Climate change during the last 150 million years: reconstruction from a carbon cycle model

Variations of the atmospheric CO₂ level and the global mean surface temperature during the last 150 Ma are reconstructed by using a carbon cycle model with high-resolution input data. In this model, the organic carbon budget and the CO₂ degassing from the mantle, both of which would characterize the carbon cycle during the Cretaceous, are considered, and the silicate weathering process is formulated consistently with an abrupt increase in the marine strontium isotope record for the last 40 Ma. The second-order variations of the atmospheric CO₂ level and the global mean surface temperature in addition to the first-order cooling trend are obtained by using high-resolution data of carbon isotopic composition of marine limestone, seafloor spreading rate, and production rate of oceanic plateau basalt. The results obtained from this model are in good agreement with the previous estimates of palaeo-CO₂ level and palaeoclimate inferred from geological, biogeochemical, and palaeontological models and records. The system analyses of the carbon cycle model to understand the cause of the climate change show that the dominant controlling factors for the first-order cooling trend of climate change during the last 150 Ma are tectonic forcing such as decrease in volcanic activity and the formation and uplift of the Himalayas and the Tibetan Plateau, and, to a lesser extent, biological forcing such as the increase in the soil biological activity. The mid-Cretaceous was very warm because of the high CO₂ level (4–5 PAL) maintained by the enhanced CO₂ degassing rate due to the increased mantle plume activities and seafloor spreading rates at that time, although the enhanced organic carbon burial would have a tendency to decrease the CO₂ level effectively at that period. The variation of organic carbon burial rate may have been responsible for the second-order climate change during the last 150 Ma.     

Measurements of electric charge distribution in volcanic plumes at Sakurajima Volcano,Japan

Measurements of perturbations in the atmospheric potential gradient around volcanic plumes at multiple (from two to five) sites, and measurements of the charge-mass ratio of ash particles falling from volcanic plumes, were carried out at Sakurajima Volcano, Japan. Results from 28 and 29 October 1995, show that the nature of the perturbations depends on the intensity of plume activity. Although plume activity was vigorous on 28 October, negative perturbations were predominant. As plume activity peaked, the magnitude of negative perturbations decreased just below the plume and increased at an off-axis site. During the peak period, positively charged ash particles fell out from the plume. This suggests that the active plume dominantly contained negatively charged materials, and that positively and negatively charged materials were added to the lower and upper parts of the plume, respectively, during the peak period. On the other hand, as plume activity became less vigorous on 29 October, the perturbations were characterized by a positive anomaly followed by a negative anomaly. Because wind velocity increased with altitude that day, we infer that positive and negative charges were distributed in the upper and lower parts of the plume, respectively. The differences in perturbations observed on 28 and 29 October suggest that volcanic plumes are generally composed of three parts: an upper part with positively charged gas and aerosol, a middle part with negatively charged fine ash particles, and a lower part with positively charged coarse ash particles. The compilation of present and previous results from Sakurajima and other volcanoes indicates that the effect of the negative charge in the middle part was predominant in most cases, although positive perturbations caused by the upper part were observed around some weak plumes. The effect of positively charged particles in the lower part was observable only when plume activity was sufficiently strong because positively charged coarse particles tended to fall out near the vent.     

Depositional model of Permian Luodianian volcanic island and its impact on the distribution of fusulinid assemblage in southern Qinghai, Northwest China

Pan-riftizational tectonic activity reached climax at Luodianian (Permian) in the East Tethyan Domain, Qinghai-Tibet Plateau. Because of eruptive volcanics and influence of terrigenous materials, a complex volcanic-sedimentary landform formed on the sea floor in southern Qinghai. Four sedimentary facies types were recognized based on detailed field mapping. Spatially, platform facies volcanic-limestone type was located at the center belt approximately trending NWW, surrounded by shallow water slope facies tuff/tuffite type at the two flanks and deep water slope facies breccia/calcirudite at the most outside. The depression facies sandstone-mudstone type, which comprised mainly mudstone, de-posited between volcanic islands (platform facies volcanic-limestone type). Based on the field map-ping and stratigraphic section data, seven rift-related sedimentary facies were recognized and a depo-sitional model for volcanic island was proposed. It is revealed that some volcanic island chain formed quickly and intermittently in the Qamdo Block during violent eruption, and small carbonate reef, shoal, platform occurred above or on edge of volcanic island, and some slope sedimentary facies surrounded volcano island chain during dormant period of volcanic activities. Three types of fusulinid assemblages were distinguished in the carbonate rocks, which deposited in varied positions of a palaeo-volcanic island: (1) Misellina-Schwagerina assemblage occurred above or on edge of volcanic island, (2) Para-fusulina assemblage was located at restricted depression facies among volcanic islands or carbonate platform, and (3) the reworked Pseudofusulina-Schwagerina assemblage occurred at slope facies near margin of volcanic island, which originally deposited in the shallow-water carbonate platform, then collapsed along the volcanic island margin with fusulinid-bearing grain-supported carbonate con-glomerate or calcirudite, and finally re-deposited on the deeper slope. The sedimentary sequence re-sulting from calm shallow water was deposited at the interior of the Qamdo Block from the Devonian to early Early Permian. At the beginning of the peak period of activity of pan-riftzation (Luodianian), al-ternate volcanic island and shallow marine environment within continent crust came into being. Uni-form and stable shallow-water carbonate platform was formed during the Xiangboan. This suggested that the activity of rift basin was evidently weakened. Subsequently the instability of the basin appre-ciably increased with the occurrence of basalt in late Kuhfengian. At last the whole Qamdo Block turned into the closure period of rift during the Late Permian.     

Diverse mid-Miocene silicic volcanism associated with the Yellowstone–Newberry thermal anomaly

The Santa Rosa–Calico volcanic field (SC) of northern Nevada is a complex, multi-vent mid-Miocene eruptive complex that formed in response to regional lithospheric extension and flood basalt volcanism. Santa Rosa–Calico volcanism initiated at ∼16.7 Ma, concurrent with regional Steens–Columbia River flood basalt activity and is characterized by a complete compositional spectrum of basalt through high-silica rhyolite. To better understand the relationships between upwelling mafic magmatism, coeval extension, and magmatic system development on the Oregon Plateau we have conducted the first comprehensive study of Santa Rosa–Calico silicic volcanism. Detailed stratigraphic-based field sampling and mapping illustrate that silicic activity in this volcanic field was primarily focused along its eastern and western margins. At least five texturally distinct silicic units are found in the western Santa Rosa–Calico volcanic field, including abundant lava flows, near vent deposits, and shallow intrusive bodies. Similar physical features are found in the eastern portion of the volcanic field where four physically distinct units are present. The western and eastern Santa Rosa–Calico units are characterized by abundant macro- and microscopic disequilibrium textures, reflecting a complex petrogenetic history. Additionally, unlike other mid-Miocene Oregon Plateau volcanic fields (e.g. McDermitt), the Santa Rosa–Calico volcanic field is characterized by a paucity of caldera-forming volcanism. Only the Cold Springs tuff, which crops out across the central portion of the volcanic field, was caldera-derived. Major and trace element geochemical variations are present within and between eastern and western Santa Rosa–Calico silicic units and these chemical differences, coupled with the observed disequilibrium textures, illustrate the action of open-system petrogenetic processes and melt derivation from heterogeneous source materials. The processes and styles of Santa Rosa–Calico silicic magmatism are linked to three primary factors, local focusing of and thermal and material contributions from the regional flood basalt event, lithospheric extension within the northern portion of the Northern Nevada rift, and interaction of mid-Miocene silicic magmas with pre-Santa Rosa–Calico lithosphere. Similar processes and styles of mid-Miocene silicic volcanism likely occurred across the Oregon Plateau in regions characterized by both focused lithospheric extension and localized mafic magmatism. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.     

Evolution of the Bayramiç magmatic complex, northwestern Anatolia

During the Oligocene–Middle Miocene period widespread magmatic activity developed in Western Anatolia, following the continental collision between the Sakarya continent and the Tauride–Anatolide platform. This produced both intrusive and extrusive rocks, which appear to be associated in space and time, as exemplified from the Bayramiç area. In the Bayramiç area, the magmatic activity started with the intrusion of the Evciler granite, and the coeval lower volcanic association. This was followed by the development of the upper volcanic association. These rock groups form collectively the Bayramiç magmatic complex, which was generated under an on-going north–south compressional regime. The Bayramiç magmatic complex has a subalkaline composition, displaying a calcalkaline trend. Trace elements and REE contents resemble to island-arc and collision-related magmas. According to the isotope values the Bayramiç magmatic complex was derived from the magmas of lithospheric mantle origin, which were later contaminated, while passing through the thick continental crust, in a post-collisional tectonic setting, during the Oligocene–Early Miocene period. The latest product of the magmatism is the Late Miocene–Pliocene basalt lavas. Their geochemical properties are clearly different from the Oligocene–Early Miocene magmatic rocks. The basalts were generated when the north–south compression gave way to the north–south extensional regime.     

Volcanic aerosol optical characteristics of Mt. Etna tropospheric plume retrieved by means of airborne multispectral images

Tropospheric volcanic plume features have been derived from airborne multispectral images collected during field measurement campaigns at the Mt. Etna volcano in June 1997, during a quiescent period, and in July 2001 during an eruptive period. Results have been obtained in terms of mapping the volcanic aerosol optical thickness (AOT), the Ångström parameters and the water vapor content using different bands from visible to infrared. The AOT values show average values of 0.1 and 1, for quiescent and eruptive plumes, respectively, demonstrating that this geophysical parameter well indicates a major contribution of particulates in the explosive plume with respect to the quiescent one. The mapping of Ångström parameters, in the explosive case, indicates the presence of larger particles and their distribution along the plume, while in the quiescent case indicates the particle size is dominated by small particles with an effective radius about 1 μm. Further in the quiescent case, the map of water vapor shows low values indicating that water vapor emitted condenses mainly in aerosols.     

Young pumice deposits on Nisyros,Greece

The island of Nisyros (Aegean Sea) consists of a silicic volcanic sequence upon a base of mafic-andesitic hyaloclastites, lava flows, and breccias. We distinguish two young silicic eruptive cycles each consisting of an explosive phase followed by effusions, and an older silicic complex with major pyroclastic deposits. The caldera that formed after the last plinian eruption is partially filled with dacitic domes. Each of the two youngest plinian pumice falls has an approximate DRE volume of 2–3 km³ and calculated eruption column heights of about 15–20 km. The youngest pumice unit is a fall-surge-flow-surge sequence. Laterally transitional fall and surge facies, as well as distinct polymodal grainsize distributions in the basal fall layer, indicate coeval deposition from a maintained plume and surges. Planar-bedded pumice units on top of the fall layer were deposited from high-energy, dry-steam propelled surges and grade laterally into cross-bedded, finegrained surge deposits. The change from a fall-to a surge/flow-dominated depositional regime coincided with a trend from low-temperature argillitic lithics to high-temperature, epidote-and diopside-bearing lithic clasts, indicating the break-up of a high-temperature geothermal reservoir after the plinian phase. The transition from a maintained plume to a surge/ash flow depositional regime occurred most likely during break-up of the high-temperature geothermal reservoir during chaotic caldera collapse. The upper surge units were possibly erupted through the newly formed ringfracture.     

Age progressive volcanism in the Comores Archipelago, western Indian Ocean and implications for Somali plate tectonics

The Comores Islands together with the Tertiary volcanic province of northern Madagascar form a sublinear trend of alkali olivine basalt shield volcanoes across the northern entrance of the Mozambique Channel. Potassium-argon dating of shield-building lavas confirms an eastward increase in age of volcanism along the chain, consistent with a hotspot origin for the lineament. The velocity of the Somali plate over the mantle magma source is 50 mm/yr.

We use the distribution of ages along the Comores-Madagascar chain in conjunction with existing age data for the Reunion-Mascarene Plateau hotspot track to model the absolute motion of the Somali plate for the last 10 m.y. We calculate the relative motion across the East African Rift by subtracting the Somali plate absolute motion from African plate absolute motion during this period. The model predicts 320 km of total separation across the East African Rift during the past 10 m.y. which is greater than has been estimated from surface geological evidence

The geometry of older portions of the Comores and Reunion trends indicates that there was no significant relative motion between the African and Somali plates prior to about 10 m.y. ago.     

Magma mixing and magma plumbing systems in island arcs

Petrographic features of mixed rocks in island arcs, especially those originating by the mixing of magmas with a large compositional and temperature difference, such as basalt and dacite, suggest that the whole mixing process from their first contact to the final cooling (= eruption) has occurred continuously and in a relatively short time period. This period is probably less than several months, considerably shorter than the whole volcanic history. There may also be a prolonged quiescent interval, lasting longer than several days, between the magmas' contact and the mechanical mixing. This interval will allow the basic magma to cool and produce a semi-solidified boundary which is later disrupted by flow movements to produce basic inclusions.Mixing of magmas of contrasting chemical composition need not be the inevitable consequence of the contact of the magmas. It is, however, made more probable by forced convection caused by motive force such as the injection of a basic magma into an acidic magma chamber. A short interval between their initial contact and the final eruption requires that the acid magma chamber has a small volume, of the same order or less than that the introduced basic magma.The volcanic activity of Myoko volcano, central Japan, of the last 100,000 years shows alternate eruptions of hybrid andesite by mixing of basaltic and dacitic magmas, and non-mixed basalt to basaltic andesite. There was a repose period of 20,000 to 30,000 years between eruptions. The acidic chamber, eventually producing the mixed andesite activity, is formed during the repose period by the « in situ » solidification of the original basic magma against its wall. The volume of the chamber is very small, probably about 10^–2 km³. Basaltic magma with constant chemical composition is supplied to the shallow chamber from another deep seated basaltic chamber. The volume of the shallow magma chamber may be critical to the characteristics of volcanic activity and its products.     

Plume chemistry provides insights into mechanisms of sulfur and halogen degassing in basaltic volcanoes

This paper deals with sulfur, chlorine and fluorine abundances in the eruptive volcanic plume of the huge October 2002-January 2003 eruption of Mount Etna, aiming at relating the relevant compositional variations observed throughout with changes in eruption dynamics and degassing mechanisms. The recurrent sampling of plume acidic volatiles by filter-pack methodology revealed that, during the study period, S/Cl and Cl/F ratios ranged from 0.1-6.8 and 0.9-5.6, respectively. Plume S/Cl ratios increased by a factor of ∼10 as volcanic activity drifted from paroxysmal lava fountaining (mid- and late November) to passive degassing and minor effusion (early January), and then decreased to the low values (S/Cl=0.1) typical of the final stages of the eruption. Parallel variations in chlorine to fluorine ratios were also observed. A theoretical model is proposed for quantitative interpretation of these changes in plume composition. The model calculates the composition of a volatile phase exsolving from an ascending Etna magma, based on knowledge of solubilities and abundances in the undegassed melt of sulfur and halogens [T.M. Gerlach, EOS 72 (1991), 249, 254-255]. According to this model, degassing of Etnean basaltic melt at high pressures and depths (>100 MPa, 3 km) is likely to release a CO₂+H₂O-rich vapor phase with S/Cl molar ratios ∼1. Extensive sulfur and chlorine degassing from the melt would take place at shallower depth (P<20 MPa, 0.6 km), with S/Cl ratios in the vapor phase increasing as pressure drops to 0.1 MPa. Comparisons between model compositions and volcanic plume data demonstrate that the chemical trends observed during the eruption may be explained by increased degassing due to depressurization of a basaltic magma batch ascending toward the surface.     

SO2 emission of the 1974 eruption of Volcán Fuego,Guatemala

Volcán Fuego in the Central American Republic of Guatemala erupted violently in October, 1974. A remote sensing correlation spectrometer. COSPEC IV, which utilizes the characteristic molecular absorption of SO₂ in the ultraviolet was used to monitor the SO₂ content of the volcanic plume. Over a 60-day period measurements were made on 37 days between and following major eruptive phases. SO₂ emission rates corrected for atmospheric scattering of the spectral signal average 423 metric tons/day with a standard deviation of 252 metric tons/days. Late stage peaks in SO₂ emission at Fuego are consistent with the presence of anomalously high contents of soluble materials on the stratigraphically highest ashes from other Central American eruptions. Indications are that the SO₂ concentration within the volcanic plume increased as activity waned. These features imply that remote spectroscopic sensing of SO₂ and perhaps other gases in a volcanic plume may provide a relatively easy and inexpensive means of determining the cessation of violent eruptive activity.     

Early Permian Tarim Large Igneous Province in northwest China

Tarim Large Igneous Province (TLIP) is the second Late Paleozoic LIPs in China after the recognition of Emeishan LIP, and is a hot research topic in geosciences. On the basis of the analysis of research history about TLIP, this paper summarizes the research result during last twenty years and suggests the key research area in the future. The residual distribution range of TLIP is up to 250000 km², and the largest residual thickness is 780 m. The eruption of basalt happened during 290–288 Ma and belongs to LIPs magmatic event with fast eruption of magma. The lithological units of the TLIP include basalt, diabase, layered intrusive rock, breccia pipe mica-olivine pyroxenite, olivine pyroxenite, gabbro, ultramafic dyke, quartz syenite, quartz syenite porphyry and bimodal dyke. The basalt and diabase of TLIP exhibit OIB-like trace element patterns and enrichment of LILE and HFSE, and mainly belong to high TiO₂ series. There is an obvious difference in isotope among the basalt from Keping and the basalt and dibase from the northern Tarim Basin. The basalt from Keping with negative ? _Nd and high REE value derives from enriched mantle, and the diabase and basalt from the northern Tarim Basin with positive ? _Nd and low REE value are related to depleted mantle. The crust uplifting in the Early Permian and the development of picrite and large scale dyke and formation of large scale V-Ti-Magnetite deposit in Wajilitag area support the view that the TLIP is related to mantle plume. The TLIP has a temporal-spatial relationship with Permian basic to ultra-basic igneous rock, which is distributed widely in Central Asia, and they represent a tectono-magmatic event with very important geodynamic setting. This paper also suggests that the deep geological process, the relation with mantle plume, mineralization, the relation with environmental change and biological evolution, and the geodynamics of the TLIP will be the key research topics in the future.     

Monitoring Etna volcanic plumes using a scanning LiDAR

In this paper, we use data obtained from LiDAR measurements during an ash emission event on 15 November 2010 at Mt. Etna, in Italy, in order to evaluate the spatial distribution of volcanic ash in the atmosphere. A scanning LiDAR system, located at 7?km distance from the summit craters, was directed toward the volcanic vents and moved in azimuth and elevation to analyse different volcanic plume sections. During the measurements, ash emission from the North East Crater and high degassing from the Bocca Nuova Crater were clearly visible. From our analysis we were able to: (1) evaluate the region affected by the volcanic plume presence; (2) distinguish volcanic plumes containing spherical aerosols from those having non-spherical ones; and (3) estimate the frequency of volcanic ash emissions. Moreover, the spatial distribution of ash mass concentration was evaluated with an uncertainty of about 50?%. We found that, even during ash emission episodes characterised by low intensity like the 15 November 2010 event, the region in proximity of the summit craters should be avoided by air traffic operations, the ash concentration being greater than 4?×?10^?3?g/m³. The use of a scanning permanent LiDAR station may usefully monitor the volcanic activity and help to drastically reduce the risks to aviation operations during the frequent Etna eruptions.     

Observations of pre-midnight 5-m irregularities in the equatorial F region over São Luís,Brazil: Solar-flux dependence and seasonal variations

The statistics of pre-midnight 5-m irregularities in the equatorial F region over São Luís is presented. The data set ranges from October 2001 to December 2008 and covers maximum solar-flux-to-minimum solar flux epoch. The variabilities in irregularity parameters, namely, height and time of their appearance in the radar echoes, with solar-flux variation are presented. The seasonal variations (combined over all years, irrespective of solar-flux) of occurrence of irregularities, occurrence of bottom-type layer (or bottom-side irregularities without plume) and bottom-side/topside plume (or bottom-side irregularities with plume) are presented. The largest occurrences of bottom-side irregularities without plume and with plume are found on April (equinox) and December (summer) months respectively. The ambient ionospheric conditions namely prereversal evening vertical drift, bottom-side density gradient and off-equatorial E region conductivity are inferred using digisonde measurements during April 2002 and December 2002. Based on these conditions and recent studies on gravity wave climatology over Brazil, it is suggested that shear in zonal plasma drift and low gravity wave activity may account for less occurrence of plume during April as compared to December months. This suggestion is quantified using numerical simulation model of collisional-interchange instability (CII) and plasma bubble.     

Imaging DOAS for volcanological applications

The simultaneous quantitative determination of two-dimensional bromine monoxide (BrO) and sulphur dioxide (SO₂) distributions in volcanic gas plumes is described. Measurements at the fumarolic field on the island Vulcano (autumn 2004) and in the plume of Mt. Etna volcano (spring 2005) were carried out with an Imaging DOAS instrument. The SO₂ fluxes of several fumaroles were estimated from two-dimensional distributions of SO₂. Additionally, the first two-dimensional distributions of BrO within a volcanic plume were successfully retrieved. Slant column densities of up to 2.6 × 10¹⁴ molecules per square centimetre were detected in the plume of Mt. Etna. The investigation of the BrO/SO₂ ratio, calculated from the two-dimensional distributions of SO₂ and BrO, shows an increase from the centre to the edge of the volcanic plume. These results have significance for the involvement of ozone during BrO formation processes in volcanic emissions.     

Mantle diapir-induced arc volcanism: The Ueno Basalts, Nomugi-Toge and Hida volcanic suites, central Japan

Stratigraphic and geochronological data show that the late Cenozoic Ueno Basalts and related Nomugi-Toge and Hida volcanic suites of the Norikura Volcanic Chain, Japan, were active for ~ 1 million years. Temporal and spatial variations of the volcanic activity and chemistry of the volcanic products suggest that it was induced by a common mantle diapir. The Ueno Basalts are small monogenetic volcanoes scattered over an area 50 km in diameter, and comprise a small volcanic province. The Ueno Basalts are almost all subalkalic basalt to basaltic andesite, erupted through the late Pliocene to the earliest Pleistocene (2.7–1.5 Ma). Andesite to dacite of the Nomugi-Toge volcanic rocks were concurrently active in the back arc side, and two eruption stages (2.6–2.2 and 2.1–1.7 Ma) are recognizable. Two voluminous dacite and rhyolite ignimbrites, the Hida Volcanic Rocks, were erupted deeper in the back-arc region, at ca 1.75 and 1.7 Ma. Both the Nomugi-Toge and Hida suites are also subalkalic, except for the last ignimbrite. In the Ueno Basalts, alkali olivine basalt was erupted in the earliest stage, and was followed by subalkalic basalt, showing that the magma segregation depth ascended with time. This coincided with uplift of the volcanic province and with quasi-concentric expansion of the eruption centers, suggesting that an upwelling mantle diapir was the cause of the volcanism. The Nomugi-Toge andesite–dacite lavas and the Hida dacite and rhyolite ignimbrites are considered to have originated from the same mantle diapir, because of their close proximity to the Ueno Basalts and their near-contemporaneous activity. Mantle diapirs have a significant role in the origin of subalkalic volcanic rocks in the island arcs.     

内蒙古贝力克玄武岩台地火山地质及成因探讨

根据火山地质特征,内蒙古锡林郭勒地区的新生代玄武岩可以划分为阿巴嘎玄武岩、贝力克玄武岩和达里诺尔玄武岩,呈NW-SE向展布.贝力克玄武岩以面积小、没有火山锥体、岩性较为单一(绝大多数为拉斑玄武岩)及不含慢源包体的熔岩台地而显著区别于另两种玄武岩.贝力克玄武岩以发育4级高低错落有致、大小不一的熔岩台地为特征,各级熔岩台地...     

New 40Ar/39Ar ages for selected young (<1 Ma) basalt flows of the Newer Volcanic Province,southeastern Australia

The Pliocene-Holocene Newer Volcanic Province (NVP) of southeastern Australia is an extensive, relatively well-preserved, intra-plate basaltic lava field containing more than 400 eruptive centres. This study reports new, high-precision ⁴⁰Ar/³⁹Ar ages for six young (300–600 ka) basalt flows from the NVP and is part of a broader initiative to constrain the extent, duration, episodicity and causation of NVP volcanism. Six fresh, holocrystalline alkali basalt flows were selected from the Warrnambool-Port Fairy area in the Western Plains sub-province for ⁴⁰Ar/³⁹Ar dating. These flows were chosen on the basis of pre-existing K-Ar age constraints, which, although variable, indicated eruption during a period of apparent relative volcanic quiescence (0.8–0.06 Ma).⁴⁰Ar/³⁹Ar ages were measured on multiple aliquots of whole rock basalt samples. Three separate flows from the Mount Rouse volcanic field yielded concordant ⁴⁰Ar/³⁹Ar age results, with a mean eruption age of 303 ± 13 ka (95% CI). An older weighted mean age of 382 ± 24 ka (2σ) was obtained for one sample from the central Rouse-Port Fairy Flow, suggesting extraneous argon contamination. Two basalt flows from the Mount Warrnambool volcano also yielded analogous results, with an average ⁴⁰Ar/³⁹Ar age of 542 ± 17 ka (95% CI). The results confirm volcanic activity during the interval of relative quiescence. Most previous K-Ar ages for these flows are generally older than the weighted mean ⁴⁰Ar/³⁹Ar ages, suggesting the presence of extraneous ⁴⁰Ar. This study demonstrates the suitability of the ⁴⁰Ar/³⁹Ar incremental-heating method to obtain precise eruption ages for young, holocrystalline alkali basalt samples in the NVP.     

The relationship between calc-alkaline volcanism and within-plate continental rift volcanism: evidence from Scottish Palaeozoic lavas

Lower Carboniferous lavas from the Midland Valley and adjacent regions of Scotland are mildly alkaline and intraplate in nature. The sequence is dominated by basalt and hawaiite, although mugearite, benmoreite, trachyte and rhyolite are also present. Basic volcanic rocks display the LIL element and LREE enrichment typical of intraplate alkali basalt terrains. Low initial⁸⁷Sr/⁸⁶Sr (0.7029–0.7046), high ε_Nd (−0.4 to +5.6) and moderately radiogenic²⁰⁶Pb/²⁰⁴Pb (17.77–18.89) ratios are also comparable with alkali basalts from other continental rifts and oceanic islands.When the Carboniferous lavas are compared with subduction-related lavas of Old Red Sandstone age, erupted in and around the Midland Valley ca. 50 Ma earlier (at 410 Ma) remarkable similarities are apparent. Significant overlap occurs in Nd and Pb isotopic compositions. Sr isotopic compositions are, however, more radiogenic in the older subduction-related lavas. This, combined with high K and Rb concentrations in ORS lavas may be explained by the incorporation of a sediment component derived from the subducted slab, which by Lower Carboniferous times had been lost from the mantle source region by convection. A pronounced negative Nb anomaly in the ORS subduction-related lavas may be explained by the retention of a Nb-bearing phase in the mantle during hydrous melting of the mantle wedge above the subduction zone.Allowing for the effects of the added component from the subducted slab, there appears to be no necessity to invoke separate mantle source regions for the two suites of lavas: both may have been derived from chemically similar portions of mantle. If volcanic arc lavas are derived from the mantle wedge, the implication is that such a source lies at relatively shallow depth within the upper mantle: the same may therefore apply to the Carboniferous continental rift basalts. This evidence, combined with the fact that there is no evident hot-spot trail across the Midland Valley despite a long period of within-plate volcanism and rapid plate movements during the Carboniferous, suggests that the alkali basalt magmatism is not the product of a deep-seated mantle plume. Rather, the volcanism appears to owe more to passive rifting and to diapiric upwelling from a source region within the uppermost mantle.     

A late pleistocene to recent rhyodacite-trachybasalt-basaltic latite volcanic association in north-east Papua

The Managalase Plateau in north-east Papua is a faultbounded block of fractured basement metabasalt and basic plutonic rock overlain in the east by some thirty small volcanic centres of late Pleistocene to Recent age which include rhyodacite ash cones and trachybasalt and basaltic latite lava. To the north andesitic strato-volcanoes of Pleistocene and Recent age occur along the margin of the Cape Vogel geosyncline, whereas to the south a series of basaltic latite, alkali basalt and ultra-alkaline lava of Pliocene age margin the Papuan basic-ultrabasic belt. There is a transition, probably by fractional crystallization from alkali basalt through trachybasalt towards trachyandesite, but the basaltic latite and ultraalkaline lava are aberrant offshoots, possibly owing to contamination by phyllite. The « orogenic andesite » shows disequilibrium relations among the minerals including complexly zoned and twinned plagioclase, and common xenocrysts and xenoliths. Their chemistry can be simulated by mixtures of rhyodacite with either alkali basalt or trachybasalt and they are richer in both magnesia and potash than other calc-alkali rock suites. The rhyodacites, however, are of normal cale-alkali character.