Geoelectrical investigation of oil contaminated soils in former underground fuel base: Borne Sulinowo,NW Poland

The survey has been carried out in the area of 0.23 km² of the former military underground fuel base. The oil derivative products were observed in excavations and the laboratory tests confirmed the occurrence of hydrocarbons (>C12) in soils. The purpose of the survey was to determine the spatial extent of the contamination. The studied area is covered by postglacial sediments: sands, gravels and till. The first water table was observed at a depth of 10–12 m. The detailed electromagnetic measurements with Geonics EM31-MK2 conductivity meter were performed in the whole area of the former fuel base. Obtained results were elaborated statistically and the map of apparent electrical conductivity to a depth of 6 m was created. Many local low conductivity anomalies were observed. The measurements with Geonics EM34-3XL were performed along one A–A′ profile and 1D electromagnetic modelling along with this profile was calculated to obtain the electrical conductivity cross-section to a depth of 30 m. Two-dimensional electrical resistivity imaging measurements were carried out along the same profile and the resistivity cross-section to a depth of 20 m was performed. Both conducivity and resistivity cross-sections show anomalous zones. The zones correlate with oil contaminated zones very well.     

Hydrochemical evaluation of groundwater quality in the Çavuşçayı basin, Sungurlu-Çorum, Turkey

The purpose of this study is to investigate the quality and usage possibility of groundwater in the Çavuşçayı basin and suggest the best water structure for the groundwater use. Results from hydrochemical analyses reveal that groundwater is mostly affected by salty (Na⁺–Cl⁻) waters of the Incik Formation and brackish (Ca²⁺, Mg²⁺–SO ₄ ²⁻ ) waters of the Bayındır Formation. The Alibaba saltpan discharged (2 l/s) from the Incik Formation is used for salt production. In the basin, salinity risk increases with depth and along the groundwater flow direction. Therefore, shallow water and trenches opened in the alluvium aquifer at the east of the basin were determined to yield suitable water with no Na⁺ and Cl⁻ contamination. Following the heavy rainy period, waters of less salinity and conductivity are possibly used for agriculture.     

Sedimentary record from Lake Hovsgol, NW Mongolia: Results from the HDP-04 and HDP-06 drill cores

The Hovsgol Drilling Project retrieved Pleistocene sediment section with the basal age of ca. 1 Ma from the Hovsgol rift basin, NW Mongolia. Detailed lithologic data on drill cores is presented and compared with analogous sediment facies in the radiocarbon-dated records of the last glacial–interglacial transition. Drill cores from two sites, presently in 239 m and 235 m water depth, represent somewhat different depositional settings. The shorter HDP-06 drill core (26 m) at the base of the gentler SE slope of the rift basin contains lithologic evidence for several recent lake lowstands on the order of −200 m. The longer HDP-04 drill core (81 m) some 8 km away at the base of the steep NW underwater slope is composed of finer sediments and contains at least 10 characteristic transitions from calcareous to carbonate-free (diatomaceous) layers. These lithologic transitions are interpreted here as signals of repeated Pleistocene lake transgressions in the Hovsgol basin. Transgressions appear to have been associated with lower sedimentation rates and with the deposition of thin turbidite beds at the drill site. Comparison of drill core lithology with the available seismic data shows reasonable agreement in terms of the number of lowstand events and the general trends of changing lake level. HDP-04 drill core retrieved shallow-water facies containing sand and carbonate oolites deposited at the time of the most dramatic mid-Pleistocene regression of the lake. At ca. 24 m core depth, this interval corresponds to a major basinwide angular unconformity apparent in the seismic pattern. Lake Hovsgol, a smaller sister rift lake of the grand Lake Baikal, has a confined local catchment, which makes it very sensitive to regional variations in the effective moisture. Consisting primarily of calcareous mud, the sedimentary record of Lake Hovsgol provides a unique regional sedimentary archive. Future multi-proxy studies of the Hovsgol sedimentary records will allow constraint of the mid-late Pleistocene history of the hydrologic budget in the Baikal region of continental interior Asia.     

Evaluation of oxygen isotopes in carbonate as an indicator of lake evolution in arid areas: The modern Qinghai Lake, Qinghai–Tibet Plateau

The oxygen isotopic composition of carbonate in lakes has been used as a useful indicator in Palaeolimnological research, and has made some important contributions to our understanding of lacustrine systems. For modern lakes in arid or cold areas, however, there are few data available to test the effect of lake salinity and temperature on the oxygen isotopic composition of various carbonate sources such as ostracod, bulk carbonate, and fine-grained carbonate (< 60 μm). Here we examined the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonates, as well as that of coexisting water from Lake Qinghai and the smaller surrounding lakes and ponds on the Qinghai–Tibet Plateau. Our investigation highlights three key effects. First, the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonate in the lakes and ponds shows a clear response to lake water δ¹⁸O values, and these vary with water salinity. The relationship between lake water δ¹⁸O and salinity is not only dominated by the evaporation/freshwater input ratios, but is also controlled by the distance to the mouth of the major rivers supplying to the lake. Second, the ostracod, bulk carbonate, and fine-grained carbonate show similar isotopic change trends in the study area, and oxygen isotopic differences between ostracods and authigenic carbonate may be explained by the different water temperatures and very small ‘vital offsets’ of ostracods. Finally, the effect of water depth on temperature leads to increasing δ¹⁸O values in carbonates as water depth increases, both in benthic ostracods living on the lake bottom, as well as in bulk carbonate precipitated at the water surface.For arid, high-altitude Lake Qinghai, our results suggest that variations in the δ¹⁸O values of carbonate in Lake Qinghai are mainly controlled by the oxygen-isotope ratio of the lake water changing with water salinity. As a secondary effect, increasing water depth leads to cooler bottom and surface water, which may result in more positive δ¹⁸O values of ostracod and bulk carbonate.     

Relationship between conductivity and analysed composition in a large set of natural surface-water samples, Queensland, Australia

 The relationship between Total Dissolved Ions (TDI) and conductivity is established in around 34000 samples collected from rivers, streams and dams in Queensland since the 1960s. These data are extremely variable in content, reliability and periodicity of sampling. The data were sorted into useable modules, and their statistical distribution was examined. The median ratios of TDI/Conductivity obtained for different salinity ranges were between 0.59 and 0.72, with normal variability ranging from below 0.35 to greater than 1.00, particularly at lower salinities. The data set used has sufficient sample numbers and areal distribution per increment to give reasonable reliability within the conductivity range of 50–1000 μScm^–1. A table has been developed that enables selection of conversion factors from conductivity to salinity (as TDI) which could be used to predict TDI from future conductivity measurements from the same surface water population. Received: 30 October 1998 · Accepted: 17 May 1999     

A geological and hydrogeological assessment of the electrical conductivity information from the HiRES airborne geophysical survey of the Isle of Wight

A recent high resolution airborne geophysical survey across the Isle of Wight (IoW) and Lymington area has provided the first electromagnetic data across the relatively young geological formations characterising much of southern England. The multi-frequency data provide information on bulk electrical conductivity to depths of the order of 100 m. A GIS-based assessment of the electrical conductivity information in relation to bedrock geological classification has been conducted for the first time. The analysis uses over 104,000 measurements across onshore IoW and has established average and statistical properties as a function of bedrock geology. The average values are used to provide baseline maps of apparent electrical conductivity and the variation with depth (measured as a function of frequency). The average conductivity as a function of depth within the main aquifer units is summarised. The data indicate that the majority of the Palaeogene is characterised by values consistently in excess of 100 mS/m and with a surprisingly high degree of spatial heterogeneity. The youngest (Oligocene) Hamstead Member displays some strong edge effects and the largest localized values in conductivity. The central Upper Chalk is associated with the lowest observed conductivity values and mineral content and/or porosity appears to increase with increasing age. The large central outcrop of the Lower Greensand Group, Ferruginous Sand Formation provides persistently low (<30 mS/m) conductivity values which imply a relatively uniform distribution of clean sand content. Non-geological (e.g. environmental) responses are contained within the data set and examples of these in relation to a closed municipal landfill and an area of potential coastal saline intrusion are discussed. In the south, the Gault clay/mudstone of the Early Cretaceous appears as a distinctive conductive unit. Cross sectional modelling of the data has been undertaken across the aquifer units of the Southern Downs. The results indicate that the Gault Formation, acting as an aquitard, can be traced as a distinct unit under the more resistive Early Cretaceous Upper Greensand and Late Cretaceous Chalk formations. The conductivity modelling should therefore allow an estimation of the subsurface configuration of the aquifer and aquitard units.     

An empirical model for estimating hydraulic conductivity of highly disturbed clastic sedimentary rocks in Taiwan

This paper presents the establishment of an empirical HC model for estimating rock mass hydraulic conductivity of highly disturbed clastic sedimentary rocks in Taiwan using high-resolution borehole acoustic televiewer and double packer hydraulic tests. Four geological parameters including rock quality designation (RQD), depth index (DI), gouge content designation (GCD), and lithology permeability index (LPI) were adopted for establishing the empirical HC model. To verify rationality of the proposed HC model, 22 in-situ hydraulic tests were carried out to measure the hydraulic conductivity of the highly disturbed clastic sedimentary rocks in three boreholes at two different locations in Taiwan. Besides, the model verification using another borehole data with four additional in-situ hydraulic tests from similar clastic sedimentary rocks was also conducted to further verify the feasibility of the proposed empirical HC model. The field results indicated that the rock mass in the study area has a conductivity between the order of 10^− 10 m/s and 10^− 6 m/s at the depth between 34 m and 275 m below ground surface. Results demonstrate that the empirical HC model may provide a useful tool to predict hydraulic conductivity of the highly disturbed clastic sedimentary rocks in Taiwan based on measured HC-values.     

Joint use of TEM and MRS methods in a complex geological setting

Transient Electromagnetic (TEM), known also as Time Domain Electromagnetic (TDEM) and Magnetic Resonance Sounding (MRS) methods were applied jointly to investigate variations in lithology and groundwater salinity in the Nahal Hever South area (Dead Sea coast of Israel). The subsurface in this area is highly heterogeneous and composed of intercalated sand and clay layers over a salt formation, which is partly karstified. Groundwater is very saline, with a chloride concentration of 100–225 g/l. TEM is known as an efficient tool for investigating electrically conductive targets like saline water, but it is sensitive to both the salinity of groundwater and the porosity of rocks. MRS, however, is sensitive primarily to groundwater volume, but it also allows delineating of lithological variations in water-saturated formations. MRS is much less sensitive to variations in groundwater salinity in comparison with TEM. We show that MRS enables us to resolve the fundamental uncertainty in TEM interpretation caused by the equivalence between groundwater resistivity and lithology. Combining TEM and MRS, we found that the sandy Dead Sea aquifer filled with Dead Sea brine is characterized by a bulk resistivity of ρ_x > 0.4 Ωm, whereas zones with silt and clay in the subsurface are characterized by a bulk resistivity of ρ_x < 0.4 Ωm. These observations are confirmed by calibration of the TEM method performed near 18 boreholes.     

Nutrient chemistry and salinity mapping of the Delhi aquifer,India: source identification perspective

Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na⁺/Cl⁻, SO₄ ²⁻/Cl⁻, Mg²⁺/Ca²⁺ and Ca²⁺/(HCO₃ ⁻ + SO₄ ²⁻) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO₃ ⁻ contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.     

Chemical and physical parameters as trace markers of anthropogenic-induced salinity in the Agua Amarga coastal aquifer (southern Spain)

Agua Amarga coastal aquifer in southern Spain has been the subject of chemical and physical measurements since May 2008 in order to monitor the potential effects of water withdrawal for the Alicante desalination plants on the salt marsh linked to the aquifer. Electrical conductivity contour maps and depth profiles, piezometric-head contour maps, hydrochemical analyses, isotopic characterizations and temperature depth profiles show not only the saltwater intrusion caused by water abstraction, but also the presence of a pronounced convective density-driven flow below the salt marsh; this flow was a consequence of saltwork activity in the early 1900s which generated saline groundwater contamination. The influence of a seawater recharge programme, carried out over the salt marsh in 2009–2010, on the diminishing groundwater salinity and the recovery of groundwater levels is also studied. Based on collected field data, the project provides a deeper understanding of how these successive anthropogenic interventions have modified flow and mixing processes in Agua Amarga aquifer.     

Delineation of saltwater intrusion into the freshwater aquifer of Lekki Peninsula,Lagos, Nigeria

Recently, the deterioration of water quality in the coastal zones of Lekki Peninsula area of Lagos due to saltwater infiltration into the freshwater aquifer has become a major concern. With the aim of providing valuable information on the hydrogeologic system of the aquifers, the subsurface lithology and delineating the groundwater salinity, vertical electrical resistivity (VES) sounding survey was carried out utilizing surface Schlumberger electrode arrays, and electrode spacing varying between 1 and 150 m. The DC resistivity surveys revealed significant variations in subsurface resistivity. Also, the VES resistivity curves showed a dominant trend of decreasing resistivity with depth (thus increasing salinity). In general, the presence of four distinct resistivity zones were delineated viz.: the unconsolidated dry sand (A) having resistivity values ranging between 125 and 1,028 Ωm represent the first layer; the fresh water-saturated soil (zone B) having resistivity values which correspond to 32–256 Ωm is the second layer; the third layer (zone C) is interpreted as the mixing (transition) zone of fresh with brackish groundwater. The resistivity of this layer ranges from 4 to 32 Ωm; while layer four (zone D) is characterized with resistivities values generally below 4 Ωm reflecting an aquifer possibly containing brine. The rock matrix, salinity and water saturation are the major factors controlling the resistivity of the formation. Moreover, this investigation shows that saline water intrusion into the aquifers can be accurately mapped using surface DC resistivity method.     

Frequency-domain electromagnetic sensing of leaching in a Californian substratum

Frequency-domain electromagnetic sensing can be an effective tool for ascertaining subsurface water dynamics. In California, the paucity of available irrigation water, recurrence of drought and presence of indigenous salts within the geological parent materials affect crop health. Subsurface leaching variability analyses were performed using dual dipolar induction surveys and stochastic computations to determine salinity conditions conducive to plant growth. Soils in the study area had randomly variable salinity with elevated salt levels within the substratum. The salinity values were mostly above 300 mS m^?1 and some areas exceeded the 1500 mS m^?1 level. The leaching conditions across the fields varied generally from 5 to 50%. Both variables showed slightly positive skewness with minutely asymmetrical tailing. The salinity distribution had less peakedness than the leaching distribution. Albeit with spatially dependent variability and skewness, the distribution patterns had low errors. There was a strong and significant correlation (r?=?0.939 at P?<?0.05) between the observed and predicted conductivity data. The leaching variables exhibited directional dependence along vertical and horizontal gradients. Spatial increase in salinity within the substratum conformed to salt leaching and water percolation processes. All observed salinity values within the substratum exceeded salt tolerance threshold limits for major crops and favorable leaching conditions were observed at low salinity levels. Sustainability of agriculture in California is heavily dependent on adequate water use planning and our approach of leaching variability analyses can facilitate water management and crop production by assessing removal of superfluous salts from the soil substratum.     

Physical and chemical properties of the waters of saline lakes and their importance for deep-water renewal: Lake Issyk-Kul, Kyrgyzstan

The relationships between electrical conductivity, temperature, salinity, and density are studied for brackish Lake Issyk-Kul. These studies are based on a newly determined major ion composition, which for the open lake shows a mean absolute salinity of 6.06 g kg⁻¹. The conductivity-temperature relationship of the lake water was determined experimentally showing that the lake water is about 1.25 times less conductive than seawater diluted to the same absolute salinity as that of the lake water. Based on these results, an algorithm is presented to calculate salinity from in-situ conductivity measurements. Applied to the field data, this shows small but important vertical salinity variations in the lake with a salinity maximum at 200 m and a freshening of the surface water with increasing proximity to the shores. The algorithm we adopt to calculate density agrees well with earlier measurements and shows that at 20°C and 1 atm Lake Issyk-Kul water is about 530 g m⁻³ denser than seawater at the same salinity. The temperature of maximum density at 1 atm is about 0.15°C lower than that for seawater diluted to the same salinity. Despite its small variations, salinity plays an important role, together with temperature changes, in the static stability and in the production of deep-water in this lake. Changes in salinity may have had important consequences on the mixing regime and the fate of inflowing river water over geological time. Uncharged silicic acid is negligible for the stability of the water column except near an ∼15 m thick nepheloid layer observed at the bottom of the deep basin.     

Hydraulic conductivity distribution in crystalline rocks, derived from inflows to tunnels and galleries in the Central Alps, Switzerland

Inflow data from 23 tunnels and galleries, 136 km in length and located in the Aar and Gotthard massifs of the Swiss Alps, have been analyzed with the objective (1) to understand the 3-dimensional spatial distribution of groundwater flow in crystalline basement rocks, (2) to assess the dependency of tunnel inflow rate on depth, tectonic overprint, and lithology, and (3) to derive the distribution of fracture transmissivity and effective hydraulic conductivity at the 100-m scale. Brittle tectonic overprint is shown to be the principal parameter regulating inflow rate and dominates over depth and lithology. The highest early time inflow rate is 1,300 l/s and has been reported from a shallow hydropower gallery intersecting a 200-m wide cataclastic fault zone. The derived lognormal transmissivity distribution is based on 1,361 tunnel intervals with a length of 100 m. Such interval transmissivities range between 10^?9 and 10^?1 m²/s within the first 200–400 m of depth and between 10^?9 and 10^?4 m²/s in the depth interval of 400–1,500 m below ground surface. Outside brittle fault zones, a trend of decreasing transmissivity/hydraulic conductivity with increasing depth is observed for some schistous and gneissic geological units, whereas no trend is identified for the granitic units.     

Positive correlation between salinity and n-alkane δ13C values in the mangrove Avicennia marina

Carbon isotope ratio (δ¹³C) values of lipid biomarkers from plants can be used to assess water use efficiency and to reconstruct environmental conditions in the past. We assessed the effect of salinity on the δ¹³C values for leaf wax n-C₃₁ and n-C₃₃ alkanes, bulk leaf matter and leaf total lipid extracts from Avicennia marina (gray mangrove) trees growing along the Brisbane River estuary in Queensland, Australia. We observed an increase in 0.19 ± 0.053‰ (R² 0.61, p 0.008) and 0.16 ± 0.052‰ (R² 0.55, p 0.01) per salinity unit for the two n-alkanes, respectively, and of 0.087 ± 0.028‰ (R² 0.41, p 0.009) for whole leaves per salinity unit, indicating that water use efficiency of A. marina increased with the salt content of water. There was no correlation between δ¹³C values of total lipid extracts and salinity, perhaps because of a decrease in lipid concentration at higher salinity or because of varying contributions of different lipid classes to the extract. The robust relationship between salinity and δ¹³C values of leaf wax lipids provides a means of quantitatively reconstructing past salinity from carbon isotope ratios of mangrove lipid biomarkers in sediments. When paired with measurements of the hydrogen isotope ratio values of the same compounds, the approach should facilitate quantitative reconstruction of the hydrogen isotope composition of environmental water. In order for the method to successfully reconstruct past salinity and water isotopes, a mangrove source for leaf wax would need to be confirmed by palynological or other evidence, or the isotopic composition of a more source specific biomarker, such as taraxerol, would need to be measured.     

Hydrogeochemical and isotopic constraints on the origins of dryland salinity,Murray Basin,Victoria, Australia

Combined hydrogeological and hydrogeochemical data allow flow systems and the origins of solutes in the Honeysuckle Creek area of the southeastern Murray Basin, which is an area affected by dryland salinity, to be constrained. Recharge occurs both on the uplands that are composed of fractured Violet Town Volcanic rocks and the Riverine Plain that comprises sediments of the Shepparton and Coonambidgal Formations. Groundwater from the Violet Town Volcanics has low salinity (<20 mmol/L Cl) and major ion geochemistry that is controlled largely by dissolution of silicate minerals. Low Cl/Br ratios (as low as 281 molar) suggest that this groundwater has not dissolved halite. Groundwater that recharged through the Riverine Plain sediments has higher Cl/Br ratios (up to 1146) and Cl concentrations of <20 mmol/L, consistent with it dissolving minor halite. Higher salinity (>20 mmol/L) groundwater has intermediate Cl/Br ratios (600–1000), which indicate that the high salinities do not simply result from halite dissolution. Rather, mixing of groundwater homogenises Cl/Br ratios, and evaporation as a consequence of a shallow water table is the dominant process that increases salinity. Oxygen and H isotopes also indicate that mixing and evaporation have occurred. These results indicate that land use over the whole region, not just the uplands, needs to be considered in any salinity management plans. Additionally future development of salinity is controlled by depth to the water table on the plains and the efficiency of recharge rather than by salt stores (halite or brines) in the unsaturated zone.     

‘PALEOVAN’, International Continental Scientific Drilling Program (ICDP): site survey results and perspectives

Lake Van is the fourth largest terminal lake in the world (volume 607 km³, area 3570 km², maximum depth 460 m), extending for 130 km WSW–ENE on the Eastern Anatolian High Plateau, Turkey. The sedimentary record of Lake Van, partly laminated, has the potential to obtain a long and continuous continental sequence that covers several glacial–interglacial cycles (ca 500 kyr). Therefore, Lake Van is a key site within the International Continental Scientific Drilling Program (ICDP) for the investigation of the Quaternary climate evolution in the Near East (‘PALEOVAN’). As preparation for an ICDP drilling campaign, a site survey was carried out during the past years. We collected 50 seismic profiles with a total length of ～850 km to identify continuous undisturbed sedimentary sequences for potential ICDP locations. Based on the seismic results, we cored 10 different locations to water depths of up to 420 m. Multidisciplinary scientific work at positions of a proposed ICDP drill site included measurements of magnetic susceptibility, physical properties, stable isotopes, XRF scans, and pollen and spores. This core extends back to the Last Glacial Maximum (LGM), a more extended record than all the other Lake Van cores obtained to date. Both coring and seismic data do not show any indication that the deepest part of the lake (Tatvan Basin, Ahlat Ridge) was dry or almost dry during past times. These results show potential for obtaining a continuous undisturbed, long continental palaeoclimate record. In addition, this paper discusses the potential of ‘PALEOVAN’ to establish new results on the dynamics of lake level fluctuations, noble gas concentration in pore water of the lake sediment, history of volcanism and volcanic activities based on tephrostratigraphy, and paleoseismic and earthquake activities.     

Shallow groundwater dynamics and origin of salinity at two sites in salinated and water-deficient region of North China Plain,China

Large salinated areas are distributed in the middle and east of the North China Plain (NCP), where the fresh water shortage is serious. In this study, two sites in Cangzhou (CZ) and Hengshui (HS) of Hebei Province were selected to study the dynamics of shallow groundwater level and salinity. Electrical conductivity (EC) of groundwater was combined with the isotope compositions of δ¹⁸O and δ²H to identify the origin of salinity. Results showed that the dynamics of groundwater level at both sites were mainly controlled by precipitation and evaporation. Soil texture and structure played a significant role in the dynamics of salinity. The summer precipitation diluted the EC of groundwater at the HS site with homogeneous soil of sand loam, suggesting the larger infiltration rate; however, it did not dilute the EC at the CZ site with heterogeneous soil of sand loam and silt loam, suggesting that the summer precipitation could not recharge the groundwater directly. In winter, the EC decreased rapidly due to the temperature gradient underground if the groundwater was above the threshold level (at least 3 m below the ground surface) after the rainy season. Isotopes of δ¹⁸O and δ²H showed that precipitation was the major recharge source for the groundwater at the two sites. The salt mainly comes from the dissolution of soil or rock at the CZ site. While, the evaporation effect was strong at the HS site leading to the increase of the salt concentration.     

Autocompaction of shallow silty salt marsh clay

Empirically derived algorithms are suggested by means of which it is possible to evaluate relations between physical properties in silty salt marsh clay. A relation between loss on ignition, sand content and bulk dry density in the topmost 5 cm was found to explain 84% of the variation of the latter. The bulk dry density in the topmost ≈ 0.5 m was found to vary as a logarithmic function of depth below the surface controlled by two constants directly dependent on the bulk dry density in the topmost 5 cm. Integration of this function illustrates that mass depth (MSD_z) down core can be directly related to the bulk dry density of the surface layer. For sediments with a surface bulk dry density between 400 kg m^? 3 and 800 kg m^? 3 the porosity was found to vary (+/?10%) with MSD_z as another logarithmic function. The results allow for an evaluation of the use of marker horizons in the topmost layers. Right after such a layer has been spread on the surface, sedimentation measured in length per time (accretion), will be significantly larger than for subsequent periods. Using marker horizons, it is therefore not trivial to know the level of the marker, as deeper located markers will indicate successively smaller accretion rates with the same sediment input.