters previous work as runoff production increased with forested area due to decreases in snow wind-scour and increases in drifting leeward of vegetation, highlighting the need to better understand the impacts of forest expansion on the spatial pattern of snow scour, deposition and catchment effective precipitation. Identifying the hydrologic response of mountainous areas to climate warming induced land cover change is critically important due to the potential water resources impacts on downstream regions.     

Changes in streamflow regimes and their responses to different soil and water conservation measures in the Loess Plateau watersheds,China

Investigating the changes in streamflow regimes in response to various influencing factors contributes to our understanding of the mechanisms of hydrological processes in different watersheds and to water resource management strategies. This study examined streamflow regime changes by applying the indicators of hydrologic alteration method and eco-flow metrics to daily runoff data (1965–2016) from the Sandu, Hulu and Dali Rivers on the Chinese Loess Plateau, and then determined their responses to terracing, afforestation and damming. The Budyko water balance equation and the double mass curve method were used to separate the impacts of climate change and human activities on the mean discharge changes. The results showed that the terraced and dammed watersheds exhibited significant decreases in annual runoff. All hydrologic metrics indicated that the highest degree of hydrologic alteration was in the Sandu River watershed (terraced), where the monthly and extreme flows reduced significantly. In contrast, the annual eco-deficit increased significantly, indicating the highest reduction in streamflow among the three watersheds. The regulation of dams and reservoirs in the Dali River watershed has altered the flow regime, and obvious decreases in the maximum flow and slight increases in the minimum flow and baseflow indices were observed. In the Hulu River watershed (afforested), the monthly flow and extreme flows decreased slightly and were categorized as low-degree alteration, indicating that the long-term delayed effects of afforestation on hydrological processes. The magnitude of the eco-flow metrics varied with the alteration of annual precipitation. Climate change contributed 67.47% to the runoff reduction in the Hulu River watershed, while human activities played predominant roles in reducing runoff in the Sandu and Dali River watersheds. The findings revealed distinct patterns and causes of streamflow regime alteration due to different conservation measures, emphasizing the need to optimize the spatial allocation of measures to control soil erosion and utilize water resources on the Loess Plateau.     

Seasonal variations in the isotopic composition of leaf and stem water from an arid region of Southeast Asia

Abstract

Stable isotopes are powerful research tools in environmental sciences and their use in ecosystem research is increasing. Stable isotope measurements allow the study of evapotranspiration fluxes, soil evaporation and leaf transpiration phenomena. Soil water and leaf water are the sources of the evapotranspiration that transfers large quantities of water from land to the atmosphere; as a result the isotopic composition of water left in the leaves is modified towards enrichment. Evaporation also changes the isotopic composition of water bodies creating a natural isotopic signal. The isotopic identity of soil water affects the oxygen isotopic signature of leaf and stem water. In this paper we present the isotopic data of bulk leaf water, showing the enrichment in isotopic value of oxygen due to evapotranspiration from leaves in conjunction with the isotopic signal of rainwater and other environmental factors such as humidity and temperature. Results suggest that the variation in the values of δ¹⁸O of Eucalyptus citriodora, Dalbergia sissoo, Melia azedarach and Pinus roxburghii is due to the seasonal changes in the δ¹⁸O of the source water for plants, i. e. rain. It is further observed that leaf water δ¹⁸O values are depleted during the months of July, August and September. This occurs due to the following reasons: (a) the sampling areas receive about 50% of the average annual rain during these months, and (b) rainfalls during these months are isotopically depleted compared with winter rains.

Citation Butt, S., Ali, M., Fazil, M. & Latif, Z. (2010) Seasonal variations in the isotopic composition of leaf and stem water from an arid region of Southeast Asia. Hydrol. Sci. J. 55(5), 844–848.     

Meltwater storage and delaying characteristics of Gangotri Glacier (Indian Himalayas) during ablation season

Himalayan basins have considerable snow‐ and glacier‐covered areas, which are an important source of water, particularly during summer season. In the Himalayan region, in general, the glacier melt season is considered to be from May to October. Changes in hydrological characteristics of the runoff over the melt season can be understood by studying the variation in time to peak and time lag between melt generation and its emergence as runoff. In the present study, the runoff‐delaying characteristics of Gangotri Glacier, one of the largest glaciers in the Indian Himalayas, have been studied. For this purpose, hourly discharge and temperature data were collected near the snout of the glacier (4000 m) for three ablation seasons (2004–2006). The diurnal variations in discharge and temperature provided useful information on water storage and runoff characteristics of the glacier. In the early stages of the ablation period, poor drainage network and stronger storage characteristics of the glaciers due to the presence of seasonal snow cover resulted in a much delayed response of melt water, providing a higher time lag and time to peak as compared to the peak melt season. A comparison of runoff‐delaying parameters with the discharge ratio clearly indicated that changes in time lag and time to peak are inversely correlated with variations in discharge. Impact of such meltwater storage and delaying characteristics of glaciers on hydropower projects being planned/developed on glacier‐fed streams in India has been discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

Estimating water balance components of tropical wetland lakes in the Pantanal dry season,Brazil

Abstract

Water balance studies with stable water isotopes have rarely been conducted in remote and tropical wetland areas. As such, little is known regarding the water balance and groundwater–surface water interaction in the Pantanal, one of the largest and most pristine wetlands in the world. We applied MINA TrêS, a water balance model utilizing stable water isotopes (δ¹⁸O, δ²H) and chloride (Cl^-) to assess the dry-season hydrological processes controlling groundwater–surface water interactions and the water balance of six floodplain lakes in the northern Pantanal, Brazil. Qualitatively, all lakes exhibited similarity in hydrological controls. Quantitatively, they differed significantly due to morphological differences in controlling groundwater inflow and lake volume. Our approach is readily transferable to other remote and tropical wetland systems with minimal data input requirements, which is useful in regions with sparse hydrometric monitoring.

Editor Z.W. Kundzewicz     

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.