钇—5—Br—PADAP—CPC—OP显色反应的研究

研究了钇(Ⅲ)-5-Br-PADAP-CPC-乳化剂OP混合体系的光度特性,在pH7.5～9.8范围内,显色体系在580nm处有最大吸收峰,空白值低,对比度(Δλ)较高,摩尔吸光系数ε为1.0×10~5。配合物组成Y:5-Br-PADAP:CPC为1:4:3,形成稳定常数(logβ)为9.84。在0—45μg Y/50ml范围内服从比尔定律。该法已成功地应用于测定Fe-Cr-Al合金和矿物中痕量钇。     

铟—1—苯基—3—甲基—4—苯甲酰基吡唑啉酮—5—安替比林体系络合吸附波？…

在ＰＨ４．５的ＨＡｃ－ＮａＡｃ介质中,Ｉｎ－１－苯基－３－甲基－４－苯甲酰基吡唑啉酮－５（ＰＭＢＰ）－安替比林体系于－０．５７Ｖ处产生一良好的极谱波。Ｉｎ在０．０１－０．５ｍｇ／Ｌ与波高呈线性关系。     

Pb—Sn—Fe—Sb—S体系相关系

用抽空石英管法研究以Fe_(0·96) Sb_(2·04) S_(4·12)为投影顶点,8×(PbS-SnS-SnS_2)为投影平面的Pb-Sn-Fe-Sb-S体系的相图表明,由于Pb(?)Sn~(2+)之间互相取代,500℃时辉锑锡铅矿固溶体中Sn~(2+)变化范围(以单位分子式11个金属原子总数为计量)是0—4.8个原子,400℃时则为0—4.0个原子。同时,Sn~(4+)变化范围是1.3—2.3个原子和1.5—2.1个原子。圆柱锡矿固溶体变化范围较小。500℃时Sn~(2+)变化范围是0.4—1.8个原子,400℃时为0.5—1.7。Sn~(+4)变化范围则分别为3.2—4.2个原子和3.3—4.2个原子。变更Fe含量(0.81—1.09)及Sb含量(1.83—2.29)进行的几组合成实验表明,上述两个矿物中Fe、Sb含量变化范围很小,不超过±0.15个原子。辉锑锡铅矿固溶体可与方铅矿、块硫锑铅矿、针硫锑铅矿、硫锡铅矿、硫锡矿、圆柱锡矿等形成平衡结线。而圆柱锡矿不与方铅矿、硫锡矿、硫锡铅矿形成平衡结线,但可与辉锑矿、SnS_2及上述其他矿物形成平衡结线。结合锡的硫化物及氧化物(锡石)热力学稳定场计算表明,在本体系内辉锑锡铅矿在300℃时稳定区的硫活度在lga_(s2)=-20(atm)附近,氧活度小于lga_(o2)=-40(atm),而圆柱锡矿稳定区硫活度大于lga_(s2)=-10(atm)。     

4—（2—羟基—4—硝基苯偶氮）—1—苯基—3—甲基吡唑啉酮与钍的显色反应

在pH为 2～ 3的HAc介质中 ,4 - ( 2 -羟基 - 4 -硝基苯偶氮 ) - 1 -苯基 - 3-甲基吡唑啉酮 (HNAPMP)与钍反应生成 2∶1的稳定络合物 ,λmax=540nm ,ε=4 .96× 1 0 4L·moL- 1·cm- 1,Th质量浓度在 0～ 2 .8mg/L内符合比尔定律。方法用于钍钨合金中钍的测定 ,相对标准偏差 (n =5)小于 1 % ,加标回收率为 97%～ 1 0 2 %。     

1—（2—羟基—3,5—二硝基苯）—3—4（4—苯基—2—噻唑）—三氮稀的合成及其与镍的显

合成了新试剂 1 - (2 -羟基 - 3,5-二硝基苯 ) - 3- (4-苯基 - 2 -噻唑 ) -三氮烯 ,研究了在表面活性剂TritonX - 1 0 0存在下 ,它与Ni2 的显色反应。结果表明 ,在 pH 6.0～ 7.5时 ,Ni2 与该试剂形成配合物 ,其最大吸收峰位于 51 5nm处 ,摩尔吸光系数为 1 .0 8× 1 0 5 L·mol- 1 ·cm- 1 。Ni2 在 0～ 0 .4mg/L内符合比尔定律。方法已用于矿物、合金、钢样中微量镍的测定 ,结果与原子吸收法相符 ,     

2—[2‘—（6—甲氧基—苯并噻唑）—偶氮]—1,8—二羟基萘—3,6—二磺酸的合成及？…

合成了新的杂环偶氮变色酸类试剂--2-[2'-(6-甲氧基-苯并噻唑)-偶氮]-1,8-二羟基萘-3,6-二磺酸,并系统探讨了在pH 4.5的邻苯二甲酸氢钾-NaOH介质中显色试剂与钛的显色反应特性.结果表明,在溴化十六烷基吡啶存在下,试剂与Ti(Ⅳ)形成2:1的络合物,显色反应15 min完全并至少稳定4 h,最大吸收波长为670 nm,表观摩尔吸光系数达1.67×105 L.mol-1.cm-1,钛的质量浓度在0～400 μg/L时符合比尔定律.用拟定的方法测定了硅砖等标准物质中的Ti(Ⅳ),所得结果与标准值的相对误差均小于4%,RSD(n=5)小于3.5%.     

省级中心镇——杜桥镇

临海市杜桥镇：位于浙江沿海中部。台州湾北岸,全镇陆地面积186平方公里。建成区面积13．6平方公里,户籍人1320．7万。2010年,全镇实现工农业总产值157．65亿元,财政总收入4．86亿元,农民人均纯收入12347元。该镇是临海东部经济、文化中心,先后荣获全国综合改革试点镇。浙江省省级中心镇、绿色小城镇、首批村镇建设现代化示范镇、教育强镇、科普示范镇、生态镇等荣誉称号,2010年列入浙江省首批27个小城市培育试点镇。     

The petrochemistry characteristics and petrogenesis of peraluminous granite in Tibet

There are 61 major peraluminous granitic bodies in Tibet (TPGs) along the south of the Bangong Co-Gêrzê-Amdo-Nujiang suture, whose lithology includes tourmaline granite, muscovite granite and two-mica granite. The TPGs have SiO₂ = 65.7%−79.52%, K₂O + Na₂O = 2.20%−12.51%, K₂O/Na₂O = 0.49−1.04 and A/CNK = 1.04−1.38. Al₂O₃ gradually decreases and the other oxides disperse with the increase in SiO₂. The rock series is mainly calc-alk series with high potassium. It has typical characteristics of strongly peraluminous granite. Based on the aluminum saturation index and QAP plots, the peraluminous granite plot is mostly within the continental collision granite (CCG) field, indicating that the peraluminous granites in Tibet formed in a continental collisional setting. Ab-Or-Q-H₂O phase diagram indicates the pressure of 0.5 × 10⁸−2 × 10⁸ Pa in TPGs, from which it can be deduced that the forming temperature was under 700°C. The TPGs mainly occurred at the collision stage between two continental crust plates, and the original magma is rooted in the remelting from the upper crust. It is the S-type granite in petrogenesis. The South Gandise belt and the Lhagoi Kangri belt have similar characteristics, suggesting that the two belts have the same magma source and the same tectonic setting. Translated from Acta Geologica Sinica, 2006, 80(9): 1329–1341 [译自: 地质学报]     

Fractionation,hybridisation and magma-mixing in the Kialineq centre East Greenland

The igneous rocks of the Kialineq centre on the coast of East Greenland at 67°N include a number of quartz syenite and granite plutons intruded 35my BP. These are subvolcanic bodies emplaced by cauldron subsidence and with ring-dike and bell-jar form. Associated with the major intrusions is an extensive acid-basic mixed magma complex. Two-liquid structures, chilling of basic against acid magma, pillows of basic in acid, and net-veining of basic by acid magma, are superbly displayed. The basic magma was of a transitional or alkaline type and underwent varying degrees of fractionation in a regime of repeated intrusions and diverse chambers. Heterogeneous hybrid rocks intermediate between basalt and quartz syenite are strongly developed and were formed by repeated mechanical mixing of contrasting magmas. The energy for this mixing probably came in the main from cauldron-block subsidence. The quartz syenite magma, which itself fractionated towards granite, has initial ⁸⁷Sr/⁸⁶Sr ratios the same as the basic magma and is itself believed to be a fractionation product of alkali basalt magma.     

Geological and Geochemical Characteristics and Petrogenesis of the Anqing—Lujiang Quartz Syenite Rock Belt,East China

The Anqing-Lujiang quartz syenite rock belt consists of the Huangmeijian, Chengshan and Dalongshan composite batholiths which intruded into the Mesozoic strata. The country rocks were subjected to thermal contact metamorphism with little sign of folding and regional metamorphism. The rock belt is Late Yenshanian in age with a Rb-Sr isochron age of 135 Ma. Major rock types are quartz syenite and, to a lesser extent, syenite porphyry and alkali feldspar granite. Rock-forming minerals are dominantly potash feldspar (more than 50%) and lesser amounts of plagioclase and quartz. Mafic minerals, mostly Mg-biotite with lesser amounts of amphibole and pyroxene, are rare. Occasionally, alkalic mafic minerals (aegirine, riebeckite) are found. Characteristic accessary minerals of the earlier intrusives are magnetite, sphene and apatite and those of the later intrusives are ilmenite and zircon. Typologic distribution and evolutionary trend of zircon population are very similar to those of granites of mantle origin as suggested by Pupin, J. P. Petrochemically, the rock belt is poor in Ca but rich in alkali and Al with Na₂O+K₂O > 10%. It belongs to the K-Na transitional series, with a high alkalinity ratio (A. R. = 3–7) and a K /Na (atom) ratio close to unity. Rocks in the belt are rich in REE which tends to decrease from the early to the late stage, belonging to LREE type. The initial Sr ratio is 0.7078–0.7064. The rock belt is the Mesozoic anorogenic product of alkalic magmatic activity from a deep-seated source. According to a mantle-crust mixing model for Sr and Pb isotopes, it is estimated that 60.2–53.8% of the materials has been derived from the mantle. Additionally, its rich alkali, poor water content and anorogenic characteristics suggest that the belt is similar to the A-type granites.     

新疆拜城县波孜果尔A型花岗岩类矿物学特征及岩浆形成的温度条件

新疆拜城县波孜果尔A型花岗岩类为富含铌、钽、锆等有用元素的含矿岩体。通过偏光显微镜、电子探针(EPMA)化学成分分析、电子探针背散射(BSE)对波孜果尔A型花岗岩类的矿物学特征进行了研究,并对岩浆形成的温度条件与构造背景进行了讨论。结果表明,波孜果尔A型花岗岩类包括霓石钠闪石英碱性长石正长岩、霓石钠闪碱性长石花岗岩、黑云母碱性长石正长岩3种岩石类型。主要造岩矿物包括石英、钠长石、钾长石、霓石、钠铁闪石和铁叶云母。副矿物包括锆石、烧绿石、钍石、萤石、独居石、氟碳铈镧矿、磷钇矿等。岩浆平均温度832~839℃,形成于非造山的板内构造环境,且具高温、无水、低氧逸度的成岩特点。     

The Pikes Peak batholith,Colorado front range,and a model for the origin of the gabbro—anorthosite—syenite—potassic granite suite

This study of the Pikes Peak batholith includes the mineralogy and petrology of quartz syenite at West Creek and of fayalite-bearing and fayalite-free biotite granite near Mount Rosa; major element chemistry of the batholith; comparisons with similar postorogenic, intracratonic, sodic to potassic intrusives; and genesis of the batholith.The batholith is elongate in plan, 50 by 100 km, composite, and generally subalkalic. It was emplaced at shallow depth 1,040 m. y. ago, sharply transects its walls and may have breached its roof. Biotite granite and biotite—hornblende granite are predominant; quartz syenite, fayalite granite and riebeckite granite are present in minor amounts.Fayalite-bearing and fayalite-free quartz syenite, fayalite-biotite granite and riebeckite granite show a well-defined sodic differentiation trend; the less sodic fayalite-free granites exhibit a broader compositional range and no sharp trends.Crystallization was largely at P_H2O < P_total; P_H2O approached P_total only at late stages. Aplite residual to fayalite-free biotite granite in the north formed at about 1,500 bars, or 5 km depth. Feldspar assemblages indicate late stages of crystallization at about 720°C. In the south ilmenite and manganian fayalite indicate f_O2 of 10^?17 or 10^?18 bars. Biotite and fayalite compositions and the ‘granite minimum’ imply completion of crystallization at about 700°C and 1,500 bars. Nearby fayalite-free biotite granite crystallized at higher water fugacity.All types of syenite and granite contain 5–6% K₂O through a range of SiO₂ of 63–76%. Average Na₂O percentages in quartz syenite are 6.2, fayalite granite 4.2, and fayalite-free granite 3.3 MgO contents are low, 0.03–0.4%; FeO averages 1.9–2.5%. FeO/Fe₂O₃ ratios are high. Fluorine ranges from 0.3 to 0.6%.The Pikes Peak intrusives are similar in mode of emplacement, composition, and probably genesis to rapakivi intrusives of Finland, the Younger Granites of Nigeria, Cape Ann Granite and Beverly Syenite, Mass., and syenite of Kungnat, Greenland, among others — allowing for different levels of erosion. A suite that includes gabbro or basalt, anorthosite, quartz syenite, fayalite granite, riebeckite granite, and biotite and/or hornblende granites is of worldwide occurrence.A model is proposed in which mantle-derived, convecting alkali olivine basaltic magma first reacts with K₂O-poor lower crust of granulite facies to produce magma of quartz syenitic composition. The syenitic liquid in turn reacts with granodioritic to granitic intermediate crust of amphibolite facies to produce the predominant fayalite-free biotite and biotite-hornblende granites of the batholith. This reaction of magma and roof involves both partial melting and the reconstitution and precipitation of refractory phases, as Bowen proposed. Intermediate liquids include MgO-depleted and Na₂O-enriched gabbro, which precipitated anorthosite, and alkali diorite. The heat source is the basaltic magma; the heat required for partial melting of the roof is supplied largely by heats of crystallization of phases that settle out of the liquid — mostly olivine, clinopyroxene and plagioclase.     

湖北竹溪蔓荆沟碱性正长岩地球化学特征及其构造环境分析

在南秦岭造山带中发现的竹溪蔓荆沟碱性正长岩,呈透镜状侵入于辉绿岩体内,个别呈独立岩体侵入于早古生代地层中。单个正长岩体规模较小。通过对其进行岩相学及岩石地球化学特征研究,表明其为全碱(Na_2O~+K_2O)含量较高的钾质碱性正长岩;岩石中Mg~#值较低,明显低于原始岩浆Mg~#值,说明其为原始岩浆经历较高程度演化的产物;岩体中稀土元素总量ΣREE较高,轻稀土元素LREE富集明显,重稀土元素HREE亏损;通过微量元素构造环境判别分析认为,研究区正长岩形成于大陆裂谷环境,且形成于大陆裂谷早期阶段,其形成时代为早志留世。     

Rb—Sr Geochronology and Magma Source of the Mesozoic Fault—Granite Belt,East Shandong

Developed in the southeast coast of te East Shandong Peninsula,the Mesozoic fault-magma belt consists of five rock series:the syenite series;the monzonite series;the megaporphyritic monzogranite series;the biotite-granite series;and the alkali granite seres.Based on their Rb-Sr isochron ages(122-220Ma),these rock series may be divided into three magma subcycles dated at Triassic,Late Jurassic and Early Cretaceous.The initial ^87Sr/^86Sr ration in these rock series range from 0.70436 to 0.7155.The starting points of the Rb-Sr isochrons exhibit four different distribution trends on the(^87Sr/^86Sr)i-^87Rb/^86Sr diagram.These characteristics show that the multiple granitic rock series are different in genesis and derivation.The syenite series might be derived from the combination of mantle-derived magma and crustal material,and the others could be derived from granulite-facies and amphibilite-facies rocks in the deep crust.     

河南方城大庄铌-稀土矿床碱性正长岩成矿机理研究

【研究目的】河南方城大庄是新探明的中型铌-稀土矿床（Nb₂O₃资源量16245 t;伴生TRE₂O₃资源量30147 t）,矿体主要赋存在碱性正长岩内。【研究方法】本文在野外地质调查基础上,对含矿碱性正长岩与无矿碱性正长岩开展了岩石学、岩相学和地球化学的对比研究。【研究结果】研究结果表明,含矿与无矿碱性正长岩均富碱、富铝,为典型的A型花岗岩,两类岩石的碱金属含量无明显差别,但（Na₂O+K₂O）/CaO、FeO^*/MgO、K₂O/MgO等参数明显不同。含矿碱性正长岩高场强元素Nb、Ta、Ce、U、Th、Zr、Y明显富集,Ba、Sr、P、Eu明显亏损;无矿碱性正长岩大离子亲石元素Rb、高场强元素Nb、Ta、Y和Th元素明显富集,而Ba、U、Sr、P、Ti和重稀土元素明显亏损,但亏损程度低于含矿碱性正长岩。【结论】方城大庄含矿碱性正长岩不是无矿碱性正长岩热液蚀变（钠长石化）的结果,二者应是同一岩浆体系不同演化阶段溶体固结的产物,含矿碱性正长岩的分异演化程度明显高于无矿化的碱性正长岩。方城大庄稀有稀土元素的富集与岩浆高演化、分异过程密切相关。这一研究可为区域找矿勘查提供一定的地质依据。创新点：岩石学和地球化学对比研究显示大庄Nb-REE矿中含矿碱性正长岩具有比无矿岩体更高的演化程度,表明成矿元素的富集与岩浆高分异演化密切相关,为找矿勘查提供了一定的岩石学证据。     

Ore geochemistry,zircon mineralogy,and genesis of the Sakharjok Y-Zr deposit,Kola Peninsula,Russia

The Sakharjok Y-Zr deposit in Kola Peninsula is related to the fissure alkaline intrusion of the same name. The intrusion ∼7 km in extent and 4–5 km² in area of its exposed part is composed of Neoarchean (2.68–2.61 Ma) alkali and nepheline syenites, which cut through the Archean alkali granite and gneissic granodiorite. Mineralization is localized in the nepheline syenite body as linear zones 200–1350 m in extent and 3–30 m in thickness, which strike conformably to primary magmatic banding and trachytoid texture of nepheline syenite. The ore is similar to the host rocks in petrography and chemistry and only differs from them in enrichment in zircon, britholite-(Y), and pyrochlore. Judging from geochemical attributes (high HSFE and some incompatible element contents (1000–5000 ppm Zr, 200–600 ppm Nb, 100–500 ppm Y, 0.1–0.3 wt % REE, 400–900 ppm Rb), REE pattern, Th/U, Y/Nb, and Yb/Ta ratios), nepheline syenite was derived from an enriched mantle source similar to that of contemporary OIB and was formed as an evolved product of long-term fractional crystallization of primary alkali basaltic melt. The ore concentrations are caused by unique composition of nepheline syenite magma (high Zr, Y, REE, Nb contents), which underwent subsequent intrachamber fractionation. Mineralogical features of zircon-the main ore mineral—demonstrate its long multistage crystallization. The inner zones of prismatic crystals with high ZrO₂/HfO₂ ratio (90, on average) grew during early magmatic stage at a temperature of 900–850°C. The inner zones of dipyramidal crystals with average ZrO₂/HfO₂ = 63 formed during late magmatic stage at a temperature of ∼500°C. The zircon pertaining to the postmagmatic hydrothermal stage is distinguished by the lowest ZrO₂/HfO₂ ratio (29, on average), porous fabric, abundant inclusions, and crystallization temperature below 500°C. The progressive decrease in ZrO₂/HfO₂ ratio was caused by evolution of melt and postmagmatic solution. The metamorphic zircon rims relics of earlier crystals and occurs as individual rhythmically zoned grains with an averaged ZrO₂/HfO₂ ratio (45, on average) similar to that of the bulk ore composition. The metamorphic zircon is depleted in uranium in comparison with magmatic zircon, owing to selective removal of U by aqueous metamorphic solutions. Zircon from the Sakharjok deposit is characterized by low concentrations of detrimental impurities, in particular, contains only 10–90 ppm U and 10–80 ppm Th, and thus can be used in various fields of application.     

Zonal distribution of oxygen isotope ratios in the Hiroshima granite complex,Southwest Japan

¹⁸O/¹⁶O ratios have been obtained for 99 minerals from rocks of the Hiroshima granite complex and adjacent Ryoke granites. Zonal distribution of oxygen isotopes is observed on a regional scale almost parallel to the extension of the Ryoke plutono-metamorphic belt, granites in or around the metamorphic belt being 2–3%₀ richer in ¹⁸O than those farther away from the belt. Isotopic fractionations among coexisting minerals indicate that isotopic zonation existed at a magmatic stage. The zonal enrichment of ¹⁸O in the granite magma in the Ryoke belt and its periphery is a result of isotopic interaction between country rocks and the magma through fluid media. Genetic relationship between granites of the Ryoke and Chugoku belts are discussed with regard to the geological situation of the former belt.