Spectral Analysis of Turbulent Aerosol Fluxes by Fourier Transform,Wavelet Analysis,and Multiresolution Decomposition

Aerosol number fluxes are spectrally analyzed using fast Fourier transform analysis, wavelet analysis and multiresolution decomposition. All three methods yield similar spectral features in general, although a detailed evaluation of the cospectra shows some differences, e.g. due to different resolutions in the time and frequency domains. Wavelet analysis yields aerosol flux estimates with a high time resolution that can be used to assess the flux variability. Multiresolution decomposition has been applied successfully to evaluate cospectra of the aerosol number flux, the buoyancy flux and the momentum flux of three 1-day datasets from diverse environments. For all scalars and all environments, the dimensionless frequency (f) of the cospectral peak was found between $f = 0.1$ and 0.2. In addition, the cospectral gap time scale of the aerosol number flux was found between 100 and 1,000 s. Thus, in this study several spectral features such as the dominant time scale and the cospectral gap time scale of aerosol number fluxes are similar to buoyancy fluxes. However, the shape of aerosol number flux cospectra often deviates from buoyancy and momentum flux cospectra, especially at very small and at very large time scales.     

黄土高原复杂地形受中尺度运动影响的稳定边界层湍流特征

利用兰州大学半干旱气候与环境观测站(Semi-Arid Climate and Environment Observatory of Lanzhou University,简称SACOL)2008年12月观测资料,研究了稳定边界层湍流特征.使用涡动相关资料研究湍流通量时,定义湍流的平均时间τ内的中尺度运动是造成湍流统计量变化范围大的主要原因,稳定情形? τ取几十秒至几分钟.对梯度理查森数大于0.3的强稳定情形的湍流尺度分解(MRD)谱分析表明,感热通量在112.4～449.9 s存在谱隙,尺度大于谱隙的中尺度运动造成了通量观测资料离散性大,甚至有支配性影响.动量通量的谱隙在112.4～224.9 s之间.弱风时,中尺度运动的影响更大,垂直风速标准差以0.1的比率随中尺度风速变化;垂直风速标准差同广义风速表现出很好的相关性,并随着广义风速消失而消失.三维风速标准差与摩擦速度呈很好的线性关系,垂直、水平、横风风速的无量纲标准差分别为1.35、2.54、2.21.对湍流动能的研究发现,在梯度理查森数大于0.3的条件下,仍然存在连续的湍流.以湍动能为依据,分析了湍流的平稳时间长度,其长度随稳定度变化而变化,2008年12月7～11日从133.5 s变化到856.2 s,湍流平稳时间长度反映了中尺度运动的发生频率.     

珠海凤凰山森林下垫面干季和湿季气象要素的对比分析与动量和感热交换系数的参数化研究

利用珠海凤凰山陆气相互作用观测塔站2014年11月至2016年5月的观测数据,对比分析了干湿季森林下垫面能量通量和气象要素的变化特征,分析了在不同稳定度下3个风向范围（315°～45°、45°～135°和135°～225°）的动量和感热交换系数随冠层表面风速的变化特征,并对动量和感热交换系数进行了参数化研究。结果表明:干季感热和潜热通量值相当,湿季潜热远大于感热。干季和湿季的夜晚都出现负感热现象,感热从大气向森林输送。相对湿度的变化幅度大,与该地气象状况密切相关,相对湿度的垂直梯度夜晚较大,白天较小。干季的气温垂直梯度比湿季的明显。风速在冬季变化平缓,夏季变化剧烈,低层风速随高度变化梯度明显,高层较紊乱。各高度风向差异不大。中性和近中性状态下,在风向为315°～45°、45°～135°和135°～225°时,动量交换系数C_dn分别为0.05、0.0055和0.022,感热交换系数C_hn分别为0.0055、0.003和0.004。在稳定和不稳定状态下,动量交换系数C_d、感热交换系数C_h随冠层表面风速v明显发生变化,稳定条件下,C_d、C_h随v的增大而增大;不稳定条件下,C_d、C_h随v的增大而减小。分不同风向对森林冠层C_d、C_h在稳定和不稳定条件下与v的关系进行了拟合,得到了参数化公式。     

Turbulence measurements above a pine forest

Eddy fluxes of momentum, sensible and latent heat, and turbulence spectra measured over the Thetford Forest during 10 days in the Spring of 1973 are described. The measured total heat flux (H + E) for 122 20-min periods agreed closely on average with independent estimates from an energy balance method. There was evidence that the energy balance data gave small systematic overestimates of available energy during the hours before noon, compensated by slight underestimates for the remainder of the day. A comparison of measured wind speeds and friction velocities in neutral stability confirmed the validity of the aerodynamic method for estimating momentum fluxes at heights of a few roughness lengths above the canopy. In stable conditions the log-linear wind profileU = (u _*/k)(ln ((z -d)/z _o) + (z -d -z _o)/L) with = 3.4 ± 0.4 provided a good fit to the data. Spectra in unstable conditions were generally more sharply peaked than those measured by other workers over smoother terrain: differences were less marked in the case of vertical velocity in stable conditions. Temperature spectra in these stable conditions showed high energy at relatively low wavenumbers, andwT cospectra showed a cospectral gap; both of these results were associated with an intermittent sawtooth structure in the temperature fluctuations.Now at the Meteorological Office, Bracknell     

Spectral Characteristics and Correction of Long-Term Eddy-Covariance Measurements Over Two Mixed Hardwood Forests in Non-Flat Terrain

We present turbulence spectra and cospectra derived from long-term eddy-covariancemeasurements (nearly 40,000 hourly data over three to four years) and the transferfunctions of closed-path infrared gas analyzers over two mixed hardwood forests inthe mid-western U.S.A. The measurement heights ranged from 1.3 to 2.1 times themean tree height, and peak vegetation area index (VAI) was 3.5 to 4.7; the topographyat both sites deviates from ideal flat terrain. The analysis follows the approach ofKaimal et al. (Quart. J. Roy. Meteorol. Soc. 98, 563–589, 1972) whose results were based upon 15 hours of measurements atthree heights in the Kansas experiment over flatter and smoother terrain. Both thespectral and cospectral constants and stability functions for normalizing and collapsingspectra and cospectra in the inertial subrange were found to be different from those ofKaimal et al. In unstable conditions, we found that an appropriate stabilityfunction for the non-dimensional dissipation of turbulent kinetic energy is of the form ₍₎ = (1 - b^-)^-1/4 - c^-, where representsthe non-dimensional stability parameter. In stable conditions, a non-linear functionG_xy() = 1 + b_xy^c _xy (c_xy < 1) was found to benecessary to collapse cospectra in the inertial subrange. The empirical cospectralmodels of Kaimal et al. were modified to fit the somewhat more (neutraland unstable) or less (stable) sharply peaked scalar cospectra observed over forestsusing the appropriate cospectral constants and non-linear stability functions. Theempirical coefficients in the stability functions and in the cospectral models varywith measurement height and seasonal changes in VAI. The seasonal differencesare generally larger at the Morgan Monroe State Forest site (greater peak VAI) andcloser to the canopy.The characteristics of transfer functions of the closed-path infrared gas analysersthrough long-tubes for CO₂ and water vapour fluxes were studied empirically. This was done by fitting the ratio between normalized cospectra of CO₂ or watervapour fluxes and those of sensible heat to the transfer function of a first-order sensor.The characteristic time constant for CO₂ is much smaller than that for water vapour. The time constant for water vapour increases greatly with aging tubes. Three methods were used to estimate the flux attenuations and corrections; from June through August, the attenuations of CO₂ fluxes are about 3–4% during the daytime and 6–10% at night on average. For the daytime latent heat flux (Q_E), the attenuations are foundto vary from less than 10% for newer tubes to over 20% for aged tubes. Correctionsto Q_E led to increases in the ratio (Q_H + Q_E)/(Q^* - Q_G) by about 0.05 to0.19 (Q_H is sensible heat flux, Q^* is net radiation and Q_G is soil heat flux),and thus are expected to have an important impact on the assessment of energy balanceclosure.     

Turbulence spectra in the near-neutral surface layer over the Loess Plateau in China

We present the power spectra of wind velocity and the cospectra of momentum and heat fluxes observed for different wind directions over flat terrain and a large valley on the Loess Plateau. The power spectra of longitudinal (u) and lateral (v) wind speeds satisfy the −5/3 power law in the inertial subrange, but do not vary as observed in previous studies within the low frequency range. The u spectrum measured at 32 m height for flow from the valley shows a power deficit at intermediate frequencies, while the v spectrum at 32 m downwind of the valley reaches another peak in the low frequency range at the same frequency as the u spectrum. The corresponding peak wavelength is consistent with the observed length scale of the convective outer layer at the site. The v spectrum for flat terrain shows a spectral gap at mid frequencies while obeying inner layer scaling in its inertial subrange, suggesting two sources of turbulence in the surface layer. All the spectra and cospectra from the valley direction show a height dependency over the three levels.     

Scaling Properties of Temperature Spectra and Heat-Flux Cospectra in the Surface Friction Layer Beneath an Unstable Outer Layer

Temperature variance and temperature power spectra in the unstable surface layer have always presented a problem to the standard Monin-Obukhov similarity model. Recently that problem has intensified with the demonstration by Smedman et al. (2007, Q J Roy Meteorol Soc 133: 37–51) that temperature spectra and heat-flux cospectra can have two distinct peaks in slightly unstable conditions, and by McNaughton et al. (2007, Nonlinear Process Geophys 14: 257–271) who showed that the wavenumber of the peak of temperature spectra in a convective boundary layer (CBL), closely above the surface friction layer (SFL), can be sensitive to the CBL depth, z _i. Neither the two-peak form at slight instability nor the dependence of peak position on z _i at large instability is compatible with the Monin-Obukhov model. Here we examine the properties of temperature spectra and heat-flux cospectra from between these extremes, i.e. from within the unstable SFL, in two experiments. The analysis is based on McNaughton’s model of the turbulence structure in the SFL. According to this model, heat is transported through most of the SFL by sheet plumes, created by the action of impinging outer eddies. The smallest and most effective of these outer eddies have sizes that scale on SFL depth, z _s. The z _s-scale eddies and plumes are organised within the overall convection pattern in the CBL, and in turn they organise the motion of smaller eddies within the SFL, whose sizes scale on height, z. The main experimental results are: (1) the peak amplitudes of the temperature spectra in the SFL are collapsed with a scaling factor (z_sz)^1/3e_o^2/3{(z_{\rm s}z)^{1/3}\varepsilon_{\rm o}^{2/3}} divided by the square of the surface temperature flux, where e_o{\varepsilon_{\rm o}} is the dissipation rate of turbulent energy in the outer CBL (above the SFL); (2) the peak wavenumbers of the temperature spectra are collapsed with the mixed length scale (z _i z _s)^1/2; (3) the peak wavenumbers of the heat-flux cospectra are collapsed with the doubly-mixed length scale (z _i z _s)^1/4 z ^1/2; (4) for z/z _s < 0.03, the peak in the cospectrum is replaced by another peak at a wavenumber about a magnitude larger. This peak’s position scales on z; (5) all these findings are consistent with the observations of Smedman et al.     

Discrepancy and Applicability of Various Similarity Functions in Flux Calculations Under Stable Conditions

Based on data obtained during the Hualhe River Basin Experiment （HUBEX） in 1999, this study intends to detect the quantitative discrepancies in the momentum （τ0）, sensible heat （H0） and latent heat （E0） fluxes among six sets of similarity functions with the aerodynamic method. It also aims to clarify the applicability of the functions under stable conditions. The relative discrepancy was studied with the normalized transfer coefficients for τ0, H0 and E0, namely CD, CH and CQ, respectively. Except for one set of functions that adopted a rather small von Kármán＇s constant （0.365）, the relative discrepancy in τ0 among the other functions was less than 10%, while that in H0（E0） sometimes reached 25% when the bulk Richardson number （R/B） was less than 0.07. The absolute discrepancy in the fluxes was studied with statistical computations. Among the six sets of functions, the discrepancy in τ0, H0 and E0 sometimes reached 0.03 kg m^-1 s^-2, 4 W m^-2 and 10 W m^-2, respectively, and the discrepancy in the energy balance ratio sometimes exceeded 0.1. Furthermore, when RiB exceeded the critical value （Ric） for a specific set of functions, no fluxes could be derived with the functions. It is therefore suggested that RiB be compared with Ric before computing the fluxes if RiB is less than Ric. Finally, two sets of nonlinear similarity functions are recommended, due to their unlimited applicability in terms of RiB.     

A Simple Model for the Vertical Transport of Reactive Species in the Convective Atmospheric Boundary Layer

We have developed a simple, steady-state, one-dimensional second-order closure model to obtain continuous profiles of turbulent fluxes and mean concentrations of non-conserved scalars in a convective boundary layer without shear. As a basic tool we first set up a model for conserved species with standard parameterizations. This leads to formulations for profiles of the turbulent diffusivity and the ratio of temperature-scalar covariance to the flux of the passive scalar. The model is then extended to solving, in terms of profiles of mean concentrations and fluxes, the NO _x –O₃ triad problem. The chemical reactions involve one first-order reaction, the destruction of NO₂ with decay time τ, and one second-order reaction, the destruction of NO and O₃ with the reaction constant k. Since the fluxes of the sum concentrations of NO _x = NO + NO₂ and O₃ + NO₂ turn out to be constant throughout the boundary layer, the problem reduces to solving two differential equations for the concentration and the flux of NO₂. The boundary conditions are the three surface fluxes and the fluxes at the top of the boundary layer, the last obtained from the entrainment velocity, and the concentration differences between the free troposphere and the top of the boundary layer. The equations are solved in a dimensionless form by using 1/(kτ) as the concentration unit, the depth h of the boundary layer as the length unit, the convective velocity scale w _* as the velocity unit, and the surface temperature flux divided by w _* as the temperature unit. Special care has been devoted to the inclusion of the scalar–scalar covariance between the concentrations of O₃ and NO. Sample calculations show that the fluxes of the reactive species deviate significantly from those of non-reactive species. Further, the diffusivities, defined by minus the flux divided by the concentration gradient may become negative for reactive species in contrast to those of non-reactive species, which in the present model are never negative.     

Analysis of Turbulence Collapse in the Stably Stratified Surface Layer Using Direct Numerical Simulation

The nocturnal atmospheric boundary layer (ABL) poses several challenges to standard turbulence and dispersion models, since the stable stratification imposed by the radiative cooling of the ground modifies the flow turbulence in ways that are not yet completely understood. In the present work we perform direct numerical simulation of a turbulent open channel flow with a constant (cooling) heat flux imposed at the ground. This configuration provides a very simplified model for the surface layer at night. As a result of the ground cooling, the Reynolds stresses and the turbulent fluctuations near the ground re-adjust on times of the order of L/u _τ , where L is the Obukhov length scale and u _τ is the friction velocity. For relatively weak cooling turbulence survives, but when Re_L=Lu_t/n <~100{Re_L=Lu_\tau/\nu \lesssim 100} turbulence collapses, a situation that is also observed in the ABL. This criterion, which can be locally measured in the field, is justified in terms of the scale separation between the largest and smallest structures of the dynamic sublayer.     

Eddy correlation measurements of methane flux in a northern peatland ecosystem

A pilot study to measure methane flux using eddy correlation sensors was conducted in a peatland ecosystem in north central Minnesota. A prototype tunable diode laser spectrometer system was employed to measure the fluctuations in methane concentration.The logarithmic cospectrum of methane concentration and vertical wind velocity fluctuations under moderately unstable conditions had a peak nearf = 0.10 (wheref is the nondimensional frequency) and was quite similar to the cospectra of water vapor and sensible heat. Daytime methane flux during the first two weeks of August ranged from 120 to 270 mg m^-2 day^-1. The temporal variation in methane fluxes was consistent with changes in peat temperature and water table elevation. Our results compared well with the range of values obtained in previous studies in Minnesota peatlands.These field observations demonstrate the utility of the micrometeorological eddy correlation technique for measuring surface fluxes of methane. The current state-of-the-art in tunable diode laser spectroscopy makes this approach practical for use in key ecosystems.Published as Paper No. 9556, Journal Series, Nebraska Agricultural Research Division.     

Spectra of CO<Subscript>2</Subscript> and Water Vapour in the Marine Atmospheric Surface Layer

Spectra of CO₂ and water vapour fluctuations from measurements made in the marine atmospheric surface layer have been analyzed. A normalization of spectra based on Monin–Obukhov similarity theory, originally developed for wind speed and temperature, has been successfully extended also to CO₂ and humidity spectra. The normalized CO₂ spectra were observed to have somewhat larger contributions from low frequencies compared to humidity spectra during unstable stratification. However, overall, the CO₂ and humidity spectra showed good agreement as did the cospectra of vertical velocity with water vapour and CO₂ respectively. During stable stratification the spectra and cospectra displayed a well-defined spectral gap separating the mesoscale and small-scale turbulent fluctuations. Two-dimensional turbulence was suggested as a possible source for the mesoscale fluctuations, which in combination with wave activity in the vertical wind is likely to explain the increase in the cospectral energy for the corresponding frequency range. Prior to the analysis the turbulence time series of the density measurements were converted to time series of mixing ratios relative to dry air. Some differences were observed when the spectra based on the original density measurements were compared to the spectra based on the mixing ratio time series. It is thus recommended to always convert the density time series to mixing ratio before performing spectral analysis.     

Monin–Obukhov Similarity Functions for the Structure Parameters of Temperature and Humidity

Monin–Obukhov similarity functions for the structure parameters of temperature and humidity are needed to derive surface heat and water vapour fluxes from scintillometer measurements and it is often assumed that the two functions are identical in the atmospheric surface layer. Nevertheless, this assumption has not yet been verified experimentally. This study investigates the dissimilarity between the turbulent transport of sensible heat and water vapour, with a specific focus on the difference between the Monin–Obukhov similarity functions for the structure parameters. Using two datasets collected over homogeneous surfaces where the surface sources of sensible heat and water vapour are well correlated, we observe that under stable and very unstable conditions, the two functions are similar. This similarity however breaks down under weakly unstable conditions; in that regime, the absolute values of the correlations between temperature and humidity are also observed to be low, most likely due to large-scale eddies that transport unsteadiness, advection or entrainment effects from the outer layer. We analyze and demonstrate how this reduction in the correlation leads to dissimilarity between the turbulent transport of these two scalars and the corresponding Monin–Obukhov similarity functions for their structure parameters. A model to derive sensible and latent heat fluxes from structure parameters without measuring the friction velocity is tested and found to work very well under moderately to strongly unstable conditions (−z/L > 0.5). Finally, we discuss the modelling of the cross-structure parameter over wet surfaces, which is crucial for correcting water vapour effects on optical scintillometer measurements and also for obtaining surface sensible and latent heat fluxes from the two-wavelength scintillometry.     

Shear stress partitioning in large patches of roughness in the atmospheric inertial sublayer

Drag partition measurements were made in the atmospheric inertial sublayer for six roughness configurations made up of solid elements in staggered arrays of different roughness densities. The roughness was in the form of a patch within a large open area and in the shape of an equilateral triangle with 60 m long sides. Measurements were obtained of the total shear stress (τ) acting on the surfaces, the surface shear stress on the ground between the elements (τ_S) and the drag force on the elements for each roughness array. The measurements indicated that τ_S quickly reduced near the leading edge of the roughness compared with τ, and a τ_S minimum occurs at a normalized distance (x/h, where h is element height) of (downwind of the roughness leading edge is negative), then recovers to a relatively stable value. The location of the minimum appears to scale with element height and not roughness density. The force on the elements decreases exponentially with normalized downwind distance and this rate of change scales with the roughness density, with the rate of change increasing as roughness density increases. Average τ_S : τ values for the six roughness surfaces scale predictably as a function of roughness density and in accordance with a shear stress partitioning model. The shear stress partitioning model performed very well in predicting the amount of surface shear stress, given knowledge of the stated input parameters for these patches of roughness. As the shear stress partitioning relationship within the roughness appears to come into equilibrium faster for smaller roughness element sizes it would also appear the shear stress partitioning model can be applied with confidence for smaller patches of smaller roughness elements than those used in this experiment.     

An Alternative Eddy-Viscosity Model for the Horizontally Uniform Atmospheric Boundary Layer

This paper explores the utility of specifying the eddy viscosity for the horizontally uniform boundary layer as the product of the variance of vertical velocity and an empirical time scale τ _w , as opposed to the more usual formulation where k is the turbulent kinetic energy (TKE), λ _k is a length scale and α is a dimensionless coefficient. Simulations were compared with the observations on Day 33 of the Wangara experiment, and with a plausible specification of τ _w (or λ _k ) each model simulated convective boundary-layer development reasonably well, although the closure produced a more realistic width for the entrainment layer. Under the light winds of Day 33, and with the onset of evening cooling, an excessively shallow and strongly-stratified nocturnal inversion developed, and limited its own further deepening. Boundary-layer models that neglect radiative heat transport and parametrize convective transport by eddy viscosity closure are prone to this runaway (unstable) feedback when forced by a negative (i.e. downward) surface flux of sensible heat.     

Turbulence Measurements above a Pine Forest

Eddy fluxes of momentum, sensible and latent heat, and turbulence spectra measured over the Thetford Forest during 10 days in the Spring of 1973 are described. The measured total heat flux (H + λE) for 122 20-min periods agreed closely on average with independent estimates from an energy balance method. There was evidence that the energy balance data gave small systematic overestimates of available energy during the hours before noon, compensated by slight underestimates for the remainder of the day. A comparison of measured wind speeds and friction velocities in neutral stability confirmed the validity of the aerodynamic method for estimating momentum fluxes at heights of a few roughness lengths above the canopy. In stable conditions the log-linear wind profile $U=(u_{?t}/k)({? ln}((z-d)/z_{0})+←pha(z-d-z_{0})/L)$ with α = 3.4 ± 0.4 provided a good fit to the data. Spectra in unstable conditions were generally more sharply peaked than those measured by other workers over smoother terrain: differences were less marked in the case of vertical velocity in stable conditions. Temperature spectra in these stable conditions showed high energy at relatively low wavenumbers, and wT cospectra showed a cospectral gap; both of these results were associated with an intermittent sawtooth structure in the temperature fluctuations.     

Turbulence Characteristics Of The Stable Boundary Layer Over A Mid-Latitude Glacier. Part Ii: Pure Katabatic Forcing Conditions

Observations obtained over a glacier surface in a predominantlykatabatic flow and with a distinctwind maximum below 13-m height are presented. The data werecollected using a 13-m high profilemast and two sonic anemometers (at about 2.5-m and 10-m heights).The spectra at frequencies belowthat of the turbulence range appear to deviate considerably fromthe curves obtained by Kaimal andco-workers during the 1968 Kansas experiment. The characteristicsof these deviations are compared tothe observations of others in surface-layers disturbed by anykind of large-scale outer-layer (orinactive) turbulence. In our case the disturbances arelikely to be induced by the highmountain ridges that surround the glacier. Moreover, the deviationsobserved in the cospectra seemto result from an, as yet, unspecified interaction between theinactive outer-layer turbulenceand the local surface-layer turbulence. Near the distinctwind maximum turbulence production ceasedwhile turbulence itself did not, probably the result ofturbulence transport from other levels. Consequently, we studied thelocal similarity relations using _w instead of u_* as an alternative velocity scale. Wellbelow the wind maximum, and for relatively low stability(0< Ri_g <0.2), the flow behaves accordingto well established local-scaling similarity relationshipsin the stable boundary layer. For higherstability (Ri_g > 0.2), and near or above the wind maximum, the boundary-layer structure conforms tothat of z-less stratification suggesting that the eddy sizeis restricted by the local stability ofthe flow. In line with this we observed that the sensibleheat fluxes relate remarkably well to thelocal flow parameters.     

Determination of kolmogorov entropy of chaotic attractor included in one—dimensional time series of meteorological data

The 1970-1985 day to day averaged pressure dataset of Shanghai and the extension method in phase space are used to calculate the correlation dimension D and the second-order Renyi entropy K2 of the approximation of Kolmogorov’s entropy, the fractional dimension D = 7.7~7.9 and the positive value K2 ≈ 0.1 are obtained. This shows that the attractor for the short-term weather evolution in the monsoon region of China exhibits a chaotic mo-tion. The estimate of K2 yields a predictable time scale of about ten days. This result is in agreement with that ob-tained earlier by the dynamic-statistical approach.The effects of the lag time τ on the estimate of D and K2 are investigated. The results show that D and K2 are convergent with respect to τ. The day to day averaged pressure series used in this paper are treated for the extensive phase space with τ = 5, the coordinate components are independent of each other; therefore, the dynamical character quantities of the system are stable and reliable.     

50 Years of the Monin–Obukhov Similarity Theory

In weak wind stable conditions, eddy-correlation fluxes calculated using conventional averaging times of 5 min or longer to define the perturbations are severely contaminated by poorly sampled mesoscale motions. A method is developed to identify the averaging time for each individual data record that captures the turbulence while excluding most of the mesoscale motions. The method is based on multiresolution decomposition of the heat flux, and provides an objective procedure for selecting the averaging time for calculating eddy-correlation fluxes. Eddy-correlation data collected in weak turbulence conditions over grass, snow, a pine forest and the ocean are used to demonstrate the approach.When the small-scale turbulence and mesoscale motions are clearly separated by a gap region in the heat flux cospectra, the variable window width reduces the influence of nonstationarity by more effectively filtering out mesoscale motions compared to traditional methods using constant averaging time. For records where turbulence and mesoscale motions overlap in scale, the method is not well posed, although such records occur infrequently for our datasets. These ambiguous cases correspond to significant nonstationarity at scales that overlap with turbulence scales. The improved turbulence fluxes calculated with the proposed method are the appropriate fluxes for evaluating flux-gradient relationships and Monin–Obukov similarity theory for developing improved model parameterizations of turbulence for weakly turbulent flows     

Daily and annual cycle of CO2 concentration near the surface depending on boundary layer structure at a rural site in Spain

CO₂ in the rural atmosphere is related to respiration–photosynthesis processes, although the evolution of the low atmosphere is also a determinant factor. CO₂ concentrations were measured at surface and meteorological variables obtained from a radio acoustic sounding system sodar at a flat rural site during a 3-year campaign. Yearly and daily cycles of CO₂ were described. Maxima were observed in spring and autumn during the night. Wind speed and thermal structure of the lower atmosphere were analysed. Low level jets were observed during the night, their core proving lower in summer. Surface inversions observed with low winds reached up to 100 m. The turbulence layer which developed during the day extended up to 300–400 m and was capped by a stable layer. Median vertical wind speed reached 1 m s^?1 in super-adiabatic conditions in summer. Determination of decoupled low level jets proved difficult with the device used and corresponding concentrations were slightly higher than medians calculated with all the observations. The bulk Richardson number was calculated in the lower atmosphere and four intervals were considered: drainage, transitional, shear flows and unstable conditions. Median CO₂ concentrations were split according to these intervals. Higher values corresponded to drainage flow, which was associated to more stable conditions being less frequent and lower values to shear flow and unstable conditions, revealing a satisfactory link between the bulk Richardson number as a turbulence indicator in the low atmosphere and CO₂ surface concentrations.