吉林白山(浑江)金矿床岩石地球化学特征

白山金矿是近年来在吉林南部地区发现的一种重要类型金矿床--微细浸染型金矿床,矿床赋存在活泼性较高的元古庙老岭群珍珠门组大理岩中.吉南元古庙分布区Au、Zn、Sb、Cd、Sn、As、Hg等元素丰度具有显著偏高特征,白山金矿区Au、Ag、W、Bi、Sb、As等元素具有浓集系数高、变异系数大、多元素套合叠加异常等特点.异常带沿构造带分布并具有明显分带现象,元素组合为Au-Sn-Zn-Ag-Cd.     

西藏浪卡子县也金嘎波金矿岩石地球化学特征

也金嘎波金矿位于冈底斯成矿带上,是对区域化探发现的Au、As多元素组合异常进行追踪发现的,属于热液型金矿床。矿区各类岩石Au、As、Sb、W、Hg、Ag、Bi、Pb元素平均值高于中国丰度值数倍以上,表明矿区具有丰富的物质来源基础。岩石地球化学研究证明,矿床地表发育Au、As、Sb等10多个元素组合异常。其中Au是成矿指示元素,As、Sb、W是密切伴生元素,Bi、Ag、Pb、Hg是一般的伴生元素。多元素组合异常浓度带发育,浓集中心互相套合叠置部位指示金矿(化)体位置。矿体指示元素(Au、As、Sb、W、Hg、Bi、Ag、Pb)异常分布在岩体、地层接触带和构造交汇处,显示金矿与岩浆活动、热液作用和断裂构造相关,属多次构造作用、岩浆热液叠加富集而成。该金矿床处在冈底斯成矿带内,此研究对该成矿带金异常的识别和查证,寻找新的金矿具有借鉴意义。     

吉林省小西南岔金铜矿床地球化学特征

小西南岔金铜矿床为浅成金铜共生大型矿床,受岩体-地层-构造联合控制,以叠加富集为主.矿区分为南山和北山两个矿段.矿化主要发育在闪长岩和斜长花岗岩中的北北西向断裂带及岩体接触带中,矿化以含金铜石英硫化物脉型及密集细脉为主.矿区水系沉积物异常元素为Au、Cu、Ag、Bi、Zn、Mo（W、Sb、As）;土壤异常元素为Cu、Mo、Au、Ag、Bi;岩石地球化学异常为Au、Cu、Ag、Bi、Ta、Ba、Sr（As、Sb、Zn、Co、Ni、W、Mo）.原生晕中轴向分带序列为（Bs、Sr）-As-Ag-Pb-Sn-W-Au-Bi-Cu-Sb-CoTe-Ni-Zn-Mo.南山矿段水平分带序列为Au-Cu-Bi-Te-Ag-Pb-Zn-As-Co-Ni-W-Sb-Mo-Sn;北山矿段为Au-Cu-Bi-Te-AgAs-Sb-Mo-Pb-Zn-Co-W-Ni-Sn.矿床地球化学异常特征及其分带性显示北山矿段矿体剥蚀程度大于南山矿段,矿区北西部矿体剥蚀强度大于南东部,表明向矿区南部仍有较大找矿远景.     

安徽庐江黄屯铜金矿床原生晕特征及矿床成因

通过对安徽庐江黄屯铜金矿床18号勘探线上的4个钻孔岩心进行系统取样和分析,研究了18号勘探线剖面地质特征及原生晕分带特征,探讨了该矿床的地球化学异常模式及矿床成因。黄屯铜金矿床的特征元素组合为Au、Ag、Cu、As、Sb、Bi、W,原生晕垂向分带序列为（Sb、As）-（Ag、Au、Cu）-（Bi、W）。18号勘探线剖面地质特征和原生晕形态特征显示,在ZK18-1钻孔和ZK18-2钻孔之间可能存在隐伏断层,造成铜金矿体和地层错动。在TK02钻孔底部发育热液矿床前缘晕元素组合异常,指示深部可能存在隐伏矿体。综合研究认为,黄屯铜金矿床的成矿物质可能主要来源于火山热液和闪长玢岩,该矿床为火山-次火山热液型矿床。     

甘肃省合作市早子沟金矿原生晕三维特征及深部找矿预测

为了评价早子沟金矿深部找矿潜力和找矿方向,以早子沟金矿61个钻孔为研究对象,对矿体出露较厚大的70勘查线原生晕数据进行多元统计分析和三维空间分布特征研究。研究表明:(1)相关分析和聚类分析结果反映,与主成矿元素Au相关性最密切的元素为As、Ag;(2)原生晕的形态特征和空间分布特征显示,矿体原生晕发育,且分带明显,矿床的前缘晕元素为As、Sb、Hg,近矿晕元素为Au、Ag、Cu、Pb、Zn,尾晕元素为W、Mo、Bi;(3)对原生晕数据进行三维插值分析,构建了早子沟金矿各元素原生晕三维模型。Au、As、Sb、Ag等指示元素和As+Sb/Au+Ag元素异常累加比值的异常模型显示,在2500 m以浅,异常规模较小;在2500 m以深,异常规模呈现出向深部越来越大,且延伸稳定。结合异常元素的空间分布特征,提出早子沟金矿78～85勘查线2000 m以深仍有较大的找矿潜力。     

江西金山金矿床深部原生晕特征与成矿预测

对江西金山金矿床深部扩建工程的0、-80、-10 m三个中段Au等元素原生晕的空间分布特征及组合特征进行研究表明,矿床原生晕组合复杂,各指示元素原生晕吻合性好,As与Au关系密切,是金矿化的最佳指示元素; As、Hg、Sb前缘晕指示元素与Bi、Mo等尾晕指示元素相互叠加,且平均异常强度较高,预测矿体应向深部延伸出现第二个富集带,具有很大的工业远景;到-10m中段Au矿化减弱,Cu矿化增强,燕山早期岩浆热液的叠加改造作用明显,在深部可能出现Cu、Au叠加矿床.     

甘肃玛曲大水金矿构造叠加晕特征研究

为探讨甘肃大水金矿深部成矿潜力,在分析矿区成矿地质条件及矿床地质特征的基础上,对大水金矿Au2主矿体开展了构造叠加晕研究。地球化学统计分析表明,大水金矿矿床元素组合为Au、Ag、Hg、As、Sb、W,矿区Au、Sb、Ag、As、Hg、U等元素背景含量较高。矿体轴向特征研究显示,大水金矿床Au2主矿体原生晕轴向分带具有"前、尾晕共存"或"反分带"特征,表明大水金矿具有多期多阶段叠加成矿-成晕的特征。在矿体上部(标高3800m),前、尾晕形成叠加或共存,指示上部矿体已剥蚀;而在矿体尾部(标高3500m),Hg、Te、As、Sb等前缘晕元素又发育内、中带强异常,形成了前、尾晕叠加或共存,指示深部找矿前景较好。     

黄松甸子砂金矿床地质-地球化学找矿预测模型研究

本文详细地研究了吉林省珲春黄松甸子砂金矿床的成矿地质条件以及矿床地球化学、自然重砂异常特征,确定了Au、Cu、As、W、Bi、Mo等具有明显找矿意义的指示元素。同时根据矿床的成矿地质背景、控矿因素和地球化学、自然重砂指标,初步建立起矿床的地质-地球化学找矿预测模型。     

内蒙古锡林郭勒金成矿带物化探综合找矿方法研究

锡林郭勒金成矿带颇具找矿潜力,文章总结了成矿带的地球物理、地球化学特征,采用数理统计分析方法,确定了矿床元素轴向分带序列为:As-Sb-Hg-Bi-Li-Sr-Ba-Ag-Pb-Au-Cu-Zn-Sn-V-Co-Cr-Ni-Ti-Mo-W,前缘晕元素为As,Sb,Hg,Bi,主成矿元素为Au,Cu,Zn,尾晕元素为Ti,Mo,W.据轴向分带特征,确定金矿体剥蚀程度的判别指标为As×Sb×Bi/Ti×Mo×W.根据研究成果部署的深部钻探工程取得了较好的找矿效果.     

刘山岩铜锌矿床地球化学异常特征及找矿评价标志

在河南省桐柏县刘山岩铜锌多金属矿区开展深部及外围预查,对矿床进行了地球化学异常特征及评价标志研究.矿床的异常元素组合主要为Cu、Zn、Pb、Ag、Ba、Mo、Cd;次为Mn、Bi、As、Ga、Ge、V、W;矿床实用元素轴向分带序列由上至下依次为Cu-Zn-As-Ga-Ag-Pb-Mo.同时,根据已知矿和非矿异常特征、元素组合及分带特征、元素比值特征等建立了矿床的找矿评价地球化学标志.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).