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1.
39Ar-40Ar ages and37Ar-38Ar exposure ages of samples representing four different lithologies of the Apollo 17 station 7 boulder were measured. The age of the dark veinlet material77015of3.98 ± 0.04AE is interpreted as representing the time of intrusion of this veinlet into the 77215 clast. The data obtained so far indicate that the vesicular basalt 77135 formed 100–200 m.y. later. However, this has to be confirmed by39Ar-40Ar investigations on separated mineral and/or grain-size fractions. A small clast enclosed in the 77135 basalt gives a well-defined high temperature age of3.99 ± 0.02AE. A sample of the noritic clast 77215 gave4.04 ± 0.03AE, the highest age found so far in this boulder. The39Ar-40Ar ages obtained are in agreement with the age relationships deduced from the stratigraphic evidence.Taking into account the shielding by the boulder itself, an average37Ar-38Ar exposure age of(27.5 ± 2.5)m.y. is obtained for the samples collected from the boulder.  相似文献   

2.
3.
代晓颖  徐栋  武俊梅  丰俊  邹书成  尹珩 《湖泊科学》2021,33(5):1415-1424
为探究"十三五"期间武汉市湖泊水质变化特征及规律,分析当前武汉市湖泊水环境的主要问题及成因,为武汉市水生态环境保护"十四五"规划提供科学支撑,以武汉市166个湖泊为研究对象,根据武汉市环境监测中心2015-2019年对各个湖泊的监测数据,采用水质综合污染指数、富营养化状态评价、动态度分析等方法,对武汉市湖泊水环境进行综...  相似文献   

4.
Internal isochrons for two Apollo 15 rocks give an age of(3.34 ± 0.09)and(3.46 ± 0.04) × 109 years with an identical87Sr/86Sr initial ratio of 0.69928. Considering the possibility for the line obtained in a87Sr/86Sr,87Rb/86Sr diagram to be a mixing line, the significance of these results are discussed.  相似文献   

5.
Correlations between40Ar and36Ar from size fractions of three Apollo 15 fines (15071, 15421, 15501) have been obtained. The40Ar intercept values of these fines and of 15091 and 15601 are generally lower than what one would expect for fines resulting from the comminution of rocks having ages of about 3.3 × 109 yr, typical for basalts of the landing site. This is interpreted to be the result of contamination by ray material from the Copernican age (equal or less than ~109 yr) craters, Autolycus and Aristillus, north of the landing site.  相似文献   

6.
The measurement of the oxygen isotopic composition of the sulfate separated from fossil shells supplies no reliable information on the isotopic values of dissolved ocean water sulfate in the past. The results obtained suggest that fossils behave as open systems from the point of view of the possible influence of post-depostional processes on the isotopic composition of shell sulfate.  相似文献   

7.
Examples of positive correlations between initial 87Sr/86Sr and δ18O have now been shown to be very common in igneous rock series. These data in general require some type of mixing of mantle-derived igneous rocks with high-18O, high-87Sr crustal metamorphic rocks that once resided on or near the Earth's surface, such as sedimentary rocks or hydrothermally altered volcanic rocks. Mixing that involves assimilation of country rocks by magmas, however, is not a simple two-end-member process; heat balance requires appreciable crystallization of cumulates. In such cases, the isotopic compositions may strongly reflect this open-system behavior and indicate the process of assimilation, whereas the major element chemical compositions of the contaminated magmas will be largely controlled by crystal-melt equilibria and crystallization paths fixed by multicomponent cotectics. A variety of oxygen and strontium isotope “mixing” curves were therefore calculated for this process of combined assimilation-fractional crystallization. The positions and characteristics of the resultant curves on δ18O-87Sr/86Sr diagrams markedly diverge from simple two end-member mixing relationships. Based on the above, model calculations can be crudely fitted to two igneous rock suites (Adamello and Roccamonfina in Italy), but the shapes of the calculated curves appear to rule out magmatic assimilation as an explanation for most δ18O-87Sr/86Sr correlations discovered so far, including all of those involving calc-alkaline granitic batholiths and andesitic volcanic rocks. The isotopic relationships in such magma types must be inherited from their source regions, presumably reflecting patterns that existed in the parent rocks (or magmas) prior to or during melting.  相似文献   

8.
The distribution of210Po and210Po in dissolved (<0.4 μm) and particulate (>0.4 μm) phases has been measured at ten stations in the tropical and eastern North Atlantic and at two stations in the Pacific. Both radionuclides occur principally in the dissolved phase. Unsupported210Pb activities, maintained by flux from the atmosphere, are present in the surface mixed layer and penetrate into the thermocline to depths of about 500 m. Dissolved210Po is ordinarily present in the mixed layer at less than equilibrium concentrations, suggesting rapid biological removal of this nuclide. Particulate matter is enriched in210Po, with210Po/210Pb activity ratios greater than 1.0, similar to those reported for phytoplankton. Box-model calculations yield a 2.5-year residence time for210Pb and a 0.6-year residence time for210Po in the mixed layer. These residence times are considerably longer than the time calculated for turnover of particles in the mixed layer (about 0.1 year). At depths of 100–300 m,210Po maxima occur and unsupported210Po is frequently present. Calculations indicate that at least 50% of the210Po removed from the mixed layer is recycled within the thermocline. Similar calculations for210Pb suggest much lower recycling efficiencies.Comparison of the210Pb distribution with the reported distribution of226Ra at nearby GEOSECS stations has confirmed the widespread existence of a210Pb/226Ra disequilibrium in the deep sea. Vertical profiles of particulate210Pb were used to test the hypothesis that210Pb is removed from deep water by in-situ scavenging. With the exception of one profile taken near the Mid-Atlantic Ridge, significant vertical gradients in particulate210Pb concentration were not observed, and it is necessary to invoke exceptionally high particle sinking velocities to account for the inferred210Pb flux. It is proposed instead that an additional sink for210Pb in the deep sea must be sought. Estimates of the dissolved210Pb/226Ra activity ratio at depths greater than 1000 m range from 0.2 to 0.8 and reveal a systematic increase, in both vertical and horizontal directions, with increasing distance from the sea floor. This observation implies rapid scavenging of210Pb at the sediment-water interface and is consistent with a horizontal eddy diffusivity of 3?6 × 107 cm2/sec. The more reactive element Po, on the other hand, shows evidence of rapid in-situ scavenging. In filtered seawater,210Po is deficient, on the average, by ca. 10% relative to210Pb; a corresponding enrichment is found in the particulate phase. Total inventories of210Pb and210Po over the entire water column, however, show no significant departure from secular equilibrium.  相似文献   

9.
87Sr/86Sr ratios of 15 samples of basalt dredged from Loihi Seamount range from 0.70334 to 0.70368. The basalt types range from tholeiite to basanite in composition and can be divided into six groups on the basis of abundances of K2O, Na2O, Rb and Sr and 87Sr/86Sr ratio. The isotopic data require that the various basalt types be derived from source regions differing in Sr isotopic composition. The Loihi basalts may be produced by mixing of isotopically distinct sources, but the tholeiites and alkalic basalts from Loihi do not show a well-developed inverse trend between Rb/Sr and 87Sr/86Sr that is characteristic of the later stages of Hawaiian volcanoes such as Haleakala and Koolau.  相似文献   

10.
The five diogenites, Johnstown, Roda, Ellemeet, Shalka and Tatahouine, give scattered data in the87Rb/86Sr,87Sr/86Sr diagram. This can result from a disturbance which occurred later than 4.45 Ga ago. However, it is shown that if samples of sufficient size were analyzed, there meteorites could plot on the eucrite isochron and are thereby in agreement with a genetic relation between eucrites, howardites and diogenites. The age of eucrite differentiation from diogenites has been computed using data from the two families yielding an age of 4.47±0.1Ga(2σ) (λ=1.42×10?11a?1), the initial87Sr/86Sr ratio being BABI.  相似文献   

11.
40Ar/39Ar incremental heating experiments on igneous plagioclase, biotite, and pyroxene that contain known amounts of excess40Ar indicate that saddle-shaped age spectra are diagnostic of excess40Ar in igneous minerals as well as in igneous rocks. The minima in the age spectra approach but do not reach the crystallization age. Neither the age spectrum diagram nor the40Ar/36Ar versus39Ar/36Ar isochron diagram reliably reveal the crystallization age in such samples.  相似文献   

12.
143Nd/144Nd,87Sr/86Sr and trace element results are reported for volcanic and plutonic rocks of the Aleutian island arc. The Nd and Sr isotopic compositions plot within the mantle array with εNd values of from 6.5 to 9.1 and87Sr/86Sr ratios of from 0.70289 to 0.70342. Basalts have mildly enriched light REE abundances but essentially unfractionated heavy REE abundances, while andesites exhibit a greater degree of light to heavy REE fractionation. Both the basalts and andesites have significant large ion lithophile element to light rare earth element (LILE/LREE) enrichments. Variations in the isotopic compositions of Nd and Sr are not related to the spatial distribution of volcanoes in the arc, nor are they related to temporal differences. εNd and87Sr/86Sr do not correlate with major element compositions but do, however, correlate with certain LILE/LREE ratios (e.g. BaN/LaN). Plutonic rocks have isotropic and trace element characteristics identical to some of the volcanic rocks. Rocks that make up the tholeiitic, calc-alkaline and alkaline series in the Aleutians do not come from isotopically distinct sources, but do exhibit some differing LILE characteristics.Given these elemental and isotopic constraints it is shown that the Aleutian arc magmas could not have been derived directly from homogeneous MORB-type mantle, or fresh or altered MORB subducted beneath the arc. Mixtures of partially altered MORB with deep-sea sediment can in principle account for the isotopic characteristics and most of the observed LILE/LREE enrichments. However, some samples have exceedingly high LILE/LREE enrichments which cannot be accounted for by sediment contamination alone. For these samples a more complex scenario is considered whereby dehydration and partial melting of the subducted slab, containing less than 8% sediment, produces a LILE-enriched (relative to REE) metasomatic fluid which interacts with the overlying depleted mantle wedge. The isotopic and LILE characteristics of the mantle are extremely sensitive to metasomatism by small percentages of added fluid, whereas major elements are not substantially effected, Major element compositions of Aleutian magmas are dominantly controlled by the partial melting of this mantle and subsequent crystal fractionation; whereas isotopic and LILE characteristics are determined by localized mantle heterogeneities.  相似文献   

13.
226Ra,210Pb and210Po were measured in oceanic profiles at two stations near the Bonin and Kurile trenches.210Po is depleted by 50% on average relative to210Pb in the surface water. In the deep water,210Pb is about 25% deficient relative to226Ra. Based on the deficiency,210Pb residence time with respect to removal by particulate matter was estimated to be less than 96 years in the deep water.210Pb deficiency in the bottom water was significantly greater than that of the adjacent deep water, indicating more effective removal near or at the bottom interface.210Pb,210Po and Th appear to have similar overall rate constants of particulate removal throughout the water column.  相似文献   

14.
Determinations of40Ar/39Ar and U-Th-Pb are reported for three clasts from the Abee (E4) enstatite chondrite, which has been the object of extensive consortium investigations. The clasts give40Ar/39Ar plateau ages and/or maximum ages of 4.5 Gy, whereas two of the clasts give average ages of 4.4 Gy. Within the range of 4.4–4.5 Gy these data do not resolve any possible age differences among the three clasts.206Pb measured in these clasts is only ~1.5–2.5% radiogenic, which leads to relatively large uncertainties in the Pb isochron age and in the207Pb/206Pb model ages. The Pb data indicate that the initial207Pb/206Pb was no more than 0.08±0.07% higher than this ratio in Can?on Diablo troilite. The U-Th-Pb data are consistent with the interpretation that initial formation of these clasts occurred 4.58 Gy ago and that the clasts have since remained closed systems, but are contaminated with terrestrial Pb. The40Ar/39Ar ages could be gas retention ages after clast formation or impact degassing ages. The thermal history of Abee deduced from Ar data appears consistent with that deduced from magnetic data, and suggests that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, and experienced no appreciable subsequent heating.  相似文献   

15.
A model that predicts the flux of222Rn out of deep-sea sediment is presented. The radon is ultimately generated by230Th which is stripped from the overlying water into the sediment. Data from many authors are compared with the model predictions. It is shown that the continental contribution of ionium is not significant, and that at low sedimentation rates, biological mixing and erosional processes strongly affect the surface concentration of the ionium. Two cores from areas of slow sediment accumulation, one from a manganese nodule region of the central Pacific and one from the Rio Grande Rise in the Atlantic were analyzed at closely spaced intervals for230Th,226Ra, and210Pb. The Pacific core displayed evidence of biological mixing down to 12 cm and had a sedimentation rate of only 0.04 cm/kyr. The Atlantic core seemed to be mixed to 8 cm and had a sedimentation rate of 0.07 cm/kyr. Both cores had less total excess230Th than predicted.Radium sediment profiles are generated from the230Th model. Adsorbed, dissolved, and solid-phase radium is considered. According to the model, diffusional losses of radium are especially important at low sedimentation rates. Any particulate, or excess radium input is ignored in this model. The model fits the two analyzed cores if the fraction of total radium available for adsorption-desorption is about 0.5–0.7, and ifK, the distribution coefficient, is about 1000.Finally, the flux of radon out of the sediments is derived from the model-generated radium profiles. It is shown that the resulting standing crop of222Rn in the overlying water may be considered as an added constraint in budgeting230Th and226Ra in deep-sea sediments.  相似文献   

16.
表生明矾石族矿物40Ar/39Ar年代学概述   总被引:2,自引:0,他引:2       下载免费PDF全文
杨静  郑德文  武颖 《地震地质》2013,35(1):177-187
近年来,激光40Ar/39Ar法成功测定了硫化物矿床氧化带中表生明矾石族矿物(明矾石和黄钾铁矾)的年龄,表明这类矿物适用于 40Ar/39Ar法定年。激光熔样方法引入40Ar/39Ar定年,不仅减少了样品的用量,同时也降低了系统的空白本底水平; 利用阶段加热法得到的年龄谱图,不仅可以有效识别原生矿物的混染和多世代矿物的存在,还可以检测样品中的过剩、继承Ar。虽然风化矿物定年还存在一些潜在的问题,但是只要有科学的采样和合理的分析流程,并结合其他检测手段,就可以获得有意义的风化年龄。这为研究新生代以来化学风化、氧化带形成时间和古气候提供了新的方法。  相似文献   

17.
吴东浩  贾更华  吴浩云 《湖泊科学》2021,33(5):1364-1375
基于太湖31个站点的逐月监测数据,分析了2007-2019年太湖藻型湖区和草型湖区的叶绿素a变化特征,并分析研究不同环境因子对不同类型湖区叶绿素a的影响.结果表明,近年来太湖不同类型湖区的总磷浓度和叶绿素a浓度变化基本一致,均呈波动上升趋势.不同类型湖区的总磷浓度拐点均为2015年,叶绿素a浓度拐点均为2016年.最低月平均水温、前冬积温、年平均水温、年均风速与藻型湖区和草型湖区叶绿素a浓度均呈显著相关.沉水植物分布面积与草型湖区叶绿素a浓度之间呈显著相关.湖西区年内和年度降雨剧烈变化,湖西区年降雨量与不同类型湖区当年叶绿素a浓度的关系不明显,5日极端降雨量与不同类型湖区下年度叶绿素a浓度均呈显著正相关.太湖蓝藻水华强度在短期内可能仍会处于较高水平,迫切需要高度重视高温时段太湖蓝藻打捞处置工作,保障饮用水安全;同时,要进一步加强湖西区强降雨期间的非点源污染防控措施研究,推动入湖污染通量稳步降低,并探索东西山之间及东茭咀附近水域沉水植物生态修复技术,降低风浪扰动作用,尽快恢复相关重要水域的沉水植物.  相似文献   

18.
Two ocean profiles from the Peru Basin from regions with different surface productivities were analyzed for total210Pb and201Po to evaluate the influence of particulates in the water column on their distribution. Comparison with a published226Ra profile for the region was made. The profile closest to the coast, where upwelling and productivity are high, shows depletion of210Pb relative to226Ra at all depths, with particularly marked excursions from radioactive equilibrium at the surface and in the bottom water.210Po appears to be deficient relative to210Pb at depth as well. Mean residence times in the deep water, relative to particulate removal from the water column to the sediments, of about 100 years for210Pb and about two years for210Po are indicated. The profile northwest of the upwelling region shows the226Ra210Pb210Po system close to equilibrium at all depths to 1500 m (except for the effect of atmospheric210Pb input seen at the surface.  相似文献   

19.
Uranium, thorium and protactinium isotopes were measured in particulate matter collected by sediment traps deployed in the Panama Basin and by in-situ filtration of large volumes of seawater in the Panama and Guatemala Basins. Concentrations of dissolved Th and Pa isotopes were determined by extraction onto MnO2 adsorbers placed in line behind the filters in the in-situ pumping systems.Concentrations of dissolved 230Th and 231Pa in the Panama and Guatemala Basins are lower than in the open ocean, whereas dissolved 230Th/231Pa ratios are equal to, or slightly greater than, ratios in the open ocean. Particulate 230Th/231Pa ratios in the sediment trap samples ranged from 4 to 8, in contrast to ratios of 30 or more at the open ocean sites previously studied. Particles collected by filtration in the Panama Basin and nearest to the continental margin in the Guatemala Basin contained 230Th/231Pa ratios similar to the ratios in the sediment trap samples. The ratios increased with distance away from the continent.Suspended particles near the margin show no preference for adsorption of Th or Pa and therefore must be chemically different from particles in the open ocean, which show a strong preference for adsorption of Th. Ocean margins, as typified by the Panama and Guatemala Basins, are preferential sinks for 231Pa relative to 230Th. Furthermore, the margins are sinks for 230Th and, to a greater extent, 231Pa transported by horizontal mixing from the open ocean.  相似文献   

20.
The straight-line relationship between depth and the square root of age predicted by recent variations of the thermal contraction model for ocean rise elevation is confirmed to an age of 80 m.y.We then examine this relationship in the immediate vicinity of the rise crest in an attempt to determine the sensitivity of the slopes thus obtained. Depth versus t1/2 profiles from a variety of rise types ranging from the topographically smooth, fast-spreading Pacific-Antarctic rise to the rough, slow-spreading Mid-Atlantic rise are discussed, ages having been assigned using a finite rotation pole. Because of the variety of superimposed anomalous features concentrated within a limited and well-surveyed region, the Galapagos Spreading Center has provided a suitable arena for determining the precision with which the method can decompose such an agglomeration into distinctly recognizable components. Although topographic “noise” precludes precise quantification of the slopes, it is concluded that, by removing the first-order effect of thermal contraction, the method can be quite revealing when topography is examined in relation to other data. Slopes for several profiles across the Pacific-Antarctic and Pacific-Nazca rises reveal the pattern expected in the case of asymmetric spreading, a conclusion which has independently been derived from the magnetic anomalies. In the Galapagos region “jumps” of the spreading center, a basic compositional difference, and uplift from below are exposed by their predictable effect on the slopes obtained from the depth versus t1/2 plots.  相似文献   

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