Gaseous air pollution background estimation in urban,suburban, and rural environments

There is a great demand for estimating the ambient air pollutant background concentrations in order to assess the effectiveness of different emission control strategies. In this paper, the background concentrations of four pollutants, namely sulfur dioxide (SO₂), nitrogen oxides (NOx), carbon monoxide (CO), and ozone (O₃) pollutants in urban, suburban, and rural environments were investigated using Kolmogorov–Zurbenko (KZ) filter technique. Air quality data from monitoring stations over a period of 4 years (2007–2010) was analyzed for three locations in Kuwait, namely urban, suburban, and rural. The spatial and temporal (daily, weekly, and monthly) variations of the four pollutants were analyzed. The results show that the levels of ambient air pollutant background concentrations were high in the urban site compared to suburban and rural area. The diurnal variation of SO₂ concentration showed an early morning peak, while the diurnal variation of NOx concentration constituted has two peaks, one was in the early morning hours (5 to 8 a.m.) and the second was in nighttime hours (8 to 11 p.m.). These two peaks were observed at all three locations. The monthly background NOx concentration reached a maximum in winter and minimum in summer. Diurnal variation of CO concentration showed a similar trend to SO₂ concentrations in all three locations. Because of the photochemical reactions that occur in the atmosphere, the background concentration of O₃ showed an inverse relation with respect to background concentration of NOx.     

Assessment of heavy metal pollution in urban topsoils from the metropolitan area of Mexico City

This study reports the degree of heavy metal pollution (Cr, Cu, Ni, Pb, Zn and V) in 135 urban topsoil samples from the metropolitan area of Mexico City. Pollution indices (PI) were calculated to identify the metal accumulation with respect to the background values. The levels of heavy metals in the analyzed samples show a wide range of variation. Lead, Zn and Cu are the elements most enriched in the analyzed area, presenting pollution indexes of up to 23.8, 21.6 and 12.4, respectively. Geochemical maps were produced to assess the spatial distribution of pollution index. It is concluded that emissions from vehicles may be the major source of Pb urban contamination; furthermore, other small or large factories are possible sources for soil pollution (Cu, Zn). The concentration of Cr, Ni, and V in most of the analyzed samples do not appear to reach pollution levels. The assessment of the soil environmental quality in the metropolitan area Mexico City in terms of PI can be used as the basis for a regular monitoring program for implementing suitable pollution control measures.     

贵阳城区大气污染物的时空变化和复合污染特征

选取贵阳市10个空气质量监测站发布的PM2.5、PM10、SO2、NO2、CO和O3实时浓度数据，通过时间序列分析法和插值法研究贵阳市大气污染物的时空变化和复合污染特征。结果表明:（1）贵阳市2014-2018年主要污染物PM2.5和PM10的年平均浓度逐渐下降，光化学污染物O3年平均浓度有所增加，空气质量逐渐转好，环境治理取得明显效果；（2）2018-2019自然年PM2.5、PM10、NO2和O3在春季污染最严重，SO2和CO在冬季污染最严重，反映出污染源、阶段性燃料燃烧和二次离子生成等因素对不同污染物的影响不同；（3）PM2.5和PM10日变化特征为“午峰晚峰”型，峰值发生的时间因季节而异，主要由不同季节人类作息的起止时间不同所致，O3日变化为单峰型，夜间O3浓度较低，从早晨8:00点开始随着太阳辐射的增大和温度的升高，在15:00-16:00点左右达到峰值；（4）PM2.5的空间分布呈现出部分郊区和工业区较高，市中心居民区较低的特征，指示城市建设向郊区推进。O3浓度呈现出市区低、郊区高的空间分布特征，反映郊区植被覆盖好，释放的天然源VOCs促进了O3生成；（5）主要污染物O3与颗粒物PM2.5和PM10在春季造成的复合污染最为严重，在夏季O3与PM10造成一定程度的复合污染，在秋冬季O3浓度最低，O3与颗粒物不产生复合污染；一天之内同一时刻O3与颗粒物不会产生叠加从而造成复合污染。      

Hydrochemistry of urban groundwater in Seoul, South Korea: effects of land-use and pollutant recharge

The ionic and isotopic compositions (δD, δ¹⁸O, and ³H) of urban groundwaters have been monitored in Seoul to examine the water quality in relation to land-use. High tritium contents (6.1–12.0 TU) and the absence of spatial/seasonal change of O–H isotope data indicate that groundwaters are well mixed within aquifers with recently recharged waters of high contamination susceptibility. Statistical analyses show a spatial variation of major ions in relation to land-use type. The major ion concentrations tend to increase with anthropogenic contamination, due to the local pollutants recharge. The TDS concentration appears to be a useful contamination indicator, as it generally increases by the order of forested green zone (average 151 mg/l), agricultural area, residential area, traffic area, and industrialized area (average 585 mg/l). With the increased anthropogenic contamination, the groundwater chemistry changes from a Ca–HCO₃ type toward a Ca–Cl(+NO₃) type. The source and behavior of major ions are discussed and the hydrochemical backgrounds are proposed as the basis of a groundwater management plan.     

Relationships between heavy metals and iron oxides,fulvic acids,particle size fractions in urban roadside soils

Urban roadside soils are the “recipients” of large amounts of heavy metals from a variety of sources including vehicle emissions, coal burning waste and other activities. The behavior of heavy metals in urban roadside soils depends on the occurrence as well as the total amount. Accordingly, knowledge of the interactions between heavy metals and other constituents in the soil is required to judge their environmental impact. In this study, correlations of heavy metal concentrations (Pb, Zn, Cu, Ag, Se, Ni, Cr and Ba) to iron extracted using dithionite–citrate–bicarbonate (DCB) buffer (Fe_DCB), fulvic acids and particle size fractions were examined from the Xuzhou urban roadside soils. Heavy metals except for Cr and fulvic acids had a positive significant correlation with Fe_DCB, indicating these metals and fulvic acids are principally associated with the surfaces of iron oxides of the soils. Significant positive correlations were also found between the contents of fulvic acids and heavy metals, showing these heavy metals (especially for Cu, Ni and Cr) form stable complexes with fulvic acids. Such finding is of importance with regard to the increased mobilization of heavy metals, e.g., into freshwater ecosystems. Ag, Se and Cr are independent of particle size fractions because of their low concentrations of Ag and Se in the studied soils. Pb, Zn, Cu, Ba and Ag are mainly enriched in the finer soil particles (especially <16 μm).     

Geochemical studies on urban soil from two sampling depths in Tampere Central Region,Finland

Preliminary geochemical mapping was carried out within urban areas in Tampere Central Region, Finland, to gain a better understanding of element concentrations in urban soil and to provide information on baselines in soil within urban centres for soil contamination assessment purposes. The soil samples were taken from central city parks, day-care centres and school yards, and residential areas. Various sampling depths have generally been used in urban geochemical surveys. The aim of this study was to compare the results from two commonly used sample types taken from the same sites in urban soil: single samples of minerogenic topsoil from the 0–25 cm layer and composite samples of minerogenic topsoil from a depth of 0–2 cm. The concentrations of most of the studied trace elements showed a significant correlation between samples from 0 to 2 and 0 to 25 cm, but element concentrations differed between the two studied sample depths. For most of the studied elements, the median concentrations were higher in the 0–25 cm samples, but anomalous concentrations were more often found in the 0–2 cm samples. Some elements had elevated concentrations when compared with the Finnish guideline values for soil contamination assessment. This study did not conclusively establish whether a sampling depth of 0–2 or 0–25 cm should be recommended for similar studies in the future. Selection of the sampling depth in geochemical studies greatly depends on the aim of the project. In order to determine the upper limits of geochemical baseline variation, the deeper sampling depth appears to be more feasible. However, for the preliminary health risk assessment of areas with sensitive land uses, e.g. children’s playgrounds, samples from 0–2 cm depth are considered informative. Such samples may also be used to indicate local sources of dusting creating site-specific hotspots of potentially harmful elements in urban topsoil.     

Large-scale spatial interpolation of soil pH across the Loess Plateau, China

Soil pH plays an important role in biogeochemical processes in soils. The spatial distribution of soil pH provides basic and useful information relevant to soil management and agricultural production. To obtain an accurate distribution map of soil pH on the Loess Plateau of China, 382 sampling sites were investigated throughout the region and four interpolation methods, i.e., inverse distance weighting (IDW), splines, ordinary kriging, and cokriging, were applied to produce a continuous soil pH surface. In the study region, soil pH values ranged from 6.06 to 10.76, with a mean of 8.49 and a median of 8.48. Land use type had a significant effect (p < 0.01) on soil pH; grassland soils had higher pHs than cropland and forestland soils. From a regional perspective, soil pH showed weak variation and strong spatial dependence, indicated by the low values of the coefficient of variation (0.05) and the nugget-to-sill ratios (<0.25). Indices of cross-validation, i.e., average error, mean absolute error, root mean square error, and model efficiency coefficient were used to compare the performance of the four different interpolation methods. Kriging methods interpolated more accurately than IDW and splines. Cokriging performed better than ordinary kriging and the accuracy was improved using soil organic carbon as an auxiliary variable. Regional distribution maps of soil pH were produced. The southeastern part of the region had relatively low soil pH values, probably due to higher precipitation, leaching, and higher soil organic matter contents. Areas of high soil pH were located in the north of the central part of the region, possibly associated with the salinization of sandy soils under inappropriate irrigation practices in an arid climate. Map accuracy could be further improved using new methods and incorporating other auxiliary variables, such as precipitation, elevation, terrain attributes, and vegetation types.     

Geochemical and mineral magnetic characterisation of urban sediment particulates,Manchester, UK

Urban sediments are part of a complex system in which particulates accumulate potentially toxic pollutants, ultimately posing a threat to urban water-bodies and public health. It is therefore important to recognise sources, signatures and pathways of urban particulates. Urban sediment samples were analysed from both inner and outer city road surfaces of Manchester, UK. High metal concentrations, coupled with the largely ferrimagnetic multi-domain (MD) mineral magnetic composition of the particulates, indicate inputs of anthropogenic origin, primarily particulates derived from automobiles, as being the dominant source to the urban sediment system. Iron and Pb concentrations show a clear spatial trend, whereby concentrations are enhanced in the inner city samples. Lead concentrations for inner and outer city samples average 354 and 185 μg g⁻¹, respectively. Iron concentrations for inner and outer city samples average 11302 and 6486 μg g⁻¹, respectively. Sequential extraction analysis shows the metals Mn, Fe, Zn and Pb are largely associated with the reducible fraction, whereas Cu is largely associated with the oxidisable fraction. Zinc is the only metal showing significant association with the exchangeable fraction (up to 33%), suggesting that it may be the most susceptible metal to mobilisation during runoff. Metal fractions identified as showing larger associations with the reducible and oxidisable fractions will continue to be vulnerable to mobilisation as a result of changes in ambient pH and/or redox conditions. Mineral magnetic concentration parameters, such as the saturation isothermal remanent magnetisation (SIRM), together with hysteresis parameters such as the coercive force and interparametric ratios (such as (B_o)_cr/H_c and IRM_-100mT/SIRM) show that ferrimagnetic MD minerals dominate the Manchester urban sediments. Average results for frequency-dependent susceptibility as a percentage (2%) suggest that the composition of these Manchester sediments is not dominated by soil-derived material, and therefore magnetically coarser, anthropogenically-derived material is dominant. Unlike Pb and Fe concentrations, mineral magnetic characteristics of the Manchester urban sediment samples exhibit no significant spatial variation.     

Relationships between geochemistry of basal till and chemistry of surface soil at forested sites in Finland

Concentrations of several elements extractable with BaCl₂ and acid ammonium acetate (pH 4.65) were measured in the organic and 4 mineral soil layers on the national forest inventory plots of the Finnish Forest Research Institute. The soil data also includes total concentrations of elements in the organic layer and site and soil physical characteristics. Data were compared with the aqua regia extractable element concentrations measured in the nationwide regional till geochemical mapping carried out by the Geological Survey of Finland.Correlations between concentrations in surface soil and underlying basal till were generally highest for K, Mg, Mn, P and Zn; in the organic layer and till they were highest for Cr and Cu. The strength of these correlations did not increase regularly from surface to deeper soil layers. All soil base cations with the exception of Ca, which is of relatively low solubility, were well correlated. The elements Zn, K, P, Al and Mn in till were the most reliable indicators of surface soil chemistry.Fuzzy clustering showed that the correlation between element concentrations in basal till and the two uppermost layers of mineral soil was better within areas of distinct till geochemistry, such as the schist belts in southwestern Finland, the Lake Ladoga–Bothnian Bay zone and the Kuusamo schist belt.Surface soil chemical variables were clearly better in discriminating fertility classes of forest sites than were element concentrations in basal till. The independent ability of till geochemistry to distinguish these productivity classes and to explain surface soil fertility was nevertheless demonstrated.     

Mapping of total nitrogen,available phosphorous and potassium in Amik Plain,Turkey

Soil nitrogen, phosphorous, and potassium concentrations accurately revealed spatial distribution maps and site-specific management-prone areas through inverse distance weighting (IDW) method in the Amik Plain, Turkey. Spatial mapping of soil nitrogen, phosphorous, and potassium is a very severe need to develop an economically and environmentally sound soil management plans. The objectives of this study were (a) to map spatial variability of total N, available P, and exchangeable-K content of Amik Plain’s soils and (b) to locate problematic areas requiring site specific management strategies for the nutrient elements. Spatial analyses of Kjeldhal-N, Olsen-P, and exchangeable-K concentrations of the soils were performed by the IDW method. Mean N content for surface soils (0–20 cm) was 1.38 g kg⁻¹, available P was 28.19 kg ha⁻¹ and exchangeable-K was 690 kg ha⁻¹ with the differences between maximum and minimum being 7.63 g N kg⁻¹, 242 kg P ha⁻¹, and 2,082 kg K ha⁻¹. For the surface soil, site-specific management-prone areas of Kjeldahl-N, Olsen-P, and exchangeable-K for “low and high + very high” classes were found to be 20.1–17.8%, 24.7–10.0%, and 4.1–39.6%, respectively. Consequently, lands with excessive nutrient elements require preventive-leaching practices, whereas nutrient-poor areas need fertilizer applications in favor of increasing plant production.     

Determining the spatial scale of variation in soil radon concentration

Increasing concern about possible links between emissions of radon and certain types of malignant disease has led to local and regional surveys to measure radon concentrations in the soil and in dwellings. The spatial scale at which radon varies is largely unknown, and so efficient sampling schemes and methods of mapping cannot be selected. To determine the spatial scale of radon variation in the English Midlands we measured radon in the soil using solid-state nuclear track detection in three areas of different geological complexity. In two of them we used an unbalanced multistage sampling scheme with seven stages of nesting: the Hereford survey covered distances from 10 m to 7.5 km, and the Buxton survey distances from 1 m to 3.75 km. The results from the nested surveys suggested that geology exerts a strong control on the variation. Finally radon was measured every 20 m along a 2-km long transect which crossed several lithologies close to Nottingham. The soil radon values changed in an erratic way along the transect. The sample variogram of radon has a substantial nugget variance, suggesting that much of the variation occurred for distances less than the sampling interval. The structure at the longer scale seems to be controlled by the underlying geology. These results have implications for designing further surveys and for selecting a method of mapping. Stratification based on lithology might be the only feasible solution to sampling, estimating and mapping radon concentrations over large areas. Where the locally erratic component of variation is large, estimation by kriging, for example, would confer little additional benefit compared with that by classification.     

Seasonal and spatial variations in water chemistry and nitrate sources in six major Korean rivers

Seasonal and spatial variations in water chemistry and contaminant sources were investigated in six major rivers in South Korea that vary widely in drainage area and length. The dissolved-load content of the rivers varied seasonally, and some dissolved ions such as Cl^? and NO₃ ^? showed large spatial differences in all of the rivers. The water type changed from Ca–HCO₃ in the upper reaches to Na–Cl–NO₃ in the lower reaches, indicating anthropogenic contamination in the lower reaches. Compared with two relatively pristine rivers (the Sumjin and Mankyung rivers), the other four rivers, which flow through agricultural and urban areas, registered much higher Cl^? and NO₃ ^? concentrations. Statistical analysis showed that seasonal and spatial variations in water chemistry occurred in all the rivers. The nitrogen and oxygen isotopes of dissolved nitrate indicated that the rivers flowing through urban and agricultural areas were significantly affected by manure, sewage, or both.     

Characterization of ambient aerosols in Northern Thailand and their probable sources

The present study examines variation of ambient aerosol mass and number concentrations in Chiang Mai, Thailand during winter. Aerosol particle samples were collected and measured at four different sites, representative of urban, industrial, residential and rural areas during daytime between December 2003 and January 2004. Average 10 h particulate matter (PM) mass concentrations were found to be in the range of 75–290 ì g/m³, with average value of 149 ± 45 ì g/m³. Urban and industrial areas appeared to have higher PM loading than residential and rural areas. Number concentration and size distribution of particles in the range of 0.3–10.0 ìm did not exhibit any marked variation between sites. Relatively stable number concentrations were reported. Temporal variation of number concentrations was not clearly significant. No short term peak observed during rush hours. During sampling period, the average number concentration for 0.3–0.5, 0.5–1.0, 1.0–5.0 and 5.0–10.0 ìm were 6.60 × 10⁶, 1.18 × 10⁶, 2.11 × 10⁵ and 1.12 × 10⁴/m³, respectively. Particles with diameter smaller than 1.0 ìm accounted for over 90 % of the total number concentration. Concentrations of major metals were determined by atomic absorption spectrophotometer (Pb, Fe, Al, Si, Cr, Cd, Ni, Zn) and flame photometer (K, Na and Ca). Data obtained were used to identify probable sources via a multivariate analysis. Si, Na, Fe, Ca, Al and K were the six dominant elements in the airborne PM. Principle component analysis was carried out and major sources of airborne PM in Chiang Mai were determined, namely, (1) long distance sources such as sea spray, earth soil and industrial combustion, (2) short-distance sources such as crustal re-suspension, vehicular related emissions and vegetation burning, and (3) the unknown distance sources with low influence of traffic emissions.     

Assessment of heavy metals contamination in urban topsoil from Changchun City,China

Due to the rapid urbanization and industrialization that has occurred in China over the last few decades, metals have been continuously emitted into the urban environment and now pose a serious threat to human health. Indeed, there is a growing concern over the potential for pollution of urban soils with heavy metals. Therefore, an extensive soil survey was conducted in urban areas of Changchun, China, to evaluate the current status of heavy metal contamination in soils and to evaluate its potential sources. A total of 352 samples of urban soils were collected from urban areas of Changchun using a systematic sampling strategy in which one sample per km² was taken (0 ~ 20 cm). The levels of Cu, Pb, Zn and the major elements (Mn, Al₂O₃, CaO, Fe₂O₃, MgO, SiO₂, K₂O and NaO) were then determined by X-Ray fluorescence spectrometry (XRF), while the level of Cd was determined by graphite furnace atomic absorption spectrometry (GF-AAS), and the Hg and As concentrations were determined by atomic fluorescence spectroscopy (AFS). The results indicated that, when compared with the background values of topsoil in the Changchun region, the topsoil in urban areas were enriched with metals, particularly Cu, Cd, Zn, Pb and Hg. The results of correlation coefficient analysis showed that Hg, As, Cd, Cu, Pb and Zn were significantly positive correlated with each other, while Cr and Mn formed another group. Moreover, significantly positive correlations were observed between pH and Zn, Pb, Cu, Cd, As and Hg, indicating that pH influences the distributions of these metals in urban soils in Changchun. Principal component analysis (PCA) was conducted to identify sources of heavy metals and the results revealed distinctly different associations among the trace metals and the major elements in the urban soils. The concentration of Cr appeared to be controlled by the parent material (natural sources), while Cu, Pb and Zn were mainly from vehicle emissions, with Zn primarily coming from vehicle tires. Additionally, Hg and As primarily originated from coal combustion, while Cd was mainly associated with industrial sources. According to the pollution index (PI) of each metal, the overall levels of metal pollution were not especially high, but there were clearly contaminated sites concentrated in the central and northeast portion of the studied region. The Nemerow integrated pollution index (NIPI) of the seven metals also indicated that urban soils in Changchun city were classified as having low level of pollution.     

Prioritization of soil conservation measures using erodibility indices as criteria in Sikkim (India)

Erodibility indices are important parameter that can be used to describe the intensity of the soil erosion problems causing environmental concerns. These indices are convenient to estimate the susceptibility to erosion where physical measurement is very difficult. Sikkim is one such state in India where measuring erosion is a tedious process due to its difficult and inaccessible terrain conditions. In the present study, spatial variation of susceptibility of erosion in East district of Sikkim was estimated by using indices such as clay ratio, dispersion ratio, mod clay ratio and critical level of soil organic matter. The result indicates soils in East district are mostly dominated by sand particles (40.5–81.06%) in majority of soil samples. The dispersion ratio values in most of the soils were >15% indicating very high vulnerability to erosion. The values of clay ratio (3.44–9), modified clay ratio (mean value of 6.9) and critical level of soil organic matter content (<5%) indicated high susceptibility to erosion. The trends of indices were generated by IDW interpolation method to understand the spatial variation of the susceptibility to erosion. The interpolated maps were overlaid on subwatershed maps to prioritize the subwatershed for planning treatment measures.     

Spatial distribution of metals in urban topsoils of Xuzhou (China): controlling factors and environmental implications

The contamination of soils by metals from various sources is a subject of increasing concern in recent times. Twenty-eight elements (Fe, Ti, Cr, Al, Ga, Pb, Sc, Ba, Li, Cd, Be, Co, Cu, Mn, Ni, V, Zn, Mo, Pt, Pd, Au, As, Sb, Se, Hg, Bi, Ag and Sn) have been analyzed from urban topsoil from the city of Xuzhou. The concentrations of these analyzed elements have been correlated to some soil parameters such as organic matter, pH, cation exchange capacity, carbonate content, and granulometric fractions (clay, silt and sand). Results of the statistical analysis show a large variety and complexity in these relationships. The spatial distributions of these metal concentrations were also constructed using geographical information system. The spatial distribution patterns of the elements analyzed show that traffic and industrial activities are the principal anthropogenic pollutant sources.     

Distribution of trace elements in waters and sediments of the Seversky Donets transboundary watershed (Kharkiv region,Eastern Ukraine)

This paper reports on the aquatic chemistry of trace elements in terms of spatial and temporal distribution, but also pollution sources in the transboundary watershed of the Seversky Donets River (Ukraine/Russia). Bed sediments and filtered water were collected from the Udy and Lopan Rivers at sites from the river source in the Belgorod region (Russia) to rural and urban areas in the Kharkiv region (Ukraine) in May and August 2009. Priority trace elements (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn), an urban tracer (Ag) and additional metals (Co, Mo, V) and Th were measured in stream water and sediments. The low levels and variability of Th-normalized concentrations indicated the absence of geochemical anomalies in the upstream part of the rivers and suggested that these data represent a regional baseline for trace elements in bed sediments. In contrast, water and sediments within the city of Kharkiv were contaminated by Ag, Pb, Cd, Cu, Cr and Zn, which are mainly attributed to municipal wastewater inputs and urban run-off. Results of the environmental quality assessment showed that element concentrations in the sediments can be considered as potentially toxic to aquatic organisms in sites downstream of the wastewater discharges.     

Analysis of raw soils and their re-suspended PM10 fractions: Characterisation of source profiles and enrichment factors

In this work, the inorganic chemical profiles of soil samples collected at different sites in the Salentum peninsula (Italy, Apulia region) are discussed. The samples were re-suspended in the laboratory, for PM10 sampling, using a ventilated wooden chamber and were then chemically analysed measuring the abundances of 17 elements. Different land use categories of soils (olive grove, arable land, vineyards, sand, and urban dust) were included in the 50 samples analysed: 45 collected in background areas and five collected in the urban area of Lecce. The objectives were to compare the chemical profiles of raw soil and re-suspended PM10 for different crustal sources and to estimate the potential improvements in the calculation of the enrichment factors of atmospheric PM10. The variability of elemental abundances in samples of the same category of soil collected in different zones was of the same order of magnitude as the differences observed between the various categories of soil. This allows the calculation of a weighted average composition of soil and urban dust and the corresponding weighted average composition of re-suspended PM10. In re-suspended PM10 from average background soil, all of the elements except Ca, Na, K and V have larger abundances with respect to raw soil. In urban dust, this is limited to Ca, V and Mg. The crustal enrichment factors (EFs) of atmospheric PM10 were evaluated by considering different reference elements and different reference tables. Results indicated that it is possible to apply a two-threshold (S₁ and S₂) scheme for the interpretation of EF, with thresholds derived from uncertainty in soil categories and from the choice of the reference element. A specific element is likely of crustal origin if EF < S₁ and likely of anthropogenic origin if EF > S₂. Between the two thresholds, the element can be considered of mixed origin. The thresholds vary according to the geological composition used in the evaluation of EF. If the average composition of local re-suspended soils is used, the thresholds are S₁ = 2 and S₂ = 4. If raw soil is used, the thresholds become S₁ = 5 and S₂ = 10. If the average upper-crust composition from literature data is used, the thresholds further increase to S₁ = 10 and S₂ = 20.     

Appraisal and mapping the spatial-temporal distribution of urban road traffic noise

The present study aims to compute the temporal and spatial distribution of road traffic induced noise pollution in an urban environment by monitoring and mapping. The study area was the entire Asansol city of West Bengal, India. A total of 35 locations were selected for collection of data, classified as industrial, commercial, residential, sensitive and mixed areas according to the national regulatory standards. Noise recordings were conducted during morning and night hours. Day time L_eq level ranged between 51.2 and 89.0 dB(A), whereas it ranged between 43.5 and 81.9 dB(A) during night. The average L_dn value was 73.28 ±8.51 dB(A) (Range: 55.1–87.3); The traffic noise index was 80.62 ± 15.88 dB(A) (Range: 49.4–115.8). The computed data were mapped by utilization of Geographic information system methodology that allowed the visualization and identification of the extent and distribution of sound pollution across the study area. This proves to be an ideal tool for carrying out noise impact assessments in urban settings. The study reveals that present noise level in all the locations exceeds the prescribed limit. Based on the finding, it can be mentioned that the population in this industrial town are exposed to significantly high noise level, which is caused mostly due to road traffic. The study reveals that vulnerable establishments like schools and hospitals are subjected to significantly high noise level throughout the day and immediate mitigatory measures are required to alleviate the problem.     

Metal sorption onto soils loaded with urban particulate matter

The potential effect of urban particulate matter (PM) accumulation on metal sorption onto two contrasting soils (Chernozem and Fluvisol) was investigated in a batch sorption experiment. While the Freundlich isotherms did not indicate any effect of PM addition to the soils, the Langmuir isotherm allowed us to estimate the potential behaviour of the PM in the soil. The PM added to the Chernozem did not lead to substantial changes in sorption of Cd, Cu, Mn, Ni, Pb, and Zn. On the contrary, the presence of PM in the Fluvisol increased the number of potential sorption sites in the soil. However, the results of the approximation showed a lower affinity of Cd, Mn and Ni for the Fluvisol and a better stability and a lower bioavailability of these elements in the Chernozem. In the case of Pb and Cu, no significant changes were observed in PM-enriched soils regardless of the soil properties.