Cyanide and isocyanide abundances in the cold, dark cloud TMC-1

We have observed emission from HCN, H13CN, HC15N, HN13C, H15NC, HC3N, CH3CN, and possibly CH3NC, and determined an upper limit for NH2CN, toward the cold, dark cloud TMC-1. The abundance ratio [HNC]/[HCN] = 1.55 +/- 0.16 is at least a factor approximately 4 and approximately 100 greater than that observed toward the giant molecular clouds DR 21(OH) and Orion KL, respectively. In contrast, for the corresponding methylated isomers we obtain [CH3NC]/CH3CN] < or approximately 0.1. We also find [NH2CN]/[CH3CN] < or approximately 0.1 and [HC3N]/[CH3CN] = 30 +/- 10. We find no evidence for anomalous hyperfine ratios for H13CN, indicating that the ratios for HCN (cf. recent work of Walmsley et al.) are the result of self-absorption by cold foreground gas.     

The HNC/HCN Ratio in Comets

The abundance ratio of the isomers HCN and HNC has been investigated in comet Hale-Bopp (C/1995 O1) through observations of the J = 4−3 rotational transitions of both species for heliocentric distances 0.93 < r < 3 AU, both pre- and post-perihelion. After correcting for the optical depth of the stronger HCN line, we find that the column density ratio of HNC/HCN in our telescope beam increases significantly as the comet approaches the Sun. We compare this behavior to that predicted from an ion-molecule chemical model and conclude that the HNC is produced insignificant measure by chemical processes in the coma; i.e., for comet Hale-Bopp, HNC is not a parent molecule sublimating from the nucleus. This revised version was published online in July 2006 with corrections to the Cover Date.     

Morphology of HCN and CN in Comet Hale-Bopp (1995 O1)

We compare images of Comet Hale-Bopp (1995 O1) in HCN and CN taken near perihelion (April 1, 1997) to determine the origin of CN in comets. We imaged the J=1→0 transition of HCN at λ=3 mm with the BIMA Array. Data from two weeks around perihelion were summed within four phase bins based on the rotational period of the comet. This increases both the signal-to-noise ratio and the u-v coverage while decreasing the smearing of the spatial features. The similarly phased narrowband CN images were taken at Lowell Observatory within the same range of dates as the HCN images. We find that there is a better correlation between HCN and CN than between HCN and the optically dominant dust. If the CN in jets does have a dust source it would have to have a very low albedo and/or small particle size. The production rates are consistent with HCN being a primary parent of CN, although there are discrepancies between the HCN destruction scalelength and the CN production scalelength which we discuss.     

A Molecular Survey of Comet C/1995 O1 (Hale-Bopp) at the IRAM Telescopes

Spectroscopic observations of comet Hale-Boppwere undertaken near perihelion at millimetre wavelengths with the Institut de Radioastronomie Millimétrique (IRAM) telescopes at Plateau de Bure (France)and Pico Veleta (Spain). They resulted in the first detections of HCOOH,SO₂, NH₂CHO and HCOOCH₃ in a comet. HDO was detected through its3₁₂–2₂₁ line at 225.897 GHz,complementing the observation of the 1₀₁–0₀₀ line at 464.925 GHz at the James Clerk Maxwell Telescope (Meier et al., 1998,Science 279, 842).Several unidentified lines are present in the spectra. Observations of HC₃N, HNCO, OCS, SO, CN, CO₊, HCO₊, in addition to more ‘classical’species CO, HCN, HNC, CH₃CN, CH₃OH, H₂CO, CS and H₂S (Biveret al., this issue) permit us to make out an extensive inventory of the composition of the coma of comet Hale-Bopp at its perihelion. It presents strong analogies with gas-phase abundances measured in interstellar hot cores and bipolar flows, which are believed to reflect the composition of interstellar grains. This revised version was published online in July 2006 with corrections to the Cover Date.     

Long-term Evolution of the Outgassing of Comet Hale-Bopp From Radio Observations

C/1995 O1 (Hale-Bopp) has been observed on a regular basis since August 1995 at millimetre and submillimetre wavelengths using IRAM, JCMT, CSO and SEST radio telescopes. The production rates of eight molecular species (CO, HCN, CH₃OH, H₂CO,H₂S, CS, CH₃CN,HNC) have been monitored as a function of heliocentric distance(r_h from 7 AU pre-perihelion to 4 AU post-perihelion. As comet Hale-Bopp approached and receded from the Sun, these species displayed different behaviours. Far from the Sun, the most volatile species were found in general relatively more abundant in the coma. In comparison to other species, HNC, H₂CO and CS showed a much steeper increase of the production rate with decreasing r_h. Less than 1.5 AU from the Sun, the relative abundances were fairly stable and approached those found in other comets near 1 AU. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about10 K at 7 AU to 110 K around perihelion. The expansion velocity of the gaseous species, derived from the line shapes, also increased with a law close tor_h ³. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Search for Variability in the HCCN to H2CO Ratio in Comet Hale-Bopp

We observed submillimeter lines of H₂CO and HCN in comet Hale-Bopp near perihelion. One of our goals was to search for short term variability. Our observations are suggestive, but not conclusive, of temporal and/or spatial changes in the coma's HCN/H₂CO abundance ratio of ～25%. If due to spatial variability, the ratio on the sunward side of the coma is enhanced over other regions. If due to temporal variability, we find the bulk ratio in the coma changed in less than 16 hours.     

A Search for Variability in the HCCN to H2CO Ratio in Comet Hale-Bopp

We observed submillimeter lines of H₂CO and HCN in comet Hale-Bopp near perihelion. One of our goals was to search for short term variability. Our observations are suggestive, but not conclusive, of temporal and/or spatial changes in the coma's HCN/H₂CO abundance ratio of ∼25%. If due to spatial variability, the ratio on the sunward side of the coma is enhanced over other regions. If due to temporal variability, we find the bulk ratio in the coma changed in less than 16 hours. This revised version was published online in July 2006 with corrections to the Cover Date.     

Gaseous Jets in Comet Hale-Bopp (1995 O1)

We report the identification of gas jets in comet Hale-Bopp in OH, NH, CN, C₂ and C₃. This is the first time OH and NH jets without an obvious optical dust jet counterpart have been identified in narrowband comet images. We also confirm the existence of CN jets as reported by Larson et al. (1997) and Mueller et al. (1998). Jet features can be seen in the March and April 1997 datasets, approximately a month before and after perihelion. Our results contribute to the understanding of both the chemical properties of the comet as well as the physical mechanisms necessary to produce these features. This revised version was published online in July 2006 with corrections to the Cover Date.     

New Molecular Species in Comet C/1995 O1 (Hale-Bopp) Observed with the Caltech Ssubmillimeter Observatory

We present millimeter-wave observations of HNCO, HC₃N, SO, NH₂CHO, H¹³CN, and H₃O⁺ in comet C/1995 O1 (Hale-Bopp)obtained in February–April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H₂O is (4-13) × 10^-4. HC₃N, SO, and NH₂CHO are detected for the first time in a comet. The fractional abundance of HC₃N based on observations of three rotational lines is (1.9 ± 0.2) × 10^-4. Four transitions of SO are detected and the derived fractional abundance, (2-8) ×10^-3, is higher than the upper limits derived from UV observations of previous comets. Observations of NH₂CHO imply a fractional abundance of (1-8) × 10^-4. H₃O is detected for the first time from the ground. The H¹³CN (3-2)transition is also detected and the derived HCN/H¹³CN abundance ratio is 90 ± 15, consistent with the terrestrial¹²C/¹³C ratio. In addition, a number of other molecular species are detected, including HNC, OCS, HCO⁺, CO⁺, and CN(the last two are first detections in a comet at radio wavelengths). This revised version was published online in July 2006 with corrections to the Cover Date.     

Evidences for extended sources and temporal modulations in molecular observations of C/1995 O1 (Hale-Bopp) at the IRAM interferometer

Comet C/1995 O1 (Hale-Bopp) has been observed on October 5 and 25, 1996 and from March 6 to March 22, 1997 with the Institut de Radioastronomie Millimétrique (IRAM) interferometer at Plateau de Bure (France). Millimetre lines of HCN,HNC, CO, H₂CO, CH₃OH, H₂S, CS and SO were mapped with spatial resolutions of 1.5–3.5 arc sec. These observations allow us to investigate whether these species are released by the nucleus or produced in the coma by extended sources or photo-processes. The brightness distribution of the HCN J (1-0) line is consistent with release from the nucleus. The HNC J (1-0) distribution deviates from that of HCN in the innermost coma, and indicates production of HNC in the coma. This is in agreement with the heliocentric variation of the HNC/HCN ratio (Biver et al., 1997, Science 275, 1915; Irvine et al., 1998, this issue) and formation by chemical reactions (Rodgers and Charnley, 1998, Ap. J. 501, L227; Irvine et al., 1998, Nature 393, 547). There is clear evidence that SO is a photo dissociation product. The observations also confirm that H₂CO is mainly produced by an extended source, as first evidenced in comet P/Halley. The contribution of the nucleus to the total H₂CO production rate does not exceed 6%. The molecular lines have also been monitored hourly with the five antennas of the interferometer in single-dish mode. The line velocity shifts show aperiodic modulation linked to the nucleus rotation. The amplitude of the modulation differs from one species to another. The periodic modulation seen for the CO J (2-1) line on March 11 suggests that a significant fraction of CO is released continuously night and day by an active source situated at equatorial latitudes on the nucleus surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

SiS in Orion-KL: evidence for "outflow" chemistry

SiS has been conclusively detected toward Orion-KL via its J = 6-5 and J = 5-4 rotational transitions at 91 and 109 GHz. Line profiles indicate that the species is present at an LSR velocity of 7.5 km s-1 with a half-width at zero power of 36 km s-1. Such characteristics associate SiS with the moderate velocity outflow (V approximately 18 km s-1) centered on IRc2 and observed in thermal SiO, the NH3 "plateau," and OH, H2O, and SiO masers. The column density estimated for SiS in this region is Ntot = 4 x 10(15) cm-2, corresponding to a fractional abundance of f approximately 4 x 10(-9). Such an abundance implies an SiO/SiS ratio of approximately 60 in the outflow material, remarkably close to the cosmic O/S ratio of approximately 40 and contrasting with the SiO/SiS value of > approximately 10(3) predicted by ion-molecule models. This difference is probably a result of the high temperatures and densities present in the outflow, which favor thermal equilibrium abundances similar to those observed in the circumstellar shells of late-type stars rather than "ion-molecule"-type concentrations. In addition to SiS, some twenty new unidentified lines near 91 and 109 GHz were detected toward KL, as well as transitions arising from HC5N, HC13CCN, HCC13CN, O13CS, and, possibly, CH3CH2OH, CH3CHO, and CH3OD.     

Estimating the Size of Hale-Bopp's Nucleus

A variety of independent methods have been used to estimate the size of the nucleus of comet Hale-Bopp. Several groups have analyzed optical and infrared images of the comet and claim to detect the signature of the nucleus, despite the presence of a strong coma. A detection of the nucleus was also claimed during mm- and cm-wave observations of Hale-Bopp shortly before perihelion. A team of observers detected the occultation of a star by the nucleus of Hale-Bopp in October 1996. The maximum observed gas production rate of the comet near perihelion can be used to place a lower limit on the size of the nucleus. This paper critically reviews the many different methods used to constrain the size of Hale-Bopp's nucleus. All of the techniques are affected by systematic errors that can be difficult to quantify precisely. Nevertheless, the available evidence strongly suggests that the nucleus of Hale-Bopp has an effective radius of at least 15 km and is probably in the range 20–35 km. Thus, the prodigious gas and production rates from this comet are naturally explained by its unusually large size. This revised version was published online in July 2006 with corrections to the Cover Date.     

Observations of High Resolution Spectra of Comet Hale-Bopp (C/1995 O1) at the SAO of the RAS

We present the results of the preliminary study of the comet Hale-Bopp spectrum obtained April 17, 1997 by K. Churyumov and F. Mussayev with the help of the 1-meter Zeiss reflector and the echelle spectrometer (spectral resolutionλ/Δ λ ≈ 50000), CCD and the long slit, oriented along the radius-vector(“Sun-comet direction”). Energy distributions for three selected regions including the C₃, C₂ (0-0) and CN(Δ ν = 0) molecules emissions of the comet Hale-Bopp spectrum were built. The rotational lines of the CN(Δ ν = 0) band were identified. The nature of the high emission peak near λ 4020 Å in the C₃ band is discussed. The presence of the cometary continuum of the nonsolar origin is assumed.     

Observations of the inner coma of C/1995O1 (Hale-Bopp)—gas and dust production

Hale-Bopp (C/1995 O1) was the most productive recent comet observed in terms of gas and dust output. Since its discovery in 1995 at a distance of 7.14 AU from the Sun, the comet has been well observed, revealing the dynamics of a rare and large comet. Hale-Bopp showed strong emissions of the principle cometary gases CN, C₃, and C₂, as well as an abundance of dust. The production rates of these gases were found to be 1.45×10²⁸, 1.71×10²⁸, and , respectively, with dust production, in terms of Afρ, , as measured in the green continuum (5260 Å). The observations for this paper are presented in two groups spanning 10 days each, one group centered near 32 days prior to and the other 21 days after perihelion. The averages of dust and gas production rates show a slightly higher value for each prior to perihelion than after perihelion, consistent with a possible peak in production a few weeks prior to perihelion passage.     

Narrow-Band Photometry of Comet C/1995 O1 (Hale-Bopp)

Photometric observations of comet C/1995 O1 (Hale-Bopp) carried out at the Stará Lesná Observatory since February to April 1997 are analyzed and discussed. Emission band fluxes and continuum fluxes are presented, from which the total numbers of molecules in the columns of the coma encircled by diaphragms are calculated. The production rates are estimated from the conventional Haser model. We found that the photometric exponent of dust contribution two months prior perihelion was n = 5.2. The photometric exponent n of the cometary magnitude solely to the C₂ emission alone equals 3.3 and that of CN equals 2.5. These values can be explained by a fact that the maximums of production rates of the gases were reached between March 2and 12 and not at the perihelion as it is valid for dust. These results are compared with the values of 1P/Halley (1986 III) under the similar conditions, obtained with the same method and instrument. C/Hale-Bopp exhibited 4.1 times more molecules radiating the CN-emission than 1P/Halley in the same column of the coma. The continuum flux of C/Hale-Bopp was also very strong. The ratios (to 1P/Halley) are 94:1 (Cont. 484.5) and 74:1 (Cont. 365.0). The cometary colour was the same as that of the Sun. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spectrocam-10 Thermal Infrared Observations Of The Dust In Comet C/1995 O1 Hale-Bopp

We describe 5 to 18 μm broadband images and R ∼ 100 spectra of comet Hale-Bopp taken with SpectroCam-10 on the 5 m Hale telescope during six runs between 1996 June and 1997 April. Our data show the gradual warming of dust grains as the comet approached perihelion. In June, the 10 μm silicate emission feature was already stronger than observed in any other comet, and it increased to about 3 times the continuum level near perihelion. Spectral structure attributed to a crystalline olivine grain component remained relatively constant, but other features associated with pyroxenes appeared to vary with heliocentric distance. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spectroscopic Observations of Comet C/1996 B2 (Hyakutake) with the Caltech Submillimeter Observatory

The apparition of Comet C/1996 B2 (Hyakutake) offered an unexpected and rare opportunity to probe the inner atmosphere of a comet with high spatial resolution and to investigate with unprecedented sensitivity its chemical composition. We present observations of over 30 submillimeter transitions of HCN, H¹³CN, HNC, HNCO, CO, CH₃OH, and H₂CO in Comet Hyakutake carried out between 1996 March 18 and April 9 at the Caltech Submillimeter Observatory. Detections of the H¹³CN (4–3) and HNCO (16_0,16–15_0,15) transitions represent the first observations of these species in a comet. In addition, several other transitions, including HCN (8–7), CO (4–3), and CO (6–5) are detected for the first time in a comet as is the hyperfine structure of the HCN (4–3) line. The observed intensities of the HCN (4–3) hyperfine components indicate a line center optical depth of 0.9 ± 0.2 on March 22.5 UT. The HCN/HNC abundance ratio in Comet Hyakutake at a heliocentric distance of 1 AU is similar to that measured in the Orion extended ridge— a warm, quiescent molecular cloud. The HCN/H¹³CN abundance ratio implied by our observations is 34 ± 12, similar to that measured in giant molecular clouds in the galactic disk but significantly lower than the Solar System¹²C/¹³C ratio. The low HCN/H¹³CN abundance ratio may be in part due to contamination by an SO₂line blended with the H¹³CN (4–3) line. In addition, chemical models suggest that the HCN/H¹³CN ratio can be affected by fractionation during the collapse phase of the protosolar nebula; hence a low HCN/H¹³CN ratio observed in a comet is not inconsistent with the solar system¹²C/¹³C isotopic ratio. The abundance of HNCO relative to water derived from our observations is (7 ± 3) × 10⁻⁴. The HCN/HNCO abundance ratio is similar to that measured in the core of Sagittarius B2 molecular cloud. Although a photo-dissociative channel of HNCO leads to CO, the CO produced by HNCO is a negligible component of cometary atmospheres. Production rates of HCN, CO, H₂CO, and CH₃OH are presented. Inferred molecular abundances relative to water are typical of those measured in comets at 1 AU from the Sun. The exception is CO, for which we derive a large relative abundance of 30%. The evolution of the HCN production rate between March 20 and March 30 suggests that the increased activity of the comet was the cause of the fragmentation of the nucleus. The time evolution of the H₂CO emission suggests production of this species from dust grains.     

C/1995 O1 (Hale-Bopp): Gas Production Curves And Their Interpretation

The discovery of C/1995 O1 (Hale-Bopp) at 7 AU from the Sun provided the first opportunity to follow the activity of a bright comet over a large range of heliocentric distances r_h. Production rates of a number of parent molecules and daughter species have been monitored both pre- and postperihelion. CO was found to be the major driver of the activity far from the Sun, surpassed by water within 3 AU whose production rate reached 10³¹ s⁻¹ at perihelion. Gas production curves obtained for various species show several behaviours with r_h. Gas production curves contain important information concerning the physical state of cometary ices, the structure of the nucleus and all the processes taking place inside the nucleus leading to outgassing. They are relevant to the study of several other phenomena such as the sublimation from icy grains, dust mantling or seasonal effects. For some species, such as H₂CO or HNC, they permit to constrain their origin in the coma. We discuss models of subsurface gas production in distant comets and predictions of how such a source may vary as the comet moves along its orbit, approaching perihelion and receding again. Features in the observed gas production curves of comet Hale-Bopp are generally interpretable in terms of either subsurface production (typical example: CO at large r_h) or free sublimation (typical example: H₂O). Possible implications for the vertical stratification of the cometary ices are reviewed, and preference is found for a model with crystallization of amorphous ice close to the nuclear surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Narrowband Electrophotometry of Comet Hale-Bopp (C/1995 O1) Near Perihelion

We present the results of narrowband photoelectric observations of comet Hale-Bopp near perihelion, which were made with the AZT-14telescope at the station Lisniki of Kyiv University Astronomical Observatory. The standard set of IHW cometary filters was used. The total number of cometary observations was more than 500 during the interval March 13–April 29, 1997. The comet's nuclear gas production rates Q of C₂ and C₃ were calculated using the stellar calibration for these filters. The calculations used the Haser model for a neutral cometary atmosphere. The value Afρ, which is characteristic of the dust production rate, was determined too. Mean values of the production rates near perihelion are log Q(C₂) = 28.4; log Q(C₃) = 27.2; (Afρ)_BC = 6.0. This revised version was published online in July 2006 with corrections to the Cover Date.     

Shock chemistry in the molecular clouds associated with SNR IC 443

Several interstellar molecules have been detected toward the highly perturbed B and G clouds associated with the supernova remnant IC 443 via their 3 mm transitions, including N2H+, SiO, SO, CN, HNC, and H13CO+. The (J, K) = (1, 1) and (2, 2) inversion lines of metastable ammonia have also been observed, as well as the J = 3-2 transition of HCO+ at 1.2 mm. Analysis of the (1, 1) and (2, 2) inversion lines of NH3 indicates minimum gas kinetic temperatures of TK = 70 K toward cloud B, and TK = 33 K in cloud G. Modeling of the J = 1-0 and J = 3-2 transitions of HCO+ implies densities greater than 10(5) cm-3 toward both positions. These data clearly show that hot and dense material is present in IC 443, and they suggest the presence of shocks in both regions. A careful analysis of the HCO+ lines indicates that the HCO+ abundance is at most enhanced by factors of a few over that found in cold, quiescent gas. This conclusion contradicts past claims of HCO+ abundance enhancements of several orders of magnitude in the perturbed regions. The N2H+ abundance was also found to be similar to that in cold gas, suggesting that there is no increase in ionization in the clouds. The abundances of SO and CS, as well as CN and NH3, do not appear to differ significantly from those found in cold dark clouds, although chemistry models predict sulfur-containing species to undergo high-temperature enhancements. SiO, however, is found to have an abundance in the perturbed gas 100 times larger than the upper limits observed in the dark cloud TMC 1, a result in agreement with high temperature chemistry models. In addition, the HNC/HCN ratio in both IC 443 B and G was found to be approximately 0.1--far from the ratio of 1 predicted by low-temperature ion-molecule chemistry, but similar to the values observed in clouds where elevated temperatures are present.