A Detailed Geochemical Study of Island Arc Crust: the Talkeetna Arc Section, South-Central Alaska

The Early to Middle Jurassic Talkeetna Arc section exposed inthe Chugach Mountains of south–central Alaska is 5–18km wide and extends for over 150 km. This accreted island arcincludes exposures of upper mantle to volcanic upper crust.The section comprises six lithological units, in order of decreasingdepth: (1) residual upper mantle harzburgite (with lesser proportionsof dunite); (2) pyroxenite; (3) basal gabbronorite; (4) lowercrustal gabbronorite; (5) mid-crustal plutonic rocks; (6) volcanicrocks. The pyroxenites overlie residual mantle peridotite, withsome interfingering of the two along the contact. The basalgabbronorite overlies pyroxenite, again with some interfingeringof the two units along their contact. Lower crustal gabbronorite(10 km thick) includes abundant rocks with well-developed modallayering. The mid-crustal plutonic rocks include a heterogeneousassemblage of gabbroic rocks, dioritic to tonalitic rocks (30–40%area), and concentrations of mafic dikes and chilled mafic inclusions.The volcanic rocks (7 km thick) range from basalt to rhyolite.Many of the evolved volcanic compositions are a result of fractionalcrystallization processes whose cumulate products are directlyobservable in the lower crustal gabbronorites. For example,Ti and Eu enrichments in lower crustal gabbronorites are mirroredby Ti and Eu depletions in evolved volcanic rocks. In addition,calculated parental liquids from ion microprobe analyses ofclinopyroxene in lower crustal gabbronorites indicate that theclinopyroxenes crystallized in equilibrium with liquids whosecompositions were the same as those of the volcanic rocks. Thecompositional variation of the main series of volcanic and chilledmafic rocks can be modeled through fractionation of observedphase compositions and phase proportions in lower crustal gabbronorite(i.e. cumulates). Primary, mantle-derived melts in the TalkeetnaArc underwent fractionation of pyroxenite at the base of thecrust. Our calculations suggest that more than 25 wt % of theprimary melts crystallized as pyroxenites at the base of thecrust. The discrepancy between the observed proportion of pyroxenites(less than 5% of the arc section) and the proportion requiredby crystal fractionation modeling (more than 25%) may be bestunderstood as the result of gravitational instability, withdense ultramafic cumulates, probably together with dense garnetgranulites, foundering into the underlying mantle during thetime when the Talkeetna Arc was magmatically active, or in theinitial phases of slow cooling (and sub-solidus garnet growth)immediately after the cessation of arc activity. KEY WORDS: island arc crust; layered gabbro; Alaska geology; island arc magmatism; lower crust     

江西宁都县北部大地热流特征及地热资源成因机制

江西省宁都县北部地区地热资源丰富,但地热地质研究程度较低,制约着区域地热资源的研究与可持续发展。在前人研究基础上,依托中国地质调查工作,对研究区大地热流特征及地热成因机制进行分析。基于钻孔测温与热导率测试数据,分析校正得到区域内大地热流平均值为93.6 mW/m2,远高于中国陆区平均值62.5 mW/m2,区域热背景值较高。通过放射性测试可知本区大面积出露的花岗岩与混合岩放射性生热率平均值为6.47 μW/m3,属高放射性岩体,岩石的放射性衰变产热应是本区大地热流值较高的重要原因,幔源供热的基础上附加壳源产热,提供了稳定的热源。在此基础上,穿越本区的2条深大断裂及其次生断裂则为地下热水深循环提供了传热与导水通道。因此推测,研究区地热资源成因机制为"高热流与高产热花岗岩体生热+多级次断裂控热导水"的成因模式,该模式代表性较强,可为赣南地区地热找矿提供指导。     

On meteotsunamis around Tsushima Strait generated by the Baiu front

On July 15, 2009, a meteotsunami occurred over Tsushima Strait and flood damage was recorded on the west coast of Tsushima Island. This study investigated the meteorological systems related to that meteotsunami event using surface observation data, grid-point value data, and a mesoscale meteorological model. The mid-latitude trough in the mid-troposphere approached the moist air of the Baiu precipitation system, and a cold downdraft occurred over a wide area of western Japan. In the western Tsushima Strait, the warm, moist air of the lower atmosphere kept the front of the cold downdraft stationary. Around this area, an atmospheric gravity wave was generated continuously with the wave-conditional instability of the second kind mechanism and propagated toward Tsushima Island. The atmospheric gravity wave generated a pressure disturbance at sea level, which produced the meteotsunami. The frequency of the pressure disturbance using the numerical model had a peak in the 5- to 20-min period range, which corresponded with the peak frequency range of the observed tidal records.     

三江地区义敦岛弧安山岩成因

义敦岛弧是一个发育于张性薄陆壳基底上的三叠纪岛弧,以发育岛弧裂谷和成对的火山弧为特征。弧火山岩主要为钙碱性火山岩系,以安山岩为主,其岩石组合为玄武岩—安山岩—英安岩。岩相学、地球化学、相平衡及定量模型计算均证实,分离结晶作用是产生钙碱性火山岩系的主导作用,安山岩是钙碱性玄武岩浆在不同压力条件下发生多阶段分离结晶的产物。岩浆演化具有相对封闭系统特征。玄武岩浆在较大压力条件下发生Ol+Cpx+Pl±Mt±Ap结晶(F=0.46)后,派生岩浆发生Hb+Cpx+Pl+Mt结晶分离(F=0.25),产生安山岩浆。该岩浆可能在较低压力下再次发生结晶分异,从而派生出英安岩。角闪石在相对较高的压力条件下的大量结晶是安山岩形成的主要原因。     

New paleomagnetic results from the northern margin of the Kohistan Island Arc

Different phases of remanent magnetizations have been identified in the Cretaceous–Tertiary rocks collected from the northern margin of the Kohistan Island Arc, northern Pakistan. Among them, a magnetite-related component is recognized as the most useful one because of its relatively stable behaviour and widespread presence in the volcanics and red beds. Calculation of mean direction for this component reveal two visible groupings in terms of paleomagnetic directions (Yasin + Baris Group: D?=?341.6º, I?=?10.6º, α ₉₅?=?23.3 º, k?=?11.7, N?=?5; Sandhi Group: D?=?28.4º, I?=??27.4º, α ₉₅?=?32.5 º, k?=?8.96, N?=?4). The fold tests applied to both these groups are inconclusive, indicating a syn-folding to post-folding origin for this component. A set of inclinations from this study provide new insight into post-collision northward displacement of the Kohistan Arc with respect to its surrounding terranes. Reliability of the paleomagnetic declinations from this study is not fully guaranteed, but when compared with previously reported paleomagnetic directions, a systematic increase in counter-clockwise deflections towards west has been detected along this paleo-island arc. This trend of declinations is well matched with the extrusion model of Asia, where counter-clockwise rotation has been suggested for the tectonic terranes around Western Himalaya. Another important observation is a divergence in paleomagnetic declinations across the rivers, which may indicate the presence of faulted zones under the cover of flowing water. This aspect can be compared to recent geological interpretations that Kohistan may not have acted as a rigid block following its collision with India but may have been deformed through localized shears and faults.     

Petrogenesis of the Late Cretaceous Tholeiitic Volcanism and Oceanic Island Arc Affinity of the Chagai Arc, Western Pakistan

The Late Cretaceous Chagai arc outcrops in western Pakistan, southern Afghanistan and eastern Iran. It is in the Tethyan convergence zone, formed by northward subduction of the Arabian oceanic plate beneath the Afghan block. The oldest unit of the Chagai arc is the Late Cretaceous Sinjrani Volcanic Group. This is composed of porphyritic lava flows and volcaniclastic rocks, and subordinate shale, sandstone, limestone and chert. The flows are fractionated low-K tholeiitic basalts, basaltic-andesites, and andesites. Relative enrichment in their LILE and depletion in HFSE, and negative Nb and Ta and positive K, Ba and Sr anomalies point to a subduction-related origin. Compared to MORB, the least fractionated Chagai basalts have low Na2O, Fe2O3T, CaO, Ti, Zr, Y and 87Sr/86Sr. Rather than an Andean setting, these results suggest derivation from a highly depleted mantle in an intraoceanic arc formed by Late Cretaceous convergence in the Ceno-Tethys. The segmented subduction zone formed between Gondwana and a collage of small continental blocks (Iran, Afghan, Karakoram, Lhasa and Burma) was accompanied by a chain of oceanic island arcs and suprasubduction ophiolites including Semail, Zagros, Chagai-Raskoh, Kandahar, Muslim Bagh, Waziristan and Kohistan-Ladakh, Nidar, Nagaland and Manipur. These complexes accreted to the southern margin of Eurasia in the Late Cretaceous.     

Continent — Island arc collision in the Banda Arc

Acoustical structure of seismic profiles, and morphology of the Timor—Tanimbar—Ceram troughs and adjacent slopes of the outer Banda Arc, show remarkable similarities to equivalent parameters of many arcs subducting oceanic lithosphere and sediments, despite the fact that the outer Banda Arc is underlain by continental crust continuous with that of the colliding Australian craton. Such similarities include diffractions and anticlinal folds at the toe of the inner slope of the Timor—Tanimbar—Ceram troughs, which could be interpreted as thrust slices and thrust folds. Slope basins comprising sediments obviously dammed behind acoustic basement highs are also common on the trough inner slope, with some basins containing strata adjacent to the highs dipping away from the trough. Ridges and basins occur on the trough inner slope oriented parallel to the trough trend, and a slab continuous with down-bowed continental margin can often be detected a considerable distance in from the trough below the inner slope. On face value these observations are compatible with a mechanism of underthrusting by Australian and New Guinea crust with consequent imbrication and accretion of packages of off-scraped sediments. However, they may also be explained as possible outward-directed gravity slides of nappes displaced from uplifted inner portions of the arc, similar to the published structural interpretation of at least the eastern portion of the neighbouring, closely related New Guinea Fold Belt. It is shown that the weight of marine geological and geophysical evidence, including the alignment with the oceanic Indonesian Arc, the gravity anomalies, and the persistence of the various morphological and structural entities around the arc, favours subduction in the Timor—Tanimbar—Ceram troughs rather than massive gravity sliding towards the troughs. By this working model the outer Banda Arc would be the accretionary prism of a subduction zone which was formerly in an ocean-crust setting but since Pliocene has been interacting with continental lithosphere. If its structural evolution is analogous to that of the New Guinea orogenic belt, then the Banda Arc has not yet reached the stage of major, foreland-directed gravity slides. The proposed structural model for the Banda Arc is at variance with some but not all structural interpretations of the island of Timor, which is an emergent portion of the outer arc. Further critical studies are obviously required, both in marine and terrestrial areas, to resolve this impasse.     

柴达木北缘超高压变质带中的岛弧火山岩

青藏高原北部柴北缘发育一套与超高压变质带并行的早古生代岛弧火山岩带,岛弧火山岩以玄武岩类为主,包括一些中酸性岩类,岩石以普遍遭受绿片岩相蚀变为特征,区别于该地区普遍遭受角闪岩相区域变质的元古代的基性火山岩。该早古生代的岛孤火山岩显示三组地球化学特征:①VTG-Ⅰ,岛弧拉斑玄武岩(IAT);②VTG-Ⅱ,高Al次钙碱性-碱性过渡型玄武岩;③VTG-Ⅲ,较N-MORB更亏损的拉斑玄武岩(异常MORB)。研究认为前两组火山岩是成熟岛弧两个发育阶段的特征性产物:洋壳俯冲到陆壳的初用,由俯冲洋壳和地幔楔的部分熔融形成岛弧拉斑玄武岩(IAT),随着俯冲板块的速度加快和岛弧周围地壳的加厚,则形成钙碱性玄武岩(CA)、高Al玄武岩。第三组火山岩形成于弧间盆地,由亏损的地幔楔高度部分熔融形成比N-MORB亏损的的火山岩(异常MORB)。岛弧火山岩的锆石LA-ICP-MS法U-Pb年龄为514.2±8.5 Ma,说明柴北缘在早古生代发生过洋壳向陆壳的俯冲作用。鉴于该地区代表陆-陆俯冲作用的柴北缘超高压变质岩石也是形成于早古生代(494Ma),认为陆-陆俯冲作用发生在洋-陆俯冲作用之后,二者时间和空间相伴随。     

The Final Stage of Silicic Island Arc Magmatism in the Northern Urals

Doklady Earth Sciences - The date of cessation of calc-alkaline volcanic complex accumulation within the Devonian (Frasnian) island arc in the Northern Urals was determined for the first time. It...     

地热水资源开发引起的环境问题分析

本文分析论述了地热水资源开发引起的主要环境问题:地震、地面沉降、地热资源衰竭、地热水有害成分污染、热污染等,同时提出了相应的防治建议.     

岛弧火山岩成因和地球化学特征

岛弧火山岩主要为俯冲带的俯冲板片脱水形成的富大离子亲石元素流体交代地幔楔,并使其发生部分熔融,产生岛弧岩浆作用而形成的,岩石组合通常为玄武岩—安山岩—英安岩—流纹岩及相应侵入岩组合。它以Al2O3、K2O高,低Ti O2,且K2ONa2O为特征,相对富集LILE,亏损HFSE,特别是Ti、Nb、Ta等。本文主要从岛弧岩浆作用的起因着手,分析流体和熔体对地幔楔的交代作用,以及岛弧岩浆作用过程,进而分析岛弧火山岩的地球化学特征。     

Theoretical and numerical analyses of pore-fluid flow focused heat transfer around geological faults and large cracks

In this paper, theoretical and numerical methods are used to investigate pore-fluid flow focused temperature distribution patterns around geological faults and cracks of any length-scales in hydrothermal systems. If the far field inflow is uniform and the long axis of an elliptical fault of any length-scale is parallel to the far field inflow direction, a complete set of analytical solutions has been presented for the pore-fluid velocity, stream function and excess pore-fluid pressure around the elliptical fault embedded in fluid-saturated porous media. Because the analytical solutions are explicitly expressed in the conventional Cartesian coordinate system, not only can they be used to gain a theoretical insight into the pore-fluid flow patterns around geological faults and large cracks, but also they can be used as valuable benchmark solutions for validating any numerical methods. After a finite element computational model is validated by comparing the numerical solutions with the present analytical solutions, it is used to investigate pore-fluid flow focused heat transfer around geological faults in hydrothermal systems. Some interesting conclusions in relation to the effects of geological faults on pore-fluid flow focused heat transfer have been made through both the theoretical and the numerical analyses.     

Cenozoic Island Arc Magmatism in Java Island (Sunda Arc, Indonesia): Clues on Relationships between Geodynamics of Volcanic Centers and Ore Mineralization

Abstract. Java island, regarded as a classic example of island arcs, is built through multi events of Cenozoic arc magmatism produced by the subduction of Indian‐Australian oceanic crusts along the southern margin of Eurasian plate. Regional crustal compositions, subducted slabs, and tectonics determined the spatial‐geochemical evolution of arc magmatism and regional metallogeny. Tertiary geodynamics of island arc was dominated by backarc‐ward migrations of volcanic centers. Only after the Miocene‐Pliocene roll‐back effects of retreating slab, slab detachment, and backarc magmatism took place in central Java. The source of arc magmas is mainly partial melting of mantle wedge, triggered by fluids released from dehydrated slabs. Increasing potassium contents of arc magmas towards the backarc‐side and younger magmas is typical for all magmas, while alkali and incompatible trace elements ratios are characteristics for different settings of volcanic centers. The oceanic nature of crust and the likely presence of hot slab subducted beneath the eastern Java determine the occurrences of adakitic magmas. Backarc magmatism has a deeper mantle source with or without contributions from subduction‐related materials. The domination of magnetite‐series magmatism determines the sulfide mineralization for the whole island. District geology, geodynamics, and magma compositions in turn control particular styles and scales of precious metals concentrations. Deep‐seated crustal faults have focused the locations of overlapping volcanic centers and metalliferous fluids into few major gold districts. Porphyry deposits are mostly concentrated within Lower Tertiary (early stage) volcanic centers in eastern Java which are not covered by younger volcanic centers, and whose sulfides are derived from partial melting of basaltic parental materials. On the other hand, high‐grade low‐sulfidation epithermal gold deposits formed in later stages of arc development and are spatially located within younger volcanic centers (Upper Miocene‐Pliocene) that overlap the older ones. Gold in low‐sulfidation epithermal system is likely to be derived from crustal materials. The overall interacting factors resulting in the petrochemical systematics that are applicable for exploration: 1) early‐stage volcanic centers with high Sr/Y and Na₂O/K₂O ratios are more prospective for porphyry mineralization, while 2) later‐stage volcanic centers with high K₂O, total alkali, and K₂O/Na₂O ratios are more prospective for low‐sulfidation epithermal mineralization.     

Pb-Nd Isotopes Indicate the Origin of Island Arc Terranes in the Early Paleozoic Pacific

The Takaka Terrane in New Zealand is one of the best exposed arc fragments of the early Paleozoic Australian-Antarctic convergent margin and constitutes one of the most outboard terranes of this margin in paleogeographic reconstructions. Pb-Nd isotope compositions of clinopyroxenes from the Cambrian Devil River Volcanics of the Takaka Terrane enable identification of the location of the terrane in the Paleo-Pacific Ocean. The Devil River Volcanics, a suite of primitive arc and back-arc rocks, are interbedded with the partly continent-derived Haupiri Group sediments. Extremely radiogenic Pb and unradiogenic Nd compositions in the arc rocks cannot be explained by assimilation of the Haupiri Group sediments or a continental basement of such a composition. Pb isotope compositions of the Takaka Terrane sediments are much less radiogenic and overlap with crustal compositions of the Lachlan Fold Belt in Australia, suggesting that both units are derived from one source, the Australian-Antarctic Pacific margin. Pb-Nd isotope compositions in the Devil River Volcanics reflect contamination of their mantle sources by subducted sediments derived from Archean provinces in either Antarctica or Laurentia. Both provinces show characteristically high 207Pb/204Pb500 and were located at the Pacific rim in the Cambrian. Mixing between mantle and Proterozoic continental material from present western South America or eastern Laurentia cannot explain the high 207Pb/204Pb500 in the New Zealand rocks. As in New Zealand, extreme spreads in Pb-Nd isotope compositions in other Cambrian volcano-sedimentary sequences in southeast Australia and Tasmania can be explained by the same model, suggesting that all these fragments originated along the Australian-Antarctic Gondwana margin. Pb isotope compositions of arc rocks, therefore, provide a new tool for terrane analysis in the early Paleozoic Pacific ocean.     

The Petrology of Plutonic Blocks and Inclusions from the Lesser Antilles Island Arc

Three main groups of plutonic nodules are present in the LesserAntilles arc and are interpreted as (a) phenocryst clusters,(b) metamorphosed wallrock xenoliths and (c) cumulate texturedxenoliths. Large cumulate blocks display felsic-mafic layering,slump structures and auto-intrusive features. The majority ofspecimens are ad- and heteradcumulates with fewer ortho- andcrescumulates. Interstitial scoria and glass are present ina variety of samples. Plagioclase, amphibole, cino- and orthopyroxene,olivine, magnetite, biotite, ilmenite, quartz and apatite arepresent in various proportions in individual blocks. Plagioclaseand amphibole are modally predominant. Significant variationalong the arc is displayed in the rarity of orthopyroxene andabundance of amphibole in the southern islands compared withthe common presence of two pyroxenes in the northern islands. Plagioclase varies from An_100–36 with very low orthoclasecomponent, and usually precedes amphibole in a given crystallizationsequence. Only on Grenada are plagioclase-free blocks present.Olivine is restricted to assemblages where coexisting plagioclaseis more calcic than An₈₉ and its composition range is Fo_90–59.Clinopyroxene is predominantly calcic augite and cinopyroxene,olivine and plagioclase all coexist stably with amphibole. Ageneral trend of decreasing Ca content in clinopyroxene fromsouth to north in the arc is present. Orthopyroxene ranges from En_73–49 and is most common inassemblages where the coexisting plagioclase is more sodic thanAn₈₃ Coexisting pyroxenes define temperatures in the range 800–1050?C. Amphibole compositions include pargasite, magnesiohastingsite,magnesio-hornblende and tschermakitic hornblende. The K contentof the amphiboles increases from north to south in the samesense as the general tholeiitic-calcalkalic-alkalic variationof parental magmas. Magnetite is the dominant spinel phase but ferrian chromiteand chromian magnetite are present in some Grenada cumulatesand pleonaste is found in rare St. Kitts samples. Ilmenite ispresent in blocks from several islands; coexisting Fe-Ti oxidesdefine a temperature range of 710?-950 ?C at of 15.5 to 10.0 bars. Biotite, quartz and apatiteare restricted to evolve cumulate types. Some modification of interstitial scoria/glass compositionsfrom equilibrium melts has occurred in the majority of samples,but general similarity with erupted lava types is importantevidence for the cognate relationship of the cumulate assemblages.The role of H₂O is crucial in determining the calcic natureof island arc plutonic plagioclase when compared with relativelydry, layered tholeiitic plutons. Some modal and chemical featuresof cumulate-lava comparisons suggest plagioclase flotation maybe significant. A variety of thermodynamic calculations indicate temperaturesand pressures of crystallization in the range 850–1050?C, 4–10 kb. No evidence exists for systematic along-arcvariations in these parameters. Standard amphibole crystallinesolution models give unsatisfactory results for calculations. Some distinctive contrasts between cumulate and phenocryst modesare present. The abundance of amphibole in equilibrium withbasaltic melts in the plutonic situation compared with its rarityin lavas is striking. Plagioclase coexisting with a given meltis more anorthitic in the plutonic than the phenocryst mode. Least squares fractionation tests demonstrate the possibilityof relating basalt-andesite-dacite suites by fractional crystallizationof the cumulus phases. Trace element systematics of cumulate-lavasuites for individual islands also generally support this hypothesis.The suggestion of sole amphibole fractionation for the generationof andesite from basalt is discarded. ^* Present address: CRAE, Box 39598, Darwin, N.T. 5798, Australia.     

Consolidation around a heat source buried deep in a porous thermoelastic medium with anisotropic flow properties

A solution is derived for the heat flow and consolidation which occur when a heat source is buried deep in a porous thermoelastic soil having anisotropic flow properties. This solution is used to examine the pore pressure generation and dissipation near both point and cylindrical heat sources. An increase in temperature will tend to generate an increase in excess pore pressure. However, the pore water will tend to flow from regions of high excess pore pressure to regions of low excess pore pressure, and so consolidation will occur, and temperature-generated excess pore pressures will tend to dissipate. Many natural soils exhibit horizontal layering and so have a higher horizontal than vertical permeability. It is shown that in soils the excess pore pressure generated by a heat source is significantly less than that in an isotropic soil having an equal vertical permeability.     

西藏那木如辉绿岩岩脉的年代学和地球化学特征

那木如辉绿岩具有较高的TiO2和P2O5含量,Mg#是0.6～0.7,表明岩石经中等程度或轻微的斜长石分离结晶作用;富集Rb、K、Th、Ba,亏损Nb、Ti、Ta和Zr、Hf,轻稀土富集,且具有负Eu的异常,表明岩石具有岛弧岩浆的性质.对那木如辉绿岩进行SHRIMP锆石U-Pb定年,其形成年龄值为64±1 Ma(2σ,MSWD=2.4),即辉绿岩结晶年龄.本次定年的结果正好处于西雅鲁藏布北亚带洋盆向北对拉萨地体南缘之下的俯冲(晚白垩世至早第三纪)时期内,说明那木如辉绿岩为此次俯冲形成的岛弧岩浆岩.位于冈底斯弧南侧的西雅鲁藏布北亚带蛇绿岩被第三系磨拉石不整合覆盖,说明蛇绿岩侵位时间早于第三系,与那木如辉绿岩的侵位年龄接近.由此可见,正是形成那木如岛弧岩浆岩的俯冲构造事件导致了西雅鲁藏布北亚带蛇绿岩的构造侵位.     

Sulfur isotope study of Quaternary volcanic rocks from the Japanese Islands Arc

The sulfide and sulfate contents and their δ³⁴S values were determined in Quaternary volcanic rocks from the Japanese Islands Arc. The total sulfur contents are much lower (less than 40 ppm) and the δ³⁴S values are higher (+4.4 ± 2.1) than those of ocean-floor basalts (800 ± 100 ppm and +0.8 ± 0.5, respectively; Moore and Fabbi, 1971; Sakaiet al., 1982). Lateral variations of both sulfur content and δ³⁴S values were observed in the four volcanic belts in Japan. In the Northeast Japan belt, the sulfur content (30 ± 10 ppm) of the rocks in the inner zone (the Japan Sea side) is 3 to 5 times that in the outer zone (the Pacific side), although the δ³⁴S values of the two zones are almost the same (+4.3 ± 1.0). The δ³⁴S values for the two belts in West Japan are on the average 2%. higher than those of East Japan.This study suggests that the primary magmas that formed the island arc volcanic rocks are initially depleted in sulfur (<120 ppm) and enriched in ³⁴S ($\text{δ}{}^{34}\text{S: +5 ～ +7}$) compared to ocean-floor tholeiitic basalts which formed at mantle under oceanic region. This indicates that the upper-mantle is heterogeneous in sulfur content and isotope composition.     

Esmeralda Bank: Geochemistry of an active submarine volcano in the Mariana Island Arc

Esmeralda Bank is the southernmost active volcano in the Izu-Volcano-Mariana Arc. This submarine volcano is one of the most active vents in the western Pacific. It has a total volume of about 27 km³, rising to within 30 m of sea level. Two dredge hauls from Esmeralda recovered fresh, nearly aphyric, vesicular basalts and basaltic andesites and minor basaltic vitrophyre. These samples reflect uniform yet unusual major and trace element chemistries. Mean abundances of TiO₂ (1.3%) and FeO^* (12.6%) are higher and CaO (9.2%) and Al₂O₃ (15.1%) are lower than rocks of similar silica content from other active Mariana Arc volcanoes. Mean incompatible element ratios K/Rb (488) and K/Ba (29) of Esmeralda rocks are indistinguishable from those of other Mariana Arc volcanoes. On a Ti-Zr plot, Esmeralda samples plot in the field of oceanic basalts while other Mariana Arc volcanic rocks plot in the field for island arcs.Incompatible element ratios K/Rb and K/Ba and isotopic compositions of Sr (⁸⁷Sr/⁸⁶Sr=0.70342–0.70348), Nd (_ND=+7.6 to +8.1), and O(¹⁸O=+5.8 to +5.9) are incompatible with models calling for the Esmeralda source to include appreciable contributions from pelagic sediments or fresh or altered abyssal tholeiite from subduction zone melting. Instead, incompatible element and isotopic ratios of Esmeralda rocks are similar to those of intra-plate oceanic islands or hot-spot volcanoes in general and Kilauean tholeiites in particular. The conclusion that the source for Esmeralda lavas is an ocean-island type mantle reservoir is preferred.Esmeralda Bank rare earth element patterns are inconsistent with models calling for residual garnet in the source region, but are adequately modelled by 7–10% equilibrium partial melting of spinel lherzolite. This is supported by consideration of the results of melting experiments at 20 kbars, 1,150° C with CO₂ and H₂O as important volatile components. These experiments further indicate that low MgO (4.1%), MgO/FeO^*(0.25) and Ni(12 ppm) in Esmeralda Bank melts are characteristic of initial melts generated by moderate degrees of melting of hydrous and carbonated mantle. Consideration of experimental determinations and spinel-lherzolite to garnet-lherzolite stabilities indicates Esmeralda Bank melts were generated by partial melting within the upper 60–110 km of the mantle.