Early Permian East-Ujimqin mafic–ultramafic and granitic rocks from the Xing’an–Mongolian Orogenic Belt,North China: Origin,chronology, and tectonic implications

The East-Ujimqin complex, located north of the Erenhot–Hegenshan fault, North China, is composed of mafic–ultramafic and granitic rocks including peridotite, gabbro, alkali granite, and syenite. We investigated the tectonic setting, age, and anorogenic characteristics of the Xing’an–Mongolian Orogenic Belt (XMOB) through field investigation and microscopic and geochemical analyses of samples from the East-Ujimqin complex and LA-MC-ICP-MS zircon U–Pb dating of gabbro and alkali granite. Petrographic and geochemical studies of the complex indicate that this multiphase plutonic suite developed through a combination of fractional crystallization, assimilation processes, and magma mixing. The mafic–ultramafic rocks are alkaline and have within-plate geochemical characteristics, indicating anorogenic magmatism in an extensional setting and derivation from a mantle source. The mafic–ultramafic magmas triggered partial melting of the crust and generated the granitic rocks. The granitic rocks are alkali and metaluminous and have high Fe/(Fe + Mg) characteristics, all of which are common features of within-plate plutons. Zircon U–Pb geochronological dating of two samples of gabbro and alkali granite yielded ages of 280.8 ± 1.5 and 276.4 ± 0.7 Ma, placing them within the Early Permian. The zircon Hf isotopic data give inhomogeneous ε_Hf(t) values of 8.2–14.7 for gabbroic zircons and extraordinary high ε_Hf(t) values (8.9–12.5) for the alkali granite in magmatic zircons. Thus, we consider the East-Ujimqin mafic–ultramafic and granitic rocks to have been formed in an extensional tectonic setting caused by asthenospheric upwelling and lithospheric thinning. The sources of mafic–ultramafic and granitic rocks could be depleted garnet lherzolite mantle and juvenile continental lower crust, respectively. All the above indicate that an anorogenic magma event may have occurred in part of the XMOB during 280–276 Ma.     

Age constraints on the formation and emplacement of Neoproterozoic ophiolites along the Allaqi–Heiani Suture,South Eastern Desert of Egypt

Ophiolites are key components of the Neoproterozoic Arabian–Nubian Shield (ANS). Understanding when they formed and were emplaced is crucial for understanding the evolution of the ANS because their ages tell when seafloor spreading and terrane accretion occurred. The Yanbu–Onib–Sol Hamed–Gerf–Allaqi–Heiani (YOSHGAH) suture and ophiolite belt can be traced ∼ 600 km across the Nubian and Arabian shields. We report five new SHRIMP U–Pb zircon ages from igneous rocks along the Allaqi segment of the YOSHGAH suture in southernmost Egypt and use these data in conjunction with other age constraints to evaluate YOSHGAH suture evolution. Ophiolitic layered gabbro gave a concordia age of 730 ± 6 Ma, and a metadacite from overlying arc-type metavolcanic rocks yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 733 ± 7 Ma, indicating ophiolite formation at ∼ 730 Ma. Ophiolite emplacement is also constrained by intrusive bodies: a gabbro yielded a concordia age of 697 ± 5 Ma, and a quartz-diorite yielded a concordia age of 709 ± 4 Ma. Cessation of deformation is constrained by syn- to post-tectonic granite with a concordia age of 629 ± 5 Ma. These new data, combined with published zircon ages for ophiolites and stitching plutons from the YOSHGAH suture zone, suggest a 2-stage evolution for the YOSHGAH ophiolite belt (∼ 810–780 Ma and ∼ 730–750 Ma) and indicate that accretion between the Gabgaba–Gebeit–Hijaz terranes to the south and the SE Desert–Midyan terranes to the north occurred as early as 730 Ma and no later than 709 ± 4 Ma.     

Field relationship of high-grade Neo- to Mesoarchaean rocks of South-East Greenland: Tectonometamorphic and magmatic evolution

South-East Greenland forms part of the North Atlantic Craton and is characterized by migmatitic orthogneisses, narrow bands of mafic granulite, ultramafic and possible meta-sedimentary rocks, and alkaline-carbonatitic intrusive rocks. Mafic granulite, meta-sedimentary and ultramafic rocks form the basement for the emplacement of granitic intrusions at ca. 2865 Ma that lasted episodically until ca. 2790 Ma and continuously during 2750–2700 Ma. The area is structurally complex with evidence of at least seven deformation events including reclined and mushroom-like fold interference patterns. An older (> 2790 Ma) foliation formed in granitic rocks and the basement during the Timmiarmiut Orogeny (D_T). Deformation associated with the ca. 2790–2700 Ma Skjoldungen Orogeny folded this early foliation, and is associated with a penetrative foliation that is refolded progressively in a northeast–southwest oriented stress field. The orientation of the stress field progressively rotated into a northnorthwest–southsoutheast orientation during the last stages of the orogeny. The orogeny is also characterized by syn-deformational anatexis at granulite-facies (at approximately 800 °C and 5–8 kbar, ca. 2790–2740 Ma), which decreased to the amphibolite-facies at ca. 2730 Ma.The late- to post-tectonic granite and alkaline rocks assigned to the Skjoldungen Alkaline Province intruded the central-northern part around 2710 Ma. This was followed by north–south extensional deformation during the Singertat Stage forming discrete shear-zones at greenschist-facies grades, which is coeval with the emplacement of pegmatite, ijolite, and carbonatite emplacement during ca. 2680–2650 Ma.Similar lithology and tectonic processes in the Tasiusarsuaq Terrane of southern West Greenland and the Lewisian Complex in Scotland suggest a possibly large Archaean terrane at that time, which, taking the present size, at least covered around 500–600 km in an east–west direction and approximately 200 km in a north–south direction.     

Deformation history and U–Pb zircon geochronology of the high grade metamorphic rocks within the Klaeng fault zone,eastern Thailand

In eastern Thailand the Klaeng fault zone includes a high-grade metamorphic rock assemblage, named Nong Yai Gneiss, which extends about 30 km in a NW–SE direction along the fault zone. The rocks of this brittle-fault strand consist of amphibolite to granulite grade gneissic rocks. Structural analysis indicates that the rocks in this area experienced three distinct episodes of deformation (D₁–D₃). The first (D₁) formed large-scale NW–SE-trending isoclinal folds (F₁) that were reworked by small-scale tight to open folds (F₂) during the second deformation (D₂). D₁ and D₂ resulted from NE–SW shortening during the Triassic Indosinian orogeny before being cross-cut by leucogranites. D₁ and D₂ fabrics were then reworked by D₃ sinistral shearing, including shear planes (S₃) and mineral stretching lineations (L₃). LA–MC–ICP–MS U–Pb zircon dating suggested that the leucogranite intrusion and the magmatic crystallization took place at 78.6 ± 0.7 Ma followed by a second crystallization at 67 ± 1 to 72.1 ± 0.6 Ma. Both crystallizations occurred in the Late Cretaceous and, it is suggested, were tectonically influenced by SE Asian region effects of the West Burma and Shan-Thai/Sibumasu collision or development of an Andean-type margin. The sinistral ductile movement of D₃ was coeval with the peak metamorphism that occurred in the Eocene during the early phases of the India–Asia collision.     

Geology and geochemistry of the Triassic Wenquan Mo deposit and Mo-mineralized granite in the Western Qinling Orogen,China

The recently-discovered Wenquan porphyry Mo deposit hosted in the Wenquan granite of the West Qinling Orogen has been recognized as a product of the Indosinian metallogenesis. Three generations of mineral assemblage for the deposit are identified as follows: (1) quartz–biotite–K-feldspar; (2) quartz–sulfide and (3) sulfide–calcite. Geochemical study shows that the mafic microgranular enclaves (MMEs) in the ore-bearing Wenquan granite have lower SiO₂, and higher Mg# and Nb/Ta ratios than the host granite itself. Different from the granite which have zircon ε_Hf(t) values of − 3.6–3.0 and T_DM2 of 1234–890 Ma, the MMEs are characterized by the ε_Hf(t) values of − 10.1–10.8 and T_DM1 of 865–441 Ma. This can be interpreted to indicate a mixture origin of the Meso- and Neoproterozoic crust-derived component and Neoproterozoic SCLM-derived materials for the formation of the Wenquan granite, which played an essential role in the Mo mineralization. Comparative Pb isotopic data between ores and K-feldspar suggest that the Wenquan granitic magma originated from the middle-lower crust of the South China Block and the ore-forming materials were incorporated by hydrothermal fluid differentiated from the Triassic magmatic system, with minor contribution of sedimentary rocks. The δ³⁴S values of 5.0–11.7‰ with a pronounced mode at 5.0 to 6.1‰ for the ores probably represent the sulfur incorporation of a typical magmatic hydrothermal fluid contaminated by heavy sulfur of Devonian sediments. The granite yielded the zircon U–Pb ages of 218 ± 2.4 Ma and 221 ± 1.3 Ma, as the same as the ages of 217 ± 2.0 Ma and 218 ± 2.5 Ma obtained for the MMEs. These ages are indistinguishable with the molybdenite Re–Os isochron age of 219 ± 5.2 Ma which is the timing for the Mo mineralization. Tectonically, the magmatic mixture processes of the Wenquan granite and the Mo mineralization to form the Wenquan Mo deposit contemporaneously occurred during the transition of tectonic regime from syn- to post-collision orogeny in the Qinling Orogen in the Late Triassic.     

Genesis of the Yuanlingzhai porphyry molybdenum deposit,Jiangxi province,South China: Constraints from petrochemistry and geochronology

The newly discovered Yuanlingzhai porphyry molybdenum (Mo) deposit in southern Jiangxi province belongs to the group of Mo-only deposits in the Nanling region. The mineralization developed at contact zones between the Yuanlingzhai granite porphyry and Neoproterozoic metamorphic rocks of the Xunwu Formation. Precise LA–MC–ICPMS zircon U–Pb dating of the Yuanlingzhai porphyry, as well as the adjacent western Keshubei and eastern Keshubei granites, yielded ages of 165.49 ± 0.59 Ma, 159.68 ± 0.43 Ma, and 185.13 ± 0.52–195.14 ± 0.63 Ma, respectively. Molybdenite Re–Os isochron ages of the ores are 160 ± 1–162.7 ± 1.1 Ma, which is consistent with the age of large-scale W–Sn deposits in South China. The Yuanlingzhai porphyry is characterized by high K₂O, P₂O₅, and A/CNK (1.33–1.59), and low CaO and Na₂O. The rock shows relatively enriched LREE without significant Eu anomalies (Eu/Eu^* = 0.80–0.90). Geochemical and mineralogical characteristics indicate that the ore-hosting porphyry is a typical S-type granite generated from the partial melting of crustal material with only minor mantle contribution. Both Harker and evolutionary discrimination diagrams indicate that the Yuanlangzhai and western Keshubei granites are not products of co-magmatic evolution. The Keshubei granites and Xunwu Formation were not significant sources for the components in the porphyry mineralization, but the Yuanlangzhai granite may have supplied some ore-forming material. However, the main ore-forming material was carried by fluids from deep sources, as demonstrated by fluid inclusion and stable isotope data from the molybdenum deposit. The Mo porphyry deposit formed in an extensional setting, and was possibly associated with Jurassic subduction of the Izanagi Plate.     

Age and petrogenesis of the Neoproterozoic Chon-Ashu alkaline complex,and a new discovery of chalcopyrite mineralization in the eastern Kyrgyz Tien Shan

Neoproterozoic volcanics and granitoids formed at Rodinia margins within a time span of 880 Ma–700 Ma, are well-documented in many terranes of the southern Central Asian Orogenic Belt (CAOB). Ages younger than 550 Ma corresponding to the opening of the Terskey Ocean are also common. However, so far, there were very few published ages in the range 700 Ma–550 Ma from the Kyrgyz Tien Shan. In this paper we present new data for the alkaline Chon-Ashu complex emplaced at the end of the Cryogenian Period of the Neoproterozoic (850–635 Ma, Gradstein et al., 2012). The alkaline complex intrudes the Precambrian metamorphic rocks north of the Nikolaev Line which separates the Northern and Middle Tien Shan terranes in the eastern Kyrgyzstan. The undeformed shallow level alkaline rocks range from olivine gabbro to nepheline and cancrinite syenites and leucosyenites. The differentiated rock assemblage can be explained by fractional crystallization of high-silica mineral phases which drives nepheline-normative melts away from the silica saturation boundary. The alkaline rocks of Chon-Ashu are enriched in LILE and HFSE indicative of their origin from lithospheric mantle. An age of 678 ± 9 Ma (U–Pb, SHRIMP) was obtained for a protolith of country gneiss, and an age of 656 ± 4 Ma was obtained for the crosscutting alkaline rocks of the Chon-Ashu complex. Seven zircon grains recovered from gneiss and alkaline rocks had bright overgrown rims which yielded a cumulative age of 400 ± 8 Ma. A metamorphic event, followed by uplift and emplacement of shallow level alkaline complex, constrains the geodynamic setting. Alkaline rocks usually form in an extensional setting and originate from lithospheric mantle. The 690 Ma xenoliths of mafic granulite from the NW Tarim have been interpreted to originate by mafic underplating. This mafic underplating may have been responsible for metamorphism in the middle crust prior to emplacement of the Chon-Ashu complex. The 670 Ma–630 Ma period of extension and emplacement of enriched alkaline rocks can be also traced on a regional scale through southern Kazakhstan and the northern Tarim. We tentatively interpret these events as a result of mafic underplating and subsequent rifting related to the break-up of Rodinia. During field work at Chon-Ashu, rich chalcopyrite mineralization has been discovered in carbonate veinlets in leucosyenite alkaline dikes and has also been found in the adjacent Cambrian gabbro and granites shown on the map as undivided Devonian–Silurian. Stockwork mineralization predominates though disseminated mineralization is also present. The Cu content reaches 16,184 ppm and is associated with elevated concentrations of Pb, Zn and Ag. The polyphase structural evolution of the area suggests that mineralization could have formed in several genetically unrelated stages. Based on structural and mineralogical evidence we tentatively relate the earliest stage of chalcopyrite mineralization to the late magmatic CO₂-rich fluids emanating from the Cryogenian alkaline complex. The Early Devonian thermal event registered by growth of new zircon at 400 Ma has important metallogenic implications on a regional scale. However the origin of two zones of alteration in the undivided Silurian–Devonian granites is ambiguous because their age was not determined geochronologically. The 522 ± 4 Ma Cambrian gabbro of the Tashtambektor Formation is strongly foliated along the splays of the Nikolaev Line, indicating a Hercynian origin of the fabric. Superimposed mineralized stockwork postdates the foliation and suggests a late-Hercynian age of mineralization in gabbro. The new data enable a reassessment of the metallogenic potential of the Eastern Kyrgyz Tien Shan. Presence of not eroded high-level mineralized Neoproterozoic alkaline intrusions points to a previously underestimated metallogenic potential of pre-Hercynian granitoids which may host preserved porphyry systems, skarns and shear-related mineralization. Finally, the Devonian magmato-metamorphic event which caused formation of a number of ore deposits in central Kyrgyzstan and Kazakhstan could also create potential exploration targets in eastern Kyrgyzstan.     

A high-pressure folded klippe at Tehuitzingo on the western margin of an extrusion zone,Acatlán Complex,southern México

High-pressure (HP) rocks at Tehuitzingo, on the western margin of the HP belt within the Paleozoic Acatlán Complex (southern México), occur in a klippe that was thrust over low-grade clastic rocks. The youngest detrital zircon cluster in the low-grade rocks yielded U-Pb ages of 481 ± 16 Ma, which provide an older limit for deposition. The HP rocks are composed of metabasites, serpentinite, granite (482 ± 3 Ma) and mica schist (youngest concordant detrital zircon: 433 ± 3 Ma). The schist and granite are inferred to be high-grade equivalents of lower Paleozoic, low-grade rocks exposed elsewhere in the Acatlán Complex, from which they are inferred to have been removed by subduction erosion. Mineral analyses indicate that the subducted rocks underwent HP metamorphism and polyphase deformation at depths of ~ 50 km (~ 16 kbar and 750 °C: eclogite facies). Subsequent retrogression passed through epidote-amphibolite to greenschist facies, which was synchronous with W-vergent thrusting over the low-grade clastic rocks. Deposition of the low-grade rocks and thrusting are bracketed between either 481–329 Ma (Ordovician-Mississippian), and was followed by F₃ synformal folding. Cooling through ca. 385 °C is indicated by 329 ± 1 and 316–317 ± 2 Ma, ⁴⁰Ar/³⁹Ar muscovite plateau ages in HP rocks, which are 5–17 my younger than those of the adjacent Piaxtla eclogites suggesting younger exhumation. The petrology, P-T conditions and ages of the Piaxtla Suite is consistent with an extrusion channel within the Acatlán Complex along the active western margin of Pangea during the Carboniferous. Detrital zircon populations in the low-grade psammite (ca. 481, 520–650, 720, 750, 815, 890, 1050 and 2750 Ma) and the HP schist (ca. 457–480, 534, 908, 954–1150, 1265, 1845 and 2035 Ma) indicate derivation from the Ordovician Acatlán granitoids, Neoproterozoic Brasiliano orogens, 900–750 Ma Goiás arc (Amazonia), 1–1.3 Ma Oaxaquia, and more ancient sources in Oaxaquia/Amazonia.     

Time constraints on deformation of the Ajjaj branch of one of the largest Proterozoic shear zones on Earth: The Najd Fault System

In active tectonic regions, shear zones play an important role in re-configuring the structure of the lithosphere. One of the largest shear zones on Earth is the Najd Fault System of the Arabian–Nubian Shield. The main active phase of this shear zone was during the last stages of the Pan-African Orogeny (ca. 630–540 Ma). Six samples of intrusive rocks that were emplaced into the shear zone at different stages during its active phase are used to illustrate the progressive evolution of the Ajjaj shear zone. A sample of coarse-grained diorite, with an intercept U–Pb zircon age of 696 ± 6 Ma, shows very weak deformation. Two samples from deformed granodiorite–tonalite intrusions at the border of the Ajjaj shear zone show conspicuous degrees of deformation, and define two U–Pb clusters of concordia ages at 747 ± 12 Ma–668 ± 8 Ma and 742 ± 5 Ma–702 ± 12 Ma. Two samples of granites show mylonitic foliation with flattened quartz and biotite parallel to the trend of the shear zone. These samples yield U–Pb ages of 601 ± 3 Ma–584 ± 3 Ma. Another granite sample is undeformed and shows cross-cutting relations with the shear foliation of the Ajjaj shear zone. It yields a concordia age of 581 ± 4 Ma. The metamorphic rocks of the Hamadat complex host the Ajjaj shear zone, and have been useful in determining the metamorphic P-T conditions attending the activity of the shear zone. The peak metamorphism of the Hamadat Complex is 505–700 °C at two ranges of pressure 8–11 and 14.5 ± 2 kbar. New data confine the activation of the Ajjaj shear zone in a limited period of time between 604 Ma and 581 Ma and the operation at different crustal levels with a maximum depth of 58 km.     

Kinematics and age constraints of deformation in a Late Carboniferous accretionary complex in Western Junggar,NW China

The Karamay area, situated in the eastern part of Western Junggar, Southern Altaids, contains an ophiolitic mélange with ultramafic rocks, gabbro, basalt, chert and limestone, which show typical block-in-matrix structures, and coherent turbidites and tuffs. These lithological associations are interpreted as incoherent and coherent series formed in an accretionary complex. On the basis of detailed field mapping and analyses of the asymmetry of imbricate thrusts, duplexes, tilted structures, shear band cleavages, and the NW-verging inclined to overturned folds, we conclude that the overall movement in the accretionary complex was top-to-the-NW. The youngest tuff involved in the deformation contains detrital zircons that have a U–Pb age (LA-MC ICP-MS) of 308 ± 7 Ma. ³⁹Ar–⁴⁰Ar resistance furnace step-heating of amphibole separates from a diorite dike, which cuts the folded and imbricated rocks in the accretionary prism, yielded a plateau age of 307 ± 2 Ma. Consequently, the age of the deformation in the prism is tightly constrained at 307–308 Ma, implying that the deformation occurred in an extremely short time-span during SE-ward subduction. Combined contemporaneous occurrence of Baogutu adakite, high-Mg, Sr-enriched and Y-poor dioritic dikes, Miaoergou charnockite, and Maliya mafic rocks, we further suggest the accretionary complex was cut by near-trench volcanic rocks and plutons possibly due to interaction with a spreading ridge.     

Zircon ages and geochemical compositions of the Manlay ophiolite and coeval island arc: Implications for the tectonic evolution of South Mongolia

Numerous small dismembered ophiolite fragments occur in South Mongolia, but they are very poorly studied. The lack of age data and geochemical analysis hampers our understanding of the Paleozoic tectonic evolution of the region. We conducted detailed studies on the Manlay ophiolitic complex and Huree volcanic rocks south of the Main Mongolian Lineament (MML) to provide some constraints on these rocks. The Manlay ophiolite consists of dunite, harzburgite, pyroxenite, gabbro, plagiogranite, basalt and chert, locally with chromite mineralization in dunite. The gabbro and plagiogranite yielded SHRIMP zircon weighted mean ²⁰⁶Pb/²³⁸U ages of 509 ± 5 Ma and 482 ± 4 Ma, respectively. The basalt and dolerite samples of this complex show enrichment in LREE and LILE and negative Nb, Ta and Ti anomalies, and the chrome spinel from the chromitite lens in the dunite is characterized by high Cr^# and low TiO₂ contents. These features suggest a supra-subduction zone (SSZ) origin for the ophiolitic complex. The Huree volcanic rocks, ranging from basalt to dacite, display enrichment in LREE and LILE, weak Eu anomalies and distinctly negative Nb, Ta and Ti anomalies, consistent with those of typical magmas in a subduction environment. An andesite sample from this arc yielded a SHRIMP ²⁰⁶Pb/²³⁸U zircon age of 487 ± 5 Ma, which is the oldest reliable age for an island arc in South Mongolia. Recognition of an Early Paleozoic ophiolitic complex and a coeval island arc indicates that South Mongolia underwent a period of active volcanism during Late Cambrian to Ordovician. Additionally, the tuff overlying the ophiolitic complex and a granite intruding the ophiolite have SHRIMP zircon U–Pb ages of 391 ± 5 Ma and 304 ± 4 Ma, respectively. Combining the available data, we propose that the Early Paleozoic subduction–accretionary complexes likely constitute the basement of the Late-Paleozoic arc formations and correlate with the Lake Zone in western Mongolia.     

U–Pb dating of granites in the Neoproterozoic Sergipano Belt,NE-Brazil: Implications for the timing and duration of continental collision and extrusion tectonics in the Borborema Province

The Sergipano Belt is the outcome of collision between the Pernambuco–Alagoas Massif and the São Francisco Craton during Neoproterozoic assembly of West Gondwana. Field relationships and U–Pb geochronology of granites intruded in garnet micaschists of the Macururé Domain are used to constrain the main collisional event (D₂) in the belt. The granites are divided into two groups, the pre-collisional granites (pre- to early-D₂) and the syn-collisional granites (syn- to tardi-D₂), the latter were emplaced as sheets along the S₂ axial plane foliation or they were collected at the hinge zones of F₂ folds. A U–Pb SHRIMP zircon age of 628 ± 12 Ma was obtained for the pre-collisional Camará tonalite. Two U–Pb TIMS titanite ages were obtained for the syn-collisional granites, 584 ± 10 Ma for the Angico granite and 571 ± 9 Ma for the Pedra Furada granite, and these ages are close to the garnet-whole rock Sm–Nd isochron of 570 Ma found for the peak of metamorphism in the Sergipano Belt. The ages of the Camará tonalite (628 Ma) and the Pedra Furada granite (571 Ma) mark respectively the maximum age for beginning of the D₂ event and minimum age for the end in the Macururé Domain. Using these ages, the main Neoproterozoic D₂ collisional event has been in operation in the Sergipano Belt for at least 57 million years. Correlation with coeval granitoids farther north in the Borborema Province indicate that while in the Sergipano Belt the syn-D₂ granites (ca. 590–570 Ma) were emplaced under compression, in the Borborema Province they emplaced under extensional conditions related to regional strike-slip shear zones. These contrasting emplacement settings for contemporaneous Neoproterozoic granitoids are explained by a combination of continent–continent collision and extrusion tectonics.     

Pan-African metamorphic evolution in the southern Yaounde Group (Oubanguide Complex,Cameroon) as revealed by EMP-monazite dating and thermobarometry of garnet metapelites

Garnet-bearing micaschists and paragneisses of the Yaounde Group in the Pan-African Central African Orogenic Belt in Cameroon underwent a polyphase structural evolution with the deformation stages D₁–D₂, D₃ and D₄. The garnet-bearing assemblages crystallized in course of the deformation stage D₁–D₂ which led to the formation of the regional main foliation S₂. In X_Ca–X_Mg coordinates one can distinguish several zonation trends in the garnet porphyroblasts. Zonation trends with increasing X_Mg and variably decreasing X_Ca signalize a garnet growth during prograde metamorphism. Intermineral microstructures provided criteria for local equilibria and a structurally controlled application of geothermobarometers based on cation exchange and net transfer reactions. The syndeformational P–T path sections calculated from cores and rims of garnets in individual samples partly overlap and align along clockwise P–T trends. The P–T evolution started at ～450 °C/7 kbar, passed high-pressure conditions at 11–12 kbar at variable temperatures (600–700 °C) and involved a marked decompression toward 6–7 kbar at high temperatures (700–750 °C). Th–U–Pb dating of metamorphic monazite by electron microprobe (EMP-CHIME method) in eight samples revealed a single period of crystallization between 613 ± 33 Ma and 586 ± 15 Ma. The EMP-monazite age populations between 613 ± 33 Ma enclosed in garnet and 605 ± 12 Ma in the matrix apparently bracket the high temperature–intermediate pressure stage at the end of the prograde P–T path. The younger monazites crystallized still at amphibolite-facies conditions during subsequent retrogression. The Pan-African overall clockwise P–T evolution in the Yaounde Group with its syndeformational high pressure stages and marked pressure variations is typical of the parts of orogens which underwent contractional crustal thickening by stacking of nappe units during continental collision and/or during subduction-related accretionary processes.     

Zircon U–Pb and molybdenite Re–Os dating of the Chalukou porphyry Mo deposit in the northern Great Xing’an Range,China and its geological significance

The newly discovered Chalukou giant porphyry Mo deposit, located in the northern Great Xing’an Range, is the biggest Mo deposit in northeast China. The Chalukou Mo deposit occurs in an intermediate-acid complex and Jurassic volcano-sedimentary rocks, of which granite porphyry, quartz porphyry, and fine-grained granite are closely associated with Mo mineralization. However, the ages of the igneous rocks and Mo mineralization are poorly constrained. In this paper, we report precise in situ LA-ICP-MS zircon U–Pb dates for the monzogranite, granite porphyry, quartz porphyry, fine grained granite, rhyolite porphyry, diorite porphyry, and andesite porphyry in the Chalukou deposit, corresponding with ages of 162 ± 2 Ma, 149 ± 5 Ma, 148 ± 2 Ma, 148 ± 1 Ma, 137 ± 3 Ma, 133 ± 2 Ma, and 132 ± 2 Ma, respectively. Analyses of six molybdenite samples yielded a Re–Os isochron age of 148 ± 1 Ma. These data indicate that the sequence of the magmatic activity in the Chalukou deposit ranges from Jurassic volcano-sedimentary rocks and monzogranite, through late Jurassic granite porphyry, quartz porphyry, and fine-grained granite, to early Cretaceous rhyolite porphyry, diorite porphyry, and andesite porphyry. The Chalukou porphyry Mo deposit was formed in the late Jurassic, and occurred in a transitional tectonic setting from compression to extension caused by subduction of the Paleo-Pacific oceanic plate.     

Neoproterozoic granitic activities in the Xingdi plutons at the Kuluketage block,NW China: Evidence from zircon U–Pb dating,geochemical and Sr–Nd–Hf isotopic analyses

Neoproterozoic igneous rocks are widely distributed in the Kuluketage block along the northern margin of the Tarim Craton. However, the published literature mainly focuses on the ca. 800 Ma adakitic granitoids in the area, with the granites that intrude the 735–760 Ma mafic–ultramafic rocks poorly studied. Here we report the ages, petrography and geochemistry of two granites in the Xingdi mafic–ultramafic rocks, in order to construct a new view of the non-adakitic younger granites. LA-ICP-MS zircon U–Pb dating provided weighted mean ²⁰⁶Pb/²³⁸U ages of 743.0 ± 2.5 Ma for the No.I granite (G1) and 739.0 ± 3.5 Ma for the No.II granite (G2). A clear core-rim texture of similar age and a high zircon saturation temperature of ca. 849 ± 14 °C were observed for the No.I granite; in contrast, G2 has no apparent core-rim texture but rather inherited older zircons and a lower zircon saturation temperature of ca. 763 ± 17 °C. Geochemical analysis revealed that G1 is an alkaline A-type granite and G2 is a high-K calc-alkaline I-type granite. Both granites share similar geochemical characteristics of arc-related magmatic rocks and enriched Sr–Nd–Hf isotopes, likely due to their enriched sources or mixing with enriched magma. Whereas G1 and its host mafic rocks form typical bimodal intrusions of the same age and similar Sr–Nd–Hf isotope compositions, G2 is younger than its host mafic rocks and its Sr–Nd–Hf isotope composition indicates a lower crust origin. Although they exhibit arc-related geochemical features, the two granites likely formed in a rift setting, as inferred from thier petrology, Sr–Nd–Hf isotopes and regional tectonic evolution.     

The stratoid granites of central Madagascar: paleomagnetism and further age constraints on neoproterozoic deformation

A paleomagnetic and ⁴⁰Ar/³⁹Ar study of a 630-Ma alkaline granite suite in Madagascar, the so-called ‘stratoid’ granites, reveals a complex history of remagnetization during the formation of the Antananarivo Zone de Virgation at ∼560 Ma (D₂) and the Angavo shear zone at ∼550 Ma (D₃). ⁴⁰Ar/³⁹Ar dating of hornblende, biotite and potassium feldspar from rocks affected by D₂/D₃ show initial cooling rates of 8 °C/Ma during the 550–520 Ma interval followed by slower cooling of 2.5 °C/Ma. The thermal effects of the D₂ and D₃ events appear to be restricted to regions surrounding the shear zones as evidenced by a ⁴⁰Ar/³⁹Ar biotite age of 611.9±1.7 Ma north of the virgation zone. The paleomagnetic data from the stratoid granites are complex and some sites, particularly in areas to the north of the virgation zone, may have been rotated about non-vertical axes following their emplacement and cooling. Because of these possible rotations, our best estimate for the paleomagnetic pole for Madagascar is derived from sites within the virgation zone. This pole falls at 6.7°S, 352.6°E (a₉₅=14.2°). A post-metamorphic cooling history for the virgation zone indicates a magnetization age of 521.4±11.9 Ma. Our work in central Madagascar, coupled with previous studies, suggests that emplacement of the 630 Ma stratoid granites followed a collisional (?) tectonic event beginning around 650 Ma, recently recognized in southern Madagascar and in Tanzania. Subsequently, the stratoid granites in the Antananarivo virgation zone were reheated (∼750–800 °C) at pressures between 3.5 and 3.6 kbars resulting in a pervasive remagnetization. We suggest that the younger shear events are genetically related to collisional tectonics elsewhere during the final stages of Gondwana assembly and are a consequence of the Kuunga Orogeny further south.     

The Zhaheba ophiolite complex in Eastern Junggar (NW China): Long lived supra-subduction zone ocean crust formation and its implications for the tectonic evolution in southern Altaids

The composite Zhaheba ophiolite complex, exposed in Eastern Junggar in the Southern Altaids, records an unusually long record of oceanic crust and magmatic arc evolution. The Zhaheba ophiolite complex consists of ultramafic rocks, gabbro, diorite, basalt and chert intruded by diabase dikes and diorite porphyry. These rocks are overlain by a several-km-thick section of tuffaceous rocks, volcaniclastic sedimentary rocks, and intermediate volcanic rocks. The igneous rocks of the ophiolite complex show negative Nb and Ta anomalies and LREE enrichment relative to HREE, suggesting the influence of fluids derived from a subducting oceanic slab. The LA-ICPMS U–Pb age of zircons from gabbro is 495.1 ± 3.5 Ma. Zircon ages from diorite and basalt are 458.3 ± 7.2 Ma and 446.6 ± 6.0 Ma, respectively. The basalt is locally overlain by bedded chert. Diabase dikes and diorite porphyry yield the U–Pb ages of 421.5 ± 4.1 Ma and 423.7 ± 6.5 Ma, respectively. The age of stratigraphically lower part of the overlying volcanic–volcaniclastic section is constrained to be about 410 Ma, the maximum depositional age of the tuffaceous sandstone from U–Pb detrital zircon ages. Late rhyolite at the top of the stratigraphic section yielded a U–Pb zircon age of 280.3 ± 3.7 Ma. The age and stratigraphic relationships for the Zhaheba ophiolite complex and related rocks suggest that the period of ~ 70 Ma of initial supra-subduction magmatism was followed by construction of a mature island arc that spanned an additional 140 Ma. Many other ophiolites in the southern Altaids appear to record similar relationships, and are represented as substrates of oceanic island arcs covered by island arc volcanism in supra-subduction zone. The occurrence of the Zhaheba ophiolite complex with tuffaceous and intermediate to felsic volcanic rocks is different from the rock association of classic Tethyan SSZ ophiolites but similar to some ophiolites in North America. Although the Zhaheba ophiolite belt is flanked by the Dulate arc in the north and Yemaquan arc in the south, it cannot stand a suture between two arcs. It is suggested that Devonian–Carboniferous Dulate arc was built on the late Cambrian–middle Ordovician Zhaheba supra-subduction oceanic crust. The late Carboniferous rocks and early Permian rocks in Dulate arc are interpreted to form in the extensional process within Zhaheba–Dulate arc composite system.     

Discovery of Neoarchean suprasubduction zone ophiolite suite from Yishui Complex in the North China Craton

The Archean tectonic realm of the North China Craton (NCC) is considered in recent models as a collage of several microblocks which were amalgamated along zones of ocean closure during late Neoarchean. Here we report the finding of a dismembered ophiolite suite from the southern margin of the Jiaoliao microblock in the interior of the unified Eastern Block of the NCC. The suite is composed of lherzolite, pyroxenite, noritic and hornblende gabbro, and hornblendite intruded by veins and sheets of leuco granite. Together with transposed layers and bands of metavolcanics and amphibolites, banded iron formation (BIF), and diabase dykes in the adjacent locations, the Yishui complex corresponds well with a dismembered suprasubduction zone ophiolite suite. Clinopyroxene in the pyroxenite and gabbroic rocks is Mg rich and range in composition from augite to diopside. Among orthopyroxenes, those in lherzolite show the highest X_Mg of 0.84–0.85. Plagioclase in hornblende gabbro shows high anorthite content (An_50–64). Calcic amphiboles in the gabbroic rocks range in composition from ferropargasite to ferro-edenite, edenite and pargasite. Spinel inclusions in lherzolite are Cr-rich magnesiospinel. Geochemically, the mafic rocks from Yishui complex show subalkaline basaltic source, whereas the granitoids show volcanic arc affinity. The hornblende gabbro and gabbro, lherzolite and hornblendite show compositional similarity to E-MORB and N-MORB respectively. The lherzolite and hornblendite possess arc-related ultramafic cumulate nature, with overall features straddling the fields of IAT and IAT-MORB. The geochemical features are consistent with evolution in a suprasubduction regime with no significant crustal contamination. The majority of zircon grains in the Yishui suite exhibit magmatic texture and high Th/U ratios. Zircon grains from hornblendite define ²⁰⁷Pb/²⁰⁶Pb upper intercept age of 2538 ± 30 Ma. Zircons from the granite show ages of 2538 ± 16 Ma and 2503 ± 21 Ma, and those from the gabbros yield ages of 2503 ± 16 Ma and 2495 ± 10 Ma. The well defined major age peak at 2500 Ma is broadly coeval with Neoarchean ages reported from the microblocks in the North China Craton. The zircon Lu–Hf data from the Yishui suite display εHf(t) values between − 2.5 and 5.0, with corresponding model ages suggesting magma derivation from Neoarchean juvenile sources together with limited reworked Paleo-Mesoarchean crustal components.Our study is the first report of Neoarchean suprasubduction-type ophiolites from a locality far from the margins of the major crustal blocks and suture zones in the NCC and strengthens the concept that the craton is a mosaic of several microblocks with intervening oceans that closed along multiple subduction zones. We envisage that the amalgamation between the Xuhuai and the Jiaoliao microblocks resulted in the accretion of the Yishui suprasubduction zone ophiolitic assemblages onto the southern margin of the Jiaoliao microblock. The Neoarchean microblock amalgamation in the North China Craton provides new insights into continental growth in the early Earth and confirms that modern style plate tectonics might have been initiated early in the history of our planet.     

The building of an Archean microcontinent: Evidence from the North China Craton

Continents on the early earth are considered to have been built through the accretion of microterranes, oceanic arcs and plateaus. The North China Craton (NCC), envisaged in recent models as a collage of several microblocks which were amalgamated along multiple zones of ocean closure during the late Neoarchean, provide a typical case to investigate the origin and amalgamation of microcontinents through convergent margin processes. Here we report a suite of magmatic rocks developed at the periphery of one of these microblocks, the Jiaoliao Block, that forms part of the composite Eastern Block of the NCC. We integrate our new data with those from various parts of this microblock to elucidate the mechanism of continent building in the Archean. We present petrological, geochemical and zircon U–Pb geochronological and Lu-Hf isotopic data from the magmatic suite that belongs to the Yishui Complex. Geochemically, the felsic units of the suite straddle from monzonite through granodiorite to granite with dominantly metaluminous affinity, magnesian composition and arc-related features. The metagranites, TTG gneisses and charnockites are characterized by negative Nb-Ta anomalies and positive K and Pb anomalies. The diorites and gabbros display negative anomalies of Th-U, Nb-Ta and Zr-Hf and positive anomalies at Ba, Pb and Sm with negative Eu anomalies and minor positive Ce anomalies, attesting to arc-related features. In the tectonic discrimination diagrams, the rocks plot in the volcanic arc field, indicating arc-related origin in subduction setting.Zircon grains from all the rocks display core–rim texture with the cores showing magmatic crystallization and the narrow structureless rims corresponding to metamorphic overgrowth. The magmatic zircons from the metagranites show upper intercept ages or ²⁰⁷Pb/²⁰⁶Pb weighted mean ages of 2505 ± 29 Ma and 2569 ± 20 Ma to 2513 ± 27 Ma, those from the TTG gneisses show 2535 ± 17 Ma to 2546 ± 39 Ma, from charnockites display 2543 ± 20 Ma–2555 ± 15 Ma, and diorite and gabbro show 2587 ± 15 Ma and 2516 ± 13 Ma respectively. The zircon rim ages of 2472 ± 23 Ma, 2457 ± 35 Ma, 2545 ± 30 Ma and 2511 ± 35 Ma suggest the timing of metamorphism (ca. 2.55–2.45 Ga). Magmatic zircons with slightly older ages of ca. 2.73 Ga, 2.64 Ga also occur suggesting multiple magmatic pulses. The Lu-Hf isotopic data show positive εHf(t) values ranging from 0.2 to 5.7 for metagranites, with Hf model ages of 2602–2815 Ma (T_DM) and 2658–3002 Ma (T_DM^C), whereas for TTG gneisses, the positive εHf(t) values are up to 6.5 and display dominant Mesoarchean Hf model ages with limited early Neoarchean Hf model ages. Charnockite samples show positive εHf(t) values 2.3–5.7 and display the Hf model ages ranging from 2601 Ma to 2772 Ma (T_DM) and 2658 Ma to 2904 Ma (T_DM^C). Diorite and gabbro also show positive εHf(t) (2.3–6.9) and yield Hf model ages of 2625–2788 Ma (T_DM) and 2647 Ma to 2903 Ma (T_DM^C). The Hf isotopic data indicate that the magmas were derived from Neoarchean-Mesoarchean juvenile sources.Integrating our data with those from the entire Jiaoliao microblock reveals vestiges of Hadean crust involved in building the Eoarchean nucleus of this microblock. Vigorous convergent margin processes ranging from Mesoarchean to late Neoarchean with multiple pules of arc magmatism associated with subduction tectonics led to further growth of continental crust, culminating in paired high temperature and high pressure metamorphism during late Neoarchean – early Paleoproterozoic transition.     

Zircon U–Pb age,Hf isotopic compositions and geochemistry of the Silurian Fengdingshan I-type granite Pluton and Taoyuan mafic–felsic Complex at the southeastern margin of the Yangtze Block

This work presents an integrated study of zircon U–Pb ages and Hf isotope along with whole-rock geochemistry on Silurian Fengdingshan I-type granites and Taoyuan mafic–felsic intrusive Complex located at the southeastern margin of the Yangtze Block, filling in a gap in understanding of Paleozoic I-type granites and mafic-intermediate igneous rocks in the eastern South China Craton (SCC). The Fengdingshan granite and Taoyuan hornblende gabbro are dated at 436 ± 5 Ma and 409 ± 2 Ma, respectively. The Fengdingshan granites display characteristics of calc-alkaline I-type granite with high initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7093–0.7127, low εNd(t) values ranging from −5.6 to −5.4 and corresponding Nd model ages (T_2DM) of 1.6 Ga. Their zircon grains have εHf(t) values ranging from −2.7 to 2.6 and model ages of 951–1164 Ma. The Taoyuan mafic rocks exhibit typical arc-like geochemistry, with enrichment in Rb, Th, U and Pb and depletion in Nb, Ta. They have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7053–0.7058, εNd(t) values of 0.2–1.6 and corresponding T_2DM of 1.0–1.1 Ga. Their zircon grains have εHf(t) values ranging from 3.2 to 6.1 and model ages of 774–911 Ma. Diorite and granodiorite from the Taoyuan Complex have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7065–0.7117, εNd(t) values from −5.7 to −1.9 and Nd model ages of 1.3–1.6 Ga. The petrographic and geochemical characteristics indicate that the Fengdingshan granites probably formed by reworking of Neoproterozoic basalts with very little of juvenile mantle-derived magma. The Taoyuan Complex formed by magma mixing and mingling, in which the mafic member originated from a metasomatized lithospheric mantle. Both the Fengdingshan and Taoyuan Plutons formed in a post-orogenic collapse stage in an intracontinental tectonic regime. Besides the Paleozoic Fengdingshan granites and Taoyuan hornblende gabbro, other Neoproterozoic and Indosinian igneous rocks located along the southeastern and western margin of the Yangtze Block also exhibit decoupled Nd–Hf isotopic systemics, which may be a fingerprint of a previous late Mesoproterozoic to early Neoproterozoic oceanic subduction.