Detailed record of SO2 emissions from Pu'u `O`o between episodes 33 and 34 of the 1983–86 ERZ eruption,Kilauea, Hawaii

A tripod-mounted correlation spectrometer was used to measure SO₂ emissions from Pu`u `O`o vent, mid-ERZ, Kilauea, Hawaii between Episodes 33 and 34 (June 13 to July 6, 1985). In 24 repose days, 906 measurements were collected, averaging 38 determinations/day. Measurements reflect 13% of the total 576 hours of the repose and 42% of the bright daylight hours. The average SO<sub>2</sub> emission for the 24-day repose interval is 167±83 t/d, a total of 4000 tonnes emitted for the entire repose. The large standard deviation reflects the puffing character of the plume. The overall rate of SO<sub>2</sub> degassing gently decreased with a zero-intercept of 44–58 days and was interrupted by two positive peaks. The data are consistent with the gas emanating from a cylindrical conduit of 50 meter diameter and a length of 1700 meters which degasses about 50% of its SO<sub>2</sub> during 24 days. This is in support of the Pu'u `O`o model of Greenland et al. (1987). 36 hours before the onset of Episode 34 (July 5–6, 1985), elevated SO₂ emissions were detected while the magma column was extremely active ultimately spilling over during dome fountaining. A mid-repose anomaly of SO₂ emission (June 21–22, 1985) occurs two days before a sudden increase in the rate of summit inflation (on June 24, 1985), suggesting magma was simultaneously being injected in both the ERZ and summit reservoir until July 24 when it was channelled only to the summit reservoir. This implies degassing magma is sensitive to perturbations within the rift zone conduit system and may at times reflect these disturbances. Periods of 7–45 min are detected in the daily SO₂ emissions, which possibly reflect timing of convective overturn in the cylindrical magma body. If the 33–34 repose interval is considered representative of other repose periods, the ERZ reposes of Jan 1983–Jan 1986 ERZ activity, contributed 1.6 × 10⁵ tonnes of SO₂ to the atmosphere. Including summit fuming from non-eruptive fumaroles (2.7 × 10⁵ tonnes SO₂); 28% of the total SO₂ budget from Kilauea between Jan 1983 to Jan 1986 was contributed by quiescent degassing, and the remainder was released during explosive fountaining episodes.     

Magma supply and storage at Kilauea volcano, Hawaii, 1956–1983

Shallow crustal magma reservoirs beneath the summit of Kilauea Volcano and within its rift zones are linked in such a way that the magma supply to each can be estimated from the rate of ground deformation at the volcano's summit. Our model builds on the well-documented pattern of summit inflation as magma accumulates in a shallow summit reservoir, followed by deflation as magma is discharged to the surface or into the rift zones. Magma supply to the summit reservoir is thus proportional to summit uplift, and supply to the rift zones is proportional to summit subsidence; the average proportionality constant is 0.33 × 10⁶ m³/γrad. This model yields minimum supply estimates because it does not account for magma which escapes detection by moving passively through the summit reservoir or directly into the rift zones.Calculations suggest that magma was supplied to Kilauea during July 1956– April 1983 at a minimum average rate of 7.2 × 10⁶ m3/month. Roughly 35% of the net supply was extruded; the rest remains stored within the volcano's east rift zone (55%) and southwest rift zone (10%). Periods of relatively rapid supply were associated with the large Kapoho eruption in 1960 and the sustained Mauna Ulu eruptions in 1969–1971 and 1972–1974. Bursts of harmonic tremor from the mantle beneath Kilauea were also unusually energetic during 1968–1975, suggesting a close link between Kilauea's deep magma supply region and shallow storage reservoirs. It remains unclear whether pulses in magma supply from depth give rise to corresponding increases in shallow supply, or if instead unloading of a delicately balanced magma transport system during large eruptions or intrusions triggers more rapid ascent from a relatively constant mantle source.     

Summit CO2 emission rates by the CO2/SO2 ratio method at Kīlauea Volcano,Hawaiʻi,during a period of sustained inflation

The emission rate of carbon dioxide escaping from the summit of Kīlauea Volcano, Hawai?i, proved highly variable, averaging 4900 ± 2000 metric tons per day (t/d) in June–July 2003 during a period of summit inflation. These results were obtained by combining over 90 measurements of COSPEC-derived SO₂ emission rates with synchronous CO₂/SO₂ ratios of the volcanic gas plume along the summit COSPEC traverse. The results are lower than the CO₂ emission rate of 8500 ± 300 t/d measured by the same method in 1995–1999 during a period of long-term summit deflation [Gerlach, T.M., McGee, K.A., Elias, T., Sutton, A.J. and Doukas, M.P., 2002. Carbon dioxide emission rate of Kīlauea Volcano: Implications for primary magma and the summit reservoir. Journal of Geophysical Research-Solid Earth, 107(B9): art. no.-2189.]. Analysis of the data indicates that the emission rates of the present study likely reflect changes in the magma supply rate and residence time in the summit reservoir. It is also likely that emission rates during the inflation period were heavily influenced by SO₂ pulses emitted adjacent to the COSPEC traverse, which biased CO₂/SO₂ ratios towards low values that may be unrepresentative of the global summit gas plume. We conclude that the SO₂ pulses are consequences of summit re-inflation under way since 2003 and that CO₂ emission rates remain comparable to, but more variable than, those measured prior to re-inflation.     

Comparison of COSPEC and two miniature ultraviolet spectrometer systems for SO2 measurements using scattered sunlight

The correlation spectrometer (COSPEC), the principal tool for remote measurements of volcanic SO₂, is rapidly being replaced by low-cost, miniature, ultraviolet (UV) spectrometers. We compared two of these new systems with a COSPEC by measuring SO₂ column amounts at Kīlauea Volcano, Hawaii. The two systems, one calibrated using in-situ SO₂ cells, and the other using a calibrated laboratory reference spectrum, employ similar spectrometer hardware, but different foreoptics and spectral retrieval algorithms. Accuracy, signal-to-noise, retrieval parameters, and precision were investigated for the two configurations of new miniature spectrometer. Measurements included traverses beneath the plumes from the summit and east rift zone of Kīlauea, and testing with calibration cells of known SO₂ concentration. The results obtained from the different methods were consistent with each other, with <8% difference in estimated SO₂ column amounts up to 800 ppm m. A further comparison between the COSPEC and one of the miniature spectrometer configurations, the ‘FLYSPEC’, spans an eight month period and showed agreement of measured emission rates to within 10% for SO₂ column amounts up to 1,600 ppm m. The topic of measuring high SO₂ burdens accurately is addressed for the Kīlauea measurements. In comparing the foreoptics, retrieval methods, and resultant implications for data quality, we aim to consolidate the various experiences to date, and improve the application and development of miniature spectrometer systems.     

Storage, migration, and eruption of magma at Kilauea volcano, Hawaii, 1971–1972

The magmatic plumbing system of Kilauea Volcano consists of a broad region of magma generation in the upper mantle, a steeply inclined zone through which magma rises to an intravolcano reservoir located about 2 to 6 km beneath the summit of the volcano, and a network of conduits that carry magma from this reservoir to sites of eruption within the caldera and along east and southwest rift zones. The functioning of most parts of this system was illustrated by activity during 1971 and 1972. When a 29-month-long eruption at Mauna Ulu on the east rift zone began to wane in 1971, the summit region of the volcano began to inflate rapidly; apparently, blockage of the feeder conduit to Mauna Ulu diverted a continuing supply of mantle-derived magma to prolonged storage in the summit reservoir. Rapid inflation of the summit area persisted at a nearly constant rate from June 1971 to February 1972, when a conduit to Mauna Ulu was reopened. The cadence of inflation was twice interrupted briefly, first by a 10-hour eruption in Kilauea Caldera on 14 August, and later by an eruption that began in the caldera and migrated 12 km down the southwest rift zone between 24 and 29 September. The 14 August and 24–29 September eruptions added about 10⁷ m³ and 8 × 10⁶ m³, respectively, of new lava to the surface of Kilauea. These volumes, combined with the volume increase represented by inflation of the volcanic edifice itself, account for an approximately 6 × 10⁶ m³/month rate of growth between June 1971 and January 1972, essentially the same rate at which mantle-derived magma was supplied to Kilauea between 1952 and the end of the Mauna Ulu eruption in 1971.The August and September 1971 lavas are tholeiitic basalts of similar major-element chemical composition. The compositions can be reproduced by mixing various proportions of chemically distinct variants of lava that erupted during the preceding activity at Mauna Ulu. Thus, part of the magma rising from the mantle to feed the Mauna Ulu eruption may have been stored within the summit reservoir from 4 to 20 months before it was erupted in the summit caldera and along the southwest rift zone in August and September.The September 1971 activity was only the fourth eruption on the southwest rift zone during Kilauea's 200 years of recorded history, in contrast to more than 20 eruptions on the east rift zone. Order-of-magnitude differences in topographic and geophysical expression indicate greatly disparate eruption rates for far more than historic time and thus suggest a considerably larger dike swarm within the east rift zone than within the southwest rift zone. Characteristics of the historic eruptions on the southwest rift zone suggest that magma may be fed directly from active lava lakes in Kilauea Caldera or from shallow cupolas at the top of the summit magma reservoir, through fissures that propagate down rift from the caldera itself at the onset of eruption. Moreover, emplacement of this magma into the southwest rift zone may be possible only when compressive stress across the rift is reduced by some unknown critical amount owing either to seaward displacement of the terrane south-southeast of the rift zone or to a deflated condition of Mauna Loa Volcano adjacent to the northwest, or both. The former condition arises when the forceful emplacement of dikes into the east rift zone wedges the south flank of Kilauea seaward. Such controls on the potential for eruption along the southwest rift zone may be related to the topographic and geophysical constrasts between the two rift zones.     

Airborne measurements of particle and gas emissions from the December 1994–January 1995 eruption of Popocatépetl volcano (Mexico)

Airborne and ground-based (correlation spectrometer, cascade impactor, and photoelectric counter together with intake filter probes) measurements are described for the volcanic emissions from Popocatépetl volcano (Mexico) from December 23, 1994 to January 28, 1995. Measurements of SO₂ restarted 48 h after the eruption onset of December 21, 1994. Maximum sulfur dioxide (4560 t d⁻¹) plus 3.8×10⁴ t d⁻¹ of particulate matter were ejected on December 24, 1994. The maximum rate of ejection occurred coincidentally with the maximum amplitude of harmonic tremor and the maximum number of seismic type B events. Sulfur dioxide emission rates ranged from 1790 to 2070 t d⁻¹ (December 23–24, 1994). Afterwards, sulfur dioxide emission rates clearly indicated a consistent decline. However, frequent gas and ash emission puffs exhibited SO₂ fluxes reaching values as high as 3060 t d⁻¹. The emission SO₂ baseline for the period of study (February 1994–January 1995) was about 1000 t d⁻¹. Ejection velocity of particulate matter was approximately 270 m s⁻¹ reaching a height of about 2.5 km over the summit. The immediate aerosol dispersion area was estimated at 6.0×10⁴ km² maximum. The microscopic structure of particles (aerosol and tephra) showed a fragile material, probably coming from weathered crustal layers. X-ray fluorescence and neutron-activation analysis from the impactor samples found the following elements: Si, Al, Ca, S, P, Cl, K, Ni, Fe, Ti, Sc, Cu, Zn, Mn, Sr, Cr, Co, Y, Br, Se, Ga, Rb, Hg and Pb. Morphological analysis shows that ash samples might be from pulverized basaltic rock indicating that the Popocatépetl eruption of December 21, 1994 was at low temperature. The microscopic structure of puff material showed substance aggregates consisted of fragile rock, water and adsorbed SO₂. These aggregates were observed within water droplets of approximately 1 mm and even larger. Sulfur transformations in the droplets occurred intensively. Volcanic ash contained 5–6% of sulfur during the first expulsion hours. Elemental relative concentrations with respect to Al show that both Si and S have relative concentrations >1, i.e., 13.73 and 2.17, respectively in agreement with the photoelectric counter and COSPEC measurements.     

SO2 from episode 48A eruption,Hawaii: Sulfur dioxide emissions from the episode 48A East Rift Zone eruption of Kilauea volcano,Hawaii

An SO₂ flux of 1170±400 (1) tonnes per day was measured with a correlation spectrometer (COSPEC) in October and November 1986 from the continuous, nonfountaining, basaltic East Rift Zone eruption (episode 48A) of Kilauea volcano. This flux is 5–27 times less than those of highfountaining episodes, 3–5 times greater than those of contemporaneous summit emissions or interphase Pu'u O'o emissions, and 1.3–2 times the emissions from Pu'u O'o alone during 48A. Calculations based on the SO₂ emission rate resulted in a magma supply rate of 0.44 million m³ per day and a 0.042 wt% sulfur loss from the magma upon eruption. Both of these calculated parameters agree with determinations made previously by other methods.     

Puhimau Thermal Area: A Window into the Upper East Rift Zone of Volcano, Hawaii?

We report the results of two soil CO₂ efflux surveys by the closed chamber circulation method at the Puhimau thermal area in the upper East Rift Zone (ERZ) of volcano, Hawaii. The surveys were undertaken in 1996 and 1998 to constrain how much CO₂ might be reaching the ERZ after degassing beneath the summit caldera and whether the Puhimau thermal area might be a significant contributor to the overall CO₂ budget of . The area was revisited in 2001 to determine the effects of surface disturbance on efflux values by the collar emplacement technique utilized in the earlier surveys. Utilizing a cutoff value of 50 g m⁻² d⁻¹ for the surrounding forest background efflux, the CO₂ emission rates for the anomaly at Puhimau thermal area were 27 t d⁻¹ in 1996 and 17 t d⁻¹ in 1998. Water vapor was removed before analysis in all cases in order to obtain CO₂ values on a dry air basis and mitigate the effect of water vapor dilution on the measurements. It is clear that Puhimau thermal area is not a significant contributor to CO₂ output and that most of CO₂ (8500 t d⁻¹) is degassed at the summit, leaving only magma with its remaining stored volatiles, such as SO₂, for injection down the ERZ. Because of the low CO₂ emission rate and the presence of a shallow water table in the upper ERZ that effectively scrubs SO₂ and other acid gases, Puhimau thermal area currently does not appear to be generally well suited for observing temporal changes in degassing at .     

Water chemistry of Lake Quilotoa (Ecuador) and assessment of natural hazards

A geochemical survey carried out in November 1993 revealed that Lake Quilotoa was composed by a thin (14 m) oxic epilimnion overlying a 200 m-thick anoxic hypolimnion. Dissolved CO₂ concentrations reached 1000 mg/kg in the lower stratum. Loss of CO₂ from epilimnetic waters, followed by calcite precipitation and a consequent lowering in density, was the apparent cause of the stratification.The Cl, SO₄ and HCO₃ contents of Lake Quilotoa are intermediate between those of acid–SO₄–Cl Crater lakes and those of neutral-HCO₃ Crater lakes, indicating that Lake Quilotoa has a ‘memory’ of the inflow and absorption of HC1- and S-bearing volcanic (magmatic) gases. The Mg/Ca ratios of the lake waters are governed by dissolution of local volcanic rocks or magmas, but K/Na ratios were likely modified by precipitation of alunite, a typical mineral in acid–SO₄–Cl Crater lakes.The constant concentrations of several conservative chemical species from lake surface to lake bottom suggest that physical, chemical and biological processes did not have enough time, after the last overturn, to cause significant changes in the contents of these chemical species. This lapse of time might be relatively large, but it cannot be established on the basis of available data. Besides, the lake may not be close to steady state. Mixing of Lake Quilotoa waters could presently be triggered by either cooling epilimnetic waters by 4°C or providing heat to hypolimnetic waters or by seismic activity.Although Quilotoa lake contains a huge amount of dissolved CO₂ (3×10¹¹ g), at present the risk of a dangerous limnic eruption seems to be nil even though some gas exsolution might occur if deep lake waters were brought to the surface. Carbon dioxide could build up to higher levels in deep waters than at present without any volcanic re-awakening, due to either a large inflow of relatively cool CO₂-rich gases, or possibly a long interval between overturns. Periodical geochemical surveys of Lake Quilotoa are, therefore, recommended.     

Transient deformation following the 30 January 1997 dike intrusion at Kīlauea volcano,Hawai’i

On 30 January 1997 an intrusion on Kīlauea volcano opened a new fissure within the East Rift Zone (ERZ) at Nāpau Crater, 3 km uprift from the ongoing eruptions at Pu’u ’Ō’ō. The fissure eruption lasted 22 h and opened a 5.1 km long, nearly vertical dike 1.9 m, extending from the surface to a depth of 2.4 km (Owen et al. 2000b). During the eruption, the lava pond at Pu’u ’Ō’ō drained, and eruptions ceased there. Pu’u ’Ō’ō eventually refilled in late February and eruptions resumed there on 28 March 1997. Continuous GPS data show a large transient following the 30 January 1997 dike intrusion. After lengthening 40 cm during the initial eruption, the baseline between two stations spanning the ERZ lengthened an additional 10 cm over the following 6 months. A coastal station KAEP also exhibited transient deformation, as it continued to move southward (5 cm) over the same 6-month period. The baseline between two stations spanning Kīlauea’s summit caldera contracted sharply during the eruption, but gradually recovered to slightly longer than its previous length 2 months after the intrusion. We use the extended network inversion filter (McGuire and Segall 2003) to invert continuous GPS data for volume change of a spherical pressure source under Kīlauea’s summit, opening distribution on a nearly vertical dike in the ERZ and potential slip on a decollement 9 km beneath the south flank. Following the 30 January intrusion, rift extension continued below the initial dike intrusion for the duration of the transient. Decollement slip, regardless of its assumed depth, is not required to fit the data. The modeled transient summit reinflation and rift opening patterns under Nāpau crater coincide with changes in observed behavior of Pu’u ’Ō’ō’s lava pond. Rift opening accelerated while Pu’u ’Ō’ō eruptions paused and began to decelerate after the lava pond reappeared nearly a month after the Nāpau eruption. The transient deformation is interpreted as resulting from shallow accommodation of the new dike volume.     

Mechanism of energy transfer in the lava lake of Niragongo (Zaire), 1959–1977

Heat and mass transfer rates were studied at the Niragongo lava lake during two expeditions directed by H. Tazieff in 1959 and 1972. The results of this study are as follows:Heat is transferred to the surface of the lake by the movement of lava; gas discharge is a result and not the cause of convection. The chemical composition of the gases and magma has changed very little between 1959 and 1972, whereas the mass and energy outputs differ by an order of magnitude. In 1977 a catastrophic explosion seems to have been caused by tectonic factors, stopping the slow convection of magma under the volcano and hence reducing surface manifestations in the form of the lava lake and escaping fumarolic and magmatic gases. The gas discharge was, in tons day⁻¹, 5000 for H₂O, 11,000 for CO₂, 1000 for SO₂ in 1959, and in 1972 7700 for H₂O, 180,000 for CO₂ and 23,000 for SO₂. These values correspond to an energy transfer of 0.9 × 10⁹ W in 1959 and 16 × 10⁹ W in 1972.     

Overview of the 1990–1995 eruption at Unzen Volcano

Following 198 years of dormancy, a small phreatic eruption started at the summit of Unzen Volcano (Mt. Fugen) in November 1990. A swarm of volcano-tectonic (VT) earthquakes had begun below the western flank of the volcano a year before this eruption, and isolated tremor occurred below the summit shortly before it. The focus of VT events had migrated eastward to the summit and became shallower. Following a period of phreatic activity, phreatomagmatic eruptions began in February 1991, became larger with time, and developed into a dacite dome eruption in May 1991 that lasted approximately 4 years. The emergence of the dome followed inflation, demagnetization and a swarm of high-frequency (HF) earthquakes in the crater area. After the dome appeared, activity of the VT earthquakes and the summit HF events was replaced largely by low-frequency (LF) earthquakes. Magma was discharged nearly continuously through the period of dome growth, and the rate decreased roughly with time. The lava dome grew in an unstable form on the shoulder of Mt. Fugen, with repeating partial collapses. The growth was exogenous when the lava effusion rate was high, and endogenous when low. A total of 13 lobes grew as a result of exogenous growth. Vigorous swarms of LF earthquakes occurred just prior to each lobe extrusion. Endogenous growth was accompanied by strong deformation of the crater floor and HF and LF earthquakes. By repeated exogenous and endogenous growth, a large dome was formed over the crater. Pyroclastic flows frequently descended to the northeast, east, and southeast, and their deposits extensively covered the eastern slope and flank of Mt. Fugen. Major pyroclastic flows took place when the lava effusion rate was high. Small vulcanian explosions were limited in the initial stage of dome growth. One of them occurred following collapse of the dome. The total volume of magma erupted was 2.1×10⁸ m³ (dense-rock-equivalent); about a half of this volume remained as a lava dome at the summit (1.2 km long, 0.8 km wide and 230–540 m high). The eruption finished with extrusion of a spine at the endogenous dome top. Several monitoring results convinced us that the eruption had come to an end: the minimal levels of both seismicity and rockfalls, no discharge of magma, the minimal SO₂ flux, and cessation of subsidence of the western flank of the volcano. The dome started slow deformation and cooling after the halt of magma effusion in February 1995.     

The establishment of a GPS deformation network in the ethiopian rift valley

In April and May 1989 the satellite Global Positioning System (GPS) was employed in the establishment of three deformation networks in the Ethiopian Rift Valley. The net E1 consists of 6 points of about 100–270 km interdistances, with two points located on each of the African and the Somalian plate and two points down in the rift. In addition two separate GPS traverses were established: one (E2) runs across the rift, and one (E3) runs about 500 km along the rift.The remeasurement of a 175 km long baseline included in two subcampaigns indicates a repeatability of the GPS observations of the order of 1×10⁻⁷ and 3×10⁻⁷ for slope distance and ellipsoidal height, respectively.Along the E2 traverse GPS/trigonometric levelled geoid undulations and gravimetric geoid undulations agree well, while the discrepancy along the E3 traverse needs further analysis.     

Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Radionuclides and sulfur content in Mount Etna plume in 1983–1995: new constraints on the magma feeding system

Radionuclide activities (²¹⁰Pb, ²¹⁰Bi, ²¹⁰Po) were investigated in Mount Etna plume from 1983 to 1995. At SE crater the long-term observation (12 years) of the ²¹⁰Po/²¹⁰Pb ratio shows that it can behave as a degassing vent not directly related to the main magma reservoir depending on the magma level inside the volcano. Since 1992, the simultaneous determination of radionuclides and sulfur in the main plume results in new constraints on the degassing model of Lambert et al. (Earth Planet. Sci. Lett., 76 (1986) 185). The ²¹⁰Po/SO₂ and ²¹⁰Pb/SO₂ ratios enable us to identify two sources of ²¹⁰Po in the plume: one is magmatic, correlated with SO₂, the other one is an additional component issued from the decay of ²¹⁰Pb in the shallow degassing cell, and depends directly on the residence time of the gases before their emission. Estimations of the volume of degassing magma, the residence time of the gases and the proportion of undegassed magma renewing the shallow degassing cell are given for the period 1992–1995. During the 1992 eruption, the rate of degassing magma volume is estimated to have been as high as 5×10⁶ m³/day, and the volume of the shallow degassing magma reservoir about 0.5 km³. In 1994 and 1995 the rate of non-erupted degassing magma volume was estimated to have been about 0.18 km³/year. During the entire 1983–1995 period, only 15–20% of the degassed magma was erupted.     

Fumarole/plume and diffuse CO2 emission from Sierra Negra caldera, Galapagos archipelago

Measurements of visible and diffuse gas emission were conducted in 2006 at the summit of Sierra Negra volcano, Galapagos, with the aim to better characterize degassing after the 2005 eruption. A total SO₂ emission of 11?±?2?t day^?1 was derived from miniature differential optical absorption spectrometer (mini-DOAS) ground-based measurements of the plume emanating from the Mini Azufral fumarolic area, the most important site of visible degassing at Sierra Negra volcano. Using a portable multigas system, the H₂S/SO₂, CO₂/SO₂, and H₂O/SO₂ molar ratios in the Mina Azufral plume emissions were found to be 0.41, 52.2, and 867.9, respectively. The corresponding H₂O, CO₂, and H₂S emission rates were 562, 394, and 3?t day^?1, respectively. The total output of diffuse CO₂ emissions from the summit of Sierra Negra volcano was 990?±?85?t day^?1, with 605?t day^?1 being released by a deep source. The diffuse-to-plume CO₂ emission ratio was about 1.5. Mina Azufral fumaroles released gasses containing 73.6?mol% of H₂O; the main noncondensable components amounted to 97.4?mol% CO₂, 1.5?mol% SO₂, 0.6?mol% H₂S, and 0.35?mol%?N₂. The higher H₂S/SO₂ ratio values found in 2006 as compared to those reported before the 2005 eruption reveal a significant hydrothermal contribution to the fumarolic emissions. ³He/⁴He ratios measured at Mina Azufral fumarolic discharges showed values of 17.88?±?0.25?R _A , indicating a mid-ocean ridge basalts (MORB) and a Galapagos plume contribution of 53 and 47?%, respectively.     

Geochemistry of the magmatic–hydrothermal system of Kawah Ijen volcano, East Java, Indonesia

Samples from Kawah Ijen crater lake, spring and fumarole discharges were collected between 1990 and 1996 for chemical and isotopic analysis. An extremely low pH (<0.3) lake contains SO₄–Cl waters produced during absorption of magmatic volatiles into shallow ground water. The acidic waters dissolve the rock isochemically to produce “immature” solutions. The strong D and ¹⁸O enrichment of the lake is mainly due to enhanced evaporation at elevated temperature, but involvement of a magmatic component with heavy isotopic ratios also modifies the lake D and ¹⁸O content. The large Δ_SO4–S⁰ (23.8–26.4‰) measured in the lake suggest that dissolved SO₄ forms during disproportionation of magmatic SO₂ in the hydrothermal conduit at temperatures of 250280°C. The lake δ¹⁸O_SO4 and δ¹⁸O_H2O values may reflect equilibration during subsurface circulation of the water at temperatures near 150°C. Significant variations in the lake's bulk composition from 1990 to 1996 were not detected. However, we interpret a change in the distribution and concentration of polythionate species in 1996 as a result of increased SO₂-rich gas input to the lake system.Thermal springs at Kawah Ijen consist of acidic SO₄–Cl waters on the lakeshore and neutral pH HCO₃–SO₄–Cl–Na waters in Blawan village, 17 km from the crater. The cation contents of these discharges are diluted compared to the crater lake but still do not represent equilibrium with the rock. The SO₄/Cl ratios and water and sulfur isotopic compositions support the idea that these springs are mixtures of summit acidic SO₄–Cl water and ground water.The lakeshore fumarole discharges (T=170245°C) have both a magmatic and a hydrothermal component and are supersaturated with respect to elemental sulfur. The apparent equilibrium temperature of the gas is 260°C. The proportions of the oxidized, SO₂-dominated magmatic vapor and of the reduced, H₂S-dominated hydrothermal vapor in the fumaroles varied between 1979 and 1996. This may be the result of interaction of SO₂-bearing magmatic vapors with the summit acidic hydrothermal reservoir. This idea is supported by the lower H₂S/SO₂ ratio deduced for the gas producing the SO₄–Cl reservoir feeding the lake compared with that observed in the subaerial gas discharges. The condensing gas may have equilibrated in a liquid–vapor zone at about 350°C.Elemental sulfur occurs in the crater lake environment as banded sediments exposed on the lakeshore and as a subaqueous molten body on the crater floor. The sediments were precipitated in the past during inorganic oxidation of H₂S in the lake water. This process was not continuous, but was interrupted by periods of massive silica (poorly crystallized) precipitation, similar to the present-day lake conditions. We suggest that the factor controlling the type of deposition is related to whether H₂S- or silica-rich volcanic discharges enter the lake. This could depend on the efficiency with which the lake water circulates in the hydrothermal cell beneath the crater. Quenched liquid sulfur products show δ³⁴S values similar to those found in the banded deposits, suggesting that the subaqueous molten body simply consists of melted sediments previously accumulated at the lake bottom.     

Horizontal ground deformation patterns and magma storage during the Puu Oo eruption of Kilauea volcano,Hawaii: episodes 22–42

Horizontal ground deformation measurements were made repeatedly with an electronic distance meter near the Puu Oo eruption site approximately perpendicular to Kilauea's east rift zone (ERZ) before and after eruptive episodes 22–42. Line lengths gradually extended during repose periods and rapidly contracted about the same amount following eruptions. The repeated extension and contraction of the measured lines are best explained by the elastic response of the country rock to the addition and subsequent eruption of magma from a local reservoir. The deformation patterns are modeled to constrain the geometry and location of the local reservoir near Puu Oo. The observed deformation is consistent with deformation patterns that would be produced by the expansion of a shallow, steeply dipping dike just uprift of Puu Oo striking parallel to the trend of the ERZ. The modeled dike is centered about 800 m uprift of Puu Oo. Its top is at a depth of 0.4 km, its bottom at about 2.9 km, and the length is about 1.6 km; the dike strikes N65° E and dips at about 87°SE. The model indicates that the dike expanded by 11 cm during repose periods, for an average volumetric expansion of nearly 500 000 m³. The volume of magma added to the dike during repose periods was variable but correlates positively with the volume of erupted lava of the subsequent eruption and represents about 8% of the new lava extruded. Dike geometry and expansion values are used to estimate the pressure increase near the eruption site due to the accumulation of magma during repose periods. On average, vent pressures increased by about 0.38 MPa during the repose periods, one-third of the pressure increase at the summit. The model indicates that the dikelike body below Puu Oo grew in volume from 3 million cubic meters (Mm³) to about 10–12 Mm³ during the series of eruptions. The width of this body was probably about 2.5–3.0 m. No net long-term deformation was detected along the measured deformation lines.     

Hydrothermal vent waters at 13°N on the East Pacific Rise: isotopic composition and gas concentration

Gas concentrations and isotopic compositions of water have been measured in hydrothermal waters from 13°N on the East Pacific Rise. In the most Mg-depleted samples ( 5 × 10⁻³ moles/kg) the gas concentrations are: 3–4.5 × 10⁻⁵ cm³ STP/kg helium, 0.62–1.24 cm³ STP/kg CH₄, 10.80–16.71 × 10⁻³ moles/kg CO₂. The samples contain large quantities (95–126 cm³/kg) of H₂ and some carbon monoxide (0.26–0.36 cm³/kg) which result from reaction with the titanium sampling bottles. δ¹³C in methane and CO₂ (−16.6 to −19.5 and −4.1 to −5.5 respectively) indicate temperatures between 475 and 550°C, whereas δ¹³C_CO is compatible with formation by reduction of CO₂ on Ti at 350°C close to the sampling temperature.³He/⁴He are very homogeneous at (7.5 ± 0.1)R_A(³He/⁴He = 1.0 × 10⁻⁵) and very similar to already published data as well as CH₄/³He ratios between 1.4 and 2.1 × 10⁶.¹⁸O and D in water show enrichments from 0.39 to 0.69‰ and from 0.62 to 1.49‰ respectively. These values correspond to W/R ratios of 0.4–7. The distinct¹⁸O enrichments indicate that the isotopic composition of the oceans is not completely buffered by the hydrothermal circulations. The³He-enthalpy relationship is discussed in terms of both hydrothermal heat flux and³He mantle flux.     

Modeling Groundwater Inflow to the New Crater Lake at Kīlauea Volcano,Hawai'i

During the 2018 eruption of Kīlauea Volcano, Hawai'i, scientists relied heavily on a conceptual model of explosive eruptions triggered when lava-lake levels drop below the water table. Numerical modeling of multiphase groundwater flow and heat transport revealed that, contrary to expectations, liquid water inflow to the drained magma conduit would likely be delayed by months to years, owing to the inability of liquid water to transit a zone of very hot rock. The summit of Kīlauea subsequently experienced an ∼2-month period of consistent repeated collapses, and the crater now extends below the equilibrium position of the water table. Liquid water first emerged into the deepened crater in late July 2019. The timing of first appearance of liquid water (about 14 months postcollapse) and the rate of crater lake filling (currently ∼27 kg/s) were well-predicted by the numerical modeling done in late spring 2018, which forecast liquid inflow after 3 to 24 months at rates of 10 to 100 kg/s. A second-generation groundwater model, reflecting the current crater geometry, forecasts lake filling over the next several years. The successful 2018 to present forecasts with both models are based on unadjusted in situ permeability estimates (1 to 6 × 10⁻¹⁴ m²) and water-table elevations (600 to 800 m) from a nearby research drillhole and geophysical surveys. Important unknowns that affect the reliability of longer-term forecasts include the equilibrium water-table geometry, the rate of evaporation from the hot and growing crater lake (currently ∼29,000 m² at 70-80 °C), and heterogenous permeability changes caused by the 2018 collapse.