The Olkhon metamorphic terrane in the Baikal region: An Early Paleozoic collage of Neoproterozoic active margin fragments

We report data from the Khadarta, Khoboi, and Orso metamorphic complexes of the Olkhon terrane in the western Baikal region. High-grade rocks in the three complexes may have been derived from active continental margin rocks (island arc–backarc basin system). The backarc basin history possibly began at 840–800 Ma, according to SHRIMP-II U-Pb zircon ages of the Orso gneiss. Many tectonic units in the Olkhon terrane belonged to the active margin of the Barguzin microcontinent which rifted off the Aldan province of the Siberian craton in the early Neoproterozoic. The accretion of the microcontinent to the craton was accompanied by high-grade metamorphism recorded in the Khadarta and Khoboi granulites. The 507 ± 8 Ma and 498 ± 7 Ma SHRIMP-II U-Pb zircon ages of the latter complexes, respectively, may refer to the earliest evolution stage of the Olkhon metamorphic terrane. New data for the Olkhon terrane agree well with the ages of other high-grade complexes along the southern Siberian craton (Slyudyanka, Kitoikin, Derba) and correspond to the initiation of the Central Asian orogen. With these data, the Olkhon metamorphic terrane has been interpreted as an Early Paleozoic collisional collage of fragments of the microcontinent’s Neoproterozoic active margin.     

A new fragment of the early earth crust: the Aasivik terrane of West Greenland

The Aasivik terrane is a ∼1500 km² complex of gneisses dominated by ∼3600 Ma components, which has been discovered in the Archaean craton of West Greenland, ∼20–50 km south of the Paleoproterozoic Nagssugtoqidian orogen. The Aasivik terrain comprises granulite facies tonalitic to granitic gneisses with bands of mafic granulite, which include disrupted mafic dykes. Four gneiss samples of the Aasivik terrain have given imprecise SHRIMP U–Pb zircon ages of 3550–3780 Ma with strong loss of radiogenic lead and new growth of zircon probably associated with a granulite facies metamorphic event(s) at ∼2800–2700 Ma. To the Southeast, the Aasivik terrane is in tectonic contact with a late Archaean complex of granitic and metapelitic gneisses with apparently randomly distributed mafic and ultramafic units, here named the Ukaleq gneiss complex. Two granitic samples from the Ukaleq gneiss complex have U–Pb zircon ages of 2817 ± 10 and 2820 ± 12 Ma and t_zircon ε_Nd values of 2.3–5.4. Given their composition and positive ε_Nd values, they probably represent melts of only slightly older juvenile crust. A reconnaissance SHRIMP U–Pb study of a sample of metasedimentary rock from the Ukaleq gneiss complex found ∼2750–2900 Ma zircons of probable detrital origin and that two or more generations of 2700–2500 Ma metamorphic zircons are present. This gneiss complex is provisionally interpreted as a late Archaean accretionary wedge. A sample of banded granulite facies gneiss from a complex of banded gneisses south of the Aasivik terrain here named the Tasersiaq gneiss complex has yielded two zircon populations of 3212 ± 11 and 3127 ± 12 Ma. Contacts between the three gneiss complexes are mylonites which are locally cut by late-post-kinematic granite veins with SHRIMP U–Pb zircon ages of ∼2700 Ma. The isotopic character and the relationships between the lithologies from the different gneiss complexes suggest the assembly of unrelated rocks along shear zones between 2800 and 2700 Ma. The collage of Archaean gneiss complexes were intruded by A-type granites, here named the Umiatsiaasat granites, at ∼2700 Ma, later than the tectonic intercalation of the gneiss complexes.     

The early Paleozoic tectonic evolution of the Russian Altai: Implications from geochemical and detrital zircon U–Pb and Hf isotopic studies of meta-sedimentary complexes in the Charysh–Terekta–Ulagan–Sayan suture zone

The Charysh–Terekta–Ulagan–Sayan suture zone was regarded as a tectonic boundary separating two distinct subduction–accretion systems in the Central Asian Orogenic Belt (CAOB). In the north, magmatic arcs, such as the Gorny Altai terrane, formed in the southwestern periphery of the Siberian continent, whereas in the south, arc-prism systems, such as the Altai–Mongolian terrane, formed around the so-called Kazakhstan–Baikal composite continent with Gondwana affinity. When did these two systems amalgamate and whether the metamorphic complexes in the suture zone represent Precambrian micro-continental slivers are critical for our understanding of the accretionary orogenesis and crustal growth rate in the CAOB. A combined geochemical and detrital zircon U–Pb–Hf isotopic study was conducted on the meta-sedimentary rocks from the Ulagan (also referred to Bashkaus) and Teletsk Complexes in the suture zone. The results indicate that the protoliths of these rocks were dominated by immature sediments deposited in a time period between 500 and 420 Ma. Thus, Precambrian micro-continental slivers may not exist in the suture zone and even in the whole Altai Orogen.The meta-sedimentary rocks from the Ulagan Complex yield geochemical compositions between those of common intermediate and felsic igneous rocks, implying that these kinds of rocks possibly served as dominant sources. Detrital zircons from this complex consist of a major population of ca. 620–500 Ma, a subordinate one of ca. 931–671 Ma and rare grains of ca. 2899–1428 Ma. This age spectrum is compatible with the magmatic records of the western Mongolia. We propose that the Ulagan Complex possibly represents part of a subduction–accretion complex built upon an active continental margin of the western Mongolia in the early Paleozoic. The remarkable similarities in source nature, provenance, and depositional setting to the early Paleozoic meta-sedimentary rocks from the northern Altai–Mongolian terrane imply that the Ulagan Complex was possibly fragmented from this terrane.The meta-sedimentary rocks from the Teletsk Complex show similar detrital zircon populations but contain higher proportions of mafic sediments and have more depleted whole-rock Nd isotopic compositions. Our data suggest that the detritus mostly came from the same source as that for the Ulagan Complex but those from the Gorny Altai terrane also contributed. This implies that the Gorny Altai and Altai-Mongolian terranes possibly amalgamated prior to the early Devonian rather than in the middle Devonian to early Carboniferous as previously thought. Thus, the widespread Devonian to early Carboniferous magmatism within these two terranes was possibly generated in a similar tectonic setting. Moreover, the dominant Neoproterozoic to early Paleozoic detrital zircons from the Teletsk Complex yield largely varied ɛ_Hf(t) values of − 23.8 to 12.4, indicating that crustal growth and reworking are both important in the accretionary orogenesis.     

Identification and isotopic studies of early Cambrian magmatism (El Carancho Igneous Complex) at the boundary between Pampia terrane and the Río de la Plata craton,La Pampa province,Argentina

We have identified late Early Cambrian metaigneous rocks very poorly exposed at the Estancia El Carancho, in central La Pampa province, Argentina. They comprise calc–alkaline metadiorite and metagranite, and tholeiitic metapyroxenite and metagabbro. They are jointly referred to as the El Carancho Igneous Complex, and regarded to pertain to the Pampean magmatic arc and backarc, respectively. Titanite U–Pb SHRIMP dating of the metapyroxenite yielded 528 ± 5 Ma, and zircon U–Pb SHRIMP dating of the metadiorite yielded 520 ± 1.4 Ma. Hafnium isotope determinations on the dated zircons show ¹⁷⁶Hf/¹⁷⁷Hf ratios corresponding to positive εHf values from + 7.18 to + 9.37; Hf model ages of the Cambrian zircons yielded 884 Ma. It is interpreted that the metadiorites of the Complex crystallized from an Early Neoproterozoic (Tonian) juvenile source. We argue that the inferred occurrence of juvenile Tonian magmatic rocks in the (otherwise, mostly Paleo-Mesoproterozoic) substratum of the southern Pampia terrane could indicate a zone of thinned basement possibly associated with the early stage of Rodinia's breakup. In addition, the studied segment of the Pampean magmatic arc is contaminated by also juvenile, Late Mesoproterozoic crust, as evidenced by the presence of xenocrystic cores of 1140–1194 Ma – T_DM-Hf 1720 Ma and εHf values of + 3.24 to + 4.85 – in the Cambrian zircons, hence suggesting that the studied segment of the Pampean magmatic arc was intruded into juvenile Late Mesoproterozoic magmatic arc rocks. The El Carancho Igneous Complex would be located at the tectonic boundary between the Pampia terrane and the Río de la Plata craton. This boundary stands out in the aeromagnetic data as a change in the structural orientation about a roughly N-S line located approximately at 65° W and representing the suture zone between the Pampia terrane and the Río de la Plata craton. Our geotectonic model envisages westward dipping subduction of oceanic crust beneath the Pampia terrane; the El Carancho Igneous Complex would, therefore, have been originated on the Pampia side (upper plate) of the suture. Slivers of the arc- and backarc-type rocks would have been tectonically imbricated in the suture zone during the Pampean orogeny.     

The Guarguaraz Complex and the Neoproterozoic–Cambrian evolution of southwestern Gondwana: Geochemical signatures and geochronological constraints

The Guarguaraz Complex, in western Argentina, comprises a metasedimentary assemblage, associated with mafic sills and ultramafic bodies intruded by basaltic dikes, which are interpreted as Ordovician dismembered ophiolites. Two kinds of dikes are recognized, a group associated with the metasediments and the other ophiolite-related. Both have N-MORB signatures, with ε_Nd between +3.5 and +8.2, indicating a depleted source, and Grenville model ages between 0.99 and 1.62 Ga. A whole-rock Sm–Nd isochron yielded an age of 655 ± 76 Ma for these mafic rocks, which is compatible with cianobacteria and acritarchae recognized in the clastic metasedimentary platform sequences, that indicate a Neoproterozoic (Vendian)–Cambrian age of deposition.The Guarguaraz metasedimentary–ophiolitic complex represents, therefore, a remnant of an oceanic basin developed to the west of the Grenville-aged Cuyania terrane during the Neoproterozoic. The southernmost extension of these metasedimentary sequences in Cordón del Portillo might represent part of this platform and not fragments of the Chilenia terrane. An extensional event related to the fragmentation of Rodinia is represented by the mafic and ultramafic rocks. The Devonian docking of Chilenia emplaced remnants of ocean floor and slices of the Cuyania terrane (Las Yaretas Gneisses) in tectonic contact with the Neoproterozoic metasediments, marking the Devonian western border of Gondwana.     

First evidence of the Cambrian basement in Upper Peninsula of Thailand and its implication for crustal and tectonic evolution of the Sibumasu terrane

Although the Sibumasu terrane in Asia was previously considered to be composed of Phanerozoic rocks with Cambrian crystalline basement, no reliable or direct radiometric dating evidences of such crystalline basement was ever reported. Our new in-situ zircon U/Pb dating of the Khao Tao orthogneiss yields a concordant age of 501.5 ± 7.5 Ma (2σ), which provides the first robust evidence for the Cambrian crust in Upper Peninsula of Thailand. The zircon εHf_(T) values range from + 3.7 to − 6.1 with model ages (T^C_DM) of 1244–1827 Ma, suggests a mixed crust-mantle source. The chemical similarity and spatial continuity of the Khao Tao orthogneiss with other pre-Neotethys marginal Eurasian and Sibumasu granitoids indicate the linear paleogeographic association under a similar magmatic arc-related regime along the Gondwana India–Australia margin as part of the Pan-African Orogeny system.     

Petrogenesis of ore-forming and pre/post-ore granitoids from the Kounrad,Borly and Sayak porphyry/skarn Cu deposits,Central Kazakhstan

Ore-forming porphyries and barren granitoids from porphyry Cu deposits differ in many ways, particularly with respect to their adakitic affinity and calc-alkaline characteristics. In this study, zircon U–Pb and molybdenite Re–Os dating, whole rock geochemistry, whole rock Sr–Nd–Pb and zircon O–Hf isotopic analyses were carried out on the ore-forming granitoids from the Kounrad, Borly and Sayak deposits, and also on pre-ore and post-ore granitoids in adjacent regions of Central Kazakhstan. Geochronology results indicate that pre-ore magmatism occurred in the Late Devonian to Early Carboniferous (361.3–339.4 Ma), followed by large scale Cu mineralization (325.0–327.3 Ma at Kounrad, 311.4–315.2 Ma at Borly and 309.5–311.4 Ma at Sayak), and finally, emplacement of the Late Carboniferous post-ore barren granitoids (305.0 Ma). The geochemistry of these rocks is consistent with calc-alkaline arc magmatism characterized by strong depletions in Nb, Ta and Ti and enrichments in light rare earth elements and large ion lithophile elements, suggesting a supra-subduction zone setting. However, the ore-forming rocks at Kounrad and Sayak show adakitic characteristics with high Sr (517.5–785.3 ppm), Sr/Y (50.60–79.26), (La/Yb)_N (9.37–19.62) but low Y (6.94–11.54 ppm) and Yb (0.57–1.07 ppm), whereas ore-forming rocks at Borly and barren rocks from northwest of Borly and Sayak have normal arc magma geochemical features. The Sr–Nd–Hf–O isotopic compositions show three different signatures: (1) Sayak granitoids have very young juvenile lower crust-derived compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.70384 to 0.70451, ɛ_Nd (t) = + 4.9 to + 6.0; T_DM2 (Nd) = 580 to 670 Ma, ɛ_Hf (t) = + 11.3 to + 15.5; T_DM^C (Hf) = 330 to 600 Ma, δ¹⁸O = 6.0 to 8.1‰), and were probably generated from depleted mantle-derived magma with 5–15% sediment melt addition in the magma source; (2) the Kt-1 granite from northwest of Sayak shows extremely enriched Sr–Nd isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.71050, ɛ_Nd (t) = − 7.8, T_DM2 (Nd) = 1700 Ma), likely derived from partial melting of ancient continental crust; (3) other granitoids have transitional Sr–Nd compositions between the Sayak and Kt-1 samples, indicating a juvenile lower crust source with the addition of 10–30% of ancient crustal material. The pre-ore magmatism was probably related to partial melting of juvenile lower crust due to northward subduction of the Junggar–Balkhash Ocean, whereas the ore-forming adakitic rocks at Aktogai, Kounrad and Sayak formed by partial melting of thickened lower crust which subsequently delaminated. The ore-forming rocks at Borly, and the later post-ore barren granites, formed by partial melting of juvenile lower crust with normal thickness. This tectonic setting supports the existence of an Andean-type magmatic arc in the Devonian to the Late Carboniferous, resulting from the subduction of the Junggar–Balkhash oceanic plate. The link between whole rock geochemistry and scale of mineralization suggests a higher metallogenic potential for adakitic rocks than for normal arc magmatism.     

Petrogenesis of Neoarchaean volcanic rocks of the MacQuoid supracrustal belt: A back-arc setting for the northwestern Hearne subdomain,western Churchill Province,Canada

Rocks exposed in the MacQuoid-Gibson Lakes region, northwest Hearne subdomain, western Churchill Province, Canada comprise three major lithotectonic assemblages: the Principal volcanic belt; the metasedimentary MacQuoid homocline and; the Cross Bay plutonic complex. Neoarchaean supracrustal rocks of the belt range in age from <2745 to <2672 Ma and were intruded during the interval <2689 to 2655 Ma by diverse plutonic units ranging from gabbro through syenogranite, but greatly dominated by tonalite. Volcanic rocks occur only in the Principal volcanic belt and the MacQuoid homocline, are metamorphosed to amphibolite facies and vary from rare pillowed to common massive basalt and andesite, intercalated with less abundant, thin, dacitic to rhyolitic tuffs, lavas and volcaniclastic rocks. Basalt and andesite are dominated by subalkaline, FeO^T-rich tholeiites with less common calc-alkaline rocks with higher SiO₂ contents and variable trace element contents. Felsic volcanic rocks exhibit calc-alkaline affinities and similarly diverse trace element abundances. The diverse trace element chemistry of the basalt and andesite supports their derivation from a heterogeneous mantle source(s) capable of generating MORB-, Arc-, BABB- and boninite-like rocks. Two geochemically distinct, arc-like suites were generated through contamination of the primary mantle-derived magmas either via assimilation of lower or middle tonalitic crust, or through contamination of their mantle source through subduction. Geochemical features of the felsic volcanic rocks indicate that these formed via both anatexis of crust in the amphibolite ± garnet stability field and via fractionation of more primitive progenitors in mid-upper crustal magma chambers. ɛNd_{t = 2680 Ma} isotopic compositions cluster near depleted mantle, indicating that significant incorporation of older, >2700 Ma crust likely did not occur. ɛNd_{t = 2680 Ma} values for three specimens, one from each of the Arc-like suites and one BABB-like basalt are slightly lower than the remainder, suggesting very minor incorporation of slightly older crust.These features imply that the processes that generated the MacQuoid supracrustal belt required simultaneous tapping of geochemically distinct mantle reservoirs with concomitant anatexis of sialic crust (garnet stability field) and fractionation of felsic magmas in upper crustal magma chambers. Shallow water deposition of abundant volcaniclastic rocks and semipelite along with minor conglomerate and quartzite was broadly contemporaneous with this magmatism. We envisage a geodynamic setting characterized by tectonomagmatic processes similar to those of modern supra-subduction zone back-arc marginal basins such as the Sea of Japan. Therein, an extensional, back-arc setting, likely proximal to continental crust, provides an explanation for a broad swath of diverse mantle-derived rocks intercalated with less common felsic rocks as well as an abundance of immature clastic metasedimentary rocks.     

Tectonic evolution of the eastern Central Asian Orogenic Belt: Evidence from zircon U–Pb–Hf isotopes and geochemistry of early Paleozoic rocks in Yanbian region,NE China

We present the first evidence of an early Paleozoic terrane in the southern Yanbian region, NE China. We used LA-ICP-MS zircon U–Pb and Hf isotope techniques to analyze one plagioclase gneiss and two garnet-bearing two-mica quartz schists from the early Paleozoic Jiangyu Group, as well as two tonalites that intruded the Jiangyu Group. The tonalites yield weighted mean ²⁰⁶Pb/²³⁸U zircon crystallization ages of 423 and 422 Ma. Zircons from the Jiangyu Group gneiss and two schist samples yield maximum depositional ages of 439 ± 4, 443 ± 2, and 443 ± 5 Ma, respectively. These constraints, together with the age of the tonalite intrusion, indicate that the Jiangyu Group was deposited between 443 and 423 Ma (i.e., Silurian). In addition, detrital zircon age spectra of the three Jiangyu Group samples exhibit prominent age peaks at 442, 473, 513, 565, 600, 635, 671, 740, 1000, and 1162 Ma, as well as secondary peaks between 1344 and 3329 Ma. The occurrence of the prominent Meso- and Neoproterozoic detrital zircon age populations for the Jiangyu Group, combined with the corresponding zircon Hf isotopic data, reveals that the Jiangyu Terrane has a tectonic affinity with northeastern Gondwana. The early Paleozoic magmatism, as suggested by the medium-K calc-alkaline I-type tonalite intrusion and Jiangyu Group detrital zircon age spectra, corresponds to coeval subduction–accretion events along the southern margin of the eastern Central Asian Orogenic Belt (CAOB). Accordingly, we propose that the Jiangyu Group is part of an exotic terrane that rifted from northeastern Gondwana, drifted northward, and ultimately became involved in the early Paleozoic tectonic evolution of the southern margin of the eastern CAOB after the Early Cambrian.     

1.3–0.9 Ga Oaxaquia (Mexico): Remnant of an arc/backarc on the northern margin of Amazonia

Rocks with ages of ca. 1 Ga occur in central and southern Mexico as inliers surrounded by ubiquitous Mesozoic and Cenozoic rocks. They appear to share a common history consisting of: (i) ca. 1300–1200 Ma arc magmatism and deposition of sediments including evaporites; (ii) ca.1160–1100 Ma intrusion of syenite, granite and anorthosite, the later part of which is synchronous with migmatization; (iii) intrusion of a ca. 1035–1010 Ma anorthosite–gabbro–charnockite–granite (AMCG) suite; (iv) a 1000–980 Ma granulite facies tectonothermal event with a stretching axis parallel to the long axis of Oaxaquia; (v) gradual exhumation at 750 and/or 545 Ma; and (vi) 517 Ma intrusion of an isolated calcalkaline granitoid pluton. The common Precambrian geological record of these outcrops suggests that they belonged to a single terrane (Oaxaquia) and formed a juvenile arc/backarc bordering a continent that underwent collision with, and overthrusting of, the Avalonian arc at 1000–980 Ma. This buried Oaxaquia to 25–30 km and was followed by further supra-subduction zone magmatism at ca. 917 Ma. These Precambrian rocks are unconformably overlain by uppermost Cambrian and Silurian platform rocks containing Gondwanan fauna and ca. 1 detrital zircons of Oaxacan provenance. The neighbouring Mixteca terrane includes lower Paleozoic, rift-passive margin sedimentary rocks that also contain 900–750 Ma detrital zircons probably derived from the Goiás arc in eastern Amazonia. The arc-backarc tectonic setting inferred for the 1300–900 Ma rocks also suggests that Oaxaquia lay on an active periphery of Amazonia until ca. 900 Ma, well after the amalgamation of Rodinia. This precludes a location for Oaxaquia off southern and western Amazonia that are inferred to have been juxtaposed against eastern Laurentia; contiguity with eastern Amazonia is also unlikely given the absence of the 900–750 Ma convergent tectonics in the Goiás arc. This leaves northern Amazonia as the most likely position, a location that requires the least relative displacement between Oaxaquia and Amazonia. The inferred 750 and 545 Ma exhumation episodes of Oaxaquia correspond to two proposed breakup stages of Rodinia.     

Detrital zircon U–Pb geochronology,trace-element and Hf isotope geochemistry of the metasedimentary rocks in the Eastern Himalayan syntaxis: Tectonic and paleogeographic implications

The origin of the Greater Himalayan Sequence in the Himalaya and the paleogeographic position of the Lhasa terrane within Gondwanaland remain controversial. In the Eastern Himalayan syntaxis, the basement complexes of the northeastern Indian plate (Namche Barwa Complex) and the South Lhasa terrane (Nyingchi Complex) can be studied to explore these issues. Detrital zircons from the metasedimentary rocks in the Namche Barwa Complex and Nyingchi Complex yield similar U–Pb age spectra, with major age populations of 1.00–1.20 Ga, 1.30–1.45 Ga, 1.50–1.65 Ga and 1.70–1.80 Ga. The maximum depositional ages for their sedimentary protoliths are ~ 1.0 Ga based on the mean ages of the youngest three detrital zircons. Their minimum depositional ages are ~ 477 Ma for the Namche Barwa Complex and ~ 499 Ma for the Nyingchi Complex. Detrital zircons from the Namche Barwa Complex and Nyingchi Complex also display similar trace-element signatures and Hf isotopic composition, indicating that they were derived from common provenance. The trace-element signatures of 1.30–1.45 Ga detrital zircons indicate that the 1.3–1.5 Ga alkalic and mafic rocks belt in the southeastern India is a potential provenance. Most 1.50–1.65 Ga zircons have positive ε_Hf(t) values (+ 1.2 to + 9.0), and most 1.70–1.80 Ga zircons have negative ε_Hf(t) values (− 7.1 to − 1.9), which are compatible with those of the Paleo- to Mesoproterozoic orthogneisses in the Namche Barwa Complex. Provenance analysis indicates that the southern Indian Shield, South Lhasa terrane and probably Eastern Antarctica were the potential detrital sources. Combined with previous studies, our results suggest that: (1) the Namche Barwa Complex is the northeastern extension of the Greater Himalaya Sequence; (2) the metasedimentary rocks in the Namche Barwa Complex represent distal deposits of the northern Indian margin relative to the Lesser Himalaya; (3) the South Lhasa terrane was tectonically linked to northern India before the Cambrian.     

Geochronological and geochemical constraints on the petrogenesis of Early Eocene metagabbroic rocks in Nabang (SW Yunnan) and its implications on the Neotethyan slab subduction

Mafic rocks similar to those of the Gangdese belt have been poorly reported in the Nabang area (SW Yunnan Province in SW China) of the Eastern Himalayan Syntaxis. This led to a widely-accepted assumption that Early Eocene mafic rocks are absent in Nabang. This paper reports new zircon U–Pb, Lu–Hf isotopic, whole-rock elemental and Sr–Nd isotopic data for the recently identified Tongbiguan and Jinzhuzhai metagabbroic plutons. Our data show that the two mafic plutons crystallized at 53.2 ± 0.4 Ma and 53.6 ± 0.7 Ma, respectively, with zircon in-situ ε_Hf(t) values ranging from − 3.1 to + 4.9. Our data confirm the presence of Early Eocene mafic rocks in Nabang, contemporaneous with the major magmatic flare-ups of ~ 52 Ma in South Tibet. The rocks show high-K calc-alkaline basalt and basaltic andesite composition. They are characterized by subparallel spiky patterns with enrichment in LILEs, depletion in HFSEs and P–Ti negative anomalies. They show (Nb/La)n = 0.21–0.63, Ce/Pb = 2.99–9.91 and Nb/U = 5.2–14.1, along with high ⁸⁷Sr/⁸⁶Sr(t) ratios of 0.7061–0.7077 and ε_Nd(t) values of − 3.4 to − 5.6. Such geochemical signatures are similar to those of the synchronous Dangxung gabbroic and Yangbajing ultrapotassic rocks. Their least-contaminated samples can petrogenetically be attributed to input of slab-derived fluid into the lithospheric mantle. In conjunction with other available data, the mafic suite can be geochronologically and geochemically correlated to those in South Lhasa and are probably the equivalents of the Gangdese southeastward extension. Their formation might tectonically be related to slab rollback in response to the decreasing convergence rate. The termination of the Neotethyan subduction in SW Yunnan might be later than ~ 52 Ma, identical to that in South Tibet.     

Age and petrogenesis of the Neoproterozoic Chon-Ashu alkaline complex,and a new discovery of chalcopyrite mineralization in the eastern Kyrgyz Tien Shan

Neoproterozoic volcanics and granitoids formed at Rodinia margins within a time span of 880 Ma–700 Ma, are well-documented in many terranes of the southern Central Asian Orogenic Belt (CAOB). Ages younger than 550 Ma corresponding to the opening of the Terskey Ocean are also common. However, so far, there were very few published ages in the range 700 Ma–550 Ma from the Kyrgyz Tien Shan. In this paper we present new data for the alkaline Chon-Ashu complex emplaced at the end of the Cryogenian Period of the Neoproterozoic (850–635 Ma, Gradstein et al., 2012). The alkaline complex intrudes the Precambrian metamorphic rocks north of the Nikolaev Line which separates the Northern and Middle Tien Shan terranes in the eastern Kyrgyzstan. The undeformed shallow level alkaline rocks range from olivine gabbro to nepheline and cancrinite syenites and leucosyenites. The differentiated rock assemblage can be explained by fractional crystallization of high-silica mineral phases which drives nepheline-normative melts away from the silica saturation boundary. The alkaline rocks of Chon-Ashu are enriched in LILE and HFSE indicative of their origin from lithospheric mantle. An age of 678 ± 9 Ma (U–Pb, SHRIMP) was obtained for a protolith of country gneiss, and an age of 656 ± 4 Ma was obtained for the crosscutting alkaline rocks of the Chon-Ashu complex. Seven zircon grains recovered from gneiss and alkaline rocks had bright overgrown rims which yielded a cumulative age of 400 ± 8 Ma. A metamorphic event, followed by uplift and emplacement of shallow level alkaline complex, constrains the geodynamic setting. Alkaline rocks usually form in an extensional setting and originate from lithospheric mantle. The 690 Ma xenoliths of mafic granulite from the NW Tarim have been interpreted to originate by mafic underplating. This mafic underplating may have been responsible for metamorphism in the middle crust prior to emplacement of the Chon-Ashu complex. The 670 Ma–630 Ma period of extension and emplacement of enriched alkaline rocks can be also traced on a regional scale through southern Kazakhstan and the northern Tarim. We tentatively interpret these events as a result of mafic underplating and subsequent rifting related to the break-up of Rodinia. During field work at Chon-Ashu, rich chalcopyrite mineralization has been discovered in carbonate veinlets in leucosyenite alkaline dikes and has also been found in the adjacent Cambrian gabbro and granites shown on the map as undivided Devonian–Silurian. Stockwork mineralization predominates though disseminated mineralization is also present. The Cu content reaches 16,184 ppm and is associated with elevated concentrations of Pb, Zn and Ag. The polyphase structural evolution of the area suggests that mineralization could have formed in several genetically unrelated stages. Based on structural and mineralogical evidence we tentatively relate the earliest stage of chalcopyrite mineralization to the late magmatic CO₂-rich fluids emanating from the Cryogenian alkaline complex. The Early Devonian thermal event registered by growth of new zircon at 400 Ma has important metallogenic implications on a regional scale. However the origin of two zones of alteration in the undivided Silurian–Devonian granites is ambiguous because their age was not determined geochronologically. The 522 ± 4 Ma Cambrian gabbro of the Tashtambektor Formation is strongly foliated along the splays of the Nikolaev Line, indicating a Hercynian origin of the fabric. Superimposed mineralized stockwork postdates the foliation and suggests a late-Hercynian age of mineralization in gabbro. The new data enable a reassessment of the metallogenic potential of the Eastern Kyrgyz Tien Shan. Presence of not eroded high-level mineralized Neoproterozoic alkaline intrusions points to a previously underestimated metallogenic potential of pre-Hercynian granitoids which may host preserved porphyry systems, skarns and shear-related mineralization. Finally, the Devonian magmato-metamorphic event which caused formation of a number of ore deposits in central Kyrgyzstan and Kazakhstan could also create potential exploration targets in eastern Kyrgyzstan.     

Triassic volcanism in eastern Heilongjiang and Jilin provinces,NE China: Chronology,geochemistry, and tectonic implications

With the aim of constraining the Early Mesozoic tectonic evolution of the eastern section of the Central Asian Orogenic Belt (CAOB), we undertook zircon U–Pb dating and geochemical analyses (major and trace elements, Sr–Nd isotopes) of volcanic rocks of the Luoquanzhan Formation and Daxinggou Group in eastern Heilongjiang and Jilin provinces, China. The analyzed rocks consist mainly of dacite and rhyolite, with SiO₂ contents of 68.52–76.65 wt%. Three samples from the Luoquanzhan Formation and one from the Daxinggou Group were analyzed using laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) U–Pb zircon techniques. Three zircons with well-defined oscillatory zoning yielded weighted mean ²⁰⁶Pb/²³⁸U ages of 217 ± 1, 214 ± 2, and 208 ± 1 Ma, and one zircon with oscillatory zoning yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 201 ± 1 Ma. These ages are interpreted to represent the timing of eruption of the volcanic rocks. The Triassic volcanic rocks are characterized by high SiO₂ and low MgO concentrations, enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), depletion in high field strength elements (HFSEs) and heavy rare earth elements (HREEs), (⁸⁷Sr/⁸⁶Sr)_i = 0.7040–0.7050 (Luoquanzhan Formation) and 0.7163–0.7381 (Daxinggou Group), and ε_Nd (t) = 1.89–3.94 (Luoquanzhan Formation) and 3.42–3.68 (Daxinggou Group). These geochemical features indicate an origin involving the partial melting of juvenile lower crust (Nd model ages (T_DM2) of 651–821 Ma) and that compositional variation among the volcanic rocks arose from mineral fractionation and minor assimilation. These volcanic rocks formed within an extensional environment following collision of the NCC and Jiamusi-Khanka Massif during the Late Paleozoic–Early Triassic.     

The Zhaheba ophiolite complex in Eastern Junggar (NW China): Long lived supra-subduction zone ocean crust formation and its implications for the tectonic evolution in southern Altaids

The composite Zhaheba ophiolite complex, exposed in Eastern Junggar in the Southern Altaids, records an unusually long record of oceanic crust and magmatic arc evolution. The Zhaheba ophiolite complex consists of ultramafic rocks, gabbro, diorite, basalt and chert intruded by diabase dikes and diorite porphyry. These rocks are overlain by a several-km-thick section of tuffaceous rocks, volcaniclastic sedimentary rocks, and intermediate volcanic rocks. The igneous rocks of the ophiolite complex show negative Nb and Ta anomalies and LREE enrichment relative to HREE, suggesting the influence of fluids derived from a subducting oceanic slab. The LA-ICPMS U–Pb age of zircons from gabbro is 495.1 ± 3.5 Ma. Zircon ages from diorite and basalt are 458.3 ± 7.2 Ma and 446.6 ± 6.0 Ma, respectively. The basalt is locally overlain by bedded chert. Diabase dikes and diorite porphyry yield the U–Pb ages of 421.5 ± 4.1 Ma and 423.7 ± 6.5 Ma, respectively. The age of stratigraphically lower part of the overlying volcanic–volcaniclastic section is constrained to be about 410 Ma, the maximum depositional age of the tuffaceous sandstone from U–Pb detrital zircon ages. Late rhyolite at the top of the stratigraphic section yielded a U–Pb zircon age of 280.3 ± 3.7 Ma. The age and stratigraphic relationships for the Zhaheba ophiolite complex and related rocks suggest that the period of ~ 70 Ma of initial supra-subduction magmatism was followed by construction of a mature island arc that spanned an additional 140 Ma. Many other ophiolites in the southern Altaids appear to record similar relationships, and are represented as substrates of oceanic island arcs covered by island arc volcanism in supra-subduction zone. The occurrence of the Zhaheba ophiolite complex with tuffaceous and intermediate to felsic volcanic rocks is different from the rock association of classic Tethyan SSZ ophiolites but similar to some ophiolites in North America. Although the Zhaheba ophiolite belt is flanked by the Dulate arc in the north and Yemaquan arc in the south, it cannot stand a suture between two arcs. It is suggested that Devonian–Carboniferous Dulate arc was built on the late Cambrian–middle Ordovician Zhaheba supra-subduction oceanic crust. The late Carboniferous rocks and early Permian rocks in Dulate arc are interpreted to form in the extensional process within Zhaheba–Dulate arc composite system.     

Crustally-derived granites in the Panzhihua region,SW China: Implications for felsic magmatism in the Emeishan large igneous province

In the Panxi region of the Late Permian (~ 260 Ma) Emeishan large igneous province (ELIP) there is a bimodal assemblage of mafic and felsic plutonic rocks. Most Emeishan granitic rocks were derived by differentiation of basaltic magmas (i.e. mantle-derived) or by mixing between crustal melts and primary basaltic magmas (i.e. hybrid). The Yingpanliangzi granitic pluton within the city of Panzhihua intrudes Sinian (~ 600 Ma) marbles and is unlike the mantle-derived or hybrid granitic rocks. The SHRIMP zircon U–Pb ages of the Yingpanliangzi pluton range from 259 ± 8 Ma to 882 ± 22 Ma. Younger ages are found on the zircon rims whereas older ages are found within the cores. Field relationships and petrography indicate that the Yingpanliangzi pluton must be < 600 Ma, therefore the older zircons are interpreted to represent the protolith age whereas the younger analyses represent zircon re-crystallization during emplacement. The Yingpanliangzi granites are metaluminous and have negative Ta–Nb_PM anomalies, low εNd_{(260 Ma)} values (? 3.9 to ? 4.4), and high I_Sr (0.71074 to 0.71507) consistent with a crustal origin. The recognition of a crustally-derived pluton along with mantle-derived and mantle–crust hybrid plutons within the Panxi region of the ELIP is evidence for a complete spectrum of sources. As a consequence, the types of Panxi granitoids can be distinguished according to their ASI, Eu/Eu*, εNd_(T), εHf_(T), T_Zr(°C) and Nb–Ta_PM values. The diverse granitic magmatism during the evolution of the ELIP from ~ 260 Ma to ~ 252 Ma demonstrates the complexity of crustal growth associated with LIPs.     

Subduction-related metasomatic mantle source in the eastern Central Asian Orogenic Belt: Evidence from amphibolites in the Xilingol Complex,Inner Mongolia,China

The Central Asian Orogenic Belt (CAOB) formed mainly in the Paleozoic due to the closure of the Paleo-Asian oceanic basins and accompanying prolonged accretion of pelagic sediments, oceanic crust, magmatic arcs, and Precambrian terranes. The timing of subduction–accretion processes and closure of the Paleo-Asian Ocean has long been controversial and is addressed in a geochemical and isotopic investigation of mafic rocks, which can yield important insight into the geodynamics of subduction zone environments. The Xilingol Complex, located on the northern subduction–accretion zone of the CAOB, mainly comprises strongly deformed quartzo-feldspathic gneisses with intercalated lenticular or quasi-lamellar amphibolite bodies. An integrated study of the petrology, geochemistry, and geochronology of a suite of amphibolites from the complex constrains the nature of the mantle source and the tectono-metamorphic events in the belt. The protoliths of these amphibolites are gabbros and gabbroic diorites that intruded at ca. 340–321 Ma with positive εHf_(t) values ranging from + 2.89 to + 12.98. Their T_DM1 model ages range from 455 to 855 Ma and peak at 617 Ma, suggesting that these mafic rocks are derived from a depleted continental lithospheric mantle. The primitive magma was generated by variable degrees of partial melting of spinel-bearing peridotites. Fractionation of olivine, clinopyroxene and hornblende has played a dominant role during magma differentiation with little or no crustal contamination. The mafic rocks are derived from a Late Neoproterozoic depleted mantle source that was subsequently enriched by melts affected by slab-derived fluids and sediments, or melts with a sedimentary source rock. The Carboniferous mafic rocks in the northern accretionary zone of the CAOB record a regional extensional event after the Early Paleozoic subduction of the Paleo-Asian Ocean. Both addition of mantle-derived magmas and recycling of oceanic crust played key roles in significant Late Carboniferous (ca. 340–309 Ma) vertical crustal growth in the CAOB. Amphibolite–facies metamorphism (P = 0.34–0.52 GPa, T = 675–708 °C) affected these mafic rocks in the Xilingol Complex at ca. 306–296 Ma, which may be related to the crustal thickening by northward subduction of a forearc oceanic crust beneath the southern margin of the South Mongolian microcontinent. The final formation of the Solonker zone may have lasted until ca. 228 Ma.     

Carpathian peri-Gondwanan terranes in the East Carpathians (Romania): A testimony of an Ordovician,North-African orogeny

The eastern branch of the Romanian Carpathians – the East Carpathians – is essentially an Alpine thrust and fold belt made up in its median part by a Crystalline–Mesozoic zone. This, in turn, is built up by several Alpine nappes (top to bottom): the Wildflysch, Bucovinian, Subbucovinian and Infrabucovinian. In the basement of the Bucovinian and Subbucovinian nappes the following Variscan tectonic units have been identified (top to bottom): Rar?u, Putna, Pietrosu Bistri?ei and Rodna. The Infrabucovinian nappes comprise the Rar?u nappe only. The Alpine nappes have an eastward vergence, opposite to the Variscan ones (present coordinates). In terms of pre-Variscan terranes distribution, the Rar?u nappe involved the Bretila terrane basement and its late Paleozoic cover, Putna the Tulghe? terrane basement, Pietrosu Bistri?ei the Negri?oara terrane basement and Rodna the Rebra terrane basement. These terranes originated along northwestern Gondwana margin during some Ordovician thermotectonic events. They do not represent Cadomian terranes and we call them Carpathian-type terranes. Two igneous protoliths from Bretila terrane basement (i.e. Anie? orthogneiss and H?ghima? granitoid) yield U/Pb LA-ICP-MS zircon ages of 462 ± 3 Ma and 469.2 ± 6.5 Ma, respectively. An orthogneiss from Tulghe? terrane basement yield 462.6 ± 3.1 Ma; the Pietrosu porphyritic orthogneiss from Negri?oara terrane basement yield 461.1 ± 5.2 Ma; and the Nichita? orthogneiss from Rebra terrane basement yield 447.9 ± 2.8 Ma. All these ages suggest the magma crystallization time. Two paragneisses from the Rebra terrane basement show a detrital zircon age distribution characteristic of a NE-African provenance. Regarding the tectonic settings, the lithology of the Bretila terrane suggests a magmatic arc on a continental margin, while of the Tulghe? terrane suggests a back arc environment, and those of the Rebra and Negri?oara terranes suggest a passive continental margin. An Ordovician metamorphism of medium grade (staurolite–kyanite zone) affected the basements of Bretila, Negri?oara and Rebra terranes, whereas a low grade (chlorite to biotite zone) event affects the Tulghe? terrane. With regard to the Variscan orogeny, the existence of a Paleotethys suture is proposed within the metamorphic basement of the East Carpathians. In this interpretation, the Bretila terrane was the upper plate, the Rebra and Negri?oara terrane pair formed the lower plate and the Tulghe? terrane was a component of the suture. The Variscan thermotectonic events reflect isothermal decompression with andalusite + cordierite in the basement of the Rebra terrane and retrogression in the basement of the other terranes.     

U–Pb zircon geochronology and geochemistry of Neoproterozoic volcanic rocks in the Tarim Block of northwest China: implications for the breakup of Rodinia supercontinent and Neoproterozoic glaciations

As the lowest volcanics-bearing unit of the Neoproterozoic succession, the Beiyixi Formation is the key to understanding the early response to the breakup of the Roninia supercontinent in the Tarim Block. The SHRIMP analyses of zircons from the volcanic rocks at the bottom of the Beiyixi Formation yield a weighted mean ²⁰⁶Pb/²³⁸U age of 755 ± 15 Ma. This is interpreted as the eruption age of the Beiyixi volcanic rocks. The Beiyixi volcanic rocks consist of bimodal basalt and dacite-rhyolite with a SiO₂ gap between 55% and 65%. The mafic rocks display negative ɛ_Nd (755 Ma) values (−9.9 to −10.8), moderate enrichment in LILE and variable depletion in Nb, Ta and P, resembling those of the tholeiitic basalts in continental rift. Geochemical and Nd isotopic characteristics suggest that the mafic rocks were derived from partial melting of an enriched lithospheric mantle reservoir. The felsic rocks show negative ɛ_Nd (755 Ma) values (−7.9 to −9.2), negative Nb, Ta, P and Ti anomalies, very high La_N/Yb_N (62–92) ratios and LILE abundances, and may be generated by melting of eclogites or garnet amphibolites in the lower crust, as a result of basalt emplacement into continental crust during continental rifting. The age of 755 ± 15 Ma indicates that the Beiyixi glaciation took place later than 755 Ma and it could be correlated with the Chang’an glaciation in the Yangtze Block and the Sturtian–Rapitan glaciation in other Rodinia Blocks. The geochemical characteristics of the Beiyixi volcanic rocks resemble those of the rift-related magmatism in other Rodinia Blocks, suggesting that the Beiyixi volcanism was a part of global magmatism during the breakup of Rodinia supercontinent. The age and geochemical features of the Beiyixi volcanic rocks also reveal that the mantle plume activity spread to the northwestern margin of the Rodinia supercontinent and probably resulted in the breakup between Australia and Tarim Blocks.     

Zircon Hf–isotopic mapping for understanding crustal architecture and metallogenesis in the Eastern Qinling Orogen

The Eastern Qinling Orogen (EQO) is a major composite collisional zone located between the North China and the Yangtze cratons. This contribution combines geological and Hf–isotopic data from magmatic rocks associated with mineralization to gain insights into links between the crust architecture and metallogeny, and to focus exploration in the orogen.The new zircon U–Pb dates reported in this study are 434 ± 2 Ma for diorite, 433 ± 2 and 436 ± 2 Ma for monzogranite, and 454 ± 2 Ma for granodiorite in the Nanzhao area; 225 ± 2 Ma for syenite and 160 ± 1 Ma for monzogranite at Songxian; and 108 ± 1 and 102 ± 1 Ma for syenogranite in eastern Fangcheng. Combining our data with those from the entire EQO reveals seven major magmatic events since the Cambrian. These magmatic events took place during the Cambrian–Silurian associated with subduction, Early Devonian magmatism related to a collisional event, Early Permian to Late Triassic magmatism related to subduction, Late Triassic collisional magmatism, Late Triassic to Early Jurassic post–collision magmatism, and Jurassic–Cretaceous magmatism during intra–continental subduction.Lu-Hf isotopic data collected from granitic rocks for this study give εHf(t) values of: − 1.4 to 10.9 for diorite and monzogranite at Nanzhao; − 27.1 to − 15.6 for syenite and − 27.5 to − 25.1 for monzogranite at Songxian; and − 12.9 to − 3.4 for syenogranite in the eastern Fangcheng. Combining Hf isotopic data for the EQO from previous studies, we have evaluated the spatio–temporal distribution of Hf isotopic compositions. The resultant Hf isotopic maps highlight the location of the Kuanping Suture as an important tectonic boundary between the North China and the Yangtze cratons, which separates the EQO into a north part with an old and reworked lower crust and a southern part representing a juvenile lower crust.The Hf isotopic mapping of the EQO also provides information on the distribution of mineral deposits. Porphyry and porphyry–skarn Mo(–W) deposits are associated with magmatic rocks were emplaced in zones with low–εHf and high T_DM^c values representing old and reworked crustal components. In contrast, porphyry and porphyry–skarn Cu(–Mo) deposits are associated with magmatic rocks emplaced in domains with variable εHf and T_DM^c values characterized by dominantly reworked old crustal components with minor juvenile material. The magmatic source for the intrusions is characterized by low–εHf and high T_DM^c values, which are granite–related Mo or Pb–Zn–Ag mineralization.