Rb–Sr Dating of Gold‐Bearing Pyrite in the Jinchang Porphyry Cu–Au Deposit,Heilongjiang Province,NE China

The Jinchang Cu–Au deposit in Heilongjiang Province, NE China, is located in the easternmost part of the Central Asian Orogenic Belt. Rb–Sr analyses of auriferous pyrite from the deposit yielded an isochron age of 113.7 ±2.5 Ma, consistent with previously reported Re–Os ages. Both sets of ages represent the timing of Cu–Au mineralization because (i) the pyrite was separated from quartz–sulfide veins of the mineralization stage in granite porphyry; (ii) fluid inclusions have relatively high Rb, Sr, and Os content, allowing precise measurement; (iii) there are no other mineral inclusions or secondary fluids in pyrite to disturb the Rb–Sr or Re–Os decay systems; and (iv) the closure temperatures of the two decay systems are ≥500°C (compared with the homogenization temperatures of fluid inclusions of 230–510°C). It is proposed that ore‐forming components were derived from mantle–crust mixing, with ore‐forming fluids being mainly exsolved from magmas with minor amounts of meteoric water. The age of mineralization at Jinchang and in the adjacent regions, combined with the tectonic evolution of the northeast China epicontinental region, indicates that the formation of the Jinchang porphyry Cu–Au deposit was associated with Early Cretaceous subduction of the paleo‐Pacific Plate.     

Genesis of Pb–Zn Mineralization Beneath the Xiangshan Uranium Orefield,South China: Constraints from H–O–S–Pb Isotopes and Rb–Sr Dating

The volcanic‐hosted Xiangshan uranium orefield is the largest uranium deposit in South China. Recent exploration has discovered extensive Pb–Zn mineralization beneath the uranium orebodies. Detailed geological investigation reveals that the major metallic minerals include pyrite, sphalerite, galena, and chalcopyrite, whilst the major non‐metallic minerals include quartz, sericite, and calcite. New δ¹⁸O_fluid and δD_fluid data indicate that the ore‐forming fluids were mainly derived from magmatic, and the sulfide δ³⁴S values (2.2–6.9‰) suggest a dominantly magmatic sulfur source. The Pb isotope compositions are homogeneous (²⁰⁶Pb/²⁰⁴Pb = 18.120–18.233, ²⁰⁷Pb/²⁰⁴Pb = 15.575–15.698, and ²⁰⁸Pb/²⁰⁴Pb = 37.047–38.446). The ⁸⁷Sr/⁸⁶Sr ratios of sulfide minerals range from 0.7197 to 0.7204, which is much higher than volcanic rocks and fall into the range of metamorphic basement. Lead and strontium isotopic compositions indicate that the metallogenic materials probably were derived from metamorphic basement. Pyrite Rb–Sr dating of the ores yielded 131.3 ± 4.0 Ma, indicating that the Pb–Zn mineralization occurred in the Early Cretaceous.     

辽东裂谷白云金矿载金黄铁矿Re-Os定年及其地质意义

白云金矿是辽东裂谷区内重要的大型金矿之一,长期以来缺少直接的年代学数据。本次对白云金矿不同矿石类型中的8件载金黄铁矿进行了Re-Os同位素定年,获得其等时线年龄为225.3±7.0 Ma(MSWD=5.8),187Os/188Os初始值为2.1±2.8。结合前人的研究成果及本次年代学研究得出:白云金矿形成于印支期,其成矿物质主要为壳源,白云金矿是与印支期岩浆活动有关的热液矿床;其形成构造背景可能为受蒙古–鄂霍次克大洋向南北两侧俯冲之后的陆内后碰撞造山环境。本次研究也为今后在辽东裂谷区寻找与印支期岩浆活动有关的矿床提供了依据。     

Re–Os Isotopic Age of the Hongqiling Cu–Ni Sulfide Deposit in Jilin Province,NE China and its Geological Significance

The Hongqiling Cu–Ni sulfide deposit in central Jilin Province is located in the eastern part of the Central Asian Orogenic Belt. Rhenium and osmium isotopes in sulfide minerals from the deposit are used to determine the timing of mineralization and the source of osmium, and ore metals. Sulfide ore samples have osmium and rhenium concentrations of 0.28–1.07 ppb and 2.39–13.17 ppb, respectively. Ten analyses yield an isochron age of 223 ± 9 Ma, indicating that the Cu–Ni sulfide deposit in the area formed in the Triassic. The initial ¹⁸⁷Os/¹⁸⁸Os ratio is around 0.295 ± 0.019 (MSWD = 1.14) and the δ³⁴S values of sulfide ores vary from ?1.50 to +3.00‰. These data indicate that the mineralizing materials were derived mainly from a mantle with some quantities of crustal components introduced into the rock‐forming and ore‐forming systems during mineralization and magmatic emplacement.     

新疆阿希金矿床黄铁矿标型特征及其地质意义

新疆阿希金矿床为西天山一典型的形成于晚古生代的与火山岩有关的大型浅成热液金矿床.电子显微探针微区成分分析结果显示,该矿床黄铁矿具有富砷贫硫的特点,w(Co)/w(Ni)比值主要介于1.79～4.61之间,反映出成矿流体以岩浆热液为主,而其比值在环带结构富砷黄铁矿核部(＞5)及环带(＜1)中的变化规律则进一步反映出成矿早...     

新疆西准噶尔提依尔金矿黄铁矿热电性与微量元素特征及其地质意义

黄铁矿是提依尔金矿主要的载金矿物,其标型特征的研究对深部找矿具有重要的指示意义。从矿物学和矿物地球化学角度系统研究黄铁矿热电性和微量元素组合特征,结果表明,黄铁矿导电类型以P-N混合型为主,P型黄铁矿出现率从浅部到深部有逐渐升高的趋势,结合各钻孔金品位垂向变化,可知P型黄铁矿出现率与金品位高值区呈正相关关系,且与矿体侧伏方向一致,预示矿体向深部有一定的延伸;成矿温度主要集中在100～330 ℃之间,属于中低温热液矿床;黄铁矿微量元素(As+Sb+Se+Te、Cu+Pb+Zn和Ti+Ni+Co+Cr)纵投影等值线图显示,250 m标高以下,0、1号勘探线之间往NW方向找矿潜力良好。获得的黄铁矿标型特征对于提依尔金矿床深部找矿具有重要指导意义。     

贵州贞丰烂泥沟卡林型金矿床含砷黄铁矿Re-Os同位素测年及地质意义

贵州贞丰烂泥沟金矿(现称锦丰金矿)是滇黔桂“金三角”已知最大的卡林型金矿床,矿体赋存于断层破碎带内,最主要的载金矿物是具环带结构的含砷黄铁矿。本文运用Re-Os同位素法对该矿床的9个含砷黄铁矿样品进行了两次测试,成功获得10-9～10-12级Re-Os同位素数据:Re0.1257～1.233ng/g,Os6.75～33.50pg/g,等时线年龄为193±13Ma,反映其成矿时代为早侏罗世。等时线的初始n(187Os)/n(188Os)值为1.127±0.043,指示成矿物质来源于地壳而不是地幔。结合其他资料,初步建立其成矿模式为:盆地流体不断地从沉积物中萃取出包括金在内的成矿组分,形成含矿流体。印支期挤压造山期间,含矿流体沿不整合接触面和同生断层向上运动,造山后的伸展含矿流体进入减压扩容空间沉淀形成超大型金矿床。成矿作用发生在从印支期挤压造山向燕山期伸展转变的构造转换期。该模式与本文得到的成矿年龄和初始比值相吻合。     

U–Pb and Re–Os Geochronology of the Tongcun Molybdenum Deposit and Zhilingtou Gold‐Silver Deposit in Zhejiang Province,Southeast China,and Its Geological Implications

Mesozoic ore deposits in Zhejiang Province, Southeast China, are divided into the northwestern and southeastern Zhejiang metallogenic belts along the Jiangshan–Shaoxing Fault. The metal ore deposits found in these belts are epithermal Au–Ag deposits, hydrothermal‐vein Ag–Pb–Zn deposits, porphyry–skarn Mo (Fe) deposits, and vein‐type Mo deposits. There is a close spatial–temporal relationship between the Mesozoic ore deposits and Mesozoic volcanic–intrusive complexes. Zircon U–Pb dating of the ore‐related intrusive rocks and molybdenite Re–Os dating from two typical deposits (Tongcun Mo deposit and Zhilingtou Au–Ag deposit) in the two metallogenic belts show the early and late Yanshanian ages for mineralization. SIMS U–Pb data of zircons from the Tongcun Mo deposit and Zhilingtou Au–Ag deposit indicate that the host granitoids crystallized at 169.7 ± 9.7 Ma (2σ) and 113.6 ± 1 Ma (2σ), respectively. Re–Os analysis of six molybdenite samples from the Tongcun Mo deposit yields an isochron age of 163.9 ± 1.9 Ma (2σ). Re–Os analyses of five molybdenite samples from the porphyry Mo orebodies of the Zhilingtou Au‐Ag deposit yield an isochron age of 110.1 ± 1.8 Ma (2σ). Our results suggest that the metal mineralization in the Zhejiang Province, southeast China formed during at least two stages, i.e., Middle Jurassic and Early Cretaceous, coeval with the granitic magmatism.     

Timing of thermal stabilization of the Zimbabwe Craton deduced from high-precision Rb–Sr chronology, Great Dyke

Dating low temperature events such as magmatic cooling or (hydro-)thermal surges in Archean and Proterozoic terranes is crucial in defining cratonal thermal stabilization after episodic continental growth during the Archean and Early Proterozoic. Rubidium–Sr chronology is potentially a powerful tool in this regard because of its low closure temperature, i.e., <400 °C in most minerals, but has until now been hampered by its relatively low precision compared to high-temperature chronometers. Consequently, Rb–Sr age investigations have so far failed to provide high-precision age constraints on the cooling of rocks older than 2 Ga. Here, it is demonstrated that internal Rb–Sr microchrons can yield important, high-precision age constraints on the cooling history of Archean intrusions. After careful mineral selection and chemical treatment, a Rb–Sr age of 2543.0 ± 4.4 Ma was obtained from the Archean Great Dyke, Zimbabwe Craton, in contrast to the intrusion age of 2575.8 ± 1 Ma, yielding an ambient average cooling of 5 ± 2 °C/Ma. The non-disturbed magmatic Rb–Sr cooling age of the Great Dyke marks the final stage of Zimbabwe craton stabilization and that the greater craton area did not experience any intensive later reheating event during metamorphic or tectonic events.     

Geochronological framework and Pb, Sr isotope geochemistry of the Qingchengzi Pb–Zn–Ag–Au orefield, Northeastern China

The Qingchengzi orefield in northeastern China, is a concentration of several Pb–Zn, Ag, and Au ore deposits. A combination of geochronological and Pb, Sr isotopic investigations was conducted. Zircon SHRIMP U–Pb ages of 225.3 ± 1.8 Ma and 184.5 ± 1.6 Ma were obtained for the Xinling and Yaojiagou granites, respectively. By step-dissolution Rb–Sr dating, ages of 221 ± 12 Ma and 138.7 ± 4.1 Ma were obtained for the sphalerite of the Zhenzigou Zn–Pb deposit and pyrargyrite of the Ag ore in the Gaojiabaozi Ag deposit, respectively. Pb isotopic ratios of the Ag ore at Gaojiabaozi (²⁰⁶Pb/²⁰⁴Pb = 18.38 to 18.53) are higher than those of the Pb–Zn ores (²⁰⁶Pb/²⁰⁴Pb = 17.66 to 17.96; Chen et al. [Chen, J.F., Yu, G., Xue, C.J., Qian, H., He, J.F., Xing, Z., Zhang, X., 2005. Pb isotope geochemistry of lead, zinc, gold and silver deposit clustered region, Liaodong rift zone, northeastern China. Science in China Series D 48, 467–476.]). Triassic granites show low Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 17.12 to 17.41, ²⁰⁷Pb/²⁰⁴Pb = 15.47 to 15.54, ²⁰⁸Pb/²⁰⁴Pb = 37.51 to 37.89) and metamorphic rocks of the Liaohe Group have high ratios (²⁰⁶Pb/²⁰⁴Pb = 18.20 to 24.28 and 18.32 to 20.06, ²⁰⁷Pb/²⁰⁴Pb = 15.69 to 16.44 and 15.66 to 15.98, ²⁰⁸Pb/²⁰⁴Pb = 37.29 to 38.61 and 38.69 to 40.00 for the marble of the Dashiqiao Formation and schist of the Gaixian Formation, respectively).Magmatic activities at Qingchengzi and in adjacent regions took place in three stages, and each contained several magmatic pulses: ca. 220 to 225 Ma and 211 to 216 Ma in the Triassic; 179 to 185 Ma, 163 to 168 Ma, 155 Ma and 149 Ma in the Jurassic, as well as ca. 140 to 130 Ma in the Early Cretaceous. The Triassic magmatism was part of the Triassic magmatic belt along the northern margin of the North China Craton produced in a post-collisional extensional setting, and granites in it formed by crustal melting induced by mantle magma. The Jurassic and Early Cretaceous magmatism was related to the lithospheric delamination in eastern China. The Triassic is the most important metallogenic stage at Qingchengzi. The Pb–Zn deposits, the Pb–Zn–Ag ore at Gaojiabaozi, and the gold deposits were all formed in this stage. They are temporally and spatially associated with the Triassic magmatic activity. Mineralization is very weak in the Jurassic. Ag ore at Gaojiabaozi was formed in the Early Cretaceous, which is suggested by the young Rb–Sr isochron age, field relations, and significantly different Pb isotopic ratios between the Pb–Zn–Ag and Ag ores. Pb isotopic compositions of the Pb–Zn ores suggest binary mixing for the source of the deposits. The magmatic end-member is the Triassic granites and the other metamorphic rocks of the Liaohe Group. Slightly different proportions of the two end-members, or an involvement of materials from hidden Cretaceous granites with slightly different Pb isotopic ratios, is postulated to interpret the difference of Pb isotopic compositions between the Pb–Zn–(Ag) and Ag ores. Sr isotopic ratios support this conclusion. At the western part of the Qingchengzi orefield, hydrothermal fluid driven by the heat provided by the now exposed Triassic granites deposited ore-forming materials in the low and middle horizons of the marbles of the Dashiqiao Formation near the intrusions to form mesothermal Zn–Pb deposits. In the eastern part, hydrothermal fluids associated with deep, hidden Triassic intrusions moved upward along a regional fault over a long distance and then deposited the ore-forming materials to form epithermal Au and Pb–Zn–Ag ores. Young magmatic activities are all represented by dykes across the entire orefield, suggesting that the corresponding main intrusion bodies are situated in the deep part of the crust. Among these, only intrusions with age of ca. 140 Ma might have released sufficient amounts of fluid to be responsible for the formation of the Ag ore at Gaojiabaozi.Our age results support previous conclusions that sphalerite can provide a reliable Rb–Sr age as long as the fluid inclusion phase is effectively separated from the “sulfide” phase. Our work suggests that the separation can be achieved by a step-resolution technique. Moreover, we suggest that pyrargyrite is a promising mineral for Rb–Sr isochron dating.     

Age and Tectonic Setting of Mesothermal Magmatic Hydrothermal Vein‐Type Pb–Zn–(Ag) Mineralization in the Xiaohongshilazi Deposit,Central Jilin Province,Northeast China

The Xiaohongshilazi deposit located in central Jilin Province, Northeast China, is a newly discovered and medium‐scale Pb–Zn–(Ag) deposit with ore reserves of 34,968 t Pb, 100,150 t Zn, and 158 t Ag. Two‐stage mineralization has been identified in this deposit. Stratiform volcanic‐associated massive sulfide (VMS) Pb–Zn mineralization interbedding with the marine volcanic rocks of the Late Carboniferous–Early Permian Daheshen Formation was controlled by the premineralization E–W‐trending faults. Vein‐type Pb–Zn–(Ag) mineralization occurs within or parallel to the granodiorite and diorite porphyries controlled by the major‐mineralization N–S‐trending faults that cut the stratiform mineralization and volcanic rocks. To constrain the age of vein‐type Pb–Zn–(Ag) mineralization and determine the relationship between mineralization and magmatism, we conducted LA–ICP–MS U–Pb dating on zircon from the ore‐bearing granodiorite and diorite porphyries and Rb–Sr dating on metal sulfide. Granodiorite and diorite porphyries yield zircon U–Pb weighted‐mean ²⁰⁶Pb/²³⁸U ages of 203.6 ± 1.8 Ma (Mean Standard Weighted Deviation [MSWD] = 1.8) and 225.6 ± 5.1 Ma (MSWD = 2.3), respectively. Sulfides from four vein‐type ore samples yield a Rb–Sr isochron age of 195 ± 17 Ma (MSWD = 4.0). These results indicate a temporal relationship between the granodiorite porphyry and vein‐type Pb–Zn–(Ag) mineralization. The granodiorite associated with vein‐type mineralization has high SiO₂ (68.99–70.49 wt.%) and Na₂O (3.9–4.2 wt.%; Na₂O/K₂O = 1.07–1.10) concentrations, and A/CNK values of 0.95–1.04; consequently, the intrusion is classified as a high‐K, calc‐alkaline, metaluminous I‐type granite. The granodiorite porphyry is enriched in large‐ion lithophile elements (e.g. Rb, Th, U, and K) and light REE and is depleted in high‐field‐strength elements (e.g. Nb, Ta, P, and Ti) and heavy REE, indicating that it represents a subduction‐related rock that formed at an active continental margin. Furthermore, the granodiorite porphyry has Mg# values of 31–34, indicating a lower crustal source. Based on petrological and geochemical features, we infer that the ore‐bearing granodiorite porphyry was derived from the partial melting of the lower crust. In summary, mineralization characteristics, cross‐cutting relationships, geochronological data, and regional tectonic evolution indicate that the region was the site of VMS Pb–Zn mineralization that produced stratiform orebodies within the Late Carboniferous–Early Permian marine volcanic rocks of the Daheshen Formation, followed by mesothermal magmatic hydrothermal vein‐type Pb–Zn–(Ag) mineralization associated with granodiorite porphyry induced by the initial subduction of the Paleo‐Pacific Plate beneath the Eurasia Plate during the Late Triassic–Early Jurassic.     

甘肃马坞金矿床8号矿体黄铁矿热电性特征及其地质意义

位于西秦岭岷(县)-礼(县)成矿带西段的马坞金矿床,是近年发现的一个中型微细浸染型金矿床。系统地研究了该矿床8号矿体黄铁矿的热电性标型特征,结果表明：8号矿体的黄铁矿热电导型以N型为主,总含量达到71.2%;成矿温度主要集中于200~300 ℃,属于中温矿床;黄铁矿热电导型及热电性参数特征反映出矿体被剥蚀到中部偏下的位置,向深部仍有一定规模的延伸;P型黄铁矿出现的频率从浅部到深部呈减小、增大再减小的趋势;金品位的高值区域、P型黄铁矿热电系数平均值的高值区域与热电系数离散度的高值区域三者相互对应。     

Geochronological challenges posed by continuously developing tectonometamorphic systems: insights from Rb–Sr mica ages from the Cycladic Blueschist Belt,Syros (Greece)

Is metamorphism and its causative tectonics best viewed as a series of punctuated events or as a continuum? This question is addressed through examination of the timing of exhumation of the Cycladic Blueschist Belt (CBB). The cause of scatter beyond analytical error in Rb–Sr geochronology was investigated using a suite of 39 phengite samples. Rb–Sr ages have been measured on phengite microsamples drilled from specific microstructures in thin sections of calcschists and metabasites from the CBB on Syros. The majority are from samples that have well‐preserved blueschist facies mineral assemblages with limited greenschist facies overprint. The peak metamorphic temperatures involved are below the closure temperature for white mica so that crystallization ages are expected to be preserved. This is supported by the coexistence of different ages in microstructures of different relative age; in one sample phengite from the dominant extensional blueschist facies fabric preserves an age of 35 Ma while post‐tectonic mica, millimetres away, has an age of 26 Ma. The results suggest that micro‐sampling techniques linked to detailed microstructural analysis are critical to understanding the timing and duration of deformation in tectonometamorphic systems. North of the Serpentinite Belt in northern Syros, phengite Rb–Sr ages are generally between 53 and 46 Ma, comparable to previous dates from this area. South of the Serpentinite Belt phengite in blueschist facies assemblages associated with extensional fabrics linked to exhumation have ages that range from 42 Ma down to c. 30 Ma indicating that extensional deformation while still under blueschist facies conditions continued until 30 Ma. No age measurements on samples with unambiguous evidence of deformation under greenschist facies conditions were made; two rocks with greenschist facies assemblages gave phengite ages that overlap with the younger blueschist samples, suggesting blueschist facies phengite is preserved in these rocks. Two samples yielded ages below 27 Ma; one is from a post‐tectonic microstructure, the other from a greenschist in which the fabric developed during earlier blueschist facies conditions. These ages are consistent with previous evidence of greenschist facies conditions from c. 25 Ma onwards. The data are consistent with a model of deformation that is continuous on a regional scale.     

黑龙江争光金矿床方铅矿黄铁矿Rb-Sr年龄及地质意义

争光金矿床位于兴安地块东缘黑龙江省多宝山铜钼-金矿集区南东端,矿体产于早奥陶世闪长岩与下奥陶统多宝山组地层接触带及多宝山组中,为大型金矿.因缺乏精确的成矿年代学研究,其成矿时代一直存在争议.本文在争光金矿床地质背景和岩石矿物学研究的基础上,对矿区内12件矿石样品中共生矿物方铅矿和黄铁矿进行Rb-Sr同位素年代学研究.结...     

烃气测量法在黑龙江乌拉嘎金矿区找矿预测评价中的应用

乌拉嘎金矿是一个大型金矿床,随着生产对探明储量的不断消耗,保有资源已近枯竭,在矿床深部及周边寻找新的隐伏矿体已刻不容缓。然而,由于该矿床形成后,其上覆盖了一层第三系的凝灰岩,以至于在地表使用常规的地球化学方法找矿效果很差。基于烃类气体具有挥发性强、运移距离远、能穿透深厚的盖层、反映深度大,并可在地表形成异常场等特点,我们将烃气测量技术应用于该地区的找矿预测。本文在分析该区烃类气体的背景特征的基础上,通过分析该区烃类组分在空间上与已知矿体之间的对应关系,异常的分带序列,测区异常的展布特征和时空结构,并结合地质和构造特征,对区内的成矿潜力进行了评价,圈定了相关找矿有利靶区。     

U-Pb SHRIMP Dating of Zircon from Quartz Veins of the Yangshan Gold Deposit in Gansu Province and Its Geological Significance

The Yangshan gold deposit is a super-large fine-grained disseminated gold deposit located in southern Gansu Province. Its metallogenic age has been determined by using the cathodoluminescence image and ion probe U-Pb dating techniques. It is found that zircons from quartz veinlet of the fine-grained disseminated gold ore show characters of magmatic origin with prism idiomorphism, oscillatory zoning and dominant Th/U ratios of 0.5-1.5. Three main populations of zircons are obtained, giving average 206Pb/238U ages of 197.6±1.7 Ma, 126.9±3.2 Ma and 51.2±1.3 Ma respectively. The first age corresponds to the K-Ar age of the plagiogranite dike, while the latter two ages indicate that buried Cretaceous and Tertiary intrusives exist in the orefield, suggesting that the Yangshan gold deposit was genetically related to the three magmatic hydrothermal activities. By contrast, zircons from coarse gold-bearing quartz vein in the mining area are much older than the host rock, indicating that the vein was formed ear     

黑龙江省乌拉嘎金矿赋矿花岗闪长斑岩锆石 U-Pb年龄、岩石成因及其地质意义

黑龙江省是我国著名金矿产区之一,发育多个浅成低温热液型金矿,它们与中生代陆相火山-次火山岩有密切的关系,但对这些陆相火山-次火山岩的成因缺乏系统研究,制约了本区金矿的成因认识和矿床勘查。本次研究采用先进的LA-ICP-MS锆石定年法、地球化学Sr-Nd-Pb同位素示踪等方法,对与乌拉嘎浅成低温热液金矿存在密切成因联系的次火山岩(花岗闪长斑岩)进行深入研究。LA-ICP-MS锆石定年法获得乌拉嘎矿区葡萄沟岩体及其南部含矿岩枝的成岩年龄分别为108.2±1.2Ma和106±1.1Ma,与区内宁远村组火山岩成岩时间基本相近,推断金矿成矿时代为早白垩世晚期,与东安金矿和高松山金矿为同期。岩石地球化学确定该岩体为高钾钙碱性(σ=1.83~2.18)偏铝质I型花岗岩特征,结合微量元素和Sr-Nd-Pb研究显示其具有活动陆缘弧岩浆岩特点,进一步得出岩浆源区和成矿物质具有来源于新元古代形成的镁铁质下地壳的部分熔融的属性。早白垩世时,中国东部处于伸展应力体制下,尤其黑龙江构造活动强烈,起源于新生下地壳重融的岩浆活动频繁,结合已有的浅成低温热液金矿床资料显示,推断区内具有巨大的成矿潜力。     

Zircon U–Pb and Wolframite Sm–Nd Dating of the Bayinsukhtu Tungsten Deposit in Southern Mongolia and its Geological Significance

The Bayinsukhtu tungsten deposit is a newly discovered quartz‐vein tungsten deposit in the Xing'an–Mongolia Orogenic Belt (XMOB) in southern Mongolia, hosted by the Bayinsukhtu granite porphyry. The granite porphyry is located mainly south of the study area, over 3 km². The rock consists of quartz and feldspar phenocrysts in a fine‐grained matrix, also mainly composed of feldspar and quartz. The granite porphyry samples demonstrate high SiO₂ and high alkalinity. All samples also straddle the high‐potassium calc‐alkaline series. In a plot of the molar ratios of A/NK versus A/CNK, the granites are metaluminous. The chondrite‐normalized REE patterns are characterized by large negative Eu anomalies and fractionated LREEs. The U–Pb age of zircons from the granite porphyry is 298.8 ± 1.8 Ma, and the Sm–Nd age of the five wolframite samples from the tungsten deposit is 303 ± 19 Ma. The cooling age of the granite porphyry and tungsten mineralization is within the error of measurement and is of the Late Carboniferous age. Geological and geochronological evidence shows that the tungsten mineralization and the granite porphyry at Bayinsukhtu are genetically closely related and that they are results of Carboniferous magmatism. Their tectonic setting is related to the accretion of the Central Asian Orogenic Belt during the late Paleozoic era.     

桂西北世加金矿黄铁矿微量元素地球化学研究

通过光学显微镜、电子探针显微分析等方法对桂西北世加金矿床矿石中的黄铁矿微量元素地球化学特征进行研究,黄铁矿中Co/Ni比值主要集中在1～10之间,表明矿石中的黄铁矿主要为热液成因,环带状黄铁矿核部的成因复杂,既有热液成因,又有受热液蚀变交代的沉积成因。黄铁矿中的Au有两种存在形式,一种以化学结合态Au(Au+)即固溶体形式存在,另一种以机械混入的纳米颗粒金形式存在于含砷黄铁矿边缘或早期黄铁矿的溶蚀孔洞中。结合矿床地质特征、黄铁矿微量元素特征以及矿床稀土元素特征,认为世加金矿床的成矿与围岩地层和辉绿岩在成矿物质来源等方面具有密切联系。     

蒙古国博洛大型金矿区花岗岩SHRIMP锆石U-Pb测年及地质意义

本文首次对博洛金矿床容矿围岩-博洛黑云母花岗岩进行锆石SHRIMP U-Pb年龄测定,获得两组年龄441.9±6.6 Ma和452.2±3.9 Ma,表明博洛花岗杂岩体应属于早古生代晚期岩浆活动的产物.其主量元素特征表现为高硅(SiO2=75.90×10-2~76.43×10-2)、富钾(K2O/Na2O=1.52~1.72)、富碱((K2O+Na2O)=8.03×10-2~8.22×10-2,碱度率AR=3.99~4.13)、低钙(CaO=0.77×10-2~0.97×10-2)、弱过铝质(A/CNK=1.02~1.05)的特点;稀土元素∑REE=(160.56~91.28)×10-6,δEu=0.19~0.41,稀土元素分布型式为具有明显负铕异常燕型曲线.微量元素除P、Ti相对原始地幔略有亏损外,其它微量元素都表现出不同程度富集,蛛网图曲线总体为右倾的趋势.(87Sr/86Sr)i=0.70986~0.70891,说明其岩浆来源应主要是壳源,但受到幔源物质的混染;(143Nd/144Nd)i=0.512138~0.512115,平均0.512127,εNd(t)变化在+1.4~+1.2,平均+1.3,为正值,具有幔源的特点.这些特征表明博洛黑云母花岗岩为壳幔相互作用的产物,并有新生地幔物质加入,产于造山后环境.博洛金矿床的形成时代为早侏罗世,博洛花岗杂岩仅仅为金矿床的容矿围岩,为矿床提供容矿空间,与金矿床成因关系不密切.