New insights into peri-Gondwana paleogeography and the Gondwana super-fan system from detrital zircon U–Pb ages

We present a synopsis of detrital zircon U–Pb ages of sandstones from North Africa and neighboring Israel and Jordan, which allows us to identify zones with characteristic sediment provenance along the northern Gondwana margin (in present-day coordinates) in Cambrian–Ordovician times, and helps us to unravel the peri-Gondwana jigsaw puzzle. A special feature of the early Paleozoic cover sequence of North Africa is the eastward increase of 1.1–0.95 Ga detrital zircons, which become ubiquitous in the early Paleozoic sandstones of the Saharan Metacraton. Detrital zircons aged about 2.7–2.5, 2.15–1.75 and 0.75–0.53 Ga are also present. Early Paleozoic sandstones with similar provenance are known from peri-Gondwana terranes in the Eastern and Western Mediterranean and from NW Iberia. These terranes need not be transported from western Gondwana (Amazonia) as suggested previously. They were likely located to the north of the Saharan Metacraton during the early Paleozoic before they rifted off from Gondwana. Furthermore, we recognize an increase, as stratigraphic ages get younger, of ca. 1.0 Ga detrital zircons at some point between the Late Cambrian and late Middle Ordovician. We speculate that this might be linked to far-field tectonics and regional uplift in central Gondwana related to plate-tectonic reorganization along the Gondwana margin, leading to erosion of ca. 1.0 Ga basement and country rocks of the Transgondwanan supermountain and fluvial dispersal of detritus toward the Gondwana margin.     

Rutile geochemistry and thermometry of eclogites and associated garnet-mica schists in the Biga Peninsula,NW Turkey

In northwest Turkey, high-pressure metamorphic rocks occur as exotic blocks within the Çetmi mélange located on the south of the Biga Peninsula. Rutile chemistry and rutile thermometry obtained from the eclogite and associated garnet-mica schist in the Çetmi mélange indicate significant trace element behaviour of subducted oceanic crust and source-rock lithology of detrital rutiles. Cr and Nb contents in detrital rutile from garnet-mica schist vary from 355 to 1026 μg/g and 323 and 3319 μg/g, respectively. According to the Cr-Nb discrimination diagram, the results show that 85% of the detrital rutiles derived from metapelitic and 15% from metamafic rocks. Temperatures calculated for detrital rutiles and rutiles in eclogite range from 540 °C to 624 °C with an average of 586 °C and 611 °C to 659 °C with an average of 630 °C at P = 2.3 GPa, respectively. The calculated formation temperatures suggest that detrital rutiles are derived from amphibolite- and eclogite-facies metamorphic rocks. Amphibolite-facies rocks of the Kazdağ Massif could be the primary source rocks for the rutiles in the garnet-mica schist from the Çetmi mélange. Nb/Ta ratios of metapelitic and metamafic rutiles fall between 7–24 and 11–25, respectively. Nb/Ta characteristics in detrital rutiles may reflect a change in source-rock lithology. However, Nb/Ta ratios of rutiles in eclogite vary from 9 to 22. The rutile grains from eclogites are dominated by subchondritic Nb/Ta ratios. It can be noted that subchondritic Nb/Ta may record rutile growth from local sinks of aqueous fluids from metamorphic dehydration.     

Coupled U–Pb–Hf of detrital zircons of Cambrian sandstones from Morocco and Sardinia: Implications for provenance and Precambrian crustal evolution of North Africa

U–Pb–Hf of detrital zircons from diverse Cambrian units in Morocco and Sardinia were investigated in order to clarify the sandstone provenance and how it evolved with time, to assess whether the detrital spectra mirror basement crustal composition and whether they are a reliable pointer on the ancestry of peri-Gondwanan terranes. Coupled with Hf isotopes, the detrital age spectra allow a unique perspective on crustal growth and recycling in North Africa, much of which is concealed below Phanerozoic sediments.In Morocco, the detrital signal of Lower Cambrian arkose records local crustal evolution dominated by Ediacaran (0.54–0.63 Ga) and Late-Paleoproterozoic (1.9–2.2 Ga; Eburnian) igneous activity. A preponderance of the Neoproterozoic detrital zircons possess positive ε_Hf(t) values and their respective Hf model ages (T_DM) concentrate at 1.15 Ga. In contrast, rather than by Ediacaran, the Neoproterozoic detrital signal from the Moroccan Middle Cambrian quartz-rich sandstone is dominated by Cryogenian-aged detrital zircons peaking at 0.65 Ga alongside a noteworthy early Tonian (0.95 Ga) peak; a few Stenian-age (1.0–1.1 Ga) detrital zircons are also distinguished. The majority of the Neoproterozoic zircons displays negative ε_Hf(t), indicating the provenance migrated onto distal Pan-African terranes dominated by crustal reworking. Terranes such as the Tuareg Shield were a likely provenance. The detrital signal of quartz–arenites from the Lower and Middle Cambrian of SW Sardinia resembles the Moroccan Middle Cambrian, but 1.0–1.1 Ga as well as ~ 2.5 Ga detrital zircons are more common. Therefore, Cambrian Sardinia may have been fed from different sources possibly located farther to the east along the north Gondwana margin. 1.0–1.1 Ga detrital zircons abundant in Sardinia generally display negative ε_Hf(t) values while 0.99–0.95 Ga detrital zircons (abundant in Morocco) possess positive ε_Hf(t), attesting for two petrologically-different Grenvillian sources. A paucity of detrital zircons younger than 0.6 Ga is a remarkable feature of the detrital spectra of the Moroccan and Sardinian quartz-rich sandstones. It indicates that late Cadomian orogens fringing the northern margin of North Africa were low-lying by the time the Cambrian platform was deposited. About a quarter of the Neoproterozoic-aged detrital zircons in the quartz-rich sandstones of Morocco (and a double proportion in Sardinia) display positive ε_Hf(t) values indicating considerable juvenile crust addition in North Africa, likely via island arc magmatism. A substantial fraction of the remaining Neoproterozoic zircons which possess negative ε_Hf(t) values bears evidence for mixing of old crust with juvenile magmas, implying crustal growth in an Andean-type setting was also significant in this region.     

First evidence for Cambrian rift-related magmatism in the West African Craton margin: The Derraman Peralkaline Felsic Complex

West of the southern, Archean, part of the Reguibat Rise of the West African Craton the Oulad Dlim Massif consists of metamorphic nappes stacked during the Mauritanides (Variscan) orogeny. In the Derraman region, about 12 km west of the nappes, we have found strongly deformed hypersolvus aegirine-riebeckite A1-type granites with SHRIMP zircon U–Pb ages of ca. 525 ± 3 Ma, ε(Nd)_525Ma (− 5.2 to − 6.8.) and Nd model ages T_CR ≈ 1.85 Ga. These granites define two km-sized bodies and a few smaller satellites. One body is emplaced within a 3.12 Ga leucocratic gneiss. The other body and its satellites are emplaced within an Archean low-grade metasedimentary sequence with detrital zircons that have ages that peak at 2.84 Ga, 2.91 Ga, and 3.15 Ga. These Archean gneisses and metapelite rocks define a tectonic unit, hereafter called the Derraman-Bulautad-Leglat (DBL) unit, which was formed from the Reguibat basement at the very margin of the WAC. The ~ 525 Ma Derraman granites are the oldest post-Archean rocks in this unit and were generated in an intraplate rifting environment from melting of crustal fenites during the ubiquitous Cambrian rifting event that affected this part of northern Gondwana. At the present level of knowledge, however, we cannot decide whether the “old” Nd isotope signature of Derraman granites resulted from melting of an old (Paleoproterozoic) fenite source or reflects the signature of the mantle-derived metasomatising fluids. The just-discovered Derraman granites are strikingly similar to other rift-related Cambrian–Ordovician hypersolvus aegirine–riebeckite granites widespread in North Gondwana. Understanding the potential connections between them would help to understand the Cambrian–Ordovician breakdown of northern Gondwana.     

The dispersal of the Gondwana Super-fan System in the eastern Mediterranean: New insights from detrital zircon geochronology

We report here new LA-ICPMS detrital zircon U–Pb ages of a quartzite from the autochthon of Peloponnesus (Feneos locality), southern Greece. The rock classifies as a mature quartz arenite and belongs to an original shale–sandstone succession now metamorphosed into a phyllite–quartzite unit. Zircon age clusters at 0.52–0.75, 0.85, 0.95–1.1, 1.75–2 and 2.4–3 Ga point at the Saharan Metacraton and the Transgondwanan Supermountain as contributing sources; the youngest concordant grain is 522 Ma old. Our data collectively suggest deposition during the Cambro-Ordovician in a collisional setting and are in excellent agreement with those of the virtually intact Cambro-Ordovician sandstone–shale sequences of Libya (Murzuq and Kufrah basins) and the Middle East (Israel and Jordan), interpreted to have been deposited in the Gondwana Super-fan System which draped the northern Gondwanan periphery from ~ 525 to 460 Ma. By contrast, re-evaluating the available zircon age-distribution pattern and depositional setting of an analogous sequence forming the autochthon of north-central Crete (Galinos beds) we demonstrate that it was originally deposited in a completely different setting, i.e. in an accretionary/fore-arc complex outboard of the south Laurussian active margin (Pelagonia) during the Late Carboniferous. Comparing similar Cambro-Ordovician metasiliciclastic rocks from north-eastern Crete (Sfaka paragneiss), north-central continental Greece (Vertiskos terrane), north-western Turkey (central Sakarya terrane) and the Romanian Carpathians we show that their detrital zircon distribution patterns testify to an original depositional setting similar to that of Peloponnesus (Feneos), Libya and the Middle East. Using key time-frames from previously published palaeogeographic reconstruction models we are able to trace in space and time the Palaeozoic–Early Mesozoic wondering paths of the aforementioned sequences. Thus, time- and facies-equivalent rocks presently cropping out in the eastern Mediterranean share a common provenance from the Gondwana Super-fan System which was diachronously dispersed between Early Silurian and Early Triassic.     

Provenance of Neoproterozoic and early Paleozoic siliciclastic rocks of the Teplá-Barrandian unit (Bohemian Massif): Evidence from U–Pb detrital zircon ages

New LA-ICP-MS U–Pb detrital zircon ages from Ediacaran and Paleozoic siliciclastic rocks are used to constrain provenance and paleogeographic affinities of the Teplá-Barrandian unit (TBU) in the centre of the Bohemian Massif (Central Europe, Czech Republic). The samples taken span the period from ≤ 635 Ma to ～ 385 Ma and permit recognition of provenance changes that reflect changes in geotectonic regime. Detrital zircon age spectra of two Ediacaran, one Lower Cambrian and three Upper Ordovician samples resemble the ages known from the NW African proportion of Gondwana, particularly the Trans-Saharan belt, while three rocks from higher Lower Cambrian to Lowermost Ordovician strata contain detritus that may have been derived exclusively from local sources. The age spectrum of the Devonian rock is a combination of the NW Gondwanan and local features. These new findings in combination with a wide range of published data are in agreement with a Neoproterozoic subduction-related setting at the margin of Gondwana followed by a Cambrian/Early Ordovician rifting stage and an Ordovician passive margin setting. Furthermore the data are in favour of a position of the TBU at the Gondwanan margin throughout pre-Variscan times.     

Peri-Gondwanan origin and early geodynamic history of NE Sicily: A zircon tale from the basement of the Peloritani Mountains

The ages of detrital zircon grains from one paragneiss and inherited zircon cores from two augen gneisses from the amphibolite facies basement of the Peloritani Mountains (southern Italy) measured by SHRIMP U–Pb constrain the previously unknown deposition age of the original sediments and help to elaborate a model for their provenance and subsequent evolution. The deposition age is latest Neoproterozoic to Cambrian (~ 545 Ma), bracketed by the combined ages of the youngest detrital/inherited zircon populations and of zircon from virtually coeval granitoids that intrude the metasediments. This is consistent with the subgreenschist facies Palaeozoic volcano–sedimentary sequences exposed in the southern Peloritani Mountains being the original cover rocks of the northern Peloritani late Neoproterozoic to early Cambrian basement. The age spectra of the detrital/inherited zircon grains show that the Neoproterozoic/Cambrian sediments were derived from the erosion of sources dominated by Neoproterozoic rocks with ages in the range of 0.85–0.54 Ga, with other main components aged 1.1–0.9 and ~ 2.7–2.4 Ga, and a minor one aged ~ 1.6 Ga, as typically found in peri-Gondwanan terranes. The presence of a large amount of Grenvillian-aged zircon contradicts previous models that propose a West African affinity for the Calabria–Peloritani Terrane, and the absence of 2.2–1.9 Ga Trans Amazonian/Tapajós–Parima/Eburnean zircon rules out an Amazonian provenance. The age spectra are more consistent with the basement sediments having an East African origin, similar to that of the early Palaeozoic sandstones in southern Israel and Jordan, part of a “provenance regionality” shared with other terranes currently located in the eastern Mediterranean area.     

The Laurentia – West Greenland connection at 1.9 Ga: New insights from the Rinkian fold belt

U-Pb data from the Rinkian fold Belt, western Greenland, provide new constraints on provenance and timing of deposition of the Karrat Group, the emplacement interval of the Prøven Igneous Complex, and the tectonic setting of west Greenland during the interval 2.03–1.83 Ga. U-Pb detrital data establish the entire Karrat Group metasedimentary succession as Paleoproterozoic in age, initiated after ca. 2029 Ma (Qeqertarssuaq Formation), with deeper water deposition after 1953 ± 31 Ma and 1905 ± 20 Ma (Nûkavsak Formation). The detrital age profiles highlight a profound change in source region after ca. 1.95 Ga that we attribute to thickening, uplift, and exhumation related to collision of a juvenile magmatic arc with the northwest margin of Rae craton at ca. 1.97–1.95 Ga (Thelon Orogen). Accordingly, the Karrat Group is viewed as having initiated as an extensional rift basin(s) that received ca. 3.00–2.95 Ga detritus from local basement sources, and which evolved into a deeper water foreland-basin succession derived from the north. This foreland basin was intruded by the Prøven Igneous Complex, for which new U-Pb data establish emplacement between 1.90 and 1.87 Ga in a within-(Rae) plate setting. Prøven plutonism is coeval with lower-plate mantle magmatism elsewhere across NE Laurentia which may have been triggered by asthenospheric thinning due to plume-induced extension of lower-plate Rae craton at 1.95–1.92 Ga. Our data refute a direct link between the Prøven Igneous Complex and the voluminous 1.86–1.845 Ga Cumberland Batholith, Baffin Island, long considered its counterpart.     

Provenance of Ordovician clastic sequences of the San Rafael Block (Central Argentina), with emphasis on the Ponón Trehué Formation

The Ordovician Ponón Trehué Formation is the only early Palaeozoic sedimentary sequence known to record a primary contact with the Grenvillian-age basement of the Argentinean Cuyania terrane, in its southwards extension named the San Rafael block. Petrographic and geochemical data indicate contributions from a dominantly upper continental crustal component and a subordinated depleted component. Nd isotopes indicate ε_Nd of ? 4.6, ?_Sm/Nd ? 0.36 and T_DM 1.47 Ga in average. Pb-isotope ratios display average values for ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb of 19.15, 15.69 and 38.94 respectively. U–Pb detrital zircon ages from the Ponón Trehué Formation cluster around values of 1.2 Ga, indicating a main derivation from a local basement source (Cerro La Ventana Formation). The Upper Ordovician Pavón Formation records a younger episode of clastic sedimentation within the San Rafael block, and it shows a more complex detrital zircon age population (peaks at 1.1 and 1.4 Ga as well as Palaeoproterozoic and Neoproterozoic detrital grains). Detailed comparison between the two Ordovician clastic units indicates a shift with time in provenance from localized basement to more regional sources. Middle to early Upper Ordovician age is inferred for accretion of the Cuyania terrane to the proto-Andean margin of Gondwana.     

Ordovician ferrosilicic magmas: Experimental evidence for ultrahigh temperatures affecting a metagreywacke source

Peculiar magmatic rocks were erupted and emplaced at depth at the margin of the Gondwana supercontinent during the Cambro-Ordovician transition. These rocks are characterized by high contents in silica and iron but they do not have equivalents in the high-silica members of the calc-alkaline series. They have particular geochemical signatures, with Al saturation index, ASI > 1, FeO > 2.5 wt.%, MgO > 0.8 wt.% for very low contents in calcium (CaO < 2.0 wt.%), supporting a derivation from near-total melting (> 80 vol.% melt) of metagreywackes. The results from inverse experiments indicate that the most plausible conditions are within the range 1000 °C (excess water) and 1100–1200 °C (subsaturated and dry) at pressures of 1.5 to 2.0 GPa. A tectonic scenario implying melting of subducted sediments within an ascending mantle-wedge plume is suggested for the generation of primary ferrosilicic melts at the Gondwana continental margin during Upper Cambrian to Lower Ordovician times.     

Neoproterozoic–Early Cambrian tectono-magmatic evolution of the Central Iranian terrane,northern margin of Gondwana: Constraints from detrital zircon U–Pb and Hf–O isotope studies

U–Pb dating and oxygen and Lu–Hf isotope analyses are applied to ~ 400 detrital zircon grains from the Neoproterozoic–Cambrian Kahar, Bayandor and Zaigun sandstones. The results reveal the evolutionary history of the Central Iranian continental crust in the northern margin of Gondwana during the Neoproterozoic–Cambrian. The U–Pb dating produces major peaks of crystallization ages at 0.5–0.7 Ga and minor peaks around the Tonian, Paleoproterozoic and Neoarchean. The zircon population in the Zaigun sandstone is dominated by long-transported grains and exhibits slightly different zircon distribution patterns than those from the older Kahar and Bayandor units. The zircon population ages and Hf isotopes of the Zaigun sample are very similar to the Neoproterozoic–Early Palaeozoic siliciclastic units in the Arabian Nubian shield (ANS) and Turkey, which suggests the late to post–Pan-African unroofing of the Afro–Arabia realm as the main process for detritus accumulation in Central Iran during the early Palaeozoic. A significant proportion of the Tonian-aged zircons (~ 64%) in the Kahar and Bayandor samples show positive εHf_(t) values, whereas those with late Cryogenian–Ediacaran ages have high δ¹⁸O and variable εHf_(t) values (~− 30‰ to + 17‰), suggesting that the crustal evolution of provenance of the Tonian-aged zircons commenced in an island arc setting and continued in an active continental margin. All the samples contain pre-Neoproterozoic zircons that are ca 1.9–2.3 Ga or 2.5–3.2 Ga, which are much older than the known Neoproterozoic igneous rocks in Iran and are more consistent with pre-Neoproterozoic igneous-metamorphic rocks in the eastern ANS and northern Africa. These ages support the eastern sector of the Afro–Arabia margin as a provenance for the detrital zircons in the oldest sedimentary sequences of Iran during the late Neoproterozoic–Cambrian. The Hf model ages of zircons with mantle-like δ¹⁸O values suggest that a significant amount of continental crust in the provenance of the detrital zircons was generated at around 1.0–2.0 and 3.0–3.5 Ga, likely by mantle-derived mafic magmas, and subsequently reworked during crustal differentiation into younger, more felsic crust with varying crustal residence times.     

Detrital zircon ages from the Ross Supergroup,north Victoria Land,Antarctica: Implications for the tectonostratigraphic evolution of the Pacific-Gondwana margin

We present new U–Pb isotopic age data for detrital zircons from 16 deformed sandstones of the Ross Supergroup in north Victoria Land, Antarctica. Zircon U/Th ratios primarily point to dominantly igneous parent rocks with subordinate contributions from metamorphic sources. Comparative analysis of detrital zircon age populations indicates that inboard stratigraphic successions (Wilson Terrane) and those located outboard of the East Antarctic craton (the Bowers and Robertson Bay terranes) have similar ~ 1200–950 Ma (Mesoproterozoic–Neoproterozoic) and ~ 700–490 Ma (late Neoproterozoic–Cambrian, Furongian) age populations. The affinity of the age populations of the sandstones to each other, as well as Gondwana sources and Pacific-Gondwana marginal stratigraphic belts, challenges the notion that the outboard successions form exotic terranes that docked with Gondwana during the Ross orogeny and instead places the terranes in proximity to each other and within the peri-Gondwana realm during the late Neoproterozoic to Cambrian. The cumulative zircon age suite from north Victoria Land yields a polymodal age spectra with a younger, primary 700–480 Ma age population that peaks at ~ 580 Ma. Cumulative analysis of zircons with elevated U/Th ratios (> 20) indicating metamorphic heritage yield ~ 657–532 Ma age probability peaks, which overlap with the younger dominantly igneous zircon population. The data are interpreted to give important new evidence that is consistent with ongoing convergent arc magmatism by ~ 626 Ma, which provided the dominant zircon-rich igneous rocks and subordinate metamorphic rocks. Maximum depositional ages as young as ~ 493–481 Ma yielded by deformed sequences in the outboard Bowers and Robertson Bay terrane samples provide new support for late Cambrian to Ordovician deformation in outboard sectors of the orogen, consistent with tectonic models that call for cyclic phases of contraction along the north Victoria Land sector of the Ross–Delamerian orogen.     

Detrital zircon U-Pb-Hf isotopes and provenance of Late Neoproterozoic and Early Paleozoic sediments of the Simao and Baoshan blocks,SW China: Implications for Proto-Tethys and Paleo-Tethys evolution and Gondwana reconstruction

Early Paleozoic evolution of the northern Gondwana margin is interpreted from integrated in situ U-Pb and Hf-isotope analyses on detrital zircons that constrain depositional ages and provenance of the Lancang Group, previously assigned to the Simao Block, and the Mengtong and Mengdingjie groups of the Baoshan Block. A meta-felsic volcanic rock from the Mengtong Group yields a weighted mean ²⁰⁶Pb/²³⁸U age of 462 ± 2 Ma. The depositional age for the previously inferred Neoproterozoic Lancang and Mengtong groups is re-interpreted as Early Paleozoic based on youngest detrital zircons and meta-volcanic age. Detrital U-Pb zircon analyses from the Baoshan Block define three distinctive age peaks at older Grenvillian (1200–1060 Ma), younger Grenvillian (~ 960 Ma) and Pan-African (650–500 Ma), with εHf(t) values for each group similar to coeval detrital zircons from western Australia and northern India. This suggests that the Baoshan Block was situated in the transitional zone between northeast Greater India and northwest Australia on the Gondwana margin and received detritus from both these cratons. The Lancang Group yields a very similar detrital zircon age spectrum to that of the Baoshan Block but contrasts with that for the Simao Block. This suggests that the Lancang Group is underlain by a separate Lancang Block. Similar detrital zircon age spectra suggest that the Baoshan Block and the Lancang Block share common sources and that they were situated close to one another along the northern margin of East Gondwana during the Early Paleozoic. The new detrital zircon data in combination with previously published data for East Gondwana margin blocks suggests the Early Paleozoic Proto-Tethys represents a narrow ocean basin separating an “Asian Hun superterrane” (North China, South China, Tarim, Indochina and North Qiangtang blocks) from the northern margin of Gondwana during the Late Neoproterozoic-Early Paleozoic. The Proto-Tethys closed in the Silurian at ca. 440–420 Ma when this “Asian Hun superterrane” collided with the northern Gondwana margin. Subsequently, the Lancang Block is interpreted to have separated from the Baoshan Block during the Early Devonian when the Paleo-Tethys opened as a back-arc basin.     

Detrital provenance evolution of the Ediacaran–Silurian Nanhua foreland basin,South China

We report here in-situ U–Pb and Hf isotopic results of detrital zircons from sixteen Cambrian–Silurian siliciclastic samples across the Nanhua foreland basin, South China. Together with published data from Ediacaran–Silurian sandstones in the region, we establish the temporal and spatial provenance evolution across the basin. Except for samples from northeast Yangtze, all other Ediacaran–Silurian samples exhibit a prominent population of 1100–900 Ma, moderate populations of 850–700 Ma and 650–490 Ma, and minor populations of 2500 Ma and 2000–1300 Ma, grossly matching that of crystalline and sedimentary rocks in northern India. Zircon Hf isotopes further reveal four episodes of juvenile crustal growth at 2.5 Ga, 1.8 Ga, 1.4 Ga and 1.0 Ga in the source regions. Utilizing the basin history and late Neoproterozoic to early Paleozoic paleogeography of South China, we conclude that the Ediacaran–Cambrian sediments in the Nanhua foreland basin were mainly sourced from northern India and adjacent orogens, and the Ordovician–Silurian sediments were derived from both locally recycled Ediacaran–Cambrian rocks and eroded Cathaysian basement. The Wuyi–Yunkai late-orogenic magmatic rocks also contributed to the Silurian sediments in the basin. The upper-Ordovician to Silurian samples in northeast Yangtze received higher proportions of local Cryogenian (850–700 Ma) magmatic rocks which were uplifted during late-Ordovician to Silurian time. We speculate that there was an Ediacaran–Cambrian collisional orogen between South China and northern India, shedding sediments to the early Nanhua foreland basin. Far-field stress during the late stage of this collisional orogeny triggered the Ordovician–Silurian intraplate Wuyi–Yunkai orogeny in South China, and erosion of the local Wuyi–Yunkai orogen further provided detritus to the late Nanhua foreland basin.     

Assembly of Pampia to the SW Gondwana margin: A case of strike-slip docking?

Different hypotheses have been proposed to account for the geologic evolution of the southwestern margin of Gondwana in the Early Paleozoic, involving accretion and displacement of different terranes in a protracted convergent margin. In order to constrain and understand the kinematic and paleogeographic evolution of the Pampia terrane a paleomagnetic study was carried out in different Cambrian to Devonian units of the Eastern Cordillera (Cordillera Oriental) and the Interandean Zone (Interandino) of NW Argentina. Paleomagnetic poles from the Campanario Formation (Middle to Upper Cambrian): 1.5°N 1.9°E A₉₅ = 9.2° K = 37.46 N = 8; and Santa Rosita Formation (Lower Ordovician): 8.6°N 355.3°E A₉₅ = 10.1° K = 26.78 n = 9, representative of the Pampia terrane, are interpreted to indicate a Late Cambrian significant displacement with respect to the Río de la Plata and other Gondwana cratons. A model, compatible with several geological evidences that explains this displacement in the framework of the final stages of Gondwana assembly is presented. We propose a simple dextral strike-slip kinematic model in which Pampia and Antofalla (? Arequipa?) blocks moved during Late Cambrian times from a position at the present southern border of the Kalahari craton into its final position next to the Rio de la Plata craton by the Early Ordovician.     

Tracing the position of the South China block in Gondwana: U–Pb ages and Hf isotopes of Devonian detrital zircons

U–Pb detrital zircon geochronology from Lower Devonian quartz arenites of the northwestern margin of the Yangtze block yields dominant early Neoproterozoic (0.85–1.0 Ga), Pan-African (0.5–0.65 Ga) and middle Neoproterozoic (0.68–0.8 Ga) age populations and minor Mesoproterozoic to middle Mesoarchean (1.0–3.0 Ga) ages. Middle Mesoarchean to Mesoproterozoic rocks, however, are widespread in the South China block. Although Hf isotopic compositions show both juvenile crustal growth and crustal reworking for all the age groupings, the crust growth, essentially mantle-derived, occurred mainly around 3.1 Ga, 1.9 Ga and 1.0 Ga, respectively. Zircon typology and youngest grain ages indicate that this suite of quartz arenites was the product of multiphase reworking. Abundant magmatic zircon detritus with concordant U–Pb Grenvillian and Pan-African ages, together with accompanying various ε_Hf(t) values, indicate an exotic provenance for the quartz arenite external to the South China block. Qualitative comparisons of age spectra for the late Neoproterozoic sediments of the Cathaysian Block, early Paleozoic sediments of pre-rift Tethyan Himalaya sequence in North India and lower Paleozoic sandstone from the Perth Basin in West Australia, show that they all have two the largest age clusters representing Grenvillian and Pan-African orogenic episodes. The resemblance of these age spectra and zircon typology suggests that the most likely source for the Lower Devonian quartz arenites of the South China block was the East African Orogen and Kuunga Orogen for their early Grenvillian and Pan-African populations, whereas the Hannan–Panxi arc, Jiangnan orogen, and the Yangtze block basements might have contributed to the detrital zircon grains of the Neoproterozoic and Pre-Grenvillian ages. Hf isotopic data indicate that the crustal evolution of the drainage area matches well with the episodic crust generation of Gondwana. These results imply that the previously suggested position of the SCB in Gondwana should be re-evaluated, and the South China block should be linked with North India and West Australia as a part of East Gondwana during the assembly of Gondwana, rather than a discrete continent block in the paleo-Pacific.     

Evolution and provenance of Neoproterozoic basement and Lower Paleozoic siliciclastic cover of the Menderes Massif (western Taurides): Coupled U–Pb–Hf zircon isotope geochemistry

In the Menderes Massif (western Taurides) a Neoproterozoic basement comprising metasediments and intrusive granites is imbricated between Paleozoic platform sediments. U–Pb–Hf zircon analyses of Menderes rock units were performed by us using LA-ICP-MS. The U–Pb detrital zircon signal of the Neoproterozoic metasediments is largely consistent with a NE African (Gondwana) provenance. The oldest unit, a paragneiss, contains significant amounts (~ 30%) of Archean-aged zircons and εHf (t) values of about a half of its Neoproterozoic zircons are negative suggesting contribution from Pan-African terranes dominated by reworking of an old crust. In the overlying, mineralogically-immature Core schist (which is still Neoproterozoic), the majority of the detrital zircons are Neoproterozoic, portraying positive εHf (t) values indicating derivation from a proximal juvenile source, resembling the Arabian–Nubian Shield.The period of sedimentation of the analyzed metasediments, is constrained between 570 and 550 Ma (Late Ediacaran). The Core schist sediments, ~ 9 km thick, accumulated in less than 20 My implying a tectonic-controlled sedimentary basin evolved adjacent to the eroded juvenile terrane. Granites, now orthogneisses, intruded the basin fill at 550 Ma, they exhibit ± 0 εHf (t = 550 Ma) and T_DM ages of 1.4 Ga consistent with anatexis of various admixtures of juvenile Neoproterozoic and Late Archean detrital components. Granites in the northern Arabian–Nubian Shield are no younger than 580 Ma and their εHf (t) are usually more positive. This implies that the Menderes does not represent a straightforward continuation of the Arabian–Nubian Shield.The lower part of the pre-Carboniferous silisiclastic cover of the Menderes basement, comprises a yellowish quartzite whose U–Pb–Hf detrital zircon signal resembles that of far-traveled Ordovician sandstones in Jordan (including 0.9–1.1 Ga detrital zircons), supporting pre-Triassic paleorestorations placing the Tauride with Afro-Arabia. The detrital signal of the overlying carbonate-bearing quartzitic sequence indicates contribution from a different source: the majority of its detrital zircons yielded 550 Ma and ± 0 εHf (t = 550 Ma) values identical to that of the underlying granitic gneiss implying exposure of Menderes-like granites in the provenance.260–250 Ma lead-loss and partial resetting of the U–Pb system of certain zircons in both basement and cover units was detected. It is interpreted as a consequence of a Permian–Early Triassic thermal event preceding known Triassic granitoid intrusions.     

Strike-slip tectonics during the Neoproterozoic–Cambrian assembly of East Gondwana: Evidence from a newly discovered microcontinent in the Indian Ocean (Batavia Knoll)

The first dredge samples recovered from the Batavia Knoll in the eastern Indian Ocean demonstrate it is a rifted continental fragment that now lies submerged in 2 km of water between the Perth Abyssal Plain and Wharton Basin, ~ 1600 km offshore Western Australia. This knoll is the second microcontinent to have been discovered in this region, lying ~ 180 km to the NE of Gulden Draak Knoll; both knolls rifted from the Indian margin at c. 104–101 Ma during the breakup of East Gondwana. Dredged rocks include granite, granodiorite, charnockite and quartz-rich pegmatite, preserving igneous microstructure and biotite-schlieren. The composite nature of many samples suggests derivation from a felsic igneous complex. This basement is at least partly covered by Late Cretaceous sedimentary strata. Zircon grains from five representative granitoid samples primarily display modified oscillatory zoning and U-Pb data that spread along concordia over ~ 50–70 m.y., suggesting protracted magmatism and Pb-loss during the latest Neoproterozoic–early Cambrian (c. 580–530 Ma). Despite the span in U-Pb zircon ages, the primary igneous populations exhibit a relatively narrow range of initial Hf isotopic ratios (Hf_i = 0.281290–0.281814; εHf_i = − 41.40 to − 23.32). This evolved nature of the Hf signature suggests derivation of melts from ancient crust (T_DM2 = 4.05–2.92 Ga) with very limited juvenile input. Plate models based on sparse paleomagnetic data imply significant relative motion between India and Australia during the late Neoproterozoic–Cambrian. We suggest the new isotopic data from the Batavia Knoll granitic rocks, coupled with other regional geological constraints, are consistent with magmatic intrusion and subsequent disturbance of U-Pb systems along a late Neoproterozoic–Cambrian sinistral strike-slip margin related to Gondwana assembly.     

Geochemistry of the apulian allochthonous karst bauxite,Southern Italy: Distribution of critical elements and constraints on Late Cretaceous Peri-Tethyan palaeogeography

A comprehensive study of pebbles from the 'Salento-type' allochthnous bauxite deposit (Otranto, southern Italy), originally derived from a pristine Campanian bauxite, has been performed for evaluating: 1) the chemical fractionation and inter-elemental relationships, especially for critical elements, 2) the climatic conditions that promoted bauxite formation, and 3) the provenance of the protolith(s) using zircon age data and conservative elemental proxies. The study confirms the capability of bauxite to concentrate many elements defined as critical by the European Union report on critical raw materials. Sc, Co, Ga, and especially Cr, are enriched when compared with the UCC composition and assuming Nb is immobile. Other critical elements such as the REEs, with the exception of La, are moderately depleted. R-mode factor analysis suggests that most of the variance in our chemical dataset is explained by a factor with significant weightings for TiO₂, Al₂O₃, Fe₂O₃, Sc, V, Nb, REEs, Pb and Th. This arises from climate effects affecting the distribution of the more abundant oxides and some trace elements, including the critical metals Nb and REEs. The texture of the pebbles is typical for Apulian karst bauxites and consists of sub-spheroidal ooids composed of boehmite and dispersed in a fine-grained matrix. The growth of the ooids, which formed under dry climate, was described in terms of fractal geometry. The average fractal dimension value of the ooids in the pebbles is close to that of the diffusion-limited aggregation models suggesting the ooid growth can be modelled using a molecular diffusion pattern, based on Fick's first law. The calculated time required for growth of the boehmite concretions is ~ 45 ÷ 310 ka. This finding is consistent with an intra-Campanian emersion event (74–76 Ma) that occurred during a dry and warm climatic stage. Since most of the karst bauxites worldwide have an ooidic texture, evaluation of the composition of concretions and the time required for their growth represents a powerful tool in reconstructing the palaeoenvironment. The zircon grains collected from the pebbles of the Salento-type karst bauxite define several concordant age populations. The youngest cluster, Early Cretaceous in age (99 ÷ 127.5 Ma), suggests that windborne particles from Cretaceous volcanics, possibly originating in the Carpatho-Balkan orogenic belts, provided material for further bauxitisation. The largest cluster (623 ÷ 689 Ma) is of Neoproterozoic age, predominately from the Late Ediacaran and Cryogenian p.p.. The 900–540 Ma Pan-African orogenic cycle was followed by continental-scale uplift and erosion, leading to the deposition of thick Cambrian–Ordovician siliciclastic sequences that represent the most widespread detrital sequence ever deposited on continental crust and that now cover large parts of North Africa. These Cambrian–Ordovician sandstones contain a large population of Neoproterozoic zircons of Cryogenian age. Neoproterozoic zircons also occur in the youngest (Silurian–Mesozoic) sandstones of the Saharan Metacraton. These sandstones also contain 1.0 Ga detrital zircons, suggesting as the oldest zircons found in the Salento-type bauxite pebbles (866 Ma and 941 Ma in age) are younger representatives of the zircon cluster present in this sandstone unit.These zircon age determinations suggest that the source material for the Salento-type bauxite pebbles was a combination of magmatic material from a distant source and clastic material derived from a continental margin (North Africa). This result concurs with the Eu/Eu* vs. Sm/Nd binary diagram, on which bauxite pebbles fall close to a mixing curve with andesite and cratonic sandstone end-members. As our results indicate that material was sourced from the North African continental margin, we suggest that a continental bridge separated oceanic domains in the Late Cretaceous of the Peri-Tethyan domain.     

U–Pb and Hf isotope data from zircons in the Macquarie Arc,Lachlan Orogen: Implications for arc evolution and Ordovician palaeogeography along part of the east Gondwana margin

The Ordovician Macquarie Arc in the eastern subprovince of the Lachlan Orogen, southeastern Australia, is an unusual arc that evolved in four vertically stacked volcanic phases over ~ 37 million years, and which is flanked by coeval, craton-derived, passive margin sedimentary terranes dominated by detrital quartz grains. Although these two terranes are marked by a general absence of provenance mixing, LA-ICPMS analysis of U–Pb and Lu–Hf contents in zircon grains in volcaniclastic rocks from 3 phases of the arc demonstrates the same age populations of detrital grains inherited from the Gondwana margin as those that characterise the flanking quartz-rich Ordovician turbidites. Magmatic Phase 1 is older, ~ 480 Ma, and is characterised by detrital zircons grains with ages of ~ 490–540 with negative ε_Hf from 0 to mainly –7.78, 550–625 Ma ages with negative ε_Hf from 0 to ?26.6 and 970–1250 Ma (Grenvillian) with ε_Hf from + 6.47 to ?6.44. We have not as yet identified any magmatic zircons related to Phase 1 volcanism. Small amounts of detrital zircons also occur in Phase 2 (~ 468–455 Ma), hiatus 1 and Phase 4 (~ 449–443 Ma), all of which are dominated by Ordovician magmatic zircons with positive ε_Hf values, indicating derivation from unevolved mantle-derived magmas, consistent with formation in an intraoceanic island arc. Because of the previously obtained positive whole rock ε_Nd values from Phase 1 lavas, we rule out contamination from substrate or subducted sediments. Instead, we suggest that during Phase 1, the Macquarie Arc lay close enough to the Gondwana margin so that volcaniclastic rocks were heavily contaminated by detrital zircon grains shed from granites and Grenvillian mafic rocks mainly from Antarctica (Ross Orogen and East Antarctica) and/or the Delamerian margin of Australia. The reduced nature of a Gondwana population in Phase 2, hiatus 1 and Phase 4 is attributed to opening of a marginal basin between the Gondwana margin and the Macquarie Arc that put it out of reach of all but rare turbiditic currents.