Ferrobasalts from the Central Indian Ocean Basin

 We report the occurrence of ferrobasalts recovered from the Central Indian Ocean Basin crust generated at the Southeast Indian Ridge during a phase of moderate to fast spreading accretion (∼110–190 mm/yr, full rate).The rocks are rich in plagioclase, FeO^* (13–19%), and TiO₂ (2.27–2.76%), poor in olivine and MgO (3.44–6.20%), and associated with topographic highs and increased amplitude magnetic anomalies corresponding to chrons A25 and A24. We suggest that secon dary eruptions from ancient N-MORB magma, which may have been trapped at a shallow depth in a horizon of neutral buoyancy, could have produced the ferrobasalts. Received: 27 January 1998 / Revision received: 25 May 1998     

Regional Variability in Occurrence and Distribution of Polymetallic Nodules in the Central Indian Basin

Regional scale morphological studies on different-sized polymetallic nodules from the Central Indian Basin show that only 2–5 cm sized nodules have highest occurrence per station (92–94% along latitudes; 88–94% along longitudes). A nodule size shows an inverse relationship with the nodule distribution, grade, and abundance. Interestingly, only 3–4 and 4–5 cm sized nodules have highest grade, abundance, and distribution percentages along longitudes in P₁, first generation mine site and relinquished area, which further implies that the nodule mining along the longitude would be beneficial. Different-sized nodule groups suggest their formation under variable environmental conditions that existed in the Central Indian Basin. The coexistence of different-sized nodules suggests different environmental conditions existed in the Central Indian Basin.     

Distribution and Origin of Seamounts in the Central Indian Ocean Basin

Approximately 200 seamounts of different dimensions have been identified, from multibeam bathymetry maps of the Central Indian Ocean Basin (CIOB) (9°S to 16°S and 72°E to 80°E), of which 61% form eight chains that trend N-S. The seamounts are clustered above and below 12°S latitude. Area II (9°–12°S) shows a concentration of smaller seamounts (≤400 m height), and area I (12°–15°S) has a mixed population (including both less and more than 400 m height). Inspite of the differences in their height, the seamounts of these eight chains are morphologically (slope angle, flatness, basal width) corelatable. Furthermore, we suggest that height-width ratio could be useful in identifying the style of seamount eruption. The seamount chains in the CIOB probably originated from propagative fractures and were produced between 61 and 52 Ma (chrons A26 to A23) as a result of the interaction between the conjugate crusts of the Central Indian and Southeast Indian Ridges during the Indo-Eurasian collision event.     

Mantle source heterogeneity and magmatic evolution at Carlsberg Ridge (3.7°N): constrains from elemental and isotopic (Sr,Nd, Pb) data

We present new major element, ICP-MS trace element, and Sr–Nd–Pb isotope data of basalts from four locations along the Carlsberg Ridge (CR), northern Indian Ocean. The basalts are low-K tholeiites with 7.52–9.51 wt% MgO, 49.40–50.60 wt% SiO₂, 0.09–0.27 wt% K₂O, 2.55–2.90 wt% Na₂O, and 0.60–0.68 Mg^#. Trace element contents of the basalts show characteristics similar to those of average normal MORB, such as LREE depleted patterns with (La/Sm)_N ratio of 0.55–0.69; however, some samples are enriched in large-ion lithophile elements such as K and Rb, suggesting probable modification of the mantle source. Poor correlations between the compatible elements [e.g. Ni, Cr, and Sr (related to olivine, clinopyroxene and plagioclase, respectively)] and the incompatible elements (e.g. Zr and Y), and positive correlations in the Zr versus Zr/Y and Nb versus Nb/Y plots suggest a magmatic evolution controlled mainly by mantle melting rather than fractional crystallization. Our results extend the CR basalt range to higher radiogenic Pb isotopes and lower ¹⁴³Nd/¹⁴⁴Nd. These basalts and basalts from the northern Indian Ocean Ridge show lower ¹⁴³Nd/¹⁴⁴Nd and higher ⁸⁷Sr/⁸⁶Sr values than those of the depleted mantle (DM), defining a trend towards pelagic sediment composition. The Pb isotopic ratios of basalts from CR 3–4°N lie along the compositional mixing lines between the DM and the upper continental crust. However, the low radiogenic Pb of basalts from CR 9–10°N lie on the mixing line between the DM and lower continental crust. Since the Pb isotopic ratio of MORB would decrease if the source mantle was contaminated by continental lithospheric mantle, we suggest that CR contains continental lithospheric material, resulting in heterogeneous mantle beneath different ridge segments. The continental lithospheric material was introduced into the asthenosphere before or during the breakup of the Gondwana. These results support the long-term preservation of continental material in the oceanic mantle which would significantly influence the isotopic anomaly of the Indian Ocean MORB.     

Engineering behavior of uplifted Smectite‐rich Cochin and Mangalore marine clays

Abstract

The present study aims to assess whether the smectite‐rich Cochin and Mangalore clays, which were deposited in a marine medium and subsequently uplifted, exhibit consistency limits response typical of expanding lattice or nonexpanding (fixed) lattice‐type clays on artificially changing the chemical environment. The chemical and engineering behaviors of Cochin and Mangalore marine clays are also compared with those of the smectite‐rich Ariake Bay marine clay from Japan. Although Cochin, Mangalore, and Ariake clays contain comparable amounts of smectite (32–45%), Ariake clay exhibits lower consistency limits and much higher ranges of liquidity indices than the Indian marine clays. The lower consistency limits of the Ariake clay are attributed to the absence of well‐developed, long‐range, interparticle forces associated with the clay. Also, Ariake clay exhibits a significantly large (48–714 times) decrease in undrained strength on remolding in comparison to Cochin and Mangalore clays (sensitivity ranges between 1 and 4). A preponderance of long‐range, interparticle forces reflected in the high consistency limits of Cochin and Mangalore clays (w_L range from 75 to 180%) combined with low natural water contents yield low liquidity indices (typically <1) and high, remolded, undrained strengths and are considered to be responsible for the low sensitivity of the Indian marine clays.     

Estimates of the mutual influence of variations in the sea surface temperature in tropical latitudes of the Pacific,Atlantic, and Indian Oceans from long-period data series

Based on the concept of the Wiener&–Granger causality, a seasonal trivariate analysis of directional couplings between sea surface temperature variations in tropical latitudes of the Pacific, Atlantic, and Indian Oceans has been performed. These variations are related to significant modes of regional and global climatic variability. We have analyzed time series of monthly indices of Pacific Ocean processes of the El Ni&ño/Southern Oscillation (ENSO), equatorial Atlantic mode (EAM), and Indian Ocean Dipole (IOD)&—along with its western and eastern poles for the period of 1870&–2015. A scheme of interactions between the processes under study where coupling strength estimates are presented, along with estimates of the season of its maximal value and the coupling coefficient sign, has been developed. We have found the seasonal influences of ENSO on the western and eastern poles of IOD, the eastern pole of IOD on ENSO, EAM on ENSO, and IOD on EAM to be the most significant couplings.     

Gas hydrate saturation in the Krishna–Godavari basin from P-wave velocity and electrical resistivity logs

During the Indian National Gas Hydrate Program (NGHP) Expedition 01, a series of well logs were acquired at several sites across the Krishna–Godavari (KG) Basin. Electrical resistivity logs were used for gas hydrate saturation estimates using Archie’s method. The measured in situ pore-water salinity, seafloor temperature and geothermal gradients were used to determine the baseline pore-water resistivity. In the absence of core data, Arp’s law was used to estimate in situ pore-water resistivity. Uncertainties in the Archie’s approach are related to the calibration of Archie coefficient (a), cementation factor (m) and saturation exponent (n) values. We also have estimated gas hydrate saturation from sonic P-wave velocity logs considering the gas hydrate in-frame effective medium rock-physics model. Uncertainties in the effective medium modeling stem from the choice of mineral assemblage used in the model. In both methods we assume that gas hydrate forms in sediment pore space. Combined observations from these analyses show that gas hydrate saturations are relatively low (<5% of the pore space) at the sites of the KG Basin. However, several intervals of increased saturations were observed e.g. at Site NGHP-01-03 (S_h = 15–20%, in two zones between 168 and 198 mbsf), Site NGHP-01-05 (S_h = 35–38% in two discrete zone between 70 and 90 mbsf), and Site NGHP-01-07 shows the gas hydrate saturation more than 25% in two zones between 75 and 155 mbsf. A total of 10 drill sites and associated log data, regional occurrences of bottom-simulating reflectors from 2D and 3D seismic data, and thermal modeling of the gas hydrate stability zone, were used to estimate the total amount of gas hydrate within the KG Basin. Average gas hydrate saturations for the entire gas hydrate stability zone (seafloor to base of gas hydrate stability), sediment porosities, and statistically derived extreme values for these parameters were defined from the logs. The total area considered based on the BSR seismic data covers ∼720 km². Using the statistical ranges in all parameters involved in the calculation, the total amount of gas from gas hydrate in the KG Basin study area varies from a minimum of ∼5.7 trillion-cubic feet (TCF) to ∼32.1 TCF.     

Sources,deposition rates and decomposition of organic carbon in recent sediment of Sachem Head Harbor,Long Island Sound

The vertical distributions of excess ²¹⁰Pb and fall out ^{239, 240}Pu imply a uniform sedimentation rate of 1·4–1·6 cm year^?1 from 0 to 105–110 cm. This sediment accumulation rate is compatible with sulfate reduction rate data from this location. Below 70 cm only ‘aged’ refractory carbon is present (C_R = 1·8% C) with an age of approximately 2400 years. This phase is present in a number of locations across Long Island Sound. Planktonic carbon (C_P) is present above the 60–67 cm horizon. A value of 1·0 for A_P (¹⁴C activity) at 32–37 cm was taken, A_P = 1·285 was used for contemporary plankton. This was obtained by correcting the measured A_P of a plankton tow sample for admixed refractory carbon. These values were then used to calculate C_R, C_P and C_F (fossil carbon) at 32–37 cm and 6–12 cm. The only values compatible with the known sulfate reduction rate data are C_R equal to pre 60–67 cm levels (1·6–1·8% C), C_F being 0·3% C at both depths, and C_P decreasing with depth from 0·3 to 0·4% C at 6–12 cm to close to zero at 32–37 cm.     

基于独立成分分析的马里亚纳弧后地幔源区特征研究

对采自太平洋洋中脊(277组)、印度洋洋中脊(159组)、马里亚纳海槽(53组)、马里亚纳岛弧(39组)、中南劳海盆(72组)共600组玄武岩数据进行了独立成分分析,从Sr-Nd-Pb五维同位素比值空间提取出占样本方差99％的3个独立成分(IC1,IC2,IC3),并利用这3个独立成分(ICs)与微量元素比值之间的相关...     

Physico‐chemical features of lake Pupuke,Auckland

Summary

Lake Pupuke, situated in the North Island of New Zealand near Auckland (Latitude 36° 53'S, Longitude 174° 52'E), is a small, circular body of water (maximum width 1.2 km, maximum depth 55 m). From November 1966 to November 1967 observations on its physico‐chemical factors were made twice monthly.

The range of temperatures in the year was 12.0–24.2°c at the surface and 11.3–14.5°c at 40 m. A thermocline farmed between early October and early January, when it became strongly developed at about 17 m and persisted until late April. Between early May and late June the stratification was breaking down and between mid July and mid September the lake was isothermal.

The values for light transmitted per metre through the water were high from mid August to mid December (53–76% per metre), very low from mid December until mid February (23–49% per metre), high in March (75% per metre) and relatively constant over the winter months (53–64% per metre). The amount of light transmitted depended closely on the density of phytoplankton. Changes in the depth at which a Secchi disc disappeared paralleled the light transmission values, and the mean Secchi depth was 2.2 m, range 1.0–5.2 m.

Oxygen concentrations down to 30 m were highest at all depths from mid November to early January (112–134% saturation). From early January to late April oxygen was strongly stratified (epilimnion 55–100% saturation, hypolimnion 24–77% saturation). During winter oxygen values gradually increased at all depths.

The range of pH was 7.8–9.5 units at the surface and 7.8–8.6 units at 30 m. From early January to late April pH values were strongly stratified but from mid July to mid August they were nearly uniform. The range of alkalinity (mainly HCO₃ ^? ions) was 76.0–80.8 ppm CaCO₃ and values showed stratification in summer. Carbonate ion was present from early October to mid June, but free carbon dioxide was only found in trace amounts.

The range of nitrate ion concentrations was 0.05–0.31 ppm; nitrate became obviously depleted in summer. Only one nitrite value was significant, 0.25 ppm. other nitrite values never exceeded 0.10 ppm. The concentration of ammoniacal nitrogen built up to a summer maximum of 0.95 ppm in the hypolimnion (annual range 0–0.95 ppm); values for albuminoid ammonia (0.016–1.03 ppm of nitrogen) varied with the quantity of living matter present.

The annual mean for total ion concentration (3.30 meq./1) was high and the order of ions was Na⁺>Mg²⁺>Ca²⁺>K⁺ and HCO₃ ^?>CI^?>SO₄ ^2?. Such dissolved salts may have arrived as airborne particles, dissolved in rain, or as sea spray.     

Formation of methane-related authigenic carbonates in a highly dynamic biogeochemical system in the Krishna–Godavari Basin,Bay of Bengal

We report the abundant occurrence of authigenic Fe-rich carbonate, high Mg-calcite (HMC) and low Mg-calcite from 11 cores recovered from the Krishna–Godavari Basin (K–G Basin), Bay of Bengal. The cores were collected as part of the Indian gas hydrate exploration program on board R/V Marion Dufresne (MD-161: May, 2007) in different environments, including mounds (mud diapirs), mass flows, and hemipelagic sediments over a range of water depths from 647 to 2079 m. Authigenic carbonates range in size from 1 mm to 12 cm and display various morphologies like roundish or platy (micro-) nodules and tube-like forms. From the cores, 173 carbonate samples have been investigated for their depth distribution, mineralogy, geochemical and stable isotopic composition. The stable carbon isotopic composition of 46 out of 88 measured carbonate samples are around −50‰ which allows the differentiation into methane-related carbonates (HMC), especially at Sites 8 and 15, but also in low abundance at Sites 1, 5, 9 and 12. Results indicate that the carbonates at Site 8 and 15 represent paleo methane seepage locations. The Fe-rich carbonates occur abundantly at many sites in the K–G Basin. Their varying carbon isotopic composition indicates that probably not only sulfate reduction through organic matter degradation but also methanogenesis are the responsible processes for their formation.     

Highly restricted gene flow between disjunct populations of the skunk clownfish (Amphiprion akallopisos) in the Indian Ocean

The skunk clownfish (Amphiprion akallopisos) has a disjunct distribution, occurring in the Eastern Indian Ocean (EIO) and the Western Indian Ocean (WIO), separated by several thousands of kilometres. Information on connectivity of marine species is very important for the correct spacing of marine protected areas, a powerful instrument for the protection of coral reefs. The population genetic structure of A. akallopisos was analysed in order to investigate connectivity amongst populations and to explain the disjunct distribution of the species. A fragment of the mitochondrial control region was used to investigate the genetic population structure. Fin clips were collected from 263 individuals at 14 sites in the WIO and three sites in the EIO. The obtained DNA sequences were used to calculate genetic diversity, evaluate demographic history and to construct a haplotype network. An analysis of molecular variance (AMOVA) was conducted to evaluate the significance of the observed genetic population structure. None of the identified 69 haplotypes was shared between the WIO and EIO. Haplotype as well as nucleotide diversity was considerably higher in the EIO than in the WIO. Significant genetic population structure was revealed by an AMOVA with an overall φ_st‐value of 0.28 (P < 0.001) in the Indian Ocean. The overall AMOVA (φ_st = ?0.00652) was not significant in the EIO, but was significant in the WIO (φ_st = 0.016; P < 0.01). Demographic analysis indicated population expansion in the EIO and WIO. Population genetic analysis revealed highly restricted gene flow between the EIO and WIO. Genetic diversity was much higher in the EIO than in the WIO, suggesting that the EIO is the geographical origin of the species. Given the large distance between the disjunct populations and the short pelagic larval duration, long‐distance dispersal is rather unlikely. A stepping stone model involving islands in the Central Indian Ocean is a more likely scenario for colonization of the WIO.     

Analysis of temporal and spatial characteristics of waves in the Indian Ocean based on ERA-40 wave reanalysis

Based on the 45-year (09/1957-08/2008) European Centre for Medium-Range Weather Forecasts (ECMWF) Reanalysis (ERA-40) wave reanalysis dataset, this study analyzes interannual and interdecadal variabilities and intraseasonal oscillations of sea surface wind speed (WS), wind sea wave height (H^w), swell wave height (H^s) and significant wave height (H_s) in the Roaring Forties and tropical waters of the Indian Ocean, to determine swell propagation characteristics. The results show: (1) monthly variabilities of H^s in the Roaring Forties are in good agreement with those in tropical waters of the Indian Ocean; swell plays a dominant role in mixed waves throughout most of the Indian Ocean; and WS, H^w, H^s, and H_s exhibit a significant increasing trend over the 45-year study period. (2) H^s in the Roaring Forties and tropical waters of the Indian Ocean share a common period of 9.8–10.4 years on an interdecadal scale; and WS and H^s in the Roaring Forties and H^s in the tropical waters of the Indian Ocean share a common period of approximately 8 days (weekly oscillation) on an intraseasonal scale. (3) Swell of the Roaring Forties needs approximately 30 h to fully respond to the wind in this region. Approximately 84 h are required for H^s to propagate from the Roaring Forties to the tropical waters of the south Indian Ocean, while it takes approximately 132–138 h for H^s to propagate from the Roaring Forties to the tropical waters of the north Indian Ocean.     

A submersible study in the western Blanco fracture Zone,N.E. Pacific: Structure and evolution during the last 1.6 Ma

During July and August 1991, the French-American Blanconaute dive program used the French submersibleNautile to investigate the West Blanco Depression (WBD), a deep, elongate trough located at the intersection of the Blanco Transform Fault Zone with the southern Juan de Fuca Ridge (JdFR). Twenty dives were carried out along the north wall of the WBD, which exposes the upper oceanic crust over a 65 km distance, from the JdFR axis (to the west) to the oblique trace of an ancient propagator (to the east, crustal age around 2 Ma). Thirteen of these dives were precisely located within a 13 × 7 km zone of the north wall, covered by a high-resolution sonar mapping operation during the Blancotrough cruise in 1987. This series of geological traverses, plus 4 dives across the south wall of the WBD (one dive) and the adjacent Parks Plateau (3 dives), collected 242 rock samples. We report here the main results of the dive program and preliminary laboratory studies:

1. Transform-related tectonic activity has recently abandoned the southern margin of Parks Plateau, and is presently located inside the WBD area, mainly along its northern wall. The tectonic features observed are compatible with a right-lateral strike-slip system, with a NE-SW extensional component.
2. Three main lithological units are exposed along the north wall of the WBD. From top to bottom, they are: (1) a Volcanic Unit, forming a steep upper cliff, made of massive and pillow flows and basaltic dikes, with an estimated average thickness of 800 m; (2) a less steep Transition Zone, about 150 to 400 m thick, largely masked by rubble but exposing both diabase outcrops and pillow flows; and (3) a massive Diabase Unit, exposed over 700–800 m, with a dike complex structure visible from place to place, and cut by a net of hydrothermal veins. Deep crustal rocks such as gabbros were not observed.
3. Spectacular mass-wasting features are visible all along the north wall of the WBD. About 60% of the face of the wall is masked by talus cones, rubble, rock avalanche deposits and slide blocks. Three main landslides, of approximately one km³ in volume each, were tentatively identified. One of them was mapped in detail and consists of an approximately 300 m thick (0.85 km³), coherent slide block detached from a zone where intense hydrothermal alteration and faulting have obviously weakened the bedrock, that is in places entirely altered to blue clays.
4. The basaltic lavas of the WBD north wall show a remarkable evolution with time, from east to west. Around the tip of the ancient propagator, they are restricted to primitive, olivine-rich picritic basalts. Proceeding westward, they exhibit a wide range of differentiation, including highly fractionated, FeTi-rich ferrobasalts at about 35–45 km from the JdFR axis. When approaching the JdFR axis, the FeTi enrichment decreases gradually, and the ferrobasalts evolve towards slightly differentiated MORB-type basalts, typical of the southern JdFR. This magmatic evolution marks the transition from the end of a propagating rift regime to a steady-state accretion regime.
5. The WBD north wall also permits the study of weathering and hydrothermal alteration processes and their evolution in space and time. Vertically, the alteration products evolve from oceanic weathering and zeolite facies (Volcanic Unit) to the greenschist facies (Transition Zone and Diabase Unit). Horizontally, the evolution with time is mainly a general hydration of the crust that is, however, very irregularly distributed.
6. Several vertical magnetic traverses along the north wall of the WBD, using a bottom magnetometer attached to the basket of the submersible, have shown a sharp 5000 to 7000 nT positive anomaly at about 3500 m depth. This anomaly corresponds exactly to the first appearance of extrusive pillow-lava outcrops, and confirms the dramatic decrease in magnetic anomaly amplitude below that depth, detected during the Blancotrough cruise in 1987. The vertical magnetic profiles thus appear to have imaged the base of the magnetic source layer.

     

Projected future changes in the contribution of Indo-Pacific sea surface height variability to the Indonesian throughflow

The Indonesian throughflow (ITF) transports a significant amount of warm freshwater from the Pacific to the Indian Ocean, making it critical to the global climate system. This study examines decadal ITF variations using ocean reanalysis data as well as climate model simulations from the Coupled Model Inter-comparison Project Phase 5 (CMIP5). While the observed annual cycle of ITF transport is known to be correlated with the annual cycle of sea surface height (SSH) difference between the Pacific and Indian Oceans, ocean reanalysis data (1959–2015) show that the Pacific Ocean SSH variability controls more than 85% of ITF variation on decadal timescales. In contrast, the Indian Ocean SSH variability contributes less than 15%. While those observed contributions are mostly reproduced in the CMIP5 historical simulations, an analysis of future climate projections shows a 25–30% increase in the Indian Ocean SSH variability to decadal ITF variations and a corresponding decrease in the Pacific contribution. These projected changes in the Indian Ocean SSH variability are associated with a 23% increase in the amplitudes of negative zonal wind stress anomalies over the equatorial Indian Ocean, along with a 12º eastward shift in the center of action in these anomalies. This combined effect of the increased amplitude and eastward shift in the zonal wind stress increases the SSHA variance over the Indian Ocean, increasing its contribution to the ITF variation. The decadal ITF changes discussed in this study will be crucial in understanding the future global climate variability, strongly coupled to Indo-Pacific interactions.

     

Analysis of SARAL/AltiKa Wind and Wave over Indian Ocean and its Real-time Application in Wave Forecasting System at ISRO

The current study aims to analyze the wind and wave parameters over Indian Ocean region obtained from first Ka –band altimeter AltiKa onboard SARAL, a collaborative mission of Indian Space Research Organization (ISRO) and Centre National d'Etudes Spatiales (CNES), France. It also demonstrates a real time application of SARAL data by assimilating the wave height in a wave model operational at the Space Applications Centre, ISRO. State-of–the art coastal wave model Simulating Wave Near shore (SWAN) is used for this purpose. The well-tested optimal interpolation technique is adopted for assimilation. Before proceeding to the assimilation per se, SARAL/AltiKa Wind and Significant Wave Height (SWH) have been validated using in- situ observations and WAVEWATCH III model. Apart from assessment of wind and wave data quality, this also served the purpose of providing error covariance to be used in assimilation. Supremacy of the assimilation run over parallel control run without assimilation has been judged by comparing the results with buoy observations at Indian National Centre for Ocean Information System (INCOIS). The statistics of validation of the assimilation run has been found to be extremely encouraging and interesting.     

Accumulation of sediments,trace metals (Pb,Cu) and total hydrocarbons in Narragansett Bay,Rhode Island

The accumulation of sediments, trace metals and hydrocarbons has been estimated from the analysis of the sediment from six coring sites in Narragansett Bay. Radionuclides (²³⁴Th_xs, ²¹⁰Pb_xs, ^239,240Pu) with known input functions and trace metals (Cu, Pb) were used. We estimate that 6·9 × 10⁴ tons of sediments, 51–90 tons of Pb, 72–100 tons of Cu and 400–1000 tons of total hydrocarbons accumulate annually under present conditions in the bay. This represents 64–117% (Pb), 89–123% (Cu) and 23–58% (hydrocarbons), respectively, of present day inputs to the bay. Furthermore, close to 100% of the particle-reactive radionuclides ²¹⁰Pb and ^239,240Pu accumulate in the bay. Present day inputs to the bay were calculated independently as 77–80 tons Pb and 81 tons of Cu. Sewage effluents were the dominant source of Cu, whereas atmospheric deposition and urban runoff were most important for Pb. Dredging activities by the U.S. Army Corps of Engineers between 1946 and 1971 removed more sediments from the bay than would have accumulated during the same time in the undredged areas of the bay. Copper smelting and coal mining on the shores of the upper bay during 1866–1880 left an imprint in the sediments which is still evident. Model derived accumulation rates of Pb, Cu and coal during that time were 3–4 times present-day inputs.     

High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010–2011

We measured dissolved isoprene (2-methyl-1,3-butadiene; C₅H₈) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L^?1 and from 181 to 313 nmol m^?2 day^?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r ² = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r ² = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO₂), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO₂ are similar within a physically stable water column.     

Distribution and Origin of Seamounts in the Central Indian Ocean Basin

Approximately 200 seamounts of different dimensions have been identified, from multibeam bathymetry maps of the Central Indian Ocean Basin (CIOB) (9°S to 16°S and 72°E to 80°E), of which 61% form eight chains that trend N-S. The seamounts are clustered above and below 12°S latitude. Area II (9°-12°S) shows a concentration of smaller seamounts (≤400 m height), and area I (12°-15°S) has a mixed population (including both less and more than 400 m height). Inspite of the differences in their height, the seamounts of these eight chains are morphologically (slope angle, flatness, basal width) corelatable. Furthermore, we suggest that height-width ratio could be useful in identifying the style of seamount eruption. The seamount chains in the CIOB probably originated from propagative fractures and were produced between 61 and 52 Ma (chrons A26 to A23) as a result of the interaction between the conjugate crusts of the Central Indian and Southeast Indian Ridges during the Indo-Eurasian collision event.     

Hydrocarbons in the Bay of Bengal and Central Indian Basin bottom sediments: indicators of geochemical processes in the lithosphere

A study on the bulk distributions and molecular structures of n-alkanes and polycyclic aromatic hydrocarbons (PAH) in organic matter of the sediments from the Bay of Bengal and the Eastern and Central Indian Basins was undertaken. The former two regions represent areas characterised by “normal” sedimentation while the third one mainly represents a region of “active tectonism”. Content of the hydrocarbons in the sediments of “normal” sedimentation ranges between 4.6 and 10.5 μg/g and aromatic hydrocarbons ranges between 0 and 0.38 μg/g. n-Alkanes in the sediments of the northern deep part of the Bay of Bengal consist mostly of long-chain structures (total C₂₅–C₃₃ up to 70%) with a high carbon preference index (CPI=3.01–3.43), indicating a large contribution of organic matter from terrigenous sources. The sediments from the Eastern Indian Basin have n-alkane distributions in which the long-chain components did not exceed 52.5% and the CPI was 1.7–1.90, indicating that the hydrocarbons are mostly derived from marine sources. Sharp increases of hydrocarbons are found in the vicinity of the tectonically active region of the Central Indian Basin, particularly in the sediments collected from the fracture zone. The total concentration of hydrocarbons increase to 170 μg/g and the aromatic hydrocarbons fraction to 156.3 μg/g. The proportion of short-chain n-alkanes increases up to 70%, CPI decreases to 0.76–1.12, and high concentrations of n-C₁₆ (16–40%) occur, all of which are absent in the other samples. The molecular content of PAH includes the unsubstituted individual structures: biphenyl, fluorene, pyrene, perylene, benzo(ghi)perylene, and the groups of homologues of naphthalene, benzofluorene, phenanthrene and chrysene. The association of the PAH and composition of paraffin hydrocarbons in the surficial sediments of deformation zone indicate that these are the resultant products of hydrothermal processes. It is, therefore, suggested that the association and composition of the hydrocarbons in sediments can be utilised as a paleoceanographic parameter to decipher the history of tectonism of an area.