Carbon isotope systematics of the Cambrian–Vendian aquifer system in the northern Baltic Basin: Implications to the age and evolution of groundwater

Groundwater in the Cambrian–Vendian aquifer system has a strongly depleted stable isotope composition (δ¹⁸O values of about −22‰) and a low radiocarbon concentration, which suggests that the water is of glacial origin from the last Ice Age. The aim of this paper was to elucidate the timing of infiltration of glacial waters and to understand the geochemical evolution of this groundwater. The composition of the dissolved inorganic C (DIC) in Cambrian–Vendian groundwater is influenced by complex reactions and isotope exchange processes between water, organic materials and rock matrix. The δ¹³C composition of dissolved inorganic C in Cambrian–Vendian water also indicates a bacterial modification of the isotope system. The corrected radiocarbon ages of groundwater are between 14,000 and 27,000 radiocarbon years, which is coeval with the advance of the Weichselian Glacier in the area.     

Reply to the comments on “Xenoliths in ultrapotassic volcanic rocks in the Lhasa block: direct evidence for crust–mantle mixing and metamorphism in the deep crust”

Stepanov et al. (Contrib Mineral Petrol, 2017) question our conclusion that the UPVs in southern Tibet were derived by partial melting of an old, metasomatized subcontinental lithospheric mantle (SCLM) of the subducted Indian plate. Instead, they propose that these ultrapotassic volcanic rocks (UPVs) are shoshonitic and were generated in two steps: direct melting of crustal rocks first, and then the melts interacted with mantle peridotite. However, the trace element, isotopic, thermal, structural, and seismic evidence is consistent with the xenolith evidence (Wang et al in Contrib Mineral Petrol 172:62, 2016) for hybridisation of ascending Indian subcontinental lithospheric mantle-derived UPV magmas with the deep, isotopically unevolved, Tibetan crust. This necessitates a model whereby partial melting of subducting Indian SCLM generates the UPV suite of southern Tibet.     

Mafic Late Miocene–Quaternary volcanic rocks in the Kamchatka back arc region: implications for subduction geometry and slab history at the Pacific–Aleutian junction

New ⁴⁰Ar/³⁹Ar and published ¹⁴C ages constrain voluminous mafic volcanism of the Kamchatka back-arc to Miocene (3–6 Ma) and Late Pleistocene to Holocene (<1 Ma) times. Trace elements and isotopic compositions show that older rocks derived from a depleted mantle through subduction fluid-flux melting (>20%). Younger rocks form in a back arc by lower melting degrees involving enriched mantle components. The arc front and Central Kamchatka Depression are also underlain by plateau lavas and shield volcanoes of Late Pleistocene age. The focus of these voluminous eruptions thus migrated in time and may be the result of a high fluid flux in a setting where the Emperor seamount subducts and the slab steepens during rollback during terrain accretions. The northern termination of Holocene volcanism locates the edge of the subducting Pacific plate below Kamchatka, a “slab-edge-effect” is not observed in the back arc region.     

Recycling of crustal materials and implications for lithospheric thinning:Evidence from Mesozoic volcanic rocks in the Hailar–Tamtsag Basin,NE China

Late Mesozoic Nb-rich basaltic andesites and high-Mg adakitic volcanic rocks from the Hailar-Tamtsag Basin,northeast China,provide important insights into the recycling processes of crustal materials and their role in late Mesozoic lithospheric thinning.The Late Jurassic Nb-rich basaltic andesites(154 ± 4 Ma) are enriched in large-ion lithophile and light rare earth elements,slightly depleted in high-field-strength elements,and have high TiO_2,P_2 O_5,and Nb contents,and(Nb/Th)PM and Nb/U ratios,which together with the relatively depleted Sr-Nd-Hf isotopic compositions indicate a derivation from a mantle wedge metasomatized by hydrous melts from subducted oceanic crust.The Early Cretaceous high-Mg adakitic volcanic rocks(129-117 Ma) are characterized by low Y and heavy rare earth element contents,and high Sr contents and Sr/Y ratios,similar to those of rocks derived from partial melting of an eclogitic source.They also have high Rb/Sr, K_2 O/Na_2 O,and Mg#values,and high MgO, Cr, and Ni contents.These geochemical features sugge st that the adakitic lavas were derived from partial melting of delaminated lower continental crust,followed by interaction of the resulting melts with mantle material during their ascent Our data,along with available geological,paleomagnetic,and geophysical evidence,lead us to propose that recycling of Paleo-Pacific oceanic crustal materials into the upper mantle due to flat-slab subduction and rollback of the Paleo-Pacific Plate during the late Mesozoic likely provided the precondition for lithospheric thinning in northeast China,with consequent lithospheric delamination causing recycling of continental crustal materials and further lithospheric thinning.     

Cartographic techniques for mapping the geochemical data of stream sediments: the “Sample Catchment Basin” approach

The Sample Catchment Basin (SCB) mapping technique extends the representativeness of the geochemical features of stream sediments to the surface of the whole upstream drainage basin. SCB boundaries clash with the water divides traced from each sampling point and are limited upstream by the presence of further SCBs. They are also assumed to represent the elementary map unit. The rank of SCBs can be defined counting the number of upstream SCBs along the branches of a fluvial network. The presence of low rank SCBs minimizes the statistical redundancy of measures. The SCB technique is particularly suitable for the geochemical mapping of mountainous or hilly areas and to correctly display the information into a morphological context. This approach can be also valuable in the case of low sampling density, inhomogeneous sampling schemes, and especially when very accurate evaluations of the spatial distribution of chemicals (with natural or anthropogenic origin) are required.     

Erratum to: “Criteria for the detection of hydrothermal ecosystem faunas in ores of massive sulfide deposits in the Urals”

The ore-formational, ore-facies, lithological, and mineralogical-geochemical criteria are defined for the detection of hydrothermal ecosystem fauna in ores of the volcanic-hosted massive sulfide deposits in the Urals. Abundant mineralized microfauna is found mainly in massive sulfide mounds formed in the jasperous basalt (Buribai, Priorsk, Yubileinoe, Sultanov), rhyolite—basalt (Yaman-Kasy, Blyava, Komosomol’sk, Sibai, Molodezhnoe, Valentorsk), and the less common serpentinite (Dergamysh) formations of the Urals (O—D₂). In the ore-formational series of the massive sulfide deposits, probability of the detection of mineralized fauna correlates inversely with the relative abundance of felsic volcanic rocks underlying the ores. This series is also marked by a gradual disappearance of colloform pyrite, marcasite, isocubanite, pyrrhotite, and pyrite pseudomorphoses after pyrrhotite; increase of the amount of bornite, fahlores, and barite; decrease of contents of Se, Te, Co, and Sn in chalcopyrite and sphalerite; and inсrease of Tl, As, Sb, and Pb in the colloform pyrite. Probability of the detection of mineralized fauna in the morphogenetic series of massive sulfide deposits decreases from the weakly degraded sulfide mounds to the clastic stratiform deposits. The degradation degree of sulfide mounds and fauna preservation correlates with the attenuation of volcanic intensity, which is reflected in the abundance of sedimentary and volcanosedimentary rocks and the depletion of effusive rocks in the geological sections.     

Discussion: “Xenoliths in ultrapotassic volcanic rocks in the Lhasa block: direct evidence for crust–mantle mixing and metamorphism in the deep crust” by Wang et al. 2016 (Contributions to Mineralogy and Petrology) 171:62

Wang et al. (Contrib Mineral Petrol 171:62, 2016a) present data on composition of xenolith from Southern Tibet and conclude that ulrapotassic melts from the region formed by melting mantle, and complex interaction with a crustal component. In this discussion we demonstrate that numerous observations presented by Wang et al. (2016a) can be explained by partial melting of crust followed by interaction between that melt and the mantle. We show that this model can explain the variability of magmas in such suits without evoking occurrence of coincidental, unrelated events. Moreover we demonstrate that our model of a crustal origin of the proto-shoshonite melts is now supported by independent lines of evidence such as geochemistry of restites after high- and ultrahigh- pressure melting and melt inclusion studies.     

“Love for sale”: Biodiversity banking and the struggle to commodify nature in Sabah,Malaysia

In Malaysia, second largest palm oil producer worldwide, logging companies, palm oil corporations, and even responsible citizens can now compensate their biodiversity impacts by purchasing Biodiversity Conservation Certificates in an emerging new biodiversity market: the Malua BioBank. Biodiversity markets are part of a wider trend of marketisation and neoliberalisation of biodiversity governance; introduced and promoted as (technical) win–win solutions to counter biodiversity loss and enable sustainable development. The existing neoliberalisation and nature literature has tended to analyse these processes as consequences of an inherent drive of capital to expand accumulation and submit ever more areas of nature to the neoliberal market logic.In contrast, I aim (a) to problematise the agency and the “work” behind marketisation of biodiversity, challenging the story of (corporate-driven) neoliberalisation as the realisation of an inherent market-logic (based on the a false conceptual state–market divide, often prevalent even in activist academic circles working on neoliberalisation of nature) and to see the state not only as regulator, but driving force behind, and part of “the market”; (b) to question the myth of neoliberalisation as state losing control to the market and to show how the state is using the biodiversity market as mode of governing; re-gaining control over its forests and its conservation policy; and (c) to demonstrate empirically the distinction between neoliberal ideology and practice, and to show that marketisation was based on pragmatic decisions, not ideology-driven political action. My analysis is based on 35 qualitative interviews with actors involved in the BioBank.     

Late Variscan “Basin and Range” magmatism and tectonics in the Central Alps: evidence from U-Pb geochronology

Abstract

Towards the end of the Variscan orogeny, volcano-sedimentary basins were formed within the mountain hell. U-Pb age determinations on zircons of volcanic and plutonic rocks from intramontane basins of the Central Alps allows us to define the age of two volcano-sedimentary units: The former one was dated older than 333 Ma (probably Visean), the younger one was deposited in a short time span between 303 and 298 Ma (Stephanien). The latter contains tuffs (303 ± 4 Ma), ignimbrites and microgranites (299 ± 2 Ma) and intrusive rhyolites (300 ± 2 Ma) that are all coeval within analytical precision. Granitoid rocks intruded into the volcano-sedimentary rocks at 333 ± 2 Ma, 310 ± 3 Ma and 298 ± 2 Ma. An angular unconformity between the older and the younger units in the Tö di area (Aar massif) indicates uplift and erosion between 310 and 303 Ma.

Our results suggest the existence of two periods of late Variscan extension (or transtension) in the Alpine realm, both combined with magmatic activity. The extensional event of Stephaniun age is characterized by a short duration of only a few million years, between 303 and 298 Ma, comprising tectonic activity, volcanism and plutonism. The plutonic rocks are characterized by a dominant lithospheric mantle component, which was contaminated by different amounts of crostai material and might have been increasingly influenced by aslhcnos-pherie mantle melts in the course of crostai thinning. The ealc-alkaline geochemical characteristics of the granites may be explained as an inherited source feature.

The overall tectonic style and the mode of magmatism resembles the situation of the Basin-and-Kange Province (eastern USA). Consequently there is no need to invoke a late-Variscan Andean-type subduction to explain the geochemical composition of the magmatic rocks. We conclude that late-orogenic extension is an important tectonic stage of the Variscan orogeny, which lasted for some 50 million years. The extension led to thinning of the crust and upwelling of hot mantle, causing high heat flow, intrusion of mantle melts and formation of huge volumes of acid melts.     

Magmatic-Hydrothermal Evolution in the “Bottoms” of Porphyry Copper Systems: Evidence from Silicate Melt and Aqueous Fluid Inclusions in Granitoid Intrusions in the Gyeongsang Basin,South Korea

The Gyeongsang Basin of southeastern Korea contains numerous Cretaceous-early Tertiary (120–40 Ma) granitoid intrusions formed at a convergent plate boundary. The geotectonic setting is similar to that associated with porphyry-type mineralization elsewhere in the Circumpacific region. However, erosion has removed higher-level economic mineralization and exposed deeper levels of the granitoids, representing the poorly mineralized “bottoms” of porphyry copper systems. The intrusions of the Gyeongsang Basin thus provide a unique opportunity to advance our understanding of magmatic-hydrothermal evolution in the roots of porphyry-type systems, below the level of economic mineralization.

The physical and chemical environment during crystallization of the magmas has been characterized through studies of silicate melt and aqueous fluid inclusions in the granitoids. Two different types of silicate melt inclusions were recognized based on occurrence and room-temperature appearance. Type-I inclusions contain one or more crystalline phases and vapor; type-II inclusions consist of a cluster of small crystals, partially devitrified glass, and vapor. Petrographic and Raman analyses indicate that most silicate melt inclusions contain muscovite daughter crystals. Some also contain feldspar. Solidus temperatures of type-I inclusions in quartz phenocrysts range from ≈630to 650°C, whereas solidus temperatures of type-I and type-II inclusions in vug quartz are slightly higher (640–670°C). Liquidus temperatures span a much wider range compared to solidus temperatures, with maximum liquidus temperatures of melts in phenocrysts being slightly higher (≤930°C) than those in vug quartz (≤910°C).

Three types of aqueous inclusions were observed based on occurrence and room temperature phase proportions. Type-A inclusions are liquid rich and low to moderate in salinity; type-B inclusions are vapor rich and low in salinity; type-C inclusions are liquid rich and contain a halite daughter mineral. Some type- A inclusions with a salinity of approximately 25 wt% NaCl equivalent are spatially associated with silicate melt inclusions in phenocrysts, where they occur as three-dimensional clusters of tiny inclusions surrounding the silicate melt inclusion. Type-A inclusions also occur along fractures in quartz phenocrysts. Non-fracture-controlled type-C inclusions are rare in phenocryst quartz, but are common in vug quartz, where they are associated with silicate melt inclusions. Type-C inclusions that coexist with silicate melt inclusions generally homogenize by halite dissolution after the vapor bubble and show a wide range in salinity, from about 30 to >60 wt% NaCl equivalent. Coexisting halite-bearing (Type-C) and vapor-rich (Type-B) inclusions in phenocryst quartz suggest local immiscibility in the late-or post-magmatic fluid.

Pressure-temperature conditions during the final stages of magmatic-hydrothermal activity associated with the granitoid intrusions of the Gyeongsang Basin were approximately 630° to 670° C and 1.9 to 2.5 kbars. These results suggest that the granitoids do not contain economic porphyry coppertype mineralization because the magmas crystallized at high pressures (relative to typical porphyry copper magmas) and did not become saturated in water until a relatively late stage in the crystallization history. Failure to reach water saturation resulted in most of the copper in the original melt being sequestered as a trace component in earlier-crystallizing silicate and sulfide phases to produce anomalous but subeconomic copper grades. Furthermore, owing to the depth of emplacement, less energy was available to fracture the rocks when water did exsolve from the magma, and the pressure remained too high for aqueous fluid immiscibility to be an important metal-concentrating or depositing mechanism. Geological, petrographic, and geochemical characteristics suggest that the granitoid rocks of the Gyeongsang Basin represent ethroot zones of porphyry-type systems, and any higher-grade mineralization that may have been present higher in the system has since been removed by erosion.     

“One needs to be very brave to stand all that”: Cycling,rational dress and the struggle for citizenship in late nineteenth century Britain

The article discusses changing ideas around citizenship through an analysis of first person accounts of women cyclists in Rational Dress in late nineteenth century Britain. A close reading of personal correspondence provides a sense of how it felt to cycle while dressed in new mobility costumes, such as bloomers, in urban and suburban English landscapes. Such attired and independently mobile women affirmed or unsettled onlooker’s understandings of how middle and upper class women should look and act in public. Some viewers subjected them to verbal and often physical assault. Others, in awe of their socio-technical sophistication were more supportive. Taking a ’bloomer point of view’ provides a unique socio-material way of gaining a deeper understanding of what enabled and also inhibited women’s claims to citizenship and freedom of movement, especially at a time when women were not citizens in a legal sense. I argue that through these richly described accounts we gain insightful glimpses into how individual sensory, embodied and political experiences collectively illuminate the becoming of ’citizen’ as it relates to mobility, gender and landscape.     

Upper crust “boudinage” during post-collisional Miocene extension in Tuscany: Insights from the southern part of the Larderello geothermal area (Northern Apennines,Italy)

A geological study carried out in the southern part of the Larderello geothermal area (Northern Apennines) provides new information on the development mechanism and timing of the earlier extensional structures that formed during the Miocene post-collisional tectonics which affected the orogen. Staircase low-angle normal faults (LANFs) affected a multilayered thickened upper crust after the collisional stage, producing the lateral segmentation of the Tuscan Nappe, the deeper non-metamorphic tectonic unit of the Northern Apennines in the Tuscan area. The tectonic history recorded in two Tuscan Nappe discontinuous bodies revealed that the LANFs took place during the Middle–Late Miocene, displacing collisional structures developed from the Late Oligocene. These Tuscan Nappe bodies are delimited by detachment faults located at the base, within the Tuscan evaporites, and at the top within the Ligurian Units. Their western and eastern margins coincide with east-dipping ramps. These structures and the Tuscan Nappe bodies were later dissected by Pliocene–Quaternary high-angle normal faults. The reconstructed deformation history implies that the Tuscan Nappe bodies are extensional horses developed through an earlier asymmetrical east-dipping extensional duplex system, involved in block faulting during the later, Pliocene-Quaternary, stage of extension.     

Evidence for early Pliocene and late Miocene transgressions in southern Patagonia (Argentina): 87Sr/86Sr ages of the pectinid “Chlamys” actinodes (Sowerby)

Numerical ages based on ⁸⁷Sr/⁸⁶Sr dating of calcitic shells belonging to the pectinid “Chlamys” actinodes (Sowerby) document the only late Miocene (Tortonian) sea flooding event in the Austral Basin at Cabo Buentiempo (8.95 ± 0.82 Ma, 2 s.e.), and provide evidence of the first documented early Pliocene (Zanclean) transgression in Argentina recorded at Cañadón Darwin (5.15 ± 0.18 Ma, 2 s.e., Austral Basin) and at Terraces of Cerro Laciar (5.10 ± 0.21 Ma, 2 s.e.), southern San Jorge Basin). The sedimentary rocks deposited during the Tortonian are correlated with the youngest beds deposited by the “Entrerriense Sea” that covered northern Patagonia. The Zanclean marine episode is correlated with the long-term cycle represented in the Southern Hemisphere by the flooding events recorded in Cockburn and James Ross Islands (Antarctica) and in North-Central Chile.     

Imageries of the contested concepts “land grabbing” and “land transactions”: Implications for biofuels investments in Ghana

In Ghana, the contested concepts of “land grabbing” and “land transaction” are strategically applied by proponents of critical and win–win discourses respectively to describe outcomes of land deals. Using case study methods and discourse analysis, this paper explores four cases of biofuels investments in Ghana and the implications of the choice of concepts used to represent them. Proponents of the critical discourse use the “land grabbing” concept to invoke imageries of “illegality”, “theft” and “food insecurity” when describing land deals. Consequently, some biofuels investments have been hampered in their potential to generate profit and local employment. The biofuel investors in this study, whose projects have been labeled “land grabbing”, therefore switched to food production to downplay public scepticism. Proponents of the win–win discourse portray biofuels investments as “pro-poor” projects and use the “land transaction” concept to pre-empt possible public criticisms in the media and elsewhere. Such representations of these biofuels investments are therefore mainly intended to pre-empt criticisms or attract public praise. Some projects with potentially promising outcomes have thus been terminated, while others with problematic outcomes have continued to be promoted. In contexts characterized by weak land regulations and ambivalence towards large-scale agriculture, the trajectory and outcomes of biofuels investments are often influenced by land deal representations drawn from global discourses and how they interact with pre-existing local discourses.